单元两相气液包裹体热力学方程的推导和应用

Three thermodynamical equations, for unitary two-phase fluid inclusions have been deduced. (1) The thermodynamical equation for mutual transformation between gas and liquid phases in fluid inclusions. The transformation direction from one phase to the other can be known in terms of the density and filling degree of gas and liquid. (2) The thermodynamical equation for pressure effect on temperature after homogenization of fluid inclusions. The coefficient of P-T variation is directly proportional to the fining degree of gas phase and inversely to the density of gas phase and liquid phase. Equations for homogenization, decrepitation and formation temperatures of fluid inclusions can be inferred from. this equation. (3) The thermodynomical equation for decrepitation temperatures of fluid inclusions. Many factors have effects on the decrepitation temperatures of fluid inclusions.Decrepitation temperature cannot be considered in any case as formation temperature.Thermal and vapor halos produced by decrepitation of minerals of the same kind and the same period from the same locality are worthy of consideration.     

CO_2 Density-Raman Shift Relation Derived from Synthetic Inclusions in Fused Silica Capillaries and Its Application

Abstract: The densities of CO2 inclusions in minerals are commonly used to determine the crystallizing conditions of the host minerals. However, conventional microthermometry is difficult to apply for inclusions of small size (< 5–10 μm) or low density. Raman analysis is an alternative method for determining CO2 density, provided that the CO2 density–Raman shift relation is known. This study aims to establish this CO2 density–Raman shift relation by using CO2 inclusions synthesized in fused silica capillaries. By using this newly-developed synthetic technique, we formed pure CO2 inclusions, and their densities were determined by microthermometry. The Raman analysis showed that the relation between CO2 density (D in g/cm3) and the separations (Δ in cm?1) between the two main bands (i.e. Fermi diad bands) in CO2 Raman spectra can be represented by a cubic equation: D (g/cm3)=0.74203(?0.019Δ3+5.90332Δ2?610.79472Δ+21050.30165)?3.54278 (r2=0.99920). Our calculated D value for a given Δ is between those obtained from two previously-reported equations, which were derived from different experimental methods. An example was given in this study to demonstrate that the densities of natural CO2 inclusions that could not be derived from microthermometry could be determined by using our method.     

气水化合物的水合常数及其在水溶液包裹体多组分挥发分测定中的应用

During the microthermometric measurement(cooling)of aqueous inclusions with multivolatile components,solid crystals of gas clathrates often occur with snow-flower-or soft-ice appearances.The structural formula of these solids is M·nH_2O(where n≥5.67).Many hydrocarbons,related compounds and their binary or multi-component mixtures may generate gas clathrates.This phenomenum is of fundamental importance to the study of inclusions with hydrocarbon aqueous solutions,because this is related to the determination of inclusion parameters and the computation of thermodynamic parameters. In the nature most aqueous inclusions contain not merely one volatile component but multi-volatile components.Therefore,the measurement of aqueous inclusions with multivolatile components is of universal significance and great importance.There have been many studies and available formula or figures about the computation of thermodynamic parameters for aqueous inclusions with one volatile component.Nevertheless,there are few studies concerning with muhivolatile components and it is very difficult to computate thermodynamic parameters for aqueous inclusions with these components. In this paper,hydrated coefficient K is introduced.K_i is the ratio of molar fraction of component i in the gas phase to that in the gas clathrate,or K_i=y_i/x_i.Because K is a function of temperatures and pressures,it can be used to evaluate the temperature-pressure conditions on the phase behavior with muhivolatile components. Based on the regression analysis of available experimental data,the authors have developed computational expression of hydrated coefficients in relation to temperature and pressure for most hydrocarbons and other volatile components,which is helpful to conveniently compute thermodynamic parameters on stability state for elathrates with volatile components.As aqueous inclusions with muhivolatile components are common in the nature,by the use of final melting temperatures of clathrates from mierothermometry and these formula,fluid density of gas phase with valotile components and bulk fluid density of inclusions can be accurately calculated. Furthermore,this method may provide foundations to determine the isochores of inclusions and to calculate trapping temperatures and pressures. Finally,detailed analyses for two computational examples about aqueous inclusions with muhivolatile components are presented.     

Density Calculation for NaCl-H_2O Solutions in the Liquid-Solid TwoPhase Field in NaCI-H_2O Three-Phase Inclusions

Three-phase NaCl-H_2O fluid inclusions featuring halite dissolution temperature(Tm)higher than vapor bubble disappearance temperature(T_h) are commonly observed in porphyry copper/molybdenum deposits,skarn-type deposits and other magmatic- hydrothermal ore deposits.Based on |ΔV_1|(the absolute value of volume variation of NaCl-H_2O solution in a heating or cooling process of inclusions)= |ΔV_s|(the absolute value of volume variation of the halite crystal in a heating or cooling process of inclusions) and on the principle of conservation of the mass of NaCl and H_2O,we systematically calculated the densities of NaCl-H_2O solutions in the solid-liquid two-phase field for temperatures(T_h) from 0.1℃ to 800℃ and salinities from 26.3 wt%to 99.2wt%.Consequently for the first time we obtained the upper limit of the density of NaCI-H_2O solutions in the solid-liquid twophase field for T_bT_m inclusions with variant salinities.The results indicate that for inclusions of the T_hT_m type with the same T_h,the higher the T_m or salinity is,the higher the density of the NaClsaturated solution will be.If a group of fluid inclusions were homogeneously trapped,they must have the same T_h value and the same T_m or salinity value.This may be used to distinguish homogeneous,inhomogeneous,and multiple entrapments of fluid inclusions.     

Determining Fluid Compositions in the H2O-NaCl-CaCl2 System with Cryogenic Raman Spectroscopy: Application to Natural Fluid Inclusions

Previous cryogenic Raman spectroscopic analysis of H₂O-NaCl-CaCl₂ solutions has identified the Raman peaks of various hydrates of NaCl and CaCl₂,and established a linear relationship between Raman band intensity of the hydrates and the composition of the solution(NaCl/（NaCl+CaCl₂） molar ratio,or X_NaC1) using synthetic fluids,which created the opportunity to quantitatively determine the solute composition of aqueous fluid inclusions with cryogenic Raman spectroscopy.This paper aims to test the feasibility of this newly established method with natural fluid inclusions.Twenty-five fluid inclusions in quartz from various occurrences which show a high degree of freezing during the cooling processes were carefully chosen for cryogenic Raman analysis.X_NaCl was calculated using their spectra and an equation established in a previous study.These inclusions were then analyzed with the thermal decrepitation-SEM-EDS method.The X_NaCl values estimated from the two methods show a 1:1 correlation,indicating that the new,non-destructive cryogenic Raman spectroscopic analysis method can indeed be used for fluid inclusion compositional study.     

Determining Pressure with Daughter Minerals in Fluid Inclusion by Raman Spectroscopy: Sphalerite as an Example

Abstract: Raman frequency of some materials, including minerals, molecules and ions, shifts systematically with changing pressure and temperature. This property is often used as a pressure gauge in high pressure experiments with the hydrothermal diamond anvil cell (HDAC). Since the system of fluid inclusion is similar to that of HDAC, it can also be used to determine the internal pressure of fluid inclusions. Sphalerite is a common daughter mineral. In this study, the frequency shift of the 350 cm?1 peak of sphalerite has been studied from 296 to 523 K and from 0.07 to 2.00 GPa using the HDAC. The global slope of the isotherms (?n350/?p)T is 0.0048 in the studied pressure range. No significant variation of the slopes with temperature has been observed. The correlation between the frequency shift of the 350 cm?1 peak of sphalerite and pressure and temperature is constrained as P=208.33(?np)350+3.13T?943.75. This relationship may be used to estimate the internal pressure of the sphalerite-bearing fluid inclusions.     

Depth of volcanic basalt degassing forecasted from CO2 fluid inclusions

Fluid inclusions have recorded the history of degassing in basalt. Some fluid inclusions in olivine and pyroxene phenocrysts of basalt were analyzed by micro-thermometry and Raman spectroscopy in this paper. The experimental results showed that many inclusions are present almost in a pure CO2 system. The densities of some CO2 inclusions were computed in terms of Raman spectroscopic characteristics of CO2 Fermi resonance at room temperature. Their densities change over a wide range, but mainly between 0.044 g/cm3 and 0.289 g/cm3. Their micro-thermometric measurements showed that the CO2 inclusions examined reached homogenization between 1145.5℃ and 1265℃ . The mean value of homogenization temperatures of CO2 inclusions in basalts is near 1210℃. The trap pressures (depths) of inclusions were computed with the equation of state and computer program. Distribution of the trap depths makes it know that the degassing of magma can happen over a wide pressure (depth) range, but mainly at the depth of 0.48 km to 3.85 km. This implicates that basalt magma experienced intensive degassing and the CO2 gas reservoir from the basalt magma also may be formed in this range of depths. The results of this study showed that the depth of basalt magma degassing can be forecasted from CO2 fluid inclusions, and it is meaningful for understanding the process of magma degassing and constraining the inorganogenic CO2 gas reservoir.     

土壤的冷生构造及其对阿拉斯加土地利用的意义

Cryogenic structure (patterns made by ice inclusions) in seasonally frozen and permafrost-af-fected soils result from ice formation during freezing. Analysis of cryogenic structures in soils is essential to our understanding of the cryogenic processes in soils and to formulating land use management interpretations. When soils freeze, the freezing front moves downward and attracts water moving upward resulting in mainly horizontal lenticular ice formation. Platy and lenticular soil structures form between ice lenses in upper active layer. The reticular soil structure usually forms above the permafrost table caused by freeze-back of the permafrost. The upward freeze-back resulted in platy soil structure and the volume changes following the annual freeze-thaw cycle resulted in vertical cracks. The combined result is an ice-net formation with mineral soils embedded in the ice net. The upper permafrost layer that used to be a part of the active layer has an ice content exceeding 50% due to repeated freeze-thaw cycles over time. The mineral soils appear in blocks embedded in an ice matrix. The permafrost layer that never experienced the freeze-thaw cycle often consists of alternate layers of thin ice lens and frozen soils with extreme hard consistence and has relatively lower ice content than the ice-rich layer of the upper permafrost. Ice contents and thaw settling potentials associated with each cryogenic structure should be considered in engineering and land use interpretations.     

Genesis and mineralization of gold-bearing quartz veins in the Xiao Qinling area, central China

Gold-bearing quartz veins of the Taihua Group consisting of Archean metavolcanic rocks are a main gold deposit type in the Xiao Qinling area,one of the three biggest gold production areas in China.The quartz veins experienced strong alteration characterized by a typical mesothermal hydrothermal altered mineral assemblage.The grade of gold is affected by the contents of sulphides,e.g.galena,pyrite and chalcopyrite.Results of minor elements analysis for the of gold-bearing quartz veins indicate higher contents of Au and high contents of Ag,Pb,Cu,Cd,W,and Mo.Abundant fluid inclusions were found in the gold-bearing quartz veins.Three types of fluid inclusions were identified:(1) aqueous inclusions;(2) CO 2-bearing inclusions;and(3) daughter crystal-bearing fluid inclusions.Homogenization temperatures ranged from 110 to 670℃ with low and high peaks appearing at 160 180℃ and 280 300℃,respectively.The salinity of aqueous inclusions varies between 1.8 wt% and 38.2 wt% NaCl.The homogenization temperature and salinity show a positive correlation.The H and O isotopes of fluid inclusions in the gold-bearing quartz veins indicate that magmatic solution and metamorphic hydrothermal solution,together with meteoric water,were involved in the formation of gold-bearing fluid.Mesozoic magma activities related to granite intrusions should be the main source of CO 2 fluid with higher temperature and salinity.     

http://www.sciencedirect.com/science/article/pii/S1674987115000031

Landslides are common natural hazards occurring in most parts of the world and have considerable adverse economic effects. Residual shear strength of clay is one of the most important factors in the determination of stability of slopes or landslides. This effect is more pronounced in sensitive clays which show large changes in shear strength from peak to residual states. This study analyses the prediction of the residual strength of clay based on a new prediction model, functional networks(FN) using data available in the literature. The performance of FN was compared with support vector machine(SVM) and artificial neural network(ANN) based on statistical parameters like correlation coefficient(R), Nash–Sutcliff coefficient of efficiency(E), absolute average error(AAE), maximum average error(MAE) and root mean square error(RMSE). Based on R and E parameters, FN is found to be a better prediction tool than ANN for the given data. However, the R and E values for FN are less than SVM. A prediction equation is presented that can be used by practicing geotechnical engineers. A sensitivity analysis is carried out to ascertain the importance of various inputs in the prediction of the output.     

Combined microthermometric and Raman spectroscopic technique to determine the salinity of H2O-CO2-NaCl fluid inclusions based on clathrate melting

Fluid inclusions approximated by the system H₂O-CO₂-NaCl are common in many geologic environments. In order to apply microthermometric data from these inclusions to infer P-T (pressure-temperature) trapping conditions, the composition of the inclusions, including the salinity, must be known. Normally, salinities of aqueous inclusions are determined from ice-melting temperatures obtained during microthermometry. However, when CO₂-bearing aqueous fluid inclusions are cooled they often form a hydrate that incorporates H₂O into the structure, and salinities estimated from ice-melting temperatures are therefore higher than the actual salinity. A technique that combines data from Raman spectroscopic and microthermometric analyses of individual inclusions was developed to determine the salinity of CO₂-bearing aqueous inclusions based on measured clathrate melting temperatures and CO₂ pressures obtained from Raman analyses. In this study, the pressure within inclusions was determined using Raman spectroscopy based on the splitting of the Fermi diad of CO₂, measured at the clathrate melting temperature. The CO₂ densities (and pressures) predicted by the equation developed in this study are in relatively good agreement with previously published equations, except for very low densities and correspondingly low pressures. The combined Raman spectroscopy - microthermometry technique thus provides both the temperature and the pressure in the inclusion at clathrate melting. For inclusions in which the clathrate melts in the presence of CO₂ liquid, the salinity can be determined with a precision of a few tenths of a wt% NaCl, whereas for inclusions in which clathrate melts in the presence of CO₂ vapor the salinity error may be a few wt% NaCl. Applying the method to synthetic fluid inclusions with known salinity suggests that the technique is valid for determining salinity of H₂O-CO₂-NaCl fluid inclusions in which clathrate melts in the presence of liquid CO₂ only or vapor CO₂ only.     

A Fluid Inclusion Study on Columnar Adularia from the Hishikari Low-sulfidation Epithermal Gold Deposit, Japan

Abstract: In the Hishikari low-sulfidation epithermal gold deposit, Japan, columnar adularia crystals commonly precipitated directly on to the fracture surface of wall rock, and then electrum precipitated on the columnar adularia with fine-grained adularia and quartz. To reveal the characteristics of mineralizing fluids and the elevation of paleo-water tables at the earliest stage of mineralization in the Honko-Sanjin zone of the Hishikari deposit, the fluid inclusions in the columnar adularia in gold-bearing quartz–adularia veins were studied.
Coexistence of vapor-rich and liquid-rich two–phase primary fluid inclusions indicates the deposition of columnar adularia from boiling fluids. The precipitation temperatures range from 175 to 215C, and generally increase with depth. The temperatures of final melting point of ice range from –1.2 to –0.1C with an average of –0.5C, corresponding to salinity ranging from 0.2 to 2.1 wt% NaCl equivalent with an average of 0.9 wt% NaCl (eq.). Concentrations of non-condensable gases such as CO₂ were under the detection limit of a laser Raman microprobe spectrometer. From the precipitation temperature of columnar adularia in the Hosen–2 vein and the boiling point – depth curve for a 0.9 wt% NaCl (eq.) fluid, paleo-water table was estimated to be at an elevation of about +170 m. The elevation of the paleo-water tables for other veins was estimated to range from +140 to +215 m.     

Fluid Inclusions in the Gold—Bearing Quartz Veins at Um Rus Area,Eastern Desert,Egypt

Fluid inclusions in the gold-bearing quartz veins at the Um Rus area are of three types: H₂O, H₂O−CO₂ and CO₂ inclusions. H₂O inclusions are the most abundant, they include two phases which exhibit low and high homogenization temperatures ranging from 150 to 200°C and 175 to 250°C, respectively. The salinity of aqueous inclusions, based on ice melting, varies between 6.1 and 8 equiv. wt% NaCl. On the other hand, H₂O−CO₂ fluid inclusions include three phases. Their total homogenization temperatures range from 270 to 325°C, and their salinity, based on clathrate melting, ranges between 0.8 and 3.8 equiv. wt% NaCl. CO₂ fluid inclusions homogenize to a liquid phase and exhibit a low density range from 0.52 to 0.66 g/cm³. The partial mixing of H₂O−CO₂ and salt H₂O−NaCl fluid inclusions is the main source of fluids from which the other types of inclusions were derived. The gold-bearing quartz veins are believed to be of medium temperature hydrothermal convective origin.     

塔里木北缘库鲁克塔格地块大金沟金矿流体包裹体特征:对矿床成因的启示

在成矿地质背景和矿床地质特征研究基础上,对大金沟金矿主矿体中含矿石英脉流体包裹体开展了系统的岩相观察和显微测温工作。结果表明:大金沟金矿含矿石英脉中主要发育富液相的气液两相包裹体,偶见纯液相或气相包裹体。这些包裹体可分为低温高盐度(75℃~121℃,16.71 wt%NaCl~19.68 wt%NaCl)、低温低盐度(100℃~172℃,0.7 wt%NaCl~5.71 wt%NaCl)、中低温中低盐度(75℃~253℃,6.16 wt%NaCl~12.51 wt%NaCl)和高温中低盐度(331℃~420℃,4.96 wt%NaCl~12.51 wt%NaCl)等4类。大金沟金矿主成矿期流体包裹体的均一温度(75℃~253℃)和盐度(0.7 wt%NaCl~19.68 wt%NaCl)变化较大,且两者的相关性不明显,属典型的中低盐度流体体系,与造山过程相关的变质流体类似,表明该矿床可能为造山型金矿床。     

Contrasting fluid inclusion characteristics of staniferous and non-staniferous pegmatites of Southeast Bastar,Central India

Tin and rare metal-bearing granitic pegmatites in the Bastar–Malkangiri pegmatite belt of Central India are hosted by metabasic and metasedimentary country rocks. Fluid inclusion studies were conducted in spatially associated two-mica granite and the staniferous and non-staniferous pegmatites to characterize the physicochemical environment of mineralization, to distinguish different pegmatites in terms of their fluid characteristics and to envisage a possible genetic link between the pegmatites and spatially associated granite. Three different types of primary inclusions were identified. The type-I, aqueous bi-phase (L+V) inclusions are the most abundant and ubiquitous. Type-II polyphase (L+V+S) inclusions are rare. Type-III, monophase (L) and metastable aqueous inclusions, though less abundant than type-I inclusions, are ubiquitous. The fluid evolution trends indicate that mixing of two different fluids of contrasting salinities, one of high salinity (20–30 wt% NaCl equivalent) and another of low salinity (0–10 wt% NaCl equivalent), was responsible for precipitation of the bulk of the cassiterite. This mixing is the single most important characteristic that distinguishes the staniferous pegmatites from their non-staniferous counterparts. The non-staniferous pegmatites, on the other hand, are typified by the presence either of a high saline or a low saline fluid that evolved through simple cooling. The minimum pressure–temperature of entrapment, estimated from the intersections of the halide liquidus with the corresponding inclusion isochores of type-II inclusions, range between 2.1–2.2 kb and 300–325 °C. The similar P–T range of fluid entrapment of the staniferous and non-staniferous pegmatites indicates that they were possibly emplaced within a similar physical environment. Type-I inclusions from granite recorded only the high salinity fluid, the salinity of which compares well with that of the highly saline fluid component of type-I inclusions in the pegmatites. This is a possible indication of a genetic link between the pegmatites and spatially associated granite.     

吉林中东部季德屯和大石河大型钼矿床流体包裹体特征及地质意义

季德屯和大石河钼矿是吉林中东部新发现的两个大型钼矿。季德屯钼矿主成矿阶段发育富液相(WL)、富气相(WG)和含CO2相(C型)三种类型流体包裹体,各类包裹体平均盐度为4.8~7.5(wt%,Na Cl)、均一温度为240℃~320℃、成矿压力为73.6~75.5 MPa;晚成矿阶段仅发育富液相(WL)包裹体,包裹体平均盐度为4.5~7.5(wt%,Na Cl)、均一温度为150℃~180℃、成矿压力为43.1~45.1 MPa。大石河钼矿主成矿阶段发育富液相(WL)和含CO2相(C型)两种类型流体包裹体,各类包裹体平均盐度为3.0~6.0(wt%,Na Cl)、均一温度为180℃~330℃、成矿压力为86.4~91.6 MPa;晚成矿阶段仅发育富液两相(WL)包裹体,盐度为1.0~4.0(wt%,Na Cl)、均一温度为160℃~220℃、成矿压力为46.8~48.8 MPa。结合矿床地质特征,确定季德屯钼矿矿床类型为与侵入岩有关的脉状钼矿床,大石河钼矿矿床类型为造山型脉状钼矿床。     

苏北青龙山超高压变质榴辉岩流体包裹体特征与流体演化

根据青龙山超高压变质榴辉岩中流体包裹体的化学成分、矿物中的分布特征将岩石中的流体包裹体分为五类,即富N2包裹体、高盐度(22.4-略大于23.2wt%NaCl)的NaCl CaCl2 H2O体系流体包裹体、中高盐度(12.6-16.0wt%NaCl)的含Mg2 或Fe2 的NaCl H2O体系流体包裹体、中等盐度(6.4-10.5wt%NaCl)水溶液包裹体和低盐度(3.3-0.2wt%NaCl)的水溶液包裹体。富N2包裹体形成于超高压变质峰期阶段,高盐度的流体包裹体形成于超高压变质岩折返早期固体出溶体出溶阶段,中高盐度的流体包裹体形成于高压变质重结晶作用阶段,中等盐度的流体包裹体形成于角闪岩相变质重结晶作用阶段,低盐度的流体包裹体形成于折返晚期的绿片岩退变质作用阶段。超高压变质峰期阶段和折返早期的高盐度流体和中高盐度的流体主要来自继承原岩中的流体(如含NH4 矿物分解或片麻岩原岩中的有机质分解,名义上无水矿物中羧基水的出溶),晚期角闪岩相退变质阶段的中等盐度的流体除名义上无水矿物中羟基水的出溶外还有外来流体的加入,绿片岩相退变质作用阶段的流体主要为外来流体。     

Fluid Inclusion Studies of Ore and Gangue Minerals from the Piaotang Tungsten Deposit, Southern Jiangxi Province, China

The Piaotang deposit is one of the largest vein-type W-polymetallic deposits in southern Jiangxi Province, South China. The coexistence of wolframite and cassiterite is an important feature of the deposit. Based on detailed petrographic observations, microthermometry of fluid inclusions in wolframite, cassiterite and intergrown quartz was undertaken. The inclusions in wolframite were observed by infrared microscope, while those in cassiterite and quartz were observed in visible light. The fluid inclusions in wolframite can be divided into two types: aqueous inclusions with a large vapor-phase proportion and aqueous inclusions with a small vapor-phase ratio. The homogenization temperature (Th) of inclusions in wolframite with large vapor-phase ratios ranged from 280°C to 390°C, with salinity ranging from 3.1 to 7.2 wt% NaCl eq. In contrast, the Th values of inclusions with small vapor-phase ratios ranged from 216°C to 264°C, with salinity values ranging from 3.5 to 9.3 wt% NaCl eq. Th values of primary inclusions in cassiterite ranged from 316°C to 380°C, with salinity ranging from 5.4 to 9.3 wt% NaCl eq. Th values for primary fluid inclusions in quartz ranged from 162°C to 309°C, with salinity values ranging from 1.2 to 6.7 wt% NaCl eq. The results show that the formation conditions of wolframite, cassiterite and intergrown quartz are not uniform. The evolutionary processes of fluids related to these three kinds of minerals are also significantly different. Intergrown quartz cannot provide the depositional conditions of wolframite and cassiterite. The fluids related to tungsten mineralization for the NaCl-H2O system had a medium-to-high temperature and low salinity, while the fluids related to tin mineralization for the NaCl-H2O system had a high temperature and medium-to-low salinity. The results of this study suggest that fluid cooling is the main mechanism for the precipitation of tungsten and tin.     

西藏甲玛铜多金属矿床成因研究——来自流体包裹体的证据

甲玛铜多金属矿床位于西藏冈底斯斑岩铜矿带东段,是近年来勘探发现的超大型斑岩-矽卡岩型铜多金属矿床。通过冷热台显微观察与测温、扫描电镜、激光拉曼探针测试,对甲玛矿床各成矿阶段典型矿物的流体包裹体研究表明,成矿流体富含挥发分,临界相均一的流体来自岩浆超临界流体出溶,主成矿阶段具有沸腾包裹体组合特征,有机质包裹体荧光效应显著。显微测温结果显示,岩浆-热液阶段斑岩中石英斑晶的流体包裹体均一温度范围为250～540℃,含石盐子晶高盐度包裹体盐度范围为35～61(wt%)NaCl.eq,中等盐度的临界均一的气液包裹体盐度范围为3～29(wt%)NaCl.eq,岩浆期后热液阶段斑岩、角岩中石英脉的流体包裹体均一温度范围为210～410℃,盐度范围为33～41(wt%)NaCl.eq,与其不混溶共生的中低盐度气液两相流体包裹体盐度范围为5～25(wt%)NaCl.eq。矽卡岩阶段矿物均一温度范围为130～360℃,盐度范围为3～41(wt%)NaCl.eq,从岩浆热液过渡阶段到石英-硫化物阶段均一温度与盐度呈阶梯式降低趋势。斑岩体石英的流体包裹体中含有较多黄铜矿子矿物,岩浆结晶分异过程中已经具成矿元素的富集。激光拉曼探针测试结果显示,成矿早期至主成矿期矿物流体包裹体气相成分主要为CO2、CH4和N2,各阶段矿物流体包裹体气相成分具有继承性。成矿流体为高温度高盐度,富含CO2、CH4的流体。成矿流体主要源于岩浆,后期混有大气降水。当岩浆热液上升时因压力的突然释放造成高温含矿热流体发生减压沸腾,CO2和CH4等气体大量逃逸,导致成矿物质快速沉淀。矿床在成因上与岩浆-热液成矿作用密切相关。