Climatic change recorded by stable isotopes and trace elements in a British Holocene tufa

Combined stable isotope (δ¹⁸O and δ¹³C) and trace element (Mg, Sr) geochemistry from bulk tufa calcite and ostracod shell calcite from an early Holocene British tufa reveal clear records of Holocene palaeoclimatic change. Variation in δ¹⁸O is caused principally by change in the isotopic composition of Holocene rainfall (recharge), itself caused mainly by change in air temperature. The δ¹³C variability through much of the deposit reflects increasing influence of soil‐zone CO₂, owing to progressive woodland soil development. Bulk tufa Mg/Ca and Sr/Ca are controlled by their concentrations in the spring water. Importantly, Mg/Ca ratios are not related to δ¹⁸O values and thus show no temperature dependence. First‐order sympathetic relationships between δ¹³C values and Mg/Ca and Sr/Ca are controlled by aquifer processes (residence times, CO₂ degassing and calcite dissolution/reprecipitation) and probably record intensity of palaeorainfall (recharge) effects. Stable isotope records from ostracod shells show evidence of vital effects relative to bulk tufa data. The ostracod isotopic records are markedly ‘spiky’ because the ostracods record ‘snapshots’ of relatively short duration (years), whereas the bulk tufa samples record averages of longer time periods, probably decades. The δ¹⁸O record appears to show early Holocene warming, a thermal maximum at ca. 8900 cal. yr BP and the global 8200 yr BP cold event. Combined δ¹³C, Mg/Ca and Sr/Ca data suggest that early Holocene warming was accompanied by decreasing rainfall intensity. The Mg/Ca data suggest that the 8200 yr BP cold event was also dry. Warmer and wetter conditions were re‐established after the 8200 yr BP cold event until the top of the preserved tufa sequence at ca. 7100 cal. yr BP. Copyright © 2004 John Wiley & Sons, Ltd.     

Palaeoenvironmental records in Holocene Spanish tufas: a stable isotope approach in search of reliable climatic archives

Tufa deposits are potential terrestrial archives of palaeoenvironmental and palaeoclimatic information. This study assesses the potential of stable isotopic archives from two closely juxtaposed Holocene tufa sites in SE Spain. The Ruidera site contains deep‐water lacustrine micrites and tufas, whereas the nearby Alcaraz site represents a shallow barrage tufa. Understanding site characteristics is critical to interpreting the stable isotopic variations. These Holocene lacustrine micrites have isotopic compositions consistent with modern European lake shore microbial carbonates, where the isotopic chemistry is strongly influenced by hydrological and residence time effects. All the lacustrine micrite δ¹³C values were influenced by microenvironmental microbial effects to some degree. Because of these effects, stable isotope data from lacustrine microbial micrites and tufas will not normally yield precise information on the isotopic composition of palaeoprecipitation, temperature or vegetation composition of an area. In contrast, Holocene tufas that formed in shallow, fast‐flowing riverine settings may contain valuable palaeoclimatic archives. The tufa deposits must be largely autochthonous, as at Alcaraz, where in situ reed stem encrustations are present. Records of relative change in air temperature and changes in the source of airmasses are potentially resolvable in the δ¹⁸O data. These interpretations can be verified by other independent climatic data where chronology is constrained. Variations in riverine tufa δ¹³C values probably record changes in local vegetation and/or soil respiration. Covariation between δ¹⁸O and δ¹³C values may be intrinsically linked to climatic factors such as aridity. Tentative palaeoclimatic interpretations for the middle Holocene at Alcaraz based on the isotope data suggest warming (or increasing influence of Mediterranean‐sourced precipitation) between approximately 5000–3000 radiocarbon years BP, accompanied by increased aridity. These interpretations are consistent with the sparse independent palaeoclimatic data and climate modelling results for the Holocene of SE Spain. This study supports the growing evidence that well‐chosen tufa sites could yield valuable palaeoclimatic information.     

Environments of the climatic optimum of MIS 11 in Britain: evidence from the tufa sequence at Hitchin,southeast England

Marine Oxygen Isotope Stage 11 (MIS 11, Hoxnian Interglacial) is an important interval for understanding both climate change in an interglacial partially analogous to the Holocene and the response of geomorphic processes, biotic systems, and hominin populations to these changes. In Britain, many sites correlated to MIS 11 have not been studied since the mid-20th century and require reinvestigation, including the Hitchin tufa sequence, where a rich, non-marine molluscan assemblage was originally recovered. Re-excavation of the Hitchin tufa sequence for this study was focussed on combined sedimentological, micromorphological and geochemical analyses of the deposits. These indicate that tufa formation occurred within a perched springline system under temperate climatic conditions. Shifts between paludal and fluvial tufa facies within this system occur concomitantly with changes in carbonate geochemistry, representing increased humidity caused by a change in rainfall amount or seasonality. This research enables a correlation of the sequence to the climatic optimum of MIS 11c, the main warm phase of MIS 11, and permits further insights into temperature and hydrological changes in this interval by generating the first geochemical records of hydroclimatic evolution during the MIS 11 thermal maximum in Britain.     

Laminated tufa sediments formed from overflow karst springs: Controls on their deposition and carbon–oxygen isotope records

Tufa sediments are freshwater carbonates that precipitate in karst regions after degassing of carbon dioxide from groundwater in contact with the atmosphere. When laminated, these carbonates can provide high‐resolution records for the study of climate, hydrological and environmental conditions at the time of their precipitation. The formation of these carbonates directly depends on the hydrological regime, and in karst regions discontinuous discharges are often recorded. This study investigates the record of recent laminated tufa sediments precipitated downstream overflow springs in Trabaque Canyon (central Spain). The hydrological dynamics of the karst system were monitored for over three years and a stable isotope record was obtained from laminated tufa carbonates precipitated from an overflow spring. Additionally, a hydrological model of overflow springs was generated and a tufa δ¹⁸O record under constrained parameters was simulated. Temperature is the dominant control of the variation in tufa δ¹³C and δ¹⁸O values within each lamina, although when comparing different laminae, δ¹³C_DIC and δ¹⁸O of river water are also major controls. The positive correlation between tufa δ¹³C values and water temperature is caused by the fractionation occurred by carbon dioxide degassing due to the thermal dependence of carbon dioxide solubility. Additionally, the system recorded a temperature‐independent degassing process caused by the large gradient between groundwater and atmospheric carbon dioxide that is limited to the proximity of the spring. This study cautions on the risk of assuming continuous deposition when studying laminated tufa sediments and highlights the potential of their stable isotope records to provide hydrological information of their aquifers during the past.     

Pleistocene fluvial terraces from northern France (Seine,Yonne, Somme): synthesis,and new results from interglacial deposits

The Seine, Yonne and Somme are the main rivers draining northwestern France and flowing into the Channel. During Pleistocene cold stages they were tributaries of the “Fleuve Manche”. They are characterised by well-developed stepped terrace systems showing up to 10 incision steps for the last 1 Ma. After 15 years of research and the synthesis of stratigraphical, sedimentological, bioclimatical data and numerical dating, these terrace systems are interpreted as the response of the fluvial environments to climatic cyclicity, superimposed on a background of slow tectonic uplift. The comparison of these three terrace systems shows that the incision budget is similar within the studied area (about 55–65 m/1 Ma), implying relative homogeneity of uplift. In the main part of the area, beyond marine influence, the analysis of each stepped alluvial formation shows regular sediment balance generally composed of coarse periglacial gravels (pleniglacial), covered by fine-grained sediments locally overlain by calcareous tufa (interglacial). However, in the Lower Seine valley, close to the present coast, the low terrace includes two estuarine interglacial units interbedded within periglacial gravel units. Nevertheless, until recently evidence of full interglacial conditions remained elusive in fluvial contexts, especially in the Somme. To address these issues a new research programme has been launched on tufa deposits that are the best candidate to register the climatic optimum. Initial results from la Celle (Seine), Saint-Acheul and Caours (Somme) allow palaeoenvironmental reconstructions of MIS 11 and 5e, and thus confirm the importance of calcareous tufa to define a reference record of Pleistocene Interglacials for northern France. Moreover, it has been previously demonstrated that the main incision leading to terrace formation can be attributed to the transition between interglacial and glacial (during early glacial phases). The new results from interglacial records have important implications concerning the precise occurrence of the major incision phases within the climatic cycle as they provide the starting point immediately preceding downcutting.     

Climatic significance of seasonal trace element and stable isotope variations in a modern freshwater tufa

We present a continuous ∼14-yr-long (1985 to 1999) high-resolution record of trace element (Mg, Sr, Ba, U) and stable isotope (δ¹³C, δ¹⁸O) variations in a modern freshwater tufa from northwestern Queensland, Australia. By utilizing the temperature dependence of the δ¹⁸O signal, an accurate chronology was developed for the sampled profile, which allowed a comparison of the chemical records with hydrological and meteorological observations. As a consequence, it was possible to constrain the relevant geochemical processes relating climate variables, such as temperature and precipitation, to their chemical proxies in the tufa record. Temperatures calculated from the Mg concentrations of the tufa samples provide close approximations of average annual water temperature variations. Furthermore, we demonstrate that temporal changes in (Mg/Ca)_water can be estimated using an empirically derived equation relating (Mg/Ca)_water to the (Sr/Ba) ratio measured in the tufa samples. By means of this relationship, it is theoretically possible to determine the (Mg/Ca) ratio of paleowaters, and hence to derive reliable estimates of former water temperatures from the Mg concentrations of fossil tufas from the study area. Sympathetic variations in Sr, Ba, and δ¹³C along the sampled profile record changes in water chemistry, which are most probably caused by variable amounts of calcite precipitation within the vadose zone of the karst aquifer. This process is thought to be markedly subdued whenever the amount of wet-season precipitation exceeds a given threshold. Accordingly, distinct minima in Sr, Ba, and δ¹³C are interpreted to reflect years with above-average rainfall. The pronounced seasonal and annual variability of the U concentration along the profile is thought to primarily record changes in the U flux from the soil to the water table. We suggest that during intensive rain events U is transported to the phreatic zone by complexing organic colloids, giving rise to conspicuous U maxima in the tufa after above-average wet seasons. This study demonstrates the potential of freshwater tufas to provide valuable information on seasonal temperature and rainfall variations. If tufa deposits turn out to be reasonably resistant to secondary processes, combined investigation of speleothems and tufas from the same area could become a promising approach in future research. While speleothems offer continuous records of long-term paleoenvironmental changes, tufas could provide high-resolution time windows into selected periods of the past.     

The last 750 ka in loess–palaeosol sequences from northern France: environmental background and dating of the western European Palaeolithic

This study presents an overview of Middle Pleistocene loess–palaeosol sequences (LPS) in northern France and discusses the palaeoclimatic significance of the pedosedimentary record in the context of western European LPS and of global climatic cycles for the last 750 ka. In this area, the oldest loess deposits (early Middle Pleistocene) are preserved in sedimentary traps (leeward scarps of fluvial terraces and dissolution sinkholes). They result from local deflation processes reworking Pleistocene sandy fluvial deposits or relicts of Tertiary sands. A large extension of typical calcareous loess over the landscape, the Loess Revolution, is then observed during MIS 6, with heavy mineral assemblages testifying to long-distance transport from the polar desert area of the dried eastern Channel. A correlation scheme is proposed between the global records of northern France in continental environments and both global palaeoclimatic records and other main western European LPS. After 30 years of research, northern France LPS stand as a fundamental archive of the impact of interglacial–glacial climatic cycles as well as millennial events. Finally, these works provide a robust chronoclimatic framework for the study of the western European Late Acheulean and Middle Palaeolithic and for the relative dating of the various fluvial terraces that they fossilise.     

Contrasting geochemical signatures on land from the Middle and Late Permian extinction events

The end of the Palaeozoic is marked by two mass‐extinction events during the Middle Permian (Capitanian) and the Late Permian (Changhsingian). Given similarities between the two events in geochemical signatures, such as large magnitude negative δ¹³C anomalies, sedimentological signatures such as claystone breccias, and the approximate contemporaneous emplacement of large igneous provinces, many authors have sought a common causal mechanism. Here, a new high‐resolution continental record of the Capitanian event from Portal Mountain, Antarctica, is compared with previously published Changhsingian records of geochemical signatures of weathering intensity and palaeoclimatic change. Geochemical means of discriminating sedimentary provenance (Ti/Al, U/Th and La/Ce ratios) all indicate a common provenance for the Portal Mountain sediments and associated palaeosols, so changes spanning the Capitanian extinction represent changes in weathering intensity rather than sediment source. Proxies for weathering intensity chemical index of alteration, ?W and rare earth element accumulation all decline across the Capitanian extinction event at Portal Mountain, which is in contrast to the increased weathering recorded globally at the Late Permian extinction. Furthermore, palaeoclimatic proxies are consistent with unchanging or cooler climatic conditions throughout the Capitanian event, which contrasts with Changhsingian records that all indicate a significant syn‐extinction and post‐extinction series of greenhouse warming events. Although both the Capitanian and Changhsingian event records indicate significant redox shifts, palaeosol geochemistry of the Changhsingian event indicates more reducing conditions, whereas the new Capitanian record of reduced trace metal abundances (Cr, Cu, Ni and Ce) indicates more oxidizing conditions. Taken together, the differences in weathering intensity, redox and the lack of evidence for significant climatic change in the new record suggest that the Capitanian mass extinction was not triggered by dyke injection of coal‐beds, as in the Changhsingian extinction, and may instead have been triggered directly by the Emeishan large igneous province or by the interaction of Emeishan basalts with platform carbonates.     

Stable isotopic and elemental characteristics of recent tufa from a karstic Krka River (south‐east Slovenia): useful environmental proxies?

Tufa samples from 16 consecutive barrages along a 13 km section of the groundwater‐fed Krka River (Slovenia) were analysed for their petrographical, mineralogical, elemental and stable carbon (δ¹³C) and oxygen (δ¹⁸O) isotope composition, to establish their relation to current climatic and hydrological conditions. Waters constantly oversaturated with calcite and the steep morphology of the Krka riverbed stimulate rapid CO₂ degassing and subsequent tufa precipitation. The carbon isotope fractionation (Δ¹³C) between dissolved inorganic carbon and tufa in the Krka River evolves towards isotopic equilibrium being controlled by continuous CO₂ degassing and tufa precipitation rate downstream. The Δ¹³C increased from 1·9 to 2·5‰ (VPDB); however, since tufa precipitation rates remain similar downstream, the major controlling factor of carbon isotope exchange is most probably related to the continuous ¹²CO₂ degassing downstream leaving the carbon pool enriched in ¹³C. In the case of oxygen, the isotope fractionation (Δ¹⁸O) was found to be from 1·0 to 2·3‰ (VSMOW) smaller than reported in the literature. The observed discrepancies are due to different precipitation rates of calcite deposits because Krka tufas on cascades grow relatively faster compared to slowly precipitated calcite deposits in cave or stream pools. Due to non‐equilibrium oxygen isotope exchange between Krka tufa and water, the δ¹⁸O proxy showed from 1·2 to 8·2°C higher calculated water temperatures compared to measured water temperatures, demonstrating that δ¹⁸O proxy‐based temperature equations are not reliable for water temperature calculations of fast‐growing tufa on cascades. Because Mg is bound to the terrigenous dolomite fraction in the Krka tufa samples, the Mg/Ca was also found to be an unreliable temperature proxy yielding over up to 20°C higher calculated water temperatures.     

Climatic sub-cycles recorded by the fourth paleosol layer at Luochuan on the Loess Plateau

The Chinese loess–paleosol succession, deep-sea sedimentary sequences and ice cores are the three types of paleoclimatic records. Measurements were made of the ancient climatic proxies of magnetic susceptibility, median diameter of grain size and content >40 μm, and the CaCO₃ content of samples collected at 1 cm depth intervals in the fourth paleosol layer of the Luochuan loess-paleosol section on the Chinese Loess Plateau. Wavelet analysis of the data identified cycles of climate change, which were compared to the marine δ¹⁸O record of SPECMAP. The results showed that: (1) when the fourth paleosol layer was forming, the paleoclimate was relatively stable but five extreme climatic events were identifiable as occurring around 408, 381, 376, 368 and 361 kaBP; (2) two of these regional events differed from the global trend; (3) during marine isotope stage (MIS)11, the fourth paleosol layer of the Luochuan loess section recorded a regional quasi-19 ka climatic sub-cycle and (4) this sub-cycle was also reflected globally in the SPECMAP data indicating that, during MIS11, this sub-cycle was regionally and globally synchronized.     

Land–sea correlation of Middle Pleistocene temperate sub-stages using high-precision uranium-series dating of tufa deposits from southern England

High-precision U-series dating allows a direct correlation to be made between terrestrial records of the penultimate interglacial (Marine Oxygen Isotope Stage 7 (MIS 7)) in Britain and sub-stage climate forcing in the marine oxygen isotope sequence. U-series ages of surficial tufa deposits are of sufficient precision to correlate discrete episodes of temperate conditions with individual warm sub-stages within MIS 7. Furthermore, detailed biostratigraphy allows periods of faunal turnover to be correlated with cold climates and lowered sea level. Ecological and environmental conditions in Britain during MIS 7 are therefore driven by the short-lived, sub-stage climate forcing that is observable in the marine isotope record. It is clear that interglacial climates are highly dynamic, producing multiple climatic optima and a diverse range of environments within single warm episodes. Consequently sub-stage records of climate forcing are crucial frameworks for reconstructing terrestrial records of environmental change.     

The δ18O stratigraphy of the Hoxnian lacustrine sequence at Marks Tey,Essex, UK: implications for the climatic structure of MIS 11 in Britain

Marine Isotope Stage 11 (MIS 11) is considered one of the best analogues for the Holocene. In the UK the long lacustrine sequence at Marks Tey, Essex, spans the entirety of the Hoxnian interglacial, the British correlative of MIS 11c. We present multiproxy evidence from a new 18.5‐m core from this sequence. Lithostratigraphy, pollen stratigraphy and biomarker evidence indicate that these sediments span the pre‐, early and late temperate intervals of this interglacial as well as cold climate sediments that post‐date the Hoxnian. The δ¹⁸O signal of endogenic carbonate from this sequence produces several clear patterns that are interpreted as reflecting the climatic structure of the interglacial. As well as providing evidence for long‐term climate stability during the interglacial and a major post‐Hoxnian stadial/interstadial oscillation the δ¹⁸O signal provides strong evidence for abrupt cooling events during the interglacial itself. One of these isotopic events occurs in association with a short‐lived increase in non‐arboreal pollen (the NAP phase). The results presented here are discussed in the context of other MIS 11 records from Europe and the North Atlantic, particularly with respect to our understanding of the occurrence of abrupt climatic events in pre‐Holocene interglacials. Copyright © 2016 The Authors. Journal of Quaternary Science Published by John Wiley & Sons Ltd.     

Stratigraphy of Pleistocene glaciations in the St Elias Mountains,southwest Yukon,Canada

At least five Middle to Late Pleistocene advances of the northern Cordilleran Ice Sheet are preserved at Silver Creek, on the northeastern edge of the St Elias Mountains in southwest Yukon, Canada. Silver Creek is located 100 km up‐ice of the Marine Isotope Stage (MIS) 2 McConnell glacial limit of the St Elias lobe. This site contains ~3 km of nearly continuous lateral exposure of glacial and non‐glacial sediments, including multiple tills separated by thick gravel, loess and tilted lake beds. Infrared‐stimulated luminescence (IRSL) and AMS radiocarbon dating constrain the glacial deposits to MIS 2, 4, either MIS 6 or mid‐MIS 7, and two older Middle Pleistocene advances. This chronology and the tilt of the lake beds suggest Pleistocene uplift rates of up to 1.9 mm a^?1 along the Denali Fault since MIS 7. The non‐glacial sediment consists of sand, gravel, loess and organic beds from MIS 7, MIS 3 and the early Holocene. The MIS 3 deposits date to between 30–36 ¹⁴C ka BP, making Silver Creek one of the few well‐constrained MIS 3‐aged sites in Yukon. This confirms that ice receded close to modern limits in MIS 3. Pollen and macrofossil analyses show that a meadow‐tundra to steppe‐tundra mosaic with abundant herbs and forbs and few shrubs or trees, dominated the environment at this time. The stratigraphy at Silver Creek provides a palaeoclimatic record since at least MIS 8 and comprises the oldest direct record of Pleistocene glaciation in southwest Yukon.     

山西娘子关泉钙华记录的MIS12/11以来的气候和植被历史

对山西娘子关绵河不同阶地上沉积的泉钙华进行了高精度的230Th定年和碳氧稳定同位素组成测定。结果发现,绵河II级阶地沉积的娘子关泉钙华的最老年龄在407～466ka,远老于早前通过钙华中的石英砂热发光法(TL)获得的年龄,即绵河II级阶地上的娘子关泉钙华是在中更新世MIS12/11阶段形成的,而非原来认为的是晚更新世的产物。由此推测,绵河III级阶地娘子关泉钙华形成的年代更早,可能是中更新世的MIS14/13阶段。230Th测年获得的绵河I级阶地顶部的钙华形成于5ka前,即是在全新世中期以前形成的。结合钙华规模及其碳氧稳定同位素组成分析进一步发现,上述绵河三级阶地上的娘子关泉钙华均主要是湿热气候下的产物。然而,自II级阶地钙华形成至今,气候总体上在向干冷方向发展,泉域植被则呈现退化的趋势。     

Central England temperature since AD 1850: the potential of stable carbon isotopes in British oak trees to reconstruct past summer temperatures

In regions with seasonal temperate climatic regimes, tree growth is rarely controlled by any single environmental factor. As a consequence, the development of robust palaeoclimate reconstructions has proved challenging. Tree‐ring stable carbon isotope ratios (δ¹³C), however, are controlled primarily by photosynthetic rate, not by net growth. Therefore, at sites where climatic controls on tree‐ring growth are not strongly expressed, a robust (isotopic) palaeoclimate signal may still potentially be preserved. This hypothesis was tested using a 160‐year record of δ¹³C measured from the pooled latewood cellulose of six Quercus petraea L. (sessile oak) trees from Allt Lan‐las in West Wales, UK. Raw δ¹³C values were corrected for changes in the isotopic ratio of atmospheric carbon dioxide and for changes in the behaviour of trees due to the increasing availability of atmospheric CO₂ since AD 1850. Strong correlations with local summer temperature and sunshine are reported, and also with the Central England Temperature record over the full length of the isotopic chronology (AD 1850–2010) (r = 0.69, P < 0.001). We conclude that tree‐ring stable isotopes can be used to extract strong palaeoclimate signals even from oak trees growing in a temperate maritime climate. This demonstrates the potential for extracting robust palaeoclimatic information from the very long and well‐replicated oak chronologies which have been developed in western and central Europe primarily for dating rather than palaeoclimatic research purposes. Copyright © 2012 John Wiley & Sons, Ltd.     

Sedimentology and geochemistry of fluvio-lacustrine tufa deposits controlled by evaporite solution subsidence in the central Ebro Depression, NE Spain

The Urrea de Jalón tufa deposits constitute the 20‐ to 50‐m‐thick caprock (0·3 km²) of an isolated mesa. They disconformably overlie horizontal strata of the Tertiary Ebro Basin (NE Spain), which contains a thick succession of lacustrine gypsum and marls, followed by limestones, marls and, locally, fluvial sandstones and mudstones. The tufa deposits show a complex, large‐scale framework of basin‐like structures with centripetal dips that decrease progressively from the base to the top of the tufa succession, and beds that thicken towards the centre of the structure (cumulative wedge‐out systems). These geometries reveal that the tufa deposits were affected by differential synsedimentary subsidence. Distinct onlapping depressions reflect time migration of the subsiding areas. The studied carbonates are composed mostly of low‐Mg calcite, with minor quartz. Some samples have anomalously high contents of Fe, Mn and Ba that may exceed 1% (goethite, haematite and barite are present). Carbonate facies are: (a) macrophyte encrustation deposits; (b) bryophyte build‐ups; (c) oncolite and coated grain rudstones; (d) non‐concentric stromatolite‐like structures; (e) massive or bioturbated biomicrites; and (f) green and grey marls. Facies a and c show a great variety of microbial‐related forms. These facies can be arranged in dm‐ to 2‐m‐thick vertical associations representing: (i) fluvial–paludal sequences with bryophyte growths; (ii) pond‐influenced fluvial sequences; and (iii) lacustrine–palustrine sequences. The Urrea de Jalón tufa deposits formed in a fluvio‐lacustrine environment that received little alluvial sediment supply. Isotope compositions (δ¹³C and δ¹⁸O) reveal meteoric signatures and accord with such a hydrologically open system of fresh waters. The Fe, Mn and Ba contents suggest an additional supply of mineralized waters that could be related to springs. These would have been discharge points in the Ebro Depression of a regional aquifer of the Iberian Ranges. Rising groundwater caused the solution of the underlying evaporites and the synsedimentary subsidence of the tufa deposits.     

A continuous stable isotope record from the penultimate glacial maximum to the Last Interglacial (159–121 ka) from Tana Che Urla Cave (Apuan Alps,central Italy)

Relatively few radiometrically dated records are available for the central Mediterranean spanning the marine oxygen isotope stage 6–5 (MIS 6–5) transition and the first part of the Last Interglacial. Two flowstone cores from Tana che Urla Cave (TCU, central Italy), constrained by 19 U/Th ages, preserve an interval of continuous speleothem deposition between ca. 159 and 121 ka. A multiproxy record (δ¹⁸O, δ¹³C, growth rate and petrographic changes) obtained from this flowstone preserves significant regional-scale hydrological changes through the glacial/interglacial transition and multi-centennial variability (interpreted as alternations between wetter and drier periods) within both glacial and interglacial stages. The glacial stage shows a wetter period between ca. 154 and 152 ka, while the early to middle Last Interglacial period shows several drying events at ca. 129, 126 and 122 ka, which can be placed in the wider context of climatic instability emerging from North Atlantic marine and NW European terrestrial records. The TCU record also provides important insights into the evolution of local environmental conditions (i.e. soil development) in response to regional and global-scale climate events.     

Seasonal temperatures from δ18O in recent Spanish tufa stromatolites: Equilibrium redux!

This study focuses on recent debate over the value of stable isotope‐based environmental proxies recorded in riverine tufa stromatolites. A twelve‐year record (1999 to 2012) of river‐bed tufa stromatolites in the River Piedra (north‐east Spain) was recovered in this study, along with a partly overlapping fifteen‐year record (1994 to 2009) of accumulations in a drainage pipe: both deposits formed in water with near identical physico/chemical parameters. Measured water temperature data and near‐constant δ ¹⁸O_water composition allowed selection of an ‘equilibrium’ palaeotemperature equation that best replicated actual temperatures. This study, as in some previous studies, found that just two published formulas for water temperature calculation from equilibrium calcite δ ¹⁸O compositions were appropriate for the River Piedra, where tufa deposition rates are high, with means between 5·6 mm and 10·8 mm in six months. The δ ¹⁸O_calcite in both the river and the pipe deposits essentially records the full actual seasonal water temperature range. Only the coldest times (water temperature <10°C), when calcite precipitation mass decreased to minimum, are likely to be unrepresented, an effect most noticeable in the pipe where depositional masses are smaller and below sample resolution. While kinetic effects on δ ¹⁸O_calcite‐based calculated water temperature cannot be ruled out, the good fit between measured water temperature and δ ¹⁸O_calcite‐calculated water temperature indicates that temperature is the principal control. Textural and deposition rate variability between the river and pipe settings are caused by differences in flow velocity and illumination. In the river, calcification of growing cyanobacterial mat occurred throughout the year, producing composite dense and porous laminae, whereas in the pipe, discontinuous cyanobacterial growth in winter promoted more abiogenic calcification. High‐resolution δ ¹⁸O_calcite data from synchronous pipe and river laminae show that reversals in water temperature occur within laminae, not at lamina boundaries, a pattern consistent with progressive increase in calcite precipitation rate as cyanobacterial growth re‐established in spring.     

Petrography and textural development of inorganic and biogenic lithotypes in a relict barite tufa deposit at Flybye Springs, NT, Canada

A relict mound of Holocene barite (BaSO₄) tufa underlies the Flybye Springs, a small, barium‐rich, cold sulphur spring system in the Northwest Territories of Canada. The tufa is composed of relatively pure barite with ≤0·34 wt% Ca²⁺ and ≤0·77 wt% Sr²⁺. The mound is made up of coated bubble, raft, undulatory sheet, stromatolitic, coated grain and detrital conglomerate barite tufa. Although previously unreported in barite, these lithotypes are akin to facies found in many carbonate spring deposits. Raft and ooid‐coated grain tufa was formed via ‘inorganic’ barite precipitation in spring water ponds and tributaries where rapid oxidation of sulphide to sulphate established barite supersaturation. Undulatory sheet tufa may have formed by the reaction of dissolved barium with sulphate derived from the oxidation of extracellular polysaccharide‐rich colloidal sulphur films floating in oxygenated, barite‐saturated spring water ponds. Coated bubble, oncoid‐coated grain and stromatolitic tufa with filamentous microfossils was formed in close association with sulphur‐tolerant microbes inhabiting dysoxic and oxygenated spring water tributaries and ponds. Adsorption of dissolved barium to microbial extracellular polysaccharide probably facilitated the development of these ‘biogenic’ lithotypes. Detrital conglomerate tufa was formed by barite cementation of microdetrital tufa, allochthonous lithoclasts and organic detritus, including caribou hair. Biogenic textures, organic artefacts and microfossils in the Flybye barite tufa have survived diagenetic aggradational recrystallization and precipitation of secondary cements, indicating the potential for palaeoecological information to be preserved in barite in the geological record. Similarities between the Flybye barite tufa and carbonate spring deposits demonstrate that analogous textures can develop in chemical sedimentary systems with distinct mineralogy, biology and physiochemistry.     

Evidence of Abrupt Climate Change during the Mid- to Late- Holocene Recorded in a Tropical Lake, Southern China

Research on abrupt paleoclimatic and paleoenvironmental change provides a scientific basis for evaluating future climate. Because of spatial variability in monsoonal rainfall, our knowledge about climate change during the mid-to lateHolocene in southern China is still limited. We present a multi-proxy record of paleoclimatic change in a crater lake, Lake Shuangchi. Based on the age-depth model from 210 Pb, 137 Cs and AMS14 C data, high-resolution mid-to late-Holocene climatic and environmental records were reconstructed using multiple indices(TOC, TN, C/N, δ13 C and grain size). Shuangchi underwent a marked change from a peat bog to a lake around 1.4 kaBP. The C3 plants likely dominated during 7.0–5.9 ka and 2.5–1.4 kaBP, while C4 plants dominated between 5.9–3.2 and 3.0–2.5 kaBP. Algae were dominant sources of organic matter in the lake sediments after 1.4 kaBP. Several intervals with high concentrations of coarser grain sizes might be due to flood events. These results reveal that several abrupt paleoclimatic events occurred around 6.6 ka, 6.1 ka, 5.9 ka, 3.0 ka, 2.5 ka and 1.4 kaBP. The paleoclimatic change recorded in the lake may be related to the migration of the Intertropical Convergence Zone(ITCZ) and El Ni?o-Southern Oscillation(ENSO) activity.