Did prolonged two-stage fragmentation of the supercontinent Kenorland lead to arrested orogenesis on the southern margin of the Superior province?

Recent geochronological investigations reinforce the early suggestion that the upper part of the Paleoproterozoic Huronian Supergroup of Ontario,Canada is present in the Animikie Basin on the south shore of Lake Superior.These rocks,beginning with the glaciogenic Gowganda Formation,are interpreted as passive margin deposits.The absence of the lower Huronian(rift succession) from the Animikie Basin may be explained by attributing the oldest Paleoroterozoic rocks in the Animikie Basin(Chocolay Group)to deposition on the upper plate of a north-dipping detachment fault,which lacks sediments of the rift phase.Following thermal uplift that led to opening of the Huronian Ocean on the south side of what is now the Superior province,renewed uplift(plume activity) caused large-scale gravitational folding of the Huronian Supergroup accompanied by intrusion of the Nipissing diabase suite and Senneterre dikes at about 2.2 Ga.Termination of passive margin sedimentation is normally followed by ocean closure but in the Huronian and Animikie basins there was a long hiatus- the Great Stratigraphic Gap- which lasted for about 350 Ma.This hiatus is attributed to a second prolonged thermal uplift of part of Kenorland that culminated in complete dismemberment of the supercontinent shortly before 2.0 Ga by opening of the Circum-Superior Ocean.These events caused regional uplift(the Great Stratigraphic Gap) and delayed completion of the Huronian Wilson Cycle until a regional compressional tectonic episode,including the Penokean orogeny,belatedly flooded the southern margin of the Superior province with foreland basin deposits,established the limits of the Superior structural province and played an important role in constructing Laurentia.     

Iron-formation and glaciogenic rocks of the Rapitan Group,Northwest Territories,Canada

In northwestern Canada, iron-formation occurs as part of the Rapitan Group, a dominantly sedimentary succession of probable Late Precambrian age. The Rapitan Group contains abundant evidence of glaciogenic deposition. It includes massive mixtites which contain numerous faceted and striated clasts. Finely bedded and laminated sedimentary rocks of the Lower Rapitan contain many large isolated (ice-rafted?) intra- and extra-basinal clasts. The Lower and Middle Rapitan are interpreted as products of a glacial marine regime. The iron-formation is interbedded with thin mixtite beds and contains large exotic clasts which are probably indicative of the existence of floating ice at the time of deposition of at least part of the iron-formation. If the apparently low paleolatitudes are confirmed, then glacial marine interpretation of the Rapitan, and the probably correlative Toby Conglomerate of southern British Columbia, support the postulate of a very extensive Late Precambrian ice sheet in North America.Similar iron-formations of similar age are present in South America (Jacadigo Series), in South-West Africa (Damara Supergroup) and in South Australia (Yudnamutana Sub-Group). All of these iron-formations are associated with glaciogenic rocks. In addition to the iron-formations, dolostones, limestones and evaporites (?) are intimately associated with Late Precambrian mixtites, considered by many to be glaciogenic.Huronian (Early Proterozoic) and correlative sequences of North America, and rocks of similar age in South Africa also contain closely juxtaposed undoubted glaciogenic rocks, iron-formations, dolostones and aluminous quartzites. The dolostones and aluminous sedimentary rocks have been interpreted as having formed under warm climatic conditions, but might also be explained by invoking higher P_CO2 levels in the Early Proterozoic atmosphere. By analogy with the Huronian succession, preservation of “warm climate” indicators in mixtite-bearing Late Precambrian sequences does not preclude a glacial origin for the mixtites.     

Neoproterozoic banded iron formations

Two epochs of the formation of ferruginous quartzites—Archean-Paleoproterozoic (3.2–1.8 Ga) and Neoproterozoic (0.85–0.7 Ga)—are distinguished in the Precambrian. They are incommensurable in scale: the Paleoproterozoic Kursk Group of the Kursk Magnetic Anomaly (KMA) extends over 1500 km, whereas the extension of Neoproterozoic banded iron formations (BIF) beds does not exceed a few tens of kilometers. Their thickness is up to 200 m and not more than 10 m, respectively. The oldest BIFs are located in old platforms, whereas Neoproterozoic BIFs are mainly confined to Phanerozoic orogenic (mobile) zones. Neoproterozoic BIFs universally associate with glacial deposits and their beds include glacial dropstones. In places, they underlie tillites of the Laplandian (Marinoan) glaciation (635 Ma), but they are more often sandwiched between glaciogenic sequences of the Laplandian and preceding Sturtian or Rapitan glaciation (730–750 Ma). Neoproterozoic BIFs are rather diverse in terms of lithology due to variation in the grade of metamorphism from place to place from low grades of the greenschist facies up to the granulite facies. Correspondingly, the ore component is mainly represented by hematite or magnetite. The REE distribution and (Co + Ni + Cu) index suggest an influence of hydrothermal sources of Fe, although it was subordinate to the continental washout. Iron was accumulated in seawater during glaciations, whereas iron mineralization took place at the earliest stages of postglacial transgressions.     

Rare earth elements in Huronian (Lower Proterozoic) sedimentary rocks: Composition and evolution of the post-Kenoran upper crust

The Huronian sequence (Lower Proterozoicl. north of Lake Huron, contains tillites and abundant fine-grained sedimentary rocks. Analyses of rare earth elements (REE) in the matrix of tillite samples from the Gowganda Formation (~ 2.3 Gal is considered to be a reasonable estimate of upper crustal REE abundances for the region north of Lake Huron at the time of Gowganda deposition. The average is characterized by a moderately steep pattern (σLREEσHREE = 9.1) and a slight negative europium anomaly ($\text{Eu}\text{Eu1}\text{= 0.89}$). This pattern is similar to estimates of the composition of the surface of the Canadian Shield and is intermediate between estimates of typical Archean and post-Archean sedimentary rocks. REE patterns for framework granitoid clasts from the tillite suggest that K-rich granites, which were apparently unimportant in the formation of Archean sedimentary rocks, were abundant in the source regions of the Gowganda Formation. This may explain the intermediate nature of the Gowganda pattern.Comparison of the tillites and associated Gowganda mudstones suggests that previous estimates of upper crustal REE abundances, which were based on the analyses of fine-grained sedimentary rocks, may be systematically high. Relative distributions, however, are the same.Analyses of mudstones from the McKim. Pecors. Serpent Gowganda Lorrain and Gordon Lake Formations suggest rapid evolution in the composition of the exposed upper crust at the close of the Kenoran orogeny. REE patterns at the base of the Huronian are similar to typical Archean sedimentary rocks. REE characteristics change up section: patterns at the top resemble typical post-Archean sedimentary rocks.It is inferred that an essentially episodic change from an early exposed upper crust dominated by a tonalite-greenstone suite to one approximating granodioritic composition is recorded in Huronian sedimentary rocks. A deviation from the evolutionary trend of the Huronian, documented in the Gowganda Formation, may be related to the glacial origin of the Gowganda.     

Origin and distribution of gold in the Huronian Supergroup, Canada — the case for Witwatersrand-type paleoplacers

Field observations and experimental results show that gold is mobile under a wide range of natural conditions in the surficial environment. However, the extent to which, and the form(s) in which gold was mobile in ancient placers remains speculative. Rather more convincing is the extent to which diagenetic and metamorphic processes have been active in redistributing the gold.Huronian paleoplacer gold deposits span a critical transition in Earth history, namely, the oxyatmoversion, evidence for which exists in the upper Gowganda Formation dated at 2.288 Ga. Prior to this transition, deposition of gold occurred under reducing atmospheric conditions, with transportation of the more finely-divided material possibly as organic-protected colloids, as has been suggested for the Witwatersrand. Following the oxyatmoversion, gold deposition will have been subject to secondary enrichment, like many Phanerozoic placer gold occurrences. For this reason, and on purely sedimentological grounds, upper Huronian strata ought to have as much potential for hosting economic deposits of gold as the basal units.A total of 121 Au and Au---U occurrences, including several past and presently producing mines from the Huronian Supergroup, are examined. These are classified according to whether mineralization is: in or adjacent to diabase dikes (11 cases); in (quartz, quartz—carbonate) veins (85 cases); stratiform (25 cases). Of the non-diabase-hosted occurrences, 41.3% occur in the Cobalt Group, 15.7% in the Quirke Lake Group, 24.9% in the Hough Lake Group and 9% in the Elliott Lake Group.Frequency of occurrence can be related to transgressive sedimentary cycles, with deposits concentrated in the Matinenda, Mississagi and Gowganda Formations, which immediately overlie the Archean—Huronian unconformity. Most of the deposits occur in the Gowganda Formation, although none of these is stratiform.In terms of Au content, there is a large overlap in class intervals of stratiform vein deposits. Vein deposits are, in general, richer than stratiform by a factor of 10. Selected stratiform deposits in the Matinenda, Mississagi and Serpent Formations are examined in light of available geological and geochemical data. In these deposits, anomalous gold values in dominantly quartzitic metasediments are accompanied by fine-grained pyrite and other heavy minerals, including uranium, which occurs in most, but not all cases. Metamorphic grade ranges from upper greenschist to lower amphibolite facies. A few of the stratiform occurrences are accompanied by accumulations of carbonaceous material, an association reminiscent of the Witwatersrand goldfields.Results of electron-microprobe study indicate that much of the gold in the Huronian metasediments occurs as low level concentrations in pyrite of morphologically different types, in arsenopyrite, chalcopyrite, and in pyrrhotite variously altered to marcasite. It is clear that Huronian paleoplacer gold deposits exist, but only in conditions much modified by diagenetic and metamorphic processes.     

A fundamental Precambrian–Phanerozoic shift in earth's glacial style?

It has recently been found that Neoproterozoic glaciogenic sediments were deposited mainly at low paleolatitudes, in marked qualitative contrast to their Pleistocene counterparts. Several competing models vie for explanation of this unusual paleoclimatic record, most notably the high-obliquity hypothesis and varying degrees of the snowball Earth scenario. The present study quantitatively compiles the global distributions of Miocene–Pleistocene glaciogenic deposits and paleomagnetically derived paleolatitudes for Late Devonian–Permian, Ordovician–Silurian, Neoproterozoic, and Paleoproterozoic glaciogenic rocks. Whereas high depositional latitudes dominate all Phanerozoic ice ages, exclusively low paleolatitudes characterize both of the major Precambrian glacial epochs. Transition between these modes occurred within a 100-My interval, precisely coeval with the Neoproterozoic–Cambrian “explosion” of metazoan diversity. Glaciation is much more common since 750 Ma than in the preceding sedimentary record, an observation that cannot be ascribed merely to preservation. These patterns suggest an overall cooling of Earth's longterm climate, superimposed by developing regulatory feedbacks involving an increasingly complex biosphere.     

One,two or no record of late neoproterozoic glaciation in South-East Cameroon?

Severe climate changes culminating in at least three major glacial events have been recognized in the Neoproterozoic sedimentary record from many parts of the world. Supportive to the global nature of these climatic shifts, a considerable amount of data have been acquired from deposits exposed in Pan-African orogenic belts in southwestern and western Africa. By comparison, published data from the Pan-African belts in Central Africa are scarce. We report here evidence of possibly two glacial events recorded in the Mintom Formation that is located on the margin of the Pan-African orogenic Yaoundé belt in South-East Cameroon.In the absence of reliable radiometric data, only maximum and minimum age limits of 640 and 580 Ma, respectively, can at present be applied to the Mintom Formation. The formation consists of two lithostratigraphic ensembles, each subdivided in two members (i.e., in ascending stratigraphic order the Kol, Métou, Momibolé, and Atog Adjap Members). The basal ensemble exhibits a typical glacial to post-glacial succession. It includes diamictites comprising cobbles and boulders in a massive argillaceous siltstone matrix, and laminated siltstones followed by, in sharp contact, a 2 m-thick massive dolostone that yielded negative δ¹³C values (<?3‰ V-PDB) similar to those reported for Marinoan cap carbonates elsewhere. However, uncertainty remains regarding the glacial influence on the siliciclastic facies because the diamictite is better explained as a mass-flow deposit, and diagnostic features such as dropstones have not been seen in the overlying siltstones. The Mintom Formation may thus provide an example of an unusual succession of non-glacial diamictite overlain by a truly glacial melt-related cap-carbonate.We also report the recent discovery of ice-striated pavements on the structural surface cut in the Mintom Formation, suggesting that glaciers developed after the latter had been deposited and deformed during the Pan-African orogeny. Striations, which consistently exhibit two principal orientations (N60 and N110), were identified in two different localities, in the west of the study area on siltstones of the Kol Member, and in the east on limestones of the Atog Adjap Member, respectively. N60-oriented striae indicate ice flow towards the WSW. Assigning an age to these features remains problematical because they were not found associated with glaciogenic deposits. Two hypotheses can equally be envisaged, i.e., either the striated surfaces are correlated: (1) to the Gaskiers (or Neoproterozoic post-Gaskiers) glaciation and represent the youngest Ediacaran glacial event documented in the southern Yaoundé belt; or (2) to the Late Ordovician Hirnantian (Saharan) glaciation, thereby providing new data about Hirnantian ice flows in Central Africa.     

http://www.sciencedirect.com/science/article/pii/S1674987113000297

This paper compiles lithostratigraphic and geochronological data obtained for the Palaeoproterozoic glacial diamictite-bearing successions,and thereby provides insights into understanding the geological processes causing the Huronian Glaciation Event.The majority of evidence for appearances of this glaciation event can be related to the Kenorland supercontinent breakup,allied to significant atmospheric change,as well as blooms of biogeochemical oxygenic photosynthesis.In this paper,the Huronian Glaciation Event is constrained to have occurred synchronously during 2.29-2.25 Ga,accompanied by dramatic environmental changes characteristic of the Great Oxidation Event which includes the pre- 2.3 Ga hydrosphere oxidation and the post-2.3 Ga atmosphere oxygenation.     

Sedimentation on an early Proterozoic continental margin under glacial influence: the Gowganda Formation (Huronian), Elliot Lake area, Ontario, Canada

Eight continuous cores up to 150 m long and spaced an average of 200 m apart yield a detailed local insight into the composition and architecture of an ancient continental margin sequence, the Gowganda Formation (early Proterozoic: Huronian) near Elliot Lake, Ontario. Nearby outcrops of similar facies provide important supplementary data on sedimentary structures. Continental glaciers provided an abundant supply of coarse debris but, apart from rafting of debris by floating ice, played little or no part in Gowganda sedimentation. The basal 50 m of the Gowganda Formation in the drill-hole area represents a continental slope depositional system. It consists mainly of gravelly and sandy sediment gravity flow deposits, interbedded with minor rain-out units of diamictite, and argillite containing dropstones. Ten types of sediment gravity flow deposit are distinguished. An overlying submarine-channel depositional system, 10–50m thick, consists of hemipelagic argillites containing dropstones and showing deformation structures. These are interbedded with well-sorted channel-fill sandstones. Submarine point bars 4·5 m thick (identified in nearby outcrops) demonstrate a meandering channel geometry. This channel-fill sequence probably formed during a period of high sea-level and reduced sediment supply, but the relationship to ice advance-retreat cycles is unclear. The subsurface sequence is completed by a blanket of massive rain-out diamictites up to 55 m thick, and a younger slope sequence of sediment gravity flow diamictites and sandstones. The stratigraphy is quite different in outcrop section 10 km to the west of the drill-holes, suggesting the presence of major lateral facies changes and/or internal erosion surfaces within the Gowganda Formation. This complexity of stratigraphy and depositional processes is probably a feature of many ancient glacial units, and points to the advisability of not making climatic or tectonic interpretations from a few generalized or composite sections.     

Climatic catastrophes in Earth history: two great Proterozoic glacial episodes

Near the beginning and end of the Proterozoic Eon (2.5 Ga–542 Ma) the Earth went through dramatic climatic perturbations. The Palaeoproterozoic (Huronian) glaciations are best known from the Canadian Shield where there is evidence of at least three such episodes. Glacial deposits of comparable age are also known from Fennoscandia, South Africa and Western Australia. In the type area, the Huronian glacial deposits are preserved in an ancient rift system that preceded break‐up of the supercraton, Kenorland, whereas those in the southern hemisphere may have been deposited in a foreland basin setting. Detailed correlations between the two hemispheres must await more geochronological data. Following a long period (~1.5 Ga) with little evidence of glaciation, the climatic upheavals of the Neoproterozoic Era began. The two most widespread glacial events are known as the Sturtian and Marinoan. The Neoproterozoic glaciations also took place on a supercontinent (Rodinia). Some were accompanied by unexpected rock types such as dolomitic cap carbonates and iron formations, both of which show evidence of hydrothermal influence. Major influences on surface temperatures on Earth include solar luminosity (increasing throughout geological history) and the concentration of atmospheric greenhouse gases such as CO₂ (generally diminishing with time). It is suggested that the two great Proterozoic climatic oscillation periods resulted from perturbations of the balance between these two variables, triggered by drawdown of atmospheric CO₂ during intensive weathering of supercontinents. A weathering‐related negative feedback loop resulted in multiple glaciations with intervening warm periods. Climatic stability only returned after the supercontinent broke apart and reduced continental freeboard moderated continental weathering. Copyright © 2012 John Wiley & Sons, Ltd.     

Palaeoenvironments and weathering regime of the Neoproterozoic Squantum ‘Tillite’, Boston Basin: no evidence of a snowball Earth

The snowball Earth hypothesis describes episodes of Neoproterozoic global glaciations, when ice sheets reached sea‐level, the ocean froze to great depth and biota were decimated, accompanied by a complete shutdown of the hydrological cycle. Recent studies of sedimentary successions and Earth systems modelling, however, have brought the hypothesis under considerable debate. The Squantum ‘Tillite’ (Boston Basin, USA), is one of the best constrained snowball Earth successions with respect to age and palaeogeography, and it is suitable to test the hypothesis for the Gaskiers glaciation. The approach used here was to assess the palaeoenvironmental conditions at the type locality of the Squantum Member through an analysis of sedimentary facies and weathering regime (chemical index of alteration). The stratigraphic succession with a total thickness of ca 330 m documents both glacial and non‐glacial depositional environments with a cool‐temperate glacial to temperate non‐glacial climate weathering regime. The base of the succession is composed of thin diamictites and mudstones that carry evidence of sedimentation from floating glacial ice, interbedded with inner shelf sandstones and mudstones. Thicker diamictites interbedded with thin sandstones mark the onset of gravity flow activity, followed by graded sandstones documenting channellized mass gravity flow events. An upward decrease in terrigenous supply is evident, culminating in deep‐water mudstones with a non‐glacial chemical weathering signal. Renewed terrigenous supply and iceberg sedimentation is evident at the top of the succession, beyond which exposure is lost. The glacially influenced sedimentary facies at Squantum Head are more consistent with meltwater dominated alpine glaciation or small local ice caps. The chemical index of alteration values of 61 to 75 for the non‐volcanic rocks requires significant exposure of land surfaces to allow chemical weathering. Therefore, extreme snowball Earth conditions with a complete shutdown of the hydrological cycle do not seem to apply to the Gaskiers glaciation.     

黔西南二叠纪早期陆源碎屑沉积体系对冈瓦纳冰川发育的响应

通常认为黔西南和黔南地区二叠纪栖霞组之下的一套陆缘碎屑岩地层,是石炭纪-二叠纪冈瓦纳大陆冰盖发育鼎盛时期大幅度海平面下降期间的沉积。最新研究表明,石炭纪-二叠纪冈瓦纳冰川是由多次不连续的冰川事件构成的。因此恢复该套以陆源碎屑岩为主地层的形成环境和堆积过程,探讨其成因与冈瓦纳冰川发育的关系,具有非常重要的科学意义。本研究查明了黔西南地区该套陆源碎屑岩的地层厚度和砂泥比值空间变化规律。在此基础上,选取碎屑岩发育最好的普安龙吟剖面开展沉积体系与成因研究。结果表明,沙子塘组主要是碳酸盐沉积体系,龙吟组和包磨山组主要为浅海陆棚三角洲沉积体系,梁山组以滨岸陆源碎屑沉积体系为主;二叠纪早期黔西南地区的陆棚相泥岩形成于冰川消融导致的海平面快速上升期间,三角洲沉积体系形成于海平面晚期高位域期间,而不是形成于冈瓦纳冰川增长期间的低位域沉积。冈瓦纳冰川的推进和消融是龙吟剖面二叠纪早期地层发育样式的主控因素。     

山西芮城水峪地区罗圈组海侵沉积物

华北陆块南缘、西南缘广泛分布的罗圈组及其相应地层多被认为是新元古代末期冰川沉积。山西南部芮城水峪剖面位于华北南缘罗圈组出露范围的最北端,罗圈组受下伏蓟县系龙家园组白云岩风化面形态控制,横向岩性变化剧烈,分别由准原地堆积的风化角砾岩、紫红色含砾泥岩及一套特殊的"含砾砂质鲕粒白云岩"组成,均为温暖气候下海侵或海侵改造产物,与冰川作用无关。"含砾砂质鲕粒白云岩"在华北南缘罗圈组中尚属首次发现,具有明显的指相意义。该地区罗圈组海侵沉积物的存在,可能表明华北南缘罗圈组在各地区存在沉积环境乃至地层时代的巨大差异,不能简单以某一冰期的"冰碛岩"笼统看待。     

Proterozoic (pre-Ediacaran) glaciation and the high obliquity,low-latitude ice,strong seasonality (HOLIST) hypothesis: Principles and tests

Sedimentological observations and palaeomagnetic data for Cryogenian glacial deposits present the climatic paradox of grounded glaciers and in situ cold climate near sea-level, glaciomarine deposition, and accompanying large (up to 40 °C) seasonal changes of temperature, all in low to near-equatorial (< 10°) palaeolatitudes (equated with geographic latitudes). Neither the “snowball Earth” nor the “slushball Earth” hypothesis can account for such strong seasonality near the palaeoequator, which together with findings from sedimentology, chemostratigraphy, biogeochemistry, micropalaeontology, geochronology and climate modelling argue against those scenarios. An alternative explanation of glaciation and strong seasonality in low palaeolatitudes is offered by a high (> 54°) obliquity of the ecliptic, which would render the equator cooler than the poles, on average, and amplify global seasonality. A high obliquity per se would not have been a primary trigger for glaciation, but would have strongly influenced the latitudinal distribution of glaciers. The principle of low-latitude glaciation on a terrestrial planet with high obliquity is validated by theoretical studies and observations of Mars. A high obliquity for the early Earth is a likely outcome of a single giant impact at 4.5 Ga, the widely favoured mechanism for lunar origin. This implies that a high obliquity could have prevailed during most of the Precambrian, controlling the low palaeolatitude of glaciations in the early and late Palaeoproterozoic and Cryogenian. It is postulated that the obliquity changed to < 54° between the termination of the last Cryogenian low-palaeolatitude glaciation at ≤ 635 Ma and the initiation of Late Ordovician–Early Silurian circum-polar glaciation at 445 Ma.The High Obliquity, Low-latitude Ice, STrong seasonality (HOLIST) hypothesis for pre-Ediacaran glaciation emerges favourably from numerous glacial and non-glacial tests. The hypothesis is in accord with such established or implied features of Cryogenian glaciogenic successions as extensive and long-lived open seas, an active hydrological cycle, aridity and palaeowesterly (reversed zonal) winds in low palaeolatitudes, and the apparent diachronism or non-correlation of some low-palaeolatitude glaciations. A pre-Ediacaran high obliquity also offers a viable solution of the faint young Sun paradox of a warm Archaean Earth. Furthermore, reduction of obliquity during the Ediacaran–early Palaeozoic would have yielded a more habitable globe with much reduced seasonal stresses and may have been an important factor influencing the unique evolutionary events of the Ediacaran and Cambrian. The palaeolatitudinal distribution of evaporites cannot discriminate unambiguously between high- and low-obliquity states for the pre-Ediacaran Earth. Intervals of true polar wander such as postulated by others for the Ediacaran and Early Cambrian imply major mass-redistributions within the Earth at those times, which may provide a potential mechanism for reducing the obliquity during the Ediacaran–early Palaeozoic.     

华北克拉通前寒武纪BIF铁矿研究:进展与问题

研究表明,BIF铁矿在华北克拉通的分布具有一定规律性.大规模BIF铁矿主要发育在绿岩带分布区的鞍山-本溪、冀东、霍邱-舞阳、五台、鲁西和固阳等地;华北克拉通时代最古老的BIF形成于古太古代,最年轻BIF形成于古元古代早期,但BIF铁矿的峰期为新太古代晚期(2.52 ～2.56Ga);BIF铁矿类型可划分为阿尔戈马型和苏比利尔湖型两类,但华北以晚太古代绿岩带中的阿尔戈马型为主,仅吕梁的古元古代袁家村铁矿具典型苏比利尔湖型铁矿特征.根据BIF在绿岩带序列中的产出部位和岩石组合关系,可将华北BIF划分为:1)斜长角闪岩(夹角闪斜长片麻岩)-磁铁石英岩组合;2)斜长角闪岩-黑云变粒岩-云母石英片岩-磁铁石英岩组合;3)黑云变粒岩(夹黑云石英片岩)-磁铁石英岩组合;4)黑云变粒岩-绢云绿泥片岩-黑云石英片岩-磁铁石英岩组合;5)斜长角闪岩(片麻岩)-大理岩-磁铁石英岩组合等5种类型.华北克拉通BIF形成时代与早前寒武纪岩浆活动的时间基本一致(2.5～2.6Ga),但与华北克拉通陆壳增生的峰期(2.7～2.9Ga)有一定偏差,其原因可能与新太古代晚期华北克拉通构造-热事件十分强烈有关.华北克拉通新太古代BIF大多形成于岛弧环境,但局部地区(如固阳)BIF铁矿可能形成于深部有地幔柱叠加的岛弧环境.华北克拉通BIF富矿主要有三种类型:原始沉积、受后期构造-热液叠加改造和古风化壳等,但总体不发育富铁矿,国外发育的风化壳型富铁在我国甚为少见.本文认为在探讨BIF铁矿类型时,需要从绿岩带发育序列进行综合判别.阿尔戈马型铁矿一般产于克拉通基底(绿岩带)环境,苏比利尔湖型铁矿一般形成于稳定克拉通上的海相沉积盆地或被动大陆边缘.华北克拉通BIF铁矿地球化学研究结果表明,BIF铁矿无Ce负异常且Fe同位素为正值,从而暗示铁矿沉淀的环境为低氧或缺氧环境,而铕正异常可能指示BIFs为热水沉积成因,其机制可能为海水对流循环从新生镁铁质-超镁铁质洋壳中淋滤出F(e)和Si等元素,在海底排泄沉淀成矿,而条带状构造的形成可能归咎于成矿流体的脉动式喷溢.但对于BIF铁矿的物质来源、成矿条件和机制、富铁矿成因、华北克拉通不发育苏比利尔湖型铁矿的原因等方面,仍需深入研究.     

Geochemistry and Si–O–Fe isotope constraints on the origin of banded iron formations of the Yuanjiacun Formation,Lvliang Group,Shanxi, China

Banded iron formations (BIFs) within the Lvliang region of Shanxi Province, China, are hosted by sediments of the Yuanjiacun Formation, part of the Paleoproterozoic Lvliang Group. These BIFs are located in a zone where sedimentation changed from clastic to chemical deposition, indicating that these are Superior-type BIFs. Here, we present new major, trace, and rare earth element (REE) data, along with Fe, Si, and O isotope data for the BIFs in the Yuanjiacun within the Fe deposits at Yuanjiacun, Jianshan, and Hugushan. When compared with Post Archean Australian Shale (PAAS), these BIFs are dominated by iron oxides and quartz, contain low concentrations of Al₂O₃, TiO₂, trace elements, and the REE, and are light rare earth element (LREE) depleted and heavy rare earth element (HREE) enriched. The BIFs also display positive La, Y, and Eu anomalies, high Y/Ho ratios, and contain ³⁰Si depleted quartz, with high δ¹⁸O values that are similar to quartz within siliceous units formed during hydrothermal activity. These data indicate that the BIFs within the Yuanjiacun Formation were precipitated from submarine hydrothermal fluids, with only negligible detrital contribution. None of the BIF samples analyzed during this study have negative Ce anomalies, although a few have a positive Ce anomaly that may indicate that the BIFs within the Yuanjiacun Formation formed during the Great Oxidation Event (GOE) within a redox stratified ocean. The positive Ce anomalies associated with some of these BIFs are a consequence of oxidization and the formation of surficial manganese oxide that have preferentially adsorbed Ho, LREE, and Ce^4 +; these deposits formed during reductive dissolution at the oxidation–reduction transition zone or in deeper-level reducing seawater. The loss of Ce, LREE, and Ho to seawater and the deposition of these elements with iron hydroxides caused the positive Ce anomalies observed in some of the BIF samples, although the limited oxidizing ability of surface seawater at this time meant that Y/Ho and LREE/HREE ratios were not substantially modified, unlike similar situations within stratified ocean water during the Late Paleoproterozoic. Magnetite and hematite within the BIFs in the study area contain heavy Fe isotopes (⁵⁶Fe values of 0.24–1.27‰) resulting from the partial oxidation and precipitation of Fe^2 + to Fe^3 + in seawater. In addition, mass-independent fractionation of sulfur isotopes within pyrite indicates that these BIFs were deposited within an oxygen-deficient ocean associated with a similarly oxygen-deficient atmosphere, even though the BIFs within the Yuanjiacun Formation formed after initiation of the GOE.     

Hydrothermal and resedimented origins of the precursor sediments to banded iron formation: sedimentological evidence from the Early Palaeoproterozoic Brockman Supersequence of Western Australia

The Early Palaeoproterozoic Brockman Supersequence comprises banded iron formation (BIF), bedded chert, limestone, mudrock, sandstone, breccia, tuffaceous mudstone, ashfall tuff and, in sections not reported here, basalt and rhyolite. Density current rhythms are preserved in sandstones, mudrocks, tuffaceous mudstones and limestones. Relics of similar rhythms in BIF imply that its precursor sediments were also deposited by density currents. Hemipelagic deposits are siliciclastic or mixed siliciclastic–volcaniclastic mudstones. Bedded chert, chert nodules and the chert matrix of BIF preserve evidence for formation by diagenetic replacement. For bedded chert (and chert nodules), silica replacement occurred before compaction close to or at the sediment–water interface, indicating that it is siliceous hardground. The chert matrix of BIF formed during compaction but before burial metamorphism. Original sediments were resedimented from two sources: (1) limestone, mudrock, sandstone, breccia and tuffaceous mudstone from a shelf; and (2) BIF from within the basin realm. Shelf sediments were resedimented to basin-floor fans during third-order lowstands. The precursor sediments to BIF are interpreted to have been granular hydrothermal muds, composed of iron-rich smectite and particles of iron oxyhydroxide and siderite that were deposited on the flanks of submarine volcanoes and resedimented by density currents. Resedimentation occurred by either bottom currents or gravity-driven turbidity currents, and the resulting sediment bodies may have been contourite drifts. The concept that BIF records high-frequency alternating precipitation from ambient sea water of iron minerals and silica is negated by this study. Instead, it is postulated that the precursor sediments to BIF originated in much the same way as modern Red Sea hydrothermal iron oxide deposits, implying that at least the particles of iron oxyhydroxide originated from the oxidation of vent fluids by sea water. Several orders of cyclicity in basin filling establish a relationship between rising to high sea levels, episodic sea-floor hydrothermal activity and BIF that is reminiscent of the link between eustacy and spreading-ridge pulses.     

Glacigenic Characteristics of the Luoquan Formation and Sediment Gravity Flow Reworking on It

The origin of the Luoquan Formation which occurs along the southern margin of the North China Blockhas long been argued. Based on recent work. the Formation is considered as a glacial sedimentary sequencepartially reworked by sediment gravity flow. The major evidence for the glacigene of Luoquan Formationdiamictites is as follows: 1, a striated and polished pavement with various features resulting from glacialabrasion and plucking, such as crescentic gouge, crescentic fracture, streamlined form and glaciated step; 2.unsorted diamictites with striated clast. faceted clast and iron-shaped stone formed by glaciation; 3. rhythmitewith dropstones; 4. a glacial sedimentary sequence bearing advance-retreat cycles; and 5. wide distribution ofthe diamictites. Glacial deposits can be distinguished from sediment gravity flow deposits by the features men-tioned above. Some characteristics of sediment gravity flow existing in the Luoquan Formation diamictites in-dicate that glacial deposits might have been partially reworked by sediment gravity flow. Therefore, this papersuggests that the Luoquan Formation diamictite is a result of a glacial event rather than a mud flow deposit.The primary tillites are the principal contribution of the Luoquan Formation, while sediment gravity flow de-posits are the redeposited diamictites and should be termed as glacigenic sediment gravity flow deposits.     

Glacial influence on Neoproterozoic sedimentation: the Smalfjord Formation, northern Norway

ABSTRACT There is much debate regarding the intensity and geographic extent of glaciation during the Neoproterozoic, particularly in response to recent geochemical work suggesting that the Neoproterozoic earth was at times ice covered from equator to poles (the ‘Snowball Earth’ hypothesis). A detailed sedimentological analysis of the Neoproterozoic Smalfjord Formation of northern Norway was conducted in order to determine the extent and intensity of glacial influence on sedimentation. In the Tarmfjorden area, the Smalfjord Formation consists of a stacked succession of diamictites interbedded with fine‐grained laminated mudstones containing rare outsized clasts. Diamictites and interbedded mudstones are interpreted as the product of subaqueous mass flows generated along the basin margin. In the Varangerfjorden area, chaotically interbedded diamictites, conglomerates and sandstones are overlain by a thick succession of stacked sandstone beds; onediamictite unit at Bigganjargga overlies a striated pavement. The Varangerfjorden outcrops appear to record deposition on a subaqueous debris apron. Although diamictites contain rare striated and faceted clasts, suggesting a glacial sediment source, their origin as subaqueous mass flows prevents the interpretation of ice mass form or distribution. Rare lonestones may be associated with floating ice in the basin, which may be of glacial or seasonal origin. Glacial ice may have contributed poorly sorted glacial debris to the basin margin, either directly or through fluvioglacial systems, but there is no evidence of direct deposition by ice at Varangerfjorden or Tarmfjorden. The overall fining‐upward trend identified in the Smalfjord Formation and overlying Nyborg Formation is consistent with depositional models of rift basin settings. This fining‐upward trend, the predominance of mass flow facies including breccias associated with scarps and the evidence for extensional tectonic activity in the region suggest that tectonic activity may have played an important role in the development of this Neoproterozoic succession. The Smalfjord Formation at Tarmfjorden and Varangerfjorden does not exhibit sedimentological characteristics consistent with severe glacial conditions suggested by the snowball Earth hypothesis.