Spatial and temporal distributions of mercury species and controlling factors in Hongfeng Reservoir, Guizhou, China

The Hongfeng Reservoir was built in 1960 and is an alkaline, hyper-eutrophic and seasonal anoxic reservoir due to the contamination from domestic and industrial wastewaters. The water samples at deferent depths from two sampling sites were collected from November 2003 to September 2004 using metal clean protocols. Total Hg （THg）, reactive Hg （RHg）, dissolved total Hg （DHg）, dissolved gaseous mercury （DGM） were measured by gold trap pre-concentration and CVAFS detection. Methyl mercury was measured by distillation followed by aqueous phase ethylation, precollection on a Tenax, isothermal gas chromatography and cold vapor atomic fluorescence detection. There was no discernible seasonal trend （about 8 ng/L） in THg concentration based on the average information developed during the four cruises except for high concentrations at bottom and water-sediment interface in May and September 2004. On the other hand, particulate mercury （PHg） and methyl mercury have discernible seasonal variability. Proportion of PHg increased from 29% in February 2004 to 50% in May 2004. In November 2003, February and May 2004 methyl mercury concentrations were relative low and increased with depth （from 0.13 to 0.40 ng/L）. In September 2004, methyl mercury concentrations increased from 0.14 ng/L in the epilimnion to 0.99 ng/L in the hypolimnion. DGM concentrations varied from 0.024 to 0.11 ng/L and decreased with depth.     

Preliminary Statistics of Temperatures and Pressures for Formation of Eclogites, Granulites and Peridotites in China

The rock-forming temperatures and pressures represent the p-T points of the local regions in the lithosphere at a certain age, providing some important information on rock formation. Based on the preliminary statistics on the temperatures and pressures for the formation of eclogites, granulites and peridotites in China, the variant ranges are given, in this paper, of temperatures, pressures and linear geothermal gradients of eclogites, granulites and peridotites. In addition, since the eclogite is different from granulite and peridotite in the p-T diagram, these three rocks can be classified into two groups: the first group includes eclogites and the second group granulites and peridotites. Then, the p-T correlation functions of these two groups of rocks are provided. Finally, the two groups of rocks have different geothermal gradients at the same pressure gradient or have different pressure gradients at the same geothermul gradient. The temperatures and pressures for the formation of the rocks can be calculated from the mineral chemical compositions, but the depths (H) for the rock formation can be calculated only under the hypotheses of given p-H (or T-H) correlation functions. The explanations for the ultrahigh pressure metamorphism vary obviously with different hypotheses.     

Geodynamics on Formation and Evolution of Bohaiwan Basin,China

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Microtexture and Distribution of Minerals in Hydrothermal Barite-Silica Chimney from the Franklin Seamount, SW Pacific: Constraints on Mode of Formation

An extinct hydrothermal barite-silica chimney from the Franklin Seamount of the Woodlark Basin, in the southwestern Pacific Ocean, was investigated for mineral distribution and geochemical composition. Six layers on either side of the orifice of a chimney show significant disparity in color, mineral assemblage and major element composition. Electron microscope(SEM) images reveal that the peripheral wall of the chimney is composed of colloform silica, suggesting that incipient precipitation of silica-saturated hydrothermal fluid initiated the development of the chimney wall. Intermediate layers, between the exterior wall and the inner fluid-orifice, dominate with barite and sulfides. Low Sr-to-Ba ratios(SrO/BaO = 0.015–0.017) indicate restricted fluid-seawater mixing, which causes relatively high-temperature formation of the intermediate layers. Whereas the innermost layer bordering the chimney orifice is characterized by more silica and a higher Sr-to-Ba ratio(SrO/BaO = 0.023), could have formed due to a paragenetic shift from a high-temperature active phase to a cooler waning stage of formation. A paragenetic shift is also probably responsible for the change in mineral formation mechanism that resulted in the textural variation of barite and colloform silica developed during different growth phases of this barite-silica chimney.     

Sedimentology and facies analysis of Miocene mixed siliciclastic–carbonate deposits of the Dam Formation in Al Lidam area,eastern Saudi Arabia

The Burdigalian mixed siliciclastic–carbonate deposits of the Dam Formation are well-exposed in Al Lidam area, in the eastern province of Saudi Arabia. They represent a shallow part of the Arabian plate continental margin. The Dam Formation is correlatable to the Miocene reservoirs in both Iran and Iraq. Therefore, studying the Dam Formation lithologic heterogeneity in a small distance with high resolution could help in further work related to pattern prediction of the Miocene reservoir properties. High-resolution sedimentological investigation was carried out through six outcrops. The facies parameters (lithology, sedimentary structures, main fossils, paleocurrent patterns and geometries of the sedimentary bodies) were described. The results revealed 15 lithofacies that have been further grouped into 7 lithofacies associations 5 of which are carbonates and include (1) interbedded dolostone and evaporates, (2) microbialite buildup, (3) ooid-dominated grainstones, (4) burrowed skeletal peloidal wackestone–packstone and (5) mollusc-dominated wackestone–packstone. The remaining two associations are of siliciclastics and include (6) intertidal siliciclastics and (7) wave-dominated siliciclastics. These lithofacies were interpreted to reflect deposition in a mixed siliciclastic–carbonate ramp system that includes subtidal, shoreface, intertidal, foreshore, supratidal and estuarine deposits in a shallowing-upward succession. Each one of these lithofacies association has distinct geometry and architecture pattern. Oolites and heterozoan lithofacies occur as sheets and show great continuity along the strike direction. Oolites pass laterally in the dip direction into more skeletal- and peloid-dominated zones, whereas heterozoan lithofacies stay continuous in the dip directions and change from siliciclastic to carbonate heterozones. In contrast, microbialite lithofacies lack continuous beds and occur as localised bioherms and biostroms. Channelised lithofacies are restricted laterally into isolated channel bodies and vertically in the contact boundary between siliciclastic and carbonate lithofacies, whereas the interbedded dolostone and evaporite lithofacies form distinct, relatively thick continuous layers. With continuous exposures in both strike (1.2 km) and dip (0.15 km) directions, the outcrops in the Al Lidam area provide unique opportunity to study the heterogeneity among lithofacies of the mixed siliciclastic–carbonate system of the Dam Formation. Such study may provide insights to predict occurrence and distribution of lithofacies bodies in their equivalent reservoirs which are important for reservoir characterisation.     

SHRIMP zircon U–Pb ages of eclogite and orthogneiss from Sulu ultrahigh-pressure zone in Yangkou area,eastern China

We report SHRIMP U–Pb age of zircons in four samples of eclogite and one sample of orthogneiss from Sulu ultrahigh-pressure (UHP) zone in Yangkou area, eastern China. UHP rocks are distributed along the Sulu orogenic belt suturing North China Block with South China Block. In Yangkou area, UHP unit is well exposed for about 200 m along Yangkou beach section and consists mainly of blocks or lenses of ultramafic rocks and eclogite together with para- and orthogneiss which are highly sheared partly. Zircon grains examined in this study from eclogite show oscillatory zoning and overgrowth texture in CL images, and most of the grains have high Th/U ratio ranging from 0.8 to 2.1 indicating an igneous origin. The weighted mean ²⁰⁶Pb/²³⁸U ages of zircons from the four samples range from 690 to 734 Ma. These ages can be correlated to the magmatic stage of the protoliths. In rare cases, zircon grains possess a narrow rim with very low Th/U ratio (< 0.02). EPMA U–Th-total Pb dating of such rim yields younger ages that range from 240 to 405 Ma marking the metamorphic stage. On the other hand, zircons from the orthogneiss show irregular shape and zoning with inclusion-rich core and inclusion-free rim. These grains of zircon yield U–Pb discordia intercept ages of 226 ± 63 Ma and 714 ± 110 Ma (MSWD 0.78). Bulk of the areas of the rims rim of the zircons demonstrate younger ²⁰⁶Pb/²³⁸U ages close to the upper intercept, with low Th/U ratio (< 0.20) indicating their metamorphic origin. In contrast, the cores show older ²⁰⁶Pb/²³⁸U ages close to lower intercept and high Th/U ratio of (0.14–5.25) indicating their igneous origin. The upper intercept age is also commonly noted in zircons from eclogite. Our results suggest a bimodal igneous activity along this zone during the Neoproterozoic, probably related to the rifting of the Rodinia supercontinent.     

Tectonic evolution of Tarim basin in Cambrian–Ordovician and its implication for reservoir development,NW China

In order to find the impact of regional tectonic evolution of Tarim basin on the inside distribution of sedimentary facies and reservoir development, this paper, based on the research of plate-tectonic evolution of Tarim basin, conducts an in-depth analysis on the basin’s inside sedimentary response to the Eopaleozoic regional geodynamic reversion from extension to convergence around Tarim plate, and concludes that the regional geodynamic environment of surrounding areas closely contributes to the formation and evolution of paleo-uplifts, differentiation of sedimentary facies in platform, distribution of high-energy reef and bank facies belts, conversion of sedimentary base level from fall to rise, obvious change of lithology from dolomite to limestone, and formation of several unconformity surfaces in Ordovician system in the basin. A series of sedimentary responses in the basin are controlled by regional dynamic setting, which not only controls the distribution of reservoirs in reef and bank facies but also restricts the development and distribution of karst reservoirs controlled by the unconformity surfaces. This offers the macro geological evidences for us to further analyze and evaluate the distribution of favorable reservoirs.     

Well log analysis and hydrocarbon potential of the Sa'ar–Nayfa reservoir,Hiswah Oilfield,eastern Yemen

Sa'ar–Nayfa reservoir is mainly made up of carbonate sediments with bands of shale that contain a substantial amount of proven oil in the Hiswah Oilfield, Sayun–Masila Basin, eastern Yemen. Several vertical wells have been drilled and penetrated these sequences. This study is concerned on the petrophysical evaluation and well log analysis of the Lower Cretaceous of 11 wells at the Hiswah Oilfield, Hadramawt Governorate, eastern Yemen. Computer-assisted log analyses were used to evaluate the petrophysical parameters such as shale volume, total porosity, effective porosity, water saturation, hydrocarbon saturation, flushed zone saturation and reservoir and pay flags. Cross-plots of the petrophysical parameters versus depth were illustrated. The Lower Cretaceous Sa'ar–Nayfa reservoir reflects that the matrix components are mainly carbonates and shales. Moreover, the lithological-geologic model reflected that these shales are strongly affecting the porosity and, consequently, the fluid saturation in the Sa'ar–Nayfa reservoir. In this study, the thickness of the Sa'ar–Nayfa reservoir increases from central toward north-eastern and north-western parts within the Hiswah Oilfield. The porosities analyses of the investigation of the Sa'ar–Nayfa reservoir for the 11 studied wells concluded that the average total porosity ranges from 5.4 % to 16.8 % while the effective porosity ranges from 5.2 % to 14.8 %. Water saturation of the Sa'ar–Nayfa reservoir ranges from 6.9 % to 75.8 %. On the other hand, hydrocarbon saturation matches with water saturation in a reverse relationship. Sa'ar–Nayfa reservoir is interpreted as good quality reservoir rocks with high average effective porosity reaching to 20 % and high hydrocarbon saturation exceeding 93 %. The Sa'ar–Nayfa reservoir reveals promising reservoir characteristics especially the upper reservoir unit, which should be taken into consideration during future development of the oilfields area. The hydrocarbon saturation map of the Sa'ar–Nayfa reservoir shows a regular pattern of distribution with a general increasing to the northeast, northwest and east directions while decreasing southwest wards, recording the maximum value of 93.1 % at the Hiswah-21 well.     

Mesozoic–Cenozoic sedimentary rock records and applications for provenance of sediments and affiliation of the Simao Terrane,SW China

ABSTRACT

As the north part of Simao Terrane, Lanping Basin is located between the Sanjiang Tethys Orogen (STO) and Yangtze Block, also the junction zone between the Gondwanaland and Cathaysian old land (Pan Huaxia mainland), which includes Yangtze and Cathaysian Blocks. The aim of this study is to decipher the provenance of the sedimentary units in the Lanping Basin and affiliation of Simao Terrane by the U-Pb ages, Hf isotope of detrital zircons and whole-rock geochemistry. The whole-rock geochemistry and the mineral composition indicate that most of the Triassic–Paleocene sedimentary rocks are derived from the upper crust and exhibit recycled orogen features. The detrital zircon U-Pb ages from the North Simao Terrane are consistent with the magmatic events during Early Neoproterozoic and Permian in the Western Yangtze Block. And the detrital zircons ages from North Simao Terrane show same distribution features as the Permian–Triassic magmatic rocks, which are distributed in the Simao Terrane and along major sutures. These comparisons suggest that the clastic sediments in Lanping Basin (North Simao Terrane) are derived from Early Neoproterozoic and Permian magmatic rocks from Western Yangtze Block, Permian–Triassic magmatic rocks from Simao Terrane, along Jinshajiang, Garz-Litang and Ailaoshan Sutures. The comparison of the detrital zircon age distributions shows that Simao Terrane and Yangtze Block exhibited similarity tectonic setting in the evolution history, especially during Paleoproterozoic–Late Paleozoic. This suggests that the Simao Terrane is part of Cathaysian old land, although Simao Terrane was separated from Yangtze Block for short period during Early Paleozoic. Besides, the Hf mapping, stratigraphic succession, paleogeography and paleomagnetism in SW China support that Simao Terrane has a Cathaysian old land-affinity, rather than one involving Gondwanaland.     

Geology, mineralization, and geochronology of the Qianhe gold deposit, Xiong’ershan area, southern North China Craton

The Qianhe gold deposit in the Xiong’ershan area is located along the southern margin of the Archean-Paleoproterozoic North China Craton. The deposit consists of six orebodies that are hosted in Paleoproterozoic andesites to basaltic andesites and structurally controlled by roughly EW-trending faults. Individual orebodies comprise auriferous quartz veins and disseminated Au-bearing pyrite within hydrothermally altered rocks on both sides of, or close to, the veins. Ore-related hydrothermal alteration has produced various mixtures of K-feldspar, quartz, sericite, chlorite, epidote, carbonate, and sulfides. Pyrite is the most important ore mineral, associated with minor amounts of galena, sphalerite, and chalcopyrite. Other trace minerals include molybdenite, arsenopyrite, scheelite, rutile, xenotime, and parisite. Gold occurs mostly as native gold and electrum enclosed in pyrite or along microfractures of sulfides and quartz. Microthermometric measurements of primary inclusions in auriferous quartz suggest that gold and associated minerals were precipitated in the range of 160–305 °C from aqueous or carbonic-aqueous fluids with salinities of 6–22 wt% NaCl equiv. Samples of molybdenite coexisting with Au-bearing pyrite have Re–Os model ages of 134–135 Ma, whereas ore-related hydrothermal sericite separates yield ⁴⁰Ar/³⁹Ar plateau ages between 127 and 124 Ma. The Re–Os and ⁴⁰Ar/³⁹Ar ages are remarkably consistent with zircon U–Pb ages (134.5?±?1.5 and 127.2?±?1.4 Ma; 1σ) of the biotite monzogranite from the Heyu-intrusive complex and granitic dikes in and close to the Qianhe gold mine, indicating a close temporal and thus possibly genetic relationship between gold mineralization and granitic magmatism in the area. Fluid inclusion waters extracted from auriferous quartz have δD values of ?80 to ?72 ‰, whereas the calculated δ ¹⁸O_H2O values range from 3.1 to 3.8 ‰. The hydrogen and oxygen isotopes from this study and previous work indicate that ore fluids were likely derived from degassing of magmas, with addition of minor amounts of meteoric water. Gold mineralization at Qianhe is temporarily coincident with pervasive bimodal magmatism, widespread fault-basin formation, and well development of metamorphic core complexes in the whole eastern North China Craton that have been interpreted as reflecting reactivation of the craton in the late Mesozoic after prolonged stabilization since its formation in the late Paleoproterozoic. It is therefore concluded that the Qianhe gold deposit formed as a result of this craton reactivation event.     

Distribution and behavior of heavy metals in a river polluted by acid mine drainage in the Dabaoshan mine area, China

Acid mine drainage （AMD） has been recognized as a major environmental pollution problem over past decades. This pollutant effluent is complex and is characterized by elevated concentrations of iron and sulfate, low pH, and high concentrations of a wide variety of metals depending on the host rock geology. Massive inadvertent discharges from acid mines have given rise to dramatic cases of ecological damage. These events indicate an improved understanding of the mechanism controlling metal transport to the river is important, since the aquatic ecology will be affected, to some degree, dependent on the phase （dissolved or particulate） in which the metal is transported. In this study, polluted water samples were collected along the Hengshi River near the Dabaoshan mine, Guangdong, China, in April 2005. The concentrations of dissolved Cu, Zn, Cd and Pb have been determined using ICP-MS and the chemical speciation of those metals in suspended particles was examined using BCR methods and SEM/EDX mineralogical analysis. Combining these two sets of data, the intention was to develop geochemical concepts, which explain the behavior of Cu, Zn, Cd and Pb in particle-water interactions of heavy metals in AMD. The results show that the dissolved heavy metals exhibited non-conservative behavior in the Hengshi River. The dissolved and particulate Cu, Zn, Cd and Pb have the similar spatial distribution, which decreased gradually along the river except in the lower reaches because of the absorption-desorption between dissolved and particulate phases. Although the metal concentrations in both phases were elevated, dissolved metals were dominant and had the maximum concentrations in the low pH region.     

U–Pb dating of zircons from tuff layer,sandstone and tillite samples in the uppermost Liantuo Formation and the lowermost Nantuo Formation in Three Gorges area,South China

Uranium-lead (U–Pb) dating was conducted on zircons in tuff layers and sandstone samples from the uppermost Liantuo Formation and in a tillite sample from the lowermost Nantuo Formation in Three Gorges area, South China, using SHRIMP and LA-ICP-MS techniques. Zircons from these samples yielded age spectrum (within 1000 Ma) of ∼890, ∼830, ∼780, ∼730, and 646 Ma. Zircons from the Liantuo tuffs have a weighted mean ²⁰⁶Pb/²³⁸U age of 734.1 ± 8.1 Ma (2σ, n = 7, MSWD = 0.48), which was regarded as the best estimation of the upper boundary age of the Liantuo Formation. Combining with previous geochronologic data, the Liantuo Formation was proposed to be a pre-Chang′an glaciation unit, and it is comparable to the middle-upper Banxi/Danzhou Group in South China.     

Geology and genesis of Kafang Cu–Sn deposit,Gejiu district,SW China

Kafang is one of the main ore deposits in the world-class Gejiu polymetallic tin district, SW China. There are three main mineralization types in the Kafang deposit, i.e., skarn Cu–Sn ores, stratiform Cu ores hosted by basalt and stratiform Cu–Sn ores hosted by carbonate. The skarn mainly consists of garnet and pyroxene, and retrograde altered rocks. These retrograde altered rocks are superimposed on the skarn and are composed of actinolite, chlorite, epidote and phlogopite. Major ore minerals are chalcopyrite, pyrrhotite, cassiterite, pyrite and scheelite. Sulfur and Pb isotopic components hint that the sources of different types of mineralization are distinctive, and indicate that the skarn ore mainly originated from granitic magma, whereas the basalt-hosted Cu ores mainly derived from basalt. Microthermometry results of fluid inclusions display a gradual change during the ore-forming process. The homogenization temperature of different types of inclusions continuously decreases from early to late mineralization stages. The salinities and freezing temperatures exhibit similar evolutionary tendencies with the T _{homogenization}, while the densities of the different types keep constant, the majority being less than 1. Oxygen and hydrogen isotopic values (δ¹⁸O and δD) of the hydrothermal fluids fall within ranges of 3.1 to 7.7‰ with an average of 6.15‰, calculated at the corresponding homogenization temperature, and − 73 and − 98‰ with an average of − 86.5‰, respectively. Microthermometry data and H–O isotopes indicate that the ore-forming fluid of the Kafang deposit is mainly derived from magma in the early stage and a mixture of meteoric and magmatic water in late stage. Molybdenite Re–Os age of the skarn type mineralization is 83.4 ± 2.1 Ma, and the stratiform ores hosted by basalt is 84.2 ± 7.3 Ma, which are consistent with the LA-ICP-MS zircon age of the Xinshan granite intrusion (83.1 ± 0.4 Ma). The evidence listed above reflects the fact that different ore styles in the Kafang deposit belong to the same mineralization system.     

Conditions for the Formation of Oil and Gas Pools in Tertiary Volcanics in the Western Part of the Huimin Sag, Shandong and Their Distribution

Conditions for the Formation of oil and gas pools in Tertiary volcanics in the western part of the Huimin sag, Shandong and then (?)stribution have been studied based on the geological, seismic and well-logging information. In this paper, the types and lithofacies of the volcanic rocks in the western part of the Huimin sag are described; the relationship between rocks and electrical properties, the seismic reflection structures, the development and distribution of the volcanic rocks are expounded; and the fourfold role of the volcanic activities in the formation of the oil and gas pools is also dealt with. It is considered by the authors that the volcanic activities were not destructive to the formation of oil and gas pools but a factor favourable to the accumulation of organic matters and their conversion to hydrocarbon. The volcanic rocks might have served as reservoir rocks and cap rocks, or as a synsedimentary anticline. The prerequisites and important factors for the formation of oil and gas pools and their distribution are pointed out in the paper.     

Environmental geochemistry and ecological risk of vanadium pollution in Panzhihua mining and smelting area, Sichuan, China

1 Introduction Vanadium (V) is a relatively abundant elemenwhich is widely distributed in nature; howeverworkable V deposits are very rare (World HealthOrganization, 2001). Vanadium is a trace elementwhich may be beneficial and possibly essential fohuman…     

Distribution and fractionation of rare earth elements in soil–water system and human blood and hair from a mining area in southwest Fujian Province,China

Accumulations of rare earth elements (REEs) in human body through multiple pathways including food ingestion, air inhalation and dermal absorption have received considerable attention due to their chronic toxicity to human health. The distribution and fractionation of 14 REEs were conducted in soil, well water, human blood and hair in the vicinity of a large-scale mining site in southwest Fujian Province, China. The LREEs/HREEs ratios were 9.17 for soil, 2.18 for water, 36.93 for human blood and 7.24 for human hair, respectively. The distribution patterns of REEs in soil, human blood and hair samples were characterized by LREEs enrichment and HREEs depletion, but LREEs depletion and HREEs enrichment in water sample. La_N/Yb_N values of these samples ranged from 0.41 to 1.83, La_N/Sm_N values from 0.43 to 4.92, and Gd_N/Yb_N values from 0.81 to 4.71. Soil and human blood showed enrichments of Ce, Gd and Er, but water showed a depletion of Ce. In addition, the normalized patterns showed a weak negative anomaly of Eu in soil and a weak negative anomaly of Nd in human blood and hair. Consequently, enrichment and depletion of REEs differ significantly among soil, water and human blood and hair, thus the REEs after entering into human body can undergo fractionation effects.     

Detachment folding in a Lower Cambrian–Upper Permian karst reservoir: 3D model of the Yubei 3D area (eastern Markit Slope,Tarim Basin,Northwest China)

A three-dimensional (3D) structural modeling of the Lower Cambrian–Upper Permian Yubei 3D area was performed to understand its structural evolution. This model reproduces the present-day structure of the basin and comprises 11 horizons within Lower Cambrian to Upper Permian rocks. The analysis is based on 3D depth views and faults. The results image salt movements due to tectonics and/or burial. From these observations, this paper deduces that salt structures are correlated to the main faults and tectonic events. From the model analysis, we interpret the timing and geometry of Tarim Basin tectonics. The fault geometry can be resolved based on the strike of the fault, the morphology of hanging wall strata, and the stratigraphic distribution. Emphasis is placed on gypsum rock detachment, considering its movements during the Middle Caledonian event and decoupling effects during tectonic evolution. Moreover, we point to the structural control of the Paleozoic basement and the crustal architecture (Yubei 3D Zone) on the geometry of the Tarim Basin.     

Reprint of “Depositional environment and tectonic implications of the Paleoproterozoic BIF in Changyi area,eastern North China Craton: Evidence from geochronology and geochemistry of the metamorphic wallrocks”

The Changyi banded iron formation (BIF) in the eastern North China Craton (NCC) occurs within the Paleoproterozoic Fenzishan Group. Three types of metamorphic wallrocks interbedded with the BIF bands are identified, including plagioclase gneisses and leptynites, garnet-bearing gneisses and amphibolites. Protolith reconstruction suggests that the protoliths of the plagioclase gneisses and leptynites are mainly graywackes with minor contribution of pelitic materials, the garnet-bearing gneisses are Fe-rich pelites contaminated by clastics, and the amphibolites are tholeiitic rocks. Trace elements of La, Th, Sc and Zr of the plagioclase gneisses and leptynites and the garnet-bearing gneisses support that these meta-sedimentary rocks were probably derived from recycling of Archean rocks with felsic and mafic materials differentiated into different rock types. ²⁰⁷Pb/²⁰⁶Pb ages of detrital zircons from the meta-sedimentary rocks concentrate at 2.7–3.0 Ga, confirming their derivation from the Archean rocks. The presence of several Paleoproterozoic detrital zircons (2240 to 2246 Ma), however, also suggests minor involvement of Paleoproterozoic materials. The Archean detrital zircons have ε_Hf(t) values varying from − 0.7 to 7.6, which mainly fall between the 3.0 Ga and 3.3 Ga average crustal evolution lines on the age vs. ε_Hf(t) diagram, further illustrating that the rocks providing materials for the meta-sedimentary rocks mainly originated from partial melting of a Mesoarchean crust. This is strongly supported by their crust-like trace element distribution patterns (such as Nb, Ta, P and Ti depletion) and ancient Nd depleted mantle model ages (T_DM = 2.9–3.4 Ga). In addition, the remarkably high ε_Hf(t) values (7.5 to 9.3) of the Paleoproterozoic detrital zircons constrain the Paleoproterozoic materials to originate from a depleted mantle. The amphibolites show low SiO₂ (46.5 to 52.8 wt.%) and high MgO (5.68 to 10.9 wt.%) contents, crust-like trace element features and low ε_Nd(t) values (− 4.5 to − 0.3), suggesting that these ortho-metamorphic rocks were mainly derived from subcontinental lithospheric mantle with some contamination by Archean crustal materials. Since an intra-continental environment was required for the formation of the above metamorphic rocks, these rocks not only confine the depositional environment of the Changyi BIF to be an intra-continental rift, but also support the rifting processes of the eastern NCC during Paleoproterozoic.