An observational aircraft-based study of sea-breeze frontogenesis

In the summer of 1988/89 flights were carried out in the Coorong coastal area of South Australia to investigate sea-breeze fronts. The flights yielded data sets of the structure of the fronts in the cross-frontal direction with a spatial resolution of approximately 3 m. The study is focused on the budgets of sensible and latent heat in the vicinity of the front and on frontogenesis/frontolysis processes which are closely related to budget considerations.The frontogenesis relationships and the budgets were established on a 2 km length scale by low-pass filtering of the space series. As the wind components were measured with high accuracy, all processes which determine frontogenesis could be evaluated and are displayed in x,z-cross-sections: these are the confluence, shear and diabatic effects, all of which play a role in q/x-, q/z-, /x- as well as /z-frontogenesis. A detailed analysis is given for two different states of frontal development. The presented results shed much light on the governing physical processes in the frontal region with strong emphasis on the effects of confluence-generated updrafts, on shear instabilities causing bulges and clefts in the frontal surface as well as producing the elevated frontal head, and on processes related to differential heating and moistening.     

Parameterizing turbulent diffusion through the joint probability density

The convective mass flux parameterization often used in meteorological modeling expresses the vertical flux of a transported scalar as proportional to the product of the difference in mean values of the scalar in updrafts and downdrafts and their characteristic velocity. The proportionality factor is a constant to be specified. We show that this proportionality factor also appears in the relaxed eddy accumulation technique of Businger and Oncley. That associates the surface-layer flux of a scalar with the product of the standard deviation of vertical velocity and the mean concentration difference between updrafts and downdrafts.We show that this constant (b) is determined uniquely by the joint probability density (jpd) of vertical velocity and the scalar. Using large-eddy simulation, we generate this jpd for a conservative scalar diffusing through a convective boundary layer. It has quite different forms in top-down and bottom-up diffusion geometries. The bottom-up jpd is fairly well represented by a jointly Gaussian form and implies b ~ 0.6, in good agreement with the surface-layer value reported by Businger and Oncley. The top-down jpd is strikingly non-Gaussian and gives b ~ 0.47. Updrafts carry the bulk of the scalar flux - 70% in the bottom-up case, 60% in the top-down case.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Estimation of the Monin-Obukhov similarity functions from a spectral model

From measured one-dimensional spectra of velocity and temperature variance, the universal functions of the Monin-Obukhov similarity theory are calculated for the range –2 z/L + 2. The calculations show good agreement with observations with the exception of a range –1 z/L 0 in which the function _m , i.e., the nondimensional mean shear, is overestimated. This overestimation is shown to be caused by neglecting the spectral divergence of a vertical transport of turbulent kinetic energy. The integral of the spectral divergence over the entire wave number space is suggested to be negligibly small in comparison with production and dissipation of turbulent kinetic energy.Notation a,b,c contants (see Equations (–4)) - C_i constants i=u, v, w, (see Equation (5) - k_me,k_mT peak wave numbers of 3-d moel spectra of turbulent kinetic energy and of temperature variance, respectively - k_mi peak wave numbers of 1-d spectra of velocity components i=u, v, w and of temperature fluctuations i= - k_sb, k_c characteristics wave numbers of energy-feeding by mechanical effects being modified by mean buoyancy, and of convective energy feeding, respectively - L Monin-Obukhov length - % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% Gabeivayaaraaaaa!3C5B!\[{\rm{\bar T}}\] difference of mean temperature and mean potential temperature - T* Monin-Obukhov temperature scale - velocity of mean flow in positive x-direction - u* friction velocity - u, v, w components of velocity fluctuations - z height above ground - von Kármanán constant - temperature fluctuation - _m nondimensional mean shear - _H nondimensional mean temperature gradient - nondimensional rate of lolecular dissipation of turbulent kinetic energy - _D nondimensional divergence of vertical transports of turbulent linetic energy     

The Effect of Atmospheric Stability on the Surface-Layer Characteristics in a Low-Wind Area of Tropical West Africa

This study details the observed effects ofatmospheric stability on characteristics of thesurface layer in a low wind speed (U = 1.5 m s-1)regime of tropical West Africa. Theaerodynamic roughness length, z0, anddisplacement height, d, obtained from profilewind-speed data at our bush land site (height 2 m)have values of 0.24 ± 0.10 m and 1.54 ± 0.04 mrespectively. In the unstable range (-2.5 < Ri < -0.1; Riis gradient Richardson number), thestandard deviation in wind speed fluctuations, u, increased from 0.57 ± 0.19 m s-1 toa maximum of 0.7 ± 0.2 m s-1 in near-neutralconditions, and in the stable range, the parameterdecreased rapidly to 0.41 ± 0.15 m s-1 at Ri 0.2.In the same stability range, the horizontal winddispersion, , decreased withincreasing stability from 19 ± 8 deg. to 13 ± 5 deg.The surface-layer integral quantity, u/u*, when plottedas a function of stability, is in agreement with theempirical results. The ratio ofsensible heat flux (estimated) to the net radiationranged between 0.1 and 0.2 at nighttime,increasing to about 0.5 during the daytime, and showeda strong dependency on season.     

The atmospheric tide as a continuous spectrum: Lunar semidiurnal tide in surface pressure

Summary The standard equations for the theory of atmospheric tides are solved here by an integral representation on the continuous spectrum of free oscillations. The model profile of back-ground temperature is that of the U.S. Standard Atmosphere in the lower and middle atmosphere, and in the lower thermosphere, above which an isothermal top extends to arbitrarily great heights. The top is warm enough to bring both the Lamb and the Pekeris modes into the continuous spectrum.Computations are made for semidiurnal lunar tidal pressure at sea level at the equator, and the contributions are partitioned according to vertical as well as horizontal structure. Almost all the response is taken up by the Lamb and Pekeris modes of the slowest westward-propagating gravity wave. At sea level, the Lamb-mode response is direct and is relatively insensitive to details of the temperature profile. The Pekeris mode at sea level has an indirect response-in competition with the Lamb mode-and, as has been known since the time of its discovery, it is quite sensitive to the temperature profile, in particular to stratopause temperature. In the standard atmosphere the Lamb mode contributes about +0.078 mb to tidal surface pressure at the equator and the Pekeris mode about –0.048 mb.The aim of this investigation is to illustrate some consequences of representing the tide in terms of the structures of free oscillations. To simplify that task as much as possible, all modifying influences were omitted, such as background wind and ocean or earth tide. Perhaps the main defect of this paper's implementation of the free-oscillation spectrum is that, in contrast to the conventional expansion in the structures of forced oscillations, it does not include dissipation, either implicity or explicity, and thus does not satisfy causality. Dissipation could be added implicity by means of an impedance condition, for example, which would cause up-going energy flux to exceed downgoing flux at the base of the isothermal top layer. To achieve complete causality, however, the dissipation must be modeled explicity. Nevertheless, since the Lamb and Pekeris modes are strongly trapped in the lower and middle atmosphere, where dissipation is rather weak (except possibly in the surface boundary layer), more realistic modeling is not likely to change the broad features of the present results.Symbols a earth's mean radius; expansion coefficient in (5.3) - b recursion variable in (7.4); proximity to resonance in (9.2) - c sound speed in (2.2); specific heatc _p in (2.2) - f Coriolis parameter 2sin in (2.2) - g standard surface gravity - h equivalent depth - i ; discretization index in (7.3) - j index for horizontal structure - k index for horizontal structure; upward unit vectork in (2.2) - m wave number in longitude - n spherical-harmonic degree; number of grid layers in a model layer - p tidal pressure perturbation; background pressurep ₀ - q heating function (energy per mass per time) - r tidal state vector in (2.1) - s tidal entropy perturbation; background entropys ₀ - t time - u tidal horizontal velocityu - w tidal vertical component of velocity - x excitation vector defined in (2.3); vertical coordinate lnp _*/p ₀ [except in (3.8), where it is lnp /p ₀] - y vertical-structure function in (7.1) - z geopotential height - A constant defined in (6.2) - C spherical-harmonic expansion coefficient in (3.6) - D vertical cross section defined in (5.6) and (5.9) - E eigenstate vector - F vertical-structure function for eigenstate pressure in (3.2) [re-defined with WKB scaling in (7.2)] - G vertical-structure function for eigenstate vertical velocity in (3.2) [re-defined with WKB scaling in (7.2)] - H pressure-scale height - I mode intensity defined in (8.1) - K quadratic form defined in (4.4) - L quadratic form defined in (4.4); horizontal-structure magnification factor defined in (5.11) - M vertical-structure magnification factor defined in (4.6) - P eigenstate pressure in (3.2); tidal pressure in (6.2) - R tidal state vector in (5.1) - S eigenstate entropy in (3.2); spherical surface area, in differential dS - T background molecular-scale (NOAA, 1976) absolute temperatureT ₀ - U eigenstate horizontal velocityU in (3.2); coefficient in (7.3) - V horizontal-structure functionV for eigenstate horizontal velocity in (3.2); recursion variable in (7.3) - W eigenstate vertical velocity in (3.2) - X excitation vector in (5.1) - Y surface spherical harmonic in (3.7) - Z Hough function defined in (3.6) - +dH/dz - (1––)/2 - Kronecker delta; Dirac delta; correction operator in (7.6) - equilibrium tide elevation - (square-root of Hough-function eigenvalue) - ratio of specific gas constant to specific heat for air=2/7 - longitude - - - background density ₀ - eigenstate frequency in (3.1) - proxy for heating functionq =c _P/t - latitude - tide frequency - operator for the limitz - horizontal-structure function for eigenstate pressure in (3.2) - Hough function defined in (6.2) - earth's rotation speed - horizontal gradient operator - ()₀ background variable - ()_* surface value of background variable - () value at base of isothermal top layer - Õ state vector with zerow-component - , energy product defined in (2.4) - | | energy norm - ()^* complex conjugate With 10 Figures     

A study of the sensitivity of bare soil evaporation schemes to soil surface wetness,using the coupled soil moisture and surface temperature prediction model,BARESOIL

Summary The performance of evaporation schemes with and approach and their combination within resistance representation of evaporation from bare soil surface is discussed. For this purpose nine schemes, based on different functions of or , on the ratio of the volumetric soil moisture content and its saturated value are used.The quality of the chosen schemes has been evaluated using the results of time integration by the coupled soil moisture and surface temperature prediction model, BARESOIL, using in situ data. A sensitivity analysis was made using two sets of data derived from the volumetric soil moisture content of the top soil layer. One with values below the wilting point (0.17 m³m^–3) and the second with values above 0.20m³m^–3. Data sets were obtained at the experimental site Rimski anevi, Yugoslavia, from the bare surface of a chernozem soil.With 4 Figures     

Effect of land management on ecosystem carbon fluxes at a subalpine grassland site in the Swiss Alps

Summary The influence of agricultural management on the CO₂ budget of a typical subalpine grassland was investigated at the Swiss CARBOMONT site at Rigi-Seebodenalp (1025m a.s.l.) in Central Switzerland. Eddy covariance flux measurements obtained during the first growing season from the mid of spring until the first snow fall (17 Mai to 25 September 2002) are reported. With respect to the 10-year average 1992–2001, we found that this growing season had started 10 days earlier than normal, but was close to average temperature with above-normal precipitation (100–255% depending on month). Using a footprint model we found that a simple approach using wind direction sectors was adequate to classify our CO₂ fluxes as being controlled by either meadow or pasture. Two significantly different light response curves could be determined: one for periods with external interventions (grass cutting, cattle grazing) and the other for periods without external interventions. Other than this, meadow and pasture were similar, with a net carbon gain of –128±17g Cm^–2 on the undisturbed meadow, and a net carbon loss of 79±17g Cm^–2 on the managed meadow, and 270±24g Cm^–2 on the pasture during 131 days of the growing season, respectively. The grass cut in June reduced the gross CO₂ uptake of the meadow by 50±2% until regrowth of the vegetation. Cattle grazing reduced gross uptake over the whole vegetation period (37±2%), but left respiration at a similar level as observed in the meadow.     

Occurrence of roll circulations in a shallow boundary layer

Meteorological measurements taken at the Näsudden wind turbine site during slightly unstable conditions have been analyzed. The height of the convective boundary layer (CBL) was rather low, varying between 60 and 300 m. Turbulence statistics near the ground followed Monin-Obukhov similarity, whereas the remaining part of the boundary layer can be regarded as a near neutral upper layer. In 55% of the runs, horizontal roll vortices were found. Those were the most unstable runs, with -z _i/L > 5. Spectra and co-spectra are used to identify the structures. Three roll indicators were identified: (i) a low frequency peak in the spectrum of the lateral component at low level; (ii) a corresponding increase in the vertical component at mid-CBL; (iii) a positive covariance {ovvw} together with positive wind shear in the lateral direction (V/z) in the CBL. By applying these indicators, it is possible to show that horizontal roll circulations are likely to be a common phenomenon over the Baltic during late summer and early winter.     

A Green Planet Versus a Desert World: Estimating the Maximum Effect of Vegetation on the Land Surface Climate

We quantify the maximum possible influence of vegetation on the global climate by conducting two extreme climate model simulations: in a first simulation (desert world), values representative of a desert are used for the land surface parameters for all non glaciated land regions. At the other extreme, a second simulation is performed (green planet) in which values are used which are most beneficial for the biosphere's productivity. Land surface evapotranspiration more than triples in the presence of the green planet, land precipitation doubles (as a second order effect) and near surface temperatures are lower by as much as 8 K in the seasonal mean resulting from the increase in latent heat flux. The differences can be understood in terms of more absorbed radiation at the surface and increased recycling of water. Most of the increase in net surface radiation originates from less thermal radiative loss and not from increases in solar radiation which would be expected from the albedo change. To illustrate the differences in climatic character and what it would imply for the vegetation type, we use the Köppen climate classification. Both cases lead to similar classifications in the extra tropics and South America indicating that the character of the climate is not substantially altered in these regions. Fundamental changes occur over Africa, South Asia and Australia, where large regions are classified as arid (grassland/desert) climate in the desert world simulation while classified as a forest climate in the green planet simulation as a result of the strong influence of maximum vegetation on the climate. This implies that these regions are especially sensitive to biosphere-atmosphere interaction.     

Properties of spatial temperature derivatives in the atmospheric surface layer

A pair of parallel cold wires separated in either the vertical or lateral direction was used to obtain the three components _x, _y, _z of the temperature derivative in the streamwise, lateral and vertical directions, respectively. The average absolute skewness values of _x and _z are nonzero and approximately equal, while the skewness of _y is approximately zero. These results appear to be consistent with the presence of a large, three-dimensional organised structure in the surface layer. There is an apparent low-frequency contamination in the spectral density of _y and _z due mainly to small errors in estimating the sensitivity of the cold wires. The temperature derivatives were high-pass filtered, the filter being set to remove possible contributions from the large structure and to minimise low-frequency sensitivity contamination. The filtered rms ratios \~_x/\~_y and \~_x/\~_z were in the range 0.7 to 0.9, a result in qualitative agreement with that obtained in the laboratory boundary layer by Sreenivasan et al. (1977). The skewness of filtered _x or _z is negligible, consistent with local isotropy of small-scale temperature fluctuations and in support of the high wavenumber spectral isotropy discussed in Antonia and Chambers (1978).     

Stable Isotope Ratios: Hurricane Olivia

The oxygen and hydrogen isotopic compositions of rains from HurricaneOlivia (1994) in the eastern Pacific were measured. The rains werecollected on 24 and 25 September during airplane flights conducted at anelevation of 3 km. Hurricane Olivia peaked in intensity to a category-4storm between the two dates. Isotope ratios of rains from HurricaneOlivia were markedly lower ( ¹⁸O = –13.9to –28.8) than that of rain collected from a thunderstormat an elevation of 2.3 km outside the influence of Olivia (¹⁸O = –3.8). A distinct decrease in isotoperatios from the first day to the next ( ¹⁸O =–18.4 to –21.9) in Hurricane Olivia wasattributed to decreased updraft velocities and outflow aloft. Thisshifted the isotopic water mass balance so that fewer hydrometeors werelifted and more ice descended to flight level. A decrease in the averagedeuterium excess from the first day to the next (d = 15.5 to 7.1)was attributed to an increase in the relative humidity of the watervapor `source' area. We hypothesize that the `source' region for therain was in the boundary layer near the storm center and that becausethe hurricane was at peak intensity prior to the second day the relative humidity was higher.     

Local similarity of spectral and cospectral characteristics in the stable-continuous boundary layer

The local similarity theory, presented in the recent papers of Sorbjan (1986a, b), is extended by taking into consideration spectral (u, v, w, ) and cospectral (uw, w, u) densities in the stable-continuous boundary layer. The resulting universal expressions for spectra, cospectra and the reduced frequencies of their peaks are in agreement with empirical data from the Kansas 1968 surface-layer and Minnesota 1973 boundary-layer experiments. In addition, the universal functions for the structure parameters and the dissipation rates are also derived and shown to fit the empirical data well.On leave from Institute of Environmental Engineering, Warsaw Polytechnic University, 00653 Warsaw, Poland.     

The validation of various schemes for parameterizing evaporation from bare soil for use in meteorological models: A numerical study using in situ data

Parameterization of evaporation from a non-plant-covered surface is very important in the hierarchy strategy of modelling land surface processes. One of the representations frequently used in its computation is the resistance formulation. The performance of the evaporation schemes using the , , and their combination resistance approaches to parameterize evaporation from bare soil surfaces is discussed. For that purpose, the nine schemes, based on a different dependence of and on volumetric soil moisture content and its saturated value, are used.The tests of performances of the considered schemes are based on time integrations by the land surface module (BARESOIL) using observed data. The 23 data sets at a bare surface experimental site in Rimski anevi, Yugoslavia on chernozem soil, were used for the resistance algorithm evaluation. The quality of the schemes was compared with the observed values of the latent heat flux using several statistical parameters.     

Recurrence statistics of concentration fluctuations in plumes within a near-neutral atmospheric surface layer

This study examines the statistical properties of the concentration derivative, , for a dispersing plume in a near-neutrally stratified atmospheric surface layer. Towards this goal, the probability density function (pdf) of , and the conditional pdf of given a fixed concentration level, , have been measured. These pdfs are found to be modeled well by a generalizedq-Gaussian (gqG) distribution with intermittency exponent,q, equal to 0.3 and 3/4, respectively. These results highlight the strong intermittency effect (patchiness) of the small-scale concentration eddy structures in the plume. The distribution of time intervals between successive high peaks in the squared derivative process, x², is found to be well approximated by a power-law distribution, implying that occurrences of these high peaks are much more clustered than would be predicted by a Poisson or shot-noise process. The results are used to improve models for the joint pdf of and , and for the expected number of upcrossings per unit time interval of a fixed concentration level that have been proposed by Kristensenet al. (1989). The predictions of the improved models are in accord with observations, and suggest that the intercorrelation between and must be explicitly incorporated if good estimates of the upcrossing intensity are to be obtained.     

Similarity of atmospheric Reynolds shear stress and heat flux fluctuations over a rough surface

Horizontal u and vertical w velocity fluctuations have been measured together with temperature fluctuations in the atmospheric surface layer, at a small height above a wheat crop canopy. Marginal probability density functions are presented for both individual fluctuations u, w, and for the instantaneous Reynolds stress uw, and heat fluxes w and u. Probability density functions of the velocity fluctuations deviate less significantly from the Gaussian form than the probability density of temperature. There appears to be closer similarity between statistics of the instantaneous heat fluxes than between the momentum flux and either of the heat fluxes investigated. The mean momentum flux receives equal contributions from the events referred to as ejections and sweeps in laboratory boundary layers. Sweeps provide the largest contribution to the heat fluxes.     

Scavenging Efficiency of ‘Aerosol Carbon’ and Sulfate in Supercooled Clouds at Mt. Sonnblick (3106 m a.s.l., Austria)

Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (_SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (_AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both _SO and _AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, _SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m³. In the case of aerosol carbon, we obtained a more gradual increase of _AC up to an LWC of 0.5 g/m³. At higher LWCs, _{_} remained relatively constant at 0.60. As the differences between _SO and _A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.     

Interactions between internal gravity waves and their traumatic effect on a continuous stratification

An investigation is made of the detailed kinematic conditions which characterize breaking of internal waves in a continuous density field. It has been observed that breaking is associated with localized, abruptly appearing intensifications of the density gradient. Turbulence subsequently develops from these intensifications or traumata.Interactions between two or more disparate waves produce distortions more extreme than would be deduced from linear combination. This is exploited experimentally by crossing two weak internal wave beams from separate sources.Lagrangian integration of the motion field defined by the beams gives extrema of isopycnic slope, Richardson number defined by shear across isopycnics and dynamic vertical density gradient, and dynamic density gradient, under conditions for the appearance of traumata.     

Reactions of alkoxy radicals under atmospheric conditions: The relative importance of decomposition versus reaction with O2

The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O₂ of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O₂ versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(H_{decomposition}–H_{O 2 reaction}), between these two reactions pathways. For (H)[22–0.5(H_{O 2 reaction})], alkoxy radical decomposition dominates over the reaction with O₂ at room temperature and atmospheric pressure of air, while for (H)[25-0.5(H_{O 2 reaction})], the O₂ reaction dominates over decomposition (where the units of H are in kcal mol^–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.     

Observed variations of σθ and σΦ in the nocturnal drainage flow in a deep valley

The variations of and in the drainage flow in the Brush Creek valley of western Colorado are investigated using data from Doppler acoustic sodars and instrumented towers. The data were obtained on two experimental nights during the 1984 ASCOT field study. There is good agreement between the variations derived from low-level observations of the sodars and those derived from the towers located throughout the valley. The observed hourly average and in the nocturnal drainage flow are about 20 ° to 25 ° and 5 °, respectively; these values are much larger than those generally observed over flat terrain during nighttime stable conditions. After sunrise (about 0600 MST), as the valley warms and the flow direction changes to up-valley, these parameters increase sharply to their peak values at about 0800 MST and then decrease to their normal daytime values after about two hours.In the drainage flow, the hourly average varies inversely with wind speed according to the relation u 0.7ms^-1. The vertical standard deviation is much less enhanced by complex terrain than the horizontal standard deviation. The observed values are predicted fairly well by the local similarity theory.Oak Ridge Associated Universities (ORAU) Summer Research Participant at ATDD in 1987 andOak Ridge Associated Universities (ORAU) Summer Research Participant at ATDD in 1987 and     

On the temperature coefficient of PCO 2 in seawater

The commonly reported temperature coefficient of P. the equilibrium partial pressure of CO₂, is (P/T) _A,C ,which is about 15 ppm/°C, or 5% of the atmospheric partial pressure of CO₂. This coefficient, however, applies only to deep water, not to surface water which can exchange CO₂ with the atmosphere. The coefficient (P/T) _A,C ,, where designates constancy of the sum of atmospheric and surface-ocean CO₂, is the appropriate value for air-sea exchange. Numerical values are mass-dependent because the depth of the exchanging ocean layer must be specified. For a 100-m surface layer, the value is ca. 1.5 ppm/°C, or 0.5% of ambient CO₂. Editor's Note:In view of the interdisciplinary importance of the carbon dioxide-climate problem, this note on seawater chemistry should be of interest to specialists beyond the discipline of ocean chemistry.