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采样层位的确定、样品粗加工粒级和指示元素选择是沟系土壤地球化学测量试验研究的重要内容。本次研究选取灰岩、玄武岩、砂页岩风化土壤的表土层、淀积层、母质层样品为研究对象,样品常温晾干后依次过20目、40目、60目、80目沈阳套筛进行粗加工,分析样品元素含量。通过研究土壤机械粒级组成和元素在不同层位、不同粒级土壤中的含量特征,确定了本区进行土壤地球化学测量时采样层位为土壤淀积层上部,样品粗加工粒级为-20~+40目粒级,指示元素以Au、Sb、As、Cu为主。试验结果确保在贵州普安—晴隆地区运用沟系土壤地球化学测量所圈定的地球化学异常成果真实、有效。 相似文献
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在黑龙江省二道坎森林–沼泽浅覆盖区,采用B、C层不同样品粒级对照分析方法,开展了土壤、岩屑测量采样方法技术剖面试验研究,选择采取的−5~+20目、−20~+60目和−60目3种粒级试验样品,并对比不同粒级样品中各元素在地球化学特征、元素组合以及异常圈定等方面存在的差异。结果表明,不同粒级样品所圈定的成矿元素地球化学异常都具备Ag-Pb-Zn-Mn多元素异常组合的特征,且异常分布范围与深部矿体较为一致,元素浓集中心与深部矿体空间位置吻合较好。具体表现为岩屑、土壤测量皆可以有效地指示银铅锌矿体,可作为该区寻找银铅锌矿的有效手段。而C层−20~+60目粒级岩屑测量效果更好,表现在元素含量更高,异常强度更强,元素组合指示意义更明显,定位矿体更精准,可以强化土壤微弱异常,有利于发现和识别弱的矿化信息。因此,在研究区内开展地球化学测量适宜采用−20~+60目粒级岩屑采样方法,其可为森林–沼泽覆盖区如二道坎地区以及多宝山矿集区开展1∶1万化探详查和找矿预测提供了技术依据。 相似文献
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为了在成矿区带和矿集区找矿工作中有所突破,开展工作区内水系沉积物和土壤剖面地球化学的试验是一项不容忽视的工作。江西九岭钨铜多金属矿集区水系沉积物、典型土壤剖面地球化学试验表明:①在赣北九岭地区寻找岩浆热液型钨、铜多金属矿床的最佳指示元素是W、Sn、Cu、Mo、Bi、Ag、Cd、F;②地球化学普查(1∶25万-1∶5万)水系沉积物的采样位置应以一级水系的采样为主,辅以少量二级水系,采样粒度以10~60目的水系沉积物为宜;③地球化学详查(1∶5000-1∶10000)土壤地球化学测量采样层位为残积土壤B层,采样深度为20~40cm,采样粒度20~40目,或小于40目均可显示出较好的异常。 相似文献
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为了在成矿区带和矿集区找矿工作中有所突破,开展工作区内水系沉积物和土壤剖面地球化学的试验是一项不容忽视的工作。江西九岭钨铜多金属矿集区水系沉积物、典型土壤剖面地球化学试验表明:①在赣北九岭地区寻找岩浆热液型钨、铜多金属矿床的最佳指示元素是W、Sn、Cu、Mo、Bi、Ag、Cd、F;②地球化学普查(1∶25万—1∶5万)水系沉积物的采样位置应以一级水系的采样为主,辅以少量二级水系,采样粒度以10~60目的水系沉积物为宜;③地球化学详查(1∶5000—1∶10000)土壤地球化学测量采样层位为残积土壤B层,采样深度为20~40cm,采样粒度20~40目,或小于40目均可显示出较好的异常。 相似文献
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为了在成矿区带和矿集区找矿工作中有所突破,开展工作区内水系沉积物和土壤剖面地球化学的试验是一项不容忽视的工作。江西九岭钨铜多金属矿集区水系沉积物、典型土壤剖面地球化学试验表明:①在赣北九岭地区寻找岩浆热液型钨、铜多金属矿床的最佳指示元素是W、Sn、Cu、Mo、Bi、Ag、Cd、F;②地球化学普查(1∶25万—1∶5万)水系沉积物的采样位置应以一级水系的采样为主,辅以少量二级水系,采样粒度以10~60目的水系沉积物为宜;③地球化学详查(1∶5000—1∶10000)土壤地球化学测量采样层位为残积土壤B层,采样深度为20~40cm,采样粒度20~40目,或小于40目均可显示出较好的异常。 相似文献
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黑龙江逊克霍吉河地区地球化学找矿方法 总被引:4,自引:1,他引:3
水系沉积物和土壤采样分析研究表明, 在研究区地球化学找矿工作中可采用两者相结合的采样方法。水系沉积物样品过筛粒级为- 10~ + 60目, 其中- 10~ + 20目和- 20~ + 40目粒级样品比较发育, 含量较高, - 40~ + 60目粒级样品含量最低, - 60目样品含量上下波动较大。样品中Au、Bi 和Sn含量变化大, 变异系数在各粒级中分别为0.41~1.41、1.84~2.49和1.40~1.50, 其他元素在各粒级中变异系数为0.31~0.94, 含量变化较小。土壤测量发现, 在B层发育部位采集B层中部土壤, 在B层不发育地段采集B +C层土壤样品, 能较好反映异常。元素含量从浅到深有增加趋势, 异常强度有所变化, 但对发现异常没有影响。 相似文献
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加纳国雅卡锰金矿床位于著名的阿散蒂金矿带上。在该成矿带进行土壤测量采样深度、样品粒级试验以及方法技术的适应性和有效性研究,可为下一步开展大面积土壤地球化学测量提供技术依据,从而圈定可靠土壤地球化学异常。本文采用的工作方法为土壤垂向剖面法,选择有代表性的地段进行试验研究,结果显示在已知矿上方获得了明显的土壤地球化学异常。通过实验研究,选取土壤测量采样深度60~80 cm,截取样品粒级-4~+20目,获得了可靠、明显的土壤地球化学异常。研究证明该方法具有显著的地球化学找矿效果。 相似文献
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矿区及外围土壤地球化学测量采样深度与粒度方法试验——以江西省九江市城门山铜矿为例 总被引:2,自引:1,他引:1
土壤地球化学测量是在重要成矿带开展深部及外围地球化学找矿的重要方法之一。为了获取无人为活动扰动的自然的、清晰的成矿和成晕信息,又要在一定程度上控制工作量,开展矿区及外围土壤剖面的深度与粒度采集试验是必须的。对江西九江城门山铜矿湿润低山丘陵景观条件下土壤剖面的深度与粒度的采样试验研究表明:①土壤采样的深度以40~50cm为宜;②土壤各层Cu元素没有明显的富集粒级,为此野外仅采集-20目(<0.84mm)的样品即可满足工作要求。 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10 μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提出了具体测定要求。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引:1,自引:0,他引:1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献