Pan-African adakitic rocks of the north Arabian–Nubian Shield: petrological and geochemical constraints on the evolution of the Dokhan volcanics in the north Eastern Desert of Egypt

The Precambrian basement of Egypt is part of the Red Sea Mountains and represents the north-western part of the Arabian–Nubian Shield (ANS). Five volcanic sections are exposed in the Egyptian basement complex, namely El Kharaza, Monqul, Abu Had, Mellaha and Abu Marwa. They are located in the north Eastern Desert (ED) of Egypt and were selected for petrological and geochemical studies as they represent the Dokhan volcanics. The volcanics divide into two main pulses, and each pulse was frequently accompanied by deposition of immature molasse type sediments, which represent a thick sequence of the Hammamat group in the north ED. Compositionally, the rocks form a continuum from basaltic andesite, andesite, dacite (lower succession) to rhyodacite and rhyolite (upper succession), with no apparent compositional gaps. These high-K calc-alkaline rocks have strong affinities to subduction-related rocks with enriched LILEs (Rb, Ba, K, Th, Ce) relative to high field strength elements (Nb, Zr, P, Ti) and negative Nb anomalies relative to NMORB. The lower succession displays geochemical characteristics of adakitic rocks with SiO₂ >53 wt%, Al₂O₃ >15 wt%, MgO >2.5 wt%, Mg# >49, Sr >650 ppm, Y <17 ppm, Yb <2 ppm, Ni >25 ppm, Cr >50 ppm and Sr/Y >42.4. They also have low Nb, Rb and Zr compared to the coexisting calc-alkaline rhyodacites and rhyolites. The highly fractionated rhyolitic rocks have strong negative Eu anomalies and possess the geochemical characteristics of A-type suites. Trace element geochemical signatures indicate a magma source consistent with post-collisional suites that retain destructive plate signatures associated with subduction zones. The adakitic rocks in the northern ANS are generated through partial melting of delaminated mafic lower crust interacting with overlying mantle-derived magma. The Dokhan volcanics were likely generated by a combination of processes, including partial melting, crystal fractionation and assimilation.     

Lu–Hf and O isotopic compositions on single zircons from the North Eastern Desert of Egypt,Arabian–Nubian Shield: Implications for crustal evolution

Neoproterozoic juvenile crust is exposed in the Eastern Desert of Egypt, between the Nile and the Red Sea, forming the basement to Cambrian and younger sedimentary strata in the northernmost part of the Arabian–Nubian Shield (ANS). In order to reveal how the crust of this vast region was formed, four examples of widespread Neoproterozoic (653–595 Ma) calc-alkaline and alkaline intrusive rocks in the northwestern most exposures, in the NE Desert of Egypt (NED) were studied. Single zircon Hf–O isotopic compositions of these intrusives were used to characterize the Neoproterozoic syn- and post-collisional granitoids in the NED. The ~ 653 Ma Um Taghir syn-tectonic granodiorite (I-type) displays isotopic characteristics of a depleted mantle source, such as high εHf(t) (+ 9.1 to + 11.2) and mantle δ¹⁸O (mean = + 5.12‰). In contrast, the ca. ~ 600 Ma post-collision A-type granites (Al-Missikat, Abu Harba, and Gattar) show slightly higher δ¹⁸O values (+ 5.15 to 6.70) and slightly lower εHf(t) values (+ 6.3 to + 10.6, mean = + 8.6). We interpret these isotopic data to reflect melting of a juvenile Neoproterozoic mantle source that assimilated slightly older Neoproterozoic crustal material during magma mixing. The involvement of crustal component is also supported by Hf-crustal model ages (0.67–0.96 Ga) and by the occurrence of xenocrystic zircons with U–Pb ages older than the crystallization ages, indicating melting of predominantly Late Neoproterozoic crustal protoliths.     

Late Neoproterozoic alkaline magmatism in the Arabian–Nubian Shield: the postcollisional A-type granite of Sahara–Umm Adawi pluton, Sinai, Egypt

The Sahara–Umm Adawi pluton is a Late Neoproterozoic postcollisional A-type granitoid pluton in Sinai segment of the Arabian–Nubian Shield that was emplaced within voluminous calc-alkaline I-type granite host rocks during the waning stages of the Pan-African orogeny and termination of a tectonomagmatic compressive cycle. The western part of the pluton is downthrown by clysmic faults and buried beneath the Suez rift valley sedimentary fill, while the exposed part is dissected by later Tertiary basaltic dykes and crosscut along with its host rocks by a series of NNE-trending faults. This A-type granite pluton is made up wholly of hypersolvus alkali feldspar granite and is composed of perthite, quartz, alkali amphibole, plagioclase, Fe-rich red biotite, accessory zircon, apatite, and allanite. The pluton rocks are highly evolved ferroan, alkaline, and peralkaline to mildly peraluminous A-type granites, displaying the typical geochemical characteristics of A-type granites with high SiO₂, Na₂O + K₂O, FeO*/MgO, Ga/Al, Zr, Nb, Ga, Y, Ce, and rare earth elements (REE) and low CaO, MgO, Ba, and Sr. Their trace and REE characteristics along with the use of various discrimination schemes revealed their correspondence to magmas derived from crustal sources that has gone through a continent–continent collision (postorogenic or postcollisional), with minor contribution from mantle source similar to ocean island basalt. The assumption of crustal source derivation and postcollisional setting is substantiated by highly evolved nature of this pluton and the absence of any syenitic or more primitive coeval mafic rocks in association with it. The slight mantle signature in the source material of these A-type granites is owed to the juvenile Pan-African Arabian–Nubian Shield (ANS) crust (I-type calc-alkaline) which was acted as a source by partial melting of its rocks and which itself of presumably large mantle source. The extremely high Rb/Sr ratios combined with the obvious Sr, Ba, P, Ti, and Eu depletions clearly indicate that these A-type granites were highly evolved and require advanced fractional crystallization in upper crustal conditions. Crystallization temperature values inferred average around 929°C which is in consistency with the presumably high temperatures of A-type magmas, whereas the estimated depth of emplacement ranges between 20 and 30 km (upper-middle crustal levels within the 40 km relatively thick ANS crust). The geochronologically preceding Pan-African calc-alkaline I-type continental arc granitoids (the Egyptian old and younger granites) associated with these rocks are thought to be the crustal source of f this A-type granite pluton and others in the Arabian–Nubian Shield by partial melting caused by crustal thickening due to continental collision at termination of the compressive orogeny in the Arabian–Nubian Shield.     

Neoproterozoic arc–back-arc system in the Central Eastern Desert of Egypt: Evidence from supra-subduction zone ophiolites

Ophiolites are widely distributed in the Central Eastern Desert (CED) of Egypt, occurring as clusters in the northern (NCEDO) and southern (SCEDO) segments. Mineralogical and geochemical data on the volcanic sections of Wizer (WZO) and Abu Meriewa (AMO) ophiolites as representatives of the NCEDO and SCEDO, respectively, are presented.The WZO volcanic sequence comprises massive metavolcanics of MORB-like compositions intruded by minor boninitic dykes and thrust over island-arc metavolcanic blocks in the mélange matrix. Such transitional MORB-IAT-boninitic magmatic affinities for the WZO metavolcanics suggest that they most likely formed in a protoarc–forearc setting. Chemical compositions of primary clinopyroxene and Cr-spinel relicts from the WZO volcanic section further confirm this interpretation. The compositional variability in the WZO volcanic sequence is comparable with the associated mantle rocks that vary from slightly depleted harzburgites to highly depleted harzburgites containing small dunite bodies, which are residues after MORB, IAT and boninite melt formation, respectively. Source characteristics of the different lava groups from the WZO indicate generation via partial melting of a MORB source which was progressively depleted by melt extraction and variably enriched by subduction zone fluids. MORB-like magma may have been derived from ~ 20% partial melting of an undepleted lherzolite source, leaving slightly depleted harzburgite as a residuum. The generation of island-arc magma can be accounted for by partial melting (~ 15%) of the latter harzburgitic mantle source, whereas boninites may have been derived from partial melting (~ 20%) of a more refractory mantle source previously depleted by melt extraction of MORB and IAT melts, leaving ultra-refractory dunite bodies as residuum.The AMO volcanic unit occurs as highly deformed pillowed metavolcanic rocks in a mélange matrix. They can be categorized geochemically into LREE-depleted (La/Yb_CN = 0.41–0.50) and LREE-enriched (La/Yb_CN = 4.7–4.9) lava types that show an island arc to MORB geochemical signature, respectively, signifying a back-arc basin setting. This is consistent, as well, with their mantle section. Source characteristics indicate depleted to slightly enriched mantle sources with overall slight subduction zone geochemical affinities as compared to the WZO.Generally, CED ophiolites show supra-subduction zone geochemical signature with prevalent island arc tholeiitic and minor boninitic affinities in the NCEDO and MORB/island-arc association in the SCEDO. Such differences in geochemical characteristics of the NCEDO and SCEDO, along with the abundance of mature island arc metavolcanics which are close in age (~ 750 Ma) to the ophiolitic rocks, general enrichment in HFSE of ophiolites from north to south, and lack of a crustal break and major shear zones, is best explained by a geotectonic model whereby the CED represents an arc–back-arc system above a southeast-dipping subduction zone.     

Carbonate alteration of ophiolitic rocks in the Arabian–Nubian Shield of Egypt: sources and compositions of the carbonating fluid and implications for the formation of Au deposits

Ultramafic portions of ophiolitic fragments in the Arabian–Nubian Shield (ANS) show pervasive carbonate alteration forming various degrees of carbonated serpentinites and listvenitic rocks. Notwithstanding the extent of the alteration, little is known about the processes that caused it, the source of the CO₂ or the conditions of alteration. This study investigates the mineralogy, stable (O, C) and radiogenic (Sr) isotope composition, and geochemistry of suites of variably carbonate altered ultramafics from the Meatiq area of the Central Eastern Desert (CED) of Egypt. The samples investigated include least-altered lizardite (Lz) serpentinites, antigorite (Atg) serpentinites and listvenitic rocks with associated carbonate and quartz veins. The C, O and Sr isotopes of the vein samples cluster between ?8.1‰ and ?6.8‰ for δ¹³C, +6.4‰ and +10.5‰ for δ¹⁸O, and ⁸⁷Sr/⁸⁶Sr of 0.7028–0.70344, and plot within the depleted mantle compositional field. The serpentinites isotopic compositions plot on a mixing trend between the depleted-mantle and sedimentary carbonate fields. The carbonate veins contain abundant carbonic (CO₂±CH₄±N₂) and aqueous-carbonic (H₂O-NaCl-CO₂±CH₄±N₂) low salinity fluid, with trapping conditions of 270–300°C and 0.7–1.1 kbar. The serpentinites are enriched in Au, As, S and other fluid-mobile elements relative to primitive and depleted mantle. The extensively carbonated Atg-serpentinites contain significantly lower concentrations of these elements than the Lz-serpentinites suggesting that they were depleted during carbonate alteration. Fluid inclusion and stable isotope compositions of Au deposits in the CED are similar to those from the carbonate veins investigated in the study and we suggest that carbonation of ANS ophiolitic rocks due to influx of mantle-derived CO₂-bearing fluids caused break down of Au-bearing minerals such as pentlandite, releasing Au and S to the hydrothermal fluids that later formed the Au-deposits. This is the first time that gold has been observed to be remobilized from rocks during the lizardite–antigorite transition.     

Tectonostratigraphy and depositional history of the Neoproterozoic volcano-sedimentary sequences in Kid area,southeastern Sinai,Egypt: Implications for intra-arc to foreland basin in the northern Arabian–Nubian Shield

This paper presents a stratigraphic and sedimentary study of Neoproterozoic successions of the South Sinai, at the northernmost segment of the Arabian–Nubian Shield (ANS), including the Kid complex. This complex is composed predominantly of thick volcano-sedimentary successions representing different depositional and tectonic environments, followed by four deformational phases including folding and brittle faults (D₁–D₄). The whole Kid area is divisible from north to south into the lower, middle, and upper rock sequences. The higher metamorphic grade and extensive deformational styles of the lower sequence distinguishes them from the middle and upper sequences. Principal lithofacies in the lower sequence include thrust-imbricated tectonic slice of metasediments and metavolcanics, whereas the middle and upper sequences are made up of clastic sediments, intermediate-felsic lavas, volcaniclastics, and dike swarms. Two distinct Paleo- depositional environments are observed: deep-marine and alluvial fan regime. The former occurred mainly during the lower sequence, whereas the latter developed during the other two sequences. These alternations of depositional conditions in the volcano-sedimentary deposits suggest that the Kid area may have formed under a transitional climate regime fluctuating gradually from warm and dry to warm and humid conditions.Geochemical and petrographical data, in conjunction with field relationships, suggest that the investigated volcano-sedimentary rocks were built from detritus derived from a wide range of sources, ranging from Paleoproterozoic to Neoproterozoic continental crust. Deposition within the ancient Kid basin reflects a complete basin cycle from rifting and passive margin development, to intra-arc and foreland basin development and, finally, basin closure. The early phase of basin evolution is similar to various basins in the Taupo volcanics, whereas the later phases are similar to the Cordilleran-type foreland basin. The progressive change in lithofacies from marine intra-arc basin to continental molasses foreland basin and from compression to extension setting respectively, imply that the source area became peneplained, where the Kid basin became stabilized as sedimentation progressed following uplift. The scenario proposed of the study area supports the role of volcanic and tectonic events in architecting the facies and stratigraphic development.     

Tonian–Ediacaran Tectonometamorphic History of the Sa’al Complex, Sinai (Egypt): Implications for the Tectonostratigraphic Framework of the Northern Arabian–Nubian Shield

The Sa''al Metamorphic Complex (SMC; southern Sinai) encompasses the oldest arc rocks in the Arabian–Nubian Shield, comprising two non-consanguineous metavolcanic successions (the Agramiya Group and the Post-Ra''ayan Formation) separated by the metasediments of the Ra''ayan Formation. It experienced three distinct deformational events (D1–D3) and two low-medium grade regional metamorphic events (M1–M2). The Agramiya Group and the Ra''ayan Formation experienced all tectonometamorphic events (D1–D3 and M1–M2), whereas the Post-Ra''ayan volcanic rocks were only affected by the D3 and M2 events. D1 is an extensional event and is connected to the late Rodinia break-up (~Tonian; 900–870 Ma). The M1 metamorphism variably affected the older Agramiya Group, the rhyolitic tuffs experiencing lower to upper greenschist facies conditions and the basic and intermediate volcanic rocks undergoing amphibolite facies metamorphism. The Ra''ayan Formation metasediments experienced upper greenschist to amphibolite facies metamorphism. The upper greenschist facies M2 affected the youngest Post-Ra''ayan volcanic rocks and other stratigraphic successions. The compressive D2 and D3 events were coeval with the accretion of dismembered terranes in the assembly of Gondwana. D2 can be linked to the Tonian–Cryogenian arc-arc assembly (~880–760 Ma; in Elat and Sinai), whereas D3 and the accompanying M2 is constrained to 622–600 Ma (Ediacaran).     

Three successive Proterozoic island arcs in the Northern Arabian–Nubian Shield: Evidence from SIMS U–Pb dating of zircon

Four isolated metamorphic complexes located within post-collisional granitoids occupying up to 70% of the total area, were distinguished in Sinai (Egypt) and Elat area (southern Israel), the northernmost part of the Arabian–Nubian Shield. The metamorphic rocks include metasediments, felsic and mafic metavolcanic rocks intruded by granitic, dioritic, and gabbroic plutons, all subjected to penetrative deformation.We present new SIMS U–Pb dating of zircons from 13 rock units comprising metasediments, volcanic rocks, gneisses and plutons from three metamorphic complexes (Sa'al, Feiran–Solaf, and Kid). In addition we present a SIMS U–Pb titanite age of a granitic gneiss previously dated using zircon. On the basis of the new and published U–Pb data, three successive Meso- to Neoproterozoic island arcs formed during a period of ca. 500 My are recognized. The Sa'al arc (represented by the oldest arc rocks in the ANS) evolved from 1.03 to 0.93 Ga (100 My); the Feiran–Elat arc developed from ca. 870 to 740 Ma (130 My), and the Kid arc formed from ca. 640 to 620 Ma (20 My). Evidence for an older, ca. 1.1 Ga, pre-Sa'al island arc was established from the zircon xenocryst population, though no exposures of rocks of this age were found. In the Sa'al and Kid arcs both volcanic and sedimentary rocks are preserved, whereas in the Elat–Feiran arc volcanic rocks are missing. We suggest that at ~ 700 Ma the Elat−Feiran arc was subjected to rifting that resulted in separating of the Qenaia block and its movement to the SE.     

Composition, age, and origin of the ~620?Ma Humr Akarim and Humrat Mukbid A-type granites: no evidence for pre-Neoproterozoic basement in the Eastern Desert, Egypt

The Humr Akarim and Humrat Mukbid plutons, in the central Eastern Desert of Egypt, are late Neoproterozoic post-collisional alkaline A-type granites. Humr Akarim and Humrat Mukbid plutonic rocks consist of subsolvus alkali granites and a subordinate roof facies of albite granite, which hosts greisen and Sn–Mo-mineralized quartz veins; textural and field evidence strongly suggest the presence of late magmatic F-rich fluids. The granites are Si-alkali rich, Mg–Ca–Ti poor with high Rb/Sr (20–123), and low K/Rb (27–65). They are enriched in high field strength elements (e.g., Nb, Ta, Zr, Y, U, Th) and heavy rare earth elements (La _n /Yb _n ?=?0.27–0.95) and exhibit significant tetrad effects in REE patterns. These geochemical attributes indicate that granite trace element distribution was controlled by crystal fractionation as well as interaction with fluorine-rich magmatic fluids. U–Pb SHRIMP zircon dating indicates an age of ~630–620?Ma but with abundant evidence that zircons were affected by late corrosive fluids (e.g., discordance, high common Pb). εNd at 620?Ma ranges from +3.4 to +6.8 (mean?=?+5.0) for Humr Akarim granitic rocks and from +4.8 to +7.5 (mean?=?+5.8) for Humrat Mukbid granitic rocks. Some slightly older zircons (~740?Ma, 703?Ma) may have been inherited from older granites in the region. Our U–Pb zircon data and Nd isotope results indicate a juvenile magma source of Neoproterozoic age like that responsible for forming most other ANS crust and refute previous conclusions that pre-Neoproterozoic continental crust was involved in the generation of the studied granites.     

Neoproterozoic SHRIMP U–Pb zircon ages of silica-rich Dokhan Volcanics in the North Eastern Desert,Egypt

Chronology of Neoproterozoic volcanosedimentary successions remains controversial for many regions of the Arabian–Nubian Shield, including the Dokhan Volcanics of NE Egypt. New U–Pb zircon SHRIMP ages have been obtained for 10 silica-rich ignimbrites and two subvolcanic dacitic bodies, mapped as Dokhan Volcanics, from the North Eastern Desert of Egypt. Crystallization ages range between 592 ± 5 and 630 ± 6 Ma (Early Ediacaran). Apparently, the late consolidation of the Arabian–Nubian Shield was accompanied by the evolution of isolated volcanic centres and basin systems which developed during a period of approx. 40 Ma, independently in space and time and probably under changing tectonic regimes. The obtained age data together with other previously published reliable ages for Dokhan Volcanics suggest two main pulses of volcanic activity: 630–623 Ma and 618–592 Ma. Five samples contain inherited zircons, with ages of 669, 715–746, 847 and 1530 Ma, supporting models that North Eastern Desert crust is mainly juvenile Neoproterozoic crust.     

Age constraints on the formation and emplacement of Neoproterozoic ophiolites along the Allaqi–Heiani Suture,South Eastern Desert of Egypt

Ophiolites are key components of the Neoproterozoic Arabian–Nubian Shield (ANS). Understanding when they formed and were emplaced is crucial for understanding the evolution of the ANS because their ages tell when seafloor spreading and terrane accretion occurred. The Yanbu–Onib–Sol Hamed–Gerf–Allaqi–Heiani (YOSHGAH) suture and ophiolite belt can be traced ∼ 600 km across the Nubian and Arabian shields. We report five new SHRIMP U–Pb zircon ages from igneous rocks along the Allaqi segment of the YOSHGAH suture in southernmost Egypt and use these data in conjunction with other age constraints to evaluate YOSHGAH suture evolution. Ophiolitic layered gabbro gave a concordia age of 730 ± 6 Ma, and a metadacite from overlying arc-type metavolcanic rocks yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 733 ± 7 Ma, indicating ophiolite formation at ∼ 730 Ma. Ophiolite emplacement is also constrained by intrusive bodies: a gabbro yielded a concordia age of 697 ± 5 Ma, and a quartz-diorite yielded a concordia age of 709 ± 4 Ma. Cessation of deformation is constrained by syn- to post-tectonic granite with a concordia age of 629 ± 5 Ma. These new data, combined with published zircon ages for ophiolites and stitching plutons from the YOSHGAH suture zone, suggest a 2-stage evolution for the YOSHGAH ophiolite belt (∼ 810–780 Ma and ∼ 730–750 Ma) and indicate that accretion between the Gabgaba–Gebeit–Hijaz terranes to the south and the SE Desert–Midyan terranes to the north occurred as early as 730 Ma and no later than 709 ± 4 Ma.     

The Wadi Zaghra metasediments of Sinai,Egypt: new constraints on the late Cryogenian–Ediacaran tectonic evolution of the northernmost Arabian–Nubian Shield

ABSTRACT

The La Tinta mélange is a small but singular ultramafic mélange sheet that crops out in eastern Cuba. It is composed of dolerite-derived amphibolite blocks embedded in a serpentinite matrix. The amphibolite blocks have mid-ocean ridge basalt (MORB)-like composition showing little if any imprint of subduction zone component, similar to most forearc and MOR basalts worldwide. Relict Cr-spinel and olivine mineral chemistry of the serpentinized ultramafic matrix suggest a forearc position for these rocks. These characteristics, together with a hornblende ⁴⁰Ar/³⁹Ar age of 123.2 ± 2.2 Ma from one of the amphibolite blocks, suggest that the protoliths of the amphibolite blocks correspond to forearc basalt (FAB)-related rocks that formed during the earlier stage of subduction initiation of the Early Cretaceous Caribbean arc. We propose that the La Tinta amphibolites correspond to fragments of sills and dikes of hypoabyssal rocks formed in the earlier stages of a subduction initiation scenario in the Pacific realm (ca. 136 Ma). The forearc dolerite-derived amphibolites formed by partial melting of upwelling fertile asthenosphere at the beginning of subduction of the Proto-Caribbean (Atlantic) slab, with no interaction with slab-derived fluids/melts. This magmatic episode probably correlates with Early Cretaceous basic rocks described in Hispaniola (Gaspar Hernandez serpentinized peridotite-tectonite). The dikes and sills cooled and metamorphosed due to hydration at low pressure (ca. 3.8 kbar) and medium to high temperature (up to 720ºC) and reached ca. 500ºC at ca. 123 Ma. At this cooling stage, serpentinite formed after hydration of the ultramafic upper mantle. This process might have been favoured by faulting during extension of the forearc, indicating an early stage of dike and sill fragmentation and serpentinite mélanges formation; however, full development of the mélange likely took place during tectonic emplacement (obduction) onto the thrust belt of eastern Cuba during the latest Cretaceous.     

A late Precambrian (∼ 710 Ma) high volcanicity rift in the southern Eastern Desert of Egypt

The late Precambrian Shadli Metavolcanics of SE Egypt constitute a slightly metamorphosed bimodal sequence that has been previously interpreted as manifesting volcanic activity at an island arc. We report the first Rb-Sr geochronologic, trace element (including REE), and Nd isotopic data for these rocks. Two types of basalt are recognized, the stratigraphically lower suite having compositions like N-MORB ferrobasalt while the overlying basalt is similar to slightly fractionated E-MORB. The two basalt types were derived from melting of a strongly depleted source, most likely within the upper 60–75 km of the upper mantle. The origin of the felsic melts is problematic, and these could either have fractionated from a mafic melt or resulted from melting of juvenile crust. The mafic and felsic lavas yield a Rb-Sr isochron age of 712±24 Ma that probably represents the time of volcanic eruption. The trace element characteristics of both mafic and felsic members of the Shadli Metavolcanics show few of the hallmarks of subduction-related melts, and we reject the hypothesis that these formed at an island arc. Instead, the field and geochemical data are most consistent with the hypothesis that these rocks originated in a magmatic rift, where the eruption of large volumes of lava accompanied large-scale lithospheric extension. This inference suggests that the tectonic setting of the important 700–715 Ma crust-forming event in NE Africa and Arabia needs to be critically reexamined.

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Zusammenfassung Die spätpräkambrischen Shadli-Metavulkanite in der südöstlichen Eastern Desert von Ägypten sind eine schwach metamorphe bimodale Basalt-Rhyodazit-Abfolge, die bisher als Ausdruck eines Inselbogen-Vulkanismus gedeutet wurde. Zwei Basalt-Typen können aufgrund ihrer unterschiedlichen chemischen Zusammensetzung unterschieden werden: der stratigraphisch untere Typ ist ein N-MORB ähnlicher Ferrobasalt, während der überlagernde Typ Charakteristika eines leicht fraktionierten E-MORB aufweist. Die beiden Basaltvarietäten werden von stark an inkompatiblen Elementen verarmten Schmelzen aus den oberen 60–75 km des Mantels abgeleitet. Die Entstehung der sauren Metavulkanite ist nicht eindeutig geklärt; sowohl Fraktionierung aus einer mafischen Schmelze als auch Aufschmelzung juveniler Kruste vom Inselbogen-Typ sind denkbar. Die mafischen und felsischen Gesteine definieren zusammen ein Rb-Sr-Isochronenalter von 712 ± 24 Ma, das wir als den Zeitraum der Eruption deuten. Die Spurenelement-Verteilung der Shadli-Metavulkanite weist keine der charakteristischen Merkmale von Subduktionsmagmatismus auf, und wir sehen daher keinen direkten Zusammenhang mit einer Inselbogen-Entwicklung. Wir interpretieren den Shadli-Vulkanismus als Resultat eines Riftprozesses in junger kontinentaler Kruste, ähnlich dem Rio Grande-Rift oder dem Afar-Dreieck, wo starke Lithosphärendehnung die Förderung großer Lavamengen ermöglichte. Diese Interpretation stellt das einfache Schema einer panafrikanischen Krustenbildung durch Inselbogen-Addition im arabisch-nubischen Schild in Frage und erfordert eine Neubewertung bisheriger Modellvorstellungen.

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Résumé Les roches volcaniques faiblement métamorphisées du Précambrien tardif de Shadli dans le Sud-Est de l'Egypte se caractérisent par une séquence bimodale qui était jusqu'ici interprétée comme résultant d'un volcanisme d'arc insulaire. Nous présentons ici les premières données isotopiques (Rb-Sr, Nd) obtenues pour ces roches ainsi que des données d'éléments en trace (y compris les Terres Rares). Deux types principaux de basaltes peuvent être distingués: les basaltes qui se trouvent dans la partie inférieure de la colonne stratigraphique, ont une composition comparable aux ferrobasaltes de type N-MORB, tandis que les roches se trouvant dans la partie supérieure de la séquence s'apparentent plutôt aux E-MORB légèrement fractionnés. Les deux types de basalte proviennent de la fusion partielle d'un manteau fortement appauvri, et ce à une profondeur probable de 60 à 75 km dans le manteau supérieur. L'origine des laves acides pose, quant à elle, quelques problèmes: elles peuvent s'être formées par cristallisation fractionnée à partir d'un liquide basique, ou alors elles sont le produit de la fusion partielle d'une croûte juvénile. La combinaison des données Rb-Sr obtenues pour les roches acides et basiques permet l'obtention d'une isochrone définissant un âge de 712 ± 24 Ma. Cet âge est interprété comme datant les éruptions volcaniques. Les données d'éléments en traces obtenues pour les laves basiques et acides ne présentent aucune des caractéristiques associées au volcanisme d'arc insulaire. Par conséquent, nous rejetons l'hypothèse selon laquelle les roches volcaniques de Shadli se seraient formées dans un contexte d'arc insulaire. Les données géochimiques et de terrain seraient plutôt en accord avec une hypothèse selon laquelle les roches volcaniques métamorphiques de Shadli se seraient formées dans une zone de rift où de très volumineux épanchements de laves auraient succédé à une extension à grande échelle de la lithosphère. Cette interprétation des données nous conduit à suggérer un réexamen critique du contexte tectonique entourant la période de formation crustale se situant entre 700 a 715 Ma, dans le nord-est de l'Afrique ainsi qu'en Arabie.

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U–Pb TIMS age constraints on the evolution of the Neoproterozoic Meatiq Gneiss Dome,Eastern Desert,Egypt

Ages are used to constrain the temporal evolution of the Meatiq Gneiss Dome, Eastern Desert, Egypt, by dating (ID-TIMS) pre-, syn-, and post-tectonic igneous rocks in and around the dome. The Um Ba’anib Orthogneiss, comprising the deepest exposed structural levels of the dome, has a crystallization age of 630.8 ± 2 Ma. The overlying mylonites are interpreted to be a thrust sheet/complex (Abu Fannani Thrust Sheet) of highly mylonitized metasediments (?), migmatitic amphibolites, and orthogneisses with large and small tectonic lenses of less-deformed intrusives. Two syn-tectonic diorite lenses in this complex have crystallization ages of 609.0 ± 1.0 and 605.8 ± 0.9 Ma, respectively. The syn-tectonic Abu Ziran diorite, cutting across the tectonic contact between mylonite gneisses of the Abu Fannani Thrust Sheet and a structurally overlying thrust sheet of eugeoclinal rocks (“Pan-African nappe”), has a magmatic emplacement age of 606.4 ± 1.0 Ma. Zircons from a gabbro (Fawakhir ophiolite) within the eugeoclinal thrust sheet yielded a crystallization age of 736.5 ± 1.2 Ma. The post-tectonic Fawakhir monzodiorite intrudes the ophiolitic rocks and has an emplacement age of 597.8 ± 2.9 Ma. Two other post-tectonic granites, the Arieki granite that intrudes the foliated Um Ba’anib Orthogneiss, and the Um Had granite that cuts the deformed Hammamat sediments, have emplacement ages of 590 ± 3.1 and 596.3 ± 1.7 Ma, respectively. We consider formation of the Meatiq Gneiss Dome to be a young structural feature (<631 Ma), and our preferred tectonic interpretation is that it formed as a result of NE–SW shortening contemporaneous with folding of the nearby Hammamat sediments around 605–600 Ma, during oblique collision of East and West Gondwana.     

Nd–Sr–Hf–O isotope provinciality in the northernmost Arabian–Nubian Shield: implications for crustal evolution

Multi-isotope study including whole-rock Nd–Sr, single zircon Hf, and SIMS δ¹⁸O analyses of zircons sheds light on magma sources in the northernmost Arabian–Nubian Shield (ANS) during ~820–570 Ma. Reconnaissance initial Nd and Sr isotope data for the older rocks (~820–740 Ma) reaffirms previous estimates that early crustal evolution in this part of the shield involved some crustal contamination by pre-ANS material. Prominent isotope provinciality is displayed by post-collisional calc-alkaline and alkaline igneous rocks of ~635–570 Ma across a NW-SE transect across basement of the Sinai Peninsula (Egypt) and southern Israel. Silicic rocks of the NW-region are characterized by lower εNd(T)–εHf(T) and higher Sr_i and δ¹⁸O compared with rocks of the SE-region, and the transition between the regions is gradual. Within each region isotope ratios are independent of the extent of magma fractionation, and zircon cores and rims yield similar δ¹⁸O values. Comparison with southern segments of the ANS shows that the source for most ~635–570 Ma rocks can be modeled as the isotopically aged lower-intermediate crust in the ANS core (SE-region) and its northern, more contaminated ANS margins (NW-region). Nevertheless, Nd–Sr isotope enrichment of the lithospheric mantle is indicated by some basic magmas of the NW-region displaying the most enriched Nd–Sr isotope compositions. Comparison of Nd and Hf depleted mantle model ages for rocks of the SE-region may indicate that crustal formation events in the ANS geographical core took place at 1.1–1.2 Ga and were followed by crustal differentiation starting at ~0.9 Ga.     

Formation of juvenile continental crust in the Arabian–Nubian shield: evidence from granitic rocks of the Nakasib suture, NE Sudan

Major and trace element data, U–Pb zircon ages, and initial isotopic compositions of Sr, Nd, and Pb are reported for ten granitic and one rhyolitic rock sample from the neo-Proterozoic Nakasib suture in NE Sudan. Chemical data indicate that the samples are medium- to high-K, "I-type" granitic rocks that mostly plot as "volcanic arc granites" on discriminant diagrams. Geochronologic data indicate that rifting occurred 790±2?Ma and constrain the time of deformation associated with suturing of the Gebeit and Haya terranes to have ended by approximately 740?Ma. Isotopic data show a limited range, with initial ⁸⁷Sr/⁸⁶Sr=0.7021 to 0.7032 (mean=0.7025), εNd(t) =+5.5 to +7.0 (mean=+6.4), and ²⁰⁶Pb/²⁰⁴Pb = 17.50–17.62. Neodymium model ages (T_DM; 0.69–0.85?Ga; mean = 0.76?Ga) are indistinguishable from crystallization ages (0.79–0.71?Ga; mean=0.76?Ga), and the isotopic data considered together indicate derivation from homogeneously depleted mantle. The geochronologic data indicate that the terrane accretion to form the Arabian–Nubian shield began just prior to 750?Ma. The isotopic data reinforces models for the generation of large volumes of juvenile continental crust during neo-Proterozoic time, probably at intra-oceanic convergent margins. The data also indicate that crust formation was associated with two cycles of incompatible element enrichment in granitic rocks, with an earlier cycle beginning approximately 870?Ma and culminating approximately 740?Ma, and the second cycle beginning after pervasive high-degree melts – possibly hot-spot related – were emplaced approximately 690–720?Ma.     

SIMS zircon U–Pb and mica K–Ar geochronology,and Sr–Nd isotope geochemistry of Neoproterozoic granitoids and their bearing on the evolution of the north Eastern Desert,Egypt

Granitic rocks are commonly used as means to study chemical evolution of continental crust, particularly, their isotopic compositions, which reflect the relative contributions of mantle and crustal components in their genesis. New SIMS and K–Ar geochronology, isotope, geochemical, and mineral chemistry data are presented for the granitoid rocks located in and around Gabal Dara in the Northern Eastern Desert of Egypt. The granitoid suite comprises quartz diorites, Muscovite (Mus) trondhjemites, and granodiorites intruded by biotite-hornblende (BH) granites and alkali feldspar (AF) granites. Mus trondhjemite, granodiorite and BH granite exhibit I-type calc alkaline affinities. Mus trondhjemite and granodiorite show medium-K calc-alkaline and metaluminous/mildy peraluminous affinities, whereas BH granites have high-K calc-alkaline and metaluminous character. Concordant ²⁰⁶Pb/²³⁸U weighted mean ages together with geochemical peculiarities suggest that Mus trondhjemites (741 Ma) followed by granodiorites (720 Ma) are genetically unrelated, and formed in subduction-related regime by partial melting of lower oceanic crust together with a significant proportion of mantle melt. The genesis of Mus trondhjemites is correlated with the main event in the evolution of the Eastern Desert, called “~750 Ma crust forming event”.The field and geochemical criteria together with age data assign the high-K calc-alkaline BH granites (608–590 Ma) and alkaline AF granites (600–592 Ma) as post-collisional granites. The differences in geochemical traits, e.g. high-K calc-alkaline versus alkaline/peralkaline affinities respectively, suggest that BH granites and AF granites are genetically unrelated. The age overlap indicating coeval generation of calc-alkaline and alkaline melts, which in turn suggests that magma genesis was controlled by local composition of the source. The high-K calc-alkaline BH granites are most likely generated from lithospheric mantle melt which have been hybridized by crustal melts produced by underplating process. AF granites exhibit enrichment in K₂O, Rb, Nb, Y, and Th, and depletion in Al₂O₃, TiO₂, MgO, CaO, FeO, P₂O₅, Sr, and Ba as well as alkaline/peralkaline affinity. These geochemical criteria combined with the moderately fractionated rare earth elements pattern (La_N/Yb_N = 9–14) suggest that AF granite magma might have been generated by partial melting of Arabian–Nubian Shield (ANS) arc crust in response of upwelling of hot asthenospheric mantle melts, which became in direct contact with lower ANS continental crust material due to delamination. Furthermore, a minor role of crystal fractionation of plagioclase, amphibole, biotite, zircon, and titanomagnetite in the evolution of AF granites is also suggested. The low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7033–0.7037) and positive ε_Nd(T) values (+ 2.32 to + 4.71) clearly reflect a significant involvement of depleted mantle source in the generation of the post-collision granites and a juvenile nature for the ANS.     

An example of post-collisional appinitic magmatism with an arc-like signature: the Wadi Nasb mafic intrusion,north Arabian–Nubian Shield,south Sinai,Egypt

We present new data for the Neoproterozoic mafic intrusion exposed in Wadi Nasb, south Sinai, Egypt (northernmost Arabian–Nubian Shield; ANS). The Nasb mafic intrusion (NMI) intrudes metasediments, Rutig volcanics, and diorite/granodiorite, and is intruded in turn by younger monzogranite and quartz-monzonite. Available geochronological data for the country rocks of the NMI provide a tight constraint on its age, between 619 and 610 Ma, during the hiatus between the lower and upper Rutig volcanics. The NMI is neither deformed nor metamorphosed, indicating post-collisional emplacement, and uralitization by late-magmatic and sub-solidus alteration is restricted to the margins of the intrusion. A quantitative fractionation model indicates a fractionating assemblage of 61% primary amphibole, 10% clinopyroxene, 28% plagioclase, 1% biotite, 0.4% apatite, and 0.15% Fe-Ti oxide. Contrary to the recent studies, we find that the nearby diorite of Gebel Sheikh El-Arab is not co-genetic with the appinitic gabbro of the NMI. Although there are volcanic xenoliths in the NMI, we find no chemical evidence requiring contamination by continental crust. A subduction-related signature in a post-orogenic intrusion requires the inheritance of geochemical tendencies from a previous subduction phase. Given that the fine-grained gabbro of the NMI is consistent with a near-primary mantle melt, we attribute this inheritance to persistence and later melting of the slab-modified mantle domains, as opposed to partial melting and assimilation of the juvenile continental crust. The fine-grained gabbro composition indicates derivation at temperature and pressure conditions similar to the sources of mid-ocean ridge basalts: mantle potential temperature near 1350°C and extent of melting about 7%. Such temperatures, neither so high as to require a plume nor so low as to be consistent with small degrees of melting of a volatile-rich source, are most consistent with a lithospheric delamination scenario, allowing the upwelling of fertile, subduction-modified asthenosphere to depths ≤50 km.     

Spinels,Fe–Ti oxide minerals,apatites, and carbonates hosted in the ophiolites of Eastern Desert of Egypt: mineralogy and chemical aspects

Spinels, Fe–Ti oxide minerals, apatites, and carbonates hosted in ophiolitic serpentinites and metagabbros of Gabal Garf (southern ED) and Wadi Hammariya (central ED) of Egypt are discussed. Microscopic and electron probe studies on these minerals are made to evaluate their textural and compositional variations. Alteration of chromites led to form ferritchromite and magnetite; rutile–magnetite intergrowths and martite are common in serpentinites. Fine trillis exsolution of ilmenite–magnetite and ilmenite–hematite and intergrowth of rutile–magnetite and ilmenite–sphene are recorded. Composite intergrowth grains of titanomagnetite–ilmenite trellis lamellae are common in metagabbros. The formation of ilmenite trellis and lamellae in magnetite and titanomagnetite indicate an oxidation process due to excess of oxygen contained in titanomagnetite; trapped and external oxidizing agents. This indicates the high P _H2O and oxygen fugacity of the parental magma. The sulfides minerals include pyrrhotite, pyrite and chalcopyrite. Based on the chemical characteristics, the Fe–Ti oxide from the ophiolitic metagabbros in both areas corresponds to ilmenite. The patites from the metagabbros are identified as fluor-apatite. Carbonates are represented by dolomites in serpentinites and calcite in metagabbros. Spinel crystals in serpentinites are homogenous or zoned with unaltered cores of Al-spinel to ferritchromit and Cr-magnetite toward the altered rims. Compared to cores, the metamorphic rims are enriched in Cr# (0.87–1.00 vs. 0.83–0.86 for rims and cores, respectively) and impoverished in Mg# (0.26–0.48 vs. 0.56–0.67) due to Mg–Fe and Al (Cr)–Fe³⁺ exchange with the surrounding silicates during regional metamorphism rather than serpentinization process. The Fe–Ti oxides have been formed under temperature of ~800 °C for ilmenite. Al-spinels equilibrated below 500–550 °C, while the altered spinel rims correspond to metamorphism around 500–600 °C. Geochemical evidence of the podiform Al-spinels suggest a greenschist up to lower amphibolite facies metamorphism (at 500–600 °C), which is isofacial with the host rocks. Al-spinel cores do not appear to have re-equilibrated completely with the metamorphic spinel rims and surrounding silicates, suggesting relic magmatic composition unaffected by metamorphism. The composition of Al-spinel grains suggest an ophiolitic origin and derivation by crystallization of boninitic magma that belonging to a supra-subduction setting could form either in forearcs during an incipient stage of subduction initiation or in back-arc basins.