Trace metals in sediment cores from Deception and Penguin Islands (South Shetland Islands, Antarctica)

This paper presents information on the levels of trace elements in sediments collected at Deception and Penguin Islands and tracks the sources of natural and anthropogenic inputs of metals into this sub-Antarctic region. The results suggest that natural processes, such as volcanic activity, hydrothermal processes and sediment transport, are more important than anthropogenic inputs in accounting for the metal concentrations measured in sediments at Deception Island. The higher levels of trace metals recorded in sediments at Penguin Island seem to reflect the composition of the source rocks of the island, which are dominated by the olivine-basalt group. Our findings show that human activities in the study areas may contribute to negligible levels of trace metals associated with anthropogenic inputs (e.g., Cr and Zn) in sediments, and these results can be used in the future as background levels related to low anthropogenic impacts.     

The P-wave velocity structure of Deception Island,Antarctica, from two-dimensional seismic tomography

Deception Island is a volcanic island with a flooded caldera that has a complex geological setting in Bransfield Strait, Antarctica. We use P-wave arrivals recorded on land and seafloor seismometers from airgun shots within the caldera and around the island to invert for the P-wave velocity structure along two orthogonal profiles. The results show that there is a sharp increase in velocity to the north of the caldera which coincides with a regional normal fault that defines the northwestern boundary of the Bransfield Strait backarc basin. There is a low-velocity region beneath the caldera extending from the seafloor to > 4 km depth with a maximum negative anomaly of 1 km/s. Refracted arrivals are consistent with a 1.2-km-thick layer of low-velocity sediments and pyroclastites infilling the caldera. Synthetic inversions show that this layer accounts for only a small portion of the velocity anomaly, implying that there is a significant region of low velocities at greater depths. Further synthetic inversions and melt fraction calculations are consistent with, but do not require, the presence of an extensive magma chamber beneath the caldera that extends downwards from ≤ 2 km depth.     

Sources and transport of As,Cu, Cd and Pb in the environmental compartments of Deception Island,Antarctica

Sources and transport processes of As, Cu, Cd and Pb were studied in different environmental compartments of Deception Island, an active volcano in the South Shetland Islands, Antarctica. Element concentrations in fresh water samples are consistent with the lowest values reported elsewhere in Antarctica. Interestingly, higher concentration values of As were found in samples collected in or near spring water courses and its transport may be related with processes of lixiviation in underground waters. While in saline waters Cu and Pb had important punctual sources, concentration values for Cd were consistently high pointing to the existence of a natural and diffuse source possibly related with the hydrothermal activity. The high Si/Al ratio, low carbon content, and a non-significant anthropogenic heavy metal input may explain the surprisingly homogeneous heavy metal content found in sediment samples.     

Subaqueous, basaltic lava dome and carapace breccia on King George Island, South Shetland Islands, Antarctica

 On King George Island during latest Oligocene/earliest Miocene time, submarine eruptions resulted in the emplacement of a small (ca. 500 m estimated original diameter) basalt lava dome at Low Head. The dome contains a central mass of columnar rock enveloped by fractured basalt and basalt breccia. The breccia is crystalline and is a joint-block deposit (lithic orthobreccia) interpreted as an unusually thick dome carapace breccia cogenetic with the columnar rock. It was formed in situ by a combination of intense dilation, fracturing and shattering caused by natural hydrofracturing during initial dome effusion and subsequent endogenous emplacement of further basalt melt, now preserved as the columnar rock. Muddy matrix with dispersed hyaloclastite and microfossils fills fractures and diffuse patches in part of the fractured basalt and breccia lithofacies. The sparse glass-rich clasts formed by cooling-contraction granulation during interaction between chilled basalt crust and surrounding water. Together with muddy sediment, they were injected into the dome by hydrofracturing, local steam fluidisation and likely explosive bulk interaction. The basalt lava was highly crystallised and degassed prior to extrusion. Together with a low effusion temperature and rapid convective heat loss in a submarine setting, these properties significantly affected the magma rheology (increased the viscosity and shear strength) and influenced the final dome-like form of the extrusion. Conversely, high heat retention was favoured by the degassed state of the magma (minimal undercooling), a thick breccia carapace and viscous shear heating, which helped to sustain magmatic (eruption) temperatures and enhanced the mobility of the flow. Received: 1 August 1996 / Accepted: 15 September 1997     

Seismicity at White Island volcano, New Zealand: a revised classification and inferences about source mechanism

The classification of earthquakes at White Island volcano, New Zealand, has been revised to address problems in existing classification schemes, to better reflect new data and to try to focus more on source processes. Seismicity generated by the direct involvement of magmatic or hydrothermal fluids are referred to as volcanic, and that generated by fault movement in response to stresses caused by those fluids, regional stresses, thermal effects and so on are referred to as volcano-tectonic. Spasmodic bursts form a separate category, as we have insufficient information to classify them as volcanic or volcano-tectonic. Volcanic seismicity is divided into short-duration, long-period volcanic earthquakes, long-duration volcanic earthquakes, and harmonic- and non-harmonic volcanic tremor, while volcano-tectonic seismicity is divided into shallow and deep volcano-tectonic earthquakes. Harmonic volcanic tremor is related to sub-surface intrusive processes, while non-harmonic volcanic tremor originates close to active craters at shallow depth, and usually occurs during eruptive activity. Short-duration, long-period volcanic earthquakes come from a single source close to the active craters, but originate deeper than non-harmonic volcanic tremor, and are not related to eruptive activity. Long-duration volcanic earthquakes often accompany larger discrete eruptions. The waveform of these events consists of an initial low-frequency part from a deep source, and a later cigar-shaped part of mixed frequencies from a shallow crater source.     

Attenuation in the uppermost inner core from PKP recordings at African seismological stations

The attenuation factor Q_P at the top of the inner core is evaluated by using the amplitude spectral ratio of PKPdf and PKPbc phases observed at African stations (BGCA mostly), from strong deep earthquakes in the Pacific Ocean area. The maximum depth of penetration of the PKPdf phase into the inner core (IC) is roughly 377 km, and the sampled region of IC is centered beneath the Southern Indian Ocean. The derived mean value of Q_P is 249 ± 31 (95% confidence level) in the frequency range 0.2–2 Hz, where no frequency dependence of attenuation has been reliably observed. By using Student’s t-test, we show that the value is statistically significantly different (with a probability greater than 95%) from other mean values of Q derived by using the same method, for both the western (180 °W to 40 °E) and eastern (40 °E to 180 °E) hemispheres of the IC. The decrease of Q with the radius of the turning point (denoted by r^TP), according to Q_P = 840 − 0.62 r^TP, has a moderate statistical support (the R-squared value is 38%). A slightly increase of Q as a function of the angle of the PKPdf path within the inner core with respect to the Earth’s spin axis is observed, in agreement with various investigations performed in the time domain. However, the value of the anisotropy, if any, is suggested to be around 3%.     

Attenuation tomography of the Southern Apennines (Italy)

The aim of this study is to improve our knowledge of the attenuation structure in the Southern Apennines using a new amplitude ratio tomography method (Phillips et al., Geophys Res Lett 32(21):L21301, 2005) applied on both direct and coda envelope measurements derived from 150 events recorded by 47 stations of the Istituto Nazionale di Geofisica e Vulcanologia National Seismic Network (Rete Sismica Nazionale Centralizzata). The two-dimensional (2-D) analysis allows us to take into account lateral crustal variations and heterogeneities of this region. Using the same event and station distribution, we also applied a simple 1-D methodology, and the performance of the 1-D and 2-D path assumptions is tested by comparing the average interstation variance for the path-corrected amplitudes using coda and direct waves. In general, coda measurement results are more stable than using direct waves when the same methodology is applied. Using the 2-D approach, we observe more stable results for both waves. However, the improvement is quite small, probably because the crustal heterogeneity is weak. This means that, for this region, the 1-D path assumption is a good approximation of the attenuation characteristics of the region. A comparison between Q tomography images obtained using direct and coda amplitudes shows similar results, consistent with the geology of the region. In fact, we observe low Q along the Apennine chain toward the Tyrrhenian Sea and higher values to the east, in correspondence with the Gargano zone that is related to the Apulia Carbonate Platform. Finally, we compared our results with the coda Q values proposed by Bianco et al. (Geophys J Int 150:10–22, 2002) for the same region. The good agreement validates our results as the authors used a completely independent methodology.     

Attenuation of P and pP waves in Vrancea area – Romania

The seismic attenuation in the Vrancea region (Romania) is investigated from teleseismic recordings of P and pP waves during the four major, intermediate-depth Romanian events that occurred since the onset of digital instrumentation. Most stations are located in Canada and in the United States, being equipped with a variety of sensors, especially short-period ones. The amplitude spectral ratio method is used, assuming no frequency dependence of the Q _P factor in the range 0.2–2 Hz. No apparent correlation between the derived attenuation value and the type of recording sensor is observed. Lateral variations of the attenuation are obtained, with a very low Q _P area (values down to 33) located in the northwestern part of the Vrancea seismogenic volume. For the stations with different azimuth angles in relation to the epicentral area, Q _P values routinely exceed 200. Most likely, the low attenuation values are related to an upwelling mantle material located immediately beneath the crust, but limited in depth to at least 100 km.     

Mt. Melbourne volcano,antarctica: Evidence of seismicity related to volcanic activity

Characterization of the microseismic activity (M _L <2.0) has been performed at Mt. Melbourne since 1990. We recorded a group of low frequency events with common morphological characteristics, i.e., an emerging onset, an unclear second phase and a sharply dropping coda. Spectral analysis of events recorded at more than one station indicates that the seismogram characteristics and spectral content are largely due to source effects. A polarization filter applied to a set of three component data revealed a first phase made up ofP waves followed (after about 0.9–1.4 sec.) by a second phase probably composed ofSH-type waves. Particle motion analysis detected a seismic ray angle direction mainly between N70°E and N110°E and apparent angle of incidence between 35° and 48° for the first phase. The studied seismicity was localized in an area on the eastern slope of Mt. Melbourne Volcano which presents a surface temperature anomaly (Mazzarini andSalvini, 1994). We formulate two hypotheses for the type of earthquakes recorded: 1) long-period events involving active presence of magmatic fluids in the source processes; 2) or the result of fracturing processes (shear?) in a medium characterized by transition between brittle and plastic behaviors. In the latter hypothesis the superficial thermal anomaly may be a symptom of this behavior at depth and is confirmed by the lown values observed for the exponential fit in the codaQ analysis.     

Three-dimensional Q structure in Jiashi earthquake region of Xinjiang

3-D S-waveQ structure in Jiashi earthquake region is inverted based on the attenuation of seismic waves recorded from earthquakes in this region in 1998 by the Research Center of Exploration Geophysics (RCEG), CSB, and a rough configuration of deep crustal faults in the earthquake region is presented. First, amplitude spectra of S-waves are extracted from 450 carefully-chosen earthquake records, called observed amplitude spectra. Then, after instrumental and site effect correction, theoretical amplitude spectra are made to fit observed amplitude spectra with nonlinear damped least-squares method to get the observed travel time overQ, provided that earthquake sources conform to Brune’s disk dislocation model. Finally, by 3-D ray tracing method, theoretical travel time overQ is made to fit observed travel time overQ with nonlinear damped least-squares method. In the course of fitting, the velocity model, which is obtained by 3-D travel time tomography, remains unchanged, while onlyQ model is modified. When fitting came to the given accuracy, the ultimateQ model is obtained. The result shows that an NE-trending lowQ zone exists at the depths of 10–18 km, and an NW-trending lowQ zone exists at the depths of 12–18 km. These roughly coincide with the NE-trending and the NW-trending low velocity zones revealed by other scientists. The difference is that the lowQ zones have a wider range than the low velocity zones. Foundation item: Joint Seismological Science Foundation of China (957-07-414) and State Key Basic Research Development and Programming Project (95-13-02-02). Contribution No. RCEG200105, Research Center of Exploration Geophysics, China Seismological Bureau.     

Estimation of Coda Wave Attenuation for the National Capital Region, Delhi, India Using Local Earthquakes

Attenuation of seismic waves is very essential for the study of earthquake source parameters and also for ground-motion simulations, and this is important for the seismic hazard estimation of a region. The digital data acquired by 16 short-period seismic stations of the Delhi Telemetric Network for 55 earthquakes of magnitude 1.5 to 4.2, which occurred within an epicentral distance of 100 km in an area around Delhi, have been used to estimate the coda attenuation Q_c. Using the Single Backscattering Model, the seismograms have been analyzed at 10 central frequencies. The frequency dependence average attenuation relationship Q_c = 142f ^1.04 has been attained. Four Lapse-Time windows from 20 to 50 seconds duration with a difference of 10 seconds have been analyzed to study the lapse time dependence of Q_c. The Q_c values show that frequency dependence (exponent n) remains similar at all the lapse time window lengths. While the change in Q₀ values is significant, change in Q₀ with larger lapsetime reflects the rate of homogeneity at the depth. The variation of Q_c indicates a definitive trend from west to east in accordance with the geology of the region.     

云南地区S波非弹性衰减与M_L震级测定研究

选取云南地震台网记录的地震波形资料,通过基于遗传算法的Atkinson方法分别计算云南3个区域的介质品质因子Q_0值。根据云南地区地震波衰减的区域性差异,通过震级偏差统计分析了47个台站的单台M_L震级偏差情况。结果显示:云南属于低Q_0值地区,区域性差异明显。位于云南西部区域1的Q_0值相对较高,为251. 3;东部的区域3的Q_0值次之,为216. 9;中部的区域2的Q_0值最低,为102. 6。Q_0值越小的地区,S波衰减程度越大,单台震级偏小于台网平均震级的台站也就越多。同一地区的台站在测定相同区域内的地震时,虽然地震波非弹性衰减程度相近,但由于受到各台站场地不同增益作用的影响,其单台震级偏差情况有所不同。     

Rescaled range ( R/S ) analysis on seismic activity parameters

The rescaled range (R/S) analysis, proposed by Hurst, is a new statistical method. Being different from traditional statistical method, R/S analysis can provide the information of maximum fluctuation (range) of statistical parameters. At present paper, several modern instrumental earthquake catalogues in different spatial scale, temporal scale, and with different seismic activity background are studied, and R/S method is used to analyze the variation of range of seismic parameters such as earthquake frequency, and earthquake time interval. For different seismic parameters, the ratio of range to standard deviation — R/S is a power law function of the length of time, and the exponent H of power law is always greater than 0.5. As we know, H=0.5 is the characteristics of all ideal random processes. Our results indicate that earthquake series is not an ideal Poisson process, on the contrary, the earthquake as a phenomenon bears dual characteristics of randomicity and regularity, and the greater H departs from 0.5, the more regularity the time series will show, and vice versa. With time scale changing, one can give the conservative estimate of the fluctuation, which might occur in a relatively long time scale, only by using the limited and known time records. Foundation item: State Natural Science Foundation of China (40074023).     

Long-Term Evolution of the Seismic Activity Preceding the 2015 Seismic Crisis at Deception Island Volcano,Antarctica (2008-2015)

Surveys in Geophysics - Deception Island is an active volcano located in the South Shetland Islands, Antarctica. Although the last eruptions occurred in 1967-1970, the volcano has undergone periods...     

Modern microbialites and their environmental significance, Meiji reef atoll, Nansha (Spratly) Islands, South China Sea

Meiji (Mischief) coral atoll, in Nansha (Spratly) Islands, South China Sea, consists of an annular reef rim surrounding a central lagoon. On the atoll rim there are either protuberant 'motu' (small coral patch reefs on the rim of atoll) islets or lower sandy cays that contain modern microbialite deposits on the corals in pinnacles and surrounding bottoms of the atoll. Microbialites, including villiform, hairy, and thin spine growth forms, as well as gelatinous masses, mats and encrustation, developed on coral colonies and atoll rim sediments between 0 and 15 m deep-water settings. The microbialites were produced by natural populations of filamentous cyanobacteria and grew on (1) bulbous corals together with Acropora sp., (2) on massive colonies of Galaxea fascicularis, (3) on dead Montipora digitata, and (4) on dead Acropora teres, some hairy microbialite growing around broken coral branches. This study demonstrates that microbial carbonates are developed in coral reefs of South China Sea and indicates that microbial processes may be important in the construction of modern reef systems. The results have significance in the determination of nature and composition in microorganisms implied in the formation ancient microbialites, and permit evaluation of the importance of microbial deposits in mo-dern coral reefs and of 'microbialites' in biogeochemical cycles of modern coral reef systems. The re-sults also provide evidence of modern analogues for ancient microbialites in shallow-water settings, and combine with sedimentological studies of ancient microbialites to understand their controls.     

Chemical and isotopic variations in fumarolic discharge and thermal waters at Vulcano Island (Aeolian Islands, Italy) during 1996: evidence of resumed volcanic activity

Gas samples from some fumaroles at ‘La Fossa' crater and Baia di Levante on Vulcano Island and from a diffuse soil gas emission were analysed during 1995–1996, along with water samples from thermal wells in the area of Vulcano Porto. During 1996, we observed a significant increase both in the gas/steam ratio and in the CO₂ concentration, as well as strong variations in δ¹³C_CO2, δD_H2O and δ¹⁸O_H2O of fumarolic gases. These variations are probably related to an increased inflow of deep fluids of magmatic origin. The temperatures of fumaroles did not show remarkable variations except for fumarole F11. In this case, temperature increased by about 80°C from February to August 1996. During the same period, remarkable variations in temperature, phreatic level and chemical and isotopic composition of water were also recorded in one of the geothermal wells in the Vulcano Porto area (Camping Sicilia; T60°C). The observed variations in this well are probably related to a pressure build-up, occurring at least in the surficial part of the system, because of increased gas flux and/or decreased permeability of the fumarolic degassing system. Chemical and isotopic composition of the water showed that during this evolutionary phase, the content of fumarolic condensate in this well was about 80 to 90%. Based on the observation of physical and chemical variables of the Camping Sicilia fluids, during this phase of activity, it is concluded that this area is affected by a phreatic eruption hazard if a volcanic episode with high energy discharge in a limited time span occurs. It follows that this well may be considered as a preferential point for volcanic activity monitoring, both in the case of normal routine surveillance and in the case of inaccessibility to the crater area.     

Volcanic emissions of metals and halogens from White Island (New Zealand) and Erebus volcano (Antarctica) determined with chemical traps

Volcanic emission rates of As, Sb, Pb, Hg, Se, Cl, and F were determined at Erebus volcano, Antarctica and White Island, New Zealand, using chemical traps. The trace metal fluxes were determined by combining the species to S ratios in the solutions with SO₂ emission rates measured by correlation spectrometry at the two volcanoes. At Erebus volcano, fluxes for the metals Pb and Hg were 2.0 × 10^− 4 and 8.1 × 10^− 6 kg s^− 11, respectively. Fluxes for Cl, F, As, Sb and Se (0.35, 0.15, 2.5 × 10^− 4, 1.2 × 10^− 5, and 4.5 × 10^− 6 kg s^− 1, respectively) agreed within error limits for values determined previously by the LiOH impregnated filter method [Zreda-Gostynska, G., Kyle, P., Finnegan, D., Prestbo, K., 1997. Volcanic gas emissions from Mount Erebus and their impact on the Antarctic environment. Journal of Geophysical Research, 102(B7): 15039–15055.], demonstrating the utility of the chemical trap method. A fall in the As/S ratio from 7 × 10^− 4 in 1997/1999 to 3 × 10^− 4 in 2000 at Erebus coincided with a change in the frequency and style of eruptive activity that may have been due to injection of magma into the system. At White Island, chemical trap data indicated fluxes of Cl = 0.90, F = 0.0079, Pb = 2.7 × 10^− 4, Hg = 1.1 × 10^− 5, As = 1.3 × 10^− 4, Sb = 1.9 × 10^− 5 and Se = 1.5 × 10^− 5 kg s^− 1. Samples collected 600 m downwind of the active crater were comparable to samples collected adjacent to the main gas vent, showing that this method can still be used at some distance from a degassing vent.     

Site attenuation and source parameters on the North Anatolian Fault zone, eastern Turkey estimated from the aftershocks of 13 March 1992 Erzincan earthquake

Site attenuation and source characteristics of 45 aftershocks of the 13 March 1992 Erzincan, eastern Turkey earthquake have been determined from SH-wave spectra using a least-squares best-fit method. Although the most of the seismograms were recorded on the ophiolitic rock sites and the average regional attenuation correction of Q(f) = 35 f^0.83 was applied, the high fall-off rates ranging between 3.0 and 4.5 beyond the corner frequencies of 8–13 Hz were observed on the SH spectra. The site attenuation value, , has been calculated from the slope of the high frequency part of the SH spectra. It was found that varied in the range of 0.0124–0.0364 s and the average was 0.0246 s with a standard deviation of 0.0047 s. The high fall-off rates of observed spectra have decreased considerably as a result of site attenuation corrections and converged to an average value of 2.3. We concluded that the high fall-off rates of SH wave spectra are mainly controlled by highly deformed Miocene ophiolitic formations which covers a wide area in the North Anatolian Fault zone in the vicinity of Erzincan region. Using the spectra that were corrected for regional and site attenuation, and assuming a Brune's source model; seismic moment, source radius, and stress-drops of the aftershocks were computed. We found that stress-drops for some of the aftershocks in Erzincan area have slightly decreased after removal of site attenuation over SH wave observed spectra.     

Attenuation characteristics of peak ground acceleration from fault trace of the 1999 Kocaeli (Turkey) earthquake and comparison of spectral acceleration with seismic design code

The 17 August 1999 Kocaeli earthquake in Turkey produced a majorsurface rupture. We traced this surface rupture from Gölcük toDüzce and located it accurately by using GPS. The closest distancefrom the surface rupture to the strong motion observation sites weredetermined. Then the attenuation characteristics of the observed peakground acceleration were compared with the attenuation relation given byFukushima and Tanaka (1992), which is suitable for the near-fault zone inJapan and gives results that closely match data recorded during the 1995Hyogo-ken Nanbu earthquake in Japan. Although this attenuation relationwas developed for Japan, we found that it agreed well with the KOCAELIearthquake. Furthermore, the observed spectral acceleration of 5%damping was compared with the building design code of Turkey and theobserved level was lower than the code.