Isolated olivines in the Yamato 82042 CM2 chondrite: The tracing of major condensation events in the solar nebula

Abstract— Yamato 82042 is an unusual CM2 chondrite consisting mainly of phyllosilicates, a few olivines and carbonates, very minor sulphides and trace metal. Olivine occurs: (1) as isolated grains dispersed in the phyllosilicate matrix, (2) as constituents of mineral aggregates or accretionary fragments associated with abundant phyllosilicates and minor sulphides, and (3) as objects which resemble barred olivine chondrules also associated with phyllosilicates. Olivine, from all occurrences, ranges in composition from 0.26 to 22.6 weight % FeO, but generally contains less than 1.25 wt.% FeO. Minor element contents, particularly Ca, Al, and Cr, are relatively high and are generally correlated, as reported for olivines in other carbonaceous chondrites. However, we report here uncorrected trends for the same minor elements which occur in distinct areas (volumes) within the same olivines. These compositional trends may be due to condensation of olivine from a vapor of non-solar composition and partial mobilization of Ca during later annealing. If this is the case, the data may be used to trace changes in the Ca/Al ratio of the parent medium during the formation of these olivines, provided that it is possible to distinguish the effects of any post-formation annealing which could have redistributed the minor elements. Some isolated olivines show distinctive minor element zoning which severely limits the possibility of any post-formation redistribution of these elements. Accordingly, these isolated olivines indeed retain evidence of early condensation processes in the solar nebula, though non-classic conditions are implied for their formation.     

Microchondrules in two unequilibrated ordinary chondrites: Evidence for formation by splattering from chondrules during stochastic collisions in the solar nebula

The diversity of silicate, glassy spherules analogous to chondrules, called microchondrules, and the implications for their presence in unequilibrated ordinary chondrites (UOCs) were investigated using different electron microscope techniques. Our observations show that the abundance of microchondrules in UOCs is much larger than the values proposed by previous studies. We identified two different types of microchondrules, porous and nonporous, embedded within fine‐grained matrices and type I chondrule rims. The porous microchondrules are characterized by distinctive textures and chemical compositions that have not been recognized previously. Additionally, we show detailed textures and chemical compositions of protuberances of silicate materials, connected to the chondrules and ending with microchondrules. We suggest that microchondrules and protuberances formed from materials splattered from the chondrules during stochastic collisions when they were still either completely or partially molten. The occurrence and distinct morphologies of microchondrules and protuberances suggest that rather than just a passive flash melting of chondrules, an additional event perturbed the molten chondrules before they underwent cooling. The bulk chemical compositions suggest that (1) nonporous microchondrules and protuberances were formed by splattering of materials that are compositionally similar to the bulk silicate composition of type I chondrules, and (2) the porous microchondrules could represent the splattered melt products of a less evolved, fine‐grained dust composition. The preservation of protuberances and microchondrules in the rims suggests that the cooling and accretion rates were exceptionally fast and that they represent the last objects that were formed before the accretion of the parent bodies of OCs.     

Nanophase iron carbides in fine‐grained rims in CM2 carbonaceous chondrites: Formation of organic material by Fischer–Tropsch catalysis in the solar nebula

Transmission electron microscope studies of fine‐grained rims in three CM2 carbonaceous chondrites, Y‐791198, Murchison, and ALH 81002, have revealed the presence of widespread nanoparticles with a distinctive core–shell structure, invariably associated with carbonaceous material. These nanoparticles vary in size from ~20 nm up to 50 nm in diameter and consist of a core of Fe,Ni carbide surrounded by a continuous layer of polycrystalline magnetite. These magnetite shells are 5–7 nm in thickness irrespective of the diameter of the core Fe,Ni carbide grains. A narrow layer of amorphous carbon a few nanometers in thickness is present separating the carbide core from the magnetite shell in all the nanoparticles observed. The Fe,Ni carbide phases that constitute the core are consistent with both haxonite and cohenite, based on electron diffraction data, energy dispersive X‐ray analysis, and electron energy loss spectroscopy. Z‐contrast scanning transmission electron microscopy shows that these core–shell magnetite‐carbide nanoparticles can occur as individual isolated grains, but more commonly occur in clusters of multiple particles. In addition, energy‐filtered transmission electron microscopy (EFTEM) images show that in all cases, the nanoparticles are embedded within regions of carbonaceous material or are coated with carbonaceous material. The observed nanostructures of the carbides and their association with carbonaceous material can be interpreted as being indicative of Fischer–Tropsch‐type (FTT) reactions catalyzed by nanophase Fe,Ni metal grains that were carburized during the catalysis reaction. The most likely environment for these FTT reactions appears to be the solar nebula consistent with the high thermal stability of haxonite and cohenite, compared with other carbides and the evidence of localized catalytic graphitization of the carbonaceous material. However, the possibility that such reactions occurred within the CM parent body cannot be excluded, although this scenario seems unlikely, because the kinetics of the reaction would be extremely slow at the temperatures inferred for CM asteroidal parent bodies. In addition, carbides are unlikely to be stable under the oxidizing conditions of alteration experienced by CM chondrites. Instead, it is most probable that the magnetite rims on all the carbide particles are the product of parent body oxidation of Fe,Ni carbides, but this oxidation was incomplete, because of the buildup of an impermeable layer of amorphous carbon at the interface between the magnetite and the carbide phase that arrested the reaction before it went to completion. These observations suggest that although FTT catalysis reactions may not have been the major mechanism of organic material formation within the solar nebula, they nevertheless contributed to the inventory of complex insoluble organic matter that is present in carbonaceous chondrites.     

Growth and sedimentation of dust grains in the primordial solar nebula

Of the formation processes in the solar system, the process of growth and sedimentation of dust grains in the primordial solar nebula is investigated for a region near the Earth's orbit. The growth equation for dust grains, which are sinking as well as being in thermal motion, is solved numerically in the wide mass range between 10^?12 and 10⁶ g. Any turbulent motions in the nebula are assumed to have already decayed when the sedimentation begins. The numerical simulation shows that the growth and sedimentation proceed faster than was found by Kusaka et al. (1970) but in accordance with the estimate of Safronov (1969) owing to a cooperative interaction of the growth and the sedimentation; that is, at about 3 × 10³ years after the beginning of the growth and sedimentation a dust layer, composed of centimeter-sized grains, is formed at the equator of the solar nebula. Furthermore, the mass density of dust grains floating in the outer layers of the nebula is found to be of the order of 10^?5 after 10⁵ years compared with that before the sedimentation. From these results, it can be estimated that at about 5 × 10³ years after the beginning of sedimentation the dust layer breaks up owing to the onset of gravitational instability.     

Accretion of dust by chondrules in a MHD-turbulent solar nebula

Numerical magnetohydrodynamic (MHD) simulations of a turbulent solar nebula are used to study the growth of dust mantles swept up by chondrules. A small neighborhood of the solar nebula is represented by an orbiting patch of gas at a radius of 3 AU, and includes vertical stratification of the gas density. The differential rotation of the nebular gas is replaced by a shear flow. Turbulence is driven by destabilization of the flow as a result of the magnetorotational instability (MRI), whereby magnetic field lines anchored to the gas are continuously stretched by the shearing motion. A passive contaminant mimics small dust grains that are aerodynamically well coupled to the gas, and chondrules are modeled by Lagrangian particles that interact with the gas through drag. Whenever a chondrule enters a region permeated by dust, its radius grows at a rate that depends on the local dust density and the relative velocity between itself and the dust. The local dust abundance decreases accordingly. Compaction and fragmentation of dust aggregates are not included. Different chondrule volume densities ρ_c lead to varying depletion and rimmed-chondrule size growth times. Most of the dust sweep-up occurs within ～1 gas scale-height of the nebula midplane. Chondrules can reach their asymptotic radius in 10–800 years, although short growth times due to very high ρ_c may not be altogether realistic. If the sticking efficiency Q of dust to chondrules depends on their relative speed δv, such that Q < 10^?2 whenever δv > v_stick ≈ 34 cm/s (with v_stick a critical sticking velocity), then longer growth times result due to the prevalence of high MRI-turbulent relative velocities. The vertical variation of nebula turbulent intensity results in a moderate dependence of mean rimmed-chondrule size with nebula height, and in a ～20% dispersion in radius values at every height bin. The technique used here could be combined with Monte Carlo (MC) methods that include the physics of dust compaction, in a self-consistent MHD-MC model of dust rim growth around chondrules in the solar nebula.     

Cr isotopes in physically separated components of the Allende CV3 and Murchison CM2 chondrites: Implications for isotopic heterogeneity in the solar nebula and parent body processes

Chromium isotopic data of physically separated components (chondrules, CAIs, variably magnetic size fractions) of the carbonaceous chondrites Allende and Murchison and bulk rock data of Allende, Ivuna, and Orgueil are reported to evaluate the origin of isotopic heterogeneity in these meteorites. Allende components show ε⁵³Cr and ε⁵⁴Cr from ?0.23 ± 0.07 to 0.37 ± 0.05 and from ?0.43 ± 0.08 to 3.7 ± 0.1, respectively. In components of Murchison, ε⁵³Cr and ε⁵⁴Cr vary from ?0.06 ± 0.08 to 0.5 ± 0.1 and from 0.7 ± 0.2 to 1.7 ± 0.1, respectively. The non‐systematic variations of ε⁵³Cr and ⁵⁵Mn/⁵²Cr in the components of Allende and Murchison were likely caused by small‐scale, alteration‐related redistribution of Mn >20 Ma after formation of the solar system. Chondrule fractions show the lowest ⁵⁵Mn/⁵²Cr and ε⁵⁴Cr values of all components, consistent with evaporation of Mn and ε⁵⁴Cr‐rich carrier phases from chondrule precursors. Components other than the chondrules show higher Mn/Cr and ε⁵⁴Cr, suggestive of chemical and isotopic complementarity between chondrules and matrix‐rich fractions. Bulk rock compositions calculated based on weighted compositions of components agree with measured Cr isotope data of bulk rocks, in spite of the Cr isotopic heterogeneity reported by the present and previous studies. This indicates that on a sampling scale comprising several hundred milligrams, these meteorites sampled isotopically and chemically homogeneous nebular reservoirs. The linear correlation of ⁵⁵Mn/⁵²Cr with ε⁵³Cr in bulk rocks likely was caused by variable fractionation of Mn/Cr, subsequent mixing of phases in nebular domains, and radiogenic ingrowth of ⁵³Cr.     

Spectral reflectance properties of carbonaceous chondrites: 2. CM chondrites

We have examined the spectral reflectance properties and available modal mineralogies of 39 CM carbonaceous chondrites to determine their range of spectral variability and to diagnose their spectral features. We have also reviewed the published literature on CM mineralogy and subclassification, surveyed the published spectral literature and added new measurements of CM chondrites and relevant end members and mineral mixtures, and measured 11 parameters and searched pair-wise for correlations between all quantities. CM spectra are characterized by overall slopes that can range from modestly blue-sloped to red-sloped, with brighter spectra being generally more red-sloped. Spectral slopes, as measured by the 2.4:0.56 μm and 2.4 μm:visible region peak reflectance ratios, range from 0.90 to 2.32, and 0.81 to 2.24, respectively, with values <1 indicating blue-sloped spectra. Matrix-enriched CM spectra can be even more blue-sloped than bulk samples, with ratios as low as 0.85. There is no apparent correlation between spectral slope and grain size for CM chondrite spectra - both fine-grained powders and chips can exhibit blue-sloped spectra. Maximum reflectance across the 0.3-2.5 μm interval ranges from 2.9% to 20.0%, and from 2.8% to 14.0% at 0.56 μm. Matrix-enriched CM spectra can be darker than bulk samples, with maximum reflectance as low as 2.1%. CM spectra exhibit nearly ubiquitous absorption bands near 0.7, 0.9, and 1.1 μm, with depths up to 12%, and, less commonly, absorption bands in other wavelength regions (e.g., 0.4-0.5, 0.65, 2.2 μm). The depths of the 0.7, 0.9, and 1.1 μm absorption features vary largely in tandem, suggesting a single cause, specifically serpentine-group phyllosilicates. The generally high Fe content, high phyllosilicate abundance relative to mafic silicates, and dual Fe valence state in CM phyllosilicates, all suggest that the phyllosilicates will exhibit strong absorption bands in the 0.7 μm region (due to Fe³⁺-Fe²⁺ charge transfers), and the 0.9-1.2 μm region (due to Fe²⁺ crystal field transitions), and generally dominate over mafic silicates. CM petrologic subtypes exhibit a positive correlation between degree of aqueous alteration and depth of the 0.7 μm absorption band. This is consistent with the decrease in fine-grained opaques that accompanies aqueous alteration. There is no consistent relationship between degree of aqueous alteration and evidence for a 0.65 μm region saponite-group phyllosilicate absorption band. Spectra of different subsamples of a single CM can show large variations in absolute reflectance and overall slope. This is probably due to petrologic variations that likely exist within a single CM chondrite, as duplicate spectra for a single subsample show much less spectral variability. When the full suite of available CM spectra is considered, few clear spectral-compositional trends emerge. This indicates that multiple compositional and physical factors affect absolute reflectance, absorption band depths, and absorption band wavelength positions. Asteroids with reflectance spectra that exhibit absorption features consistent with CM spectra (i.e., absorption bands near 0.7 and 0.9 μm) include members from multiple taxonomic groups. This suggests that on CM parent bodies, aqueous alteration resulted in the consistent production of serpentine-group phyllosilicates, however resulting absolute reflectances and spectral shapes seen in CM reflectance spectra are highly variable, accounting for the presence of phyllosilicate features in reflectance spectra of asteroids across diverse taxonomic groups.     

Experimental study and TEM characterization of dusty olivines in chondrites: Evidence for formation by in situ reduction

Abstract— An analytical transmission electron microscopy (ATEM) study was undertaken in order to better understand the formation conditions of dusty olivines (i.e., olivines containing abundant tiny inclusions of Fe‐Ni metal) in primitive meteorites. Dusty olivines from type I chondrules in the Bishunpur chondrite (LL3.1) and from synthetic samples obtained by reduction of San Carlos olivines were examined. In both natural and experimental samples, micron size metal blebs observed in the dusty region often show preferential alignments along crystallographic directions of the olivine grains, have low Ni contents (typically <2 wt%), and are frequently surrounded by a silica‐rich glass layer. These features suggest that dusty olivines are formed by a sub‐solidus reduction of initially fayalitic olivines according to the following reaction: Some volatilization of SiO_gas may account for the apparent excess of metal relative to silica‐rich glass observed in both experimental and natural samples. Comparison with experimentally produced dusty olivines suggests that time scales of the order of minutes usually inferred for chondrule formation are also adequate for the formation of dusty olivines. These observations are in agreement with the hypothesis that at least part of the metal phase in chondrites originated from reduction during chondrule formation.     

Formation of solar nebula and mass distribution in the planetary system

The formation of the solar nebula and the distribution of mass in its planetary system is studied. The underlying idea is that the protosun, fragmented out from an interstellar cloud as a result of cluster formation, gathered the planetary material and, hence, spin angular momentum by gravitational accretion during its orbital motion around the centre of the Galaxy. The study gives the initial angular momentum of the solar nebula nearly equal to the present value of the solar system.     

Formation of planetary systems by successive contractions of the solar nebula

The theory discussed in the present paper is a solar nebula-type theory which assumes the initial existence of a big disk-shaped gas cloud in rotational motion around the Sun. At the outer edge of the gas cloud there is a steady loss of angular momentum, which is mainly caused by the diffusion induced by turbulence and shock waves. This leads to the formation of a doughnutshaped gas ring at the edge of the cloud, outside of which there is plasma in a state of partial corotation. The gas ring is then slowly shifted towards the Sun, whereby the grains of solid matter within the gas cloud are also transported and collected within the gas torus. During the contraction process the following two situations arise: First, due to the small amount of friction, the angular momentum of the inner part of the ring rapidly exceeds that of the outer part. Second, the angle between the orbits of the inner and outer part of the gas ring increases gradually. When, during contraction, a certain distance is covered, the gas ring turns over, i.e. there is a sudden interchange of the inner and outer parts of the gas ring, where two adjacent rings of solid matter (jet streams) are formed. Immediately after the turn-over process the speed of contraction is at first drastically reduced, but then the gas ring is shifted once more towards the Sun. This process is then repeated periodically. The planets originate from the outer rings of solid matter, which contain much more matter than their adjacent inner rings. The inclination between the inner and outer rings is roughly 5°. In particular, Mercury, the Moon, Titan as well as Triton result from the innermost rings of matter. Having gone through the formation process, most of the planets acquire a rotating gas disk out of which the regular satellites are also created by the same periodic contraction process (hetegonic principle). This theory is the first that can explain all noteworthy facts about our planetary system and the satellite systems in a qualitative yet conclusive way.     

Aqueous alteration of kamacite in CM chondrites

Abstract– The study of aqueous alteration of kamacite in CM chondrites provides insight on the conditions, products, and relative timing of aqueous alteration. We studied unaltered, partially altered, and fully altered kamacite grains from Murray, Murchison, Cold Bokkeveld, and Nogoya using optical microscopy, electron microprobe analysis, scanning electron microscopy, and Raman spectroscopy. From textual evidence and chemical analysis, we established three separate microchemical environments. 1) In a microchemical environment with a high S activity, kamacite alters to form tochilinite, P‐bearing sulfides, eskolaite, and schreibersite. Mass balance calculations show that 81% of the Fe in kamacite is removed from the alteration region, making it available for the formation of other minerals or Fe‐rich aureoles. The release of Fe can alter the mesostasis of type‐I chondrules forming cronstedtite. 2) In a microchemical environment with a high Si activity and a low S activity, kamacite alters to form cronstedtite with small accessory sulfide inclusions. 3) A microchemical environment with limited S and Si activity results in kamacite alteration forming magnetite. The resulting magnetite retains associated Ni that can distinguish it from precipitated magnetite. In addition, the accessory phases of pentlandite and apatite can be formed if S or Ca are present. Finally, we note that small tochilinite grains in the matrix lack typical Ni, P, and Co levels, suggesting that they did not form from kamacite but possibly by sulfidization of magnetite.     

Carbonates in CM chondrites: Complex formational histories and comparison to carbonates in CI chondrites

Abstract– CM chondrites are primitive solar‐system materials that have undergone high degrees of aqueous alteration, resulting in the formation of secondary minerals including carbonates. Two different carbonate minerals (calcite/aragonite and dolomite) together constitute 1.4–2.8 vol% of CM chondrites. In contrast, CI chondrites contain four different carbonate minerals: calcite/aragonite, dolomite, breunnerite, and siderite. CI chondrites have abundant dolomite, a mineral that seems to be absent in the most aqueously altered CM chondrites. In this study, carbonates in seven CM chondrites (Y‐791198, LaPaz Icefield 04796, Cold Bokkeveld, Nogoya, Queen Alexandra Range 93005, Allan Hills 83100, and Meteorite Hills 01070) were studied petrographically and by electron microprobe. The results indicate that carbonate formation in CM chondrites differs from that in CI chondrites and is more complex than previously recognized. Our studies of CM chondrites indicate that (1) carbonates formed on the parent asteroid in an aqueous environment that gradually changed in composition, (2) at some stage, Ca and Mg activities in the environment were high enough to form metastable dolomite, and (3) dolomites disappeared in the most aqueously altered CM chondrites.     

Contraction of the solar nebula

The concept of Roche limit is applied to the Laplacian theory of the origin of the solar system to study the contraction of a spherical gas cloud (solar nebula). In the process of contraction of the solar nebula, it is assumed that the phenomenon of supersonic turbulent convection described by Prentice (1978) is operative and brings about the halt at various stages of contraction. It is found that the radius of the contracting solar nebula follows Titius-Bode law R _p = Ra^p, where R is the radius of the present Sun and a = 1.442. We call a the Roche's constant. The consequences of the relation are also discussed. The aim, here, is an attempt to explain, on the basis of the concept of Roche limit, the distribution of planets in the solar system and try to understand the physics underlying it.     

The identification of early condensates from the solar nebula

Calcium-aluminum-rich chondrules which are highly deficient in alkalis were extracted from the carbonaceous chondrite Allende and yield a range of compositions with the lowest measured isotopic composition of $\text{(}{}^{87}\text{Sr}\text{/}{}^{86}\text{Sr}\text{)}{}_{\mathrm{<mtext>ALL</mtext>}}\text{= 0.69877±0.00002}$ and identify this material as the earliest known condensate from the solar nebula. Other chondrules suggest the possible presence of even more primitive Sr in this meteorite. This result also shows that some chondritic material formed very near the earliest part of the condensation sequence. Using alkali-deficient planetary objects (Moon, basaltic achondrites, Angra dos Reis, Allende), the Sr data indicate a time interval for condensation of 10 m.y. (from ALL to BABI) if condensation occurred in a solar Rb/Sr environment. A variety of alkali-rich olivine chondrules and CaAl-rich aggregates from Allende fail to determine an isochron and indicate that the element distribution in this meteorite was disturbed later than 3.6ae, possibly recently, in a cometary nucleus. This disturbance requires that the determination of initial ⁸⁷Sr/⁸⁶Sr be done on essentially Rb-free phases. Strontium data from equilibrated chondrites and from an iron meteorite establish an interval for metamorphism or differentiation in protoplanetary objects which followed the condensation process by ≈80 mm.y. The chronology for condensation and early planetary evolution obtained for Sr is in disagreement with the ¹²⁹I chronology but can be brought into agreement, if it is assumed that the high temperature iodine containing phases have not been affected by the metamorphic events determined by Sr.     

Kamacite sulfurization in the solar nebula

Abstract— The kinetics and mechanisms of kamacite sulfurization were studied experimentally at temperatures and H₂S/H₂ ratios relevant to the solar nebula. Pieces of the Canyon Diablo meteorite were heated at 558 K, 613 K, and 643 K in 50 parts per million by volume (ppmv) H₂S-H₂ gas mixtures for up to one month. Optical microscopy and x-ray diffraction analyses show that the morphology and crystal orientation of the resulting sulfide layers vary with both time and temperature. Electron microprobe analyses reveal three distinct phases in the reaction products: monosulfide solid solution (mss), (Fe, Ni, Co)_1-xS, pentlandite (Fe, Ni, Co)_9-xS₈, and a P-rich phase. The bulk composition of the remnant metal was not significantly changed by sulfurization. Kamacite sulfurization at 558 K followed parabolic kinetics for the entire duration of the experiments. Sulfide layers that formed at 613 K grew linearly with time, while those that formed at 643 K initially grew linearly with time then switched to parabolic kinetics upon reaching a critical thickness. The experimental results suggest that a variety of thermodynamic, kinetic, and physical processes control the final composition and morphology of the sulfide layers. We combine morphological, x-ray diffraction, electron microprobe, and kinetic data to produce a comprehensive model of sulfide formation in the solar nebula. Then, we present a set of criteria to assist in the identification of solar nebula condensate sulfides in primitive meteorites.     

Grain motions in the solar nebula

Isotopic analyses of meteorites suggest the possibility that some interaction between supernova ejecta and grains occurred in the solar nebula. In particular, the dynamics of grain motions in the solar nebula can explain the observed mixing of nucleosynthetic components. The effect of a shock wave on the motions of grains are examined. A steady-state, plane shock propagating into a uniform region of gas and dust grains is followed by a zone of gas/grain slip, in which the grains are accelerated by drag forces from the pre-shock to the post-shock gas velocity, i.e. reducing the relative velocity between the gas and grains to zero. On the basis of these calculations, it is estimated that if grains carried the isotopic anomalies investigated by Lee, Papanastassoiu, and Wasserburg (1978), then those grains could be no bigger than 2×10^–4 cm in size. A scenario is suggested in which the sluggishness of grains provides a natural way to concentrate and mix the nucleosynthetic components carried by grains in the ejecta and in the solar nebula.Paper presented at the Conference on Protostars and Planets, held at the Planetary Science Institute, University of Arizona, Tucson, Arizona, between January 3 and 7, 1978.     

The effects of the tidal force on shear instabilities in the dust layer of the solar nebula

The linear analysis of the instability due to vertical shear in the dust layer of the solar nebula is performed. The following assumptions are adopted throughout this paper: (1) The self-gravity of the dust layer is neglected. (2) One fluid model is adopted, where the dust aggregates have the same velocity with the gas due to strong coupling by the drag force. (3) The gas is incompressible. The calculations with both the Coriolis and the tidal forces show that the tidal force has a stabilizing effect. The tidal force causes the radial shear in the disk. This radial shear changes the wave number of the mode which is at first unstable, and the mode is eventually stabilized. Thus the behavior of the mode is divided into two stages: (1) the first growth of the unstable mode which is similar to the results without the tidal force, and (2) the subsequent stabilization due to an increase of the wave number by the radial shear. If the midplane dust/gas density ratio is smaller than 2, the stabilization occurs before the unstable mode grows largely. On the other hand, the mode grows faster by one hundred orders of magnitude, if this ratio is larger than 20. Because the critical density of the gravitational instability is a few hundreds times as large as the gas density, the hydrodynamic instability investigated in this paper grows largely before the onset of the gravitational instability. It is expected that the hydrodynamic instability develops turbulence in the dust layer and the dust aggregates are stirred up to prevent from settling further. The formation of planetesimals through the gravitational instabilities is difficult to occur as long as the dust/gas surface density ratio is equal to that for the solar abundance. On the other hand, the shear instability is suppressed and the planetesimal formation through the gravitational instability may occur, if dust/gas surface density ratio is hundreds times as large as that for the solar abundance.     

Accumulation of planetesimals in the solar nebula

Characteristic time scales relevant to the accumulation of planetesimals in a gaseous nebula are examined and the accumulation toward the planets is simulated by numerically solving a growth equation for a mass distribution function. The eccentricity and inclination of planetesimals are assumed to be determined by a balance between excitation due to mutual gravitational scattering and dissipation due to gas drag. Two kinds of mass motion in the radial direction, i.e., diffusion due to mutual scattering and inward flow due to gas drag, are both taken into account. The diffusion is shown to be effective in later stages with a result of accelerating the accumulation. As to the coalescent collision cross section, the usual formula for a binary encounter in a free space is used but the effect of tidal disruption which increases substantially the cross section is taken into account. Numerical results show that the gravitational enhancement factor (i.e., the so-called “Safronov number”), contained in the cross section formula, always takes a value of the order of unity but the accumulation proceeds relatively rapidly owing to the effects of radial diffusion and tidal disruption. That is, a proto-Earth, a proto-Jupiter, and a proto-Saturn with masses of 1×10²⁷ g are formed in 5×10⁶, 1×10⁷, and 1.6×10⁸ years, respectively. Also, a tentative numerical computation for the Neptune formation shows that a proto-Neptune with the same mass requires a long accumulation time, 4.6×10⁹ years. Finally, the other effects which are expected to reduce the above growth times further are discussed.     

Multiple precursors of secondary mineralogical assemblages in CM chondrites

We report a petrographic and mineralogical survey of tochilinite/cronstedtite intergrowths (TCIs) in Paris, a new CM chondrite considered to be the least altered CM identified to date. Our results indicate that type‐I TCIs consist of compact tochilinite/cronstedtite rims surrounding Fe‐Ni metal beads, thus confirming kamacite as the precursor of type‐I TCIs. In contrast, type‐II TCIs are characterized by complex compositional zoning composed of three different Fe‐bearing secondary minerals: from the outside inwards, tochilinite, cronstedtite, and amakinite. Type‐II TCIs present well‐developed faces that allow a detailed morphological analysis to be performed in order to identify the precursors. The results demonstrate that type‐II TCIs formed by pseudomorphism of the anhydrous silicates, olivine, and pyroxene. Hence, there is no apparent genetic relationship between type‐I and type‐II TCIs. In addition, the complex chemical zoning observed within type‐II TCIs suggests that the alteration conditions evolved dramatically over time. At least three stages of alteration can be proposed, characterized by alteration fluids with varying compositions (1) Fe‐ and S‐rich fluids; (2) S‐poor and Fe‐ and Si‐rich fluids; and (3) S‐ and Si‐poor, Fe‐rich fluids. The presence of unaltered silicates in close association with euhedral type‐II TCIs suggests the existence of microenvironments during the first alteration stages of CM chondrites. In addition, the absence of Mg‐bearing secondary minerals in Paris TCIs suggests that the Mg content increases during the course of alteration.     

Settling and growth of dust particles in a laminar phase of a low-mass solar nebula

It is considered that some vertical convection as well as possible turbulence in an early phase of solar nebula soon terminates owing to diminution of the temperature dependence of dust opacity due to rapid growth of dust particles. We reexamine settling and growth of dust particles in the subsequent laminar phase of the solar nebula in detail, treating a dust layer as a two-component fluid composed of the dust and the gas. We obtain analytic expressions for the settling path, the growing size, and the settling time. The settling process is divided into two phases, i.e., an early gas-dominant phase and a later dust-dominant phase. So far, only the former phase, where the particle path finally turns from vertical to radial, has been investigated. In the latter phase, dust particles drag the gas, rather than the gas does dust particles. Consequently, the particle path turns from radial to vertical. Dust particles grow most appreciably and rapidly in a radially sweeping phase. The final radii of dust particles at the onset of gravitational instability of the dust layer are 20, 5.9, and 0.60 cm in the Earth's, Jupiter's, and Neptune's zones, respectively. These values are much smaller than those obtained previously by S.J. Weidenschilling [1980, Icarus44, 172–189] and Y. Nakagawa et al. [1981, Icarus45, 517–528]. The total settling times are 1.9 × 10³, 4.6 × 10³, and 2.8 × 10⁴ years in the above-mentioned three zones, respectively. These are somewhat smaller than those obtained by the previous studies. Most of the settling time is spent in the early vertically settling phase.