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1.
Concentrations of cadmium, lead and copper have been determined in the lower estuary of the St. Lawrence River during the summer of 1972 (from May to August). Seven sample stations distributed in the estuary have been studied. Analysis measurements have been made using atomic absorption spectrophotometry and are related to the soluble metals. The concentrations of cadmium are low and no important variations occur. Mean analysis of cadmium abundance gives a value of 1.05 μg/l. Similar variations are observed for copper and lead contents with a Cu/Pb ratio which is nearly equal to unity. Average concentrations for all the stations are 3.11 μg/l for copper and 3.48 μg/l for lead. Higher values are measured for copper and lead during the month of May and these are related to the fresh-water inflow arising from the thawing period. The lowest concentrations are observed during the months of June and July and are in correspondence with the spring period of intense primary production. The biologic-dynamic conditions affecting the concentrations of cadmium seem to be different from those affecting copper or lead contents (without considering pollution phenomena). The highest average values for copper and lead have been found on the south shore of the estuary. The values obtained in this work compared favourably with other results gathered in the neighbouring area.  相似文献   

2.
Determination of total chromium on two profiles and chromium III on four samples of equatorial Pacific Ocean water have been carried out using coprecipitation of chromium from sea water with hydrous iron oxides, followed by ion-exchange separation and isotope dilution mass spectrometry. Results for two Pacific profiles show increasing total chromium concentration from surface to 250 m. The Cr concentration appears to be different below 1,000 m, with nearly homogeneous concentrations for the first profile and regularly increasing Cr concentrations from 0.330 to 0.550 μg/l at 3,900 m for the second one. Results for Cr(III) show that trivalent species are dominant in these samples.  相似文献   

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4.
A study of the C/N ratios of particulate matter in the eastern part of the Gulf of Guinea demonstrated a statistically significant spatial variation in these ratios. The variation in the ratios ranged between 7.2 and 9.5 and were due in part to differences in the composition of the suspended organic matter and in part to its age and history. Young nutrient rich waters had low ratios (generally less than 7), whereas older waters often had ratios greater than 10. A relation between Chlorophyl a and the C/N ratio was also observed. The distribution of C/P ratios with depth showed a linear correlation with the vertical distribution of oxygen (r = 0.74). C/P values in the neighbourhood of 100 at the surface, increased with depth to around 300 at 1000 m.  相似文献   

5.
The evolution of hydrocarbons in sediments was studied from 1978 to 1980 at eight stations in the Ile Grande marshes (Brittany) polluted by the Amoco Cadiz oil spill. Generally, in 1980 (except for one heavily polluted site) the amounts of hydrocarbons were found to be far less important than in 1978 and sometimes biogenic hydrocarbons were found. In the superficial layer of the sediments biodegradation processes were generally important with the preferential degradation of n-alkanes. On the other hand, aromatic hydrocarbons seem not to have been altered after three years. Degradation of percolated hydrocarbons proceeds more slowly than in the surface layer. The number of degrading bacteria decreases when n-alkanes disappear.  相似文献   

6.
In this work we attempt to estimate the short- and long-term effects of the Amoco Cadiz oil spill on benthic microalgal populations (cyanophytes and diatoms) which, under natural conditions, live on upper layers of ‘schorres’ soils or of ‘slikke’ muds in the Ile Grande salt marsh system (Côtes du Nord, France). These populations were completely destroyed in 1978 in the oil-affected sites. Ubiquitous species settled fairly rapidly on intertidal polluted muds (tidal flat). The chlorophyll a content values reached 100 μg g−1 dry sediment, i.e. 1000 mg m−2 in 1980. Conversely, the salt marsh soils are still much less densely repopulated 3 years after the Amoco Cadiz grounding—especially when they are infrequently flooded (3 to 40 μg Chl.a g−1, i.e. 40 to 270 mg m−2). Some of these soils remain ten times less populated than reference stations.  相似文献   

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