Validating post IR-IRSL dating on K-feldspars through comparison with quartz OSL ages

Recent developments have opened up the possibilities of using potassium feldspar for dating Pleistocene sediments; a stable (less-fading) part of the infrared stimulated luminescence (IRSL) signal can be selected by largely depleting the unstable part of the IR signal, using a combination of thermal and IR stimulation: post IR-IRSL dating (pIR-IRSL).This study aims to test the validity of pIR-IRSL dating on feldspars. We obtained pIR-IRSL ages on a large suite of samples from several locations in the Netherlands area, covering a wide range of depositional environments and ages. Age control was provided by quartz optically stimulated luminescence (OSL) ages on the same samples; these ages were shown to accord with geological age constraints. Comparison with IRSL ages enabled us to evaluate the improvement that pIR-IRSL dating provides over conventional IRSL methods.The majority of feldspar ages obtained with pIR-IRSL showed good agreement with both the quartz OSL ages and the geological age constraints. Our study demonstrates that pIR-IRSL dating is more robust than conventional IRSL and should be the method of choice in feldspar luminescence dating of Pleistocene sediments.     

Optically stimulated luminescence dating of young (<500 years old) sediments: Testing estimates of burial dose

The reliability of single-grain optically stimulated luminescence (OSL) dating of young (<500 years old) samples is assessed by examining the results of 166 single-grain OSL analyses of Australian alluvial, lacustrine, estuarine, coastal and marine sediment samples. All samples have been analysed using the modified SAR protocol of Olley et al. [2004b. Optical dating of Holocene sediments from a variety of geomorphic settings using single grains of quartz. Geomorphology 60, 337–358], with burial doses (D_b) calculated by fitting a single Gaussian curve to the peak of a multi-Gaussian summed probability distribution (PDF_Gaussian). The near-equivalence of this approach to currently accepted methods of palaeodose estimation – namely the minimum age and central age models of Galbraith et al. [1999. Optical dating of single and multiple grains of quartz from Jinmium rock shelter, northern Australia: part I, experimental design and statistical models. Archaeometry 41, 339–364] – is demonstrated. Considered as a whole, OSL ages calculated using the PDF_Gaussian D_b determination method are consistent with other chronometric, geomorphological, botanical and historical indicators of depositional age, while four alternative (previously published) methods are generally less reliable when applied to the samples analysed here. The single-grain data from 12 samples of known age (reported by Olley et al. [2004b. Optical dating of Holocene sediments from a variety of geomorphic settings using single grains of quartz. Geomorphology 60, 337–358]) are re-analysed using the PDF_Gaussian approach, with all but one yielding a D_b consistent with the independently known age. Examples of luminescence data (dose recovery tests, preheat plateaux, continuous-wave and linear-modulated OSL, growth curves, single-grain dose distributions) are provided that together indicate the suitability of Australian quartz for dating young sediments.     

Evaluating isothermal thermoluminescence and thermally transferred optically stimulated luminescence for dating of Pleistocene sediments in Amazonia

The paleogeography of Amazonia lowlands during the Pleistocene remains hampered by the lack of reliable absolute ages to constrain sediment deposition in the hundred thousand to few million years timescales. Optically stimulated luminescence (OSL) dating applied to quartz has provided important chronological control for late Quaternary sediments, but the method is limited to the last ∼150 ka. In order to extend the age range of luminescence dating, new signals from quartz have been investigated. This study tested the application of isothermal thermoluminescence (ITL) and thermally transferred optically stimulated luminescence (TT-OSL) signals of quartz for dating of fluvial terraces from eastern Amazonia. ITL and TT-OSL signals measured in a modern fluvial sediment sample have shown small residual doses (4 and 16 Gy), suggesting adequate bleached sediments for the target dose range (>150 Gy). This sample responded well to dose recovery test, which showed that the ITL and TT-OSL signals grow to higher doses compared to the doses estimated by the conventional OSL signal. The ITL signal saturated for doses significantly lower than doses reported in the literature. Most dating samples were beyond the ITL saturation doses and only TT-OSL signals were suitable to estimate equivalent doses. Burial ages ranging from 107 to 340 ka were estimated for the fluvial terraces in the lower Xingu River. The main ages uncertainties are related to dose rate changes through time. Despite the uncertainties, these ages should indicate a higher channel base level during the Middle Pleistocene followed by channel incision, possibly due to episodes of increased precipitation in the Xingu watershed.     

OSL and IRSL dating of raised beach sand deposits along the southeastern coast of Norway

Raised beach sand deposits along the southeastern coast of Norway were dated by optical (OSL) and infrared stimulated luminescence (IRSL) and the quartz and K-feldspar luminescence characteristics were described. Due to the poor quartz luminescence characteristics, only a limited number of samples were suitable for OSL dating. More promising are the K-feldspar extracts, with typical K-feldspar luminescence characteristics and no sign of fading. For equivalent dose (D_e) determination, sand-size quartz and feldspar extracts were used, applying a single aliquot regenerative (SAR) protocol. Both, OSL and IRSL D_e estimates show a wide distribution, unexpected for beach deposits. The calculated OSL and IRSL age estimates were generally in good agreement and the correctness of the ages was confirmed by independent age control. Because only a limited number of the quartz samples were suitable for OSL dating, IRSL dating of the K-feldspar represents an alternative to OSL quartz dating.     

Quartz and polymineral luminescence dating of Japanese loess over the last 0.6 Ma: Comparison with an independent chronology

There are only a few luminescence dating studies of loess sediments in Japan, but interleaved with these deposits are many well-described tephras of known age based on ¹⁴C and fission track analysis; these independent age controls provide an opportunity to test the reliability of loess luminescence ages. This study provides such a comparison at two sites in central Honshu, the largest island in the Japanese archipelago. Samples were collected from sequences of interleaved volcanic tephra and loess deposited on a Middle Pleistocene river terrace in the Niigata Prefecture and on an Early to Middle Pleistocene dissected fluvial surface at in the Tochigi Prefecture, Honshu. Equivalent doses (D_e) were estimated from fine grains (4–11 μm) using both polymineral IR-OSL and (post-IR) blue-OSL, and quartz blue-OSL. The blue-stimulated luminescence signals could be represented by up to three exponentially decaying components; only the most light sensitive of these components was used in the final D_e estimation. Almost all the estimates of D_e from polymineral IR-OSL are smaller than those from polymineral (post-IR) blue-OSL and quartz blue-OSL, whereas the latter two are in good agreement. The blue-light stimulated luminescence ages using the most light sensitive component are shown to be in good agreement with the independent control, up to 500 ka. Although the IR-OSL signals underestimate the known age, a simple laboratory fading test is found empirically to correct for this underestimation. We conclude that the most rapidly blue-stimulated luminescence signals from quartz extracted from our loess samples give reliable ages, and that future loess dating studies should concentrate on these signals.     

水成沉积物回授光释光测年可行性初探

通过对滹沱河冲洪积物、阳原盆地湖相地层细颗粒石英天然热转移光释光(TT-OSL)信号测量、回授剂量恢复测试以及简单多片光释光(OSL)与回授光释光(Re-OSL)测量结果对比等,探讨了细颗粒石英回授光释光在水成沉积物测年中应用的可能性。结果表明,冲积样品回授光释光信号没有随深度逐步增加的规律,而湖相样品热转移光释光信号随深度逐渐增大;冲洪积物细颗粒石英样品回授光释光不能得出剂量值,剂量不能恢复;而湖相样品回授实验室附加剂量与测得的剂量在2%的误差范围内一致,说明回授光释光测年在一定时间范围内对于湖相样品测年是可行的;细颗粒石英回授释光在测量>10万a的湖相样品年龄方面具有很大的潜力     

Timing of Holocene lake highstands around Dawa Co in inner Tibetan Plateau: Comparison of quartz and feldspar luminescence dating with radiocarbon age

Lakes over the inner Tibetan Plateau (TP) are very sensitive to the regional environmental transformations and climate changes. Well-preserved lake sediments around these lakes provide critical geomorphological and sedimentary evidence that can be used to infer the past hydroclimate changes. In this study, a lacustrine section from a sandy shoreline (∼74 m above the modern lake) situated to the northwest of modern Dawa Co in the inner TP was investigated using both luminescence and radiocarbon dating methods. Our results demonstrated: (1) the quartz optically simulated luminescence (OSL) dating yielded much younger ages (∼4 ka) than that of the post-infrared IRSL (pIRIR) dating of the K-feldspar fraction; (2) fading test showed g-values ranging between 1.34 and 4.46%/decade for quartz OSL signals, which is considered to be responsible for the underestimation of the corresponding ages; (3) the AMS ¹⁴C age of the charcoal sample from the section is in line with the K-feldspar pIRIR₂₂₅ ages, confirming the reliability of the pIRIR₂₂₅ dates and the underestimation of the quartz OSL ages. The anomalous fading of quartz OSL signals and the consequent age underestimation have been reported in several other lakes on the TP, we presented here for the first time firm evidence of the phenomenon with the help of a robust independent control of AMS ¹⁴C age of the charcoal. Based on the pIRIR₂₂₅ and AMS ¹⁴C ages, we conclude that Dawa Co underwent a prominent highstand during the early Holocene (∼9–7 ka), which was probably controlled by the large amounts of glacial meltwater input and the increased monsoonal precipitation.     

OSL dating of southeast Australian quartz: A preliminary assessment of luminescence characteristics and behaviour

Australian quartz has been widely considered particularly suitable for OSL dating of sediments. We present the results of a preliminary investigation into the luminescence characteristics and behaviour of quartz from various regions and depositional contexts across southeastern Australia. In doing so, we find that quartz from this region is generally well suited to the SAR protocol, although individual sample behaviour should nevertheless be assessed to confirm this. Furthermore, luminescence sensitivity appears to relate to depositional context, with aeolian samples exhibiting the highest sensitivity values, and lacustrine and periglacial sediments the lowest. The extent of a sample's sedimentary history, which in many cases is characteristic of the region from which it is derived, may also influence quartz sensitisation through repeated cycles of burial and reworking.     

Testing the use of feldspars for optical dating of hurricane overwash deposits

The geological record preserved in coastal salt marshes provides an opportunity to determine past hurricane activity during the Late Holocene in New England, USA. High precision dating is important to correlate overwash sand layers associated with hurricane strikes between different sites along the coastline. Three different optical dating methods have been tested and compared with independent age control; i) optically stimulated luminescence from quartz, ii) infrared stimulated luminescence from K-feldspar, and iii) a subtraction method.Quartz and K-feldspar dating results for three samples in a core from Round Hill Beach Marsh are in stratigraphic order and they are consistent within errors with radiocarbon ages and with each other. Subtraction dating results agreed with the quartz and K-feldspar ages for two of the three samples, but the subtraction age of the youngest sample gave an age underestimate. Replicate equivalent dose values from quartz showed a larger variation than those from feldspars, and this resulted in larger errors for the quartz and subtraction ages than those based on feldspars. K-feldspar yields the most precise optical ages, but is complicated by the need to correct for anomalous fading. Both quartz and K-feldspar are suitable for optical dating of hurricane overwash deposits in New England.     

Holocene moist period recorded by the chronostratigraphy of a lake sedimentary sequence from Lake Tangra Yumco on the south Tibetan Plateau

Palaeolimnological studies together with geomorphological investigations of exposed lacustrine sections on the Tibetan Plateau provided valuable palaeoclimate records. Radiocarbon dating is the most commonly used method for establishing chronologies of lake sediments. However, ¹⁴C dating of such sediments could be problematic due to the lack of organic matter or a reservoir effect, which commonly appears in radiocarbon ages of lacustrine sediments from the Tibetan Plateau. OSL dating is an alternative for dating the lake sediments and also provides the opportunity to independently test radiocarbon chronologies. The current study tries to compare OSL and ¹⁴C dating results in order to evaluate the reservoir effect of ¹⁴C dating, and then based on quartz OSL dating and stratigraphic analysis, to construct the chronostratigraphy of a lacustrine sedimentary sequence (TYC section), an offshore profile from Tangra Yumco lake on the southern Tibetan Plateau. Results suggest that: (1) it is possible to obtain robust OSL age estimates for these lake sediments and the OSL ages of the three samples range from ca. 7.6 ka to ca. 2.3 ka; (2) The discrepancy between the OSL and ¹⁴C ages is ca. 4–5 ka, which possibly results from the age overestimate of ¹⁴C dating due to a reservoir effect in the studied lake; (3) the chronostratigraphy of TYC section and sedimentological environmental analysis show a large lake with a lake level distinctively above the present during ca. 7.6–2.7 ka indicating a wet mid-Holocene in the study area.     

The effect of weathering on optically stimulated luminescence dating

Optically stimulated luminescence (OSL) dating was applied to quartz samples recovered from the gravel sediments of deformed marine terrace at the Suryum site, southeastern Korea, but has yielded stratigraphically inconsistent ages. Micromorphological, chemical, and mineralogical analyses of the gravels indicate the possible influence of chemical weathering on the apparent OSL ages. In the course of weathering after emerging from beach environments, originally permeable gravels underwent infilling by halloysite-rich clays in their voids, export and import of radioactive elements, and loss of mechanical strength with the creation of a porosity within pebbles. Calculation based on the evolution of the weathering profile showed a severe fluctuation of dose rate caused by the change of water content and radioactive element concentrations. Samples recovered from the weathering profile inevitably include quartz grains derived from mechanically weakened pebbles or illuviated from the upper layer, making it difficult to determine the equivalent dose (D_e) values of exclusively depositional quartz sands. Quantitative evaluation of the change of fabric and chemistry of the sediments on the basis of pedologic insight significantly aids in the derivation of OSL ages consistent with geomorphology and other independent age controls.     

Testing the application of quartz and feldspar luminescence dating to MIS 5 Japanese marine deposits

The applicability of both quartz and feldspar luminescence dating was tested on twenty-five samples from a marine succession now forming a coastal cliff at Oga Peninsula, Honshu Island, Japan. The quartz optically stimulated luminescence (OSL) signal shows thermal instability and linear modulated (LM)-OSL analysis revealed the dominance of a slow component. When compared with independent age control provided by two marker tephras, the quartz OSL ages grossly underestimate the depositional age. In contrast, potassium (K)-rich feldspar is a suitable dosimeter when measured using post-IR infrared stimulated luminescence (IRSL) at 225 °C (pIRIR₂₂₅). Scanning electron microscope (SEM) analyses on the feldspar extracts revealed that the grains are amorphous with small crystalline inclusions; using standard internal dose rate parameters, this would result in a too large dose rate. Dose rates were calculated using the observed grain size of 40 ± 20 μm with an assumed K concentration of 12.5 ± 0.5%. The fading corrected pIRIR₂₂₅ ages agree well with independent age control, and the sediments of the Katanishi Formation were deposited between 82 ± 6 and 170 ± 16 ka. This study demonstrates that pIRIR dating of feldspar is a powerful chronological tool for the dating of sediments of volcanic origin.     

OSL dating of mixed coastal sediment (Sylt,German Bight,North Sea)

As part of a study on coastal sedimentary processes this paper presents the OSL dating of mixed coastal sediment samples from the southern North Sea island of Sylt (German Bight). During coring of the swash-bar (beach) sediments, five samples were presumably contaminated by younger overwash and aeolian sediments because of the sampling method employed. To obtain reliable burial ages for these swash-bar sediments, single-grain and small aliquot measurements were used together with the Finite Mixture Model (FMM) proposed by Roberts et al. (2000) to identify the grain population containing the largest doses (from the deepest part of the core). Before the FMM was applied to dating, the parameters and performance of the FMM were first investigated by systematically comparing small aliquot (∼20 grains) and single-grain measurements of an undisturbed aeolian and swash-bar sample and a laboratory mixture of both sediments. This test case demonstrates the advantage of selecting the time interval immediately following the initial luminescence signals for background subtraction because unsuitable quartz grains were removed from the dose distribution. It is concluded that the measurement of small aliquots can be regarded as a reliable proxy for single-grain dose distribution if the sediment contains only a small proportion of quartz grains emitting a luminescence signal and that the FMM results are relatively insensitive to changes of the over-dispersion parameter between 5–40% for small aliquots and 10–40% for single-grains.We show that the burial ages of the contaminated swash-bar samples resulting from the maximum age populations from equivalent dose distributions measured using small aliquots are consistent with the stratigraphy and with ages obtained from uncontaminated samples.     

Dating of lower terrace sediments from the Middle Rhine area, Germany

Modern and known-age Pleistocene fluvial sediments were investigated by optical dating of quartz to test the suitability of the approach for dating deposits from the deeply incised Middle Rhine Valley. Samples from modern flood sediments revealed skewed distributions indicating different residual levels of equivalent dose (D_e) within the different aliquots. Nevertheless, a substantial number of aliquots from the modern deposits reflect D_e values close to zero. For the Pleistocene samples, optical ages are in general consistent with age control given by the presence of the Laacher See Tephra and radiocarbon dating. However, some samples overestimate the known age by a few thousand years when using the arithmetic mean. This is apparently explained by including aliquots in the determination of mean D_e where the optical signal was incompletely bleached at deposition. The most difficult issue in this context is identifying a suitable approach that can distinguish between the variability of D_e due to partial bleaching and microdosimetry. However, even when considering these limitations it appears that optical dating will by a quite suitable method to date Pleistocene sediments from such a complex fluvial environment, especially when focusing on a precision scale beyond a few thousand years.     

Testing single-grain quartz OSL methods using sediment samples with independent age control from the Bordes-Fitte rockshelter (Roches d'Abilly site,Central France)

We present quartz single-grain dose distributions for four well-bleached and unmixed sediment samples with independent age control (22–48 ka), from the archaeologically important Bordes-Fitte rockshelter at Roches d'Abilly, France. This site has previously been dated using ¹⁴C AMS dating and standard multi-grain OSL dating using both quartz and feldspar. The effect of rejection criteria usually employed in single-grain dating on dose and over-dispersion is tested using both laboratory irradiated samples and natural samples. It is shown that had these samples been analysed in the absence of other age control, standard modelling decisions based on the shape of single-grain dose distributions would have led to significant misinterpretation of results and a corresponding >40% underestimation in age. If we instead ignore this standard decision process and apply weighted average and mixing models then the most likely results deviate from the expected ages by >10%. Finally, we show that by careful consideration of the luminescence characteristics of individual grains, we are able to obtain good agreement with the independent age control by applying alternative rejection criteria but this is at the cost of reducing the accepted grain population by more than an order of magnitude, with the corresponding inevitable decrease in precision.     

Single grain optical dating of glacigenic deposits

Determining the age of glacigenic sediments is difficult for many geochronological methods because of the lack of suitable materials for analysis. Luminescence dating can be applied to the mineral grains making up the glacigenic sediments. However a major source of uncertainty in previous studies has been whether the mineral grains were exposed to sufficient daylight prior to deposition for the luminescence signal to be reset. Measurements of the optically stimulated luminescence signal from single sand-sized quartz grains offers the potential for explicitly identifying if a sediment contains grains that were not exposed to sufficient daylight to reset their signal. Statistical analysis of the resulting data can then reject those grains to allow the age of the sample to be determined. This study is the first to apply single grain optical dating to glacigenic sediments, and demonstrates the issues involved by analysis of samples from Chile and Scotland. Ages from 2.4±0.5 to 17.3±1.5 ka are produced. Comparison of the results with independent age control suggests that the ages are reliable. The results also show that the extent of bleaching at deposition varies considerably from one sample to another. For the most incompletely bleached sample, luminescence measurements based on the average of many hundreds or thousands of grains would have overestimated the age of the sample by 60 ka, but the single grain method proposed here was able to reliably date it.     

Underestimated ~(14)C-based chronology of late Pleistocene high lake-level events over the Tibetan Plateau and adjacent areas: Evidence from the Qaidam Basin and Tengger Desert

The palaeolake evolution across the Tibetan Plateau and adjacent areas has been extensively studied, but the timing of late Pleistocene lake highstands remains controversial. Robust dating of lacustrine deposits is of importance in resolving this issue. This paper presents 14 C or optically stimulated luminescence(OSL) age estimates from two sets of late Quaternary lacustrine sequences in the Qaidam Basin and Tengger Desert(northeastern Tibetan Plateau). The updated dating results show:(1) the radiocarbon dating technique apparently underestimated the age of the strata of >30 ka BP in Qaidam Basin;(2) although OSL and 14 C dating agreed with each other for Holocene age samples in the Tengger Desert area, there was a significant offset in dating results of sediments older than ~30 ka BP, largely resulting from radiocarbon dating underestimation;(3) both cases imply that most of the published radiocarbon ages(e.g., older than ~30 ka BP) should be treated with caution and perhaps its geological implication should be revaluated; and(4) the high lake events on the Tibetan Plateau and adjacent areas, traditionally assigned to MIS 3a based on 14 C dating, are likely older than ~80 ka based on OSL chronology.     

Luminescence dating of the late Quaternary sediments in Hangzhou Bay,China

Coastal plain of Hangzhou Bay, to the south of the present Yangtze Estuary, is closely linked to the evolution of the Yangtze River delta. However, absolute age of Pre-Holocene sediments is limited, which hinders the understanding of this area's environmental evolution. In this study, using optically stimulated luminescence (OSL), single aliquots and single grains of quartz and K-feldspar were used to date the late Quaternary sediments in coastal plain on the southern Hangzhou Bay. The vertical difference in particle size composition render either silt- or sand-sized quartz for dating. Cross-checking of multiple OSL dating methods indicated that the upper ∼65 m recorded the Holocene part of the succession; sediment from a depth of 136.6 m was dated to ∼180 ka. It was found that the single-grain method was more reliable in comparison to single-aliquot age, the former minimized the effect of signal components. Single-grain quartz and K-feldspar luminescence yielded consistent ages at sample depth of 136.6 m (∼160–180 ka), while the latter gave robust age at depth of 115.5 m (∼150 ka). This chronology is in general in accordance with neighbouring cores and can constrain paleomagnetic dating results in those cores. Taking together, the study site has thickest Holocene deposits in comparison to the highland centered around Taihu Lake on the southern Yangtze delta. Moreover, the luminescence characteristics of quartz from different sample depths, behaved differently with respect to luminescence sensitivity, signal components and saturation level, perhaps reflecting varied provenance and weathering characteristics caused by climate change.     

Rapid age assessment in the Namib Sand Sea using a portable luminescence reader

A rapid assessment of burial age for sedimentary materials is useful to aid in-situ interpretation of sites and sequences during fieldwork. This can assist with targeted field sampling strategies for full dating back in the laboratory, for example when the study is concerned with reconstructing landscape dynamics during a specific time period. Field-based luminescence measurements are possible using a portable luminescence reader; the challenge is translating relative portable luminescence reader signal intensities of samples into an estimate of age. This study uses a portable luminescence reader for the first time in the analysis of African dunefield sediments. Samples from the Namib Sand Sea (NSS) with established luminescence ages are used to assess what in-situ information about relative sample age can be gleamed at and between sites using the portable luminescence reader, and to establish whether first-order estimates of sample age can be obtained. Two sites in the NSS, which are of modern, very late Holocene and last interglacial age were selected for this assessment and a simple calibration between portable luminescence reader signals and sample age is made. Results show that portable luminescence reader signals differ by over two orders of magnitude between late Holocene and last interglacial age samples and that useful relative-age information can be established using bulk material in the field. Predicted ages from portable luminescence reader signals using a linear regression appear to be indicative and useful. Further development of this calibration using a wider range of sample ages would confirm its applicability in the NSS, and a similar approach is applicable to other sand sea environments.