新疆尾亚地区石英二长闪长岩的岩浆混合成因

新疆东天山的尾亚钒钛磁铁矿矿区,在花岗岩中含有大量闪长岩包体,而且花岗岩与闪长岩相互包裹、渗透,并在花岗岩与闪长岩接触带形成二者混合的产物——岩浆混合岩。通过野外特征、岩相学和矿物成分对比,发现矿区中部的石英二长闪长(斑)岩体与岩浆混合岩完全相同,表明该岩体系岩浆混合成因。各类参与岩浆混合作用岩石的岩相学和矿物学表现出典型的岩浆混合作用特征。矿物不平衡组构主要有:钾长石的更长环斑结构、斑晶的环边结构、针状磷灰石发育、暗色矿物的聚晶团块、岩浆混合岩中出现钾长石"变晶"等等。各类岩石中斜长石和角闪石的主要氧化物成分对SiO_2(%)表现出类似全岩哈克图解的线性关系。主要造岩矿物的化学成分以及钾长石巨晶的化学成分剖面,反映出本区岩浆混合作用有化学混合的参与。黑云母的化学成分表明,本区岩浆混合为以壳慢混源为基础的混合作用。     

河南省安林矽卡岩型铁矿的成岩时代和成矿物质来源探讨

位于华北克拉通中部的河南省安林铁矿是典型的邯邢式矽卡岩型铁矿,矿体产于闪长质岩石和中奥陶统灰岩的接触带。LA-ICPMS锆石U-Pb定年结果表明安林闪长岩体的侵位年龄为123.38±0.81Ma,略晚于华北克拉通东部地区的含矿岩体,形成于岩石圈大规模减薄伸展时期。但其中含有古老的锆石说明岩浆经历了地壳的混染。闪长质岩石具有相对低SiO2、高Mg#、高碱,富集Ba、Sr和LREE大离子亲石元素,亏损Nb、Ti、Ta等高场强元素的特点,暗示了其形成于岩石圈地幔。岩相学特征以及Harker图解指示了岩浆经历了较强的分离结晶作用,因此推断安林闪长岩可能是软流圈地幔上涌导致富集的岩石圈地幔发生部分熔融形成原始的辉长质岩浆在上升过程中或岩浆房中发生了以铁镁矿物为主的分离结晶作用,同时受到地壳物质的混染的结果。安林地区矿石具有和闪长岩体相似的稀土元素地球化学特征,反映铁的成矿作用与岩浆作用密切相关。矿床中闪长岩体、矽卡岩、矿石和碳酸盐围岩的主量元素对比研究表明钠交代作用引起Na、K、Fe、Si等元素在各岩类间的迁移,其中迁移出的铁为成矿提供了物质基础。安林地区初始岩浆富含水,分离结晶作用使残留岩浆水饱和而发生出溶;且岩浆在演化过程中受到区内膏盐层和碳酸盐地层的混染,促进了岩浆中流体的出溶并使出溶的流体富含Cl-,为有利于铁质活化的富Cl-岩浆流体的形成创造了条件。     

新疆哈密黄山东铜镍硫化物矿床成岩成矿作用

黄山东铜镍硫化物矿床赋存于橄榄岩、苏长岩、辉长岩和闪长岩组成的镁铁-超镁铁质杂岩体中,赋矿岩体包含至少4套岩石组合。不同类型岩石微量元素和稀土元素原始地幔标准化配分模式指示,该矿床明显亏损Nb、Ta、Zr、Hf等高场强元素和Cr元素,富集Sr及大离子亲石元素;(La/Yb)N=1.08～2.70,δEu=0.50～2.57;含矿岩石Cu/Pd比值和Ti/Pd比值大于原始地幔值,表明不同类型岩石是高镁玄武质岩浆在深部分异结晶演化的产物。根据橄榄石和全岩化学组成可估算出母岩浆MgO含量约为12%。成矿岩浆深部演化过程中,富硅的地壳混染组分和外来流体的加入可能促成了岩浆中的硫饱和;深部熔离的不混溶硫化物珠滴被上升岩浆携带,富集在橄榄岩和苏长岩的底部。     

新疆黄山铜镍硫化物矿床成矿岩浆作用过程

黄山铜镍硫化物矿床镁铁．超镁铁质岩体岩相发育良好,主要包括橄榄岩、辉石岩、辉长岩和闪长岩,橄榄岩中部分橄榄石包含有硫化物珠滴。对该岩体不同岩相进行了主元素、微量元素、铂族元素和单矿物的分析,结果表明,不同类型岩石的化学组成受橄榄石、辉石和斜长石结晶分异作用的控制。微量元素和稀土元素具有相似的分布模式,（La／Yb）N介于1．14—3．65之间,明显亏损Nb和Ta,富集Sr。含矿岩石Cu／Pd和Ti／Pd比值大于原生地幔岩浆。上述结果揭示黄山镁铁-超镁铁质岩体不同岩性的岩石具有不同的主元素和微量元素特征,但母岩浆来自同一源区。根据橄榄石的F0值和全岩的主要氧化物组成估算出母岩浆为高镁（MgO约为15％）玄武岩岩浆,在岩浆作用过程中地壳富硅组分的混染是导致硫化物熔离的主要机制。     

胶东早白垩世中-酸性脉岩造岩矿物微区地球化学特征研究

胶东地区广泛发育早白垩世中-酸性脉岩群,但是其成因演化及成岩地质背景至今仍存在诸多争论。本文利用电子探针(EMPA)与激光剥蚀电感藕合等离子质谱(LA-ICP-MS)技术分析了胶东早白垩世石英闪长脉岩与闪长脉岩中主要造岩矿物(斜长石和黑云母)的主、微量元素组成;并结合岩石地球化学特征,对两者的岩浆源区和岩浆演化进行了研究探讨。石英闪长脉岩与闪长脉岩中黑云母低于检测线的Ca O含量与斜长石主量元素之间良好的线性关系指示两者为未受到后期变质作用影响的原生矿物,进一步说明胶东中生代石英闪长脉岩与闪长脉岩岩浆形成后,在上涌成岩过程中未受到变质作用的影响。石英闪长脉岩中壳源黑云母矿物成分基本一致的,以及斜长石正环带中核边部线性变化的An值与Fe、Mg、Sr、Ba等不相容元素特征指示石英闪长脉岩源于华北克拉通东部古老的加厚下地壳部分熔融作用,并在岩浆演化早期和晚期有一定幔源镁铁质岩浆混入,整个岩浆演化过程并未受到大气、俯冲、变质流体混入或构造作用的影响。闪长脉岩中黑云母矿物较大的Fe2+/(Fe2++Mg)比值范围,Al含量与结晶压力高度正相关以及斜长石中不相容元素特征指示本次研究中胶东闪长脉岩源自俯冲的板片来源的流体或沉积物混入所形成富集岩石圈地幔源区。胶东早白垩世石英闪长脉岩与闪长脉岩形成的大地构造动力学背景为古太平洋板俯冲-回撤引起热-机械侵蚀,进而导致岩石圈地幔减薄。在此情况下软流圈地幔上涌加热导致胶东富集岩石圈地幔部分熔融形成地幔熔体。这些幔源熔体经历分离结晶形成早白垩世闪长脉岩。此外,幔源镁铁质岩浆持续加热导致加厚下地壳部分熔融,形成了石英闪长脉岩。     

安徽铜陵中生代侵入岩地质地球化学特征再认识及成因讨论

安徽铜陵地区是我国最著名的铜多金属矿产地,岩浆岩出露广泛,岩浆作用与成矿关系密切.作者广泛收集了前人对铜陵地区中生代岩浆岩的研究资料和成果,并在此基础上进行了仔细的岩相学观察和深入的岩石学、岩石化学和微量元素及同位素地球化学研究,系统总结了该区中生代侵入岩的地质地球化学特征,并探讨了其成因机制.研究认为:①铜陵地区中酸性侵入岩形成于晚侏罗世-早白垩世(135 ～ 147Ma),岩浆活动持续时间大约为10～15Ma;岩体沿近东西向深断裂呈带状分布,浅成侵入产出,受多期不同方向和性质的断裂控制.②依据Q-A-P图解确定区内侵入岩主要为辉石闪长岩、石英(二长)闪长岩和花岗闪长岩3类中酸性闪长质岩石,均属亚碱性高钾钙碱性系列.③3类侵入岩具有相似的微量元素、稀土元素和Pb-Sr-Nd-O同位素地球化学特征,反映原始岩浆起源于富集岩石圈地幔,受到壳源物质的混染.④3类侵入岩可能是地壳深部带状岩浆房不同岩浆层中的岩浆与构造运动诱发的深断裂相沟通并随机地上升、脉动式侵位形成的;深部岩浆房中的带状岩浆层可能是由于温度梯度引起扩散对流作用进而发生一定程度的熔离分异作用所致;岩浆演化过程中存在镁铁矿物及磷灰石和锆石等矿物的结晶分异作用.⑤铜陵地区中生代岩浆活动的大地构造背景是大陆板块内部,岩浆作用与晚侏罗纪古太平洋板块的俯冲作用密切相关,但同时受区域前中生代基底构造的制约;侵入岩原始岩浆起源于挤压向拉张转换的动力学背景下的岩石圈地幔加厚之后的减压熔融并底侵下地壳岩石.     

浙北湖(州)-安(吉)火山岩盆地：锆石U-Pb年代学、地球化学与岩浆成因

处于浙-赣火山岩带东北缘的湖(州)-安(吉)盆地内的火山岩/潜火山岩从中性到酸性,中间没有明显的成分间断,以中酸性—酸性组分占绝对优势,中性组分相对较少,缺少基性组分,代表一套连续的中性—酸性岩浆系列。岩石化学总体表现为富碱和高钾的特征,中性岩属橄榄玄粗岩系列,中酸性—酸性岩类属高钾钙碱性系列。盆地内的火山岩在地球化学上均表现为富集大离子亲石元素和轻稀土元素,而高场强元素Nb、Ta、Ti等则有一定程度的亏损。火山岩中主量和微量元素的变异规律揭示分离结晶作用是盆地内岩浆演化的主要机理,但岩浆演化的不同阶段分离的矿物相有所差异,斜长石自始至终都是分离结晶的重要矿物相,在中性—中酸性岩浆演化阶段,角闪石可能也是重要的分离矿物,而中酸性—酸性岩中钾长石和黑云母的分离结晶也起着重要影响。本文所作的精确定年结果表明,盆地内三期火山活动产物的LA-ICPMS锆石U-Pb年龄在误差范围内几乎一致,介于128~130 Ma之间,指示盆地内主要火山活动持续的时间很短。另外测得粗安岩集块的SHRIMP锆石U-Pb年龄为136±1 Ma,可能意味着该盆地初期有少量偏基性的火山活动。推测湖安火山岩盆地发育于活动大陆边缘的后造山环境,岩浆的形成可能受控于岩石圈的拆沉或俯冲板片的断落,母岩浆主要是由镁铁质下地壳物质部分熔融形成的,几乎没有地幔物质的参与,所形成的安山质-英安质岩浆在浅部岩浆房中发生过强烈的分异演化。     

西准噶尔萨吾尔地区科克托别基性岩体岩石成因:地球化学和锆石U-Pb年代学证据

萨吾尔地区位于西准噶尔东北缘,广泛发育晚古生代中酸性侵入岩和火山岩以及少量基性侵入岩,这些岩浆岩的年代学研究对于限制西准噶尔地区石炭纪构造环境具有重要的意义。本文通过研究萨吾尔地区科克托别岩体的岩相学特征、锆石SHRIMP U-Pb年龄以及地球化学特征,探讨该岩体构造背景以及成因机制,为进一步论证西准噶尔地区石炭纪构造环境提供佐证。科克托别岩体包括中粗粒辉长岩、细粒辉长岩和闪长岩,在野外露头显示细粒辉长岩以脉状侵入中粗粒辉长岩中,细粒辉长岩中包裹有中粗粒辉长岩包体,中粗粒辉长岩与闪长岩之间呈渐变过渡接触关系,说明科克托别岩体是不同期次岩浆侵位形成的杂岩体,早期岩浆侵入形成中粗粒辉长岩和闪长岩,晚期岩浆上侵就位于中粗粒辉长岩构造裂隙中形成细粒辉长岩。科克托别岩体中细粒辉长岩锆石SHRIMP U-Pb年龄为323.2±6.2Ma,表明岩体形成于早石炭世晚期。该岩体成岩年龄晚于该地区蛇绿岩套岩石年龄,也晚于岛弧火山岩年龄以及含斑岩矿床侵入岩年龄,与该地区I型花岗岩年龄相似,而明显早于碰撞后A型花岗岩和双峰式火山岩的形成年龄,说明科克托别岩体可能形成于同碰撞构造环境中。不同岩相的岩石主量元素之间的相关关系以及微量元素配分型式相似性说明它们为同源岩浆结晶分异的产物。岩相学和地球化学特征表明岩体初始岩浆可能为软流圈地幔与上覆交代地幔相互作用形成,板片断离可能为软流圈地幔的上涌起到重要作用。     

The distribution of trace elements during strong fractionation of basic magma—a further study of the Skaergaard intrusion,East Greenland

A number of trace elements have been determined spectrographically in the rocks and minerals of the Skaergaard intrusion, East Greenland. The original basic magma from which the varied rocks of the complex were developed is shown to have had a normal trace element composition. The sorting out of the trace elements into the various mineral series produced by strong fractional crystallization of the original basic magma is traced in detail by means of analyses of the separated minerals. Certain of the trace elements (Cr, Ni) are shown to be strongly concentrated in the early rocks so that later fractions have little or none of them; other elements (P, V, Cu, Sc, Mn, S) reach maximum values in the middle, or late middle stages represented by certain olivine-free gabbros and ferrogabbros; other elements (Li, Zr, Y, La, Ba, Rb) tend to remain in the residual liquid during fractionation and are thus abundant in the latest granite fraction. Still other trace elements (Co, Sr, Ga, Mo) show only small changes in amount throughout the series. Of these Co is a little more abundant in the early and middle stages, Sr in the middle stages, Ga in the later stages and Mo in the early and later but not in the middle stages. The distribution of the trace elements in the rocks is considered in relation to the varying composition of the minerals produced by the fractional crystallization processes and an attempt is made to discuss the mineral compositions in terms of crystal chemical concepts.The Skaergaard sequence of differentiation from gabbros, through ferrogabbros, to granite is considered to be a common trend of fractionation of basic magma at high levels in the crust, and the observed changes in trace element composition are therefore regarded as having wide geochemical significance. The trace element composition of the intermediate Skaergaard differentiates is significantly different from that of diorites reported by other workers and suggests that diorites have had some other origin than by fractionation of basic magma. On the other hand the trace element composition of many granites resembles that of the granite fraction produced in the Skaergaard intrusion.     

Petrology of the Marginal Border Series of the Skaergaard Intrusion

The Marginal Border Series (MBS) of the Skaergaard intrusionconsists of rocks formed by in situ crystallization againstthe walls of the intrusion. Most of these rocks are productsof fractional crystallization, though samples believed to representchilled liquid occur locally at the intrusive contact. The MBScomprises only 5% of the exposed volume of the intrusion, butwithin its thickness, the order of crystallization and the compositionsof fractionated rocks and minerals vary systematically withdistance inward from the intrusive contact in largely the samemanner as rocks and minerals upward through the Layered Series(LS). Earliest differentiates are cumulates of olivine and plagioclase.The most basic compositions of cumulus plagioclase (An₇₂) andolivine (Fo₈₄) in these rocks indicate that the amount of fractionationpreceding formation of the exposed LS was substantially lessthat previously believed. Field and compositional data indicatethat picritic blocks are xenoliths rather than cumulates ofthe Skaergaard magma. Xenoliths of gneiss in all stages of reactionare locally abundant; however, there is no evidence that uppercrustal material contaminated the magma from which the MBS cumulatesformed. Compositions of cumulus minerals in the MBS differ fromthose in comparable LS rocks. Cumulates in the lower marginscontain more calcic plagioclase, more magnesian augite in allbut the late differentiates, and more iron-rich olivine. Thecompositions of cumulus olivine and to a lesser degree thoseof other mafic silicates, were modified to more iron-rich compositionsby re-equilibration with relatively large amounts of interstitialliquid. The lower MBS and LS crystallized from the same magma, but fractionationoccurred at different rates on the walls and floor of the intrusion.The upper margin may have crystallized from a magma of modifiedcomposition and fractionated at rates different from that inthe lower margin and Upper Border Series (UBS). Crystals onthe floor and roof of the intrusion accumulated faster or moreefficiently than on the walls. At any given stage of fractionation,crystals also accumulated against all sides of the magma chamberat about the same rate. Either the rates of cooling, crystallization,and crystal retention affected accumulation rates locally asfunctions of rock type and geometry of the walls, or these rateswere largely independent of wall rock owing to buffering ofconductive heat loss possibly to an envelope of hydrothermalfluid circulating around the crystallizing magma. The appearanceor disappearance of cumulus minerals in the lower MBS occursat higher structural levels than in the LS and at lower structurallevels than in the UBS. These relationships together with cumulusmineral compositions indicate that magma at the margins wasalways somewhat less fractionated than that at the floor androof of the chamber. It is proposed that these relationshipsreflect the combined effects of liquid and crystal fractionationof the magma within largely independent convection systems inthe lower and upper parts of the chamber.     

云南景洪南联山橄榄岩—闪长岩型岩体的特征及地质意义

岩相学和地球化学特征表明,南联山岩体是岩浆侵位的,岩石的分布显示环带构造;从中心向外依次为角闪橄榄岩、辉绿(辉长)岩和闪长岩。它们的结构和化学特征指示,这些岩石是由辉长-闪长岩质的岩浆结晶分异作用而形成的,角闪橄榄岩和部分辉绿岩为堆晶岩,其它的岩石为堆晶作用后分异而成的岩浆共结结晶作用所形成。原始岩浆的成分类似于高铝玄武岩和(或)玄武质安山岩。     

普朗斑岩铜矿岩浆混合作用：岩石学及元素地球化学证据

普朗斑岩铜矿花岗闪长斑岩中存在大量的随机分布的镁铁质微粒包体,包体与寄主岩存在渐变接触关系。包体成分为闪长质,具有岩浆结构,存在针状磷灰石,显示了快速冷却结晶的特征。包体内可见具有暗色矿物镶边的眼球状石英,表明存在岩浆混合作用。寄主岩岩体规模较小,呈岩枝状产出,包体和寄主岩均为似斑状结构,说明两种岩浆侵位和发生岩浆混合作用的深度较浅。元素地球化学特征显示包体与寄主岩的之间有成分交换。包体和寄主岩强不相容元素均富集,高场强元素Nb、Ta、Ti均表现出显著的负异常,具有典型的岛弧岩浆岩的微量元素特征,包体和寄主岩Mg＃较高,在同等Si条件下比玄武岩部分熔融体富K2O和MgO,意味着源区必须有幔源岩浆的贡献。普朗斑岩铜矿蚀变矿化模式反映了其成矿环境偏基性,暗示镁铁质岩浆的加入对成矿具有贡献。     

Petrochemistry of Volcanic Rocks in the Hishikari Mining Area of Southern Japan, with Implications for the Relative Contribution of Lower Crust and Mantle-derived Basalt

Abstract. This study presents the petrographical, mineralogical, and geochemical characteristics of Late Pliocene‐Pleistocene volcanic rocks distributed in the Hishikari gold mining area of southern Kyushu, Japan, and discusses their origin and evolution. The Hishikari volcanic rocks (HVR), on the basis of age and chemical compositions, are divided into the Kurosonsan (2.4–1.0 Ma) and Shishimano (1.7–0.5 Ma) Groups, which occur in the northern and southern part of the area, respectively. Each group is composed of three andesites and one rhyodacite. HVR are characterized by high concentrations of incompatible elements compared with other volcanic rocks in southern Kyushu, and have low Sr/Nd and high Th/U, Th/Pb, and U/Pb ratios compared with typical subduction‐related arc volcanic rocks. Modal and whole‐rock compositions of the HVR change systematically with the age of the rocks. Mafic mineral and augite/hypersthene ratios of the andesites decrease with decreasing age in the Kurosonsan Group, whereas in the Shishimano Group, these ratios are higher in the youngest andesite. Similarly, major and trace element compositions of the younger andesites in the former group are enriched in felsic components, whereas in the latter group the youngest andesite is more mafic than older andesites. Moreover, the crystallization temperature of phenocryst minerals decreases with younger age in the former group, whereas the opposite trend is seen in the latter group. Another significant feature is that rhyodacite in the Shishimano Group is enriched in felsic minerals and incompatible elements, and exhibits higher crystallization temperatures of phenocryst minerals than the rhyodacite of the Kurosonsan Group. Geochemical attributes of the HVR and other volcanic rocks in southern Kyushu indicate that a lower subcontinental crust, characterized by so‐called EMI‐type Sr‐Nd and DUPAL anomaly‐like Pb isotopic compositions, is distributed beneath the upper to middle crust of the Shimanto Supergroup. The HVR would be more enriched in felsic materials derived from the lower crust by high‐alumina basaltic magma from the mantle than volcanic rocks in other areas of southern Kyushu. The Kurosonsan Group advanced the degree of the lower crust contribution with decreasing age from 51 %, through 61 and 66 % to 77 %. In the Shishimano Group, the younger rhyodacite and andesite are derived from hotter magmas with smaller amounts of lower crust component (58 and 57 %) than the older two andesites (65 % and 68 %). We suggest that the Shishimano rhyodacite, which is considered to be responsible for gold mineralization, was formed by large degree of fractional crystallization of hot basaltic andesite magma with less lower crustal component.     

Crystallization of quartz dioritic magmas at 2 and 1 kbar: experimental results

Crystallization experiments were performed on quartz diorite (~55 wt.% SiO₂, 3.1–8.4 wt.% MgO) from the G?siniec Intrusion (Bohemian Massif, SW Poland) at 1?2 kbar, 750–850°C, various mole fractions of water and with fO₂ buffered by the NNO buffer. The two natural quartz diorites (leucocratic poikilitic quartz diorite - ‘LPD’ and melanocratic quartz diorite - ‘MD’) differ in whole rock and mineral composition with MD being richer in MgO and poorer in CaO than LPD, probably due to accumulation of mafic minerals or melt removal in MD. LPD represents melt composition and is used to reconstruct crystallization conditions in the G?siniec Intrusion. The crystallization history of LPD magma, deduced from experimental and natural mineral compositions, includes a higher pressure stage probably followed by emplacement at ~2 kbar of partly crystallized magma at temperatures ~850?800°C and quick cooling. The mineral assemblage present in LPD requires water contents in the magma of at least 5 wt% and oxygen fugacity below that controlled by the NNO buffer. The compositions of mafic minerals in the MD composition were equilibrated at temperatures below 775°C and at subsolidus conditions. The equilibration was probably due to the reaction between water-rich, oxidizing residual melt and the cumulatic-restitic mineral assemblage. MD is characterized by occurrence of the euhedral cummingtonite and increasing anorthite content in the rims of plagioclase. A similar reaction was reproduced experimentally in both LPD and MD compositions indicating that cummingtonite may be a late magmatic phase in quartz dioritic systems, crystallizing very close to solidus and only from water saturated magma.     

长江中下游地区鄂东南和九瑞矿集区成矿岩体特征及其识别标志

长江中下游地区是我国一条重要的铜多金属成矿带,成矿与燕山期岩浆活动密切相关,矿床类型主要有斑岩型和矽卡岩型。在长江中下游成矿带西段的鄂东南和九瑞地区产有该带中几个十分重要的大型铜多金属矿床,如铜绿山、鸡冠嘴、铜山口、城门山、武山等。通过对该区岩体的系统对比研究表明,成矿岩体和不成矿岩体的矿物组成,主微量元素成分及成岩年龄上并无明显差异。总体而言,九瑞地区岩浆岩的形成年龄集中在141～148Ma之间,略早于鄂东南地区与铜矿相关的岩浆岩(集中在137～140Ma)。对岩浆岩全岩的Sr-Nd同位素和锆石Hf同位素研究表明,一些成矿岩体具有比不成矿岩体更高比例的幔源物质贡献。对岩浆岩中主要造岩矿物,如角闪石和黑云母的详细研究,可以区分它们的不同结晶历史,从而揭示岩浆从早至晚演化过程中,相容元素和不相容元素、成矿元素和挥发份元素的变化规律,判别岩浆分离结晶过程、流体出溶过程,指示成矿与否。通过对角闪石和黑云母温压计的应用,估测了九瑞和鄂东南地区成矿岩体与不成矿岩体的侵位压力和深度,发现成矿岩体一般具有较低的压力(4kbar)和较浅的侵位深度。九瑞和鄂东南地区成矿岩体均具有较高的氧逸度。成矿岩体演化到晚期,氧逸度显示升高的趋势,岩浆中的挥发分/成矿金属含量较高。而不成矿岩体就位前岩浆贫化Cu、S、Cl等元素,不能分异出含足够成矿元素的成矿热液。因此,通过详细的矿物学、特别是造岩矿物角闪石和黑云母以及副矿物锆石和磷灰石的主微量元素和同位素组成的研究,以及由其计算出的温度、压力、氧逸度、流体成分等参数,可以区分成矿与不成矿岩体,从而为长江中下游成矿带乃至其他类似地区的深部找矿工作提供理论指导。     

西天山托云盆地及周边中新生代岩浆活动的岩石学、地球化学与年代学研究

天山西南部白垩纪-老第三纪发育的托云盆地及其周边出露的岩浆岩是一套完整的碱性岩浆岩系列，包含了苦橄质玄武岩、玄武岩、碧玄岩、碱玄岩（橄榄玄武岩、黑云母辉长二长岩、辉长辉绿岩、辉石橄榄岩）和响岩等多种岩石类型。野外工作显示有火山喷出岩和侵入岩两种不同的产状。年代学结果指示岩浆岩形成于120-50Ma间，为晚白垩世-老第三纪盆地形成演化阶段岩浆活动的产物。分离结晶作用是岩浆演化和岩浆系列形成最主要的因素，托云岩浆岩大致经历了结晶分异过程的两个阶段：早期苦橄质岩浆中橄榄石、尖晶石的结晶分离，表现为MgO和微量元素Cr含量随SiO2含量增加大幅度的降低；晚期主要是单斜辉石、斜长石和钛铁矿等矿物的结晶分异，以CaO、FeO、TiO2等随SiO2含量增加大幅度的降低为特点。苦橄质岩石的出现指示了地幔较高温熔融事件的存在，进而为托云盆地地幔柱的存在提供了有力的证据。无论如何，碱性岩浆的活动表明托云盆地形成的大地构造背景是大陆主动裂谷环境，对应的深部背景为区域性的地幔柱构造。首次发现的响岩是结晶分异作用的最终产物。响岩较极端地指示了岩浆结晶分离过程对岩浆演化的巨大影响。托云岩浆岩的同位素特征指示其源区是一个接近于PREMA地幔，但微量元素特征显示其受地壳流体交代改造的特点。岩浆岩的Nd同位素TDM集中在250～600Ma之间，反映了一个古生代时期形成的新生岩石圈地幔，与新疆北部地区的晚古生代新生岩石圈地幔的事实相符。     

内蒙古乌拉特中旗索伦山地区中元古代石英闪长岩的发现及其构造意义

在内蒙古乌拉特中旗索伦山地区首次发现了中元古代的石英闪长岩岩体。岩石富镁、碱(尤其富钠)和钙,贫硅、钛,属碱性系列岩石。轻稀土富集,重稀土相对亏损,Eu异常不明显。微量元素富集Rb、Ba、Sr等大离子亲石元素,亏损Nb、Ta、Zr、Hf、Ti等高场强元素,显示出与板块俯冲作用有关的弧岩浆特点。岩体形成于与俯冲消减作用有关的火山弧构造环境,其岩浆来源于受俯冲的板片流体/沉积物交代的岩石圈地幔部分熔融,源岩可能为变质玄武岩或变质英云闪长岩。采用LA- ICP- MS锆石U- Pb法获得的207Pb/206Pb加权平均年龄为1410±11Ma,代表了该石英闪长岩体的结晶年龄。结合区域地质背景,认为至少在1410Ma时华北北缘发生了板块俯冲汇聚作用,石英闪长岩可能是板块俯冲汇聚作用的直接产物。该成果为华北板块北缘俯冲汇聚作用开始的时限提供了新证据,同时为华北板块北缘在中元古代构造演化提供了重要依据。     

西藏拉萨地块西段狮泉河地区晚侏罗世花岗岩年代学、地球化学与岩石成因

目前关于拉萨地块西段狮泉河地区中生代岩浆岩的报道相对较少,限制了对该地区中生代岩浆作用的认识.对狮泉河地区石英闪长岩和闪长质包体的锆石U-Pb年龄、岩石学特征与元素地球化学进行了研究.结果显示,寄主石英闪长岩的年龄为161.1±1.7 Ma,闪长质包体的年龄为159.8±1.6 Ma和157.0±1.3 Ma,两者为同期形成.寄主石英闪长岩为I型准铝质中钾-高钾钙碱性系列岩石,具有富集大离子亲石元素、亏损高场强元素的特征.闪长质包体为准铝质中钾-高钾钙碱性系列岩石.岩石学、地球化学特征研究表明,该套岩石可能与中侏罗世班公湖-怒江特提斯洋南向俯冲有关,班公湖-怒江特提斯洋南向俯冲引起幔源物质发生熔融,上涌的幔源岩浆与拉萨地块古老基底重熔形成的酸性岩浆混合,形成了含闪长质包体的晚侏罗世岩体.      

桂东北里松花岗岩中暗色包体的岩浆混合成因

在桂东北姑婆山地区的里松花岗岩中,暗色包体广泛分布,包体的形貌、结构构造和矿物学特征表明,它们是岩浆快速冷凝结晶产物;主元素和微量元素组成说明它们属钾玄岩系列,其源岩具OIB型微量元素特征;包体与寄主花岗岩中锆石U-Pb年龄的相同性,排除了来源于深部固体岩石熔融残留体或浅部围岩捕虏体的可能性,而两种岩石化学成分、岩石结构暗色包体和寄主花岗岩在岩石结构和全岩Sr-Nd同位素组成方面的明显差别性,又排除了同源包体或析离体、堆积体的可能性。里松花岗岩在很多地质-地球化学特征上都介于里松暗色包体和姑婆山主体花岗岩之间,里松暗色包体的总体特征显示了岩浆混合成因,是里松暗色包体岩浆与姑婆山主体花岗岩岩浆发生混合时不完全混合的残留物。     

Cumulate gabbros from the Southwest Indian Ridge, 54°S-7° 16′ E: implications for magmatic processes at a slow spreading ridge

A diverse volcanic and plutonic rock suite was recovered from the center of the 80 km long ridge segment of the Southwest Indian Ridge (54°S, 7°16 E) between the Islas Orcadas and Shaka Fracture Zones. The cumulus nature of the gabbroic rocks in the suite is indicated by phase, modal and cryptic layering, igneous lamination, and low incompatible element abundances. We present a mass-balance model for calculating the proportions and compositions of cumulus phases and crystallized intercumulus liquid from bulk-rock major element compositions. The model is based on the ability to define a compositional array of basaltic liquids and on the assumption that cumulus minerals are initially in equilibrium with trapped liquid. Calculated proportions of trapped liquid range from 3%–15%; values that are characteristic of adcumulates to mesocumulates. Models of postcumulus crystallization indicate significant enrichments of incompatible elements and buffering of compatible elements in residual trapped liquids, thus explaining the high TiO₂ contents observed in magnesian clinopyroxenes. Cumulus phase assemblages and compositions suggest solidification in shallow level magma chambers, but disequilibrium plagioclase compositions suggest some crystallization at greater depth. Furthermore, basalt compositions projected onto the olivine-clinopyroxenequartz pseudoternary suggest magma generation over a range of pressures (from less than 10 to greater than 20 kb) as well as polybaric fractional crystallization. We suggest that the Southwest Indian Ridge is characterized by low magma supply with small batches of melt that either ascend directly to the surface having undergone limited polybaric crystallization or are trapped in shallow crustal magma chambers where they evolve and solidify to form cumulate gabbros. The adcumulus nature of the gabbros investigated here suggests slow cooling rates typical of large intrusions implying relatively large, but ephemeral magma chambers below segments of the Southwest Indian Ridge.