生物标志的环境含义及其应用

生物标志,包括生物的壳体构造、生态特征、地球化学和群落组合等,在地球科学研究中具有十分重要的理论意义和实用价值。本文首先论述了影响生物生存的环境因素,包括地球因素和宇宙因素。并根据西南地区晚古生代地层中主要生物门类,特别是微体古生物的古生态,论证生物标志的环境含义。在此基础上,指出生物标志在地学研究中的应用,包括划分和对比地层、判断沉积相、分析古气候变化、划分生物地理区、推断海（湖）平面变化、指示地质找矿和阐释宇宙演变。最后,探讨生物标志的研究方法,包括分类统计学方法、形态构造学方法、地球化学方法和沉积埋藏学方法。     

Geochemistry of surface sediments in the southwestern East/Japan Sea

We analyzed 77 surface sediment samples collected in the southwestern East/Japan Sea from the Korea Strait through the Ulleung Basin and the Korea Plateau for grain size, calcium carbonate, organic carbon, and major (Na, Mg, Al, Fe, K, Ca, and Ti) and trace elements (P, Mn, Sr, Li, Sc, V, Cr, Co, Ni, Zn, Cu, and Pb).The chemical composition of the surface sediments was found to be highly variable spatially. Cluster analysis of surface sediment chemical compositions indicated five major geochemical sedimentary environments: basin, lower slope, coast and upper slope, inner shelf, and outer shelf. Continental-shelf sediments were rich in shell fragments and had relict and coarse-grained characteristics. Recent fine-grained sediments were only distributed in coastal, slope, and basin areas. Concentrations of Al, K, Ca, Ti, Cr, and Sc were highest in the coastal and upper slope areas and decreased with water depth. Elemental ratios using major and trace elements indicated that coastal and upper slope detrital sediments were mixtures of sediments derived from the Changjiang (Yangtze) and Nakdong Rivers. Although the concentrations of organic carbon, P, Mn, V, Co, Ni, Cu, and Pb increased with water depth, their distribution patterns indicated authigenic (V, Cu, and Pb) and diagenetic (Fe, P, Mn, Co, and Ni) origins. The distribution pattern with water depth suggested that the chemical composition of surface sediment was determined by sedimentologic and geochemical processes, such as the supply of detrital and biogenic materials, and authigenic and post-depositional diagenetic processes in sediments.     

Geochemical reconnaissance survey and environmental assessment for stream sediments of Wadi Um Gier,Southeastern Desert,Egypt

The purposes of this study were to assess the influence of old mining activities on the geochemistry and quality of sediments and to identify the sites of economic elements. Thirty sites of stream sediment were sampled in the study area covered by granitic, metarhyodacitic and meta-andesitic rocks and related tuffs-hosted abandoned Au mine. The suite of chemical elements, Ag, Bi, Cd, Cu, Fe, Ga, Hg, Mn, Nb, Pb, Rb, Sb, Se, Sn, Te, Th, U, Y, Zn and Zr, pH value and total organic carbon were determined, and univariate, bivariate and multivariate statistical methods were applied. The results show that the enrichment factor (EF) is very high in the case of Te and significant also with respect to Ag, Bi, Cu, Sb, Se, Sn and Zn. Likewise, geoaccumulation indices (Igeos) varied from very highly polluted with Sn and Te, strongly to very strongly polluted with Bi and Se, and moderately polluted with Sb. The polluted sites of Ag, Bi, Sb, Se, Sn and Te were outlined using Igeos maps, and economic sites of Ag and Sn were identified by geochemical maps leading to their sources, which are likely to be mining activities and lithogenic processes. The pollutant elements may cause toxicity in stream sediments, or surface or underground water, as well as plants and animals in the area. This investigation provides an environmental baseline for future monitoring of possible human/anthropogenic, industrial and agricultural impacts on the study area and considers an attempt at re-mining Ag and Sn.     

Book reviews

Book review in this article
Cross-bedding, Bedforms and Paleocurrents, by D. M. Rubin
Beach and Nearshore Sediments and Processes, ed. By R. A. Davis Jr.,
Sedimentary Processes on the Amazon Continental Shelf, ed. by C. A. Nittrouer and D. J. DeMaster
Fjords: Processes and Products, by J. P. M. Syvitski, D. C. Burrell, and J. M. Skei
Alluvial Soils, ed. by J. Gerrard,
Electron Micrographs (TEM, SEM) of Clays and Clay Minerals, by K.-H. Henning and M. Störr
The Origins of Angiosperms and their Biological consequences, ed. by E. M. Friis, W. G. Chaloner & P. R. Crane
The Motion of Allochthonous Terranes Across the North Pacific Basin, by M. G. Debiche, A. Cox and D. Engebretson
Geomorphic Systems of North America, ed. by W. L. Graf
Approaches to Interpretation of Sedimentary Environments, ed. by D. J. Cant and F. J. Hein
Carbonate Depositional Environments: Modern and Ancient. Part I. Reefs.
European Dinantian Environments, ed. by J. Miller, A.E. Adams, and V.P. Wright
Mesozoic and Cenozoic Oceans, ed. by K. J. Hsü
Marine Minerals: Advances in Research and Resource Assessment, ed. by P.G. Teleki, M.R. Dobson, J.R. Moore and U. von Stackelberg.
Sedimentation and Mineral Deposits in the Southwestern Pacific Ocean, ed. by D.S. Cronan
A Practical Approach to Sedimentology, by Ray Lindholm
Clastic Particles, Scanning Electron Microscopy and Shape Analysis of Sedimentary and Volcanic Claste, ed. by John R. Marshall     

华北地块东南缘中生代侵入杂岩中所含榴辉岩类包体矿物微量元素地球化学特征及其意义

华北地块东南缘中生代侵入杂岩中所含榴辉岩类包体中矿物的分析结果表明, 组成榴辉岩类包体的各矿物之间元素的分配在榴辉岩相变质阶段已经达到了化学平衡;石榴石中Al、Fe、Mn, 单斜辉石中Na、Mg、Ca, 角闪石中Na、Mg、Fe等主量元素含量与其全岩之间均呈良好的正相关, 受全岩成分制约;石榴石明显富集HREE、贫LREE, 单斜辉石相对富集LREE、MREE、贫HREE, 两者轻、重稀土含量呈相互消长的互补关系, 石榴石和单斜辉石中分别富集Y、Sr, Ga和过渡族元素Sc、Ti、V、Cr、Co等含量较高, 其含量受全岩成分控制;金红石中稀土元素的含量很少, Fe、Al、Mg、Ca、Mn、Nb、Ta、Cr和Zr含量相对较高, Rb、Sr、Ba含量极低, 部分微量元素(如Nb、Cr、Fe、V、W等)含量与其原岩有继承和对应关系;部分原生或/和退变角闪石的REE配分模式分别与单斜辉石和石榴石相似, 过渡族金属元素等的含量与石榴石、单斜辉石和全岩具有一定的相关性, 角闪石容纳Na、K、Sr、Rb、Ba等元素的能力较强, 其成分除受全岩成分的制约外, 石榴石、单斜辉石对其形成也有影响。榴辉岩类包体与其寄主中生代侵入杂岩中部分高价态/高场强元素(HFSE)和重稀土元素(HREE)呈相互消长的关系。榴辉岩的形成与扬子地块和华北地块之间的俯冲-碰撞作用有关。     

沉积岩石学的室内研究方法综述*

为了正确、高效地完成沉积岩石学的研究内容,势必要求沉积岩石学的研究方法具多样性和先进性,并可在实践中不断完善和发展。作者着重阐述了沉积岩石学的室内研究方法,旨在为沉积岩石学研究者系统介绍合适的技术和手段。室内研究方法主要包括矿物成分与结构分析、无机与有机地球化学分析和其他实验方法。矿物成分与结构分析主要包括薄片鉴定、粒度分析、重矿物分析、激光拉曼光谱和荧光光谱分析、微区矿物识别和元素分析、阴极发光分析,以及X射线衍射、红外光谱和热谱分析。无机地球化学分析主要包括元素地球化学、风化强度的量化、稳定同位素分析和测年分析。有机地球化学分析主要包括总有机碳、岩石热解分析、镜质体分析、气相色谱分析和生物标志物色谱—质谱分析、非生物标志化合物和有机化合物稳定同位素组成分析等。此外,沉积岩石学的室内研究方法还包括磁性矿物学、物理和数值模拟、岩石地球物理方法和地质大数据方法等。新技术、新方法的应用和发展,是促进沉积岩石学发展的重要原因之一。     

微生物岩研究的发展与展望

概述了微生物岩的定义、研究范围和实用意义；划分了早期启蒙阶段、古生物学派与现实主义（沉积）学派对立阶段、比较现实主义（沉积学）阶段和微生物沉积学阶段等４个研究发展阶段（涉及微生物岩的岩石、微生物、生态系、环境、分类和演化）；介绍了微生物礁丘、热泉沉积和磷铁锰微生物岩等研究热点；指出在构造类型、沉积环境、组成岩石和成因标志等方面的发展趋势；提出当前任务是要分析鉴定微生物岩的细菌化石，微生物成因的结构构造和矿物，标志元素、同位素和生物标志物，以及微生物生态系统和成岩成矿机理.     

Geochemical and Mineralogical Characteristics of Pleistocene Lignites and Associated Sediments of Marathousa Coal Field,Central Peloponnese,Greece

The mineralogy and geochemistry data are presented for thirty-seven shales,four concretions,two carbonate sediments and seven lignites from the Marathousa coal field of the Megalopolis Basin in Greece.The argillaceous rocks consist of chlorite,illite,kaolinte,albite,quartz.opal-A,calcite and dolomite;the concretions of aragonite,gypsum and pyrite;and the carbonate rocks of calcite,quartz and illite.The mineral matter in the lignites consists of gypsum,quartz,albite,chlorite,illite,opal-A,dolomite,pyrite,and rarely calcite and kaolinite Athree-factor model explains the total variaition of major and trace elements in the argillaceous sediments.The first factor is an aluminosilicate factor and involves the following elements:Al,Si,Mg,Na,K,Ti,Mn,Nb,Y,Rb,Zn,Cu,Ni,Cr,Nband V,associated with chlorite,albite and illite.The second factor involves the elements Ca,Sr,Ba,Znand Sc and is related to carbonate lithology and mainly the carbonate concretions with gypsum.The third factor involves Fe and Ce with a weak association with Mn.The diagenesis of the Marathousa sediments and lignites was not very advanced as indicated by (a) the total thickness of the sequence (500m),(b) the presence of biogenic silica(opal-A) and (c) the age of the deposit(Pleistocene).FOr these reasons the rpresence of chlorite,illite and kaolinite in the sediments and lignite is due not to diagenetic reactions but to weathering of the flysch and metamorphic rocks at the edges of the Megalopolis Basin and transport of the weathering products(illite,chlorite,kaolinite)into the basin of deposition.The diagenetic minerals of the Marathousa sequence include pyrite,gypsum,dolomite and aragonite.     

Very Low Grade Metamorphism of Upper Paleozoic–Lower Mesozoic Sedimentary Rocks Related to Burial and Thrusting in the Central Taurus Belt,Konya, Turkey

Metasedimentary and sedimentary rocks that represent the allochthonous Bolkardagi Unit crop out in the Central Taurus Belt. Devonian units include mainly slate, metadolomite, metadolomitic limestone, and metasandstone. Slates with slaty cleavage and chlorite-mica stacks are characterized by phyllosilicate, quartz, calcite, dolomite, feldspar, and goethite. Phyllosilicates consist of 2M₁ and lesser amounts of 1M muscovite, IIb chlorite, pyrophyllite, paragonite. PM, C-V, C-S. rectorite, and dickite, and reflect conditions of the low epizone-anchizone. In the Carboniferous-Triassic units, limestone, clayey limestone, dolomitic limestone, marl, shale, and sandstone retaining primary textures are composed of calcite, dolomite, quartz,1Md illite, chlorite, and I-S, and locally smaller quantities of 2M₁ muscovite, PM, paragonite, pyrophyllite, and rectorite. In contrast, the Triassic formation is made up of calcite, 1M_d illite, I-S, kaolinite, smectite, chlorite, C-S, C-V, dolomite, and quartz. Textural and mineralogical data indicate that development of the diagenetic-metamorphic grade in the Central Taurus was related to sedimentary burial and thrusting; moreover, the metasedimentary rocks were metamorphosed in a typical anticlockwise P-T-t pathway in an extensional setting.     

论油气勘探开发中的水文地质,工程地质方法技术

油气勘探开发涉及水文地质,工程地质许多领域及其方法技术,油气水烃类,矿化度等有机,无机地球化学信息是判别油气成藏与油气运移的重要依据,通过对此类地化参数的检测可有效地指导油气勘探,如塔中,松南。油田水文地质直接关系到油田开发方案的合理设计与顺利实施－对油田水文地质条件前期分析,开采中水文地质参数的跟踪监测,选择合适的注水方式,时机及注水量,是油田稳产增产的关键;钻井,试采工程技术受不同工区（地表,     

油气成藏与分布的递变序列

在分析成藏过程的基础上,指出了不同类型油气藏分布的序列性。油气生成的多源性和不同聚集条件下成藏聚集的多变性构成了油气在平、剖面上发育和分布的序列性,它由生供烃序列、运移序列、封存序列以及成藏序列等构成,多因素变化导致不同盆地中的油气藏分布构成多种变化序列。若将不同盆地中的典型油气藏片段进行时空组接,则上述所有油气藏类型都将在理想的盆地中出现,构成理论上完整的油气成藏机理序列。对具体的盆地而言,由于不同类型油气藏的存在几率及发育的规模和程度各有差异,通常形成以几种机理类型为主的油气藏组合序列。单就一定条件下的天然气成藏分析而言,煤层气或页岩气、根缘气、致密砂岩气、水溶气、常规圈闭气以及甲烷水合物等可构成完整的油气成藏机理递变序列。     

金星探测研究进展与未来展望

金星探测是解答太阳系类地行星形成演化,地球宜居性的形成和未来发展,以及外太阳系宜居星球搜索策略的关键.由于金星恶劣的环境条件、对探测技术的多重挑战和相对高昂的探测成本,金星探测和研究程度远不及月球和火星.自20 世纪90 年代后期,金星探测任务相对匮乏.本文梳理了国际上金星探测研究进展、关键科学问题及技术需求,提出了未来金星的探测目标和探测方式建议.目前,对金星大气和气候研究程度最高,包括大气结构和大气化学,能量平衡和热结构,云层和霾层,大气环流和动力学以及气候演化等.高层大气的物理化学和太阳风与金星的相互作用方面也有重要进展.金星地表和内部的研究则相对滞后,研究涵盖金星表面形貌特征,撞击和重塑历史,火山和构造活动,地表物质组成,地表和大气相互作用等,但受限于数据的空间覆盖率和较低的分辨率和精度,诸多重大问题尚未解答,迫切需要新的探测数据.除探测任务外,金星研究还依赖于地基观测、实验室模拟和数值模拟研究.地面模拟设施对支持金星探测任务研发和金星基础科学研究尤为重要.未来十年是中国开展金星探测的契机和研发相关技术的关键时期.本文可为对金星探测、行星科学、太阳系探测感兴趣的科学家和工程人员提供参考.     

The Distribution of Petroleum Resources and Characteristics of Main Petroliferous Basins along the Silk Road Economic Belt and the 21st-Century Maritime Silk Road

The Silk Road Economic Belt and the 21st-Century Maritime Silk Road Initiative, abbreviated as the Belt and Road Initiative, is a primary development strategy of China’s future international cooperation. Especially, the energy resource cooperation, including oil and gas resources cooperation, is an important part of this initiative. The Belt and Road has undergone complicated geological evolution, and contains abundant mineral resources such as oil, gas, coal, uranium, iron, copper, gold and manganese ore resources. Among these, Africa holds 7.8% of the world’s total proven oil reserves. The oil and gas resources in Africa are relatively concentrated, with an overall low exploration degree and small consumption demand. Nigeria and Libya contain the most abundant oil resources in Africa, accounting for 2.2% and 2.9% of the world’s total reserves, respectively. Nigeria and Algeria hold the richest natural gas resources in Africa, occupying 2.8% and 2.4% of the world’s total reserves, respectively. Africa’s oil and gas resources are mainly concentrated in Egypt, Sultan and Western Sahara regions in the northern Africa, and the Gulf of Guinea, Niger River and Congo River area in the western Africa. The Russia–Central Asia area holds rich petroleum resources in Russia, Kazakhstan, Turkmenistan and Uzbekistan. The potential oil and gas areas include the West Siberia Basin, East Siberia Basin and sea continental shelf in Russia, the northern and central Caspian Basin in Kazakhstan, the right bank of the Amu-Darya Basin, the East Karakum uplift and the South Caspian Basin in Turkmenistan, and the Amu–Daria Basin, Fergana Basin, Afghan–Tajik Basin and North Ustyurt Basin in Uzbekistan. The Middle East oil and gas resources are mainly distributed in the Zagros foreland basin and Arabian continental margin basin, and the main oil-producing countries include Saudi Arabia, Iran and Iraq. The Asia Pacific region is a new oil and gas consumption center, with rapid growth of oil and gas demand. In 2012, this region consumed about 33.6% of the world’s total oil consumption and 18.9% of the world’s total natural gas consumption, which has been ranked the world’s largest oil and gas consumption center. The oil and gas resources are concentrated in China, Indosinian, Malaysia, Australia and India. The abundant European proven crude oil reserves are in Norway, Britain and Denmark and also rich natural gas resources in Norway, Holland and Britain. Norway and Britain contain about 77.5% of European proven oil reserves, which accounts for only 0.9% of the world’s proven reserves. The Europe includes main petroliferous basins of the Voring Basin, Anglo–Dutch Basin, Northwest German Basin, Northeast German–Polish Basin and Carpathian Basin. According to the analysis of source rocks, reservoir rocks, cap rocks and traps for the main petroliferous basins, the potential oil and gas prospecting targets in the Belt and Road are mainly the Zagros Basin and Arabic Platform in the Middle East, the East Barents Sea Basin and the East Siberia Basin in Russia–Central Asia, the Niger Delta Basin, East African rift system and the Australia Northwest Shelf. With the development of oil and gas theory and exploration technology, unconventional petroleum resources will play an increasingly important role in oil and gas industry.     

当代世界的矿产资源

论述了最近５０年来世界矿产资源供求关系的变化和现状,着重讨论了独联体国家、北美地区西欧国家、中欧和东欧国家、日本、澳大利亚和南非共和国、欧佩克国家的矿产资源情况。俄罗斯仍是矿产资源大国,但矿山开采工业每况愈下,许多矿种没有清楚的探明储量。独联体一些国家某些矿种储量大,但没有维持经济正常发展的其它矿种。美国的某些矿种储量大,但其它矿种不足,例如石油、天然气、煤、铝、铜、铅、锌、锡、镍、钴、钨等需求量     

滇西腾冲-梁河地块石英闪长岩-二长花岗岩锆石U-Pb年龄、Hf同位素特征及其地质意义

高黎贡-腾梁花岗岩带是冈底斯花岗岩带的东延部分。腾梁花岗岩中辉长-闪长质包体、花岗岩、石英闪长岩密切共生。辉长-闪长质包体的结构构造、矿物学特征表明,它们是岩浆快速冷凝结晶的产物。地球化学数据显示,辉长-闪长质包体为钙碱性系列,具有低SiO2、高MgO和Mg#的特征,富集Rb、Sr、Th、Ba和Ce,亏损Nb、Ta、P、Zr、Yb和Y;寄主花岗岩为中钾—高钾钙碱性系列,准铝质到弱过铝质,富集Rb、Th、Zr和Hf,亏损Nb、Ta、Ti、Sr、P和Ba,具有中等程度的负Eu异常;石英闪长岩介于二者之间。锆石U-PbLA-ICP-MS定年显示,石英闪长岩形成年龄为127.10±0.96Ma,花岗岩形成年龄为123.8±2.5Ma。结合辉长-闪长质包体形成年龄为122.6Ma,三者年龄基本一致,从年代学角度为花岗岩、辉长-闪长质包体和石英闪长岩岩浆混合作用成因提供了证据。石英闪长岩锆石εHf(t)值变化于-7.61～-3.80。结合辉长-闪长质包体、花岗岩的εHf(t)值及地球化学特征,认为花岗岩来源于古老地壳的部分熔融,辉长-闪长质包体来源于地幔楔橄榄岩部分熔融,石英闪长岩为幔源岩浆与古老地壳部分熔融的岩浆完全混合的产物。腾梁地块早白垩世侵入岩很可能与班公湖-怒江洋壳岩石圈向南俯冲的动力学背景有关。     

近10年中国耕地资源时空变化特征

利用80年代末与90年代末期遥感图像解译得到的中国土地利用矢量图,分析了近10年来全国耕地资源的动态变化及空间特征,利用土地利用转移矩阵的方法分析了中国耕地资源的来源、去向及其空间分布特征。研究表明,城乡建设用地扩张、生态退耕是耕地资源减少的主要原因,城镇扩张造成耕地减少最大的依次是江苏、山东、河南、河北、广东、北京、浙江、四川、广西、上海;农村居民点扩张造成耕地减少最大的依次是江苏、河北、安徽、山东、广东、新疆、河南。退耕还林主要集中在浙江、东北、西南、内蒙古、广东等地区,退耕还草主要分布在内蒙古及宁夏地区。广东、湖北、江苏、山东由于农业结构调整,部分耕地被转变为库塘。新开垦耕地资源主要来源于草地、林地,毁林开荒主要发生在东北及内蒙古东部地区,开垦草地主要发生在内蒙古、黑龙江和新疆地区。中国耕地资源的动态变化表现为沿海地区耕地资源的减少及东北、西北地区耕地资源开垦,耕地开垦的结果是对西北及东北的生态环境造成破坏。     

喀斯特断陷盆地水资源高效开发利用模式构建

在调查研究典型喀斯特断陷盆地水文地质特征、地表水文过程、“五水”转换及水资源均衡,研发地下水高效开发利用、地表水调蓄、水污染风险评估与水质修复、农田节水灌溉及土壤保墒、水资源优化调控等系列技术的基础上,以可持续发展和系统科学理论为指导,构建了喀斯特断陷盆地水资源高效开发利用模式,包括理论与技术支撑体系和开发利用工程体系两个层次。前者的基本构成及内涵为:水资源高效开发利用工作流程、理论依据及技术支撑,是模式的理论与技术内涵;后者为沿着盆地地表、地下水的形成、运动和转换过程,从上游山区到下游河谷区,逐级分区部署的水资源开发利用工程体系,工程布局做到因地制宜、科学合理,大、中、小、微型并举,集中供水与分散供水兼顾,同时系统推进水质修复、水循环利用、节约用水等措施,实现水资源的高效和可持续开发利用。      

煤炭开发工程“五化协同”模式研究

矿业工程是人类获取能源与原料的重要手段,随着新一代信息化技术与传统采矿技术的深入融合,传统矿业工程管理技术难以适应煤炭资源高效开发与利用的需求。由此,提出了基于融合赋能管理思想的“五化协同”工程管理方法,阐述了包含绿色化、智能化、集成化、专业化、精细化的“五化”主要内容,分析了“五化”协同建设的多目标、协同、开放、伺服、自组织等特性,构建了以价值最优化为整体目标,以“五化”协同融合为核心的全生命周期工程构架体系。在指导煤矿智能化建设实践中,取得了智能化开采与智能化建井工程的安全高效建设。为矿业工程决策、建设与管理提供了一条科学的可借鉴、可复制的工程管理模式,以引领我国煤矿智能化建设与管理新方向,践行工程与经济、工程与技术、工程与管理及人与自然和谐统一的工程哲学思想,对于工程建设与管理具有重要意义。      

Metal contents of recent thermal waters, mineral precipitates and hydrothermal alteration in active geothermal fields, Kamchatka

All the Kamchatkan recent hydrothermal systems are restricted to two volcanic zones, Central Kamchatka of Late Miocene-Pliocene age and East Kamchatka, where several active volcanoes are located. Solutions from active hydrothermal systems commonly contain elements, including As, Sb, Hg, Li, Rb, Cs, B, Cu, Pb, Zn, Ag, Au,Sr and Ba, with the first seven predominating. Higher abundances of ore elements occur in active hydrothermal systems with solutions of sodium chloride composition. Those are the Kireunskaya, Dvukhyurtochnaya and Apapelskaya systems in the Central Kamchatka volcanic zone and the Uzon hydrothermal system in the East Kamchatka volcanic zone. The hydrothermal systems are restricted to structures having very long histories of evolution and which are characterized by contrasting types of magmatism. At present chemical precipitates and altered rocks with higher abundances of As, Sb and trace amounts of Au, Ag, Cu, Ph and Zn are forming in the discharge zones of these hydrothermal systems. Large zones of alterations (alunitic quartzites^* and argillites) with high abundances of As, Sb, Hg, Cu, Pb, Ga and Zr occur in the Central Kamchatka volcanic zone. Here zones of mineralization (cinnabar, realgar, stibnite, orpiment, pyrite, chalcopyrite, sphalerite, galena) occur also; native gold, native silver and gudmundite occur rarely.In the recent Uzon caldera hydrothermal system, As-Sb-Hg mineralization with bitumen and oils is now forming. The ore deposit is zoned, with the most abundant ore minerals being realgar, uzonite, alacranite, stibnite and pyrite. Cinnabar, orpiment, marcasite and native mercury occur occasionally, and single grains of native gold, native silver and native copper are present. At present a total of 7000 t As, 350 t Sb and 200 t Hg have been deposited in the mineralization zone at geochemical boundaries. The general geological and geochemical data suggest that at depth the As-Sb-Hg mineralization may change to gold-silver mineralization.     

应力化学

应力化学是研究应力的性质,作用方式和规模,组合和序列,它们的发生,发展,演化所成生的化学作用和过程,以及物理－化学动态机制。当应力作用于地质体时,接受能量和释放能量的作用方式之一就是应力化学作用,应力化学作用主要受应力性质,应力配置和应力序列的影响,以剪应力化学作用最为重要,应力作用可产生化学作用,改善化学反应所需条件,因而促进和加速了化学作用。