Uranium minerals from the San Marcos District, Chihuahua, Mexico

The mineralogy of the two uranium deposits (Victorino and San Marcos I) of Sierra San Marcos, located 30 km northwest of Chihuahua City, Mexico, was studied by optical microscopy, powder X-ray diffraction with Rietveld analysis, scanning electron microscopy with energy dispersive X-ray analysis, inductively coupled plasma spectrometry, and gamma spectrometry. At the San Marcos I deposit, uranophane Ca(UO₂)₂Si₂O₇·6(H₂O) (the dominant mineral at both deposits) and metatyuyamunite Ca(UO₂)(V₂O₈)·3(H₂O) were observed. Uranophane, uraninite (UO_2+x), masuyite Pb(UO₂)₃O₃(OH)·3(H₂O), and becquerelite Ca(UO₂)₆O₄(OH)₆ ·(8H₂O) are present at the Victorino deposit. Field observations, coupled with analytical data, suggest the following sequence of mineralization: (1) deposition of uraninite, (2) alteration of uraninite to masuyite, (3) deposition of uranophane, (4) micro-fracturing, (5) calcite deposition in the micro-fractures, and (6) formation of becquerelite. The investigated deposits were formed by high-to low-temperature hydrothermal activity during post-orogenic evolution of Sierra San Marcos. The secondary mineralization occurred through a combination of hydrothermal and supergene alteration events. Becquerelite was formed in situ by reaction of uraninite with geothermal carbonated solutions, which led to almost complete dissolution of the precursor uraninite. The Victorino deposit represents the second known occurrence of becquerelite in Mexico, the other being the uranium deposits at Peña Blanca in Chihuahua State.     

The Cretaceous sediment-hosted copper deposits of San Marcos (Coahuila,Northeastern Mexico): An approach to ore-forming processes

In the San Marcos ranges of Cuatrociénegas, NE Mexico, several sediment-hosted copper deposits occur within the boundary between the Coahuila Block, a basement high mostly granitic in composition and Late Paleozoic to Triassic in age, and the Mesozoic Sabinas rift basin. This boundary is outlined by the regional-scale synsedimentary San Marcos Fault. At the basin scale, the copper mineralization occurs at the top of a ～1000 m thick red-bed succession (San Marcos Formation, Berrisian), a few meters below a conformable, transitional contact with micritic limestones (Cupido Formation, Hauterivian to Aptian). It consists of successive decimeter-thick roughly stratiform copper-rich horizons placed just above the red-beds, in a transitional unit of carbonaceous grey-beds grading to micritic limestones. The host rocks are fine- to medium-grained arkoses, with poorly sorted and subangular to subrounded grains. The detrital grains are cemented by quartz and minor calcite; besides, late iron oxide grain-coating cement occurs at the footwall unmineralized red-beds. The source area of the sediments, indicated by their modal composition, is an uplifted basement. The contents of SiO₂ (40.70–87.50 wt.%), Al₂O₃ (5.91–22.00 wt.%), K₂O (3.68–12.50 wt.%), Na₂O (0.03–2.03 wt.%) and CaO (0.09–3.78 wt.%) are within the ranges expected for arkoses. Major oxide ratios indicate that the sedimentary-tectonic setting was a passive margin.The outcropping copper mineralization essentially consists in a supergene assemblage of chrysocolla, malachite and azurite. All that remains of the primary mineralization are micron-sized chalcocite grains shielded by quartz cement. In addition, pyrite subhedral grains occur scattered throughout the copper-mineralized horizons. In these weathered orebodies copper contents range between 4.24 and 7.72 wt.%, silver between 5 and 92 ppm, and cobalt from 8 to 91 ppm. Microthermometric measurements of fluid inclusions in quartz and calcite crystals from footwall barren veinlets gave temperatures of homogenization between 98 °C and 165 °C, and ice-melting temperatures between ?42.5 °C and ?26.1 °C.The primary copper mineralization formed during the early diagenesis, contemporary with the active life of the Sabinas Basin. The mineralizing fluids were dense, near neutral, moderately oxidized brines that originally formed from seawater that, driven by gravity, infiltrated to the deepest parts of the basin and dissolved evaporites. As a result, they became hydrothermal fluids of moderate temperature capable of leaching high amounts of copper. The source of this metal could be mafic detrital grains and iron oxides of the underlying Jurassic and Lower Cretaceous red-beds. Copper precipitation took place when the brines passed through the redox boundary marked by the transition from red- to grey-beds. The upward movement of the brines was promoted by a high heat flow that allowed their convective circulation and their ascent along the synsedimentary San Marcos Fault.     

Geochemical evaluation of the geothermal resources in the San Marcos region,Guatemala

The chemical and isotopic compositions of hot springs in the San Marcos region of Guatemala are internally consistent with a hydrologic model in which a deep 240°C reservoir and one or more shallow 195–200°C reservoirs are present. Variations in hot-spring water compositions results from a combination of boiling, mixing with cold, dilute water, and chemical re-equilibration with decreasing temperature. The recharge water for the deep 240°C reservoir is isotopically heavier than the local meteoric water and probably comes from many kilometers to the west or southwest. The water in the shallow reservoir is a mixture of the 240°C water with about 20 ± 5% of cold, locally derived meteoric water. After mixing, the water in the shallow reservoir re-equilibrates with reservoir rock at 195–200°C. In some places additional mixing with cold water occurs after water leaves the shallow reservoir.     

Effects of pressure on the micromechanics of faulting in San Marcos gabbro

Samples of San Marcos gabbro were deformed to both pre- and post-failure stages at confining pressures of 100, 250 and 350 MPa. Scanning electron microscope observations were performed on the samples after ion-milling. The unstressed gabbro has insignificant crack porosity but a high volume fraction of healed and sealed cracks. Extensive stress-induced cracking at high angles to the maximum compressive stress is observed at the two higher pressures. Such high-angle cracks are mostly associated with the pre-existing healed cracks or cleavage planes, and they control the geometry and length scale of crack networks in plagioclase. Intensive kinking in biotite is widely observed at 350 MPa pressure, which together with the crack networks control the brittle fracture process. Stress-induced cracks in samples deformed at 100 MPa pressure are predominantly subparallel to the maximum compressive stress, and their coalescence leads to shear localization.Quantitative measurements of crack density as a function of differential stress indicate that crack interaction is appreciable beyond about 90% peak stress for all three pressures. The data also show significant decreases in stress-induced anisotropy as pressure increases, suggesting that there may be a threshold pressure beyond which stress-induced anisotropy vanishes with the onset of cataclasis.     

Rock Reference samples, San Marcos Gabbro, GSM-1 and Lakeview Mountain Tonalite, TLM-1

Two rock samples from the San Marcos Gabbro and the Lakeview Mountain Tonalite of the Southern California Batholith were prepared as U.S. Geological Survey reference samples. These samples were chosen to supply reference data for rocks having intermediate silica contents in the range of 45-60 percent. Unpublished data by members of the U.S. Geological Survey and some published data are summarized, and provisional estimates of the major and minor oxide and traceelement contents are given.     

Aspects of the marine Cretaceous of China

The marine Cretaceous of China is distributed mainly in southwestern Xinjiang, the West Kunlun Mountains, the Karakorum Mountains and most parts of Xizang (Tibet), with findings even from Taiwan.The marine Cretaceous of China may be divided into three sedimentary belts according to the lithologic and tectonic characters, biological provinces and the different modes of deposition.On the basis of recent research on the Cretaceous marine strata and faunas in China, the lithostratigraphic and biostratigraphic sequences have been preliminarily established and the division and correlation of strata and boundaries between the Jurassic and Cretaceous, Lower Cretaceous and Upper Cretaceous, as well as Cretaceous and Tertiary outlined; the position of the beach line of the Laurasian landmass in China and the events of the tectonic movement and the transgression and regression during the Cretaceous period are discussed.     

Depositional environments of marine-dominated bedded halite, Permian San Andres Formation, Texas

The interpretation of the depositional environments in which bedded halite is formed is a frontier of evaporite sedimentology. Facies studies, supplemented by geochemical data, define an evaporite shelf depositional environment for the halite of the San Andres Formation of the Palo Duro Basin, Texas Panhandle, that is significantly different from modern and previously described ancient halite-precipitating environments such as playas, salinas, sabkhas, and barred basins. A coastal palaeoenvironmental setting for the San Andres halite is defined by its facies position between normal marine-shelf carbonates and aeolian deposits. The San Andres brine pool extended over more than 10 000 km² but was very shallow. Perennial brine-pool conditions (thick sequences of halite) alternated with ephemeral brine-pool conditions (halite, haloturbated mudstone-halite, mudstone interbeds, and microkarst). The depositional sequence in the perennial brine pool includes (1) flooding and minor dissolution of previously deposited halite, (2) precipitation of a thin lamina of gypsum, and (3) evaporation and precipitation of halite. Bottom-growth forms of halite, including chevrons and vertically elongated crystals, are well preserved. Cumulates of foundered, floating crystals and rafts were probably abundant but have been almost completely recrystallized. Mudstone interbeds in halite and microkarst features cut into bedded halite record the episodic interruption of brine-pool deposition and the establishment of subaerial conditions. Vertically elongated karst pits originate at the palaeosurfaces, cross-cut primary brine-pool fabrics, and are filled with geopetal sediment and coarse halite cement. Mudstone interbeds and mixtures of mudstone and halite have been haloturbated by the alternating growth and dissolution of halite reflecting conditions of fluctuating salinity. The geochemistry of halite from both ephemeral and perennial brine-pool environments reflects the frequent influx of marine brine, indicating that communication with the marine environments to the south was ‘good’ considering that restriction was sufficient to precipitate halite.     

Salviniales from the Late Cretaceous of the Golfo San Jorge Basin

The freshwater ferns (Salviniales) are well represented in the Maastrichtian deposits of Cerro de los Fragmentos in the headwaters of the Río Chico, Golfo San Jorge Basin. The fossil material of Salviniaceae includes complete megaspore apparatuses with attached microspore massulae and dispersed megaspores, float systems and microspore massulae of Azolla. The new species Azolla colhuehuapensis displays distinctive morphological characters including relative small megaspore apparatuses with easily detached floats and usually attached eglochidiate massulae. The Marsileaceae are represented by the megaspore Molaspora lobata, microspores of Crybelosporites and vegetative remains of Marsileaceaephyllum sp. The assemblage also includes zygospores of the green filamentous algae Zygnemataceae, spores of Marchantiophyta and Monilophyta (Schizaeales), megaspores of Isoetalean affinity and Palm-type angiosperm pollen grains. All these organic microfossils and the associated palynomorphs indicate the presence of a freshwater environment where abundant water ferns were developing and reproducing.     

An Upper Cretaceous (middle Campanian) marine chondrichthyan and osteichthyan fauna from the Rattlesnake Mountain sandstone member of the Aguja Formation in West Texas

A thin phosphate-granule conglomerate within the Upper Cretaceous (middle Campanian) Rattlesnake Mountain sandstone member of the Aguja Formation preserves a diverse chondrichthyan and osteichthyan fauna. This highly fossiliferous deposit (the ‘Ten Bits Microsite’) yielded about 5000 teeth, spines, and denticles in a small amount of matrix (c. 150 kg). About 30 identifiable species of sharks, rays, and bony fishes are recognized. Two of the three most abundant chondrichthyan species at Ten Bits (Scapanorhynchus texanus and Ischyrhiza mira) are also the most common species in other middle to late Campanian marine vertebrate faunas along the Gulf and Atlantic Coastal Plain. The myliobatiform rays Brachyrhizodus and Rhombodus that occur at Ten Bits also appear to be characteristic of the Gulf and Atlantic Coast, as are lamniform sharks such as Cretalamna and Serratolamna. These taxa are entirely absent or extremely rare in Western Interior Campanian faunas. In contrast, some small orectolobiform sharks (Cantioscyllium, Chiloscyllium, Columbusia) and small rays (Protoplatyrhina) found at Ten Bits are common in shallow water faunas of the Western Interior and Texas Coastal Plain, but rarely reported from the eastern Gulf or Atlantic Coast. The common Western Interior ray Myledaphus bipartitus does not occur at Ten Bits or in any Gulf or Atlantic Coast fauna. Ptychotrygon agujaensis is abundantly represented in the Ten Bits fauna, but unknown in correlative marine faunas. Although Ptychotrygon occurs in all Western Interior, Gulf and Atlantic Coastal Plain faunas, it is represented elsewhere by apparently endemic species at each collection site. The differences between Western Interior, Gulf, and Atlantic Coastal Plain faunas probably reflect latitudinal variation in water temperature or salinity, or different oceanic water circulation patterns between the Western Interior Seaway and the Gulf or Atlantic Coast that restricted the distributions of some marine fish species. The Ten Bits fauna shares typical species with both Western Interior and Gulf and Atlantic Coast faunas, reflecting its position at the border between these provinces; however, the dominant taxa found at Ten Bits are the same as those found on the Gulf and Atlantic Coast, and indicate that western Texas was more closely allied biogeographically with that province than with the Western Interior of North America. One species tentatively identified in the Ten Bits fauna on the basis of a single tooth, Igdabatis cf. I. indicus, is otherwise known only from southern Europe and Asia, although a similar large myliobatid ray also occurs rarely in Texas Coastal Plain faunas. These occurrences indicate that western Texas may have been near the northern limit of the range for some tropical Tethyan marine vertebrate species.     

Deccan traps mantle degassing in the terminal Cretaceous marine extinctions

Mantle degassing continually releases gases onto the earth's surface. Over geologically long time intervals, a general equilibrium probably exists between mantle CO₂ release and uptake by surficial sinks. However, during periods of rapid plate movement, or continental flood basalt volcanism, the increased rate of mantle CO₂ release may exceed that of uptake, leading to CO₂ accumulation in the atmosphere and the marine mixed layer (top 50–100 m). This in turn triggers chemical changes in the mixed layer, climatic warming, and bioevolutionary turnover. The Cretaceous/Tertiary ($\text{K}\text{T}$) transition at 65 Ma seems to have been a time of major mantle degassing which induced a perturbation of the carbon cycle. During the $\text{K}\text{T}$ transition, Deccan Traps volcanism, perhaps the greatest episode of continental flood basalt volcanism in the Phanerozoic, flooded an estimated 2.6 × 10⁶ km² of India with basaltic lavas, releasing 5 × 10¹⁷ moles of CO₂ into the earth's atmosphere over a duration 0.53–1.36 Ma at the rate of 3.9 × 10¹¹ to 9.6 × 10¹¹ moles CO₂ per year. The modern mean annual rate of mantle CO₂ release from all sources is 4.1 × 10¹² moles CO₂ per year; assuming a comparable rate of release prior to the Deccan Traps volcanism, the Deccan Traps addition would have elevated the rate of mantle CO₂ release by 10–25%. Sluggish marine circulation and warm, deep, oceans (14–15°C) would have exacerbated CO₂ buildup in the atmosphere, accounting for the Cretaceous to Tertiary drop in oxygen-18 via climatic warming, and, in the marine mixed layer (top 50–100 m), explaining the selective nature of the terminal Cretaceous marine extinctions via a pH change. The extinctions were most severe amongst the calcareous microplankton of the mixed layer; calcareous microplankton (planktonic foraminifera and coccolithophorids) begin to have pH problems at 7.8 and 7.5, respectively. Failure of the coccolithophorids would have disrupted the Williams-Riley pump (algal productivity-gravity pump of CO₂ from the atmosphere and mixed layer into the deep oceans) producing dead ocean conditions (severely reduced photosynthesis and CaCO₃ production). Failure of the Williams-Riley pump is reflected in the extinctions themselves, and in the loss of biogenic CaCO₃ to the sea floor, causing the $\text{K}\text{T}$ boundary hiatus and (or) the $\text{K}\text{T}$ boundary clay. Failure of the pump today would elevate atmospheric pCO₂ severalfold; the $\text{K}\text{T}$ failure would have responded comparably. Dead ocean conditions would, in themselves, have produced a major CO₂ buildup. Early Tertiary “Strangelove” conditions in the mixed layer, characterized by a dominance of the thoracosphaerids, braarudosphaerids and small planktonic foraminifera, were coeval with the main pulse of Deccan Traps volcanism. Overall, the record is one of gradual $\text{K}\text{T}$ bioevolutionary turnover during a period of disequilibrium between the rate of mantle CO₂ degassing and uptake by sinks. Mantle degassing during the Deccan Traps volcanism unifies the $\text{K}\text{T}$ biological and physicochemical records.     

Cretaceous transgressions and regressions on the Russian Platform, in Crimea and Central Asia

This paper is a brief explanation of the diagrams of the Cretaceous transgressions and regressions on the Russian Platform, in the Crimea (Figures 1–3) and some regions of central Asia—the western flanks of the Tien Shan mountains, the Fergana basin, the Zeravshan-Gissar and Alaj mountains, and the Northern Pamirs (Figures 5–7).Internationally recognized stages are employed. They are interpreted by Sasonova (1967) for the Lower Cretaceous (K₁) of the Russian Platform, by Naidin (1977) for the Upper Cretaceous (K₂) of the Platform and the Crimea, by Djalilov (1971) and Pojarkova (1976) for the Upper Cretaceous of central Asia. General data on the stratigraphy of the Cretaceous of central Asia may be found in Anon 1977.     

Late Cretaceous marine fossils and seawater incursion events in the Songliao Basin,NE China

The Songliao Basin is the largest non-marine oil-bearing basin in China. Because of the absence of substantial evidence, the hypothesis of seawater incursion events into the Songliao Basin remains controversial. The presence of marine fossils could provide direct proof to support this supposition. Here, we report new discoveries of foraminifera, calcareous nannofossils, brackish dinoflagellates, and other marine and brackish-water fossils to support the suggestion of seawater incursion events in the Songliao Basin. Relatively abundant benthic and planktonic foraminifera, calcareous nannofossils, marine and brackish-water dinoflagellates, fish, and bivalves have been discovered in Members 1 and 2 of the Nenjiang Formation, a few foraminifera and brackish-water dinoflagellates have been found in the lower Qingshankou Formation, and just a few brackish-water bivalves have been found in the uppermost Qingshankou Fm. Based on the presence of marine molecular fossils and other evidence, we suggest that relatively large seawater incursion events occurred during the sedimentation of the lower Nenjiang Fm., relatively smaller seawater incursions occurred during the deposition of the lower Qingshankou Fm., and possibly a very small seawater incursion occurred during the sedimentation of the uppermost Qingshankou Fm. These seawater incursion events in the Songliao Basin were controlled by regional tectonic activity, evolution of the palaeo Songliao Lake, and global sea level change. These periodic seawater incursions brought marine biota into the palaeo Songliao Lake.     

Late Cretaceous marine reptiles (Elasmosauridae and Mosasauridae) of the Chatham Islands, New Zealand

A new marine reptile record for the Upper Cretaceous of the Chatham Islands is described from the Takatika Grit. Incomplete mosasaur and plesiosaur remains represent the first record of marine reptiles from the Chatham Islands and wider New Zealand. Present among the myriad bones are elasmosaurid plesiosaurs and mosasaurine mosasaurs. This assemblage is comparable to the New Zealand marine reptile record and represents apex predators that flourished in a zone of upwelling in a Late Cretaceous southern high-latitude ecosystem.     

藏南岗巴地区上白垩统海相碳酸盐岩碳稳定同位素研究

本文对藏南岗巴地区上白垩统海相碳酸盐岩的碳稳定同位素组成特征及变化趋势进行了研究,对比分析了藏南其它地区及欧洲同时代地层,认为岗巴地层的碳稳定同位素的记录很好地响应了白垩纪期间全球性的缺氧事件。通过对岗巴地区岩石地层学及区域环境的分析说明,全球性的海平面升降及板块运动造成了大洋溶解氧含量的波动是碳稳定同位素δ¹³C值偏移的根本原因。     

A new neoselachian shark from the marine Early Cretaceous of Southern England

Rare, isolated teeth of Corysodon multicristatus sp. nov. are described from two levels in the Atherfield Clay Formation (Early Aptian, Early Cretaceous) of Atherfield Point on the Isle of Wight, UK. Ten teeth of the new species were recovered from 1095 kg of washed and graded sediment residues. The teeth themselves are very small (around 0.5 mm high) and possess a distinctive crown bearing a tiered series of transverse crests adapted for rasping. Details of the dental architecture of the Atherfield Clay Formation specimens clearly indicate that the Cretaceous material differs significantly from the teeth of the type species for the genus, Corysodon cirinensis, recorded from the Kimmeridgian of northern France and Switzerland. C. multicristatus is the first substantiated record of the genus from the Early Cretaceous, thereby extending the stratigraphic range of the genus from the latest Jurassic, and the geographical range from continental Europe to the UK.     

Mineralogy and pressure–temperature–time path of Cretaceous granulite gneisses, south-eastern San Gabriel Mountains, southern California

Mid-Cretaceous granulite gneisses crop out in a narrow belt in the Cucamonga region of the south-eastern foothills of the San Gabriel Mountains, southern California. Interlayered mafic granulites and pelitic, carbonate, calc-silicate and quartzofeldspathic metasediments record hornblende granulite subfacies metamorphism at approximately 8 kbar and 700–800°C. Regional deformation and formation of banded gneisses ceased by c. 108 Ma. although mafic-intermediate magmatism and high-grade metamorphism continued locally as late as c. 88 Ma. Garnet zoning in metapelitic gneisses suggests that peak metamorphism was followed locally by a period of near-isobaric cooling, but this interpretation requires diachronous cooling of the granulite belt which cannot be demonstrated without detailed thermo-chronological data. It is more likely that the entire terrane remained at granulite facies P–T conditions until 88 Ma, followed by rapid uplift associated with juxtaposition against adjacent middle and upper crustal arc terranes. Uplift occurred between c. 88 and 78 Ma at rates of approximately 1–2 km Ma^-1. The geotectonic evolution of the Cucamonga granulites is similar to mid-Cretaceous high- P granulites in the Sierra Nevada and Salinian block of central California. Late Cretaceous uplift common to these granulites may provide an important tectonic link between dismembered Mesozoic batholithic terranes in the California Cordillera.     

The Correlation of the Upper Cretaceous Zonal Schemes of the Eastern European Platform Based on Foraminifera,Radiolaria, and Nannoplankton

This article proposes a biostratigraphic scheme for the Upper Cretaceous of the East European Platform on the basis of the distribution in the sections of three groups of microfossils: foraminifera (both planktonic and benthic), radiolarians, and nannoplankton. Most of the stage and substage boundaries are confirmed by macropaleontological data. The most divided units are those distinguished based on benthic foraminifers and nannoplankton. The diversity of these microfossils and their constant presence allowed us to identify zones and subzones, while it is possible to subdivide only the beds by planktonic foraminifers and radiolarians. The most favorable stages in the development of plankton biota can be considered the Turonian–Coniacian interval when the basins of the East European Platform experienced an intensive influence from warm waters of the Tethys Ocean. The global Campanian cooling is clearly recorded, which affected the taxonomic diversity of all microfossil groups.     

Early Cretaceous sea level fluctuations in the eastern part of the East European Platform

The quantitative sea-level curve in the eastern part of the East European Platform during the Early Cretaceous first compiled for this region is based on the results of analysis of the corresponding deposits and the bathymetric distribution of benthic foraminifers in their sections. This quantitative curve is correlated with the sea-level curve constructed for central areas of the East European Platform [9]. According to [9], the basin in the central part of the platform was as deep as 110 m, while in its eastern areas the depth amounted to 350 m. It is revealed that tectono-eustatic cycles defined previously in the central part of the platform and cycles (megasequences) in its eastern areas are asynchronous and are characterized by different orders. Such asynchrony is determined by the different tectonic trends in these regions during the Early Cretaceous.