Microbial signatures in peritidal siliciclastic sediments: a catalogue

A catalogue of microbial structural signatures is presented, based upon the coupling of fundamental biogeochemical–microbial processes and local morphogenetic determinants. It summarizes a collection of sedimentary structures obtained from two modern siliciclastic peritidal environments in different climatic zones (temperate humid: Mellum Island, southern North Sea; subtropical arid: coast of southern Tunisia). Textural geometries reveal a high structural diversity, but their determinants are primarily based upon six major parameters: (1) intrinsic biofactors: structural diversification of sedimentary microbial films and mats inherent in the organisms, i.e. their construction morphology, growth, taxis and behaviour, and local abundance of specific morphotypes. Most prominent are the ensheathed filamentous cyanobacteria Microcoleus chthonoplastes and Lyngbya aestuarii, and the sheathless filamentous cyanobacterium Oscillatoria limosa. (2) Biological response to physical disturbances: sediment supply, erosion and fracturing of surface layers resulting from desiccation cause growth responses of biofilms and microbial mats. (3) Trapping/binding effects: physicobiological processes give rise to grain orientations and wavy to lenticular lamina, lamina‐specific grain arrangements and ‘sucrose’ calcium carbonate accumulations. (4) Secondary physical deformation of biogenic build‐ups: mechanical stresses acting upon sediments overgrown and biostabilized by biofilms and mats produce erosional and overthrust structures. (5) Post‐burial processes: textural fabrics that evolve from mechanical effects of gas formation from decaying mats, and features related to the formation of authigenic minerals (calcium carbonates, calcium sulphates, pyrite). (6) Bioturbation and grazing: post‐depositional structures, such as Skolithos‐type dwellings, traces of burrowing insects, gastropod grazing traces and faecal pellets. In synopsis, the catalogue firstly comprises a sound set of ubiquitous signatures. This uniformity in architectural characteristics is attributed to the presence and local dominance of certain microbes throughout the different settings. The catalogue secondly documents signatures that are extremely sensitive to tidal position, hydrodynamic regime and overall climatic conditions. These kinds of signature indicate narrow facies zones, which often coincide with the activity or dominance zones of certain organisms. An overview of structures of microbial origin from the fossil record underlines the potential of many of the signatures included in this catalogue to become fossilized and provide strong indicators of former siliciclastic tidal settings.     

Origin of fine-grained carbonate and siliciclastic sediments in an Early Palaeozoic slope sequence, Cow Head Group, western Newfoundland

The Cow Head Group is an Early Palaeozoic base-of-slope sediment apron composed of carbonate and shale. Whereas coarse-grained conglomerate and calcarenite are readily interpreted as debris-flow and turbidite deposits, calcilutite (lime mudstone), calcisiltite, and shale combine to form three distinct lithofacies whose present attributes are a function of both sedimentation and early diagenesis. Shale is the most common lithology. Black, green, and red shale colour variations reflect the abundance of organic matter in the source area and oxygenation conditions of the sea bottom. In black and green shale, millimetre- to centimetre-thick, alternating dark and light laminations represent terrigenous mud turbidites and hemipelagites, respectively. The calcisiltite/shale facies is uncommon and is composed of numerous graded carbonate-shale sequences (GCSS) deposited from waning carbonate turbidites and fall-out of terrigenous muds. Some of the characteristics of ribbon and parted lime mudstones in the calcilutite/shale facies can be explained by deposition of carbonate mud from dilute turbidity currents or hemipelagic settling. Other features are diagenetic in origin. The lack of micrite in GCSS and in the interbedded shales of the calcilutite/shale facies is interpreted to reflect early dissolution of the finer carbonate from these sediments. This remobilized carbonate was precipitated locally to: lithify lime mudstone turbidites or hemipelagites; form diagenetic lime mudstone beds and nodules; cement calcisiltites; and form dolomite. Many of the calcisiltites and calcilutites were, therefore, carbonate enriched at the expense of adjacent argillaceous sediments. These attributes characterize not only fine-grained sediments of the Cow Head Group but many other Early Palaeozoic slope carbonates as well, suggesting that the model proposed here for depositionl diagenesis has wider application.     

Metamorphism of the H-group chondrites: implications from compositional and textural trends in chondrules

Major and minor element bulk compositions of 373 individual chondrules from 18 H3 to H6 chondrites were determined in polished thin sections by broad-beam electron probe analysis. Bulk chondrule FeO and Al₂O₃ increase and TiO₂ and Cr₂O₃ decrease with increasing petrologic type; normative fayalite, albite and plagioclase increase through the petrologic sequence. Chondrule diameters correlate with phenocryst sizes in porphyritic chondrules of type 3 chondrites, but this correlation is diminished in the higher petrologic types. Furthermore, for a given chondrule diameter, phenocryst sizes are larger in the higher petrologic types. We attribute most compositional trends in chondrules through the petrologic sequence to diffusion and equilibration among chondrules and between chondrules and matrix in response to increasing degrees of thermal metamorphism. Increased phenocryst sizes in the higher petrologic types are probably the result of grain growth during metamorphism.We suggest that H-group chondrites formed by accretion of high-temperature (chondrules) and low-temperature (matrix) materials. Parent materials of each of the petrologic types resembled type 3 chondrites, but had slight compositional differences (e.g. volatiles, rare gases, total iron) inherited during accretion. These differences were predominantly functions of decreasing temperature in the nebula as accretion progressed. Internal reheating of the parent materials to different temperatures and (probably) for different times, as a function of depth in the parent body, caused compositional equilibration, grain coarsening, and reduction of FeO to Fe° by carbon.     

Diagenesis in carbonate sediments: A review

Reading the old textbooks of more than twenty-five years ago reveals the enormous progress made in our understanding since those days. Advances have been made along several related paths, particularly through the study of texture and structure with the microscope, the examination of Recent marine sediments and the application of the principles of solution chemistry. As a result we can now relate many diagenetic products with distinctive textures or structures to one of, say, four main types of aqueous solution. Sea water yields characteristic growths of aragonite and Mg-calcite whose fossilized calcitic remains we can yet recognise in the ancient. Fresh water gives rise to other individual calcite textures whose imprint also we can distinguish in the old rocks. Solution extruded at depth from compacting clays produce even other calcite textures which we are now beginning to understand. Certain mixtures of sea water with fresh water provide not only beach rocks with aragonite and Mg-calcite cements but dolomites through the Dorag process. Clearly influential in the control of marine precipitation we find organic compounds such as the humic acids.Superimposed on these products are the results of pressure solution. Clues to the action of processes in the distant past remain in the form of traces of magnesium, strontium or uranium and of relic isotopic ratios of oxygen and carbon, indicators of the composition of long vanished solutions. We think more clearly that before about rates of processes, duration of exposure to diagenetic environments, the balance between relatively closed and open chemical systems, the movements and mixing of ground waters and their chemical changes. In these and other ways carbonate diagenesis has come of age.

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Zusammenfassung Liest man alte Lehrbücher, die vor mehr als 25 Jahren erschienen sind, so erkennt man, welcher Fortschritt auf dem Gebiet der Karbonatdiagenese seither zu verzeichnen ist. Diese Fortschritte sind auf verschiedenen benachbarten Wegen erreicht worden, speziell durch Gefügeuntersuchungen mit dem Mikroskop, durch das Studium rezenter mariner Sedimente und durch die Anwendung der Prinzipien der Elementreaktionen in Lösungen. Als Ergebnis können wir heute viele diagenetische Stadien mit bestimmten Gefügemerkmalen und in erster Annäherung mit 4 Lösungsmilieus in Verbindung bringen. Meereswasser bewirkt typisches Wachstum von Aragonit und Hoch-Mg-Calcit, die wir in den fossilen calcitischen Gefügen wiedererkennen können. Süßwasser bewirkt auf der anderen Seite ein typisches Calcitwachstum, das wir ebenfalls in alten Gesteinen wiederfinden können. Lösungen, die aus kompaktierenden tonhaltigen Sedimenten aufsteigen, erzeugen calcitische Zementationsgefüge, die wir heute zu verstehen gelernt haben. Eine Mischung von Meereswasser und Süßwasser ist nicht nur für die beach-rock Zementation mit Aragonit und Hoch-Mg-Calcit verantwortlich, sie bewirkt auch Dolomitisierung nach dem Dorag-Modell.Organische Komponenten wie etwa Huminsäuren haben einen deutlichen Einfluß auf die Diageneseprozesse unter marinen Bedingungen. Den Diageneseprodukten werden schließlich die Einwirkungen der Drucklösung überlagert. Als Schlüssel zum Ablauf der Diagenese vergangener Zeiten verbleiben Spurenelemente wie Magnesium, Strontium und Uran sowie das reliktische Isotopenverhältnis von Sauerstoff und Kohlenstoff erhalten; sie markieren die Zusammensetzung längst vergangener Lösungen. Wir können heute besser die Anteile verschiedener Diageneseprozesse, die Dauer der Wirkung bestimmter Prozesse, den Ausgleich zwischen geschlossenen und offenen chemischen Systemen, die Bewegungen und Mischungen sowie chemischen Veränderungen des Grundwassers abschätzen.

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Résumé Parmi les vieux manuels agés de vingt-cinq ans ou davantage, on est frappé d'un coup d'il du progrès réalisé, surtout par l'étude des textures et des structures au microscope, par l'examen des sédiments marins actuels et par l'application de la chimie aqeuse. Conséquement on peut aujourd'hui lier les produits diagénétiques avec quatre solutions principaux. L'eau de mer donne les accroissements typiques en aragonite et en calcite-hautement magnésienne, reconnaisables aux calcaires anciens. L'eau douce fait surgir des textures individuelles en calcite. Aux profondeurs plus grands, les solutions exprimées des argiles y peuvent encore provoquer d'autres textures en calcite. L'eau de mer et l'eau douce, melées ensembles, y donnent naissance aux beach-rocks et aux dolomies. Franchement influents, aux précipitations marines, sont les composés organiques. Tout peut Être subi de la pression-solution. Données de la diagenèse ancienne restent telles que les traces du magnésium, du strontium et de l'uranium et des niveaux en ¹⁸O et ¹³C, témoins des compositions des solutions depuis longtemps disparues. On pense plus clairement qu'autrefois des taux des processus, des durées d'exposition aux milieux diagénétiques, du bilan entre les systèmes relativement fermés ou ouverts, des mouvements et des mélanges des eaux sousterraines et de leures changements chimiques. Dans telles mesures, l'étude de la diagenèse carbonatée a atteint sa majorité.

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Quantitative mineralogical analysis of carbonate sediments by X-ray diffraction: a new, automatic method for sediments with low carbonate content

A new X-ray diffraction method has been developed whereby the weight percentages of aragonite and low and high-magnesium calcite are determined from the integrated peak areas of samples. Peak areas are measured by a step scanning method. The weight percentages of MgCO₃ in calcite are determined from the angular position of the calcite peak. This technique uses a direct calculation method which simplifies the preparation of the samples and the calibration processes and increases the quality of the results. The fully automatic method uses a desk-top computer to guide the diffractometer and to carry out the necessary calculations. Tests on precision and accuracy of the method indicate that results with less than ± 4% error (mineral %) and ± 0.6% error (MgCO₃%) are obtainable for all samples even those with a low (10%) carbonate content.     

Differentiating fluvio-marine depositional environments in the Nile Delta using textural and compositional components

Textural and coarse fraction compositional components are evaluated to distinguish samples from modern environments of the Nile Delta of Egypt. These environments include: river, coastal dune, accretion ridges, beach, neashore, lagoon and prodelta. In this study petrological variables (12 textural and 18 mineralogical, faunal and floral) were considered for each sample. Discrimination was achieved by using simple bar graphs of the raw data for each environment and Q-mode factor analysis. The factor analysis yielded four compositional assemblages: Factor 1 is dominated by terrigenous fine sand; factor 2 consists of biogenic mud; factor 3 contains terrigenous coarse and medium sands; and factor 4 comprises composite silty sand. Discrimination of the seven environments is generally good, with a lower resolution for beach, coastal dune and river sands.Having discriminating the examined environments using Q-mode factor analysis, a graphic model was constructed to help determine the origin of ‘unknown’ samples. As a test, this model is satisfactory in identifying and interpreting the origin of sediments of Holocene age from two additional cores recovered off the delta coast.     

混合沉积研究进展与关键问题

近年来,混合沉积研究已逐渐成为沉积学领域颇受关注的重要课题。在前人研究的基础上系统梳理、总结了国内外混合沉积研究所取得的进展,提出了现阶段混合沉积研究面临的主要问题。国内外混合沉积研究可划分为4个阶段:现象描述阶段、基础理论研究阶段、海相混合沉积研究阶段、陆相混合沉积及综合研究阶段。受不同地质条件的约束,混合沉积岩石学分类方案并未形成统一的标准。混合沉积成因类型一般包括间断混合、相混合、原地混合与母源混合。混合沉积现象具有普遍性,可发育于海相、淡水湖盆、咸化湖盆等各类型沉积环境中,具有多样化的沉积类型,其控制因素一般包括碎屑物质供给、气候与水体环境、海（湖）平面变化、古地貌条件、构造作用以及水动力条件等。混合沉积具有重要的油气地质意义,与三角洲伴生的近源混合沉积、水下隆起区的远源混合沉积以及藻混合沉积可形成优质的陆相混积型油气储层。现阶段混合沉积研究中主要存在以下几方面问题:岩石分类方案不统一、缺乏与野外露头剖面和现代沉积的考察对比、层序格架内混合沉积发育模式不清、传统的成因类型在复杂陆相混合沉积研究中的应用存在较大局限性、混积型储层地震响应特征不明确。针对混合沉积进行全面、深入的研究,对古地理环境恢复、沉积动力学分析及相关油气勘探具有重要的意义。     

U-Th-Pb systematics of precambrian carbonate rocks: Dating of the formation and transformation of carbonate sediments

The current state in the Pb-Pb dating of the formation and epigenesis of Precambrian carbonate sediments has been reviewed. The geochemistry of admixture elements (U, Th, Pb, Rb, Sr, Mn, and Fe) constituting carbonate minerals and the redistribution of the elements in the course of early diagenesis and epigenesis have been considered. The advantages of choosing samples for Pb-Pb dating on the basis of geochemical criteria similar to those applied for Sr-isotope stratigraphy and the potentialities of applying different methods of decontamination of specimens, analyzed from surface contamination and possible epigenetic carbonate phases, were illustrated. By the example of a series of carbonate formations, distinctions in susceptibility of U-Pb and Rb-Sr systems of carbonate minerals to secondary transformations have been demonstrated. The prospects for using the method of step solution allowing noncogenetic carbonate generations to be separated and thus the accuracy and reliability of Pb-Pb dates to be upgraded were considered.     

The compositional classification of chondrites: III. Ungrouped carbonaceous chondrites

Seven carbonaceous chondrites (Allan Hills A77307, Adelaide, Al Rais, Coolidge, Grosnaja, Karoonda and Renazzo) with uncertain classifications were analyzed by instrumental and radiochemical neutron activation analysis for 29 elements: Na, Mg, Al, K, Ca, Sc, V, Cr, Mn, Fe, Co, Ni, Zn, Ga, Ge, As, Se, Br, Ru, Cd, Sb, La, Sm, Eu, Yb, Lu, Os, Ir and Au. Five of these chondrites (A77307, Adelaide, Al Rais, Karoonda and Renazzo) are unique ‘grouplets’, not closely related to other groups or to each other. Only Coolidge (CV4) and Grosnaja (CV3-an) are members of previously established groups. A77307 and Adelaide have refractory lithophile abundances similar to those in the CM-CO clan; A77307 probably is a member of that clan, but Adelaide, which shows CV-like petrographic characteristics, cannot as yet be assigned to a clan. Al Rais and Renazzo have similar refractory lithophile abundances (essentially at CI levels) and probably belong to the same clan, i.e., formed in the same region of the nebula. There are insufficient data to determine whether they formed at the same general region as the CI chondrites, but separates having O-isotope compositions near the terrestrial fractionation line indicate that this is plausible. Karoonda has refractory lithophile abundances ~ 1.21 × CI and appears to belong to a new clan distinct from CM-CO (1.11 × CI) and CV (1.34×).     

Storm-influenced siliciclastic and carbonate ramp deposits, the Lower Ordovician Dumugol Formation, South Korea

The Dumugol Formation (Lower Ordovician) in the southern part of the Baegunsan syncline, South Korea, contains mixed siliciclastic and carbonate ramp deposits. The ramp sediments were frequently influenced by storm events resulting in tempestites of sandstone-mudstone couplets, bioclastic grainstones to packstones, flat-pebble conglomerates, a skeletal lag layer and laminated calcisiltites. All tempestites are characterized by an erosive to sharp base, poor grading and a transitional upper boundary. The difference in lithology of tempestites appears to have been controlled by the nature of substrates and by proximality. For example, laminated calcisiltites have developed on the shallow carbonate ramp, flat-pebble conglomerates are closely associated with nodular limestones on shallow and deep ramps, and thin skeletal lag layers from fossiliferous argillaceous sediments formed in a basinal setting. The stratigraphic succession of the Dumugol Formation represents an initial transgression followed by a regression. The vertical facies change records the transition from a shallow siliciclastic ramp to a deep carbonate ramp, to a basin, shallowing to a deep carbonate ramp, and to a shallow carbonate ramp. Storm effects are mostly well preserved in shallow to deep ramp deposits.     

The compositional classification of chondrites: II The enstatite chondrite groups

We present new data from a neutron activation analysis of four enstatite chondrites including the taxonomically important St. Sauveur, and discuss the classification of enstatite chondrites. The enstatite chondrites can be divided into two compositionally distinct sets; in one set abundances of nonrefractory siderophiles and moderately volatile chalcophiles and alkalis are 1.5–2.0× higher than in the other. A well-resolved compositional hiatus separates these two sets. The differences in composition are as great as those between the groups of ordinary chondrites, and therefore it appears best to treat these sets as separate groups. By analogy with the symbols used for ordinary chondrites we propose to designate the high-Fe, high siderophile group EH and the low-Fe, low-siderophile group EL. Known members of the EH group belong to petrologic types 4 and 5, whereas all EL members are petrologic type 6. Within the EH group no correlation is observed between petrologic type and abundance of nonrefractory siderophiles or moderately volatiles or alkalis.Two physical properties show only modest overlap between the EH and EL groups. Cosmic-ray ages for EH chondrites are 0.5–7 Ma, while those for EL chondrites are 4–18 Ma. Relative to Bjurböle, I-Xe formation intervals are $\text{?1.3 ± 0.6}$ Ma for EH chondrites and $\text{2.9 ± 0.5}$ Ma for EL chondrites. The weight of the chemical and physical evidence indicates that the EH and EL groups formed separate bodies at similar distances from the Sun.The available evidence for Shallowater and Happy Canyon, two strongly recrystallized silicate-rich meteorites containing > 40 mg/g Fe-Ni, indicates that the former is an enstatite-clan chondrite altered by loss of sulfide- and plagioclase-rich melts, whereas the latter is intermediate in composition between EL chondrites and the chondritic silicates in the Pine River IAB-anomalous meteorite.     

U-Th dating of carbonate platform and slope sediments

Absolute chronology of marine sediment beyond the ¹⁴C age range provides a test for models of climate change and has many other applications. U-Th techniques have been used for such chronology by dating corals, but extending these techniques to marine sediment is complicated by the presence of significant initial ²³⁰Th—both in detrital material and scavenged from seawater. In this study, we investigate four methods of solving the initial ²³⁰Th problem for a particular type of marine sediment—the aragonite-rich sediments of carbonate platforms and slopes. Bulk sediment U-Th analyses can be corrected for initial Th to yield ages with ≈2 to 3 kyr precision for highstand periods when sediment aragonite contents are particularly high. Uncertainty on the corrections causes inadequate precision for sediment from other periods, however. Removal of scavenged Th before analysis would enable a dramatic increase in this precision but has not proved successful despite a range of chemical leach approaches. Using heavy liquids to separate the various carbonate minerals found in Bahamas sediment enables an isochron approach to correct for initial Th, but the presence of initial Th from two sources requires correction or removal of one source of initial Th before the other is deconvolved by the isochron. Quantitative removal of detrital material before isochron analysis proves a successful approach. Such isochron data demonstrate that, although sediment remains closed to U-Th on a centimetre scale, nuclides are moved from grain to grain by α-recoil. Such intergrain exchange is expected to be observed in all sediments containing mineral grains with different U concentrations. Measured ²³⁴U/²³⁸U allows the recoil movement to be corrected and results in isochron ages with precision sometimes as low as 3 kyr. The accuracy of this approach has been proved by dating samples within the ¹⁴C age range. Sediments spanning the penultimate deglaciation have also been dated. After a small correction for bioturbation, the age for this event is found to be 135.2 ± 3.5 ka. This date is ≈8 kyr before the peak in northern hemisphere insolation and suggests that deglaciation is initiated by a mechanism in the southern hemisphere or tropics. This isochron approach shows considerable promise for dating of sediments older than this event, which will provide further information about the timing and mechanisms of global climate change.     

Quantitative compositional analysis of a Triassic carbonate platform (Southern Alps,Italy)

We have estimated abundance and distribution of automicrite, marine cements and skeletal grains in the Triassic Sella massif, an isolated platform flanked by steep (25–35°) clinoforms. 108 samples were taken at constant intervals from measured sections of the major zones of the platform edifice: the platform top, margin–upper slope, and lower slope. In a first step, carried out in the field and on hand specimen, purely detrital deposits were separated from automicrite facies, i.e. beds with automicrite, cement-filled, primary vugs and admixtures of skeletal carbonate and lithoclasts. In the second step, samples with automicrite facies were thin-sectioned and point counted. The categories used for point counting were (a) automicrite, (b) vugs and cement, (c) microspar or neomorphic spar, (d) skeletal grains and (e) internal sediments. At the platform top 46% of samples are pure detrital deposits, 27% consist of automicrite facies and 27% are too strongly altered by dolomitization to allow classification. At the margin–upper slope 68% of samples consist of automicrite facies, 22% are pure detrital sediments and 10% are strongly altered. At the lower slope 63% are detrital deposits, 10% automicrite facies and 27% are extensively dolomitized. The most important contributors to the automicrite facies are automicrite (41% on the platform top, 29% on the margin–upper slope, 28% on the lower slope) and early marine cement (35% on the platform top, 48% on the margin–upper slope, 27% on the lower slope). The amount of skeletal grains is less than 10%.The automicrite facies stabilized the platform margin and upper slope. Automicrite, abundant early marine cements and micro-organisms such as Tubiphytes, formed a rigid framework, thus substituting for the lack of a metazoan reef. On the upper slopes, the framework of automicrite facies stabilized the slope but intermittently. The automicrite layers are frequently dissected by sediment-filled fractures or are broken into clasts. We assume that they slid on the layers of loose detritus. Bigger slides turned into rubbly debris flows that formed metre-thick breccias at the lower slope and the proximal basin floor. The planar shape and steep angle of the clinoforms indicate that the large-scale geometry of the slope was not controlled by the automicrite but rather by non-cohesive layers of sand and rubble piled up to the angle of repose.The production mode of the Sella is comparable of that of a (mud) mound factory. This factory was highly productive: in 1 Ma, the platform aggraded over 300 m and prograded over 2000 m in all directions.     

The compositional classification of chondrites: IV. Ungrouped chondritic meteorites and clasts

Six specimens of unusual chondritic materials were analyzed by neutron activation for 30 elements in order to assess their degree of chondritic compositional pristinity and to search for evidence of genetic links to other chondrites. Five have highly recrystallized textures; the other, the Cumberland Falls chondrite, has suffered minor metamorphic recrystallization. Acapulco and Allan Hills A77081, are closely related and have subpristine compositions; they are more distantly related to Enon which has an altered composition. Udei Station appears to be a IAB meteorite even though its $\text{FeO}\text{(FeO + MgO)}$ ratio is slightly above the IAB field. The highly weathered meteorite Tierra Bianca is closely related to IAB but has a δ¹⁸O value 5 standard deviations higher than the IAB mean and is designated ungrouped. Udei Station and Tierra Bianca have altered compositions; rare earth element patterns indicate loss of a phosphate phase. The elemental composition of the Cumberland Falls chondrite is virtually identical to that of LL chondrites and its O-isotope composition is closely similar to those of some unequilibrated ordinary chondrites including LL Semarkona. The $\text{FeO}\text{(FeO + MgO)}$ ratios in its olivine are generally much lower than those in pyroxene, a relationship we show to be indicative of in situ reduction resulting from exchange with the aubritic host. The names winonaites and forsterite chondrites have no taxonomic utility.     

Diagenetic processes in Holocene carbonate sediments: Florida Bay mudbanks and islands

The sedimentology, mineralogy and pore fluid chemistry of seven cores from the Holocene sediments of Florida Bay were studied to determine the physical processes and diagenetic reactions affecting the sediments. The cores were taken in a transect from a shallow mudbank onto a small adjacent island, Jimmy Key. Steady state models of pore fluid chemistry are used to estimate the rates of various reactions. In the mudbank sediments, little carbonate mineral diagenesis is taking place. No change in sediment mineralogy is detectable and pore water profiles of Ca²⁺, Mg²⁺ and Sr²⁺ show only minor variation. Chloride concentrations indicate substantial biological mixing of seawater from the bay into the sediments in one of the cores. Pore water analyses of sulphate and alkalinity show only a low degree of sulphate depletion and a decreasing extent of sulphate reduction downcore. Models of sulphate reduction in the mudbank show that there is substantial chemical exchange between the sediment pore fluids and water from the bay probably as a result of bio-irrigation. The sulphate and alkalinity data also suggest that the underlying Pleistocene rocks contain water of near normal seawater composition. Stratigraphic analysis and δ¹³C analyses of the organic carbon in the sediments of the island cores show that the sediments were primarily deposited in a subtidal mudbank setting; only the upper 20–30 cm is supratidal in origin. Nevertheless, island formation had a significant effect on pore fluid chemistry and the types of diagenetic reactions throughout the sediment column. Chloride in the sediment pore fluids is more than twice the normal seawater concentrations over most of the depth of the cores. The constant, elevated chloride concentrations indicate that hypersaline fluids which formed in ponds on the island are advected downward through the sediments. Models of the chloride profiles yield an estimate of 2·5 cm yr^?1 as a minimum advective velocity. Changes in pore water chemistry with depth are interpreted as indicating the following sequence of reactions: (1) minor high-Mg calcite dissolution and low-Mg calcite precipitation, from 0 to 35 cm; (2) Ca- or Mg-sulphate dissolution and low-Mg calcite precipitation, from 5 to 35 cm; (3) dolomite or magnesite precipitation together with sulphate reduction, from 35 to 55 cm; and (4) little reaction below 55 cm. In addition, one or more as yet unidentified reactions must be taking place from 5 to 55 cm depth as an imbalance in possible sources and sinks of alkalinity is observed. The imbalance could be explained if chloride is not completely conservative. Despite the pore fluid chemical evidence for diagenetic reactions involving carbonate minerals, no changes in sediment mineralogy were detected in X-ray diffraction analyses, probably because of the comparatively young age of the island.     

Mixed precision parallel preconditioner and linear solver for compositional reservoir simulation

Reservoir simulation role in value creation and strategic management decisions cannot be over emphasized. Simulation of complex challenging reservoirs with millions of grid blocks especially in compositional mode is very time-consuming even with fast modern computers. On the other hand, high price of cluster supercomputers prevents them for being commonly used for fast simulation of such reservoirs. In recent years, the development of many-core processors like cell processors, DSPs, and graphical processing units (GPUs) has provided a very cost-effective hardware platform for fast computational operations. However, programming for such processors is much more difficult than conventional CPUs, and new parallel algorithm design and special parallel implementation methods are needed. Using the computational power of CPUs, GPUs, and/or any other processing unit, Open Computing Language (OpenCL) provides a framework for programming for heterogeneous platforms. In this paper, OpenCL is used to employ the computational power of a GPU to build a preconditioner and solve the linear system arising from compositional formulation of multiphase flow in porous media. The proposed parallel preconditioner is proved to be quite effective, even in heterogeneous porous media. Using data-parallel modules on GPU, the preconditioner/solver runtime reduced at least 1 order of magnitude compared to their serial implementation on CPU.     

Bathymetry and sediments on the carbonate platform off western India: Significance of Halimeda bioherms in carbonate sedimentation

Bathymetry across the carbonate platform off western India indicated small-size pinnacles and their lateral coalescence into 2 -6-m high mounds landward, and linear elongated carbonate ridges and troughs, mounds and banks up to a height of 20-m seaward of the platform. Seismic data indicated that these mounds were transparent with no rigid internal structure and can be defined as bioherms. The sediments were abundantly aragonite faecal pellets, Halimeda grains and ooids and their radiocarbon ages ranged from 11 to 7.5 ka BP. It appears that the growth of Halimeda bioherms on the platform was facilitated by intense upwelling during the early Holocene. The terrigenous sediments brought by rivers were deposited in the inner shelf and have not affected the growth of bioherms. It is estimated that the platform comprises at least 1.85 Gt of mass CaCO\(_3\) accumulated during the early Holocene and comparable to those on the Great Barrier Reef. Halimeda bioherms produce abundant carbonate sediments and their growth period represents a geological carbonate sink and release of high CO\(_2\) to the atmosphere. Detailed shallow seismic studies and sediment cores are needed to quantify the exact mass content of CaCO\(_3\) and model climate change during the early Holocene.     

Physical and biological controls on the formation of carbonate and siliciclastic bedforms on the north-east Brazilian shelf

The continental shelf of the State of Rio Grande do Norte, Brazil, is an open shelf area located 5°S and 35°W. It is influenced by strong oceanic and wind-driven currents, fair weather, 1·5-m-high waves and a mesotidal regime. This work focuses on the character and the controls on the development of suites of carbonate and siliciclastic bedforms, based on Landsat TM image analysis and extensive ground-truth (diving) investigations. Large-scale bedforms consist of: (i) bioclastic (mainly coralline algae and Halimeda) sand ribbons (5–10 km long, 50–600 m wide) parallel to the shoreline; and (ii) very large transverse siliciclastic dunes (3·4 km long on average, 840 m spacing and 3–8 m high), with troughs that grade rapidly into carbonate sands and gravels. Wave ripples are superposed on all large-scale bedforms, and indicate an onshore shelf sediment transport normal to the main sediment transport direction. The occurrence of these large-scale bedforms is primarily determined by the north-westerly flowing residual oceanic and tidal currents, resulting mainly in coast-parallel transport. Models of shelf bedform formation predict sand ribbons to occur in higher energy settings rather than in large dunes. However, in the study area, sand ribbons occur in an area of coarse, low-density and easily transportable bioclastic sands and gravels compared with the very large transverse dunes in an offshore area that is composed of denser medium-grained siliciclastic sands. It suggests that the availability of different sediment types is likely to exert an influence on the nature of the bedforms generated. The offshore sand supply is time limited and originates from sea floor erosion of sandstones of former sea-level lowstands. The trough areas of both sand ribbons and very large transverse dunes comprise coarse calcareous algal gravels that support benthic communities of variable maturity. Diverse mature communities result in sediment stabilization through branching algal growth and binding that is thought to modify the morphology of dunes and sand ribbons. The occurrence and the nature of the bedforms is controlled by their hydrodynamic setting, by grain composition that reflects the geological history of the area and by the carbonate-producing benthic marine communities that inhabit the trough areas.     

Benthic foraminifera in sandy (siliciclastic) coastal sediments of the Arabian Gulf (Saudi Arabia): a technical report

The Uromia–Dokhtar Magmatic Arc (UDMA) is a northwest–southeast trending magmatic belt which is formed due to oblique subduction of Neotethys underneath Central Iran and dominantly comprises magmatic rocks. The Jebal-e-Barez Plutonic Complex (JBPC) is located southeast of the UDMA and composed of quartz diorite, granodiorite, granite, and alkali granite. Magmatic enclaves, ranging in composition from felsic to mafic, are abundant in the studied rocks. Based on the whole rock and mineral chemistry study, the granitoids are typically medium-high K calc-alkaline and metaluminous to peraluminous that show characteristics of I-type granitoids. The high field strength (HFS) and large ionic radius lithophile (LIL) element geochemistry suggests fractional crystallization as a major process in the evolution of the JBPC. The tectonomagmatic setting of the granitoids is compatible with the arc-related granitic suite, a pre-plate collision granitic suite, and a syncollision granitic suite. Field observations and petrographic and geochemical studies suggest that the rocks in this area are I-type granitoids and continental collision granitoids (CCG), continental arc granitoids (CAG), and island arc granitoid (IAG) subsections. The geothermobarometry based on the electron probe microanalysis of amphibole, feldspars, and biotite from selected rocks of JBPC implies that the complex formed at high-level depths (i.e., 9–12 km; upper continental crust) and at temperatures ranging from 650 to 750 °C under oxidation conditions. It seems that JBPC is located within a shear zone period, and structural setting of JBPC is extensional shear fractures which are product of transpression tectonic regime. All available data suggested that these granitoids may be derived from a magmatic arc that was formed by northeastern ward subduction of the Neotethyan oceanic crust beneath the Central Iran in Paleogene and subsequent collision between the Arabian and Iranian plates in Miocene.