Solar response in the vertical structure of ozone and temperature in the tropical stratosphere

The aim of the present paper is to study the solar response in the vertical structure of ozone and temperature over the Indian tropical region and a search for any mutual relationship between their solar coefficients on a decadal scale in the lower stratosphere. For the purpose, the data obtained by ozonesonde and Umkehr methods for the lower stratospheric ozone and that of the total ozone amount from Dobson spectrophotometer during the period 1979–2001 have been analyzed. These data are analyzed using the multi-functional regression model, which takes into account most of the known natural and anthropogenic signals. The NCEP- and MSU-satellite data for the temperature over this region have been used. Results indicate an in-phase correlation of around 0.5 between ozone and solar flux (F10.7) in the vertical structure over the equatorial station, Trivandrum (8.3°N) but no significant correlation over Pune (18.3°N). The solar components of ozone and temperature indicate an in-phase but poor correlation in the lower stratospheric altitudes over both stations. However, when total ozone content data is analyzed, it indicates a very high correlation (⩾0.9) between the solar components of ozone and temperature. The solar trend in the vertical distribution of ozone is found to be of the order of 5–25% per 100 units of F10.7 solar flux for Trivandrum but it is relatively smaller (1.6–15.2%) over Pune. The solar dependence of temperature is found to be quite significant for the entire Indian tropical region with not much latitudinal variation.     

A method of computing the vertical profile of ozone concentration based on radiation field analysis

Summary A methodical approach is presented of solving the inverse problem of atmospheric optics for the vertical profile of ozone concentration. Observations of spectral sky radiance and direct solar radiation are taken as input data. A gradient method is suggested for solving the inverse problem. on leave from the Astronomical Institute, Slovak Academy of Sciences     

On the theoretical model for vertical ozone density distributions in the mesosphere and upper stratosphere

Diurnal variations in the vertical ozone density distribution have been calculated for the height range 40–150 km by extending our existing computer programs. The steady-state profiles were first calculated for fifteen constituents in the original program and three additional constituents (CH₄, CO and CO₂); the result was used as the initial condition for the time-dependent solution. The profile of the eddy diffusion coefficient used in this study was determined by comparing the model profile with the observations for CH₄, whose density distribution is verysenstive to the eddy diffusion coefficient The effects of hydrogen and nitrogen compounds on the ozone density are discussed somewhat quantitatively; they reduce the ozone density mainly in the mesosphere and stratosphere, respectively. Special attention is given to the large depression of the ozone density at around 70–85 km, which has been obtained in many theoretical models but has neither been explained nor definitely confirmed by observations. Our time-dependent model indicates that the depression develops at night by the effect of hydrogen-oxygen and nitrogen-oxygen reactions and of eddy diffusion transports. The latter effect also produces an increase of the ozone density after midnight at some heights in the depression region.     

Temperature and ozone variations in the stratosphere

Examined are temperature and ozone variations in the Northern Hemisphere stratosphere during the period 1958–77, as estimated from radiosondes rocketsondes, ozonesondes, and Umkehr measurements. The temperature variation in the low tropical stratosphere is a combination of the variation associated with the quasi-biennial oscillation, and a variation nearly out of phase with the pronounced 3-yearly temperature oscillation (Southern Oscillation) present in the tropical troposphere since 1963. Based on radiosonde and rocketsonde data, the quasibiennial temperature oscillation can be traced as high as the stratopause, the phase varying with both height and latitude. However, the rocketsonde-derived temperature decrease of several degrees Celsius in the 25–55 km layer of the Western Hemisphere between 1969 (sunspot maximum) and 1976 (sunspot minimum) is not apparent in high-level radiosonde data, so that caution is advised with respect to a possible solar-terrestrial relation.There has been a strong quasi-biennial oscillation in ozone in the 8–16 km layer of the north polar region, with ozone minimum near the time of quasi-biennial west wind maximum at a height of 20 km in the tropics. A quasi-biennial oscillation in ozone (of similar phase) is also apparent from both ozonesonde data and Umkehr measurements in 8–16 and 16–24 km layers of north temperate latitudes, but not higher up. Both measurement techniques also suggest a slight overall ozone decrease in the same layers between 1969 and 1976, but no overall ozone change in the 24–32 km layer. Umkehr measurements indicate a significant 6–8% increase in ozone amount in all stratospheric layers between 1964 and 1970, and in 1977 the ozone amount in the 32–46 km layer was still 4% above average despite the predicted depletion due to fluorocarbon emissions. The decrease in ozone in the 32–46 km, layer of mid latitudes following the volcanic eruptions of Agung and Fuego is believed to be mostly fictitious and due to the bias introduced into the Umkehr technique by stratospheric aerosols of volcanic origin. Above-average water vapor amounts in the low stratosphere at Washington, DC, appear closely related to warm tropospheric temperatures in the tropics, presumably reflecting variations in strength of the Hadley circulation.     

Nonlinear behavior on an ozone photochemical system in the stratosphere

A nonlinear box system describing ozone photochemistry in the stratosphere is presented. Influences of pollutants, such as odd chlorine (Cl_x) and odd nitrogen (NO_x) discharged by human activities, on photochemical states of the system are investigated in detail. The results show that the solutions of the box system constitute a ‘cusp’ catastrophe manifold in the state-parameter space. An increase of about 30% for Cl_x source strength or a decrease of about 30% for NO_x source strength from their current level may lead to catastrophic transition and results in a reduction of ozone concentration about 50 times. Project supported by the National Natural Science Foundation of China and Laboratory for Aeronomy and Global Environmental Observation of IAP.     

OH radical concentration in the stratosphere

The consumption of both methane and carbon monoxide in the lower stratosphere is due predominantly to reaction with OH radicals. The possibility of deriving OH concentration from measurements of the decrease of CH₄ and CO mixing ratios above the tropopause is explored. The observations and the basic chemistry are briefly summarized. Simple one-dimensional diffusion models are employed to derive expressions for the decrease of CH₄ and CO mixing ratios with altitude above the tropopause, and the influence of important parameters is discussed. Vertical air velocities resulting from large-scale organized mean motion and from synoptic variations are shown to distort the concentration altitude profiles of methane and carbon monoxide, respectively. Suitable averaging of observational data is required to eliminate the effects due to vertical motion. Then a reliable value for the effective OH number density should be obtainable. At present an estimate of 4×10⁶ molecules/cm³ is derived.     

Influence of strong sudden stratospheric warmings on ozone in the middle stratosphere according to millimeter wave observations

This paper reports the study data on variations in the ozone content in the middle stratosphere over Moscow based on millimeter wavelength observations during a range of midwinter sudden stratospheric warmings that occurred in the past two decades. The relation of ozone with planetary waves and the intensity of the polar stratospheric vortex has been established. The ozone vertical distribution has been monitored with a highly sensitive spectrometer with a two-millimeter wave band. The discovered phenomena of a relatively long-term lower ozone content in December in the considered cold half-year periods are related to the higher amplitude of the planetary wave with n = 1. Such phenomena preceded the development of strong midwinter stratospheric warmings, which, in turn, were accompanied by a significant increase in the ozone content in January. This ozone enrichment was related to the lower amplitude of the wave with n = 1 and higher amplitude of the wave with n = 2 and was accompanied by geopotential H _c.v. growth in the polar vortex center. Specific features of variations in the ozone content under the influence of the major atmospheric processes are observed not only in certain cold half-year periods but are also well seen in the general averaged pattern for winters with strong stratospheric warmings.     

Atmospheric ozone and the movement of the air in the stratosphere

Using over 2200 ozonesonde ascents, published byHering andBorden [1]–[5] and byDütsch et al. [6], [7], the average vertical distribution of the ozone mixing ratio is found for different latitudes and for different seasons up to a height of 30 km. The method by which the ozone formed at great heights in low latitudes becomes concentrated in the lower stratosphere of high latitudes is discussed, and the meridional circulation theory is strongly suggested.Oxford, May 1972.     

Microwave measurements of the ozone content in winter arctic stratosphere

As a result of the long-term observations lead in region of Kola Peninsula, connection between character of variations of the ozone content in a stratosphere of Arctic regions and behavior and structure of a winter polar vortex is established. During winter seasons with well developed cyclone and duration of stable existence not less than 1.5–2 months were observed extremely low ozone number density at heights 20–25 km connected, apparently, with its chemical destruction. On the other hand, during disturbances of the vortex, accompanied strong stratospheric warming, was registered almost double increase of ozone amount in a high-altitude interval from 20 up to 40 km. Comparison of results of ground-based microwave monitoring of an ozone layer to data of the satellite instrument EOS MLS installed on satellite AURA is lead. In most cases comparison has shown satisfactory within the limits of an error of measurements coincidence of results. However in conditions of atmospheric disturbances when arose significant spatial heterogeneity, the discrepancy of results of comparison was marked. The possible reasons which cause the detected disagreement in results are discussed.     

Influence of short-term changes in solar activity on baric field perturbations in the stratosphere and troposphere

Influence of short-term changes in solar activity on baric (pressure) field perturbations is studied using such characteristics as the Sazonov index (IS), describing the intensity of meridional transfer, the Blinova index (IB), describing the intensity of zonal transfer, and ‘vorticity area index’ (VAI) describing the tropospheric cyclonic perturbations. The epoch superposition method is used to reveal effects of the solar central meridian (CM) passage of active regions, the Forbush decreases (FD) in galactic cosmic rays, and the solar proton (SP) events. The results of the analysis show that influence of short-term changes in the solar activity on baric field perturbations is the most evident in the stratosphere (30 mbar-level). The meridional circulation in case of the FD and SP events begin to increase about 5–7 days before the key date, reaches maximum nearby the key date and decays after the key date. The meridional circulation in case of the solar CM passage of active regions starts to increase after the key date and reaches the maximum by 5–6 days. Fluctuations of baric field within periods of 5–7 days typical of meridional and zonal transfers in troposphere (500 mbar-level) are evidently connected with internal dynamics of the atmosphere, not with the effects of solar activity. VAI characterizing cyclonic activity in the troposphere, shows the striking correspondence to changes of the meridional circulation in the stratosphere. Comparison of changes in the stratospheric perturbations with behavior of the UV irradiance in course of the FD and SP events show their full correspondence at the initial stage of these processes. The conclusion is made that growth of baric perturbations observed in the stratosphere in associations with the FD and SP events before the key date is caused by the solar UV irradiance increase, whereas decay of the baric perturbations after the key date is related to direct influence of the solar energetic corpuscular fluxes on the stratosphere.     

Experimental errors of measurements of vertical geomagnetic gradients in the stratosphere

The errors of measurements of vertical geomagnetic gradients at altitudes of 20–40 km, using a balloon magnetic gradiometer with a 6-km-long measuring base oriented along gravity, have been studied in the work. The errors related to the deviation of the measuring base position relative to the vertical have been studied during the real balloon flight with the help of the navigation GPS receivers. The deviations of the measuring base within 5°, which can sometimes reach 15°, have been obtained. This results in a decrease in the magnetic gradient measurement accuracy due to the errors introduced in the specification of the normal magnetic field used to detect magnetic anomalies. To eliminate this error, a GPS receiver was built in each magnetometer in order to observe magnetometers during synchronous measurements and to correct the measurements for the normal magnetic field. It has been indicated that the effect of deviations of the measuring base position on the results is not more than 2% of the measured value at such organization of a gradiometer.     

The vertical distribution of CFM and related species in the stratosphere

Available data on halogenated molecules in the stratosphere will be reviewed. Presently vertical profiles of CFCl₃ and CF₂Cl₂ in the stratosphere exist to 50 km altitude. Only measurements in the lower stratosphere are reported for the other major halocarbons, CCl₄ and CH₃Cl. Profiles of the product species ClO, Cl, HCl, and HF exist to about 35 km.Comparison with theoretical profiles from 1-D models shows generally good agreement except for ClO where the earliest measured concentrations exceed the calculated ones considerably.     

On the vertical distribution of carbon monoxide and methane in the stratosphere

The vertical distribution of the methane concentration in the stratosphere is related to its dissociation by two simultaneous daytime reactions with excited oxygen atoms O(¹D) and with OH radicals and depends on the stratospheric eddy diffusion coefficient.Dissociation of CH₄ in the lower stratosphere leads to the production of CO molecules while in the upper stratosphere thepphotodissociation of CO₂ molecules is an additional process to the CO production.In the upper stratosphere (40±10 km) there is an equilibrium between the formation and destruction processes of carbon monoxide which leads to a minimum of its mixing ratio. There is an increase of the CO mixing ratio in the troposphere and mesosphere compared with that of the stratosphere.The vertical distribution of the CO mixing ratio is closely related to the eddy diffusion coefficient in the whole stratosphere but the absolute values of the hydroxyl radical concentration also determine the values of the CO mixing ratio.     

Possible correlation between ozone and aitken nuclei counts in the lower stratosphere

A study is presented of a possible correlation between ozone and Aitken nuclei concentration measured between 6 km and 19 km by the instruments installed on the WB-57F aircraft. Samples were taken between 48°N and 9°S latitudes over the U.S., the Gulf of Mexico, and Central and South America between March 1974 and February 1975.A weak negative correlation between AN and ozone concentrations was found at altitudes higher than the tropical tropopause. Scattering of the signs and magnitudes of correlation coefficients was found below the tropopause. Largest variations of the coefficient values were related to the stratospheric pollution following the eruption of the Guatemalan volcano Fuego.     

坡地地形对竖向地震动反应谱特性的影响分析

为分析坡地地形对竖向地震动反应谱特性的影响规律,采用有限元数值分析方法,对黏弹性岩质坡地在白噪声输入下的响应进行计算。分析了坡地地形对场地竖向反应谱及谱比的影响,研究了随着坡高及坡角的增加,坡地斜坡段及平台段竖向反应谱及谱比的变化规律,给出了坡地斜坡段及平台段设计竖向地震动放大系数,有关的研究结论可为坡地上工程结构的抗震设计提供参考。     

Influence of wave activity on the composition of the polar stratosphere

The planetary wave impact on the polar vortex stability, polar stratosphere temperature, and content of ozone and other gases was simulated with the global chemical–climatic model of the lower and middle atmosphere. It was found that the planetary waves propagating from the troposphere into the stratosphere differently affect the gas content of the Arctic and Antarctic stratosphere. In the Arctic region, the degree of wave activity critically affects the polar vortex formation, the appearance of polar stratospheric clouds, the halogen activation on their surface, and ozone anomaly formation. Ozone anomalies in the Arctic region as a rule are not formed at high wave activity and can be registered at low activity. In the Antarctic Regions, wave activity affects the stability of polar vortex and the depth of ozone holes, which are formed at almost any wave activity, and the minimal ozone values depend on the strong or weak wave activity that is registered in specific years.     

Estimate of the effect of the 11-year solar activity cycle on the ozone content in the stratosphere

Using spectral, cross-spectral, and regression methods, we analyzed the effect of the 11-year cycle of solar activity on the ozone content in the stratosphere and lower mesosphere via satellite measurement data obtained with the help of SBUV/SBUV2 instruments in 1978–2003. We revealed a high coherence between the ozone content and solar activity level on the solar cycle scale. In much of this area, the ozone content varies approximately in phase with the solar cycle; however, in areas of significant gradients of ozone mixing ratio in the middle stratosphere, the phase shift between ozone and solar oscillations can be considerable, up to π/2. This can be caused by dynamical processes. The altitude maxima of ozone sensitivity to the 11-year solar cycle were found in the upper vicinity of the stratopause (50–55 km), in the middle stratosphere (35–40 km), and the lower stratosphere (below 25 km). Maximal changes in ozone content in the solar cycle (up to 10% and more) were found in winter and spring in polar regions.     

Lagrangian motion of air parcels in the stratosphere in the presence of planetary waves

Development of thoughts on tracer transport mechanisms in the stratosphere which lead to new approaches to two-dimensional modeling of the tracer problem is reviewed.Three-dimensional motions of individual air parcels affected by a planetary wave are investigated theoretically, treating a steady, upward propagating wave in a uniform flow. It is shown that trajectories of air parcels are of elliptical form when projected onto the meridional plane and that they have no mean meridional or vertical motion, even though the usual zonal Eulerian-mean vertical motion exists. The origin of the difference between the mean air parcel motion and the Eulerian-mean motion is discussed.On the basis of the knowledge of air parcel motion, two approaches to two-dimensional modeling are considered. The generalized Lagrangian mean motion (quasi-zonal weighted mean taken over a meandering material tube), recently introduced by Andrews and McIntyre, is identical with the mean motion of an air parcel in a steady state. Such a mean meridional circulation may be used for advecting a tracer in the meridional plane in a two-dimensional model. The transport effect is represented solely by the advection and an eddy transport does not appear in this scheme, to a first approximation.The finding that trajectories of air parcels are elliptical necessitates a reexamination of the Reed-German eddy diffusivity currently used in two-dimensional chemical-dynamical models. By applying a mixing length type hypothesis, we derive an eddy diffusivity formula for use in Eulerian-mean calculations, which, in the case of a conservative tracer is dominated by an anti-symmetric tensor. The eddy transport due to this anti-symmetric tensor diffusivity is of advective type (not diffusive) and has the effect of taking the Stoke drift effect into account, when used in the usual Eulerian-mean formulation.     

Statistical characteristics of the vertical ozone distribution in mid-latitudes

Summary The correlation matrix for the vertical ozone distribution and the temperature-ozone cross-correlation matrix, which was calculated from ozone soundings made over Berlin between 1967 and 1970, the statistical structure of the vertical ozone profile (correlation coefficients, average profiles, average standard deviation, relative variability) was derived for the three ozone seasons. The partial ozone pressure does not at all heights follow a normal distribution (e. g. at tropopause level). Generally, the correlation between tropospheric and stratospheric ozone is rather poor. In some layers the highest correlation coefficients, i.e. –0.3 and +0.4, occur in autumn (October to December) and in winter and spring (January to April). The correlation between the ozone amounts of various stratospheric layers is distinct in autumn, less distinct in summer (May to September) and entirely missing from January to April. Conspicuous cross-correlations between temperature and ozone have been found for all three seasons. a) With a negative correlation between tropospheric temperature and middle tropospheric to middle stratospheric ozone (maximum up to –0.8); b) with a rather strong positive correlation between the ozone amount and the temperature in the lower stratosphere (maximum up to +0.84); c) with a positive correlation between the ozone amount of the middle stratosphere and the temperature of the middle stratosphere (maximum up to +0.8). The highest correlation coefficients occur in autumn.