The petrology of a melilitolite,melteigite, carbonatite and syenite ring dike system,in the Gardiner complex,East Greenland

The Tertiary Gardiner complex in East Greenland comprises ultramafic cumulates cut by dikes, ring dikes and cone sheets. One major ring dike is of melilite-rick rocks (melilitolites), and shows phase layering and cryptic layering with respect to melilite, perovskite and phologopite. The vertical variation in the assemblages through the ring dike is consistent with established fractionation trends in undersaturated melilite-bearing experimental systems. Related veins and dikes are: a) undersaturated rocks of the melteigite-ijolite-urtite/nepheline syenite suite, b) melanite-calcite veins and søvite dikes and sheets and c) coarse-grained magnetite-phlogopite-diopside-calcite pegmatites and dolomite rocks. It is proposed that a CO₂-bearing Ln-normative nephelinite liquid is parential to both melilitolites and related veins through a combination of fractional crystallization, liquid immiscibility and CO₂-metasomatism of dunite country rocks. Unlike other localities where melilitolites are attributed to metasomatic processes, the Gardiner melilitolites are magmatic.     

Relationships between tectonite and cumulate in ophiolites: the Miyamori ultramafic complex,Kitakami Mountains,northeast Japan

The Miyamori ultramafic complex forms the basal ultramafic portion of an ophiolite. The complex consists of a tectonic member which is composed dominantly of harzburgite and dunite, and a cumulate member which is composed of interlayered wehrlite, dunite and clinopyroxenite. The tectonite member is overlain by the cumulate member and characterized by tabular granular or porphyroclastic textures, a strong lineation and magnesian olivine (Mg/Mg + Fe = 0.88–0.93). In contrast, the cumulate member exhibits igneous textures and shows no evidence of a penetrative deformation. The olivine is less magnesian than that of the tectonite member (Mg/Mg + Fe = 0.82–0.89). At the boundary of the two members, harzburgite xenoliths have been found in wehrlite of the cumulate member. The minerals at the core of a few large harzburgite xenoliths preserve the compositional characteristics of typical harzburgites in the tectonic member. The occurrence of the harzburgite xenolith in vehrlite and the structural and textural features of the two members indicate that the tectonite member had already been deformed before a magma intruded into the tectonite member and formed a magma chamber in which cumulates were deposited together with harzburgite fragments on the floor of the tectonite. The xenoliths show a fine grained mosaic texture, which may be attributed by the heat of the intruded magma. This hiatus implies that the magma which made the cumulate member did not originate directly from the underlying harzburgite.     

Selectively contaminated magmas of the Tertiary East Greenland macrodike complex

Chemical interaction between tholeiitic magmas of the East Greenland Tertiary macrodike complex and anatectic melts of the Precambrian basement produced a wide range of hybrid magmas. Field evidence indicates that, although coexisting magmas were stirred, mechanical mixing only occurred to a limited extent before segregation of magmas into a stratified system. The initial ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd isotope ratios for hybrid compositions fall between those of the mafic and felsic end-members. However, the covariation of these isotope ratios differs from that expected of bulk mixing. Major- and trace-element distributions in hybrid magmas are also inconsistent with simple mixing, as well as with fractional crystallization coupled with bulk assimilation (AFC) involving reasonable end-members of the macrodike-crust system. Rather, the chemical and isotopic modification of mafic and felsic magmas of the macrodike complex appears to have been controlled fundamentally by interdiffusion of silicate liquid species during mingling and buoyant roofward segregation of crust-derived granophyres. The relationships among juxtaposed hybrid magmas of the Miki Fjord macrodike are shown to be consistent with expectations of selective diffusional exchange based on available experimental interdiffusion data for silicate liquids. Comparison between these hybrid compositions and rocks from the felsic series of the Vandfaldsdalen macrodike suggest that the latter compositions were affected by a similar opensystem process operating presumably during the transient development of the felsic cap. Once hybrid magmas ponded at the roof of the intrusion they effectively were isolated from further exchange.     

The Zoned Plagioclase of the Skaergaard Intrusion, East Greenland

The variation in zoning and An-content of plagioclases in theSkaergaard intrusion was investigated using microprobe analysisand optical methods on material from the surface of the intrusionas well as from a drill core from the hidden zone of the layeredseries. The plagioclases display cryptic variation and prominentvariations in type of zoning with structural height: oscillatoryzoned and resorbed plagioclase cores are predominant in thehidden zone, unzoned cores are typical of the lower zone, andplagioclases of the upper zone display skeletal zoning. Thereverse, oscillatory and skeletal zoning of plagioclase coresis ascribed to supercooled crystallization, and not to convectionor other petrogenetic factors. The variations in type of zoningand An-content of plagioclases from the hidden zone suggestonset of convection at the same time in the cooling historyof the intrusion as is indicated by the transition between thetranquil division and the banded division of the marginal bordergroup. A crystallization model is suggested, which accountsfor the observed variations. The variation in An-content ofplagioclases from the hidden zone suggests a limited extensionof some hundred metres of the intrusion at depth.     

The last glacial cycles in East Greenland, an overview

Marine, fluvial and glacigene sediments exposed in coastal cliffs and stream-cut sections in East Greenland between latitudes 69° and 78° N display a record of Quaternary climatic and environmental change going back to pre-Saalian times (> 240 ka), but with main emphasis on the last interglacial/glacial cycle. The stratigraphical scheme is based on studies on the Jameson Land peninsula, and contains five glacial stages and stades with the Greenland ice sheet or its outlets reaching the outer coasts. Individual sites are correlated and dated by a combination of biostratigraphy, luminescence dating, amino acid analyses, as well as ¹⁴C- and uranium series dating. The pre-Weichselian Lollandselv and Scoresby Sund glaciations were the most extensive. During the Weichselian the Inland Ice margin in this part of East Greenland was apparently very stable. The Aucellaelv, Jyllandselv and Flakkerhuk stades mark the advance and subsequent retreat of outlet glaciers from the Inland Ice which advanced through the wide Scoresby Sund basin and reached the inner shelf. In-between the glacier advances, three interglacial or interstadial periods have been recognized. During the Langelandselv interglacia-tion (≅ Eemian) the advection of warm Atlantic water was higher than during the Holocene, and the terrestrial flora and insect faunas show that summer temperatures were 3–4°C higher than during the Holocene optimum. There is no unambiguous evidence for cooling in the sediments from this interval. Later, in isotope stage 5, there were apparently two ice-free periods. During the Hugin Sø interstade, stable Polar water dominated Scoresby Sund, and the terrestrial flora suggests summer temperatures 2° -3° lower than the present. The marine and fluvial sediments from the second ice-free period, the Mønselv interstade, are devoid of organic remains.     

The new geological map of East Greenland

NE Greenland has seen epic polar exploration, bitter territorial disputes, scientific skulduggery but contains some of the world's most striking scenery and geology. It is now documented with a new geological map from 70°N to 82°N, which documents the architecture of the Caledonian mountain range over 1300km.     

Replenishment episodes and crustal assimilation in the development of an early Tertiary magma chamber, East Greenland: evidence from layered cumulates of the Kælvegletscher ultramafic complex, Kangerlussuaq

Summary  From the early Tertiary K?lvegletscher ultramafic cumulate complex, emplaced into the Archaean basement on the west side of the Kangerlussuaq Fjord, East Greenland, we present geochemical and isotopic data from an outcrop of finely layered dunitic adcumulates. The dunites were deposited in a trough structure, interpreted to be a fossilized feeder channel to the K?lvegletscher magma chamber. Detailed geochemical sampling of the trough reveals subtle cryptic compositional variations of olivines (Fo = 86.5–89.3; Ni = 2000–2700 ppm) and chromites (Cr# = 66–80) in a stratigraphical profile perpendicular to the layering as well as relatively large simultaneous variations of whole-rock ⁸⁷Sr/⁸⁶Sr ratios. The dunites are separable into sequences of normal and reverse cryptic zonations which are interpreted as resulting from fractional crystallisation and magma chamber recharge, respectively. Up to 20% of magma chamber replenishment by high-Mg melts is suggested. Sr-isotope compositions of the cumulates correlate with olivine compositions and suggest mixing of fractionated and unfractionated parental melts assimilating up to 8% local basement. We propose the existence of a vigorous volcanic system at the K?lvegletscher site in early Tertiary times, where plume-derived magmas incorporated minor amounts of local basement and underwent fractionation and mixing in crustal chambers. Estimates of processed magma volumes during deposition of the trough cumulates are in the range of 100–130 km³. Received January 18, 2000;/revised version accepted December 19, 2000     

The Late Quaternary sedimentary record in Scoresby Sund, East Greenland

Until recently, little was known about the Quaternary marine sedimentary record in East Greenland. Geophysical and geological investigations in Scoresby Sund were undertaken to characterize the nature and chronology of this record. Seismic records show that almost 70% of the outer fjord system is covered by about 10 m of unlithified sediments, making direct correlation with the Quaternary records on land and the adjacent continental margin difficult. These acoustically unstratified sediments are scoured by icebergs above 550 m water depth. Almost 90% of core material is massive diamicton of Holocene age, deposited mainly from iceberg rafting and turbid meltwater. Sedimentation rates are 0.1 -0.3 m 1000 yr-¹. Thicker accumulations of unlithified Quaternary sediments in Scoresby Sund occur as sediment ridges and in two other major depocentres. A low sediment ridge runs across the mouth of Scoresby Sund, and is interpreted as an end moraine of Late Weichselian Flakkerhuk stadial age. The very restricted sediment thickness suggests that grounded ice filled the fjord during the Flakkerhuk and an ice shelf was not present. High inputs of ice rafted debris to the continental margin at about 18 000 BP indicate this as a probable age for the moraine. During the Allerød Interstadial, ice probably retreated from the outer fjord system, since massive diamictons similar to those of Holocene age are present at the base of most cores. A major depocentre of acoustically stratified sediments at the head of Hall Bredning is interpreted to represent ice proximal deposits from a glacier margin extending across the fjord. It is adjacent to dated moraines on land and is inferred to be of Milne Land stadial age (about 10 000 BP). A similar age is interpreted for acoustically laminated sediments and a moraine at the entrance of Vikingebugt, on the south side of Scoresby Sund. Dated kame terraces in the inner fjord system indicate that ice retreated to its present position 6–7000 years ago.     

The Mesozoic of Western Scandinavia and East Greenland

Thick Mesozoic sediments are found offshore Norway and Denmark, and Mesozoic rocks are present and well exposed in Denmark, along the coast of East Greenland and on the arctic islands of Svalbard.
During the Mesozoic, Scandinavia and Greenland were subject to major extension in the Late Permian-Early Triassic and Late Jurassic-Early Cretaceous, prior to Cenozoic opening of the North Atlantic. Deep basins developed along the rift zones of the North Sea and between East Greenland and Norwa）; and were .filled with sediments derived from mainland Scandinavia and Greenland. The marginal areas bordering the rift zones suffered less subsidence, as did the epicontinental Barents Sea.     

俄罗斯极地乌拉尔Сыум-Key超基性岩体中的硬玉岩

俄罗斯极地乌拉尔Сыум-Key超基性岩体中的硬玉岩呈脉状在以叶蛇纹石为主的蛇纹岩中产出,硬玉岩由硬玉和绿辉石组成,根据硬玉岩的颜色、结构和构造可划分出三个世代,可能对应存在三期硬玉化过程.第一世代硬玉为主体,灰白色,粗粒结构,致密块状,硬玉分子(Jd)含量54%～88%;第二世代硬玉发育在灰白色硬玉中,呈浅绿色,细粒-隐晶结构,细脉状.囊状,硬玉分子(Jd)含量74%～86%;第三世代硬玉呈绿色-深绿色,半透明-透明,中-细粒结构,瘤状.第二、三世代硬玉达到珠宝首饰级,具有较高的商业价值.根据硬玉岩的产状和晶体具有韵律生长环带及流体包裹体发育等特征,认为硬玉岩是在高压低温环境中由富含Na、Al、Si的流体直接结晶形成的.     

The interglacial-glacial record at the mouth of Scoresby Sund, East Greenland

The sedimentary record around outer Scorcsby Sund begins with the Scorcsby Sund glaciation (≅ isotope stage 6), but is incomplete. Both at Kap Hope, headward of the fjord mouth, and at Kikiakajik on the outer coast. there are shallow marine sediments, correlated with the Langelandselv interglaciation (≅ isotope substagc 5e) on the basis of molluse assemblages and luminescence dates. Abundant Balanus crenatus , and several bivalves. show that thc adveetion of warm Atlantic water to the East Greenland coast was higher during that interglacial than during the Holocenc. Glacial striae at Kap Brewster (facing the open ocean) and till on top of the interglacial beds at Kikiakajik show that both an outlet from the Greenland Iee Sheet, and more local glaciers reached the continental shelf during the Weichselian. This glacial event is poorly dated. but tentatively correlated with the Flakkerhuk stade (≅ 19 15 ka BP) when, from marine geological data, it is suggested that thc Scoresby Sund glacier terminated c . 30 km east of Kap Brewster. During the Milne Land stade ( c . 10 ka BP) there was a resurgence of local ice caps in the mountains both north and south of the fjord mouth, but Scoresby Sund and Hall Bredning probably remained free of glaciers. Dating of these events was achieved through Iuminescence- (TL and OSL) and the ¹⁴C-method. and biostratigraphical and amino acid correliition Interglacial shells on thc outer coast show much lower amino acid D/L ratios than shells of the same age within the Scoresby Sund area. This may indicate that the outer coast remained free of ice cover and marine inundation much longer, arid suffered colder temperatures than areas along the fjord.     

The Isotopic Composition of Strontium in the Skaergaard Intrusion, East Greenland

The isotopic composition of strontium in the different partsof the differentiated Skaergaard intrusion has been determined.The average Sr⁸⁷/Sr⁸⁶ ratio for the basic rocks was found tobe 0?7065?0?002. Higher values, between 0?7101 and 0?7303, wererestricted to the late-stage acid granophyres. The Sr⁸⁷/Sr⁸⁶ratios for the basic Skaergaard rocks are similar to those foundby previous workers. The enrichment in Sr⁸⁷ expressed in theSr⁸⁷/Sr⁸⁶ ratio is taken to indicate contamination of the acidgranophyres by a source enriched in Sr⁸⁷. From considerationsbased upon circumstantial evidence the average country rock,composed of old Precambrian acid to intermediate gneiss, isnot sufficiently enriched in.Sr⁸⁷ to account for the Sr⁸⁷ enrichmentobserved in the acid granophyres by a simple assimilation process.At the present stage of the investigation the enrichment ofthe acid granophyres in Sr⁸⁷ is unexplained.     

Recent sedimentary processes in Scoresby Sund, East Greenland

The fjord system of Scoresby Sund on the east coast of Greenland has been the subject of two research cruises by RV Polarstern in 1988 and 1990. Most of the year, the fjord is covered by sea-ice. Sediment input takes place mostly via drifting icebergs during the short summer period. Depending on the distance to glaciers, surface sediments carry varying proportions of coarse ice-rafted debris (IRD). The degree of sediment reworking by scouring icebergs is controlled by the depth of the fjord, with the most intense reworking in areas shallower than about 450 m depth. Both IRD contribution and intensity of sediment scouring clearly control the distribution pattern of benthic organisms.     

Glacial history of interior Jameson Land, East Greenland

The plateaus between 400 and 800 m a.s.l. around the water-divides on central and eastern Janieson Land are covered by the 'Jameson Land Drift' up to 50 m thick glacial. placiotluvial and glaciolacustrine deposits. A high content of far-travelled wcsterii rocks indicates the overriding by extensive glaciers channelled from the west through the Scoresby Sund basin. The Jameson Land Drift deposits have bccn lithostratigraphically divided into two groups. each representing the sedimentary successions from one glaciation in the wider sense of the word. sediments from the lower Lollandselv glaciation are upwards delimited by a distinct periglacial surface. TL-dates suggest a prc-Saalian (approximately isotope stages 11–9) age. The following Scoreshby Sund glaciation . when most of the studied Jameson Land Drift sediments were laid down. is of Saalian age (e. isotope stages 8 6). The deposits from the Scoresby Sund glaciation are interpreted as representing a complete glaciation deglaciation succession, including proglacial sandur and glaciolacustrine sediments. followed by till deposition, with an overlying succession of glaciolacustrinc and glaciofluvial sediments. From 200–250 m to c . 400 m a.s.l. there is a driftless area, exposing Jurassic sandstones, probably a result of intensive and long-lasting periglacial erosion. Extensive occurrences of tors and of glaciofluvially (subglacially as well as subaerially) eroded canyons and channels characterize the landscape. A similar. although less well defined. upper driftless zone is found above c 500 m a.s.l. on northern Jameson Land, north of the drift-covered plateaus. During the Wcichsclian (isotope stages 5d 2). thick glacial. fluvial and marine deposits were laid down in a coastal zone below c . 200 m a.s.l., and only cold-based local ice caps seem to have existed on the interior plateaus of Jameson Land. The now driftless areas were characterized by periglacial erosion during this period.     

俄罗斯极地乌拉尔Сыум-Кеу超基性岩体中的硬玉岩

俄罗斯极地乌拉尔Сыум-Кеу超基性岩体中的硬玉岩呈脉状在以叶蛇纹石为主的蛇纹岩中产出,硬玉岩由硬玉和绿辉石组成,根据硬玉岩的颜色、结构和构造可划分出三个世代,可能对应存在三期硬玉化过程。第一世代硬玉为主体,灰白色,粗粒结构,致密块状,硬玉分子(Jd)含量54%～88%;第二世代硬玉发育在灰白色硬玉中,呈浅绿色,细粒-隐晶结构,细脉状-囊状,硬玉分子(Jd)含量74%～86%;第三世代硬玉呈绿色-深绿色,半透明-透明,中-细粒结构,瘤状。第二、三世代硬玉达到珠宝首饰级,具有较高的商业价值。根据硬玉岩的产状和晶体具有韵律生长环带及流体包裹体发育等特征,认为硬玉岩是在高压低温环境中由富含Na、Al、Si的流体直接结晶形成的。     

Geochemistry and petrology of ultramafic lamprophyres from Schirmacher Oasis, East Antarctica

Summary Petrographic and geochemical data are presented for some ouachitites from the Schirmacher Oasis. The studied dike intruded into the metamorphic basement of the East Antarctic craton. The ouachitite samples contain substantial amounts of zoned phlogopite and diopsidic to salitic pyroxene as phenocrysts. K-rich nepheline is the predominant phase of the matrix. The rocks are characterized by low SiO₂ concentrations (up to 36.5 wt.%), low mg# and high abundances of Al²O³, alkalis and volatiles. Trace element compositions of the Schirmacher ouachitites differ from those of ultramafic lamprophyres from other regions in that they contain significantly lower Cr and Ni concentrations and relatively low enrichments in LILE and LREE. The studied rocks have low¹⁴³Nd/¹⁴⁴Nd and enhanced⁸⁷Sr/⁸⁶Sr ratios. Pb isotope compositions of the ouachitites closely resemble those of MORB. The ¹⁸O values range between 4.1 and 4.7⁰/₀₀ which may be due to interactions with meteoric water. Because the Schirmacher ouachitites are only represented by a few samples it is impossible to discuss the petrogenesis of this magma. However, according to trace element and isotopic characteristics, it can be ruled out that Schirmacher ouachitites and associated minettes (documented inHoch, 1997;Hoch andTobschall, 1998) were derived from the same mantle reservoir.

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Geochemie und Petrologie von Ouachititen aus der Schirmacher Oase, Ostantarktika

Zusammenfassung In dieser Arbeit werden petrologische und geochemische Daten von Ouachititen aus der Schirmacher Oase vorgestellt. Der beprobte Gang intrudierte in das metamorphe Basement des ostantarktischen Kratons. Zonierte Phlogopite und diopsidische bis salitische Pyroxene sind die häufigsten mafischen Einsprenglinge. K-reiche Nepheline bilden die Hauptmineralphase der Grundmasse. Charakteristisch für die Ouachititproben sind niedrige SiO₂-Konzentrationen (bis 36.5 Gew.%) und mg#, aber hohe Gehalte an Al₂O₃ Alkalien und volatilen Bestandteilen. Die Spurenelementzusammensetzung der Schirmacher Ouachitite unterscheidet sich von UML-Proben aus anderen Regionen durch ihre extrem geringen Cr- und Ni-Konzentrationen und die vergleichsweise niedrigen Anreicherungen an LILE und LREE. Die bearbeiteten Gesteine zeigen niedrige¹⁴³Nd/¹⁴⁴Nd- und erhöhte⁸⁷Sr/⁸⁶Sr-Verhältnisse. Die Pb-Isotopie der Ouachitite entspricht der von MORB. 6180-Werte variieren zwischen 4.1 und 4.7⁰/₀₀, was auf eine eventuelle Beeinflussung durch meteorische Wässer hindeutet. Da von den Schirmacher Ouachititen nur wenige Proben für eine Bearbeitung zur Verfügung standen, ist es nicht möglich, die Petrogenese des Magmas zu diskutieren. Aber aufgrund der Spurenelement- und Isotopensignaturen kann ein gemeinsames Mantelreservoir der Schirmacher Ouachitite und Minette (beschrieben inHoch, 1997;Hoch undTobschall, 1998) ausgeschlossen werden.

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With 6 Figures     

The Eemian and Weichselian stratigraphy of the Langelandselv area, Jameson Land, East Greenland

Coastal Jameson Land is characterized by thick Quaternary deposits from the last interglacial/glacial cycle. The successions at the mouth of Langelandselv exhibit a key stratigraphy where sediments from the Langelandselv interglaciation (Eemian) are overlain by three till units interbedded with glacimarine and deltaic interstadial successions. Immediately after the retreat of glaciers after the extensive Scoresby Sund glaciation (Saalian). advection of warm Atlantic surface water surpassed what is known from the Holocene. The two lowermost Weichselian tills, deposited during the Aucellaelv and Jyllandselv stades (Early Weichselian), reflect short-lasting readvances of fjord glaciers. Luminescence dates and correlation with adjacent areas suggest ages of 110–80 ka and 70–60 ka for the Hugin Sø and the Møselv interstades, respectively.     

Petrology of the Vandfaldsdalen Macrodike, Skaergaard Region, East Greenland

The Vandfaldsdalen macrodike is a layered and differentiatedgabbroic dike approximately 3?5 km long and from 200 to 500m wide. It appears to cut the eastern margin of the Skaergaardintrusion and may have served as a feeder for the Basistoppensill. The macrodike can be divided into three series of rocks:a marginal series of differentiated gabbros adjacent to thewalls of the dike; a central series of differentiated and subhorizontallylayered gabbros and ferrodiorites in the interior of the dike;and an upper felsic series of granophyric rocks with abundantquartzo-feldspathic xenoliths. The mineral and bulk-rock compositionsthrough both the marginal series and central series show progressiveiron enrichment. The most Ca-rich plagioclase (An₆₉) and mostmagnesian pyroxene (Wo₄₂ En₄₆ Fs₁₂) occur in olivine-bearingrocks of the marginal series about 5 m from the contact withwall rocks. The most Na-rich plagioclase (An₃₉) and Fe-richpyroxene (Wo₃₈ En₂₄ Fs₃₈) are in olivine-free ferrodiorite ofthe central series, about 20 m below the contact with the felsicseries. Evidence from field observations, bulk-rock chemical compositions,and Sr and Nd isotopic data indicate the felsic series formedas a mixture of the initial macrodike magma and granitic countryrock. ⁸⁷Sr/⁸⁶Sr ratios of specimens from the felsic series rangebetween 0?7129 and 0?7294. ¹⁴³Nd/¹⁴⁴Nd ratios vary between 0?51208and 0?51118. Both ratios vary serially with the SiO₂ contentsof the specimens. We suggest that the felsic series evolvedas a separate body of low density liquid which floated on thedenser gabbroic magma of the central series. Heat from crystallizationof the gabbroic magma must have diffused into the felsic layer,enabling extensive assimilation of the granitic xenoliths, butour data indicate there was very little exchange of chemicalcomponents between the two liquids.     

The opaque minerals and economic geology of the nemeiben ultramafic complex,saskatchewan, canada

The main rock types of the Nemeiben ultramafic complex form grossly concentric layers of clinopyroxenite, websterite, wehrlite and dunite. These rocks were partially amphibolitized late in the Hudsonian orogeny; consequently numerous relict primary textural and mineralogical features are preserved. Disseminated primary magmatic nickeliferous pyrrhotite, pentlandite, chalcopyrite, magnetite and chromite occur throughout this complex and local concentrations of sulfides occur. Textures, mineralogy and chemistry of these phases are indicative of a high temperature magmatic origin. Unmixing phenomena in pyrrhotite are attributable to post crystallization dissociation of a high temperature Fe-Ni-Cu-Co monosulfide solid solution. A secondary assemblage of fine-grained iron oxides, sulfides and native metals developed in altered ultramafic rocks. Magnetite and hematite, bravoite, violarite and millerite are among the minerals formed during serpentinization. Trace amounts of nickeliferous copper, native gold and silver occur in hematite veinlets and at the center of hematized former sulfide grains. Supergene alteration has affected most of the sulfides. Thus the most plausible explanation of the opaque minerals is that they represent a metamorphosed primary magmatic assemblage modified by supergene alteration.