Relation between concentrations of giant chloride nuclei and exchange in the atmosphere

Summary In Northern Bohemia 33 research flights were made during which concentration of giant condensation chloride nuclei was measured up to a height of 3,500 m above the earth's surface. Chloride particles were determined by traces left by them in a sheet of gelatine with silver nitrate (Liesegang circles). The actual size of the particles was obtained by comparison of particles of a known size, falling in a sedimentation tube, with images in the sensitive sheet, and the result was adapted to the analysis of samples during the flight. For each level at which a sample was exposed the spectrum of the sizes of nuclei was determined. During the year the average concentration of the giant chloride nuclei at a height of 100 m above the earth was 7.3×10^–3 cm^–3. At greater heights concentration of the nuclei decreased successively, so that at 2,000 m it was only 0.3×10^–3 cm^–3 and above the level of 3,000 m the nuclei occurred sporadically, on the whole. Under the influence of atmospheric exchange the concentration of the nuclei in the boundary layer up to 1,000 m above the earth's surface changes considerably both during the day and during the year. The highest concentration occurs at a height of several hundred metres above the earth in the winter month, at the morning and evening hours, i.e. during a more stable temperature lapse rate. From the established concentrations of the nuclei relation between the turbulent diffusion coefficient and the height above the earth was determined. Its average value during the year increases up to a height of 300 to 400 m above the earth. Above this level it decreases roughly according to the relation ofKz ^–6/7. The exponent changes not only with temperature stratification (with the time of day and year), but also with the average wind speed. For sodium-chloride particles of 2.5 in diameter the maximum value of turbulent diffusion coefficient (at level of 400 m), reaches about 18×10³ cm² sec^–1 while the minimum value is about 5×10³ cm² sec^–1 (above 2,000 m).     

The nuclei of atmospheric condensation

Summary Our present knowledge concerning the abundance, size, physical properties, origin and nature of condensation nuclei is reviewed and critically assessed.     

Dependence of the effective attachment coefficient of small ions upon the size of condensation nuclei

Summary To clarify the ionization equilibrium near the ground, simultaneous measurements of the rate of ion pair production (q), the concentrations of small ions (n) and condensation nuclei (Z), and the diffusion coefficient of condensation nuclei (D) were carried out at several stations in the central area of Japan. The total rate of ion pair production (q) was estimated fromq=q(Rn)+q(Tn)+q()+q(+CR). The value ofq was estimated as 10J to 20J. The mean life () and the effective attachment coefficient () of small ions were also estimated at each station. Correlations amongn, Z, q, andD were also studied. If we take the variation ofD into consideration, the correlation was expressed by the simple formula;q=n Z. The dependence of upon size of nuclei (2r) were also measured, and was found to correlate well withD orr.     

A continuous recorder for condensation nuclei

Summary A continuous recorder of condensation nuclei with multiple ranges that are substantially linear over the range of 500 to 50,000 nuclei per ml full scale is described. The range can be extended but the scale law becomes proportional to the cube root of the nuclei concentration. The sampling rate is 100 ml/sec and the response time is less than 2 seconds.The unit works on fog-scattered light with dark-field illumination. The expansion ratio is adjustable (at the expense of recalibration) and can be made high enough to respond to a radium source. The electronics are simple and sturdy; the unit has been used on a truck in motion.     

An ionometric counter for condensation nuclei

Summary Condensation nuclei detectable in the range of supersaturation used in the expansion method do not play the role expected earlier, for the production of water droplets in natural clouds.However, these nuclei exist in the atmosphere, and they can be of importance in other processes in the air; for example, they can be partners for annihilation of small air ions there. Therefore, a direct investigation of the interaction between the condensation nuclei and the small air ions may be of interest. For this purpose an, ionometric counter for condensation nuclei is designed, in which the air under examination is mixed in a mixing chamber with small air ions produced by a tritium ion-generator, and the presence of condensation nuclei is measured by the decrease of the concentration of air ions recorded with an aspiration ion counter as compared to the concentration recorded when filtered air was originally sucked through the mixing chamber.Comparatively rapid variations of the concentration of nuclei can be continuously recorded. The electrical properties of the aerosol particles destroying air ions can be investigated by inserting an electrical filter. By the ionometric counter condensation nuclei can be investigated without adding water particles to them.     

Production of atmospheric condensation nuclei by sunrays

Summary 1) It is confirmed that in filtered, nucleus-free air, in a polyethylene balloon, if irradiated by sunglight, an immediate large number of condensation nuclei appear. — 2) The nucleus count rises to about 35. 000/cm³ and if the irradiation is continued does not increase, but decreases. This decreased is accelerated in the dark. — 3) Less intensive sunlight as when the sun was covered by clouds, gives slower and smaller increases. — 4) The same was observed if, instead of air, inducstrial oxygen or nitrogen was used. — 5) Traces of H₂S increase the sun effect enormously. — 6) Traces of NH₃ also increase it, but less than H₂S. — 7) SO₂ filtered through cottonwool gave also in the dark nuclei, which then decreased in number. — 8) It is supposed that H₂S is oxydized by the photochemical action of the sun's visible spectrum to SO₂ SO₃ SO₄ which is a nucleus. With NH₃ the formation of (NH₃)₂ SO₄ is probable. But no direct proof is given that these are the actual impurities which explain the sun's action on air. It is calculated that dilutions of 10^–15 of an impurity of the type of H₂S can quantitatively explain the sun effect. — 9) The work ofAitken is extensively quoted, who noticed, 50 years ago, the «fog produced by sun».

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Zusammenfassung 1) Es wird bestätigt, dass Sonnen-Bestrahlung von filtrierter kernfreier Luft, welche in einem Polyethylen-Ballon aufbewahrt ist, zum Entstehen einer hohen Zahl von Kondensations Kernen führt. — 2) Die Kernzahl steigt auf etwa 35 000/cm³. Wird die Bestrahlung fortgesetzt, dann steigt sie nicht weiter sondern nimmt ab. Die Abnahme wird im Dunkeln beschleunigt. — 3) Durch Wolken abgeschwächtes Sonnenlicht gibt eine langsamere, weniger grosse Kernbildung. — 4) Dieselben Beobachtungen wurden mit industriellem Sauerstroff und Stickstoff auch gemacht. — 5) Spuren von H₂S verstärken den Sonneneffekt enorm. — 6) Spuren von NH₃ verstärken ihn auch, jedoch weniger. — 7) SO₂ Gas, gefiltert durch Baumwollfilter giebt auch im Dunkeln schon Kerne, deren Zahl dann wieder abnimmt. — 8) Es wird angenommen, das H₂S durch photochemische Wirkung des sichtbaren Sonnenlichtes oxidiert wird zu SO₂ SO₃ SO₄ welch letzteres bereits als H₂HO₄ ein Kondensationskern ist. Mit NH₃)₂ SO₄ Kondensationskerne gebildet werden. Es sind jedoch keine direkten Beweise dafür vorhanden, dass diese Gase die Verunreinigungen der atmosphärischen Luft sind, welche den Sonnenffekt geben. Es wird aber berechnet, dass schon Verdünnungen von 10^–15 eine Verunreinigung H₂S den Sonnen-Effekt erklären. — 9)Aitken's Werk, der bereits vor 50 Jahren von « durch Sonne verursachten Nebel « sprach, wird gewürdigt.

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From the Clima-physiological Laboratory of St. Moritz-Bad.     

Influence of sunlight on atmospheric condensation nuclei

I has been shown that irradiation of air by sun-rays leads to a formation of atmospheric condensation nuclei, as measured with the automatic nucleus counter (1).To control the influence of the material, experiments were done in a gasometer where a rubber balloon was built in, also in a metal container covered either with uviol glass or window glass, or with air in a polyethylene balloon. The same influence of sunrays was observed in each case.Similar experiments were then done with compressed air from a metal container, or with oxygen gas, nitrogen gas or nitrous oxide all from metal containers. In all cases sun-rays produced condensation nuclei; the effect was present both at 1800 m and at 270 m altitude. Diffuse sunlight with high clouds also had an effect. Infra-red radiation and mechanical shaking were without result, but ultraviolet rays from a quartz-mercury lamp increased the nucleus count of the balloon whether it contained air or one of the above-mentioned gases.As yet it has not been possible to decide the mechanism of formation of these nuclei and what their meteorological and biological role might be.The detailed paper will appear later in «Geofisica pura e applicata».     

On some measurements of the condensation of different vapors upon Aitken condensation nuclei

No final theory on the activity of Aitken nuclei has been established yet. In particular the supersaturation is not known for the Aitken nuclei to grow into droplets, f.e. according toF. Volz only nuclei of radius >0.1 can cause condensation under atmospheric conditions. On the other hand according toH. G. Müller condensation over the continents has to occur at the Aitken nuclei since precipitation washes out the other nuclei.This uncertainty becomes obvious in the interpretation of the experimental results.Chr. Junge found that the necessary activation supersaturation of a continental Aitken aerosol and of artificial aerosols of the same size of nuclei lies between 2 and 20%, 10% being sufficient for the main fraction of nuclei to grow.In contrastW. Wieland was able to activate in a mixing cloud chamber a big portion, if not all, of the nuclei of a continental aerosol at supersaturations below 1.5%. Some of our own results, obtained with the same technic, agree with this. At supersaturations below 0.8% at least half of the Aitken nuclei present are activated. To obtain the same result with benzene and acetone we found, that benzene required a slightly smaller, and acetone a somewhat bigger supersaturation.However later experiments revealed a considerable effect of the geometry of the mixing cloud chamber upon the results. Since the physics of the chamber has not been fully explored the method was abandoned. Instead the principle of cooling by adiabatic expansion was used. An expansion apparatus based on the principle of a fotoelectric nucleus counter was developed allowing us to measure with two cathode ray oscillographs the pressure and simultaneously the change of intensity of a lightbeam due to the scattering on the forming cloud as a function of time. The length of the lightbeam could be chosen between 60 and 200 cm. The overpressure before the expansion was always 180 mm of mercury. The ratio of expansion rates was 12.53060 at the beginning of the expansion. The slowest rate was about 6 seconds, corresponding to a rate of ascent of 210 m/s at the beginning of the expansion. Smaller rates could not be obtained because of heat transfer at the chamber walls.The present work has been performed for the Eidgenössische Kommission zum Studium der Hagelbildung und der Hagelabwehr (Switzerland) at the research station Osservatorio Ticinese Locarno-Monti della Centrale Meteorologica Svizzera     

Uncharged condensation nuclei produced by ultra-violet light

Summary A large number of experiments have been carried out with the object of determining the nature, properties and source of the condensation nuclei produced by the action of a beam of ultra-violet light within an expansion chamber. This paper is essentially a qualitative summary of the results which have been obtained. It is concluded that these experiments show that it is the rubber component of the chambers that has been responsible for the major part of the effect. It is by no means suggested that this is the only source of the nuclei, but it is implied that only apparatus free from rubber should be used in any study of the properties of the nuclei associated with a given gas or vapour.Work ofA. J. Barnard (now at University of Natal, Pietermaritzburg) andJ. R. Atkinson.     

A condensation nuclei counter with photographic recording

Summary A condensation nuclei counter based onAitken's principle is described and depicted. It permits simultaneous observations of the graticule by two persons or the observation of the graticule by one person and the synchroeous photographic recording of the droplets on 35 mm film strip or single plates. With one exposure, the droplets on 24 squares of the millimetre graticule can be recorded so that a repetition of the necessary operations required by other counters in order to obtain an average count becomes superfluous and the time taken for one experiment is reduced to three quarters of a minute. The limitation to five droplets per square mm recommended for all hitherto existing nuclei counters with eye observations is removed when the droplets and the graticule are photographed. By the use of a special sealing arrangement and by employment of vacuum taps which proved most satisfactory with the previous construction of a photo-electric nuclei counter, leakages are practically impossible. The glass windows of the receiver are interchangeable with plates of conducting glass which can be heated by the passage of an electric current. The construction ensures that the 1 cm distance above the graticule is always maintained, independent of the tightening of the sealing arrangement. The receiver is equipped with a stirrer operated from outside by a permanent magnet. Two easily detached pumps are provided; one for purifying the air in the receiver and for the dilatation, the other for sucking the sample of impure air into the receiver. The adiabatic cooling in the receiver can be produced e. g. by means of an expansion pump. The method of measuring is discussed. Examples of records are reproduced. Applications and the development of a fully automatic recording nuclei counter are indicated.

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Zusammenfassung Ein Kernzähler, derAitkens Prinzip benützt, wird beschrieben und abgebildet. Er gestattet die gleichzeitige Beobachtung des Zählglases durch zwei Personen oder die Beobachtung des Zählglases durch eine Person und die gleichzeitige photographische Registrierung der Tröpfchen auf Kino-Normalfilm (von 35 mm) oder Platten. Miteiner Aufnahme können die Tröpfchen auf 24 Quadraten des in Quadratmillimeter geteilten Zählglases festgehalten werden, so dass eine Wiederholung der erforderlichen Operationen, welche bei allen anderen Kernzählern vorgeschrieben sind, um Mittelwerte der Einselzählungen zu erhalten, überflüssig ist und die Dauereines vollständigen Experimentes auf dreiviertel Minuten reduziert wird. Die Beschränkung auf fünf Tröpfchen per Quadratmillimeter, welche für die meisten bisherigen Kernzähler bei Augenbeobachtungen empfohlen wird, wird aufgehoben, wenn die Tröpfchen und das Zählglas photographiert werden. Durch eine spezielle Dichtungseinrichtung und durch Verwendung von Vakuum-Hähnen, welche sich bei der Konstruktion eines photo-elektrischen Kernzählers so sehr bewährt haben, ist Undichtwerden des Rezipienten praktisch unmöglich. Die Spiegelglasfenster des Rezipienten können gegen solche aus leitendem Glas ausgetauscht werden, welche mittels eines durch sie geschickten elektrischen Stromes geheizt werden können. Die Konstruktion gewährleistet, dass der Abstand (1 cm) oberhalb des Zählglases stets erhalten bleibt, unabhängig vom Drucke, der auf die Dichtung ausgeübt wird. Der Rezipient ist mit einem Rührer ausgestattet, der von aussen durch einen permanenten Magneten betätigt wird. Es sind zwei Pumpen vorgesehen, die leicht abnomontiert werden können; die eine ist für die Reinigung der Luft im Rezipienten und für die Dilatation zur Herbeiführung des Tropfenfalles bestimmt, die andere dient zum Einsaugen der zu untersuchenden Luftprobe in den Rezipienten. Die adiabatische Abkühlung im Rezipienten kann z.B. mittels der Dilatationspumpe erzeugt werden. Die Messmethode wird beschrieben. Probe von photographischen Registrierungen der Tröpfchen auf dem Zählglase werden reproduziert. Einige Anwendungen und die Entwicklung eines voll-automatisch registrierenden Kernzählers wird angedeutet.

     

On condensation nuclei produced at heated surfaces

Summary An investigation of heated surfaces of glass, metal and oil as sources of condensation nuclei is reported. Below a certain transition temperature the nucleus production is of a temporary nature and decreases to zero with the continued heating of the surface. Above this temperature, however, the nucleus production does not change with time. The transition temperature varies with the material of the surface and is not always associated with the onset of incandescence. The nuclei produced at the lower temperatures have a radius of about 10^–5 cm and, on production, are mainly uncharged. Electric light bulbs can produce appreciable numbers of these nuclei.

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Zusammenfassung Es wird über eine Untersuchung von geheizten Glas-, Metall-und Öloberflächen als Quelle von Kondensationskernen berichtet. Unterhalb einer gewissen Übergangstemperatur ist die Kernerzeugung unbeständig und sinkt bei fortgesetzter Heizung der Oberfläche auf null. Oberhalb dieser Temperatur ändert sich die Kernproduktion nicht mit der Zeit. Es wurde gefunden, dass sich die Übergangstemperatur mit dem Material der Oberfläche ändert und nicht immer mit dem Beginn des Glühens assoziiert ist. Die Kerne, welche bei den niedrigeren Temperaturen erzeugt werden, haben einen mittleren Radius von ungefähr 10^–5 cm und sind bei ihrem Entstehen grösstenteils ungeladen. Elektrische Glühlampenkönnen eine beträchtliche Zahl dieser Kerne erzeugen.

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Note: The research reported in this document has been sponsored in part by the Office, Chief of Research and Development, U.S. Department of Army, through its European Office under Contract No. DA-91-508-EUC-194.     

The condensation nuclei produced by point discharge

Summary The properties of condensation nuclei generated at a metal point corona discharge have been examined. The threshold voltages for nucleus production and for small ion production are the same. The fraction of the nuclei which is charged is initially small and becomes virtually zero after a few seconds. It is demonstrated that in the non-uniform field near the point there is a force on the nuclei driving them to the point. From determinations of the diffusion coefficient it is tentatively concluded that a portion at least of the nuclei are originally of molecular size. No satisfactory explanation has been found for certain anomalous features of the variations in size and in concentration of the nuclei with time after production.

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Zusammenfassung Es wurden die Eigenschaften von Kondensationskernen untersucht, die durch Koronaentladung von einer Metallspitze erzeugt wurden. Die Spannungsschwelle für die Erzeugung von Kondensationskernen und kleinen Ionen ist die gleiche. Der Bruchteil der Kerne, welche geladen sind, ist anfangs klein und wird nach einigen Sekunden praktisch null. Es wird gezeigt, dass in dem inhomogenen Felde nahe der Spitze eine Kraft auf die Kerne wirkt, welche sie zur Spitze treibt. Aus Bestimmungen des Diffusionskoeffizienten wird versuchsweise geschlossen, dass wenigstens ein Teil der Kerne ursprünglich molekulare Grösse hat. Keine befriedigende Erklärung für gewisse anomale Eigenschaften der zeitlichen Änderungen der Grösse und Konzentration der Kerne nach ihrer Erzeugung wurde gefunden.

     

Production of atmospheric condensation nuclei by solar radiation

Summary Air with a very low count of atmospheric condensation nuclei was irradiated by direct sunlight through an uviol glass window, or through ordinary glass or in a polyethylene balloon. The nucleus count rises immediately and reaches very high values.

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Zusammenfassung Luft mit sehr niedriger Zahl von atmosphärischen Kondensations-Kernen wurde mit direktem Sonnenlicht bestrahlt, entweder durch ein UV Glas oder durch gewöhnliches Glas oder durch einen Polyethylen-Ballon. Die Zahl der atmosphärischen Kondensations-Kerne steigt sogleich und erreicht sehr hohe Werte.

     

The generation of condensation nuclei by ionising radiation

Summary The production of condensation nuclei by the irradiation of filtered nuclei-free air by X-rays, alpha particles and beta particles is described. It is found that nuclei are created in large numbers by such irradiation and that there appears to be a threshold radiation dose at which the nucleus concentration is increased by a factor of more than a hundred.The effect of varying sulphur dioxide content of the irradiated air has been investigated and for concentrations of between one and ten milligrams per cubic metre of air there is some proportionality between the sulphur dioxide content of the air and the nucleus concentration produced by a given radiation dose.It is shown, however, that sulphur dioxide cannot be exclusively responsible for the generation of condensation nuclei by irradiation of filtered air and other possible agents and mechanisms are suggested.     

Vertical profiles of condensation nuclei in the stratosphere

An automatic condensation nuclei counter was developed for the concentration range of about 1 to 400 particles per cubic centimeter. After expansion, the water droplets are photographed when they are still suspended in the air so that the counter can be considered an absolute one. The volume in which the droplets are counted is determined by the size of the picture of the droplets as a function of their distance from the focal plane. To eliminate any effect of decreasing pressure with altitude, the cloud chamber is filled with clean air prior to expansion to about half an atmosphere above ambient pressure. This counter was used to obtain vertical profiles of condensation nuclei up to altitudes of 27 km with high altitude balloons. A total of seven profiles was obtained over a period of about one year at 47° N over the United States. Because of the restrictions in the range of the meter no data could be obtained below 5 km. The profiles show the following main features:

1. 1.
   Although there are pronounced fluctuations in the individual flights the average nuclei concentration of 200 to 300/cm³ remains fairly constant from 5 km to the tropopause.     
   
   

The effects of condensation nuclei in atmospheric electricity

Summary The effects of condensation nuclei in the atmosphere are discussed, particularly in relation to the «sunrise effect» and it is shown that the introduction of positively charged nuclei is the only process yet suggested that can explain the observed results.     

A new condensation nuclei counter with continuous oversaturation

Summary By mixing atmospheric air, saturated water vapour and hydrochloric acid a water vapour supersaturation corresponding to that in theScholz-nucleus counter is formed. The density of the fog formed is reproducibly related to the number of condensation nuclei per cm³ and can easily be measured by photocells.

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Zusammenfassung Durch Mischung von atmosphärischer Luft, gesättigtem Wasserdampf und Chlorwasserstoff entsteht eine demScholz'schen Kernzähler entsprechende Wasserdampfübersättigung. Die Dichte des entstehenden Nebels steht in reproduzierbarem Zusammenhang mit der Kondensationskernzahl pro cm³ und kann leicht mittels Fotozellen gemessen werden.

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Presented by Dozent Dr. Ing.R Mühleisen, Max-Planck-Institut für Physik der Stratosphäre,Weissenau bei Ravensburg (Federal Republic of Germany).