Quantitative evaluation of weathering degree through Fuzzy-AHP method and petrophysics analysis for sandstone carvings

Natural Hazards - The assessment of weathering degree of sandstone carvings plays an important role in scientific conservation. However, the current state of weathering assessment research cannot...     

香港的考古文物、古迹与岩画

香港地区考古发现多种石器及离岛的"石壁画龙"-岩画,均属新石器时代文物.发现铜器、陶器等也不少,有些有隶书年号,为周、秦时代文物.香港自南北朝以来,与两广、福建和中原地区来往密切,遗留许多名胜古迹.     

On the stability of gold-silver alloys in the weathering environment

Thermodynamic analysis of the stability conditions for gold-silver solid solutions reveals that the silver component is unstable with respect to chlorargyrite and silver sulfate in most weathering environments. As a consequence supergene (secondary) gold and gold found in modern river placers (detrital and authigenic) tends to be pure. Impure, detrital placer gold is subject to natural purification processes as evidenced by silver depleted, spongey grain margins. In contrast, under hydrothermal conditions the silver content of primary gold can be controlled by equilibrium reactions with argentite.     

Modelling the physical and chemical changes in roofing slate caused by weathering processes

This research identifies the changes which takes place in roofing slate due to natural exposure and tries to replicate these changes experimentally. Traditional methods of testing, used by the British and other national standards, concentrate on the properties of unweathered samples and give no information on the relative durability of the different slates. Instead of concentrating on the initial properties, this research focuses on changes in the properties in order to assess durability. The effects of natural weathering were assessed by comparing old, used slates with new slates from the same or a similar source. The new slates were then weathered experimentally by repeated cycles of wetting and drying, and the increase in water absorbency compared with that observed in naturally weathering. Mineralogical differences due to both natural and experimental weathering were also measured using X-ray diffraction analysis. It was found that the effects of experimental weathering, using repeated cycles of wetting and drying, are similar to those observed in natural weathering. These include increased water absorbency and loss of crystallinity of the principal minerals. The greatest changes are found in those slates which are the most vulnerable to weathering, making it possible to identify poor quality slates.     

Concentration mechanisms of iron oxides and alumina in deep weathering crusts (Goshikidai, Kagawa, Western Japan)

Concentration of Fe-oxides and alumina in weathering processes are main geological reactions for lateritization and bauxitization, respectively. In western Japan, red-coloured soil formed by weathering processes developed in many places. This soil is composed of hydrous Fe-oxide minerals, hydrous alumina minerals and other minerals. It was formed in the upper part of deep weathering crust by weathering processes under some kind of sub-tropical climate, probably in the Pliocene. One of these occurrences is observed in the upper part of Goshikidai and Konodai, west part of Takamatsu city, northeast Shikoku Island, west Japan. A deep weathering crust is distributed on wide hilly plains ranging from 250 to 400 m a.m.s.l. in the northwestern region of Takamatsu city. Original rock of the weathering crust is bronzite andesite and glassy bronzite andesite, so-called ‘sanukite’. The andesites had been weathered under some special climate, and the geological age of the weathering is the same as above. The mineral assemblage and formation mechanism are similar to those of laterite and bauxite. The weathering crust developing in this region are subdivided into the three following zones: (1) A zone, composed of hydrous Fe-oxides and metahalloysite with small amounts of gibbsite and it is associated with white veins of metahalloysite; (2) B zone, composed of hydrous Fe-oxides and metahalloysite (some material is associated with -cristobalite); and C zone, composed of metahalloysite or halloysite and -cristobalite with relict crystals of feldspar and quartz, and some material is associated with montmorillonite. Chemical analyses of the materials of the three zones show the formation mechanisms of the weathering crust.     

Mineralogical changes during intense chemical weathering of sedimentary rocks in Bangladesh

Bangladesh is situated in a subtropical to tropical climatic zone. A recently weathered crust has developed on sedimentary bedrock (sandstone, siltstone, shale and claystones) of Tertiary–Quaternary age. Weathered samples were collected from 16 sections totaling 68 samples and were analyzed mineralogically. The main primary minerals identified in the weathered crust of sedimentary rocks are quartz, plagioclase, K-feldspar, biotite, muscovite, sparse carbonate and epidote. The secondary minerals are kaolinite, illite, chlorite, gibbsite and goethite. Weathering initiated along the grain boundaries and cleavage planes of the minerals, forming small cloudy materials which were very difficult to identify. In the advanced stage of weathering, these cloudy materials have turned into secondary minerals. In region 1, high rain fall (7100 mm/yr) and monsoonic climate resulted in a kaolinite–gibbsite–goethite suite through the weathering of feldspars and biotite. The occurrence of gibbsite in the relatively elevated lands of Sylhet and Fe-kaolinite throughout the study areas is indicative of a humid–tropical climate during formation of the weathered crust.     

Comparative evaluation of landslide susceptibility in Minamata area, Japan

Landslides are unpredictable; however, the susceptibility of landslide occurrence can be assessed using qualitative and quantitative methods based on the technology of the Geographic Information Systems (GIS). A map of landslide inventory was obtained from the previous work in the Minamata area, the interpretation from aerial photographs taken in 1999 and 2002. A total of 160 landslides was identified in four periods. Following the construction of geospatial databases, including lithology, topography, soil deposits, land use, etc., the study documents the relationship between landslide hazard and the factors that affect the occurrence of landslides. Different methods, namely the logistic regression analysis and the information value model, were then adopted to produce susceptibility maps of landslide occurrence. After the application of each method, two resultant maps categorize the four classes of susceptibility as high, medium, low and very low. Both of them generated acceptable results as both classify the majority of the cells with landslide occurrence in high or medium susceptibility classes, which could be believed to be a success. By combining the hazard maps generated from both methods, the susceptibility was classified as high–medium and low–very low levels, in which the classification of high susceptibility level covers 6.5% of the area, while the areas predicted to be unstable, which are 50.5% of the total area, are classified as the low susceptibility level. However, comparing the results from both the approaches, 43% of the areas were misclassified, either from high–medium to low–very low or low–very low to high–medium classes. Due to the misclassification, 8% and 3.28% of all the areas, which should be stable or free of landsliding, were evaluated as high–medium susceptibility using the logistic regression analysis and the information value model, respectively. Moreover, in the case of the class rank change from high–medium susceptibility to low–very low, 35% and 39.72% of all mapping areas were predicted as stable using both the approaches, respectively, but in these areas landslides were likely to occur or were actually recognized.     

乌干达苏库卢碳酸岩风化壳成矿元素地球化学评价指标

碳酸岩是一种特殊的火成岩,常与多种成因类型的矿床密切相关,故引起国内外学者的广泛关注。笔者以乌干达苏库卢碳酸岩风化壳为研究对象,选取区内典型剖面AB和钻孔ZK14(W),应用剖面地球化学异常和钻孔地球化学异常的方法总结了矿床的成矿规律和成因。笔者提出采用[w(Nb_2O_5)*w(REO)*w(TFe)*1000]/w(P_2O_5)累乘比值作为矿体剥蚀的判别指标(K_1),得出:强风化区K_1500,半、弱风化区500K_1100,碳酸岩原岩K_1100。同时,本文首次尝试为地球化学勘查理论适用于风化壳矿床提供勘查实例。     

Quantitative studies of weathering in saprolitized charnockites associated with a landslip zone at the porthimund dam,India

Studies on saprolitized charnockites associated with a landslip observed in the Blue Mountains in close proximity of the Porthimund Dam (11°22'E 76°34′30″N), Nilgiris District, Tamilnadu State, South India, are reported.Laboratory investigations of the geotechnical properties were carried out to evaluate the nature and degree of weathering quantitatively for estimating the soundness of the charnockites constituting the slip zone. The results of per cent decomposed product of the crest, scarp and toe portions of the slip denote positive correlations with porosity and compressibility; and negative correlations against density, wave velocity, Young's modulus, compressive strength and tensile strength. It is also seen that in the absence of the information on decomposed product, weatherability could still be evaluated considering the per cent change of any physical parameter.Such studies should prove valuable in the mapping of weatherability zones and the assessment and determination of foundation conditions.     

Source mechanisms and tectonic significance of historical earthquakes along the nankai trough,Japan

Two recent and three historical earthquakes which occurred along the Nankai trough, marking the northern plate boundary between the Philippine Sea and the Asian Plate, are studied mainly on the basis of the data of crustal deformations and tsunami waves. These earthquakes are the 1946 Nankaido, the 1944 Tonankai, the 1854 Ansei I, II and the 1707 Hoei earthquakes. They are all interpreted as low-angle thrust faults at the plate boundary, with the oceanic side underthrusting northwestward against southwestern Japan. The fault parameters of the historical earthquakes are assumed here to be common to those of the recent two earthquakes, except for the magnitude of dislocation.The entire fault region, which extends for 530 km from western Shikoku Island in the west to the Tokai district in the east, is divided into four fault planes, which are denoted the planes A, B, C and D, from west to east, respectively. Then, the five earthquakes may be attributed to the planes A, B, C and D, in the following manner: the Nankaido earthquake, A + B; the Tonankai earthquake, C; the Ansei II earthquake, A + B; the Ansei I earthquake, C + D; and the Hoei earthquake, A + B + C + D.The latest cycle of earthquake migration seems incomplete as proved by the recent inactivity in D. Consequently, the future major earthquake next to occur is expected there, off the Tokai district. Eight further ancient earthquakes from A.D. 684 to 1605 are also discussed. Taking the results of the foregoing studies into consideration, their sequence is well interpreted by the four migration cycles. Topographical data, tilt of coastal terraces and location of hinge lines, prove that the thrusting has continued all along the extension of the Nankai trough for at least 300,000 years.     

Assessment of rock slope stability with the effects of weathering and excavation by comparing deterministic methods and slope stability probability classification (SSPC)

Cut slopes are prone to fail due to the disturbance on original geometry and strength. In addition, because of these disturbances and stress relief, natural apertures which increase the weathering effects widen in engineering time. Owing to these reasons, slope stability assessment has a prominent role on these road cuts. Generally, slope stabilities are assessed by deterministic approaches with a significant engineering judgment. Because of this reason the reputation of probabilistic approaches is increasing. In this study, 20 road cuts located in North West Black Sea region of Turkey were evaluated using slope stability probability classification (SSPC). Considering this probabilistic approach, rock strength parameters and failure mechanisms were determined. Furthermore, slope mass rating (SMR) classification was applied for each road cut in order to compare with the results obtained from SSPC. These overall results were then evaluated with the field observations considering rockslope deterioration assessment (RDA) and Falling Rock Hazard Index (FRHI) for the disturbed/weathered zones, and failure mechanisms. According to these, SSPC is found to be more accurate for surficial degradations (raveling and fall) using samples taken from the disturbed/weathered zones rather than using relatively fresh samples beyond the disturbed zone. Moreover, despite strength differences between weathered and relatively fresh zones, SMR classification is identified to reveal the same stable probabilities. It is found that SSPC shows more detailed probabilistic results than SMR. Lastly, rockfall and raveling mechanisms determined by RDA and rockfall risk by FRHI were found to be coherent with SSPC and field observations.     

Weathering damage evaluation of rock properties in the Bunhwangsa temple stone pagoda,Gyeongju, Republic of Korea

The stone pagoda of the Bunhwangsa temple in Republic of Korea was made of piling small brick-shaped stones. The majority of stone bricks are andesitic rocks with variable geneses. Rock properties of the pagoda roof suffer partial significant deterioration, such as multiple peel-offs, exfoliation, onion-peel-like decomposition, cracks forming round lines and falling-off stone pieces. The stylobates and tabernacles at the four corners are composed of granitic rocks, which are heavily contaminated by lichens and mosses. Some of these contamination marks show dark black or yellowish brown colors by inorganic secondary hydrates. The four tabernacles and northern face of the pagoda body have been exposed to relatively high humidity, which causes light gray efflorescence as stalactites between the northern and western sides of the body. The efflorescences are composed of calcite, gypsum and clay minerals. The stone lion statues at the southeast and northeast corners are made of alkali granite, while the others are lithic tuff. Total rock properties of the pagoda consist of 9,708 stone bricks. Among them, 11.0% are fractured, 6.7% are fallen off, and 7.0% show considerable surface efflorescence, which shows that the pagoda has been highly deteriorated by physical, chemical and biological weathering. The authors strongly suggest long-term monitoring and comprehensive conservation researches.     

The detection of weathering in coal by petrographic,rheologic and chemical methods

This study examines petrographic, rheologic, proximate and ultimate analyses techniques, to investigate the effects of natural weathering on coal. The applicability of such tests to both the detection of weathering and to the prediction of the properties of a fresh coal, based upon analyses of a weathered sample, is discussed.Rheologic parameters and a petrographic staining technique showed the most sensitive response to weathering. The latter test is considered the most suitable of these for the detection of weathering, as it is independent of prior knowledge of the properties of the fresh coal and of the petrographic composition. A petrographic approach is also considered most suitable for estimation of fresh coal characteristics from weathered samples. Rank may be closely approximated and petrographic type determined microscopically, even on highly weathered samples, and these two parameters may be used to estimate properties such as volatile matter, calorific value and dilatation. Minor modification should be made to vitrinite reflectance measurements, according to the degree of weathering as revealed by selective staining.     

强烈气洗作用导致原油成分变化的定量计算:以库车坳陷天然气藏为例

库车坳陷以产天然气为主,同时产出少量原油和凝析油,油气充注不同步,普遍具有"油早气晚"的特点,晚期大量天然气的侵入,必然对早期聚集的油藏发生改造作用。对气藏中原油成分变化的定量计算和讨论,可为天然气的注入强度定量评价提供直接证据。未遭受气洗的原油,正构烷烃摩尔浓度的对数与相应的碳数呈线性关系,而气洗作用可使轻组分的正构烷烃最先溶解于干气中,并随着天然气继续向前运移,原始油藏中的轻组分正构烷烃大大减少。以此为理论基础,建立了正构烷烃损失的定量计算模型。结果表明克拉2构造原油正构烷烃损失程度最高,平均可达70%左右,大北构造带原油正构烷烃损失程度差异较大,与该地区断块发育有关。气洗作用导致原油正构烷烃减少,而金刚烷、多环芳烃等在天然气中溶解度较低的化合物得以浓缩富集,相对含量大大增加。轻芳烃含量也会随之而增加,原油芳香度增加,石蜡度降低。在模拟实验基础上对气洗程度进行了定量评价,初步估算表明,克拉2构造原油遭受的气洗作用最强,是其他构造带的2～5倍。     

Long-term stability of flow-path structure in crystalline rocks distributed in an orogenic belt, Japan

Most evaluations of the contaminant retardation processes likely to be important in geological disposal (e.g. for high level radioactive waste (HLW)) consider only the present characteristics of fractures and associated mineral infills. Relatively little attention has been given to possible long-term changes in these features, and their influence on groundwater flow. The work reported here seeks to provide analogous evidence that such changes are not likely to be important and hence to improve confidence in the presently adopted evaluation methodology and its long-term applicability.

In the orogenic belt that is formed by the Japanese islands, there are wide areas of crystalline rock. The rocks in each area have a distinctive age sequence which is partly reflected in the characteristics of the fracture systems and associated mineral fillings that occur. These characteristics generally imply that groundwater and solutes can be conducted through fracture networks, except in the cases of fault zones or crushed zones. The structural and mineralogical features of these networks readily illustrate how certain contaminants might react and be retarded by the fracture fillings and open pore geometry, due to chemical sorption and/or physical retardation.

Here, we describe the fracture systems developed in crystalline rocks with different ages that are intruded into the Japanese orogenic belt. The aim is to build a model for the long-term fracturing process and hence to evaluate fracture ‘stability’. In particular, the comparisons are made between the fracture geometries and the frequencies observed in the 1.9–0.8 Ma Takidani Granodiorite (the youngest exposed pluton in the world), the ca. 67 Ma Toki Granite and the ca. 117 Ma Kurihashi Granodiorite located in central to northwest Japan. The observations show that all these crystalline rocks have similar fracture frequencies, with 1 to 2 fractures per meter in the massive part of rock bodies. Mineralogical studies and dating analyses of fracture fillings also suggest that fractures are relatively physically stable. Major new fractures tend not to be created in the massive part of rock bodies even when a pluton has been subjected to the regional stresses of plate movements with a duration of about 100 Ma. The results show the unique characteristics of the fracture forming process and the relatively stable geometries of fracture network systems in crystalline rocks distributed within the orogenic belt. This analogue also enables us to provide a model to build confidence in a technical approach applicable for modeling of hydrogeology and geology over long time scales under the orogenic stress field present in Japan. The model may also be useful for other stable tectonic settings as well as for a characterizing sites in crystalline rocks for the possible geological disposal of HLW and other toxic wastes.     

成都金堂李家梁子M23号墓石棺构件矿物组成及风化机理研究

成都金堂李家梁子M23号墓出土的汉朝石棺存在表面粉化、剥落等病害现象,急需保护修复。现场调查表明,该石质文物风化病害主要表现为裂隙状风化、页片状风化、粒状风化、粉末状风化等。本文借助X射线衍射(XRD)、偏光显微镜、扫描电镜等对金堂石质文物进行了微观成分及结构分析。结果表明,文物材质为红色砂岩,其碎屑物主要为石英、钠长石、岩屑和少量云母,胶结物以钙质为主,含少量的炭质及泥质。该砂岩产生风化病害的主要原因是钙质胶结物的溶解流失及泥质胶结物遇水的崩解,同时还受岩屑、长石类碎屑风化蚀变的影响。该研究可为石棺的后期保护修复工作提供基础科学数据。     

Natural building stone composed of light-transmissive minerals: impacts on thermal gradients,weathering and microbial colonization. A preliminary study,tentative interpretations,and future directions

A number of modern buildings employing claddings of granites or marbles have experienced bowing of the rock panels together with weathering of the material. Theoretical and field-based data analysis and laboratory experimentation have assumed that heat exchange resulting from incoming solar radiation is at the material surface. However, a number of recent experiments have clearly shown that some lithologies, including both marble and granite, comprise a number of light-transmissive minerals that significantly change the thermal responses in the outer few millimetres of the rock. Further, this translucence will create mineral-to-mineral stresses where light-transmissive minerals are in contact with opaque ones. The whole is further exacerbated by differences in thermal coefficients of expansion and conductivity which themselves may depend on the mineral axis; surface modifiers such as paints further complicate the situation. The degree of light penetration, based on field measurements, can be significant and can facilitate rapid changes in temperature (ΔT/Δt > 2°C min⁻¹) at depth within the rock thereby increasing the sub-surface stresses. The amount of light penetration for any given mineral will be dependent upon material slope, the latitude, season, and albedo. Albedo is identified as a complex variable, changing as a function of the angle of the sun to the particular surface; polished surfaces, as often with cladding, will further influence this. Data analysis suggests that, in the Northern hemisphere, south of the polar circle, the summer may not be the time of the largest heat loading on the southern aspect and that larger loadings, coupled with lower air temperatures, occur early and late in the year. This seasonal impact has great potential for thermal stresses on the southern aspect. The presence of light-transmissive minerals also allows sub-surface biotic colonization and results in weathering. Overall, where light transmissive minerals/lithologies occur the thermal responses are highly complex and in need of more rigorous consideration.     

Mineralogical and chemical changes of soil and stream sediment formed by intense weathering of the Danburg granite, Georgia, U.S.A.

A series of soil and stream sediments developed during intense weathering on the metaluminous Danburg granite, northeastern Georgia, U.S.A., have been analyzed mineralogically and chemically. The concentrations of Ba, Na, Rb and Cs in the silt and coarser fractions are controlled mainly by feldspars and biotite. Hf is controlled by zircon, and the REE (rare-earth elements) and Th are largely controlled by sphene. Variations in feldspar, sphene and zircon may produce small variations in Eu/Sm and La/Lu ratios. Ferromagnesian minerals control Ta, Fe, Co, Sc and Cr concentrations.

The mineralogical and chemical composition of the Danburg granite is more closely reflected in the silt than in the sand or gravel fractions of stream sediments. In the silt, the contents of Rb, REE, Th, Ta, Fe, Co and Sc and the ratios of La/Sc, Th/Sc, La/Co, Th/Co, Eu/Sm and La/Lu are similar to those in the unweathered granite. In contrast, these element contents or ratios in the sands and gravels are 0.05−3× the concentration in the unweathered granite. Ta and Ba contents are an exception to the above. The Ta and Ba contents of the sands and gravels are similar to those of the granite.

In the kaolinite-halloysite clays, the content of Na is depleted relative to the source. Rb, Cs, Ba, Hf and Ta are depleted or enriched in the clays relative to the source, while the REE, Th, Fe, Co, Sc and Cr are enriched. The Eu/Sm (Eu anomaly size) and La/Lu ratios, and the REE patterns of the clays are similar to those of the source.

Thus, the mineralogy and element contents of a siltstone developed from metaluminous, granitic sources during intense weathering would be expected to be more similar to the source rock than the sandstones and conglomerates. Claystones should contain similar REE patterns and Eu/Sm ratios as the source rock, but such fine-grained sediments might represent much larger areas of source rocks than the more locally derived sandstones or conglomerates.     

贵州铜仁地区锰矿定量预测与评价

应用地质、化探、物探、遥感等手段和资料进行多元信息成矿预测已成为找矿工作的重要方法。以贵州铜仁地区锰矿为研究对象,基于研究区与成矿相关的多元信息,建立区域找矿模型;运用GIS技术对多元信息进行综合处理并提取有利成矿信息,形成找矿标志专题图层,构成找矿预测指标集;利用证据权重法建立锰矿综合预测模型,结合研究区成矿地质条件、已知锰矿床（点）等因素,确定找矿有利地区,并圈定7个远景区,为发现大规模锰矿产地提供参考。