Late Quaternary aeolian dust input variability on the Chinese Loess Plateau: inferences from unmixing of loess grain-size records

The grain-size distributions (GSDs) of loess–paleosol sequences may provide valuable information on provenance, transport and paleoclimate variability, and consequently, a wide range of methods to extract genetic information from loess GSDs has been proposed. Here it is shown that a genetically meaningful decomposition of a series of Late Quaternary loess grain-size records extending across the Chinese Loess Plateau can be accomplished with the end-member modelling algorithm (EMMA). The unmixing results in conjunction with loess accumulation rate estimates reveal that two contrasting dust supply patterns were active over the Loess Plateau during the last glacial–interglacial cycle: (i) a background sedimentation pattern that was dominant during interglacial periods, especially over the central and southern parts of the Loess Plateau, is reflected by the constant flux of the fine-grained loess component, (ii) an episodic, highly variable dust input pattern, that was dominant during glacial periods throughout the Loess Plateau and noticeable during interglacial periods mainly over the northern Loess Plateau and almost disappearing over the southern Loess Plateau, is reflected in the admixture of two coarse-grained loess components. A genetic interpretation and the paleoclimatic significance of the mixing model are provided by comparison of the modelled end members with modern dust samples in terms of their GSD and flux rates.     

Quaternary environmental changes in tropical Lake Towuti,Indonesia, inferred from end-member modelling of X-ray fluorescence core-scanning data

Continental and marine sediments are composed of a mixture from different sources and are influenced by a variety of environmental factors and transport processes prior to deposition. For analysis and interpretation, these sources and processes are often challenging to disentangle. We show that end-member modelling of X-ray fluorescence (XRF) core-scanning data helps to overcome these challenges by unmixing different environmental signals from high-resolution sediment geochemical records. We apply this approach to a 100 m long lacustrine succession from Lake Towuti, Indonesia, to separate the regional climate and tectonic history from local ecological and diagenetic processes. The resulting six end-members (EMs) are interpreted to represent changes in ecological (EM1), climatic (EMs 2–4), tectonic (EM 5) and geomorphic (EM6) processes determining changes in sediment composition. Because end-member analysis allows for the tracking of transient and overlapping processes, climatic changes can be followed throughout the 100 m-long succession, suggesting alternating wet and dry periods in Central Sulawesi over long (several 100 000 years) time scales. We show that end-member analysis on elemental data sets offers a detailed and objective means to disentangle depositional processes in sedimentary successions resulting from varying tectonic and environmental factors involved in sediment formation and deposition.     

Sedimentology of a Late Quaternary lacustrine record from the south-eastern Carpathian Basin

The Upper Pleistocene geoarchives in the south-eastern Carpathian Basin are represented predominantly by loess–palaeosol records. In 2015, a 10 m sediment core composed of clay-rich lacustrine sediments was recovered by vibracoring a dry lake basin located between the Vršac Mountains (Serbia) and the Banat Sands in the south-eastern Carpathian Basin; a location relevant for placing regional archaeological results in a palaeoenvironmental context. Here, we present results from geoelectrical prospection and a lithostratigraphic interpretation of this sequence supported by a detailed granulometric study supplemented by ostracod analysis. An age model based on luminescence dating is discussed against sedimentological proxy data and its implication for palaeoenvironmental change. The cores show a stratigraphy of lighter ochre-coloured and darker greyish sediment, related to the deposition of clay and silt trapped in an aquatic environment. Geophysical measurements show ~20 m thick lacustrine sediments. The grain-size distributions including the variability in fine clay are indicative of a lacustrine environment. Fine particles were brought into the depositional environments by aquatic input and settled from suspension; also, direct dust input is constrained by grain-size results. Riverine input and aeolian dust input interplayed at the locality.     

Dust supply from river floodplains: the case of the lower Huang He (Yellow River) recorded in a loess–palaeosol sequence from the Mangshan Plateau

The Mangshan Plateau is located on the south bank of the Huang He (Yellow River) just west of the city of Zhengzhou, well outside the Loess Plateau in central China. Mixing models of the grain‐size data indicate that the loess deposits are mixtures of three loess components. Comparison of the mixing model with existing models established for a series of loess–palaeosol sequences from the Loess Plateau indicates that the Mangshan loess has been supplied from a proximal dust source, the Huang He floodplain, during major dust outbreaks. The high accumulation rates, the composition of the loess components, and especially the high proportions of a sandy loess component support this. Owing to the exceptionally high accumulation rates, the Mangshan grain size, magnetic susceptibility and carbonate records provide a high‐resolution archive of environmental and climate change. Copyright © 2008 John Wiley & Sons, Ltd.     

粒度分布的端元建模分析及检验:以“吉兰泰—河套”盆地西部DK-12钻孔晚第四纪沉积物为例*

端元建模分析能够从复杂的多峰分布特征的沉积物中提取出具有不同沉积动力过程的端元,但是,由于沉积物的粒度分布还受到沉积环境等多种因素的影响,该方法的有效性及获得的端元组分的地质意义有待其他环境代用指标的进一步检验。以位于“吉兰泰—河套”盆地西部磴口次级隆起区的DK-12钻孔晚第四纪沉积物为例,采用BEMMA算法对该钻孔沉积物的粒度资料进行了端元建模分析,并以黏土矿物组合和前人的孢粉组合数据作为检验指标,结合该地区的区域地质背景,对获得的4个端元进行了综合检验分析,认为获得的沉积物粒度端元具有明确的地质意义,其中EM 1为远源粉尘、EM 2为近源的风成沙、EM 3和EM 4为河流冲积沙。     

Dust deposition in the Aral Sea: implications for changes in atmospheric circulation in central Asia during the past 2000 years

We investigated mineral aerosol (dust) deposition in the Aral Sea with intention to understand the variability of dust in central Asia and its implications for atmospheric circulation change in the late Holocene. Using an 11.12-m sediment core of the lake, we calculated bulk sediment fluxes at high time-resolution and analyzed grain-size distributions of detrital sediments. A refined age-depth model was established by combined methods of radiocarbon dating and archeological evidence. Besides, a principal component analysis (PCA) of grain-size fractions and elements (Fe, Ti, K, Ca, Sr) was used to assess the potential processes controlling detrital inputs. The results suggest that two processes are mainly relevant for the clastic input as the medium silt fractions and Ti, Fe and K are positively correlated with Component 1 (C1), and the fine size fractions (<6 μm) are positively correlated with Component 2 (C2). Taking the results of the PCA, geological backgrounds, clastic input processes into account, we propose that the medium silt fractions and, in particular, the grain-size fraction ratio (6–32 μm/2–6 μm), can serve as indicators of the variability of airborne dust in the Aral Sea region. On the contrary, the fine size fractions appear to be contributed mainly by the sheetwash processes. The bulk sediment deposition fluxes were extremely high during the Little Ice Age (LIA; AD 1400–1780), which may be related to the increased dust deposition. As indicated by the variations of grain-size ratio and Ti, the history of dust deposition in central Asia can be divided into five distinct periods, with a remarkably low deposition during AD 1–350, a moderately high value from AD 350–720, a return to relatively low level between AD 720 and AD 1400 (including the Medieval Warm Period (MWP, AD 755–1070)), an exceptionally high deposition from AD 1400 to 1940s and an abnormally low value since 1940s. The temporal variations in the dust deposition are consistent with the changes in the Siberian High (SH) and mean atmospheric temperature of the northern hemisphere during the past 2000 years, with low/high annual temperature anomalies corresponding to high/low dust supplies in the Aral Sea sediments, respectively. The variations in the fine size fraction also show a broadly similarity to a lacustrine δ¹⁸O record in Turkey (Jones et al., 2006), implying that there was less moisture entering western central Asia from the Mediterranean during the LIA than during the MWP.     

An objective technique for determining end-member compositions and for partitioning sediments according to their sources

A modification of Q-mode factor analysis provides an objective technique for end-member characterization of geologic mixtures. Factor analysis has not often been used to determine the actual composition of end-member sources in geologic mixtures, because transformations of the original data variables during the analysis result in negative factor scores for some variables and negative “concentrations” of some variables in the end-members. We use a non-orthogonal rotation of end-member vectors toward the mean vector to bring the end-members into the positive vector space.This technique is demonstrated on a large data set of elemental analyses of bulk sediment surface samples from the Nazca Plate in the southeast Pacific. These data were chosen because they had been studied in detail previously. Our technique identified five geologically reasonable end-members which represent detritus, siliceous biogenic sediment, hydrothermal sediment, hydrogenous or authigenic sediment, and a refractory residue left after the dissolution of biogenic debris. The number, composition, and distribution of the end-members are similar to those derived from previous extensive partitioning studies of the sediments.     

Sedimentary responses to the Pleistocene climatic variations recorded in the South China Sea

Grain-size analyses, coupled with end-member modelling, have been performed on the terrigenous fraction of two Leg 184 Ocean Drilling Program sites (1144 and 1146) from the South China Sea. The grain-size distributions over the last 1.8 Ma enable a new interpretation of their connections to sea-level variations and East Asian monsoon strength. Previous investigations in this area have associated grain-size variability with enhanced eolian input during glacial stages. End-member modelling downgrades the importance of this eolian contribution and indicates that the sediments can be described as a mixture of three end-members: fluvial mud inputs, shelf reworking and river mouth migration. Grain-size variations in the Pleistocene section of the cores indicate a multiple-stage evolution: (i) from 1.8 to 1.25 Ma, the downcore grain-size variations are low but show a correspondence between monsoon rainfall intensity and the fine grain-sized fluvial inputs; no link with sea-level variations is noticeable; (ii) from 1.25 to 0.9 Ma, there is an increase (decrease) in the intermediate (fine) end-member (∼ 100 kyr cycle) that is associated with the onset of a stronger summer monsoon and modest shelf reworking; (iii) from 0.9 to 0 Ma the grain-size record is dominated by global sea-level variations; each glacial stage is associated with extensive shelf reworking and conveyance of coarse particles to the basin.     

Aeolian origin and palaeoclimatic implications of the ‘red clay’ (north China) as evidenced by grain‐size distribution

The ‘Red Clay’ is an important deposit underlying the Quaternary loess–palaeosol sequence in the Chinese Loess Plateau, being regarded as an excellent record of palaeoclimate changes in the late Tertiary. Several properties of the ‘Red Clay’ have been measured previously in order to derive climatic information. However, the sedimentary processes involved and the origin of the materials remain controversial. Here we present results of grain‐size analyses of the ‘Red Clay’ from four representative sites in the Chinese Loess Plateau. In particular their grain‐size distribution is compared with that of typical Quaternary aeolian loess–palaeosol, as well as lacustrine and fluvial sediments. It appears from the sedimentological evidence that the major part of the ‘Red Clay’ is of aeolian origin. It is rather similar in some of its properties to the Quaternary loessic palaeosols. The dust forming the ‘Red Clay’ was transported by a wind system that was weaker than that involved in the accretion of the Quaternary loess. Furthermore, the ‘Red Clay’ sediment has been modified by post‐depositional weathering. Copyright © 2001 John Wiley & Sons, Ltd.     

The Hilina Pali palaeomagnetic excursion and possible self‐reversal in the loess from western Ukraine

A loess‐palaeosol succession from the last glacial cycle was palaeomagnetically studied in the Rivne abandoned brickyard (western Ukraine). Two samples of undisturbed loess from the same depth of parallel sections display steep negative inclinations. These reversed directions in the loess dated at c. 18 ka may possibly be correlated with the Hilina Pali palaeomagnetic excursion. This is the first occurrence of the Hilina Pali in a loess sediment. Unfortunately, the loess with negative inclination does not form any continuous layer that could be suitable for studies of detailed features of geomagnetic field inversion. Another six samples from an illuvial horizon of the Holocene soil also showed negative inclinations and strongly deviated declinations. This part of the section does not represent, however, any palaeomagnetic excursion. The anomalous magnetization in maghemite‐ and titanomagnetite‐rich sediment results most probably from self‐reversal remagnetization. A new insight into palaeomagnetic excursions noted in loess, especially in its parts affected by pedogenic processes, is recommended.     

湖泊沉积物中风成和水成组分定量判据的初步研究———以青海湖为例

对青海湖沉积物进行物质来源进行聚类分析, 并对周边风成黄土与现代湖泊表层沉积物进行粒度分析, 在此基础上, 以青海湖周边典型风成黄土作为风成组分端元, 以青海湖表层沉积物作为水成组分端元, 首次利用已知端元的粒度分布特征对青海湖沉积物中典型粒度分布进行拟合, 进而估算了其中风成和水成组分的比例。结果表明, 青海湖沉积物粒度分布特征可分为三大类:1.水成组分占主导; 2.风成组分占主导(风成黄土主导); 3.两者以不同比例混合。希望此方法能成为未来湖泊沉积物中不同组分的定量判据和古环境的解读提供新途径。      

源区距离对黄土粒度多组分分布特征的影响

利用高分辨率激光粒度仪MS2000对陕西渭南、北京灵山、河南邙山等地大量黄土样品的粒度多组分分布特征进行了系统研究,总结了其多组分粒度分布及组分间差异特征并讨论了源区距离对黄土粒度多组分分布特征的影响。取得了以下认识：（1）黄土粉尘粒径以〈70μm的悬浮组分为主,其粒度由细、中、粗3个组分（中值粒径范围分别为〈1μm、1～10μm、10～70μm）构成,表现为多组分粒度特征。粗粒组分含量最高,峰形最明显。粗粒与中粒组分粒径与百分含量变化很大程度受控于源区距离变化。（2）不同地区黄土粉尘粒度差异明显,粗粒组分中值粒径随源区距离增加而减小,二者负相关;中粒组分百分含量随源区距离增加而增加,二者正相关。（3）粒度组分分离方法能够反映同一源区粒度的细微差异,显示其粒度组分分离的优越性。（4）理论推导了黄土粗粒组分的中值粒径与源区距离的关系并用实际拟合函数验证了其正确性。     

Regional lithofacies and pedofacies variations along a north to south climatic gradient during the Last Glacial period in the central Loess Plateau,China

Five lateral sand–loess–palaeosol continua occur within the last glacial sediments of the central Loess Plateau of China along a 500 km north to south climatic gradient. The continua shift southward or northward in concert with desert expansion or contraction, respectively. Lateral lithofacies (desert sand to loess) variations are evident at the north end of the gradient and follow Walther's Law of the correlation of facies. Lateral pedofacies (loess to palaeosol) variations are present near the south end of the gradient, where the climate was warmer and wetter. The lateral stratigraphic changes from sand to loess or loess to soil are driven by variations in the rate of sedimentation along a climatic gradient.Vertical stratigraphic profiles at the north end of the gradient reveal alternating sand and loess beds. In contrast, alternating loess and palaeosols occur within the same stratigraphic interval in the southern Loess Plateau, where dust accretion rates were lower. However, in high resolution studies of climate change vertical profiles of alternating loess and palaeosols (especially weak palaeosols) may not reflect regional or global climate change. Alternating loess and weak palaeosols may reflect local variations in the balance between the rates of dust accretion and pedogenesis. Local fluctuations in either of these rates could result in the presence of time equivalent loess and palaeosols at high resolutions. Thus, some of the high resolution loess-palaeosol alternations may reflect local climatic variation rather than global or hemispherical climate change.     

Luminescence chronology of the Upper Pleistocene loess record at Kurtak in M iddle Siberia

The loess/palaeosol sequence of Kurtak, situated at the western bank of the upper Yenisei in Middle Siberia, represents one of the best developed Middle and Upper Pleistocene sediment records in Yenisei Siberia. More than 40 m thick loess and loess-like sediments intercalated by at least four pedocomplexes are exposed at a steep erosional slope at the bank of the Krasnoyarsk Water Reservoir. Infrared optically stimulated luminescence (IRSL) and thermoluminescence (TL) dating techniques have been applied on 38 fine grain samples from the upper 23 m of the profile, representing the penultimate and last interglacial–glacial cycle. The IRSL and TL age estimates are in good agreement with the geological estimates up to the last interglacial soil horizon (oxygen isotope substage (OIS) 5e). The luminescence ages show that the lowermost truncated palaeosol of kastanosjem-type is likely to have formed during the penultimate interglacial upon subaerial deposits. Three weak reddish brown palaeosols intercalated by reworked loess-like sediments correlate with early Upper Pleistocene interstadials (OIS5dion of -a), and a succession of humic horizons alternated by cryoturbation processes (Kurtak pedocomplex) is linked with OIS 3. Thick loess deposits between the pedocomplexes show now significant age increase with depth, indicating high accumulation rates at around 23 ka (OIS 2) and 60 ka (OIS 4).     

Climatic implications of loess deposits from the Beijing region

Variations in magnetostratigraphy, pedostratigraphy, grain size and magnetic susceptibility of the loess deposits near Beijing have been studied at two sections. The sections are about 400 km east of the main loess deposits in China, have a maximum thickness of 100 m and extend back to 1.1 Ma. The sequence consists of 14 loess–palaeosol couplets (S0‐S14), which correlate well with sequences in the Loess Plateau. Susceptibility records from the sites near Beijing are comparable to the Xifeng, Luochuan and Baoji sections located in the middle part of the Loess Plateau; however, the down‐core variations in the grain size in the Upper Lishi Formation exhibit some differences. The median grain size increases by about 25–30 µm from L4 to L2, with the sandy grains (>63 µm) increasing from 10–20 wt% to 40–50 wt% . This implies that the depositional environment of the dust sources in the Beijing loess section is different in some aspects from the Loess Plateau. The Beijing loess may have had a different dust source than the Loess Plateau. Copyright © 2001 John Wiley & Sons, Ltd.     

Identification and mapping of some soil types using field spectrometry and spectral mixture analyses: a case study of North Sinai, Egypt

This study examines linear spectral unmixing technique for mapping the surface soil types using field spectroscopy data as the reference spectra. The investigated area is located in North Sinai, Egypt. The study employed data from the Landsat 7 ETM+ satellite sensor with improved spatial and spectral resolution. Mixed remotely sensed image pixels may lead to inaccurate classification results in most conventional image classification algorithms. Spectral unmixing may solve this problem by resolving those into separate components. Four soil type end-members were identified with minimum noise fraction and pixel purity index analyses. The identified soil types are calcareous soils, dry sabkhas, wet sabkhas, and sand dunes. Soil end-member reference spectra were collected in the field using an ASD FieldSpec Pro spectrometer. Constrained sum-to-one and non-negativity linear spectral unmixing model was applied and the soil types map was produced. The results showed that linear spectral unmixing model can be a useful tool for mapping soil types from ETM+ images.     

山东青州地区黄土的粒度组成及成因分析

在鲁中山地北侧的山间谷地及山麓地带广泛发育厚度不一的黄土堆积。对该区青州傅家庄黄土剖面进行了系统的粒度分析, 并与黄土高原的第四纪黄土-古土壤、北京现代降尘、剖面附近的河流相样品进行了对比。结果表明, 青州黄土的粒度分布特征与北京现代降尘、黄土高原黄土非常相似, 与河流相样品则有很大的不同; 在整个序列中, 青州黄土粒度变化与黄土高原典型的风成黄土、古土壤一致, 黄土层颗粒粗, 古土壤层颗粒细。上述结果从沉积学的角度为青州黄土风成成因提供了证据。青州黄土的粒度组成特征及前人的研究表明, 青州黄土主要来源于沉积区以北的黄泛平原和莱州弯等地出露的海相地层, 其次是高空气流携带的西北内陆的远缘粉尘。      

Quartz luminescence sensitivity variation in the Chinese loess deposits: the potential role of wildfires

The sensitivity of optically stimulated luminescence (OSL) of quartz grains has been applied to trace the provenances of sediments in various environments. Here, we studied the OSL sensitivity of quartz grains in four sections (Jingyuan, Huanxian, Xifeng and Luochuan) along a west–east transect on the Chinese Loess Plateau (CLP). The quartz OSL sensitivity in the palaeosol units is higher overall than that in the loess units, and it shows an increasing trend from the west CLP to the east CLP. In palaeosol units, it increases by a factor of ~20 along the west–east transect; while in loess units it increases by a smaller degree of 3–5. The change of provenances and the change of distances between the provenances and the loess sections cannot fully account for the large degree of sensitivity variation between the loess and palaeosol units in the central and eastern CLP. We propose that wildfires may have played an important role in enhancing the quartz OSL sensitivity in the palaeosol units in the central and eastern CLP. Quartz OSL sensitivity has the potential to be used as a proxy for palaeowildfires.     

Genetically meaningful decomposition of grain-size distributions

All spatio-temporal grain-size patterns in sediments can be characterized by a mathematical representation of (un)mixing. This implies that an inverse model of (un)mixing would be ideally suited to obtain genetically meaningful interpretations of observed grain-size distributions (GSDs). GSDs are therefore often decomposed into theoretical end members by parametric curve-fitting procedures. Many researchers have been tempted to use goodness-of-fit measures as a means of justifying such decompositions in the absence of generic process-based models of end-member GSDs. A critical examination of parametric curve fitting through a series of numerical experiments shows that the goodness-of-fit of an approximation may be a poor guide to its genetic significance. The genetic interpretation of GSDs is a poorly constrained problem that cannot be solved without taking into account the geological context of GSDs, which may be captured by the covariance structure of grain-size classes across a series of GSDs sampled in a contiguous area. Curve-fitting methods cannot exploit this geological context, which explains why the geological relevance of curve-fitting results obtained in black-box mode is questionable. The desired genetic interpretation of GSDs can be obtained by applying the end-member-modelling algorithm EMMA to a series of GSDs simultaneously. Many end-member GSDs estimated by EMMA do not conform to one of the popular theoretical GSD models. Consequently, parametric curve fitting with theoretical distributions is more likely to obscure than to reveal the existence of genetically significant grain-size populations in sediments, especially if such populations are present in small proportions.     

Rb and Sr Geochemical Characterization of the Chinese Loess Stratigraphy and Its Implications for Palaeomonsoon Climate

Concentrations and distributions of Rb and Sr in loess and palaeosol samples from the Luochuan profile have been studied, in grain-size fractions and chemical forms. Results show that Rb is quite rich in the fraction of less than 2μm, and exits only in the residual phase, while Sr is distributed in sand and silt fractions, occurring in the residual and carbonate phases. Therefore, variations of the concentrations of Rb and Sr in loess and palaeosols are closely related not only to dustfall compositions depending on winter monsoon wind strength but also to summer monsoon-induced pedogenic intensity. This indicates that variations of Rb/Sr ratio in Chinese loess sequences represent cyclic alternations of East Asian summer and winter monsoon climates on the orbital time-scale. Variations in Sr concentrations along the sequence bear a high similarity to the oxygen isotope record of the deep sea sediments over the past 2.5 Ma, whereas variations in Rb concentrations are in good agreement with the record of