Modelling of nitrate leaching from arable land into unsaturated soil and chalk 1. Development of a management model for applications of sewage sludge and fertilizer

A mathematical model has been produced to examine the impact of sewage sludge and fertilizer application to arable land and the effect of different crop regimes on the amount of nitrate leached to chalk groundwater. Previous work on nitrate leaching has concentrated on either a soil science or a hydrogeological approach with little overlap between the two. This study considered both fields to obtain an overall picture of the nitrate leaching process. IMPACT is a layered deterministic N-leaching model which predicts the nitrogen loads entering groundwater daily from arable land, and can be used as a management tool in development of sludge application and agricultural policy. The model relates nitrogen species movement resulting from the application of sewage sludge and fertilizer to differing vegetation-soil-hydrogeological conditions. Field data collected at three sites on the unconfined chalk aquifer of East Anglia, England over a two and a half year period was used to produce an initial conceptual model and to constrain the mathematical model during development. IMPACT simulates nitrogen and transport processes in the soil and unsaturated zone of the chalk. The nitrogen processes include: mineralisation of soil organic-N and sewage sludge organic-N, nitrification; crop uptake; volatilization; denitrification; and N inputs from fertilizers and precipitation. A mixing cell method is used to model solute transport in both the soil and chalk. Matrix flow and combined fissure-matrix flow are considered for the chalk. The model enables examination of the relationship between the arable/hydrogeological systems and the environmental implications of sludge application and of different arable regimes. Results are of use in developing strategies for arable farming and sludge application in areas sensitive to nitrate leaching. This Part 1 paper describes the model development approach. Results of associated modelling scenarios are presented separately in the associated Part 2 paper.     

A comparison of groundwater recharge estimation methods in a semi‐arid,coastal avocado and citrus orchard (Ventura County,California)

We assess the relative merits of application of the most commonly used field methods (soil‐water balance (SWB), chloride mass balance (CMB) and soil moisture monitoring (NP)) to determine recharge rates in micro‐irrigated and non‐irrigated areas of a semi‐arid coastal orchard located in a relatively complex geological environment. Application of the CMB method to estimate recharge rates was difficult owing to the unusually high, variable soil‐water chloride concentrations. In addition, contrary to that expected, the chloride concentration distribution at depths below the root zone in the non‐irrigated soil profiles was greater than that in the irrigated profiles. The CMB method severely underestimated recharge rates in the non‐irrigated areas when compared with the other methods, although the CMB method estimated recharge rates for the irrigated areas, that were similar to those from the other methods, ranging from 42 to 141 mm/year. The SWB method, constructed for a 15‐year period, provided insight into the recharge process being driven by winter rains rather than summer irrigation and indicated an average rate of 75 mm/year and 164 mm/year for the 1984 – 98 and 1996 – 98 periods, respectively. Assuming similar soil‐water holding capacity, these recharge rates applied to both irrigated and non‐irrigated areas. Use of the long period of record was important because it encompassed both drought and heavy rainfall years. Successful application of the SWB method, however, required considerable additional field measurements of orchard ET_c, soil‐water holding capacity and estimation of rainfall interception – runoff losses. Continuous soil moisture monitoring (NP) was necessary to identify both daily and seasonal seepage processes to corroborate the other recharge estimates. Measured recharge rates during the 1996 – 1998 period in both the orchards and non‐irrigated site averaged 180 mm/year. The pattern of soil profile drying during the summer irrigation season, followed by progressive wetting during the winter rainy season was observed in both irrigated and non‐irrigated soil profiles, confirming that groundwater recharge was rainfall driven and that micro‐irrigation did not ‘predispose’ the soil profile to excess rainfall recharge. The ability to make this recharge assessment, however, depended on making multiple field measurements associated with all three methods, suggesting that any one should not be used alone. Copyright © 2000 John Wiley & Sons, Ltd.     

The role of nitrogen in crop production and losses of nitrate by leaching from agricultural soil

Managing land to produce food, fibre or timber must have some environmental impact, the magnitude of which will depend on the cropping system and the intensity of management. Nitrogen is an indispensable input for modern agricultural systems, which not only aim to feed people but seek to sustain rural communities dependent on agriculture. In temperate regions there is a universal problem of nitrate leaching from agricultural land, and increases in nitrate concentrations in water bodies in recent years have been a cause for concern, especially the role of nitrate in the development of algal blooms. Nitrate invariably appears in drainage from agricultural land in the absence of any significant input of nitrogen as a result of the breakdown of soil humus or from aerial deposition of combined nitrogen in various forms. Where only inorganic nitrogen fertilizers are applied in amounts and at times to satisfy crop demand, they are apparently used efficiently. Where nitrate in drainage is a direct residue from applied nitrogen fertilizers, it can usually be associated with the use of excessive quantities or with the failure of a crop to achieve its expected yield. Most of the nitrate which appears in soil in autumn comes from the microbial mineralization of soil organic matter. The soil microbial population breaking down organic matter does not differentiate between soil humus or organic matter added to soil by ploughing in grass leys, forage legumes or large quantities of organic manures. Adding such organic materials to soil can lead to the release of much nitrate. Such microbial processes would be impossible to control in environmentally benign ways.     

The application of electromagnetic techniques to groundwater recharge investigations

The use of electrical methods for estimating spatial patterns of groundwater recharge was evaluated at a field site in southeastern Australia. Here, recharge increased from less than 0.2 mm year⁻¹ under native Eucalyptus vegetation, to between 1 and 14 mm year⁻¹ under dryland agriculture. This increase in recharge results in progressive leaching of salts in the soil profile. Differences in recharge can be estimated from differences in depth of leaching. The estimated recharge rates are correlated with soil texture, with higher recharge rates generally occurring through sandier soils. The relationships of recharge to salt content and soil texture both contribute to lower apparent electrical conductivities for higher recharge rates.

The effect of recharge rate on measured apparent electrical conductivities was modelled for various geophysical devices (including frequency-domain (FEM) and time-domain (TEM) electromagnetic instruments and direct current resistivity). The soil-texture effect was shown to have a greater effect than the solute leaching effect in determining the correlation between recharge and apparent electrical conductivity. Analysis of sensitivity to geological noise showed that variations in soil type below 2 m could disguise any correlation.

Correlations between recharge rate, measured at core sites from chloride tracer techniques, and apparent electrical conductivity, measured with FEM electromagnetic devices, supported the conclusions of the model. For DC resistivity and TEM methods, correlations between recharge and apparent electrical conductivity were not significant, although for resistivity this may be due partly to the small number of measurements made. The FEM device most sensitive to variations in recharge had an operating frequency of 9.8 kHz. At lower frequencies the sensitivity is reduced, as the instruments are sensing too deeply. The poor correlations for TEM, as compared with FEM, are due probably to the relatively deeper penetration of the TEM instrument used in the study, rather than any inherent differences between the techniques.

Because the major reason for the correlation between recharge and apparent electrical conductivity is soil texture, in this area the geophysical devices are mostly mapping soil type.     

Improved Recharge Estimation from Portable,Low‐Cost Weather Stations

Groundwater recharge estimation is a critical quantity for sustainable groundwater management. The feasibility and robustness of recharge estimation was evaluated using physical‐based modeling procedures, and data from a low‐cost weather station with remote sensor techniques in Southern Abbotsford, British Columbia, Canada. Recharge was determined using the Richards‐based vadose zone hydrological model, HYDRUS‐1D. The required meteorological data were recorded with a HOBO^TM weather station for a short observation period (about 1 year) and an existing weather station (Abbotsford A) for long‐term study purpose (27 years). Undisturbed soil cores were taken at two locations in the vicinity of the HOBO^TM weather station. The derived soil hydraulic parameters were used to characterize the soil in the numerical model. Model performance was evaluated using observed soil moisture and soil temperature data obtained from subsurface remote sensors. A rigorous sensitivity analysis was used to test the robustness of the model. Recharge during the short observation period was estimated at 863 and 816 mm. The mean annual recharge was estimated at 848 and 859 mm/year based on a time series of 27 years. The relative ratio of annual recharge‐precipitation varied from 43% to 69%. From a monthly recharge perspective, the majority (80%) of recharge due to precipitation occurred during the hydrologic winter period. The comparison of the recharge estimates with other studies indicates a good agreement. Furthermore, this method is able to predict transient recharge estimates, and can provide a reasonable tool for estimates on nutrient leaching that is often controlled by strong precipitation events and rapid infiltration of water and nitrate into the soil.     

Contamination of the Sandstone Aquifer of Prince Edward Island, Canada by Aldicarb and Nitrogen Residues

Prince Edward Island is wholly dependent upon ground water from a highly permeable fractured sandstone aquifer for all industrial, domestic, agricultural, and potable uses. The contamination of this aquifer by agricultural residues, principally aldicarb and nitrate, has caused concern among Islanders. Ground water quality was monitored between 1985 and 1988 beneath two potato fields to which aldicarb (Temik) was applied at planting once or twice between 1983 and 1986. In May of 1988,12 percent of 48 monitoring well samples exceeded the drinking water guideline of 9μg/L for total aldicarb. Furthermore 32 percent of all samples exceeded the nitrate guideline of 10 mg/L. Aldicarb persistence appears related to its application at planting when soil temperatures are low and recharge is high and to the inhibiting pH effect that ammonium (from fertilizers and soil organic nitrogen) oxidation has on its degradation. Therefore, based on the research of others, it is recommended that aldicarb be applied at plant emergence when degradation is more rapid and recharge is lower.     

Spatial and temporal changes in the structure of groundwater nitrate concentration time series (1935–1999) as demonstrated by autoregressive modelling

Autoregressive modelling is used to investigate the internal structure of long-term (1935–1999) records of nitrate concentration for five karst springs in the Mendip Hills. There is a significant short term (1–2 months) positive autocorrelation at three of the five springs due to the availability of sufficient nitrate within the soil store to maintain concentrations in winter recharge for several months. The absence of short term (1–2 months) positive autocorrelation in the other two springs is due to the marked contrast in land use between the limestone and swallet parts of the catchment, rapid concentrated recharge from the latter causing short term switching in the dominant water source at the spring and thus fluctuating nitrate concentrations. Significant negative autocorrelation is evident at lags varying from 4 to 7 months through to 14–22 months for individual springs, with positive autocorrelation at 19–20 months at one site. This variable timing is explained by moderation of the exhaustion effect in the soil by groundwater storage, which gives longer residence times in large catchments and those with a dominance of diffuse flow. The lags derived from autoregressive modelling may therefore provide an indication of average groundwater residence times. Significant differences in the structure of the autocorrelation function for successive 10-year periods are evident at Cheddar Spring, and are explained by the effect the ploughing up of grasslands during the Second World War and increased fertiliser usage on available nitrogen in the soil store. This effect is moderated by the influence of summer temperatures on rates of mineralization, and of both summer and winter rainfall on the timing and magnitude of nitrate leaching. The pattern of nitrate leaching also appears to have been perturbed by the 1976 drought.     

Mobility of major ions and nutrients in the unsaturated zone during paddy cultivation: a field study and solute transport modelling approach

Study of the movement of water and solute within soil profiles is important for a number of reasons. Accumulation of prominent contaminants from agricultural chemicals in the unsaturated zone over the years is a major concern in many parts of the world. As a result, the unsaturated zone has been a subject of great research interest during the past decade. Hence, an intensive field study was conducted in a part of Palar and Cheyyar river basins to understand the variation of major ions and nutrients in the soil zone during paddy cultivation. The chloride and nitrate data were used to model the movement of these chemicals in the unsaturated zone using the HYDRUS‐2D model. The field study shows that fertilizer application and irrigation return flow increases the major ions and nutrients concentration in the unsaturated zone. Further, the nutrient concentrations are regulated by plant uptake, fertilizer application and infiltration rate. Additionally, denitrification and soil mineralization processes also regulate the nitrogen concentration in the unsaturated zone. The solute transport modelling study concluded that the simulated results match reasonably with the observed trends. Simulated concentrations of chloride and nitrate for a 5‐year period indicate that the concentrations of these ions fluctuate in a cyclic manner (from 60 to 68 mg l^?1 and from 3·4 to 3·5 mg l^?1 respectively in groundwater) with no upward and downward trend. The influence of excessive fertilizer application on groundwater was also modelled. The model predicts an increase of about 17 mg l^?1 of chloride and 2·3 mg l^?1 of nitrogen in the groundwater of this area when the application of fertilizers is doubled. The model indicates that the present level of use of agrochemicals is no threat to the groundwater quality. Copyright © 2007 John Wiley & Sons, Ltd.     

Denitrification in riparian buffer zones: the role of floodplain hydrology

The broad purpose of the study described here was to assess the role of denitrification in riparian zones in ameliorating groundwater pollution through nitrate loss, and as a potential source of nitrous oxide to the atmosphere. A suitable riparian zone was identified at Cuddesdon Mill on the River Thame floodplain near Oxford, England. Measurements were made of water and nitrate moving from arable land through the riparian zone and into the river. Techniques to measure denitrification were tested and applied, and the factors controlling denitrification measured. While there was considerable potential for denitrification at the site, this was not realized because much of the water moving off the farmland bypassed the riparian zone, entering the river directly via springs or through gravel lenses beneath the floodplain soil. Management of this site would not reduce nitrate leaching unless the floodplain hydrology could be substantially modified, and the main conclusion is that nitrate buffer zones will only operate efficiently where the hydrology of the site is appropriate. Copyright © 1999 John Wiley & Sons, Ltd.     

Nitrate subsurface transport and losses in response to its initial distributions in sloped soils: An experimental and modelling study

Transport and losses of nitrate from sloped soils are closely linked to nitrogen fertilizer management. Previous studies have always focused on different types of fertilizer applications and rarely analysed various initial nitrate distributions as a result of nitrogen fertilizer applications. Under certain conditions, both subsurface lateral saturated flow and vertical leaching dominate nitrate losses. Soil tank experiments and HYDRUS‐2D modelling were used to better understand the subsurface nitrate transport and losses through lateral saturated flow and vertical leaching under various initial nitrate distributions. Low (L: 180 mg L^?1), normal (N: 350 mg L^?1), and high (H: 500 mg L^?1) nitrate concentrations were used in five different distributions (NNNN, NLLN, LHHL, LNLN, and HNHN) along the slope of the tank. The first two treatments (NNNN and NLLN) were analysed both experimentally and numerically. Experiments were conducted under 12 rainfall events at intervals of 3 days. The HYDRUS‐2D model was calibrated and validated against the experimental data and demonstrated good model performance. The other three treatments (LHHL, LNLN, and HNHN) were investigated using the calibrated model. Nitrate concentrations in purple sloped soils declined exponentially with time under intermittent rainfalls, predominantly in the upper soil layers. Non‐uniform initial nitrate distributions contributed to larger differences between four locations along the slope in deeper soil layers. The non‐uniform nitrate distribution either enhanced or reduced decreases in nitrate concentrations in areas with higher or lower initial nitrate concentrations, respectively. Higher nitrate concentrations at the slope foot and along the slope were reduced mainly by lateral flow and vertical leaching, respectively. Increasing nitrogen application rates increased subsurface nitrate losses. Mean subsurface lateral nitrate fluxes were twice as large as mean vertical leaching nitrate fluxes. However, due to longer leaching durations, total nitrate losses due to vertical leaching were comparable with those due to lateral flow, which indicated comparable environmental risks to surface waters and groundwater.     

Contamination of groundwater under cultivated fields in an arid environment, central Arava Valley, Israel

The purpose of this study is to obtain a better understanding of groundwater contamination processes in an arid environment (precipitation of 50 mm/year) due to cultivation. Additional aims were to study the fate of N, K, and other ions along the whole hydrological system including the soil and vadose zone, and to compare groundwater in its natural state with contaminated groundwater (through the drilling of several wells).

A combination of physical, chemical, and isotopic analyses was used to describe the hydrogeological system and the recharge trends of water and salts to the aquifers. The results indicate that intensive irrigation and fertilization substantially affected the quantity and quality of groundwater recharge. Low irrigation efficiency of about 50% contributes approximately 3.5–4 million m³/year to the hydrological system, which corresponds to 0.65 m per year of recharge in the irrigated area, by far the most significant recharge mechanism.

Two main contamination processes were identified, both linked to human activity: (1) salinization due to circulation of dissolved salts in the irrigation water itself, mainly chloride, sulfate, sodium and calcium, and (2) direct input of nitrate and potassium mainly from fertilizers.

The nitrate concentrations in a local shallow groundwater lens range between 100 and 300 mg/l and in the upper sub-aquifer are over 50 mg/l. A major source of nitrate is fertilizer N in the excess irrigation water. The isotopic compositions of δ¹⁵N–NO₃ (range of 4.9–14.8‰) imply also possible contributions from nearby sewage ponds and/or manure. Other evidence of contamination of the local groundwater lens includes high concentrations of K (20–120 mg/l) and total organic carbon (about 10 mg/l).     

The spatial and temporal variability of groundwater recharge in a forested basin in northern Wisconsin

Recharge varies spatially and temporally as it depends on a wide variety of factors (e.g. vegetation, precipitation, climate, topography, geology, and soil type), making it one of the most difficult, complex, and uncertain hydrologic parameters to quantify. Despite its inherent variability, groundwater modellers, planners, and policy makers often ignore recharge variability and assume a single average recharge value for an entire watershed. Relatively few attempts have been made to quantify or incorporate spatial and temporal recharge variability into water resource planning or groundwater modelling efforts. In this study, a simple, daily soil–water balance model was developed and used to estimate the spatial and temporal distribution of groundwater recharge of the Trout Lake basin of northern Wisconsin for 1996–2000 as a means to quantify recharge variability. For the 5 years of study, annual recharge varied spatially by as much as 18 cm across the basin; vegetation was the predominant control on this variability. Recharge also varied temporally with a threefold annual difference over the 5‐year period. Intra‐annually, recharge was limited to a few isolated events each year and exhibited a distinct seasonal pattern. The results suggest that ignoring recharge variability may not only be inappropriate, but also, depending on the application, may invalidate model results and predictions for regional and local water budget calculations, water resource management, nutrient cycling, and contaminant transport studies. Recharge is spatially and temporally variable, and should be modelled as such. Copyright © 2009 John Wiley & Sons, Ltd.     

Unsaturated Zone Flow Processes and Aquifer Response Time in the Chalk Aquifer,Brighton, South East England

The Chalk aquifer is one of the main sources of water in South East England. The unsaturated zone in the aquifer plays an important role controlling the time and magnitude of recharge and is major pathway for contaminant transport to the water table. A range of previous work has addressed flow processes in the Chalk unsaturated zone, but physical understanding is still incomplete. Here we present the results of a study on flow mechanism in the Chalk unsaturated zone using a combination of statistical analysis and novel laboratory methods. The study was undertaken at three sites (North Heath Barn [NHB], Pyecombe East [PE], and Preston Park [PP]) on the Chalk of the Brighton block, South East England. Daily and hourly time series data of groundwater level and rainfall were correlated. The results show that a slower groundwater level response to rainfall occurs during dry seasons (summer and autumn) when the amount of effective rainfall is less than 4 mm/day, with a thicker and drier unsaturated zone. A faster response occurs during wet seasons (winter and spring) when the daily effective rainfall exceeds 4 mm/day with a thinner and wetter unsaturated zone. Periods of very rapid response (within 15 h) were observed during wet seasons at NHB and PE sites, with unsaturated hydraulic conductivity (K_u) inferred to reach 839 mm/day. A slower response was observed at an urbanized site (PP) as a result of reduction in direct recharge due to reduced infiltration, due to presences of impermeable infrastructure covering the area around PP borehole. Laboratory measurements of K_u of the Chalk matrix using a geotechnical centrifuge show variation from 4.27 to 0.07 mm/day, according to the level of saturation. Thus, the rapid responses cannot be linked to matrix flow only but indicate the contribution of fracture and karstic flow processes in conducting water.     

Impact of seasonal variations in hydrological stresses and spatial variations in geologic conditions on a TCE plume at an industrial complex in Wonju,Korea

Spatial and temporal variations in a trichloroethylene (TCE) plume at an industrial complex in Wonju, Korea, were examined based on hydrogeological data and seven rounds of groundwater quality data collected over a year. The site has considerable vertical heterogeneities; the top layer of soil is covered by impermeable paving material at several locations, followed by a series of reclaimed or residual soil layers, and with weathered rocks to the crystalline biotite granite at the bottom. Areal heterogeneity in the surface conditions plays an important role in controlling groundwater recharge. The heterogeneity structure is influenced by complex surface conditions paved with asphalt and concrete. Owing to the presence of limited recharge area and concentrated summer precipitation events, the effects of seasonal variations on groundwater hydraulics tend to diminish with distance from the recharge area. This result was established by analysing the influence of the contrasting surface recharge conditions between the near‐source zone and the far zone, and the seasonally concentrated precipitation on the transport patterns of a TCE plume. In addition, variations in the plume's downstream contaminant flux levels were also analysed along a transect line near the source zone. The results show that the general tendency of the TCE plume contaminant concentration and mass discharges were reproducible if we account for seasonal recharge variations and the associated changes in the groundwater level. During recharge events, the TCE concentration variations appear to be influenced by leaching of the residual dense non‐aqueous‐phase liquid (DNAPL) TCE trapped in the unsaturated zone. This result shows that seasonal variations in contaminant plume near the source zone is inevitable at this site, and that these variations indicate the presence of residual DNAPL at or above the water table, at least in some isolated locations. Copyright © 2011 John Wiley & Sons, Ltd.     

The Role of Groundwater for Lake‐Water Quality and Quantification of N Seepage

The heterogeneous nature of both groundwater discharge to a lake (inflow) and nitrate concentrations in groundwater can lead to significant errors in calculations of nutrient loading. Therefore, an integrated approach, combining groundwater flow and transport modelling with observed nitrate and ammonium groundwater concentrations, was used to estimate nitrate loading from a catchment via groundwater to an oligotrophic flow‐through lake (Lake Hampen, Denmark). The transport model was calibrated against three vertical nitrate profiles from multi‐level wells and 17 shallow wells bordering a crop field near the lake. Nitrate concentrations in groundwater discharging to the lake from the crop field were on average 70 times higher than in groundwater from forested areas. The crop field was responsible for 96% of the total nitrate loading (16.2 t NO₃/year) to the lake even though the field only covered 4.5% of the catchment area. Consequently, a small change in land use in the catchment will have a large effect on the lake nutrient balance and possible lake restoration. The study is the first known attempt to estimate the decrease of nitrate loading via groundwater to a seepage lake when an identified catchment source (a crop field) is removed.     

Evaluation of nitrate levels in groundwater under agricultural fields in two pilot areas in central Chile: A hydrogeological and geochemical approach

The aim of this study is to evaluate the impact of the application of industrial fertilizers and liquid swine manure in groundwater in two pilot agricultural areas, San Pedro and Pichidegua, which have been under long‐term historic use of fertilizers. A comprehensive hydrogeological investigation was carried out to define the geology and the groundwater flow system. Chemical and isotopic tools were used to evaluate the distribution and behavior of the nitrate in the groundwater. The isotopic tools included δ¹⁸O, δ²H, and ³H, which provide information about the origin and residence time of the groundwater; δ¹⁵N‐NO₃^? and δ¹⁸O‐NO₃^?, which provide information about nitrate sources and processes that can affect nitrate along the groundwater flow system. The application rate of liquid manure and other fertilizers all together with land uses was also evaluated. The hydrogeological investigation identified the presence of a confined aquifer underneath a thick low‐permeability aquitard, whose extension covers most of the two study areas. The nitrate concentration data, excepting a few points in zones located near recharge areas in the upper part of the basins and lower areas at the valley outlets (San Pedro), showed nitrate concentration below 10 mgN/L at the regional scale. The isotope data for nitrate showed no influence of the liquid swine manure in the groundwater at the regional scale, except for the high part of the basins and the outlet of the San Pedro valley, which are areas fertilized by manure. This data showed that the regional aquifer on both pilot study areas is protected by the thick low‐permeability aquitard, which is playing an important role on nitrate attenuation. Evidence of denitrification was also found on both shallow and deep groundwater in the Pichidegua site. This study showed that a comprehensive hydrogeological characterization complemented by chemical and isotope data is key for understanding nitrate distribution and concentration in aquifers from areas with intensive agriculture activities.     

Risk of nitrate leaching from two soils amended with biosolids

High concentrations of N and P in biosolids are one of the strongest appeals for their agronomic use. However, it is essential to understand the fate of N in soils treated with biosolids for both plant nutrition and managing the environmental risk of NO ₃ ⁻ -N leaching. This work aims to evaluate the risk of nitrate leaching from a sandy Podosol soil and from a clay Ferrosol soil, each one amended at the range 0.5–8.0 dry Mg/ha rates of freshly tertiary sewage sludge, composted sludge, limed sludge, heating-dried sludge and solar-irradiated sludge. Results showed that for similar biosolids application rates NO ₃ ⁻ -N accumulated up to 3 times as much in the Ferrosol than in Podosol soil. However, there was a fixed 20% NO ₃ ⁻ -N loss from the 20 cm amended-Ferrosol topsoil, whilst the N-nitrified expected to leach down from 20 cm amended-Podosol topsoil layer ranged from 42% to 76% of the accumulated NO ₃ ⁻ -N, depending on the biosolid type. After all, NO ₃ ⁻ -N expected to leach from Podosol soil ranged from 0.6 (heating-dried sludge) to 3.9 times (limed sludge) relative to Ferrosol soil at similar biosolid application rates. Nevertheless, the risk of NO ₃ ⁻ -N groundwater contamination caused by biosolids applied at 0.5−8.0 dry Mg/ha rates could be considered very low. Published in Russian in Vodnye Resursy, 2006, Vol. 33, No. 4, pp. 492–503.     

Prediction of the arrival of peak nitrate concentrations at the water table at the regional scale in Great Britain

A simple process‐based approach to predict regional‐scale loading of nitrate at the water table was implemented in a GIS for Great Britain. This links a nitrate input function, unsaturated zone thickness, and lithologically dependent rate of nitrate unsaturated zone travel to estimate arrival time of nitrate at the water table. The nitrate input function is the loading at the base of the soil and has been validated using unsaturated zone porewater profiles. The unsaturated zone thickness uses groundwater levels based on regional‐scale observations infilled by interpolated river base levels. Estimates of the rate of unsaturated zone travel are attributed from regional‐scale hydrogeological mapping. The results indicate that peak nitrate loading may have already arrived at the water table for many aquifers, but that it has not where the unsaturated zone is relatively thick There are contrasting outcomes for the two main aquifers which have similar unsaturated zone velocities, the predominantly low relief Permo‐Triassic sandstones, and the Chalk, which forms significant topographic features. For about 60% of the Chalk, the peak input has not yet reached the water table and will continue to arrive over the next 60 years. The methodology is readily transferable and provides a robust method for estimating peak arrival time for any diffuse conservative pollutant where an input function can be defined at a regional scale and requires only depth to groundwater and a hydrogeological classification. The methodology is extendable in that if additional information is available this can easily be incorporated into the model scheme. British Geology Survey © NERC 2011. Hydrological Process © 2011 John Wiley & Sons, Ltd     

Variations in the loadings and riverine transport of nitrate and nitrite in Latvia

The intra-annual and long-term variations in the nitrate and nitrite concentrations and transport are considered for the years 1948–1990. The nutrient loading on the Latvian rivers is subject to considerable intra-annual variations. Weak direct relationships with the fresh water inputs were observed for nitrite, while inverse ones were characteristic for nitrate. The nitrate and nitrite concentrations have been increasing since the late 1950s followed by an increase of the year-to-year variability. Non-point sources of anthropogenic impact (fertilizers leaching from agriculture and the reclamation) increase riverine concentrations of nitrogen compounds, and in particular of nitrate from 300–500 to 1300–1500%.     

Prediction of regional-scale groundwater recharge and nitrate storage in the vadose zone: A comparison between a global model and a regional model

Extensive nitrogen loads at the soil surface exceed plant uptake and soil biochemical capacity, and therefore lead to nitrogen accumulation in the deep vadose zone. Studies have shown that stored nitrogen in the vadose zone can eventually reach the water table and affect the quality of groundwater resources. Recently, global scale models have been implemented to quantify nitrate storage and nitrate travel time in the vadose zone. These global models are simplistic and relatively easy to implement and therefore facilitate analysis of the considered transport processes at a regional scale with no further requirements. However, the suitability of applying these models at a regional scale has not been tested. Here, we evaluate, for the first time, the performance and utility of global scale models at the regional scale. Applied to the Loess Plateau of China, we compare estimates of groundwater recharge and nitrate storage derived from global scale models with results from a regional scale approach utilizing the Richards and advection-dispersion equations. The estimated nitrate storage was compared to nitrate observations collected in the deep vadose zone (>50 m) at five sites across the Loess Plateau. Although both models predict similar spatial patterns of nitrate storage, the recharge fluxes were three times smaller and the nitrate storage was two times higher compared with the regional model. The results suggest that global scale models are a potentially useful screening tool, but require refinement for local scale applications.