High resolution OSL and post-IR IRSL dating of the last interglacial–glacial cycle at the Sanbahuo loess site (northeastern China)

Northeastern China is located in the East Asian monsoon region; it is sensitive to both high and low latitude global climate systems. Loess deposits in the region have considerable potential as sensitive archives of past climate changes. However, research into loess deposition and climate change in this region is restricted by the lack of independent age control. In this study, coarse-grained quartz SAR OSL and K-feldspar post-IR infrared (IR) stimulated luminescence (post-IR IRSL; pIRIR₂₉₀) methods have been used to date the Sanbahuo loess site in northeastern China. The quartz OSL characteristics are satisfactory. The measured pIRIR₂₉₀ D_e's do not vary significantly with IR stimulation temperatures between 50 °C and 260 °C; a first IR stimulation temperature of 200 °C was adopted. Dose recovery tests were performed by adding different laboratory doses to both laboratory bleached (300 h SOL2) samples and natural samples; the results are satisfactory up to ∼800 Gy. Resulting quartz OSL and feldspar pIRIR₂₉₀ ages are in good agreement at least back to ∼44 ka; beyond this feldspar pIRIR₂₉₀ ages are older. The feldspar ages are consistent with the expected age of the S1 palaeosol (MIS 5). There appears to have been a period of fast loess deposition at ∼62 ka, perhaps indicative of winter monsoon intensification with a very cold and dry climate that lead to a serious desertification of dunefields in northeastern China.     

Storm-related sea level variations along the North Sea coast as simulated by a high-resolution model 1958–2002

Storm-related sea level variations 1958–2002 along the North Sea coast from a high-resolution numerical hindcast are investigated and compared to the results of earlier studies. Considerable variations were found from year to year and over the entire period. The large-scale pattern of these variations is consistent with that derived from previous studies, while the magnitudes of the long-term trends differ. The latter is attributed to different analysis periods, improvements in the atmospheric forcing, and the enhanced spatial resolution of the numerical simulation. It is shown that the different analysis periods, in particular, represent an issue as the increase in storm-related sea levels was found to be weaker over the last few years that have not been included in earlier studies. These changes are consistent with observed changes of the storm climate over the North Sea. It is also shown that observed and hindcast trends may differ significantly. While the latter are in agreement with observed changes in the storm climate, it may be concluded that observed sea level changes along the North Sea coast comprise a considerable fraction that cannot be attributed to changes in the large-scale atmospheric circulation.

Luminescence properties and optically (post-IR blue-light) stimulated luminescence dating of limnic sediments from northern Lake Malawi – Chances and limitations

Affected by the shifting Intertropical Convergence Zone, Lake Malawi holds an outstanding limnic sediment archive storing palaeo-environmental information of a climatically highly responsive landscape in the East African Rift Valley. Reliable chronological data are essential to interpret the lake-bottom sediments and optically stimulated luminescence (OSL) dating is an important method to build up the chronology. We report on material-property studies and OSL-dating results for polymineral fine grains extracted from piston cores obtained from the northern basin of Lake Malawi during the 1998 campaign of the International Decade of the East African Lakes (IDEAL). OSL-dating is based on a post-IR blue (pIRB) light stimulation single aliquot regeneration (SAR) protocol. Our results support earlier publications demonstrating the general applicability of OSL-dating on Lake Malawi sediments of Holocene and late Pleistocene age. However, the study also shows that dose rate estimations imply major challenges which need to be investigated in more detail to improve future OSL-dating results.     

Biomarker responses in flounder (Platichthys flesus) and mussel (Mytilus edulis) in the Klaipeda-Būtinge area (Baltic Sea)

During the EU project BEEP a battery of biomarkers was applied in flounder (Platichthys flesus) and the blue mussel (Mytilus edulis) collected at three locations off the Lithuanian coast (Baltic Sea) in June and September 2001 and 2002. The elevated biomarker responses in specimens sampled in September 2001 were apparently related to the extensive dredging activities in the Klaipeda port area and subsequent dumping of contaminated sediments. High concentrations of organic pollutants (organochlorines and PBDEs) were also measured in the tissues of both indicator species. In addition, response levels of genotoxicity, cytotoxicity, immunotoxicity as well as concentrations of PAH metabolites in the bile of flounder showed elevations in 2002 after an oil spill in the Būtinge oil terminal in November 2001. In flounder, biomarker measurements 10 months after the spill indicated recovery processes but in mussels a high level of genotoxicity could still be observed 22 months later. The present study illustrates the usefulness of the multi-biomarker approach in the detection of biological effects of pollution in this region of the Baltic Sea.     

Trace elements and stable isotope ratios (δC and δN) in fish from deep-waters of the Sulu Sea and the Celebes Sea

Trace elements (TEs) and stable isotope ratios (δ¹⁵N and δ¹³C) were analyzed in fish from deep-water of the Sulu Sea, the Celebes Sea and the Philippine Sea. Concentrations of V and Pb in pelagic fish from the Sulu Sea were higher than those from the Celebes Sea, whereas the opposite trend was observed for δ¹³C. High concentrations of Zn, Cu and Ag were found in non-migrant fish in deep-water, while Rb level was high in fish which migrate up to the epipelagic zone, probably resulting from differences in background levels of these TEs in each water environment or function of adaptation to deep-water by migrant and non-migrant species. Arsenic level in the Sulu Sea fish was positively correlated with δ¹⁵N, indicating biomagnification of arsenic. To our knowledge, this is the first study on relationship between diel vertical migration and TE accumulation in deep-water fish.     

Paleotemperature variations at Lake Caohai,southwestern China,during the past 500 years:Evidence from combined δ~(18)O analysis of cellulose and carbonates

The oxygen isotopic values of aquatic plant cellulose and carbonates in Lake Caohai sediments were measured using a continuous flow isotopic ratio mass spectrometer(CF-IRMS).Because of predictable oxygen isotopic fractionation between cellulose and its source water,the oxygen isotopic composition of paleo-lake water has been established quantitatively.Combined oxygen isotopic values of cellulose and carbonates were used in the‘Craig’equation to determine paleotemperatures and their variation in the lake during the past 500 years.Results show that the paleotemperature trend correlates well with meteorological records from Weining.There are four notable cold intervals at Lake Caohai over the past 500 years,namely 1540–1570AD,1670–1715AD,1780–1870AD and 1900–1930AD,and the former three cold intervals have been observed in the conventional Little Ice Age(LIA).These cold periods at Lake Caohai correspond well with those recorded from tree ring,peat,and ice core data from adjacent regions,particularly temperature those inferred fromδ18O of peat cellulose from Hongyuan Southwestern China.The trend in paleotemperature variations at Lake Caohai are also consistent with both the change of Indian summer monsoon,derived fromδ18O values of a stalagmite in Dongge,and a recorded shift in solar activity.The findings of this study illustrate that coupled analysis ofδ18O values of cellulose and carbonates from lake sediments may be used as a paleotemperature proxy.These results also provide further evidence of the existence of LIA in southwestern China.     

δ~(18)O record and temperature change over the past 100 years in ice cores on the Tibetan Plateau

1 IntroductionMeteorological stations on the Tibetan Plateau are few in number and uneven in distribution, with a majority concentrated in the east and south. No stations exist so far within the large expanse in the middle or west of the Plateau. Moreover…     

Chloropigments a in the Gulf of Gdańsk (Baltic Sea) as markers of the state of this environment

The Gulf of Gdańsk receives the waters of the Wis?a (Vistula), the largest Polish river and the second largest river flowing into the Baltic Sea. Chloropigments a (chlorophyll a and its derivatives) were determined in water and sediments from the Gulf. Samples were collected during cruises of R.V. 'Oceania' at 19 stations located at different water depths and distances from the shore, in May (2003) and October (2004), i.e., at the beginning and at the end of the growing season, respectively. Seawater was also sampled on the beach at Sopot in June, July and August 2004, i.e., during the height of the growing season. All water samples were collected with a bathometer and passed through Whatman GF/F filters. Recent sediments (0-10 cm) were collected with a core sampler and divided into sub-samples (0-1, 1-5 and 5-10 cm). The pigments were determined using HPLC-DAD. The results were first correlated with a set of parameters measured in situ during sample collection (salinity, temperature, oxygen content of seawater) and determined in the same material (organic carbon content, granulometry), then worked up statistically. Although this investigation shows that particular chloropigments a in recent sediments are indicative of the prevailing environmental conditions in the study area and the trends in their variations, they should be treated as a relative and not an absolute measure, since this is the first such study based on a large and coherent set containing both chloropigment a and environmental data. In addition, a chlorophyll a budget is estimated for the Gulf of Gdańsk on the basis of the literature and the authors' own data. Only c. 10% of the chlorophyll a produced annually in the Gulf of Gdańsk is transferred to sediments in the form of chloropigments a; 2.8% is in the form of undecomposed chlorophyll a and 7.2% in the form of chlorophyll a derivatives. About 90% of chlorophyll a is decomposed to colourless products.     

Measurements of biomarker levels in flounder (Platichthys flesus) and blue mussel (Mytilus trossulus) from the Gulf of Gdańsk (southern Baltic)

In the framework of the EU funded BEEP project a set of biomarkers, gross morphometric indices and tissue concentrations of selected organic pollutants were measured in flounder (Platichthys flesus) and mussels (Mytilus trossulus) collected twice a year (April and October) from three sites in the inner Gulf of Gdańsk between autumn 2001 and spring 2003. In flounder, seasonal differences in most biomarkers were observed, but no correlations with tissue pollutant levels could be found. In mussels, highly variable levels in biomarker responses were seen, but no clear seasonal or spatial trends, directly related to tissue concentrations, could be established. The observed biomarkers distribution the study sites are probably mostly caused by interannual, seasonal and individual variability and, in case of flounder, possibly by exchange of stocks between the sampling sites.     

Floods and floodplain changes of the River Morava,the Strážnické Pomoraví region (Czech Republic) over the past 130 years

Abstract

The development of the River Morava floodplain has been influenced by several natural and anthropogenic factors. This paper focuses on variations in flood activity and channel changes of the River Morava in the region of Strá?nické Pomoraví (southeastern Czech Republic). Floods are analysed in terms of measured peak water stages, H_k (Rohatec, 1886–1920) and peak discharges Q_k (Rohatec/Strá?nice, 1921–2010) evaluated with respect to their N-year return period (H _N or Q_N ). The frequency of floods with Q_k ≥ Q ₂ reaches a significant maximum in March, followed by July. According to flood series compiled from 1881 onwards, their frequency peaked in the 1961–1970 decade with the most severe events occurring in July 1997 (Q ₁₀₀), March 2006 and June 2010 (Q ₅₀). During the study period the natural dynamics of the original anabranching channel patterns were significantly modified by human intervention, such as the abandonment of some anabranching channels, channel straightening, enlargement of the main channel, flood-dike construction, and the creation of the Ba?a shipping channel. These changes resulted in decreased frequency and a reduction in the extent of floodplain inundations compared to the period prior to channel modifications in the 1930s.

Citation Brázdil, R., Má?ka, Z., ?ezní?ková, L., Soukalová, E., Dobrovolný, P. & Matys Grygar, T. (2011) Floods and floodplain changes of the River Morava, the Strá?nické Pomoraví region (Czech Republic) over the past 130 years. Hydrol. Sci. J. 56(7), 1166–1185.     

United States Quaternary coastal sequences and molluscan racemization geochronology – What have they meant for each other over the past 45 years?

The field of amino acid racemization (AAR) geochronology had its beginnings in the 1960's with the analysis of Quaternary mollusks of known relative age from United States Atlantic coast sites. Subsequent AAR studies of sites from Florida, California and then the entire western and eastern coasts of the U.S. have documented two important concepts: 1) in both uplifted marine terrace and subsurface sections, it can be demonstrated that D/L values increase with increasing geologic age; 2) D/L values in samples of equal age increase with decreasing latitude (increasing temperature). These two north–south coastlines with broad latitude ranges (Pacific sites span more than 20°, Atlantic sites more than 15°) provide an ideal, rare framework to test these principles, and the contrast in thermal histories of these two coasts (one maritime, the other more continental) adds additional insights into issues of aminozone correlation over latitude ranges as small as 2°. The trend of D/L values vs. latitude (isochrons) is established using calibrations based primarily on U–Th coral dating, the best of these calibrated trends seen for multiple sites on the Pacific coast. Pacific coast isochrons follow smooth trends and have been used to create and evaluate kinetic models using the modern latitudinal temperature gradient for comparison. Atlantic coast isochrons are more difficult to reconcile with the modern temperature gradient and available U–Th coral ages, suggesting either complex effective temperatures or unknown diagenetic effects on the AAR results. In addition to these studies that used local or regional field studies to test and evaluate AAR methods, relative or numerical ages based on AAR studies on both coasts have contributed to research on coastal uplift or subsidence rates, coastal stratigraphy and sea-level history, age mixing, and diagenesis of carbonate fossils.     

Deep water gravity core from the Marsili Basin (Tyrrhenian Sea) records Pleistocenic–Holocenic explosive events and instability of the Aeolian Archipelago, (Italy)

A 4.8 m long gravity core was recovered on a relative topographic high in the northern part of the Marsili Basin (southern Tyrrhenian Sea) at a water depth of 3200 m. The core was taken in order to decipher the sedimentary record of the past volcanic events of the nearby Aeolian arc. A succession of thin (2 cm to 5 cm thick) fine-grained turbidites, mainly of volcaniclastic origin, topped by hemipelagic mud layers and a number of primary tephra layers were recovered by the core. The most prominent turbidite occurs in the lower part of the core at 385 cm. It consists of a 20 cm-thick, thinning-upward, pebble to sand-sized bed.     

Seasonal and inter-annual variability in alkalinity in Liverpool Bay (53.5° N, 3.5° W) and in major river inputs to the North Sea

A critical factor controlling changes in the acidity of coastal waters is the alkalinity of the water. Concentrations of alkalinity are determined by supply from rivers and by in situ processes such as biological production and denitrification. A 2-year study based on 15 cruises in Liverpool Bay followed the seasonal cycles of changing concentrations of total alkalinity (TA) and total dissolved inorganic carbon (DIC) in relation to changes caused by the annual cycle of biological production during the mixing of river water into the Bay. Consistent annual cycles in concentrations of nutrients, TA and DIC were observed in both years. At a salinity of 31.5, the locus of primary production during the spring bloom, concentrations of NO _x decreased by 25 ± 4 μmol kg⁻¹ and DIC by 106 ± 16 μmol kg⁻¹. Observed changes in TA were consistent with the uptake of protons during primary biological production. Concentrations of TA increased by 33 ± 8 μmol kg⁻¹ (2009) and 33 ± 15 μmol kg⁻¹ (2010). The impact of changes in organic matter on the measured TA appears likely to be small in this area. Thomas et al. (2009) suggested that denitrification may enhance the CO₂ uptake of the North Sea by 25%, in contrast we find that although denitrification is a significant process in itself, it does not increase concentrations of TA relative to those of DIC and so does not increase buffer capacity and potential uptake of CO₂ into shelf seawaters. For Liverpool Bay historical data suggest that higher concentrations of TA during periods of low flow are likely to contribute in part to the observed change in TA between winter and summer but the appropriate pattern cannot be identified in recent low-frequency river data. On a wider scale, data for the rivers Mersey, Rhine, Elbe and Weser show that patterns of seasonal change in concentrations of TA in river inputs differ between river systems.     

The mesoscale eddies and Kuroshio transport in the western North Pacific east of Taiwan from 8-year (2003–2010) model reanalysis

The relationship between the Kuroshio volume transport east of Taiwan (~24°N) and the impinging mesoscale eddies is investigated using 8-year reanalysis of a primitive equation ocean model that assimilates satellite altimetry and SST data. The mean and fluctuations of the model Kuroshio transport agree well with the available observations. Analysis of model dynamic heights and velocity fields reveals three dominant eddy modes. The first mode describes a large eddy of ~500 km in diameter, centered at ~22° N. The second mode describes a pair of the north–south counter-rotating eddies of?~?400 km in diameter each, centered at 23° and 20° N, respectively. The third mode describes a pair of the east–west counter-rotating eddies of?~?300 km in diameter each, centered at 21° N. The associated velocity fields indicate eddies extending to 600–700 m in depth with vertical shears concentrated in the upper 400 m. All three modes and the model Kuroshio transport have similar dominant timescales of 70–150 days and generally are coherent. The decreased Kuroshio volume transports typically are associated with the impinging cyclonic eddies and the increased transports with the anticyclonic eddies. Selected drifter trajectories are presented to illustrate the three eddy modes and their correspondence with the varying Kuroshio transports.     

Poly-aromatic hydrocarbon (PAH) inputs from the Rhône River to the Mediterranean Sea in relation with the hydrological cycle: impact of floods

The concentrations of dissolved and particulate polycyclic aromatic hydrocarbons (PAHs) were monitored in waters of the Rhône River (France) every fortnight for a full calendar year, from June 1994 to May 1995. All flood events occurring over the course of the experiment were sampled at higher frequency to better quantify the impact of these extreme hydrological episodes on the annual export of PAHs to the Mediterranean Sea. This time-series indicates that more than 90% of the annual load of particulate PAHs is transported during flood episodes, with 77% discharged during the course of only one extreme flood event occurring in November 1994. During these intense events, riverine particles are depleted in PAHs while at low river discharge particles are PAH-enriched. Dissolved PAHs were less variable and less abundant than adsorbed PAHs, consistently with the low solubility of these compounds.     

Time-Domain Moment Tensors for shallow (h ≤ 40 km) earthquakes in the broader Aegean Sea for the years 2006 and 2007: The database of the Aristotle University of Thessaloniki

We present a catalog of moment tensor (MT) solutions and moment magnitudes, M_w, for 119 shallow (h ≤ 40 km) earthquakes in Greece and its surrounding lands (34°N–42°N, 19°E–30°E) for the years 2006 and 2007, computed with the 1D Time-Domain Moment Tensor inversion method (TDMT_INV code of Dreger, 2003). Magnitudes range from 3.2 ≤ M_w ≤ 5.7. Green's functions (GF) have been pre-computed to build a library, for a number of velocity profiles applicable to the broader Aegean Sea region, to be used in the inversion of observed broad band waveforms (10–50 s). All MT solutions are the outcome of a long series of tests of different reported source locations and hypocenter depths. Quality factors have been assigned to each MT solution based on the number of stations used in the inversion and the goodness of fit between observed and synthetic waveforms. In general, the focal mechanisms are compatible with previous knowledge on the seismotectonics of the Aegean area. The new data provide evidence for strike-slip faulting along NW–SE trending structures at the lower part of Axios basin, close to the heavily industrialized, and presently subsiding, region of the city of Thessaloniki. Normal faulting along E–W trending planes is observed at the Strimon basin, and in Orfanou Gulf in northern Greece. A sequence of events in the east Aegean Sea close to the coastline with western Anatolia sheds light on an active structure bounding the north coastline of Psara–Chios Islands about 20–25 km in length exhibiting right lateral strike-slip faulting.