The D/H Ratio in Methane in Titan: Origin and History

We propose a new interpretation of the D/H ratio in CH₄ observed in the atmosphere of Titan. Using a turbulent evolutionary model of the subnebula of Saturn (O. Mousis et al. 2002, Icarus156, 162-175), we show that in contrast to the current scenario, the deuterium enrichment with respect to the solar value observed in Titan cannot have occurred in the subnebula. Instead, we argue that values of the D/H ratio measured in Titan were obtained in the cooling solar nebula by isotopic thermal exchange of hydrogen with CH₃D originating from interstellar methane D-enriched ices that vaporized in the nebula. The rate of the isotopic exchange decreased with temperature and became fully inhibited around 200 K. Methane was subsequently trapped in crystalline ices around 10 AU in the form of clathrate hydrates formed at 60 K, and incorporated into planetesimals that formed the core of Titan. The nitrogen-methane atmosphere was subsequently outgassed from the decomposition of the hydrates (Mousis et al. 2002). By use of a turbulent evolutionary model of the solar nebula (O. Mousis et al. 2000, Icarus148, 513-525), we have reconstructed the entire story of D/H in CH₄, from its high value in the early solar nebula (acquired in the presolar cloud) down to the value measured in Titan's atmosphere today. Considering the two last determinations of the D/H ratio in Titan—D/H=(7.75±2.25)×10⁻⁵ obtained from ground-based observations (Orton 1992, In: Symposium on Titan, ESA SP-338, pp. 81-85), and D/H=(8.75^+3.25_−2.25)×10⁻⁵, obtained from ISO observations (Coustenis et al. 2002, submitted for publication)—we inferred an upper limit of the D/H ratio in methane in the early outer solar nebula of about 3×10⁻⁴. Our approach is consistent with the scenario advocated by several authors in which the atmospheric methane of Titan is continuously replenished from a reservoir of clathrate hydrates of CH₄ at high pressures, located in the interior of Titan. If this scenario is correct, observations of the satellite to be performed by the radar, the imaging system, and other remote sensing instruments aboard the spacecraft of the Cassini-Huygens mission from 2004 to 2008 should reveal local disruptions of the surface and other signatures of the predicted outgassing.     

Interpretation of the carbon abundance in Saturn measured by Cassini

Spectral observations of Saturn from the far infrared spectrometer aboard the Cassini spacecraft [Flasar, F.M., et al., 2005. Temperatures, winds, and composition in the Saturnian system. Science 307, 1247-1251] have revealed that the C/H ratio in the planet is in fact about twice higher than previously derived from ground based observations and in agreement with the C/H value derived from Voyager IRIS by Courtin et al. [1984. The composition of Saturn's atmosphere at northern temperate latitudes from Voyager IRIS spectra - NH₃, PH₃, C₂H₂, C₂H₆, CH₃D, CH₄, and the Saturnian D/H isotopic ratio. Astrophys. J. 287, 899-916]. The implications of this measurement are reanalyzed in the present report on the basis that volatiles observed in cometary atmospheres, namely CO₂, CH₄, NH₃ and H₂S may have been trapped as solids in the feeding zone of the planet. CH₄ and H₂S may have been in the form of clathrate hydrates while CO₂ presumably condensed in the cooling solar nebula. Carbon may also have been incorporated in organics. Conditions of temperature and pressure ease the hydratation of NH₃. Such icy grains were included in planetesimals which subsequently collapsed into the hydrogen envelope of the planet, then resulting in C, N and S enrichments with respect to the solar abundance. Our calculations are consistent, within error bars, with observed elemental abundances on Saturn provided that the carbon trapped in planetesimals was mainly in the form of CH₄ clathrate and CO₂ ice (and maybe as organics) while nitrogen was in the form of NH₃ hydrate. Our approach has implications on the possible pattern of noble gases in Saturn, since we predict that contrary to what is observed in Jupiter, Ar and Kr should be in solar abundance while Xe might be strongly oversolar. The only way to verify this scenario is to send a probe making in situ mass spectrometer measurements. Our scenario also predicts that the ¹⁴N/¹⁵N ratio should be somewhat smaller in Saturn than measured in Jupiter by Galileo.     

Models of the protosatellite disk of Saturn: Conditions for Titan’s formation

Models of the protosatellite accretion disk of Saturn are developed that satisfy cosmochemical constraints on the volatile abundances in the atmospheres of Saturn and Titan with due regard for the data obtained with the Cassini orbiter and the Huygens probe, which landed on Titan in January 2005. All basic sources of heating of the disk and protosatellite bodies are taken into account in the models, namely, dissipation of turbulence in the disk, accretion of gaseous and solid material onto the disk from the feeding zone of Saturn in the solar nebula, and heating by the radiation of young Saturn and thermal radiation of the surrounding region of the solar nebula. Two-dimensional (axisymmetric) temperature, pressure, and density distributions are calculated for the protosatellite disk. The distributions satisfy the cosmochemical constraints on the disk temperature, according to which the temperature at the stage of the satellite formation ranged from 60–65 K to 90–100 K at pressures from 10^?7 to ?10^?4 bar in the zone of Titan’s formation (according to estimates, r = 20–35R _Sat). Variations of the basic input parameters (the accretion rate onto the protosatellite disk of Saturn from the feeding zone of the planet ?; the parameter α characterizing turbulent viscosity of the disk; and the mass concentration ratio in the solid/gas system) satisfying the aforementioned temperature constraint are found. The spectrum of models satisfying the cosmochemical constraints covers a considerable range of consistent parameters. A model with a rather small flux of ? = 10^?8 M _Sat/ yr and a tenfold depletion of Saturn’s disk in gas due to gas scattering from the solar nebula is at one side of this range. A model with a much higher flux of ? = 10^?6 M _Sat/yr and a hundredfold decrease in opacity of the disk matter owing to decreased concentration of dust particles and/or their agglomeration into large aggregates and sweeping up by planetesimals is at the other side of the range.     

Deciphering the origin of the regular satellites of gaseous giants - Iapetus: The Rosetta ice-moon

Ever since their discovery the regular satellites of Jupiter and Saturn have held out the promise of providing an independent set of observations with which to test theories of planet formation. Yet elucidating their origins has proven elusive. Here we show that Iapetus can serve to discriminate between satellite formation models. Its accretion history can be understood in terms of a two-component gaseous subnebula, with a relatively dense inner region, and an extended tail out to the location of the irregular satellites, as in the SEMM model of Mosqueira and Estrada (2003a,b) (Mosqueira, I., Estrada, P.R. [2003a]. Icarus 163, 198-231; Mosqueira, I., Estrada, P.R. [2003b]. Icarus 163, 232-255). Following giant planet formation, planetesimals in the feeding zone of Jupiter and Saturn become dynamically excited, and undergo a collisional cascade. Ablation and capture of planetesimal fragments crossing the gaseous circumplanetary disks delivers enough collisional rubble to account for the mass budgets of the regular satellites of Jupiter and Saturn. This process can result in rock/ice fractionation as long as the make up of the population of disk crossers is non-homogeneous, thus offering a natural explanation for the marked compositional differences between outer solar nebula objects and those that accreted in the subnebulae of the giant planets. For a given size, icy objects are easier to capture and to ablate, likely resulting in an overall enrichment of ice in the subnebula. Furthermore, capture and ablation of rocky fragments become inefficient far from the planet for two reasons: the gas surface density of the subnebula is taken to drop outside the centrifugal radius, and the velocity of interlopers decreases with distance from the planet. Thus, rocky objects crossing the outer disks of Jupiter and Saturn never reach a temperature high enough to ablate either due to melting or vaporization, and capture is also greatly diminished there. In contrast, icy objects crossing the outer disks of each planet ablate due to the melting and vaporization of water-ice. Consequently, our model leads to an enhancement of the ice content of Iapetus, and to a lesser degree those of Titan, Callisto and Ganymede, and accounts for the (non-stochastic) compositions of these large, low-porosity outer regular satellites of Jupiter and Saturn. For this to work, the primordial population of planetesimals in the Jupiter-Saturn region must be partially differentiated, so that the ensuing collisional cascade produces an icy population of ?1 m size fragments to be ablated during subnebula crossing. We argue this is likely because the first generation of solar nebula ∼10 km planetesimals in the Jupiter-Saturn region incorporated significant quantities of ²⁶Al. This is the first study successfully to provide a direct connection between nebula planetesimals and subnebulae mixtures with quantifiable and observable consequences for the bulk properties of the regular satellites of Jupiter and Saturn, and the only explanation presently available for Iapetus’ low density and ice-rich composition.     

Enrichment in volatiles in the giant planets of the Solar System

We propose an interpretation of the enrichments in volatiles observed in the four giant planets with respect to the solar abundance. It is based on the assumption that volatiles were trapped in the form of solid clathrate hydrates and incorporated in planetesimals embedded in the feeding zones of each of the four giant planets. The mass of trapped volatiles is then held constant with time. The mass of hydrogen and of not trapped gaseous species continuously decreased with time until the formation of the planet was completed, resulting in an increase in the ratio of the mass of trapped volatiles to the mass of hydrogen (Gautier et al., Astrophys. J. 550 (2001) L227). The efficiency of the clathration depends upon the amount of ice available in the early feeding zone. The quasi-uniform enrichment in Ar, Kr, Xe, C, N, and S observed in Jupiter is reproduced because all volatiles were trapped. The non-uniform enrichment observed in C, N and S in Saturn is due to the fact that CH₄, NH₃, and H₂S were trapped but not CO and N₂. The non-uniform enrichment in C, N and S in Uranus and Neptune results from the trapping of CH₄, CO, NH₃ and H₂S, while N₂ was not trapped. Our scenario permits us to interpret the strongly oversolar sulfur abundance inferred by various modelers to be present in Saturn, Uranus and Neptune for reproducing the microwave spectra of the three planets. Abundances of Ar, Kr and Xe in these three are also predicted. Only Xe is expected to be substantially oversolar. The large enrichment in oxygen in Neptune with respect to the solar abundance, calculated by Lodders and Fegley (Icarus 112 (1994) 368) from the detection of CO in the upper troposphere of the planet, is consistent with the trapping of volatiles by clathration. The upper limit of CO in Uranus does not exclude that this process also occurred in Uranus.     

The role of Fischer-Tropsch catalysis in the origin of methane-rich Titan

Fischer-Tropsch catalysis, which converts CO and H₂ into CH₄ on the surface of iron catalyst, has been proposed to produce the CH₄ on Titan during its formation process in a circum-planetary subnebula. However, Fischer-Tropsch reaction rate under the conditions of subnebula have not been measured quantitatively yet. In this study, we conduct laboratory experiments to determine CH₄ formation rate and also conduct theoretical calculation of clathrate formation to clarify the significance of Fischer-Tropsch catalysis in a subnebula. Our experimental result indicates that the range of conditions where Fischer-Tropsch catalysis proceeds efficiently is narrow (T∼500-600 K) in a subnebula because the catalysts are poisoned at temperatures above 600 K under the condition of subnebula (i.e., H₂/CO = 1000). This suggests that an entire subnebula may not become rich in CH₄ but rather that only limited region of a subnebula may enriched in CH₄ (i.e., CH₄-rich band formation). Our experimental result also suggests that both CO and CO₂ are converted into CH₄ within time significantly shorter than the lifetime of the solar nebula at the optimal temperatures around 550 K. The calculation result of clathration shows that CO₂-rich satellitesimals are formed in the catalytically inactive outer region of subnebula. In the catalytically active inner region, CH₄-rich satellitesimals are formed. The resulting CH₄-rich satellitesimals formed in this region play an important role in the origin of CH₄ on Titan. When our experimental data are applied to a high-pressure model for subnebula evolution, it would predict that there should be CO₂ underneath the Iapetus subsurface and no thick CO₂ ice layer on Titan's icy crust. Such surface and subsurface composition, which may be observed by Cassini-Huygens mission, would provide crucial information on the origin of icy satellites.     

Formation of the regular satellites of giant planets in an extended gaseous nebula I: subnebula model and accretion of satellites

We model the subnebulae of Jupiter and Saturn wherein satellite accretion took place. We expect each giant planet subnebula to be composed of an optically thick (given gaseous opacity) inner region inside of the planet’s centrifugal radius (where the specific angular momentum of the collapsing giant planet gaseous envelope achieves centrifugal balance, located at rCJ ∼ 15R_J for Jupiter and rCS ∼ 22R_S for Saturn) and an optically thin, extended outer disk out to a fraction of the planet’s Roche-lobe (R_H), which we choose to be ∼R_H/5 (located at ∼150 R_J near the inner irregular satellites for Jupiter, and ∼200R_S near Phoebe for Saturn). This places Titan and Ganymede in the inner disk, Callisto and Iapetus in the outer disk, and Hyperion in the transition region. The inner disk is the leftover of the gas accreted by the protoplanet. The outer disk may result from the nebula gas flowing into the protoplanet during the time of giant planet gap-opening (or cessation of gas accretion). For the sake of specificity, we use a solar composition “minimum mass” model to constrain the gas densities of the inner and outer disks of Jupiter and Saturn (and also Uranus). Our model has Ganymede at a subnebula temperature of ∼250 K and Titan at ∼100 K. The outer disks of Jupiter and Saturn have constant temperatures of 130 and 90 K, respectively.Our model has Callisto forming in a time scale ∼10⁶ years, Iapetus in 10⁶-10⁷ years, Ganymede in 10³-10⁴ years, and Titan in 10⁴-10⁵ years. Callisto takes much longer to form than Ganymede because it draws materials from the extended, low density portion of the disk; its accretion time scale is set by the inward drift times of satellitesimals with sizes 300-500 km from distances ∼100R_J. This accretion history may be consistent with a partially differentiated Callisto with a ∼300-km clean ice outer shell overlying a mixed ice and rock-metal interior as suggested by Anderson et al. (2001), which may explain the Ganymede-Callisto dichotomy without resorting to fine-tuning poorly known model parameters. It is also possible that particulate matter coupled to the high specific angular momentum gas flowing through the gap after giant planet gap-opening, capture of heliocentric planetesimals by the extended gas disk, or ablation of planetesimals passing through the disk contributes to the solid content of the disk and lengthens the time scale for Callisto’s formation. Furthermore, this model has Hyperion forming just outside Saturn’s centrifugal radius, captured into resonance by proto-Titan in the presence of a strong gas density gradient as proposed by Lee and Peale (2000). While Titan may have taken significantly longer to form than Ganymede, it still formed fast enough that we would expect it to be fully differentiated. In this sense, it is more like Ganymede than like Callisto (Saturn’s analog of Callisto, we expect, is Iapetus). An alternative starved disk model whose satellite accretion time scale for all the regular satellites is set by the feeding of planetesimals or gas from the planet’s Roche-lobe after gap-opening is likely to imply a long accretion time scale for Titan with small quantities of NH₃ present, leading to a partially differentiated (Callisto-like) Titan. The Cassini mission may resolve this issue conclusively. We briefly discuss the retention of elements more volatile than H₂O as well as other issues that may help to test our model.     

Production of organic molecules in the outer solar system by proton irradiation: Laboratory simulations

In the past few years considerable attention has been given to the determination of likely compounds that could account for the various colors observed in the outer solar system: and to possible formation mechanisms for these compounds. Many experiments have been done using electrical discharges (Chadha, M. S., et al., 1971, Icarus15, 39) and ultraviolet light (Khare, B. N., and Sagan, C., 1973, Icarus20, 311) on mixtures of CH₄, NH₃, and H₂S, which are most likely the dominant minor constituents of the atmospheres of Jupiter, Saturn, Titan, and possibly the other satellites early in their histories. Colored polymers, usually brownish-red, have been produced in these experiments. With the passage of Pioneer 10 around Jupiter, there is another source of energy worthy of consideration, energetic protons (and electrons). Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures by protons are discussed. Two to four Mev protons were used, with corresponding beam fluxes (as measured at 6R_J from the planet) equivalent to approximately 80 Earth years at Jupiter per hour of exposure. As in the other types of experiments, colored polymers have been produced. An important feature of this work is the presence or absence of absorption at 5 μm in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system.     

On the C/H and D/H ratios in the atmospheres of Jupiter and Saturn

Using a method defined in a previous paper [M. Combes and T. Encrenaz, Icarus39 1–27 (1979)], we reestimated the C/H ratio in the atmospheres of Jupiter and Saturn by the measurements of the weak visible CH₄ bands, the CH₄ 3ν₃ band, and the (3-0) and (4-0) quadrupole bands of H₂. In the case of Jupiter we conclude that the C/H ratio is enriched by a factor ranging from 1.7 to 3.6 relative to the solar value. In the case of Saturn, our derived C/H value ranges from 1.2 to 3.2 times the solar value. The Jovian D/H ratio derived from this study is 1.2 × 10^?5 < D/H < 3.1 × 10^?5. The value derived for the D/H ratio on Saturn is not precise enough to be conclusive.     

Formation of the regular satellites of giant planets in an extended gaseous nebula II: satellite migration and survival

For a satellite to survive in the disk the time scale of satellite migration must be longer than the time scale for gas dissipation. For large satellites (∼1000 km) migration is dominated by the gas tidal torque. We consider the possibility that the redistribution of gas in the disk due to the tidal torque of a satellite with mass larger than the inviscid critical mass causes the satellite to stall and open a gap (W.R. Ward, 1997, Icarus 26, 261-281). We adapt the inviscid critical mass criterion to include gas drag, and m-dependent nonlocal deposition of angular momentum. We find that such a model holds promise of explaining the survival of satellites in the subnebula, the mass versus distance relationship apparent in the saturnian and uranian satellite systems, the concentration of mass in Titan, and the observation that the satellites of Jupiter get rockier closer to the planet whereas those of Saturn become increasingly icy. It is also possible that either weak turbulence (close to the planet) or gap-opening satellite tidal torque removes gas on a similar time scale (10⁴-10⁵ years) as the orbital decay time of midsized (200-700 km) regular satellites forming in the inner disk (inside the centrifugal radius (I. Mosqueira and P.R. Estrada, 2003, Icarus, this issue)). We argue that Saturn’s satellite system bridges the gap between those of Jupiter and Uranus by combining the formation of a Galilean-sized satellite in a gas optically thick subnebula with a strong temperature gradient, and the formation of smaller satellites, closer to the planet, in a disk with gas optical depth ?1, and a weak temperature gradient.Using an optically thick inner disk (given gaseous opacity), and an extended, quiescent, optically thin outer disk, we show that there are regions of the disk of small net tidal torque (even zero) where satellites (Iapetus-sized or larger) may stall far from the planet. For our model these outer regions of small net tidal torque correspond roughly to the locations of Callisto and Iapetus. Though the precise location depends on the (unknown) size of the transition region between the inner and outer disks, the result that Saturn’s is found much farther out (at ∼3rcS, where rcS is Saturn’s centrifugal radius) than Jupiter’s (at ∼ 2rcJ, where rcJ is Jupiter’s centrifugal radius) is mostly due to Saturn’s less massive outer disk and larger Hill radius. However, despite the large separation between Ganymede and Callisto and Titan and Iapetus, the long formation and migration time scales for Callisto and Iapetus (I. Mosqueira and P.R. Estrada, 2003, Icarus, this issue) makes it possible (depending on the details of the damping of acoustic waves) that the tidal torque of Ganymede and Titan clears the gas disk out to their location, thus stranding Callisto and Iapetus far from the planet. Either way, our model provides an explanation for the presence of regular satellites outside the centrifugal radii of Jupiter and Saturn, and the absence of such a satellite for Uranus.     

Estimated impact shock production of N2 and organic compounds on early Titan

Bombardment of Titan by Uranus-Neptune planetesimals and/or fragments of a disrupted Hyperion progenitor supplied more than enough energy to drive vigorous atmospheric shock chemistry. Chemical equilibrium modeling of the shock products in simulated atmospheres indicates that impact energy has produced large amounts of N₂ and organic compounds over Titan's history. The mole fraction of organic compounds in the shocked gas mixture (T = 1200−2500°K, P = 10⁻¹−10³bar) reaches a maximum of approximately 3% in a current Titan mixture and 12% in a primordial CH₄, NH₃-rich mixture. Atmospheric water mixing ratio controls the organic yield in shock reactions, but its limiting effect may have been reduced by cold-trapping of water in a cooling atmosphere. Kinetic inhibition of graphite formation in the shocked gas enhanced the yield of radicals and organic. The resulting mixture of carbonaceous soot and condensed hydrocarbons subsequently settled onto the surface; the depth of the generated layer was on the order of hundreds of meters. Impact shock energy was capable of converting massive amounts of NH₃ to N₂ early in Titan history—over twice the present atmospheric and 1.5 times the total ocean-atmospheric inventory of N₂. Shock conversion of NH₃ into N₂ bypasses the difficulties of other schemes of N₂ production and may have been of singular importance in Titan's atmospheric evolution.     

Radial migration of preplanetary material: Implications for the accretion time scale problem

Radial drift of planetesimals due to density wave interaction with the solar nebula is considered. The mechanism is most effective for large masses and provides mobility over a size range where aerodynamic drag is unimportant. The process could shorten accretion time scales to ≈O(10⁵–10⁶ years) throughout the solar system. Accumulation stalls down when growing objects are massive enough to open gaps in the gas disk. Implications of this process for current cosmogonic models are discussed.     

Planetesimal dissolution in the envelopes of the forming,giant planets

We have assessed the ability of planetesimals to penetrate through the envelopes of growing giant planets that form by a “core-instability” mechanism. According to this mechanism, a core grows by the accretion of solid bodies in the solar nebula and the growing core becomes progressively more effective in gravitationally concentrating gas from the surrounding solar nebula in an envelope until a “runaway” accretion of gas occurs. In performing this assessment, we have considered the ability of gas drag to slow down a planetesimal; the effectiveness of gas dynamical pressure in fracturing and ultimately finely fragmenting it; the ability of its strength and self-gravity to resist such fracturing; and the degree to which it is evaporated due to heating by the surrounding envelope, including shock heating that develops during the supersonic portion of its trajectory. We also consider what happens if the planetesimal is able to reach the core at free-fall velocity and the ability of the envelope to convectively mix dissolved materials to different radial distances. These calculations were performed for various epochs in the growth of a giant planet with the model envelopes derived by Bodenheimer and Pollack (1986,67, 391–408). As might have been anticipated, our results vary significantly with the size of the planetesimal, its composition, and the stage of growth of the giant planet and hence the mass of its envelope. Over much of the growth phase of the core, prior to its reaching its critical mass for runaway gas accretion, icy planetesimals less than about 1 m in size dissolve in the outer region of the envelope, ones larger than about 1 m and smaller than about 1 km dissolve in the middle region of the envelope, ones larger than 1 km either reach the core interface or dissolve in the deeper regions of the envelope. Similarly rocky planetesimals smaller than about a kilometer dissolve in the middle portion of the envelope, while larger ones can penetrate more deeply. Furthermore, the convection zones of the envelopes during this stage are confined to localized regions and hence dissolved materials experience little radial mixing then. Thus, if much of the accreted mass is contained in planetesimals larger than about a kilometer, the critical core mass for runaway accretion is not expected to change significantly when planetesimal dissolution is taken into account. After accretion is terminated and the planet contracts toward its present size, the convection zone grows until it encompasses the entire envelope. Therefore, dissolved material should eventually become well mixed through the envelope. We proposed that the envelopes of the giant planets should contain significant enhancements above solar proportions in the abundances of virtually all elements relative to that of hydrogen, with the magnitude of the enhancement increasing approximately linearly with the ratio of the high Z mass to the (H, He) mass for the bulk of the planet. This prediction is in accord both qualitatively and quantitatively with the systematic increase in the atmospheric C/H ratio from Jupiter to Saturn to Uranus and Neptune and semiquantitatively with the results of recent interior models of the giant planets. It is not clear whether it is consistent with the abundances of H₂O and NH₃ in the atmospheres of some of the outer planets. Finally, the complete reduction of some dissolved materials, especially C containing compounds, is expected to consume some of the H₂ in the envelopes. Consequently, the He/H₂ ratios in the atmospheres of Uranus and Neptune may be slightly enhanced over the solar ratio. We estimate that the He/H₂ ratios for Uranus' and Neptune's atmospheres should be about 6 and 15% larger, respectively, than the solar ratio.     

On the composition of ices incorporated in Ceres

We use the clathrate hydrate trapping theory and gas drag formalism to calculate the composition of ices incorporated in the interior of Ceres. Utilizing a time-dependent solar nebula model, we show that icy solids can drift from beyond 5 au to the present location of the asteroid and be preserved from vaporization. We argue that volatiles were trapped in the outer solar nebula in the form of clathrate hydrates, hydrates and pure condensates prior to having been incorporated in icy solids and subsequently in Ceres. Under the assumption that most of volatiles were not vaporized during the accretion phase and the thermal evolution of Ceres, we determine the per mass abundances with respect to H₂O of CO₂, CO, CH₄, N₂, NH₃, Ar, Xe and Kr in the interior of the asteroid. The Dawn space mission, scheduled to explore Ceres in August 2014, may have the capacity to test some predictions. We also show that an in situ measurement of the D/H ratio in H₂O in Ceres could constrain the distance range in the solar nebula where its icy planetesimals were produced.     

The rotation rate of Uranus,its internal structure,and the process of planetary accretion

Models of Uranus were computed which match J₄ with a 17.24-hr rotation rate as measured by Voyager 2. These models imply an atmospheric enhancement of H₂O, NH₃, and CH₄ of not more than about 30 times the solar value, and have a total planetary ice to rock ratio more than 16. A scenario is presented whereby such high values of I/R may be attained.     

An interpretation of the nitrogen deficiency in comets

We propose an interpretation of the composition of volatiles observed in comets based on their trapping in the form of clathrate hydrates in the solar nebula. The formation of clathrates is calculated from the statistical thermodynamics of Lunine and Stevenson (1985, Astrophys. J. Suppl. 58, 493-531), and occurs in an evolutionary turbulent solar nebula described by the model of Hersant et al. (2001, Astrophys. J. 554, 391-407). It is assumed that clathrate hydrates were incorporated into the icy grains that formed cometesimals. The strong depletion of the N₂ molecule with respect to CO observed in some comets is explained by the fact that CO forms clathrate hydrates much more easily than does N₂. The efficiency of this depletion, as well as the amount of trapped CO, depends upon the amount of water ice available in the region where the clathration took place. This might explain the diversity of CO abundances observed in comets. The same theory, applied to the trapping of volatiles around 5 AU, explains the enrichments in Ar, Kr, Xe, C, and N with respect to the solar abundance measured in the deep troposphere of Jupiter [Gautier et al 2001a] and [Gautier et al 2001b].     

Formation of the giant planets

Observational constraints on interior models of the giant planets indicate that these planets were all much hotter when they formed and they all have rock and/or ice cores of ten to thirty earth masses. These cores are probably soluble in the envelopes above, especially in Jupiter and Saturn, and are therefore likely to be primordial. They persist despite the continual upward mixing by thermally driven convection throughout the age of the solar system, because of the inefficiency of double-diffusive convection. Thus, these planets most probably formed by the hydrodynamic collapse of a gaseous envelope onto a core rather than by direct instability of the gaseous solar nebula. Recent calculations by Mizuno (1980, Prog. Theor. Phys.64, 544) show that this formation mechanism may explain the similarity of giant planet core masses. Problems remain however, and no current model is entirely satisfactory in explaining the properties of the giant planets and simultaneously satisfying the terrestrial planet constraints. Satellite systematics and protoplanetary disk nebulae are also discussed and related to formation conditions.     

Observations of Jupiter and Saturn at 5–8 μm

Moderate-resolution spectrophotometry (Δλ/λ～0.015) has shown the effects of known atmospheric constituents (NH₃, CH₄, C₂H₆) on the 5–8 μm spectrum of Jupiter. Broadband observations of Saturn at 6.5 μm are also reported.     

The absence of endogenic methane on Titan and its implications for the origin of atmospheric nitrogen

We calculate the D/H ratio of CH₄ from serpentinization on Titan to determine whether Titan’s atmospheric CH₄ was originally produced inside the giant satellite. This is done by performing equilibrium isotopic fractionation calculations in the CH₄-H₂O-H₂ system, with the assumption that the bulk D/H ratio of the system is equivalent to that of the H₂O in the plume of Enceladus. These calculations show that the D/H ratio of hydrothermally produced CH₄ would be markedly higher than that of atmospheric CH₄ on Titan. The implication is that Titan’s CH₄ is a primordial chemical species that was accreted by the moon during its formation. There are two evolutionary scenarios that are consistent with the apparent absence of endogenic CH₄ in Titan’s atmosphere. The first is that hydrothermal systems capable of making CH₄ never existed on Titan because Titan’s interior has always been too cold. The second is that hydrothermal systems on Titan were sufficiently oxidized so that C existed in them predominately in the form of CO₂. The latter scenario naturally predicts the formation of endogenic N₂, providing a new hypothesis for the origin of Titan’s atmospheric N₂: the hydrothermal oxidation of ¹⁵N-enriched NH₃. A primordial origin for CH₄ and an endogenic origin for N₂ are self-consistent, but both hypotheses need to be tested further by acquiring isotopic data, especially the D/H ratio of CH₄ in comets, and the ¹⁵N/¹⁴N ratio of NH₃ in comets and that of N₂ in one of Enceladus’ plumes.     

The atmospheric composition and structure of Jupiter and Saturn from ISO observations: a preliminary review

Infrared spectra of Jupiter and Saturn have been recorded with the two spectrometers of the Infrared Space Observatory (ISO) in 1995–1998, in the 2.3–180 μm range. Both the grating modes (R=150–2000) and the Fabry-Pérot modes (R=8000–30,000) of the two instruments were used. The main results of these observations are (1) the detection of water vapour in the deep troposphere of Saturn; (2) the detection of new hydrocarbons (CH₃C₂H, C₄H₂, C₆H₆, CH₃) in Saturn’s stratosphere; (3) the detection of water vapour and carbon dioxide in the stratospheres of Jupiter and Saturn; (4) a new determination of the D/H ratio from the detection of HD rotational lines. The origin of the external oxygen source on Jupiter and Saturn (also found in the other giant planets and Titan in comparable amounts) may be either interplanetary (micrometeoritic flux) or local (rings and/or satellites). The D/H determination in Jupiter, comparable to Saturn’s result, is in agreement with the recent measurement by the Galileo probe (Mahaffy, P.R., Donahue, T.M., Atreya, S.K., Owen, T.C., Niemann, H.B., 1998. Galileo probe measurements of D/H and ³He/⁴He in Jupiters atmosphere. Space Science Rev. 84 251–263); the D/H values on Uranus and Neptune are significantly higher, as expected from current models of planetary formation.