Stability of iron oxides and their role in the formation of rock magnetism

Thermodynamic conditions (first of all, temperature) are the main dynamic factors in the transformation process of ferrous to ferric iron (TFFI). TFFI usually takes place within a temperature range of 473–843 K (most active at temperatures above 673 K) and does not require presence of the oxidizing agents above 673 K. Analysis of the chemical composition of different rocks and minerals indicates that only for some sedimentary rocks is the relative content of ferrous iron oxide less than its value in magnetite, and this value is minimal for oceanic sediments. The relative content of ferrous iron oxide in oceanic magmatic rocks exceeds this value in continental magmatic rocks and depends on the rate of rock cooling. An investigation of the role of the titanium oxide content of different rocks on stability of ferrous iron oxide against its transformation to ferric iron oxide shows that a significant correlation (r = 0.79) does exist between the relative content of ferrous iron oxide and ratio of TiO₂/Fe₂O₃. Temperature within the solar nebula at location of the Earth was within the temperature range of the TFFI. During the Earth accretion and its early evolution, ferric iron oxide was unstable and most likely did not exist. The first magnetic minerals containing ferric iron could have appeared only after the Earth’s surface had cooled below ∼843 K. The formation of the first Algoma-type banded iron formations could be used as a marker of the Earth’s surface cooling below ∼843 K.     

Magnetostratigraphy of Upper Permian sediments in the southwestern slope of Pai-Khoi (Khei-Yaga River section): Evidence for the global Permian-Triassic crisis

The study of rock samples from the Upper Permian Khei-Yaga River section revealed an r-n-r-n-r magnetic polarity succession based on the prefolding characteristic component of natural remanent magnetization. With account for stratigraphic and previous magnetostratigraphic data on Lower Triassic rocks from the Khei-Yaga River section, the examined strata of the Pechora Group (Silova Formation) may be compared with magnetic zones R₁P₂u and N₁P₃t in the magnetostratigraphic scale of European Russia. The gap in the paleomagnetic record, which corresponds in the examined section to the interval of the mid-Severodvinian Stage to basal Induan Stage, Zone N₁T included, is estimated to be 10 Ma long. It is assumed that this hiatus represents one of the local signs of the global Permian-Triassic crisis.     

Rock magnetic properties of a loess-paleosol couple along an N-S transect in the Chinese Loess Plateau

We have conducted detailed rock magnetic experiments on samples from loess unit 8 (L8) and paleosol unit 8 (S8) in Jingbian, Yichuan and Duanjiapo loess sections along an N-S transect in the Chinese Loess Plateau. Major rock magnetic results are as follows: (i) An increase of high field susceptibility (χ_h) in the same level of loess or paleosol from north to south is observed, suggesting an enhancement of pedogenesis. (ii) The low field susceptibility(χL) in loess unit L8 is almost the same in three sections. In contrast, the χ_L of paleosol unit S8 in Yichuan is highest, and the χ_L of Duanjiapo is lower than that in Yichuan section, suggesting that there is not correlation between the χ_L and the degree of pedogenesis in loess-paleosols. (iii) With the increasing of χ_L, both the contents of the superparamagnetic (SP) and the ferrimagnetic grains in loess-paleosol increase, however, the enhancement of magnetic susceptibility is probably dependent more on the increase of the ferrimagnetic concentration than on a change in the grain size. (iv) The content of the maghemite in loess unit 8 increases from the northern to the southern part of the Chinese Loess Plateau, and is positively correlated with the pedogenesis of the loess.     

Rock magnetic analyses as a tool to investigate diversity of drift pumice clasts: An example from Japan's 2021 Fukutoku-Oka-no-Ba (FOB) eruption

The crystallization of nanolites within magma chambers has recently raised a strong interest due to their impact on increasing melt viscosity and triggering magmatic eruptions. In 2021, the Fukutoku-Oka-no-Ba (FOB) underwater eruption produced large quantities of pumices that eventually formed rafts drifting at the surface of the ocean to the East coasts of Japan. Pumices collected along the shore shortly after grounding show various colors, microscopic and Raman analyses made by Yoshida et al. (Island Arc, 31, 1, 2022) revealed the presence of magnetite nanolites in some of them. In this study, we explore the magnetic properties of a batch of pumices of different colors from the FOB eruption, aiming to refine characterization of iron oxide nanolites. We used various analytical techniques such as SEM and FEG-SEM observations, EDS-X analyses, and rock magnetic experiments, including thermomagnetic analyses, hysteresis curves, coercivity analyses and FORC measurements. Our findings reveal that the iron oxides present in the FOB samples are Ti-magnetite, with minor amounts of Mg and Al. The magnetic crystals show a wide range of sizes, from extra small iron oxide nanolites (ESION) in the pumices with the lighter colors, to more bulky grains reaching the micrometer size in some of the dark color samples, significant diffusion is inferred in that case. Consequently, the magnetic characterization of iron oxide crystals within the Fukutoku-Oka-no-Ba pumices reveals varying stages of nucleation, dissolution, growth, and diffusion processes, providing evidences for the heterogeneous state of the magma during the eruption.     

Seismological Evidence of Active Faulting in the Tendaho Rift (Afar Triangle, Ethiopia)

—A temporary network has been used to study the seismic activity in the central-northern part of the Tendaho Rift (Afar Triangle, Ethiopia). Small size earthquakes (M < 2.5) characterize the seismicity during the time interval 1993–1994 when the seismic array was operating. Shocks are mainly located in the central part of the Tendaho rift and their epicentral distribution highlights a remarkable coincidence with NW-SE trending tectonically active structures. Focal depths are confined in the range of 3–8?km. ? The few acceptable fault plane solutions suggest the occurrence of both strike-slip and dip-slip rupture mechanisms, which are often characterized by a nodal plane oriented approximately NW-SE. ?A detailed study of earthquake waveforms using polarization analysis showed the occurrence of splitting phenomena for the S waves. Despite the differences in focal mechanisms, the similarity of the faster S-wave directions (NW-SE to NNW-SSE) suggests that the direction of geological structures and/or the systems of fractures adjacent to the faults could bias shear-wave propagation. The splitting time between fast and slow shear waves shows no systematic relationship with either hypocentral distance or focal depth, suggesting that the anisotropic volume is constrained to depths shallower than 3?km.     

On the development mechanism of the lacustrine high-grade hydrocarbon source rocks of Chang 91 member in Ordos Basin

As revealed from recent drilling and organic geochemical testing and research, a series of lacustrine high-grade hydrocarbon source rocks was discovered in the upper section of the Chang 9 oil reservoir member of upper Triassic in Ordos Basin. The hydrocarbon source rocks show average TOC content as high as 5.03%, average bitumen "A" content as high as 0.8603%, and good quality organic precursors, which are of the sapropelic type mainly derived from lower aquatic plants and have reached the thermal evolution stage featured by oil-producing climax. Generally the lacustrine high-grade hydrocarbon source rocks were developed in local depressions of a lake basin, and the Chang 91 member was particularly formed in a depositional environment characterized by fresh water to weakly saline water, weakly oxidizing to weakly reducing setting and semi-deep lake facies, as was demonstrated by a variety of organic to inorganic geochemical parameters. As a result, high productivity constitutes the principal controlling force for generation of this series of high-grade hydrocarbon source rocks. Deposition of thinly-bedded and laminated tuffs as well as positive Eu anomaly corroborate the possible occurrence of anoxic geological event closely related to contemporaneous volcanic eruption, which would play a key part in development of the Chang 91 member of high-grade hydrocarbon source rocks.     

A quick cooling event of the East Asian monsoon responding to Heinrich Event 1: Evidence from stalagmite δ18O records

Based on TIMS U-series dating results and annual band counting method, an annual-resolution time scale from 17450 to 14420 aBP has been established for a stalagmite from the Hulu Cave at Tangshan, Nanjing. A high-resolution oxygen isotopic record reveals decadral-centural oscillations in air temperature in the East Asian monsoon climate area during the last glacial maximum. The most conspicuous feature in the oxygen isotopic record in the period is the particular cold event synchronized with the last Heinrich event (H1) in the northern Atlantic deep-sea records. This particular cold event, beginning at 16140 ( 100 aBP, shows a rapid cooling down with a magnitude of 7-8℃ in air temperature within 36 years. Furthermore, (6)18O record demonstrates that the event lasted 790 years with gradually warming tendency (10 cycles of air temperature oscillations) after the remarkable cooling down. We believed that this unique pattern of event recorded in the stalagmite ? 8O might be controlled by various factors including changes of insolation at mid-latitude Northern Hemisphere, the southern extend of the last ice-rafted event in the North Atlantic and changes of the Equatorial Pacific sea surface temperature.     

黑龙江省小南山遗址受热历史的考古磁学证据

考古磁学技术为考古遗址的受热历史研究提供了重要的定性/定量分析方法.黑龙江省东北部的小南山是中国东北地区重要的史前遗址之一,该遗址记录的最早人类活动可以追溯到更新世末期.遗址揭露了距今约16 ka以来序列性的人类生活遗物及遗迹,包括大量的石制品和少量的陶片,以及与当时人类生活方式相关的疑似用火遗迹.本文对小南山遗址内疑似用火区及周边的散土样品进行了一系列岩石磁学测试,包括低频磁化率、逐步磁化率随温度变化曲线（χ-T）、磁滞回线、等温剩磁获得曲线、反向场退磁曲线和一阶反转曲线（FORC）等,旨在通过磁学指标为遗址受热温度、受热范围等信息提供定量化证据.实验结果显示,采样区域内两处疑似用火区（ZB、ZC）磁化率普遍偏高、逐步χ-T曲线在400~600℃之间表现出较好的热稳定性、饱和等温剩磁偏强、FORC信号偏强;而表层烧土被清理后的疑似用火区（ZA）和非疑似用火区磁化率普遍偏低、逐步χ-T曲线显示样品在加热过程中逐渐发生热变化、饱和等温剩磁和FORC信号偏弱.这些磁学特征意味着ZB、ZC两处疑似用火区曾受过加热烘烤,而从ZA采集到的样品和疑似用火区外的样品则可能没有受热.逐步χ-T曲线结果显示疑似用火区高磁化率样品在400~600℃之间表现出较好的热稳定性,而当温度达到700℃时则发生明显的热转化,指示样品历史最高受热温度应该在600~700℃之间.

     

Rain event properties in nature and in rainfall simulation experiments: a comparative review with recommendations for increasingly systematic study and reporting

In hydrology and geomorphology, less attention has been paid to rain event properties such as duration, mean and peak rain rate than to rain properties such as drop size or kinetic energy. A literature review shows a lack of correspondence between natural and simulated rain events. For example, 26 studies that report event statistics from substantial records of natural rain reveal a mean rain rate of just 3·47 mm h^?1 (s.d. 2·38 mm h^?1). In 17 comparable studies dealing with extreme rain rates including events in cyclonic, tropical convective, and typhoon conditions, a mean maximum rain rate (either hourly or mean event rain rate) of 86·3 mm h^?1 (s.d. 57·7 mm h^?1) is demonstrated. However, 49 studies using rainfall simulation involve a mean maximum rain rate of 103·1 mm h^?1 (s.d. 81·3 mm h^?1), often sustained for > 1 h, exceeding even than of extreme rain events, and nearly 30 times the mean rain rate in ordinary, non‐exceptional, rain events. Thus rainfall simulation is often biased toward high rain rates, and many of the rates employed (in several instances exceeding 150 mm h^?1) appear to have limited relevance to ordinary field conditions. Generally, simulations should resemble natural rain events in each study region. Attention is also drawn to the raindrop arrival rate at the surface. In natural rain, this is known to vary from < 100 m^?2 s^?1 to > 5000 m^?2 s^?1. Arrival rate may need to be added to the list of parameters that must be reproduced realistically in rainfall simulation studies. Copyright © 2008 John Wiley & Sons, Ltd.     

Assessing entrainment of bed material in a debris‐flow event: a theoretical approach incorporating Monte Carlo method

Entrainment of underlying bed sediment by a debris flow can significantly increase the debris‐flow magnitude. To study this phenomenon, a theoretical approach to assessing bed‐sediment entrainment is presented. The approach is based on a static approximation that bed‐sediment entrainment occurs when the shearing stress of the flow is sufficiently high to overcome the basal resistance of the bed sediment. In order to delineate erodible zones in a channel, we analyze the critical condition of this static equilibrium model, and subsequently propose a new concept of a critical line to detect the entrainment reaches in a channel. Considering the spatial and temporal uncertainties of the input parameter, the approach is further incorporated within a Monte Carlo method, and the distribution of entrainment zones and post‐entrainment volumes can be analyzed. This approach is illustrated by back‐analysis of the 2010 Yohutagawa debris‐flow event, Japan. Results from 10 000 trials of Monte Carlo simulation are compared with the in situ surveys. It is shown that the present approach can be satisfactorily used to delineate erodible zones and estimate possible entrainment volume of the event. Discussion regarding the sensitivities and limitations of the approach concludes the paper. Copyright © 2015 John Wiley & Sons, Ltd.     

Multi‐site calibration using a grid‐based event rainfall–runoff model: a case study of the upstream areas of the Nakdong River basin in Korea

Most runoff analyses using a grid‐based distributed model use one parameter group calibrated at the outlet of a watershed, instead of dividing the watershed into subwatersheds. Significant differences between the observed value and the simulation result of the subwatersheds can occur if just one parameter group is used in all subwatersheds that have different hydrological characteristics from each other. Therefore, to improve the simulation results of the subwatersheds within a watershed, a model calibrated at every subwatershed needs to be used to reflect the characteristics of each subwatershed. In this study, different parameter groups were set up for one or two sites using a distributed model, the GRM (Grid based Rainfall‐runoff Model), and the evaluations were based on the results of rainfall–runoff analysis, which uses a multi‐site calibration (MSC) technique to calibrate the model at the outlet of each site. The Hyangseok watershed in Naeseong River, which is a tributary of Nakdong River in Korea, was chosen as the study area. The watershed was divided into five subwatersheds each with a subwatershed outlet that was applied to the calibration sites . The MSC was applied for five cases. When a site was added for calibration in a watershed, the runoff simulation showed better results than the calibration of only one site at the most downstream area of the watershed. The MSC approach could improve the simulation results on the calibrated sites and even on the non‐calibrated sites, and the effect of MSC was improved when the calibrated site was closer to the runoff site. Copyright © 2014 John Wiley & Sons, Ltd.     

Assessment of magnetite as a magnetic tracer for sediments in the study of ephemeral gully erosion: Conditioning factors of magnetic susceptibility

In gully erosion, the detached soil can be transported over long distances along the landscape. The eroded material can be redistributed and/or deposited on the soil surface along the landscape and then eventually be buried by newly eroded and deposited sediment. There can be significant variability of the soil conditions (e.g., texture and moisture content) over which the eroded material travels. The eroded material can be detected through the use of magnetic tracers attached to or mixed with the eroded soil. In this study we evaluated the degree to which the magnetic signal of the magnetite is conditioned by (i) burial depth of tracer, (ii) condition of soil covering the tracer and (iii) tracer concentration. In the laboratory containers were filled with a specific soil. In the filling process, a 0.5-cm layer of a soil–magnetite mixture was interspersed in the soil profile at a certain depth. Experiments encompassed three different soil–tracer concentrations (1000:1, 200:1, 100:1), four burial depths of tracer (0 cm, 3 cm, 5 cm and 10 cm from soil surface), and two different soils. In each case, the magnetic susceptibility was measured with a susceptometer. Experiments were repeated with different soil moisture contents. If the tracer is located under the soil surface, a minimum soil–tracer concentration of 200:1 is required for its correct detection. The intensity of the magnetic signal decreases dramatically with the vertical distance of the tracer from the soil surface. The maximum detection depth for the tracer's magnetic signal is strongly dependent on the natural magnetic susceptibility of the soil, which masks the tracer's signal. Variation in soil moisture content does not significantly affect the magnetic signal. For extensive field studies, the soil–tracer volume to be handled would be very high and therefore, it is necessary to explore new tracer application techniques.     

声波电视在刚果(金)铜钴矿勘察中的应用

声波电视是利用声波走时和振幅参数进行钻孔壁成像的一种地球物理测井系统。由于采用数字技术和配置功能完善的软件,系统具有图像分辨率高、测井速度快、可在混浊的井液中工作、数据处理和分析过程相对简单的特性,是研究岩层结构面的有效手段。在刚果（金）某铜钴矿岩体稳定性评价中,采用声波测井方法,获取岩体的优势结构面,为确定采坑边坡角、岩体抗剪强度指标提供了可靠数据。本文介绍RG声波电视测井的原理及方法,以DK02孔为例,对所揭露岩层结构面、裂隙发育信息进行分析。工程实践说明,声波井下电视在进行深部岩体的原位勘察方面具有明显优势。     

苏里格南部地区地震储层预测技术研究——以盒8段为例

苏里格南部地区是近年来勘探评价的重点地区.该地区上古生界沉积体系、下古生界奥陶系风化壳和古隆起台缘斜坡礁滩相沉积体系中均孕育着巨大的天然气产能,成为鄂尔多斯盆地天然气勘探开发的战略接替区.研究区目标层埋深大,储层厚度小;下古生界地层间波阻抗差异小,地层反射能量弱,分辨率低.针对这些难点,本文利用精细闭合差技术刻画目的层,采用波形特征分析、叠前反演等方法精细描述目的层的构造形态并预测砂体厚度,采用谐振法对目的层进行含油气检测.研究结果表明:研究区北部砂体厚薄变化相对较快,而南部总体砂体厚度变化较小.根据砂体厚度分布、有效砂厚与试气成果对盒8段进行有利区评价,有利勘探目标约为7505 km²,其中Ⅰ类面积约为4729 km²,Ⅱ类面积约为2776 km²,预测结果为钻探井位提供了准确依据.     

Evidence for a seafloor rupture of the Carboneras Fault Zone (southern Spain): Relation to the 1522 Almería earthquake?

High-resolution sea floor imaging (narrow beam sediment profiler) yields evidence for an offshore rupture along a strand of the Carboneras Fault Zone (CFZ) in the Gulf of Almería off southern Spain. The observed faults affect the seafloor and cut the Late Holocene sedimentary cover, hence the faults are regarded as active and the escarpments as relatively fresh. Seafloor faulting is associated with escarpments, fissures, pressure ridges, folds, and reverse faults indicating sinistral strike-slip faulting with a significant vertical displacement. Adjacent to the major fault zone secondary phenomena such as submarine slumps and slides are observed. The observed fresh escarpments imply an offshore rupture during a major earthquake along the CFZ. The southern Iberian margin and the Afro-Eurasian convergence zone form an area of moderate seismicity. However, some major events occurred, such as the 1522 Almería earthquake (EMS IX; [IGN (2005) Instituto Geografico Nacional, www.ign.es]), which affected large areas in the western Mediterranean. Different epicentral areas have been suspected, mainly along the 50 km long sinistral CFZ; however, no on-shore surface ruptures and paleoseismological evidences for this event have been found. Based on our data, a new epicentral area is proposed in the Gulf of Almería precisely along the observed sea floor rupture area, where the CFZ extend at least for 100 km offshore. Our findings suggest a specific seismic hazards and tsunami potential for offshore active and seismogenic faults in the Alborán Sea.     

Tetrahedral occupancy of ferric iron in (Mg,Fe)O: Implications for point defects in the Earth's lower mantle

We investigated the concentration and site occupation of ferric iron (Fe³⁺) in (Mg,Fe)O to understand the influence of point defects on transport properties such as atomic diffusion, electrical conductivity and viscosity. We conducted Mössbauer spectroscopy of (Mg_0.8Fe_0.2)O single crystals synthesized at temperatures from 1673 to 2273 K and pressures from 5 to 15 GPa with Re–ReO₂ and Mo–MoO₂ oxygen fugacity buffers. The isomer shift of the Mössbauer spectra suggests that Fe³⁺ occupies mostly the tetrahedral site at reduced conditions and both the octahedral and tetrahedral sites at oxidized conditions. We formulate a thermodynamic model of point defect dissolution in (Mg,Fe)O which suggests that unassociated tetrahedral Fe³⁺ is more stable than unassociated octahedral Fe³⁺ at high-pressure and low oxygen fugacity due to the effect of configurational entropy. The pressure dependence of Fe³⁺ concentration indicates a change in the dominant site occupancy of Fe³⁺: (1) Fe³⁺ in the tetrahedral site, (2) Fe³⁺ in the octahedral site, and (3) defect clusters of Fe³⁺ and cation vacancy, in the order of increasing oxygen fugacity and decreasing pressure. This is in reasonable agreement with previously reported experiments on Fe³⁺ concentration, Mg–Fe interdiffusivity and electrical conductivity. We consider it plausible that (Mg,Fe)O accommodates Fe³⁺ in the tetrahedral site down to the lower mantle. Based on our results and available experimental data, we discuss the solubility competition between Fe³⁺ and protons (H⁺), and its implications for transport properties in the lower mantle.     

Large amplification of ground motion at rock sites within a fault zone in Nocera Umbra (central Italy)

During the two mainshocks of September 26, 1997 inthe Umbria-Marche border a strong-motion accelerographrecorded peak ground accelerations as large as 0.6 g,approximately, in the town of Nocera Umbra, atdistances of 10 to 15 km from the epicentres. Thisvalue is significantly larger than expected on thebasis of the usual regressions with magnitude anddistance. A broad-band amplification up to a factor of10 was consistently estimated in previous papers,using both weak and strong motion data recorded at theaccelerograph site during local moderate earthquakes.To study the cause of this amplification we deployedsix seismologic stations across the tectonic contactbetween the Ceno-Mesozoic limestone and the Mesozoicmarly sandstone where the accelerograph is installed.Seismograms of 21 shallow aftershocks in the magnituderange from 2.2 to 4.0 and a subcrustal M_w = 5.3event are analysed. Regardless of epicentre location,waveforms show a large complexity in an approximately200 m wide band adjacent to the tectonic contact. Thisis interpreted as the effect of trapped waves in thehighly fractured, lower velocity materials within thefault zone.     

Geochemical characteristics of Bikou volcanic group and Sr-Nd-Pb isotopic composition: Evidence for breakup event in the north margin of Yangtze plate, Jining era

The geodynamic setting of the Bikou volcanic group is a critical question to trace the Precambrain tectonic framework and evolution for the Yangtze plate. This study has suggested that the Bikou volcanic group is composed of several residual oceanic crust units MORB (mid-ocean ridge basalt), Alk-OIB (alkaline ocean island basalt) and Th-OIB (tholeiitic ocean island basalt) as well as subduction-related volcanic rocks. According to field observation, those distinct rocks occurred collectively in form of tectonic contact, implying that the Bikou volcanic group was an ophiolitic mélange. Coupled with geochronological data, a perished oceanic basin at the northern margin of the Yangtze block during Neoproterozoic was tested by this ophiolitic mélange. Meanwhile, the isogeochemical data suggest that the ocean occurred in the Southern Hemisphere identical to Indian, South Atlantic and South Pacific oceans in terms of their Dupal anomalies, and the original source of the rocks could be probably mixing by EMⅠand EMⅡ component caused by dehydration melting of subducting oceanic crust during subduction process. On the basis of geochemical characteristics of the studied rocks, the Bikou volcanic group could imply that a partial breakup event occurred in the northern margin of Yangtze plate during the Neoproterozoic era.     

A new version of the USLE‐MM for predicting bare plot soil loss at the Sparacia (South Italy) experimental site

Improving empirical prediction of plot soil erosion at the event temporal scale has both scientific and practical importance. In this investigation, 492 runoff and soil loss data from plots of different lengths, λ (11 ≤ λ ≤ 44 m), and steepness, s (14.9 ≤ s ≤ 26.0%), established at the Sparacia experimental station, in Sicily, South Italy, were used to derive a new version of Universal Soil Loss Equation (USLE)‐MM model, by only assuming a value of one for the topographic length, L, and steepness, S, factors for λ = 22 m and s = 9%, respectively. An erosivity index equal to (Q_REI₃₀)^b1, Q_R and EI₃₀ being the runoff coefficient and the event rainfall erosivity index, respectively, with b₁ > 1 was found to be an appropriate choice for the Sparacia area. The specifically developed functions for L and S did not differ appreciably from other, more widely accepted relationships (maximum differences by a factor of 1.22 for L and 1.09 for S). The new version of the USLE‐MM performed particularly well for highly erosive events, because predicted soil loss differed by not more than a factor of 1.19 from the measured soil loss for measured values of more than 100 Mg ha^?1. The choice of the relationships to predict topographic effects on plot soil loss should not represent a point of particular concern in the application of the USLE‐MM in other environments. However, tests of the empirical approach should be carried out in other experimental areas in an attempt to develop analytical tools, usable at the event temporal scale, reasonably simple and of wide validity. Copyright © 2015 John Wiley & Sons, Ltd.     

Geochemical characteristics of Bikou volcanic group and Sr-Nd-Pb isotopic composition: Evidence for breakup event in the north margin of Yangtze plate,Jining era

The geodynamic setting of the Bikou volcanic group is a critical question to trace the Precambrain tectonic framework and evolution for the Yangtze plate. This study has suggested that the Bikou volcanic group is composed of several residual oceanic crust units: MORB (mid-ocean ridge basalt), Alk-OIB (alkaline ocean island basalt) and Th-OIB (tholeiitic ocean island basalt) as well as subduction-related volcanic rocks. According to field observation, those distinct rocks occurred collectively in form of tectonic contact, implying that the Bikou volcanic group was an ophiolitic mélange. Coupled with geochronological data, a perished oceanic basin at the northern margin of the Yangtze block during Neoproterozoic was tested by this ophiolitic mélange. Meanwhile, the isogeochemical data suggest that the ocean occurred in the Southern Hemisphere identical to Indian, South Atlantic and South Pacific oceans in terms of their Dupal anomalies, and the original source of the rocks could be probably mixing by EMI and EMII component caused by dehydration melting of subducting oceanic crust during subduction process. On the basis of geochemical characteristics of the studied rocks, the Bikou volcanic group could imply that a partial breakup event occurred in the northern margin of Yangtze plate during the Neoproterozoic era.