Resistance of Enzymes to Ionizing Radiation under Model Conditions of the Martian Regolith

Solar System Research - Ionizing radiation is one of the main factors that destroy biomolecules in extraterrestrial conditions. The effects of radiation depend on the conditions of the exposure...     

Magnetic properties of Martian meteorites: Implications for an ancient Martian magnetic field

Abstract— The magnetic properties of samples of seven Martian meteorites (EET 79001, Zagami, Nakhla, Lafayette, Governador Valadares, Chassigny and ALH 84001) have been investigated. All possess a weak, very stable primary natural remanent magnetization (NRM), and some have less stable secondary components. In some cases, the latter are associated with magnetic contamination of the samples, imparted since their recovery, and with viscous magnetization, acquired during exposure of the meteorites to the geomagnetic field since they fell. The magnetic properties are carried by a small content (<1%) of titanomagnetite and, in ALH 84001, possibly by magnetite as well. The most likely source of the primary NRM is a thermoremanent magnetization acquired when the meteorite material last cooled from a high temperature in the presence of a magnetic field. Current evidence is that this was 1.3 Ga ago for the nakhlites and Chassigny and 180 Ma for shergottites: the time of the last relevant cooling of ALH 84001 is not presently known. Preliminary estimates of the strength of the magnetizing field are in the range 0.5–5 üT, which is at least an order of magnitude greater than the present field. It is tentatively concluded that the magnetic field was generated by a dynamo process in a Martian core with appropriate structure and properties.     

Martian cratering revisited: Implications for early geologic evolution

Improved crater statistics from varied Martian terrains are compared to lunar crater populations. The distribution functions for the average Martian cratered terrain and the average lunar highlands over the diameter range 8–2000 km are quite similar. The Martian population is less dense by approximately 0.70 from 8 to 256 km diameter and diverges to proportionally lower densities at greater diameters. Crater densities on Martian “pure” terra give a lower limit to the Mars/Moon integrated crater flux of 0.75 since the last stabilization of the respective planetary crusts. The crater population >8 km diameter postdating the Martian northern plains is statistically indistinguishable from that population postdating the lunar maria. Monte Carlo simulations were performed to constrain plausible mechanisms of crater obliteration. The models demonstrate that if the crater density difference between the lunar and Martian terra has been due to resurfacing processes, random intercrater plains formation cannot be the sole process. If plains preferentially form in and obliterate larger craters, then the observed Martian distribution retains its “shape” as the crater density decreases. This result is consistent with the morphology of Martian intercrater plains.     

Implications of abundant hygroscopic minerals in the Martian regolith

Converging lines of evidence suggest that a significant portion of the Martian surface fines may consist of salts and smectite clays. Salts can form stoichiometric hydrates as well as eutectic solutions with depressed freezing points; clays contain bound water of constitution and adsorb significant quantities of water from the vapor phase. The formation of ice may be suppressed by these minerals in some regions on Mars, and their presence in abundance would imply important consequences for atmospheric and geologic processes and the prospects for exobiology.     

Noble gases in the Martian meteorite Northwest Africa 2737: A new chassignite signature

Abstract— We report noble gas data for the second chassignite, Northwest Africa (NWA) 2737, which was recently found in the Moroccan desert. The cosmic ray exposure (CRE) age based on cosmogenic ³He, ²¹Ne, and ³⁸Ar around 10–11 Ma is comparable to the CRE ages of Chassigny and the nakhlites and indicates ejection of meteorites belonging to these two families during a discrete event, or a suite of discrete events having occurred in a restricted interval of time. In contrast, U‐Th/He and K/Ar ages <0.5 Ga are in the range of radiometric ages of shergottites, despite a Sm‐Nd signature comparable to that of Chassigny and the nakhlites (Misawa et al. 2005). Overall, the noble gas signature of NWA 2737 resembles that of shergottites rather than that of Chassigny and the nakhlites: NWA 2737 does not contain, in detectable amount, the solar‐like xenon found in Chassigny and thought to characterize the Martian mantle nor apparently fission xenon from ²⁴⁴Pu, which is abundant in Chassigny and some of the nakhlites. In contrast, NWA 2737 contains Martian atmospheric noble gases trapped in amounts comparable to those found in shergottite impact glasses. The loss of Martian mantle noble gases, together with the trapping of Martian atmospheric gases, could have occurred during assimilation of Martian surface components, or more likely during shock metamorphism, which is recorded in the petrology of this meteorite.     

History of Martian volatiles: Implications for organic synthesis

A theoretical reconstruction of the history of Martian volatiles indicates that Mars probably possessed a substantial reducing atmosphere at the outset of its history and that its present tenous and more oxidized atmosphere is the result of extensive chemical evolution. As a consequence, it is probable that Martian atmospheric chemical conditions, now hostile with respect to abiotic organic synthesis in the gas phase, were initially favorable. Evidence indicating the chronology and degradational history of Martian surface features, surface mineralogy, bulk volatile content, internal mass distribution, and thermal history suggests that Mars catastrophically developed a substantial reducing atmosphere as the result of rapid accretion. This atmosphere probably persisted—despite the direct and indirect effects of hydrogen escape—for a geologically short time interval during, and immediately following, Martian accretion. That was the only portion of Martian history when the atmospheric environment could have been chemically suited for organic synthesis in the gas phase. Subsequent gradual degrassing of the Martian interior throughout Martian history could not sustain a reducing atmosphere due to the low intensity of planet-wide orogenic activity and the short atmospheric mean residence time of hydrogen on Mars. During the post-accretion history of Mars, the combined effects of planetary hydrogen escape, solar-wind sweeping, and reincorporation of volatiles into the Martian surface produced and maintained the present atmosphere.     

Noble gases in planetary atmospheres: Implications for the origin and evolution of atmospheres

The radiogenic and primordial noble gas content of the atmospheres of Venus, Earth, and Mars are compared with one another and with the noble gas content of other extraterrestial samples, especially meteorites. The fourfold depletion of ⁴⁰Ar for Venus relative to the Earth is attributed to the outgassing rates and associated tectonics and volcanic styles for the two planets diverging significantly within the first billion or so years of their history, with the outgassing rate for Venus becoming much less than that for the Earth at subsequent times. This early divergence in the tectonic style of the two planets may be due to a corresponding early onset of the runaway greenhouse on Venus. The 16-fold depletion of ⁴⁰Ar for Mars relative to the Earth may be due to a combination of a mild K depletion for Mars, a smaller fraction of its interior being outgassed, and to an early reduction in its outgassing rate. Venus has lost virtually all of its primordial He and some of its radiogenic He. The escape flux of He may have been quite substantial in Venus' early history, but much diminished at later times, with this time variation being perhaps strongly influenced by massive losses of H₂ resulting from efficient H₂O loss processes.Key trends in the primordial noble gas content of terrestial planetary atmospheres include (1) a several orders of magnitude decrease in ²⁰Ne and ³⁶Ar from Venus to Earth to Mars; (2) a nearly constant ²⁰Ne/³⁶Ar ratio which is comparable to that found in the more primitive carbonaceous chondrites and which is two orders of magnitude smaller than the solar ratio; (3) a sizable fractionation of Ar, Kr, and Xe from their solar ratios, although the degree of fractionation, especially for ³⁶Ar/¹³²Xe, seems to decrease systematically from carbonaceous chondrites to Mars to Earth to Venus; and (4) large differences in Ne and Xe isotopic ratios among Earth, meteorites, and the Sun. Explaining trends (2), (2) and (4), and (1) pose the biggest problems for the solar-wind implantation, primitive atmosphere, and late veneer hypotheses, respectively. It is suggested that the grain-accretion hypothesis can explain all four trends, although the assumptions needed to achieve this agreement are far from proven. In particular, trends (1), (2), (3), and (4) are attributed to large pressure but small temperature differences in various regions of the inner solar system at the times of noble gas incorporation by host phases; similar proportions of the host phases that incorporated most of the He and Ne on the one hand (X) and Ar, Kr, and Xe on the other hand (Q); a decrease in the degree of fractionation with increasing noble-gas partial pressure; and the presence of interstellar carriers containing isotopically anomalous noble gases.Our analysis also suggests that primordial noble gases were incorporated throughout the interior of the outer terrestial planets, i.e., homogeneous accretion is favored over inhomogeneous accretion. In accord with meteorite data, we propose that carbonaceous materials were key hosts for the primordial noble gases incorporated into planets and that they provided a major source of the planets' CO₂ and N₂.     

Siderophile and chalcophile element abundances in shergottites: Implications for Martian core formation

Elemental abundances for volatile siderophile and chalcophile elements for Mars inform us about processes of accretion and core formation. Such data are few for Martian meteorites, and are often lacking in the growing number of desert finds. In this study, we employed laser ablation inductively coupled plasma–mass spectrometry (LA‐ICP‐MS) to analyze polished slabs of 15 Martian meteorites for the abundances of about 70 elements. This technique has high sensitivity, excellent precision, and is generally accurate as determined by comparisons of elements for which literature abundances are known. However, in some meteorites, the analyzed surface is not representative of the bulk composition due to the over‐ or underrepresentation of a key host mineral, e.g., phosphate for rare earth elements (REE). For other meteorites, the range of variation in bulk rastered analyses of REE is within the range of variation reported among bulk REE analyses in the literature. An unexpected benefit has been the determination of the abundances of Ir and Os with a precision and accuracy comparable to the isotope dilution technique. Overall, the speed and small sample consumption afforded by this technique makes it an important tool widely applicable to small or rare meteorites for which a polished sample was prepared. The new volatile siderophile and chalcophile element abundances have been employed to determine Ge and Sb abundances, and revise Zn, As, and Bi abundances for the Martian mantle. The new estimates of Martian mantle composition support core formation at intermediate pressures (14 ± 3 GPa) in a magma ocean on Mars.     

Carbon,Nitrogen, and Noble Gases in the Diamond Fractions of the Novo Urei Ureilite

We measured the contents and isotopic compositions for C, N, and noble gases in the diamond fractions separated in a heavy liquid ( = 2.9 g/cm³) from a sample enriched with diamond from the Novo Urei ureilite. The results show that the concentrations of nitrogen and noble gases in the diamond fraction isolated from the supernatant (the fraction is named DNU-1) are more than a factor of 1.5 higher than those in the diamond fraction from the residue (DNU-2). This difference is probably caused by smaller sizes of grains and (or) clusters of smaller grains as well as by larger defectiveness of the crystal lattice of the diamond in the DNU-1 fraction as compared to DNU-2. Both fractions are similar in the isotopic composition of C and N and in the ratios of trapped chemical elements. The results obtained and the published data concerning C, N, and noble gases in different fractions of other ureilites allow us to conclude the following. (1) The ureilite diamond was most likely formed from graphite and the fine-grained crystalline (or semiamorphous) carbonaceous phase as a result of shock transformation in the parent bodies. (2) The negative result in the search for the isotopically light component of nitrogen (¹⁵N is about –100) in the Antarctic unshocked ureilite ALH 78019 (Rai et al., 2002), which introduced serious difficulties for explaining the origin of the ureilite diamond in the parent bodies during the impact, is most likely caused by the absorption of atmospheric nitrogen by the carbonaceous material in the processes of terrestrial weathering. (3) The source of light nitrogen (¹⁵N –100) in the ureilite diamond was probably the presolar diamond in the initial carbonaceous material of the ureilite parent bodies, because the impurity elements, including nitrogen (¹⁵N < –350), in this diamond could be trapped in the magmatic processes by the carbonaceous material, which became a precursor of the ureilite diamond in the shock event.     

Martian planetwide crater distributions: Implications for geologic history and surface processes

Population-density maps of craters in three size ranges (0.6 to 1.2 km, 4 to 10 km, and >20 km in diameter) were compiled for most of Mars from Mariner 9 imagery. These data provide: historical records of the eolian processes (0.6 to 1.2 km craters); stratigraphic, relative, and absolute timescales (4 to 10 km craters); and a history of the early postaccretional evolution of the uplands (> 20 km craters).Based on the distribution of large craters (>20 km diameters), Mars is divisible into two general classes of terrain, densely cratered and very lightly cratered—a division remarkably like the uplands-maria dichotomy of the moon. It is probable that this bimodal character in the density distribution of large craters arose from an abrupt transition in the impact flux rate from an early intense period associated with the tailing off of accretion to an extended quiescent epoch, not from a void in geological activity during much of Mars' history. Radio-isotope studies of Apollo lunar samples show that this transition occurred on the moon in a short time.The intermediate-sized craters (4 to 10 km diameter) and the small-sized craters (0.6 to 1.2 km diameter) appear to be genetically related. The smaller ones are apparently secondary impact craters generated by the former. Most of the craters in the larger of these two size classes appear fresh and uneroded, although many are partly buried by dust mantles. Poleward of the 40° parallels the small fresh craters are notably absent owing to these mantles. The density of small craters is highest in an irregular band centered at 20°S. This band coincides closely with (1) the zone of permanent low-albedo markings; (2) the “wind equator” (the latitude of zero net north or south transport at the surface); and (3) a band that includes a majority of the small dendritic channels. Situated in the southermost part of the equatorial unmantled terrain which extends from about 40°N to 40°S, this band is apparently devoid of even a thin mantle. Because this belt is also coincident with the latitutde of maximum solar insolation (periapsis occurs near summer solstice), we suggest that this band arises from the asymmetrical global wind patterns at the surface and that the band probably follows the latitude of maximum heating which migrates north and south from 25°N to 25°S within the unmantled terrain on a 50,000 year timescale.The population of intermediate-sized craters (4–10 km diameter) appears unaffected by the eolian mantles, at least within the ±45° latitudes. Hence the local density of these craters is probably a valid indicator of the relative age of surfaces generated during the period since the uplands were intensely bombarded and eroded. It now appears that the impact fluxes at Mars and the moon have been roughly the same over the last 4 b.y. because the oldest postaccretional, mare-like surfaces on Mars and the moon display about the same crater density. If so, the nearness of Mars to the asteroid belt has not generated a flux 10 to 25 times greater than the lunar flux. Whereas the lunar maria show a variation of about a factor of three in crater density from the oldest to the youngest major units, analogous surfaces on Mars show a variation between 30 and 50. This implies that periods of active eolian erosion, tectonic evolution, volcanic eruption, and possibly fluvial modification have been scattered throughout Martian history since the formation and degradation of the martian uplands and not confined to small, ancient or recent, epochs. These processes are surely active on the planet today.     

Noble gas adsorption with and without mechanical stress: Not Martian signatures but fractionated air

Abstract– Sample preparation, involving physical and chemical methods, is an unavoidable step in geochemical analysis. From a noble gas perspective, the two important effects are loss of sample gas and/or incorporation of air, which are significant sources of analytical artifacts. This article reports on the effects of sample exposure to laboratory air without mechanical influence and during sample grinding. The experiments include pure adsorption on terrestrial analog materials (gibbsite and olivine) and grinding of Martian meteorites. A consistent observation is the presence of an elementally fractionated air component in the samples studied. This is a critical form of terrestrial contamination in meteorites as it often mimics the heavy noble gas signatures of known extra‐terrestrial end‐members that are the basis of important conclusions about the origin and evolution of a meteorite. Although the effects of such contamination can be minimized by avoiding elaborate sample preparation protocols, caution should be exercised in interpreting the elemental ratios (Ar/Xe, Kr/Xe), especially in the low‐temperature step extractions. The experiments can also be transferred to the investigation of Martian meteorites with long terrestrial residence times, and to Mars, where the Mars Science Laboratory mission will be able to measure noble gas signatures in the current atmosphere and in rocks and soils collected on the surface in Gale crater.     

冰穹C的大气条件:天文含意

在南极洲高原的冰穹C有望发现非凡的天文观测条件,受此鼓舞,许多国际小组协同努力对该地的大气条件作全面的测量．评述对冰穹C的选址现况,讨论过去、现在和计划中的选址仪器,迄今已得到的结果,以及这些结果的天文含意．     

Dome C's Atmospheric Conditions: Implications for Astronomy

The expectation that exceptional conditions for astronomy would be found at Dome C on the high Antarctic plateau has motivated a coordinated effort by a number of international teams to comprehensively measure the atmospheric conditions at this site. This paper presents an overview of the current status of site testing at Dome C. We discuss the past, present, and planned instrumentation, the main results obtained to date, and the implications of these results.     

Galactic Chemical Evolution of the Lighter Neutron Capture Elements Sr, Y and Zr

Based on a three-component Galaxy chemical evolutionary model satisfying a large set of Galactic and extragalactic constraints, we compute the chemical evolution of the lighter neutron capture elements (e.g., Sr, Y and Zr) taking into account contributions from three processes. We compare our model results with available observational results and find that the observed trends can be understood in the light of present knowledge of neutron capture nucleosynthesis.     

Thermal modeling of shock melts in Martian meteorites: Implications for preserving Martian atmospheric signatures and crystallization of high‐pressure minerals from shock melts

The distribution of shock melts in four shergottites, having both vein and pocket geometry, has been defined and the conductive cooling time over the range 2500 °C to 900 °C calculated. Isolated 1 mm² pockets cool in 1.17 s and cooling times increase with pocket area. An isolated vein 1 × 7 mm in Northwest Africa (NWA) 4797 cools to 900 °C in 4.5 s. Interference between thermal haloes of closely spaced shock melts decreases the thermal gradient, extending cooling times by a factor of 1.4 to 100. This is long enough to allow differential diffusion of Ar and Xe from the melt. Small pockets (1 mm²) lose 2.2% Ar and 5.2% Xe during cooling, resulting in a small change in the Ar/Xe ratio of the dissolved gas over that originally trapped. With longer cooling times there is significant fractionation of Xe from Ar and the Ar/Xe ratio increases rapidly. The largest pockets show less variation of Ar/Xe and likely preserve the original trapped gas composition. Considering all of the model calculations, even the smallest isolated pockets have cooling times greater than the duration of the pressure pulse, i.e., >0.01 s. The crystallization products of these shock melts will be unrelated to the peak shock pressure experienced by the meteorite.     

Geologic features of Wudalianchi volcanic field,northeastern China: Implications for Martian volcanology

Wudalianchi volcanic field, located in northeast China, consists of 14 Quaternary volcanoes with each volcano as a steep-sided scoria cone surrounded by gently sloping lava flows. Each cone is topped with a bowl-shaped or funnel-shaped crater. The volcanic cones are constructed by the accumulation of tephra and other ejecta. In this paper, their geologic features have been investigated and compared with some Martian volcanic features at Ascraeus Mons volcanoes observed on images obtained from High-Resolution Imaging Science Experiments (HiRISE), Mars Orbiter Camera (MOC), Context Imager (CTX) and Thermal Emission Imaging System (THEMIS). The results show that both Wudalianchi and Ascraeus Mons volcanoes are basaltic, share similar eruptive and geomorphologic features and eruptive styles, and have experienced multiple eruptive phases, in spite of the significant differences in their dimension and size. Both also show a variety of eruptive styles, such as fissure and central venting, tube-fed and channel-fed lava flows, and probably pyroclastic deposits. Three volcanic events are recognized at Ascraeus Mons, including an early phase of shield construction, a middle eruptive phase forming a low lava shield, and the last stage with aprons mantling both NE and SW flanks. We suggest that magma generation at both Wudalianchi and Ascraeus Mons might have been facilitated by an upwelling mantle plume or upwelling of asthenospheric mantle, and a deep-seated fault zone might have controlled magma emplacement and subsequent eruptions in Ascraeus Mons as observed in the Wudalianchi field, where the volcanoes are constructed along the northeast-striking faults. Fumarolic cones produced by water/magma interaction at the Wudalianchi volcanic field may also serve as an analogue for the pseudocraters identified at Isidis and Cerberus Planitia on Mars, suggesting existence of frozen water in the ground on Mars during Martian volcanic eruptions.     

Search for Water in Martian Soil Using Global Neutron Mapping by the Russian HEND Instrument Onboard the US 2001 Mars Odyssey Spacecraft

We present the first results of the global neutron mapping of Mars by the Russian High-Energy Neutron Detector (HEND) onboard the US 2001 Mars Odyssey spacecraft. Global neutron maps of Mars in various spectral ranges allow the content of water ice and adsorbed and bound water in a near-surface layer of the planet 1 to 2 m in thickness to be estimated. Huge regions of permafrost with a high (several tens of percent by weight) content of water ice are shown to be present in the north and the south of Mars. The continuous observations of Mars for 12 months, from February 18, 2002, through February 8, 2003, are indicative of significant seasonal variations on Mars where the transition from northern winter to northern summer occurred.     

Epitaxial growth of nanophase magnetite in Martian meteorite Allan Hills 84001: Implications for biogenic mineralization

Abstract— Crystallographic relationships between magnetite, sulfides, and carbonate rosettes in fracture zones of the Allan Hills (ALH) 84001 Martian meteorite have been studied using analytical electron microscopy. We have focused on those magnetite grains whose growth mechanisms can be rigorously established from their crystallographic properties. Individual magnetite nanocrystals on the surfaces of carbonates are epitaxially intergrown with one another in “stacks” of single-domain crystals. Other magnetite nanocrystals are epitaxially intergrown with the surfaces of the carbonate substrates. The observed magnetite/carbonate (hkl) Miller indices orientation relationships are (?, ?, 3)_m ‖ (1, ?, 0)_c and (1, ?, 1)_m ‖ (0,0, 3)_c with lattice mismatches of ～13% and ～11%, respectively. Epitaxy is a common mode of vapor-phase growth of refractory oxides like magnetite, as is the spiral growth about axial screw dislocations previously observed in other magnetite nanocrystals in ALH 84001. Epitaxy rules out intracellular precipitation of these magnetites by (Martian) organisms, provides further evidence of the high-temperature (>120 °C) inorganic origins of magnetite in ALH 84001, and indicates that the carbonates also have been exposed to elevated temperatures.