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1.
The isotopic composition of Sr has been measured in brine samples from the Upper Jurassic Smackover Formation in southern Arkansas; 87Sr86Sr ratios range from 0.7071 to 0.7101. With one exception, the 32 Smackover brines contain Sr which is significantly more radiogenic than the Sr in Late Jurassic sea water, indicating sizable Sr contributions from detrital sources. Isotopic analyses of core samples from rock units associated with the brines and regional stratigraphic relationships suggest that the radiogenic Sr was released from detrital minerals in Bossier shale to interstitial fluids expelled from the underlying Louann Salt in the North Louisiana salt basin. These fluids migrated through the Bossier Formation updip to the South Arkansas shelf, where they entered the upper Smackover carbonate grainstone. The radiogenic fluids mixed with Sr-rich interstitial marine waters that had the isotopic composition of Late Jurassic sea water; mixing in variable proportions resulted in the random distribution pattern of variable 87Sr86Sr ratios that is observed in Smackover brines within the 5000 km2 study area. Isotopic analyses of nonskeletal carbonate grains and coexisting coarse calcspar cement from the upper Smackover grainstone imply that the grains were diagenetically stabilized in the presence of interstitial marine waters, whereas the calcspar cement is a relatively late diagenetic phase precipitated after the arrival of radiogenic fluids.  相似文献   

2.
Twenty-six new high precision 87Sr86Srratio determinations and existing analyses are used to discuss the strontium isotopic composition of the Upper Cretaceous ophiolitic rocks of the Troodos Massif, Cyprus. Relative to initial magmatic 87Sr86Sr ratios (0.70338 ± 0.00010 to 0.70365 ± 0.00005), the hydrothermally metamorphosed pillow lavas and dyke complex have been contaminated by isotopically heavier strontium.This observation confirms the hypothesis that hydrothermal metamorphism was a consequence of sea water-rock interaction, since sea water was the only readily accessible reservoir of isotopically heavier strontium. The fact that metagabbros and altered trondhjemites were also Sr isotopically contaminated shows that sea water penetrated approximately 2 km into the oceanic crust represented by the ophiolitic sequence.The amount of Sr isotopic contamination requires that the bulk sea water: rock ratio was at least ~15:1 and shows that water-rock interaction occurred in a flow system. The degree of oxidation decreases with increasing depth. This shows that the vertical component of fluid flow was downward. The absolute bulk water/rock ratio (for water at S.T.P.), as estimated from the oxidation profile, may have been as large as ~3 × 103:1 —a large figure which independently confirms that rocks showing strong δ18O shifts have interacted with large volumes of water.The sites of discharge of the hot fluid, which must have come out of the system, are identified as the cupriferous pyrite ore deposits. This process of mass transfer corresponds to hydrothermal convection in a permeable medium with an open upper boundary surface.  相似文献   

3.
Morphological, mineralogical, chemical and RbSr isotopic studies have been made on Fesmectites (nontronites) from southern Pacific red clays cored near the Marquisas Islands. These minerals have at the top of the core, an 87Sr86Sr ratio of 0.70917 ± 0.00007, which indicates an authigenic origin in isotopic equilibrium with seawater. Weak leaching experiments with 1N HCl show that the nontronites also contain a volcanic component with a lower 87Sr86Sr ratio which, combined with the morphology of the particles, suggests a transportation by bottom currents of clay formed elsewhere.During burial, the nontronites experience diagenetic modifications resulting in an increase in Fe, K and Rb contents, a concomitant decrease of Mg, Ca, Ti, Na and Sr, and a preferential migration of radiogenic 87Sr from the clays into the surrounding pore waters.The 87Sr86Sr ratio of the Sr adsorbed on the outermost surfaces of the nontronites does not change with depth in the core, and is, therefore, independent of diagenetic influence, which is rather characterized by the 87Sr86Sr ratios of the interstitial waters. The isotopic composition of both the adsorbed Sr and that of the pore fluids may yield useful information on the crystallization environment and subsequent history of deep sea red clays.  相似文献   

4.
Pleistocene and Recent lavas from the Sunda arc range from those showing affinities with the island arc tholeiitic series, through a spectrum of calc-alkaline to high-K alkaline rocks. The tholeiitic rocks have relatively low 87Sr86Sr ratios averaging 0–7043; the calc-alkaline rocks show a wide range (from 0.7038 to 0.7059, averaging 0.7048); the high-K alkaline rocks average 0.7045. A rhyolitic ignimbrite from Sumatra has an 87Sr86Sr ratio of 0.7139.The relationship between 87Sr86Sr and major and trace element geochemistry is variable and complex. Lavas from the same volcano sometimes show significant differences in 87Sr86Sr despite close geochemical relationships. Rocks of the calc-alkaline suite show a regular decrease in 87Sr86Sr from West Java to Bali and there is some evidence for increasing 87Sr86Sr with increasing depth to the Benioff zone. Calc-alkaline and tholeiitic rocks from the Sunda arc have significantly higher 87Sr86Sr ratios than those from other island arcs, except from those arcs where continental crustal involvement has been inferred (e.g. New Zealand).A model of 87Sr enrichment due to isotopic equilibration of oceanic crust with sea water and disequilibrium melting in the slab and/or mantle is favoured to explain the Sr isotopic composition of the tholeiitic and normal calc-alkaline lavas. Calc-alkaline lavas with high 87Sr86Sr ratios are best explained by either sialic contamination, or the presence of alkali basalt as a component of the downgoing slab. The Sr isotopic data for the high-K alkaline lavas suggest a mantle origin. The high 87Sr86Sr ratio in the Lake Toba rhyolite implies a crustal origin.  相似文献   

5.
Strontium isotopic studies on twenty three whole rock kimberlites from two petrographic provinces in India show variation of initial 87Sr86Sr ratios from 0.7027 to 0.7102. The variation is unrelated to the degree of alteration. Between the micaceous and basaltic varieties there is some overlap in the Sr isotopic ratios. Leaching experiments on whole rock samples showed more highly radiogenic Sr in leaches compared to the bulk samples.In two diatremes, the initial 87Sr86Sr ratios show a positive correlation with RbSr which is believed to reflect a source event earlier than the formation of the kimberlites. The observed Sr isotopic data can be caused by (i) melting of a heterogeneous source or (ii) disequilibrium partial melting in the source region. In the former case, variable isotopic composition would be a necessary consequence of melting in small subsystems.  相似文献   

6.
The isotopic composition of Pb and Sr and the abundances of Rb, Sr, U, Th, and Pb were determined for whole rock samples from all major volcanic centres of the Cenozoic alkaline volcanism of Central and South Italy, together with some samples from the contemporaneous anatectic Tuscan volcanism. The Sr and Pb isotopic compositions of the alkaline rocks show a negative correlation combined with a regional trend: the 87Sr86Sr ratios decrease from 0.711 in the north-west to 0.704 in the south-east, while the 206Pb204Pb ratios increase from 18.7 to 20.0. Variations in both isotopic compositions are generally small throughout erupted rock sequences for any volcanic centre.The Pb and Sr isotopic abundance variations are interpreted on the basis of two alternative models, which correspond to two groups of geological processes: variations can result (i) from a time dependent development in subsystems with different RbSr or U(Th)Pb ratios or, (ii) from mixing of Sr or Pb with different isotopic compositions. Combining both Pb and Sr isotope abundance measurements it is shown that the source of each volcanic centre is formed by various degrees of mixing between two components. One component and the most southern Tuscan anatectic rocks most likely have a common source, whereas the other component of the mixing process is suggested to be a liquid fraction derived from a small degree of partial fusion of a hydrous mantle. Thus at least a two-stage evolution of the Italian alkaline rocks is indicated: first a mixing process leading to the formation of the parental material followed by differentiation processes leading to the formation of the erupted rock sequences.The geodynamic model which explains the data best is that of a lateral inhomogeneous mantle. The lateral inhomogeneities in the mantle would be the result of mixing between originally mantle and crustal derived material. The mixing process itself would not have any primary connection with the Quarternary volcanic activity.  相似文献   

7.
Allan G. Krill 《Lithos》1983,16(2):85-93
The Saetra Nappe, consisting of feldspathic psammite cut by pre-tectonic dolerite dikes, is a distinctive tectonostratigraphic unit of the Western Gneiss Region of Norway. Although the rocks were metamosphosed at amphibolite facies, RbSr whole-rock sf three well preserved dikes a date of 745 ± 37 Ma with initial 87Sr/86Sr = .7046, interpreted to record the dike intrusion. Analysis of small psammite samples collected in rows parallel to the foliation and in columns perpendicular to it, indicate that the RbSr isotopic systems were not equilibrated on the whole-rock scale. The Strata Nappe provides evidence of a strong Caledonian deformation/metamorphic event in the Western Gneiss Region of Norway.  相似文献   

8.
87Sr86Sr measurements of 108 sedimentary carbonate rocks have been used to trace variations in the strontium isotopic composition of seawater during the Phanerozoic. The lowest 87Sr/86Sr observed for any suite of carbonates is taken as the best approximation to the value in well-mixed contemporary seawater. Our data support the existence of low 87Sr86Sr in the Cretaceous and Late Jurassic but they do not support further structure beyond a general trend through the Phanerozoic, which may correlate with the continental denudation rate.  相似文献   

9.
Twelve samples of mid-Tertiary felsic volcanic rocks from Zacatecas and San Luis Potosí (both belonging to the Sierra Madre Occidental) and one sample of Lower Tertiary porphyritic andesite from Zacatecas are analyzed for 87Sr86Sr, K, Rb, and Sr. Eight selected samples are also analyzed for 143Nd144Nd. A linear regression of the present-day 87Sr86Srand87Rb86Sr of the felsic volcanic rocks in Zacatecas gives an approximate date of 30 ± 8 Ma. The initial 87Sr86Sr ratios are high and widely distributed (from 0.705 to 0.712 or higher) whereas the initial 143Nd144Nd ratios are somewhat low and show a narrow range (0.5125–0.5127). The available isotopic and trace-element data are best explained in terms of a binary mixing model in which the magmas derived from a slightly depleted-mantle fractionate and mix with varying proportions of the overlying middle/upper continental crust and undergo further shallow-level fractional crystallization before eruption. This model is also compatible with the trace-element and Sr isotopic data published from other areas of the Sierra Madre Occidental for which a purely mantle origin has been proposed.  相似文献   

10.
Strontium isotopic measurements were made on Late Proterozoic carbonates from West African Craton. Comparison of samples with acceptable trace element patterns with coeval data from southern Africa and with the published Australian results suggests that the 87Sr86Sr ratio of the Late Proterozoic sea water evolved in the following manner about 0.7075 at 1000 ± 50 Ma, 0.7056 to 0.7074 at 900 ± 50 Ma, 0.7068 to 0.7091(0.7106) at 800 ± 50 Ma, 0.7074 to 0.7077 at 700 ± 50 Ma, and 0.7076 to 0.7089(0.7096) at 600 ± 50 Ma ago. The variations are comparable in magnitude and frequency to those described previously for the Phanerozoic. Strontium isotopic values in the radiogenic part of this range suggest that the continental river flux of Sr into Late Proterozoic oceans was of comparable isotopic composition to its present day counterpart (~0.711). Consequently, the non-radiogenic 87Sr86Sr value at ~900 ± 50 Ma ago signifies a large flux of “mantle” strontium into the ocean at this time. Because the present time resolution is only about 75 ± 25Ma, additional sampling as well as better stratigraphie resolution and more definite selection criteria are required for construction of a more detailed Late Proterozoic sea water curve.  相似文献   

11.
The 87Sr86Sr ratio of interstitial waters squeezed from recent sediments of the Pacific Ocean increases from 0.70920 ± 0.00017 (2σ) to 0.70960 ± 0.0023 and 0.70984 ± 0.00040 at 1.50 and 1.60 m depth—reference value for sea water: 0.70910 ± 0.00035. This variation underlines the likely existence of exchanges between the clays and the interstitial environment. The isotopic homogenization of strontium between the clays and their environment, result of these changes, becomes thus a credible phenomenon. This is a new argument for the dating of clays by the RbSr method.  相似文献   

12.
13.
Aragonite mineralization was observed in serpentinized peridotites from the Romanche and Vema Fracture Zones in the Atlantic and the Owen Fracture Zone in the Indian Ocean, either in veins or as radial aggregates in cavities within the serpentinites. Evidence of incipient dissolution of the aragonite crystals was observed in one case. The aragonites tend to have lower Mg content (< 0.03%) and higher Sr content (> 0.95%) relative to other marine aragonites. Their 18O16O, 13C12C and 87Sr86Sr isotopic ratios suggest the aragonite was deposited at ocean floor temperatures from solutions derived from sea water circulating in fissures and fractures within the ultramafic rocks. The 18O16O ratios of the serpentines indicate serpentinization occurred at higher temperatures, probably deeper in the crust. Low-T reactions between circulating seawater and Mg-silicates (primarily serpentine and pyroxenes) caused high pH and enrichment of Mg and Ca in the solution, conditions favoring carbonate precipitation. Aragonite was formed rather than calcite presumably because the high Mg2+ concentration in the solution inhibited calcite precipitation. The high Sr content of the aragonites is probably related, at least in part, to their low temperature of formation. Opaque mineral grains containing over 8% NiO and over 40% MnO were observed concentrated along the margins of some of the aragonite veins, suggesting that Ni is one of the elements mobilized during reactions between ultramafic rocks and circulating seawater.  相似文献   

14.
New analyses of K, Rb, Sr and Ba contents and the 87Sr86Sr ratios of eight amphiboles, one phlogopite, two diopsides and one host alkalic basalt for an amphibole are reported: The samples are mostly inclusions in alkalic basalts and occur in association with peridotite inclusions. Two of the samples are from alpine-type peridotite bodies — one from the Etang de Lhers massif in the French Pyrenees and the other from the Finero massif in the Ivrea zone in northern Italy. The kaersutites come from the following localities: Hoover Dam, Arizona; Deadman Lake, California; Massif Central, France; Queensland; Spring Mountain, New South Wales.The data indicate that kaersutitic amphiboles are genetically unrelated to their host basalts. The isotopic and trace element data of these amphiboles further strengthens the suggestion of BASU and MURTHY (1977) that kaersutites play a significant role in ocean ridge basalt genesis. In addition, pargasitic amphibole with higher 87Sr86Sr ratios, if present, may be important in the source regions of alkalic basalts.The bulk amphibole lherzolite from Lherz has the KRbratio and 87Sr86Sr ratio appropriate for source material of ridge tholeiites. If the diopside and the amphibole in this rock had isotopically equilibrated under upper mantle conditions, the data show the time of last equilibration to be approximately 735 m.y., in contrast to the young emplacement age of the ultramafic massif.The coexisting phlogopite and diopside in the spinel lherzolite inclusion from Kilbourne Hole, New Mexico, show, surprisingly, isotopic equilibration under upper mantle conditions despite their drastically different RbSr ratios. The data show that the phlogopite must have formed very recently in the upper mantle. This phlogopite also has a high KRb ratio (1133), contrary to the commonly held view that mantle phlogopites have low KRb ratios. The coexisting diopside shows high K content (778 ppm) and a lower KRb ratio than the phlogopite. This phlogopite lherzolite has trace elemental and isotopic characteristics that may be adequate for the origin of alkalic basalts upon partial melting.  相似文献   

15.
The 87Sr86Sr ratio in sea water has varied over geologic time due to the addition of strontium to the sea from rocks with a variety of 87Sr86Sr ratios. The measurements by Petermanet al. (Geochim. Cosmochim. Acta34, 105–120, 1970) of the value of the marine 87Sr86Sr ratio have been confirmed by several other workers and by some new measurements on JOIDES samples. They form the basis of a model calculation of the relative proportions of ‘basaltic’ (87Sr86Sr = 0.704) and ‘granitic’ (87Sr86Sr = 0.718) strontium being supplied to the sea. For the last 200 million years, the proportions of these two sources appear to reflect the history of global tectonics; ‘basaltic’ during rifting and increasingly ‘granitic’ during the present episodes of uplift and continental collision  相似文献   

16.
Cameronet al. (1981) proposed a “Free Line Model” for calculating formation ages for rock systems that have undergone local scale homogenization by 87Sr migration. This model is valid only if the variation in the 87Rb86Sr ratio is independent of the variation in Sr-content within the rock system. If Sr increases linearly with increasing 87Rb86Sr the calculated age will be too high. If Sr decreases linearly with increasing 87Rb86Sr, the calculated age will be systematically too low. If the rate of change in Sr with increasing 87Rb86Sr varies systematically through a rock system the “isochron” will be curved and the calculated ages will be younger or older than the real age, depending on the position of samples in relation to the curvature of the “isochron.” This problem with the “Free Line Model” is inherited in both the “Bulk Earth Model 1” and the “Bulk Earth Model 2.”  相似文献   

17.
RbSr whole rock analyses have been performed on 2 CI and 3 CM chondrites. Four of these stones (Ivuna, Orgueil, Cold Bokkeveld and Erakot) were previously studied in this laboratory and were shown to be discordant from a 4.6 Gyr isochron. The fifth, Murchison, was not previously studied. The new data support the discordance of the first four stones, and indicate that Murchison is also discordant. Studies of Sr isotope ratios in unspiked Orgueil show that the discordance is not due to inhomogeneities in the Sr84Sr86 ratio caused by incomplete mixing of nucleosynthesis products.In order to gauge the effects of weathering, two leaching experiments were performed on fresh, interior samples of Murchison; one for a period of 1.5 hr and the other for 117 hr. The results indicate that the relative solubility of nonradiogenic Sr is approximately twice that of Rb and radiogenic Sr is more soluble than the nonradiogenic Sr. This gives the residue a lower model age than the whole rock both by increasing the RbSr ratio and by decreasing the Sr87Sr86 ratio. This result is in contrast to that expected from studies of ordinary chondrite finds, which generally show higher model ages than falls. The constancy of KRb and KSr ratios between the two leaching experiments, and their difference from the unaltered whole rock ratios suggest that the bulk ratios are produced by dissolution of a single phase, and the higher radiogenic Sr content by selective leaching of other phases.  相似文献   

18.
The isotopic composition of strontium of pore water and of authigenic minerals leached from the sediment of core 119K with hot aqua regia is similar to that of the brine in the Discovery deep and differs from that of normal seawater. The average 87Sr86Sr ratio of strontium removed by acid leaching is 0.7077 ± 0.0007 (1σ) compared to a value of 0.70904 for the Red Sea. The detrital silicate fraction exhibits an approximate inverse correlation between 87Sr86Sr ratios and strontium concentrations which provides tentative support for a model in which the detrital silicate fraction of deep-sea sediment is considered to be a mixture of terrigenous dust of sialic composition enriched in radiogenic 87Sr and of volcanogenic material of basaltic composition and low 87Sr abundance. The 87Sr86Sr ratios of the shells of foraminifers and pteropods, expressed as δ 87Sr‰ relative to 0.70904 for seawater, decrease from ?0.23 ± 0.17‰ at 90 cm to ?0.82 ± 0.17‰ at 273 cm and remain constant at this value to a depth of 450 cm. The lowering of the δ 87Sr values is attributed both to the presence of aragonite overgrowths on pteropod shells and to possible isotope exchange with strontium in the connate fluid.  相似文献   

19.
Initial isotopic ratios of strontium have been determined in some calc-alkali rocks of Sardinia. The values of these ratios are from 0.7044 and 0.7047 in two basalts, and from 0.7063 to 0.7081 in five andesites. A dacite and a rhyolite have intermediate values of 0.7056 and 0.7058.It is suggested that increase of radiogenic strontium in andesite is most likely related to a contamination process involving water expelled from an underthrusting plate. This water also contributes to the increase in the potassium and related trace element contents in andesites.In spite of the87Sr86Sr difference between basalt and andesite, a cogenetic relationship between these two kinds of rocks cannot be precluded  相似文献   

20.
Rb-Sr and Pb/Pb whole rock isochrons on the Qôrqut Granite Complex yield ages of 2530 ± 30 Myr (initial87Sr86Sr = 0.7081 ± 0.0008) and 2580 ± 80 Myr respectively. A model relating initial Sr and Pb isotopic compositions of the Qôrqut granites to the Sr and Pb isotopic compositions of the Amîtsoq gneisses (ca. 3700 Myr) and Nûk gneisses (ca. 2900 Myr) at 2550 Myr ago, as well as Sr and Pb contents of the gneiss units, suggests that between 40 and 50% of the Qôrqut granite magma was generated by partial melting of Amîtsoq gneisses, and the remainder by partial melting of Nûk gneisses.  相似文献   

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