On the interest and the limits of using combined ESR/U-series model in the case of very late uranium uptake

Before ESR/U-series models were applied to ungulate teeth, it is generally assumed that calculated ages are close to the “real” ages when they range between the values obtained with the EU and LU models. When the samples show signs of uranium-leaching, a realistic mathematical modelling of the age is not possible. On the other hand, some samples have undergone a very late U-uptake “affecting” directly the U-series ages and rendering the calculated ages younger.

We present results obtained on two open-air sites, which show the limits of such combined models in the case of late uranium incorporation. For the Middle Pleistocene site of Isernia la Pineta (Italy), the ESR dates are expected to fall within the limits imposed by the Ar–Ar results. The other site, the Lower Palaeolithic deposits of Ambrona (Spain), yielded two sets of samples: some at the top of the sequence with uranium uptake ranging between EU and LU limits and thus giving a good idea of the “real” age of the site; others at the base displaying a very late U-uptake, which render an age determination difficult.     

Investigating the effect of diagenesis on ESR dating of Middle Stone Age tooth samples from the open-air site of Lovedale,Free State,South Africa

Teeth are usually targeted for dating archaeological sites because they are less prone to dissolution, in comparison with bones. However, despite this apparent resistance, teeth do undergo diagenesis, which needs to be accounted for in order to obtain accurate ages. In particular, the uptake of trace elements such as uranium in dental tissues needs to be considered for dose rate determination when dated using electron spin resonance (ESR). Characterising the mineralogy and structural integrity of samples prior to dating may thus provide important information related to their state of preservation, especially in the case of teeth whose U content can significantly affect the dose rate.In this study, we dated five teeth of small-sized bovids using combined ESR/U-series dating. They were collected at the Middle Stone Age site of Lovedale, located in the central interior of South Africa. Micromorphology provided sedimentary context to the samples, which were recovered from a layer of gravel rich in faunal remains. Using cathodoluminescence, laser-induced fluorescence, Fourier transform infrared spectroscopy and Raman micro-spectroscopy we assessed the degree of preservation of the enamel. Results reveal that carbonate hydroxyapatite underwent post-depositional alteration, based on its molecular structure and elemental composition. Although the teeth all originate from the same layer and were sampled in the same 1-m square and at a similar elevation, U-content in the enamel differs highly from one tooth to the other, with values ranging from 1.7 to 29.6 ppm. These values are correlated with equivalent doses (D_e) from 228 to 923 Gy and are consistent with variations in crystallinity determined with vibrational spectroscopy. We also investigated the possible saturation of the ESR signal, by repeating measurements with microwave power values from 1 to 20 mW.Despite such diversity in U-content, the ages calculated assuming an early uptake of U all fall within the same range, from 63 ± 8 ka to 68 ± 15 ka and may only represent a minimum estimate.     

Effect of deposit alterations on the dating of herbivorous teeth from Arago cave by the ESR–U-series method

Geochemical alteration processes in archaeological sites may affect the environmental dose rate during the burial history and cause inaccuracy in age determination by palaeodosimetric dating methods, such as luminescence or ESR. In Arago Cave (Tautavel, France), the original composition of the sandy aeolian sediments of palaeoanthropological level G, where the Homo heidelbergensis Arago XXI skull was found, has been modified by both carbonation and phosphatization processes. Eight fossil teeth were collected from different geochemically affected parts of level G and analyzed by the ESR–U-series method. All the teeth are presumably contemporaneous. The results show that the samples from the phosphated area agree within error with those from the carbonated area. Surprisingly, the samples from the non-altered area show ages 100–150 ka younger. This difference is mainly due to the remarkable changes in the gamma dose rate over time. The measured in situ dose rate accounts for more than 50% of the total dose rate for all the samples. We observed that the samples' equivalent dose (D_E) were generally 20% lower in the non-altered area than in the carbonated and phosphated ones. These results show the crucial effect of the geochemical processes affecting the age calculation by ESR–U-series method in comparison with independent chronological data.     

ESR/U-series dating of Eemian human occupations of Northern France

Palaeolithic sites associated with the Eemian Interglacial (MIS 5e) are very rare in NW Europe, and especially in Northern France, where their preservation is restricted to very specific geological contexts, in association with carbonated tufa (Caours) or peat deposits (Waziers). In order to check the reliability of ESR/U-series method to date teeth recovered from archaeological levels in such specific geological environments, teeth were sampled on these two Middle Palaeolithic sites and systematic in situ dosimetry was performed using portable gamma spectrometer. The ESR/U-series ages obtained on the Caours site are very homogeneous allowing the calculation of a mean age equal to 125 ± 11 ka, in agreement with the geological age, mammal's association and other available geochronological data (U-series on tufa carbonate, TL on burnt flints, OSL on sediments), despite a relatively heterogeneous dosimetric environment (gamma dose rate ranging between ca 200–450 μGy/a). At Waziers, reducing (water logging) environment linked to the peat leads to very specific U-series data of the analysed teeth (U content lower than 0.1 ppm in all the dental tissues, evidence of leaching in some tissues), but the mean ESR/U-series age, 129 ± 4 ka, is also in agreement with the available geological and palaeoenvironmental data indicating that the dated teeth were associated with Late Glacial deposits prior to the climatic interglacial optimum. These two case studies then confirm the reliability of ESR/U-series method to date with good reliability and accuracy the archaeological levels linked to such relatively short climatic events (ca 10 ka).     

Dating results on sedimentary quartz,bones and teeth from the Middle Pleistocene archaeological site of Coudoulous I (Lot,SW France): A comparative study between TT-OSL and ESR/U-series methods

This study presents palaeodosimetric results from the Middle Pleistocene archaeological site of Coudoulous I (Lot, SW France). Nine sedimentary quartz samples (41–60 μm) have been analyzed using a multiple aliquot protocol based on the measurement of the TT-OSL signal. In addition, 7 teeth and 7 bones have been dated by combining the ESR method with U-series analyses. Both methods gave consistent age results allowing correlation of the Early Middle Paleolithic Human occupation of the site to MIS 6 and part of the Lower Paleolithic tools to MIS 7. Beyond the establishment of a radiometric chronology for the Coudoulous I sequence, this study focuses on the information extracted from the intercomparison of the methods. Our data suggest that 1) the TT-OSL signal is stable over at least the last 230 ka (considering the age range of the studied samples), 2) there are not significant problems of incomplete bleaching leading support to the applicability of the TT-OSL technique for sedimentary deposits associated with karstic contexts. This approach highlights the interest of combining luminescence and ESR/U-series methods to discuss the reliability of the dating results.     

Applying a Bayesian approach for refining the chronostratigraphy of the Yumidong site in the Three Gorges region,central China

Yumidong (Corn Cave) is a newly discovered Paleolithic site in the Three Gorges region of central China. Numerous Paleolithic artifacts have been excavated from the sedimentary deposits of the cave in association with faunal remains attributed to the Middle-Late Pleistocene Ailuropoda-Stegodon fauna of southern China. To establish the chronology of the sedimentary sequence (>5 m thick), ¹⁴C dating was applied to bone and charcoal samples (n = 6); the U-series method was used to date in situ precipitated speleothems (n = 12), transported speleothem samples (n = 6) and 18 subsamples of a fossil tooth; and the coupled ESR/U-series method was used to date fossil teeth (n = 6). The derived dates were combined using a hierarchical Bayesian approach to generate a unified chronostratigraphy for the Yumidong sequence. In our Bayesian analyses, the ¹⁴C and coupled ESR/U-series dates were considered to provide direct age estimates for the target layers, while the U-series dates of the in situ precipitated speleothems and fossil tooth were used as minimum age constraints and those of the transported speleothem fragments as maximum age constraints. The Bayesian analyses provided robust time intervals for the archeological layers: L2-Upper (14–23 ka), L2-Lower (27–63 ka), L3 (106–171 ka), L4 (140–192 ka), L10 (157–229 ka), L11 (181–256 ka), and L12 (214–274 ka) with a probability of 95%, allowing the establishment of a ∼300 ka long geological and archeological history for the Yumidong site and placing it as a reference site for Paleolithic cultural evolution in the Three Gorges region from the late Middle Pleistocene to Late Pleistocene.     

New ESR/U-series dates of the lowest Acheuleo-Yabrudian levels of Qesem cave

Qesem cave is a Middle Pleistocene site located close to Tel Aviv, Israel, assigned to the Acheuleo-Yabrudian Cultural Complex (AYCC) of the Lower Palaeolithic. The site provides rich assemblages of knapped flint, animal remains and some human teeth making it of particular interest. Its location in the Levantine corridor confers a major interest to the understanding of human dynamics during the Middle Pleistocene.A series of 6 herbivorous teeth from the base of the 11 m archaeological sequence of AYCC Qesem Cave was analysed by combined ESR/U-series method; this complements previous dating series carried out on teeth and on heated flints on higher parts of the sequence (Mercier et al., 2013; Falguères et al., 2016) The teeth were measured according a regular protocol for which each tissue was analysed by inductively coupled plasma-quadrupole mass spectrometry (ICP-Q-MS) for U-series using a combination of a Thermo iCAP-RQ mass spectrometer coupled to a Cetac Aridus III desolvator system, and ESR analyses were implemented on enamel tissue. All these data were combined in order to yield modelled ages.The goal was to find out whether there was a time gap between the carbonates layers dated to 420 ka (Gopher et al., 2010) and archaeological layers of the AYCC found throughout the cave's sequence. The new results yield ages ranging between 220 and 430 ka confirming a great antiquity and a long duration of AYCC in the Levant.     

Optical dating of flowstone and silty carbonate-rich sediments from Panxian Dadong Cave,Guizhou, southwestern China

Panxian Dadong Cave located in the western Guizhou is a very important Paleolithic site in China. At this site bone and stone artifacts, human teeth and mammalian fossils (known as Ailuropoda-Stegodon fauna) were found, and the site was previously dated to 120–300 ka using ESR/uranium-series methods. In this study, we successfully extracted fine quartz grains from flowstone and silty carbonate-rich sediments in the excavated area. The quartz extracts displayed excellent luminescence properties, and satisfied the SAR (single-aliquot regenerative dose method) acceptance criteria. The sensitivity-corrected OSL signals are not saturated at a dose up to about 1400 Gy. The cultural unit was OSL dated to 190–300 ka, corresponding to MISs 7–8. The flowstone deposits overlying the cultural unit were determined to be 13–190 ka and the silty carbonate-rich sediments underlying the cultural unit to be 300–360 ka. The optical ages are in general agreement with the coupled ESR/U-series and U-series ages.     

ESR/U-series dating of faunal remains from the paleoanthropological site of Biache-Saint-Vaast (Pas-de-Calais,France)

Discovered accidently during factory building construction works, the Middle Palaeolithic site of Biache-Saint-Vaast (Pas-de-Calais, France) was excavated from 1976 to 1982 by a team of Lille University directed by Alain Tuffreau. An abundant archaeological and paleontological material, including two human skulls, was there recovered from fossil alluvial deposits of the Scarpe River. In order to determine the ages of these remains, the ESR/U-series method was applied on bone and teeth. As the U-series data obtained of the main part of the analyzed tissues do not allow the use of the classical US-ESR model, the recently proposed AU-ESR model, taking into account if necessary U-leaching from some of the tissues, was used to calculate combined ESR/U-series ages for these samples. The obtained ages suggest a MIS7 attribution to the faunal remains and permit an age of ca 240 ka to be assigned for the human remains and associated archaeological material, in accordance with the stratigraphic data and the large mammal associations.     

Age of the oldest hominin settlements in Spain: Contribution of the combined U-series/ESR dating method applied to fossil teeth

This paper presents a synthesis of the combined Uranium-Series/ESR age results obtained on fossil teeth from several Early Pleistocene archaeological and/or palaeontological Spanish localities: Atapuerca Gran Dolina TD-6, Fuente Nueva-3, Barranco León, Venta Micena and Vallparadís. While the age results show some scattering, they are nevertheless encouraging and provide a significant contribution to the understanding of the first hominin settlements in Western Europe.These “old” samples are mainly characterised by high ²³⁰Th/²³⁴U activity ratios that may sometimes exceed secular equilibrium, and by high Uranium concentrations (several tens of ppm or more). The modelling of U-uptake is therefore really crucial for the age calculation process. In the case of the combined US–ESR approach, this uptake is derived from the U-series data measured in dental tissues, which seem to be strongly dependant on the hydro-geological context. Consequently, when dating “old” samples, a special attention has to be paid to the accuracy and the meaning of the U-series data collected from the dental tissues, which may be influenced by several factors such as spatial heterogeneity and recent U-uptake overprint. Some rapid scanning procedures should be developed in order to pre-identify the samples that are the most suitable for ESR dating.     

40Ar/39Ar and ESR/U-series dates for Guado San Nicola,Middle Pleistocene key site at the Lower/Middle Palaeolithic transition in Italy

The Middle Pleistocene archaeological site of Guado San Nicola was discovered in 2005 in a fossil fluvial terrace of the Volturno River, close to the village of Monteroduni, Molise, Italy. Palaeontological remains and lithic artefacts, including both handaxes and Levallois, discoid and opportunistic debitage, were recovered in fluvial and slope sediments rich in volcanoclastic materials. This site includes four distinct human occupation levels. In two of them both “shaping-façonnage” and “knapping-débitage” technologies are highlighted, placing this site at the Lower/Middle Palaeolithic transition.In the present study, geochronological analyses by ⁴⁰Ar/³⁹Ar on single-crystal and ESR/U-series on teeth were performed to precise the chronological framework of the occupations. The ⁴⁰Ar/³⁹Ar data obtained securely bracket the human occupation levels at the transition between the interglacial and glacial marine isotopic stages MIS 11 (i.e. 400 ± 9 ka) and MIS 10 (i.e. 345 ± 9ka). The weighted mean age obtained from ESR/U-series dating of six teeth (i.e. 364 ± 36 ka) is in very good agreement with the ⁴⁰Ar/³⁹Ar results. The radio-isotopic constraints we presented place the Guado San Nicola site as one of the earliest testimonies of Levallois debitage in Western Europe and confirm the potential and accuracy of paleo-dosimetric methods to date Middle Pleistocene sites.     

Contribution of ESR/U-series dating to the chronology of late Middle Palaeolithic sites in the middle Rhône valley,southeastern France

The establishment of a chronology for late Middle Palaeolithic sites on the right bank of the Rhône valley in southeastern France is important for the knowledge of Neandertal dynamics and their demise in this area. The suite of dating methods that are directly applicable to fossils is limited for this period, especially around 50 ka where radiocarbon dating is beyond its technical limits. Currently applied to Middle and Lower Pleistocene periods, the use of combined ESR/U-series dating on Upper Pleistocene samples led to new issues, such as the acquisition of an age for samples yielding low equivalent doses and low uranium content in dental tissues. The gamma dose rate measurement thus plays a key role in age calculation. Beyond the discussion on methodological issues, the present study contributes to the establishment of a chronological framework that covers the Neandertal occupations between MIS 5 and MIS 3 for this area.     

ESR chronology of the Somme River Terrace system and first human settlements in Northern France

The Somme Valley, Northern France, is famous for its archaeological sequence, where numerous rich Palaeolithic sites, such as Saint-Acheul, the type site of the Acheulian, have been discovered. The archaeological levels are often directly associated with fossil alluvial sediments of the River Somme or with slope deposits, including loess and palaeosols. In the middle reaches of the valley, near Amiens, the system of fossil-stepped fluvial terraces is particularly well developed and preserved, and occurs on 10 alluvial formations. These terraces, from +5 to +55 m above the present-day valley bedrock, allow the study of the environmental changes and the human settlement of this area through the Pleistocene.

Since 1988, ESR dating was systematically applied on bleached quartz extracted from the fossil fluvial deposits, in order to better describe the geological evolution of the stepped system. More recently, U-series/ESR dating has also been performed on teeth collected from the different terrace deposits. Here we present a synthetic review of the main ESR results, and propose an ESR chronology for the geological evolution of the Somme fluvial system and for the Middle Pleistocene human settlement of northern France.     

Radiometric dating of Meipu hominin site in China by coupled ESR/U-series and cosmogenic 26Al/10Be burial dating methods

The Three Gorges and Western Hubei area in the geographic central part of China was a potential migration corridor for early hominin and mammals linking South and North China during the Pleistocene period. Some key early hominin sites are known in this region where limestone cave and fissure sites are numerous but difficult to date as beyond the dating range of OSL and mass spectrometry U-series method. Here, we report radiometric dating study for such a hominin site, Meipu (Hubei Province), by coupled ESR and U-series dating of nine fossil teeth and cosmogenic ²⁶Al/¹⁰Be burial dating of one quartz sediment. The burial age calculated by simple burial model (573 ± 266 ka) gives a minimum age constraint of the sediment. The fossil dating provided two main age groups at 541 ± 48 ka and 849 ± 39 ka, the older age group is in agreement with the U-series age (>630 ka) of the flowstone overlying the fossil layer and the paleomagnetic data which placed the Brunhes-Matuyama boundary in the fossil layer. The reason of this age difference is probably caused by the U-content discrepancy in the enamel of the dated fossil samples. This study exhibits the limitation of ESR/U-series fossil dating and the importance of using multiple dating approach when it is possible in order to identify the problematic ages.     

Radiometric dates for the Middle Palaeolithic sequence of Payre (Ardèche, France)

The archaeological site of Payre (France) yielded Middle Palaeolithic layers with Neanderthal remains, which are partly bracketed by two stalagmitic flowstones. To obtain a precise chronological framework for the human occupation and the faunal remains of this site, several dating methods were used: uranium-series (U-series by alpha spectrometry and TIMS) and electron spin resonance (ESR) on stalagmitic flowstones, combined ESR/U-series on teeth and bones, and thermoluminescence (TL) on burnt flints. Most of the ages obtained for levels H to C range from 300 to 140 ka. The age-spread obtained for the anthropic (burnt flints) and faunal remains (bones and teeth) suggests that the dated levels represent several human occupation periods, near the transition from MIS8 to MIS7 (levels G–F) and from MIS6 to MIS5 (levels D–E).     

Chronology of the Upper Pleistocene loess sequence of Havrincourt (France) and associated Palaeolithic occupations: A Bayesian approach from pedostratigraphy,OSL, radiocarbon,TL and ESR/U-series data

In connection with the future Seine-North Europe Canal (Seine-Scheldt), a large-scale rescue archaeological survey was conducted at Havrincourt (northern France) between 2008 and 2011. The discovery of several levels of Palaeolithic flint artefacts embedded in a relatively thick loess sequence (ca 6–7 m) preserved on a gentle slope facing North-East, resulted in a 6000 m² excavation. This opened the opportunity for a detailed pedosedimentary and interdisciplinary geochronological survey (¹⁴C, optically stimulated luminescence, thermoluminescence, ESR/U-series) that has allowed us date the sequence reliably. On the basis of these results we propose this sequence as a new pedostratigraphic and archaeological reference sequence for northern France. We present here the optical dating of the sequence performed on fine (4–11 μm) quartz grains extracted from 17 samples. The luminescence characteristics of these extracts indicate that the single-aliquot regenerative dose optically stimulated luminescence (SAR-OSL) procedure that was applied is well suited. A consistent set of optical ages was obtained for the loess deposited up to around 70 ka ago. Independent age control (pedostratigraphy, ¹⁴C, ESR/U-series dates) allowed us to apply a Bayesian approach to build a chronometric model. This in turn enabled a regional chronostratigraphic framework to be built, to constrain the correlations with neighboring regions (northern France and Belgium) and to calculate a precise age for the four Palaeolithic levels discovered, including a unique occupation related to the early Upper Palaeolithic which was previously unknown in the area.     

ESR/U-series chronology of the Neanderthal occupation layers at Galería de las Estatuas (Sierra de Atapuerca,Spain)

The Galería de las Estatuas is a Mousterian site located within the Cueva Mayor-Cueva del Silo karstic system at the Sierra de Atapuerca (Burgos, Spain). This site is characterised by an important Upper Pleistocene stratigraphic sequence in which a large number of lithic artefacts exhibiting clear Mousterian affinities and a rich assemblage of faunal remains have been found.Additionally, this site has yielded a foot phalanx of a clear Neanderthal affinities and its sediment has yielded Neanderthal mitochondrial and nuclear DNA.Two test pits, GE-I and GE-II, have been excavated since 2008 which have been divided in 5 and 2 lithostratigraphical units, respectively. A minimum age of 45 ka cal BP for this site was obtained by radiocarbon dating in GE-II. This chronology was refined using single-grain Optically Stimulated Luminescence (OSL: 80–112 ka in GE-I and 70–79 ka in GE-II) and single-grain thermally transferred OSL (TT-OSL). Although in all case TT-OSL ages were systematically older than their single-grain counterparts. The detrital sequence is sealed by a flowstone whose base is dated to 53.7 ± 3.5 ka cal BP using U-series dating.In order to better constrain the age of this site, nine herbivorous teeth were collected from the whole sedimentary sequence to be dated by the ESR/U-series dating method though only seven provided modelled ages. Six of them were collected from levels 2 to 5 of the GE-I test pit while the last tooth was taken from level 2 of the GE-II test pit. Our results, ranging between 80 and 110 ka, are in agreement with those obtained by single grain TT-OSL and suggest that the sedimentological levels containing Mousterian lithic artefacts and faunal and human remains began to be deposited during the second part of the MIS5. These results fill a temporal gap in the chronology of the Atapuerca sites for which no contemporary MIS5 date was obtained until recently.     

U-series,ESR and 14C studies of the fossil remains from the Mousterian levels of Zafarraya Cave (Spain): A revised chronology of Neandertal presence

Zafarraya Cave is considered a reference site for the last presence of Homo neanderthalensis presence in the south of the Iberian Peninsula. In this paper, accelerator mass spectrometry (AMS) radiocarbon dates were carried out on charcoals and faunal remains, U–Th dating using either alpha spectrometry or Thermal-Ionization Mass Spectrometry (TIMS) and ESR dating were performed on faunal remains. These analyses were carried out on samples from the Mousterian levels of the site (archaeostratigraphic units UC, UD, UE, UF, UG). The ¹⁴C AMS dates of charcoal samples (n = 11) were scattered and displayed no coherence with the stratigraphy suggesting possible alteration. The delicate charcoal and faunal samples underwent the gentle RR, ZR (ABA) or AG (ABA) pretreatment procedures at ORAU. The RR protocol is currently considered too gentle and the results are considered with caution. Four ZR charcoal pretreatments failed due to the fact that the charcoal samples were altered. Only two charcoals samples subjected to the ZR pretreatment yielded a reliable % C (>60%) (OxA-9001 and OxA-9002, 40,294–42,761 and 38,763–40,604 cal BP). Their ages are consistent with the stratigraphy and are considered to provide the best age estimate for the level bearing the Z2 Neandertal mandible (Unit UE). For the dentine and the bone samples, the ¹⁴C AMS were less dispersed. ¹⁴C analyses failed for four bone samples due to insufficient collagen content. Moreover, the %C is very low for two samples, suggesting alteration of the fossil remains at Zafarraya. Only two other samples with enough %C (>30%) were retained: OxA-8024 and OxA-8999 (Unit UE). The respective ¹⁴C ages range from ∼34 to 39 ka cal BP. The U/Th (TIMS) analyses of enamel samples displayed an extremely low uranium content (< ∼ 0.02–0.04 ppm). Moreover, the U/Th age range of faunal remains is large, thus providing no conclusive results. ESR dating was chosen for this exercise as, in combination with U-series, it can be used to assess U-uptake in open systems. The combined ESR and U/Th (TIMS) age estimates on tooth enamel yielded US-ESR ages between 33 (+3/−4) ka to 43 ± 3 ka (MIS3) for two Equus teeth and one Capra tooth in unit UE, overlapping with the oldest charcoal and bone ¹⁴C dates. The age of the Zafarraya fossil remains was derived from the US-ESR time range of 30–46 ka (MIS 3). We consider this age range to be more representative of the Neandertal occupations at the site than the hitherto widely cited uncalibrated ¹⁴C age of around 30 ka.     

ESR/U-series dating of teeth recovered from well-stratigraphically age-controlled sequences from Northern France

During the last two decades, extensive road-construction works in Northern France have allowed the discovery of numerous Middle Palaeolithic sites. Geological and multidisciplinary studies performed on these localities allowed the establishment of a precise chronostratigraphical and biostratigraphical framework of regional significance, which could be correlated to the global marine palaeoclimatic scale. Each human occupation layer has been linked to this regional framework, thus providing a stratigraphical age-control for the Middle Palaeolithic human settlements of this area.At the same time, a program of geochronological studies was developed using TL, OSL, U-series, ESR and, as often as possible, ESR/U-series methods. Hence, bones and teeth recovered from archaeological sites of Savy, Ault, Caours, Gentelles and La Celle-sur-Seine, were analyzed and the results compared to the chronostratigraphical ages. The age results are generally in good agreement with the geological data while bones and dental tissues display in some cases U-series ages higher that the EU-ESR ones, suggesting U-loss phenomena.     

ESR dating in Song Terus cave (East Java, Indonesia)

Electron spin resonance (ESR) dating on teeth has been used to determine the antiquity of the human presence in the area of Gunung Sewu (East Java, Indonesia). The Song Terus cave is one of the archaeological sites located in this area, which has yielded an important collection of fossil bones and prehistoric lithic industry. ESR dating shows that this cave belongs to a karstic system which has been in place since Middle Pleistocene. The results of coupled ESR/Uranium-series dating indicates closed system for uranium in tooth tissues yielding ages of between 216 and 392 ka for the oldest archaeological levels, confirming the possibility of finding Middle Pleistocene human occupations in such karstic sites in Java.