CIPW标准矿物计算方法与程序设计

CIPW标准矿物计算方法是一百多年前由Cross、Iddings、Pirrson和Washington四位学者设计的岩浆岩岩石化学数据的处理方法,至今在岩浆岩研究中仍发挥着重要的作用.国外学者先后开发了多款软件及Excel工作表,但国内在相关的软件开发方面却显得薄弱.本文在全面评估CIPW标准矿物计算方法的基础上,介绍了作者应用Excel VBA设计的一套计算机程序,该程序除了可计算出标准矿物组成以外,还可计算常用的岩石化学参数.经与前人的计算结果对比表明,该程序的计算结果正确的、可靠的.     

ClPW标准矿物电算程序

一前言岩石化学分析数据的换算、整理和对比的方法很多,换算工作量也较大.笔者就国内外常用的CIPW标准矿物计算方法,用ALGOL60语言编制了电算程序.该程序除计算并输出经典的CIPW标准矿物含量外,还同时计算并输出近十年来岩石化学领域常用到的其他一些化学成分特征参数,供岩系划分、岩石分类命名时参考.本程序尽量做到一次计算后能获得更多的数据.     

花岗岩类自然矿物岩石化学换算及程序设计

花岗岩类自然矿物岩石化学换算是由我国学者朱为方和唐春景设计的针对花岗岩类的标准矿物计算方法.该方法相对于CIPW标准矿物计算做了很大的改进,突出的表现在:(1)几乎能计算出花岗岩中所有的矿物,如各类云母、角闪石、堇青石、夕线石,使标准矿物与实际矿物的组成更加接近;(2)部分矿物的化学组成(如云母、角闪石)会随主岩的成分...     

CIPW标准矿物计算法应用时存在问题的探讨

CIPW法是当今最广泛应用的岩石化学计算法之一,其目的在于提供模拟矿物成分和相对数量,为岩石正确命名提供依据.作者在应用CIPW法过程中,发现不同教科书上的计算原理及方法存在差异,给实际应用造成不便;本文就斜长石牌号的计算方法、CIPW计算原理以及钠长石分配方法等问题进行了探讨.     

一种计算岩石中矿物组成的新方法

介绍根据显微下观察,应用岩石化学全分析结果和分子量计算法计算岩石中矿物组成的新方法。所得各种矿物的组成是整块岩石在三维立体体积中各种矿物的质量分数,比目前沿用的目测一个岩石切面上各种矿物的面积百分比法更准确,比CIPW标准矿物分子法更符合岩石样品组合的实际情况,而且可用于含云母族、绿泥石族和铀矿物等蚀变矿化的花岗岩及沉积岩、变质岩的矿物组成计算。     

微型计算机的岩石和矿物数据处理系统

中国科学院地质所岩石研究室经过多年实际运用,有下列主要岩石学和矿物学数据处理系统程序: 1.标准矿物分子(CIPW)计算程序:输入岩石化学分析数据,可计算28个标准矿物分子和39个常用的岩石化学特征参数,在程序中设计了几种Fe~(3+)和Fe~(2+)修正可选择开关, 2.矿物晶体化学式和某些矿物端员分子数计算程序:包括氧原子法和阳离子法,适用于硅酸盐矿物(含水矿物除外,但可计算含OH矿物的分子式)和氧化物。使用者可自由地进     

火山岩储层斜长石选择性溶蚀的岩石学特征和热力学条件

长石溶孔是火山岩中重要的孔隙类型之一,火山岩的主要孔隙类型中长石溶孔所占的比例在1.24%～60.61%之间,在储层中占有重要地位.从岩相学、岩石化学CIPW标准矿物成分、热力学等方面论证了斜长石的选择性溶蚀.岩相学特征表现出斜长石选择性溶蚀的特征,即钙长石溶蚀时钠长石没有溶蚀,同时出现斜长石选择性溶蚀时钠长石和钾长石生长的现象.斜长石选择性溶蚀得到了CIPW标准矿物成分的支持,在CIPW标准矿物成分中长石的端元组分主要为钠长石和钾长石,而钙长石绝大多数为0或接近0.热力学研究表明,在同样的温度、压力和地层水成分的条件下,在斜长石中优先溶解钙长石组分.当地层水中Na+和K+浓度达到饱和时发生钠长石和钾长石沉淀,出现斜长石选择性溶蚀的同时发生钠长石和钾长石生长的现象.     

CIPW系统标准计算法的介绍

W.Cross,J.P.Iddings,L.V.Pirsson,H.S.Washington等在1902年创立了CIPW系统。原文为《火成岩的定量化学—矿物分类和定名》,是以分类命名为主,而标准矿物分子的计算只是方法和手段。在该文出版以前,出版了W.Cross的文章《十九世纪系统岩类学的发展》作为前驱。     

火山岩储层斜长石选择性溶蚀的岩石学及热力学研究

长石溶孔是火山岩中重要的孔隙类型之一,火山岩的主要孔隙类型中长石溶孔所占的比例在1.24%～60.61％之间,在储层中占有重要地位。从岩相学、岩石化学CIPW标准矿物成分、热力学等方面论证了斜长石的选择性溶蚀。岩相学特征表现出斜长石选择性溶蚀的特征,即钙长石溶蚀时钠长石没有溶蚀,同时出现斜长石选择性溶蚀时钠长石和钾长石生长的现象。斜长石选择性溶蚀得到了CIPW标准矿物成分的支持,在CIPW标准矿物成分中长石的端元组分主要为钠长石和钾长石,而钙长石绝大多数为0或接近0。热力学研究表明,在同样的温度、压力和地层水成分的条件下,在斜长石中优先溶解钙长石组分。当地层水中Na+和K+浓度达到饱和时发生钠长石和钾长石沉淀,出现斜长石选择性溶蚀的同时发生钠长石和钾长石生长的现象。     

基于改进的SVM技术和高光谱遥感的标准矿物定量计算

基于支持向量机(SVM)统计理论,并对其从核函数构造方面进行改进,通过主成分分析、包络线去除、光谱导数变换等对原始Hyperion高光谱数据进行降维、变换与特征提取,分析比较了这些变换后不同的回归效果,并将其应用在内蒙古霍林郭勒地区岩石中氧化物质量分数的反演中。同时,鉴于某些重要矿物本身并没有明显的特征光谱曲线,提出一种新的矿物定量方法。首先,基于高光谱遥感数据,利用改进的SVM回归技术反演矿物中的化学成分,然后通过标准矿物计算（CIPW）推导岩石中标准矿物的质量分数。研究结果表明：基于改进核函数后的SVM回归精度有所提高,其中导数变换后的反演精度达74.87%,比原始光谱反演精度提高了4.11%。CIPW应用于高光谱遥感地质填图效果良好,为岩性鉴定和评价提供了科学依据。     

关于火山熔岩分类命名的建议

岩浆岩的分类、命名是研究岩浆岩岩石学的基础,愈来愈为岩石学者所重视。在24届国际地质会议上确定了深成岩的分类、命名方案,并已得到广泛应用。但由于火山岩的复杂性,在分类、命名方面,至今尚无统一的口径。因此,火山岩分类方案多如雨后春笋,岩石名称杂乱,对岩石学的发展颇为不利,故迫切需要建立一个国际统一的分类、命名方案。     

Geochemical characteristics of igneous rocks associated with epithermal mineral deposits—A review

Newly synthesized data indicate that the geochemistry of igneous rocks associated with epithermal mineral deposits varies extensively and continuously from subalkaline basaltic to rhyolitic compositions. Trace element and isotopic data for these rocks are consistent with subduction-related magmatism and suggest that the primary source magmas were generated by partial melting of the mantle-wedge above subducting oceanic slabs. Broad geochemical and petrographic diversity of individual igneous rock units associated with epithermal deposits indicate that the associated magmas evolved by open-system processes. Following migration to shallow crustal reservoirs, these magmas evolved by assimilation, recharge, and partial homogenization; these processes contribute to arc magmatism worldwide.Although epithermal deposits with the largest Au and Ag production are associated with felsic to intermediate composition igneous rocks, demonstrable relationships between magmas having any particular composition and epithermal deposit genesis are completely absent because the composition of igneous rock units associated with epithermal deposits ranges from basalt to rhyolite. Consequently, igneous rock compositions do not constitute effective exploration criteria with respect to identification of terranes prospective for epithermal deposit formation. However, the close spatial and temporal association of igneous rocks and epithermal deposits does suggest a mutual genetic relationship. Igneous systems likely contribute heat and some of the fluids and metals involved in epithermal deposit formation. Accordingly, deposit formation requires optimization of source metal contents, appropriate fluid compositions and characteristics, structural features conducive to hydrothermal fluid flow and confinement, and receptive host rocks, but not magmas with special compositional characteristics.     

辽宁省清原县东山岔金-钼矿床地质特征及找矿标志

东山岔金钼矿床位于王小堡-线金厂-井家沟金成矿带上.目前已发现多处小型金矿床及矿点.金矿体主要赋存于云英岩化紫苏花岗质片麻岩及云英岩中,受断裂构造控制明显.矿化类型有金-钼矿化和金矿化.矿床找矿标志主要包括矿体的原生露头、近矿围岩蚀变、矿物地球化学及地球物理特征方面.通过对区内已知矿床的矿体形态、矿石组成、结构构造、围岩蚀变等进行对比和分析,认为该区成矿物质主要来源于含矿岩体和地层,矿床成因应属与中酸性侵入岩密切相关的中低温热液型金钼矿床.     

Oxidation potential and the composition of metamorphic fluid as a solution to the inverse problem of convex programming

Using the Selektor-C software program package, oxidation potential and the composition of metamorphogenic fluid were determined for mineral assemblages from nine samples of granulite-grade metamorphic rocks by solving the inverse problems of convex programming. The calculated and real mineral assemblages are in good agreement with respect to the composition and association of minerals, which is compelling evidence for the attainment of chemical equilibrium (minimum of Gibbs free energy) under given P-T conditions. Based on the dual solution of the inverse problem, a new approach was proposed for the estimation of the oxidation potential of fluid and mineral assemblages, which can be used to determine oxygen potential for almost any mineral association, independent of the presence of magnetite, ilmenite, or graphite. It was found that magnetite-free mineral associations are characterized by highly reducing conditions corresponding to oxygen potentials close to the CCO buffer. The external metamorphic fluid that was present during granulite-facies metamorphism was probably formed in the graphite stability field. The results of calculations for the model aqueous electrolyte solution-mineral assemblage suggest high SiO₂ solubility in the metamorphogenic fluid. Therefore, the process of granulite metamorphism may be a potent geochemical factor of the redistribution and transportation of silica from lower to upper crustal levels.     

Calculated phase equilibria in K2O-FeO-MgO-Al2O3-SiO2-H2O for sapphirine-quartz-bearing mineral assemblages

Sapphirine, coexisting with quartz, is an indicator mineral for ultrahigh‐temperature metamorphism in aluminous rock compositions. Here a new activity‐composition model for sapphirine is combined with the internally consistent thermodynamic dataset used by THERMOCALC, for calculations primarily in K₂O‐FeO‐MgO‐Al₂O₃‐SiO₂‐H₂O (KFMASH). A discrepancy between published experimentally derived FMAS grids and our calculations is understood with reference to H₂O. Published FMAS grids effectively represent constant a_H2O sections, thereby limiting their detailed use for the interpretation of mineral reaction textures in compositions with differing H₂O. For the calculated KFMASH univariant reaction grid, sapphirine + quartz assemblages occur at P–T in excess of 6–7 kbar and 1005 °C. Sapphirine compositions and composition ranges are consistent with natural examples. However, as many univariant equilibria are typically not ‘seen’ by a specific bulk composition, the univariant reaction grid may reveal little about the detailed topology of multi‐variant equilibria, and therefore is of limited use for interpreting the P–T evolution of mineral assemblages and reaction sequences. Calculated pseudosections, which quantify bulk composition and multi‐variant equilibria, predict experimentally determined KFMASH mineral assemblages with consistent topology, and also indicate that sapphirine stabilizes at increasingly higher pressure and temperature as X_Mg increases. Although coexisting sapphirine and quartz can occur in relatively iron‐rich rocks if the bulk chemistry is sufficiently aluminous, the P–T window of stability shrinks with decreasing X_Mg. An array of mineral assemblages and mineral reaction sequences from natural sapphirine + quartz and other rocks from Enderby Land, Antarctica, are reproducible with calculated pseudosections. That consistent phase diagram calculations involving sapphirine can be performed allows for a more thorough assessment of the metamorphic evolution of high‐temperature granulite facies terranes than was previously possible. The establishment of a a‐x model for sapphirine provides the basis for expansion to larger, more geologically realistic chemical systems (e.g. involving Fe³⁺).     

太古宙花岗岩中的暗色包体

在华北陆台北缘太古宙花岗质岩石的成因研究中,对其中的暗色包体进行了较详细的矿物学和岩相学研究,从中获得了许多反映花岗质岩浆来源及其成岩演化过程的信息,从而为花岗岩的岩浆起源提供了证据。这些暗色岩包体按成因及来源可分为:深源火成岩包体,围岩包体及深熔同生包体。研究表明,深源火成岩包体是花岗岩的母岩浆(基性岩浆)的早期结晶分离相,有些包体可能代表岩浆源区—上地幔岩的岩块。而深熔同生包体和围岩包体则是在深熔岩浆的形成过程中母岩中难熔组分的聚集物和岩浆上侵过程中捕获围岩的产物。     

Multiple Mesozoic mineralization events in South China—an introduction to the thematic issue

Mesozoic mineral deposits in South China include world-class deposits of W, Sn and Sb and those that provide the major sources of Ta, Cu, Hg, As, Tl, Pb, Zn, Au and Ag for the entire country. These deposits can be classified into polymetallic hydrothermal systems closely related to felsic intrusive rocks (Sn–W –Mo granites, Cu porphyries, polymetallic and Fe skarns, and polymetallic vein deposits) and low-temperature hydrothermal systems with no direct connection to igneous activities (MVT deposits, epithermal Au and Sb deposits). Recent studies have shown that they formed in the Triassic (Indosinian), Jurassic–Cretaceous (Early Yanshanian), and Cretaceous (Late Yanshanian) stages. Indosinian deposits include major MVT (Pb–Zn–Ag) deposits and granite-related W–Sn deposits. Early Yanshanian deposits are low-temperature Sb–Au and high-temperature W–Sn and Cu porphyry types. Many Late Yanshanian deposits are low-temperature Au–As–Sb–Hg and U deposits, and also include high-temperature W–Sn polymetallic deposits. The formation of these deposits is linked with a specific tectonothermal evolution and igneous activities. This special issue brings together some of the latest information in eight papers that deal with the origins and tectonic environments of mineral deposits formed in these stages. We anticipate that this issue will stimulate more interests in these ore deposits in South China.     

柴北缘西段古近纪物源体系分析

沉积区物源分析对研究造山带构造演化、盆地沉积过程及划分油气区带等方面具有重要的意义。为了查明柴达木盆地北缘构造带古近纪物源方向,通过对古近系碎屑岩的碎屑组成、岩屑成分、重矿物组合特征和ZTR指数的研究,并结合前人的研究成果,初步确定古近纪柴北缘西段发育五大主力物源区:(1)牛东物源主要来自阿尔金山东段,重矿物组合以稳定且含量较高的电气石区别于邻区,碎屑组分中以石英和含量较高的长石为特征,岩屑中含有少量的碳酸盐岩岩屑;(2)冷北物源主要来自小赛什腾山方向,重矿物组合中榍石和赤铁矿的含量明显偏高,碎屑组分中以高岩屑为特征;(3)赛西物源主要来自赛什腾山西段,电气石和角闪石含量较高,碎屑组分较为均一,母岩以变质岩和火成岩为主,含少量碳酸盐岩岩屑;(4)赛东物源主要来自赛什腾山东段,其白钛矿含量明显高于邻区,碎屑组分以较高含量的石英和长石为主,岩屑类型主要为变质岩、火成岩和沉积岩岩屑;(5)九龙山物源主要来自九龙山和绿梁山地区,石榴石含量高且稳定,碎屑组分较为均一,母岩以变质岩和火成岩为主,含少量的非碳酸盐岩类沉积岩岩屑。     

重矿物聚类分析在物源分析及地层对比中的应用——以东海陆架盆地西湖凹陷平湖地区为例

摘要：通过对重矿物进行Ｒ型、Ｑ型聚类分析,结合沉积学及砂岩矿物成分的研究,认为西湖凹陷平湖区第三系沉积物陆源区母岩类型共３类。其中由重矿物组合反映的母岩包括变质岩和火成岩共２类５型。在平面分布上,平湖地区南、北母岩类型有差别：南部以中性、中酸性火成岩为主,而北部既有各类变质岩又有中基性、酸性火成岩;在纵向演化上,南北也存在较大的差异,表现为充填过程中由于物源变化而反映的不同类型重矿物组合的交替变化。第三系沉积充填过程中物源供应总体方向由西而东,可进一步分为南部古渔山凸起和中北部古海礁凸起物源区。反映物源区或母岩性质变化的Ｑ型聚类分析,作为地层划分与对比的一种辅助方法在实际工作中具有一定的使用价值。     

A review of mineral resources in Malawi: With special reference to aluminium variation in mineral deposits

The lithology of Malawi is characterized by Precambrian metamorphic and igneous rocks which form part of the polyphase East African Orogen. Rift-related sedimentation and igneous activity during the late Paleozoic (Karoo System) and the late Mesozoic (Chilwa Province) have produced a great variety of rocks that underwent strong chemical weathering and erosion when the entire region received its final shape by peneplanation and fluvial incision during the Cenozoic under (sub)tropical climatic conditions. Aluminum is a dominating element in minerals (e.g., corundum, kyanite, beryl, gibbsite) in this region. Some minerals were concentrated in deposits bound to Al-enriched host rocks (zircon, pyrochlore, eudialyte, uranium minerals) with high A/CNK ratios, whereas others, e.g., asbestos, chalcedony, monazite, kaolinite, ilmenite and garnet have host rocks of a low A/CNK ratio. Aluminum was used to categorize these various mineral deposits. The abundance of aluminum and accumulations of Nb, Zr, Ti, REE, Sr and Ba point for some mineralisations to similar subcrustal carbonatite-forming systems that were operative during periods of the Precambrian and the Mesozoic in Malawi. Aluminum variation does not only reflect differentiation in the various igneous rock series but it is also visible in the sedimentary realm during transport and weathering. In context with other elements such as Ti and P, Al provides an opportunity to reveal chemical relationships between rocks and mineral deposits. Spinel and Al-enriched silicate minerals can be used as pathfinder minerals in the stream sediments to guide the exploration geologist to non-metallic deposits.