Effect of Pollutants on the Physical and Engineering Behavior of Lime-Treated Marine Clay

Abstract

Rapid industrial growth and increasing population has resulted in the discharge of wastes into the ocean, wastes which ultimately reach the seabed and contaminate the marine sediments. The soil-contaminants interaction, and their associated physico chemical properties with sediments control the behavior of marine clays. Marine clay deposits of low strength and high compressibility are located in many coastal and offshore areas. There are several foundation problems encountered in these weak marine clays. In this study, experimental work was carried out in the laboratory to stabilize soft marine clays using the lime column technique. Also the lime-induced effects on the physical and engineering behavior of marine clays in sulfate-contaminated marine environment was investigated. Consolidation tests indicate that compressibility of the lime-treated samples was reduced to 1/2–1/3 of the virgin soil after 45 days treatment. The test results also suggest that the lime column technique can be conveniently used to improve the behavior of contaminated marine clay deposits.     

Compressibility behaviour of lime-treated marine clay

The necessity to tap natural marine resources from the ocean beds represents a considerable challenge for the construction of offshore structures on weak marine deposits. The use of lime to improve the behaviour of soft clays is not new. The present investigation examines lime-induced changes in the compressibility of marine clay. The test results indicate a reduction of 1/2 to 1/3 in the compressibility of the soil system within 30 to 45 days of treatment. The formation of various cementation compounds due to soil–lime reactions improves the soil characteristics with time. The results encourage the application of lime column and lime injection techniques to improve the engineering behaviour of soft marine clayey deposits. However, one has to be cautious in applying the lime technique to marine clays that contain sodium sulfate.     

Sulphate Attack in Lime-Treated Marine Clay

The use of lime to improve the properties of soft clays is not new. Recently the deep lime mixing technique has been extended to coastal regions for improving the behavior of weak marine clays. But lime treatment technique should be approached carefully for clay containing a high percentage of sodium sulphate. The presence of sulphate in lime-treated clays may result in high swelling due to the formation of the expansive mineral, ettringite. A limited study of lime-treated marine clays has shown a need to further explore the formation of ettringite and its stability with time. In this article, a laboratory investigation was carried out to examine the influence of sodium and calcium sulphates on the behavior of lime column treated marine clay. Scanning electron microscopy (SEM) was used to identify the formation of various reaction products, including ettringite. Test results indicate that the formation of ettringite in the lime-sodium sulphate-clay system adversely affects the engineering behavior of the marine clay, whereas the addition of calcium sulphate significantly improves the engineering characteristics of the soil.     

Sulphate Attack in Lime-Treated Marine Clay

ABSTRACT

The use of lime to improve the properties of soft clays is not new. Recently the deep lime mixing technique has been extended to coastal regions for improving the behavior of weak marine clays. But lime treatment technique should be approached carefully for clay containing a high percentage of sodium sulphate. The presence of sulphate in lime-treated clays may result in high swelling due to the formation of the expansive mineral, ettringite. A limited study of lime-treated marine clays has shown a need to further explore the formation of ettringite and its stability with time. In this article, a laboratory investigation was carried out to examine the influence of sodium and calcium sulphates on the behavior of lime column treated marine clay. Scanning electron microscopy (SEM) was used to identify the formation of various reaction products, including ettringite. Test results indicate that the formation of ettringite in the lime-sodium sulphate-clay system adversely affects the engineering behavior of the marine clay, whereas the addition of calcium sulphate significantly improves the engineering characteristics of the soil.     

Permeability characteristics of lime treated marine clay

An attempt has been made to investigate the lime induced permeability changes in the permeability and engineering behavior of different lime column treated soil systems. Lime columns treated marine clay shows an increase in permeability up to a maximum value of 15–18 times that of untreated soil with time. The shear strength of the treated soil systems show an increment up to 8–10 that of untreated soil within a period of 30–45 days curing. In the case of lime injection systems, the permeability has been increased up to 10–15 times that of untreated soil, whereas the strength of the soil has been higher by 8–10 times that of untreated soil. Further, consolidation tests show a reduction in the compressibility up to 1/2–1/3 of original values. The test results revealed that both lime column and injection techniques could be used to improve the behaviour of underwater marine clay deposits.     

Lime injection technique to improve the behaviour of soft marine clays

Soft marine clay deposits pose several foundation problems and such weak clay deposits have been found both along seacoasts and in offshore areas spread over many parts of the world. We suggest using some chemical injection techniques to improve the engineering behaviour of soft underwater marine clays. A test programme was carried out by injecting lime into a soft marine clay in a test tank. The penetration of lime into the soil was established by taking a number of pH measurements and calcium oxide estimation from samples taken at various radial distances. The improvement in the plasticity characteristics of the soil has been verified by indices tests. Test results indicated the improvement in the strength and reduction in the compressibility of the soil with time. The beneficial changes that occurred in the soil have been attributed to the formation of cementation compounds and these compounds have been identified by using X-ray Diffraction Technique (XRD). The test results show good promise for the use of lime grouting in the treatment of weak marine clayey deposits.     

Physico-chemical and mineralogical studies on cochin marine clays

Large deposits of marine clays are encountered all along the Indian coastal belt. These clays are pleistocene to recent in origin, are considered to be young, and were deposited in a salt or brackish environment. These clays are very soft in consistency with low in-situ strength and high compressibility. The properties of these soil deposits depend mainly on the clay minerals present. In the present investigation, the mineralogical studies of some Cochin marine clays were carried out using XRD technique. The physical and chemical properties of these deposits were also reported. The test results were compared with some earlier reported works on marine clays.     

Lime migration studies in marine clays

Weak marine clay deposits are present in several regions of the world and they are imposing severe problems for structures founded in these deposits. The use of lime to improve the properties of these soft deposits is not new. In the present investigation, a test programme was carried out to study the migration of lime into the marine clay from the installed lime columns and lime slurry injected points. The formation of various cementation compounds due to soil-lime reactions were identified by X-ray diffraction studies and the attributed changes occurring in the engineering properties of the soil systems were studied. The test results indicate that a sufficient amount of lime is diffused into the soil systems with time and the presence of excessive sodium ions in sea water does not retard the effective penetration of lime into the soil. It is suggested that both the lime-column and lime-injection techniques can be conveniently used to improve the behaviour of soft marine clayey deposits. For weak marine clays under large depths of water, the lime-injection technique is better suited.     

Fabric and mineralogical studies on lime treated marine clays

The use of lime to improve the engineering properties of weak marine clays is a common method from the past. Recent studies indicate that the various foundation problems occurred with passage of time for offshore structures due to hostile wave conditions and adverse climatic conditions. Hence, there is an urgent need to improve the engineering properties of these soft deposits using well established ground improvement techniques. In the present investigation, an attempt has been made on two marine clays to investigate the microchanges that occurred at particulate level due to the addition of lime and sodium hydroxide chemicals. The influence of sodium hydroxide additive on the fabric of lime treated marine clays has also been studied using scanning electron microscopy (SEM) technique. The formation of various new reaction products due to soil-lime reactions and their stability in marine environment were also studied and reported using x-ray diffraction (XRD) technique. The test results indicate that lime stabilization is effective for improving the properties of marine clays and the presence of sea water increases the efficiency of lime stabilization.     

A Laboratory model study on the performance of lime pile application for marine soils

In this study, research was conducted to examine the performance of the lime pile application, a deep chemical stabilization method to improve the engineering characteristics of marine soil deposits. By using a laboratory-scale model, the marine soil sample was compacted into soil blocks in circular steel test tanks, with the installation of lime piles in them. An experimental program examined the effect of lime piles on physical and engineering properties of the soil in terms of curing periods and lime pile radial distances. Test results showed that clay fines, linear shrinkage, compressibility, and swelling pressure decreased, while permeability, preconsolidation pressure, and stiffness increased significantly with an increase in curing periods and within a close distance to the lime piles. Also, the electrical resistivity of the treated soils was examined to monitor the changes in their electrical properties. Finally, the correlation between the measured electrical resistivity and swell pressure values of the tested soils at different curing periods suggested that the electrical resistivity values can be used as a monitoring technique for deep chemical treatments of the subsurface soil.     

Pollutants behaviour and temperature effect on chemical piles treated marine clay

Weak marine clay deposits are present in several regions of the world and they are imposing severe problems for structures founded in these deposits. The use of chemicals lime to improve the properties of these soft deposits is not new. In the present investigation, a test programme was carried out to study the influence of temperature on the engineering behaviour of chemical piles treated clays in the presence of sulphate and chloride contaminated marine environment. The formation of various cementation compounds due to soil-lime reactions were identified by X-ray diffraction studies, and the attributed changes occurred in the engineering properties of the soil systems were also brought out. The test results indicated that the increase in temperature has improved the engineering properties of soil significantly.     

Electro-osmotic stabilization of marine clay with chemical piles

Weak marine clay deposits exist all along the seacost of many parts of the world. Due to the poor engineering characteristics of these deposits, they pose several foundation problems to various coastal structures. Because of the high salt content in these deposits, the electro-osmotic technique has been effectively adopted to stabilize these deposits with some inorganic additives. In this investigation, the physico-chemical changes that occurred in a marine clay with various inorganic additives are presented and discussed. The improvement in the strength and plasticity characteristics of the soil have also been studied and reported. The newly formed reaction products arising out of the diffusion of lime are identified using X-ray diffraction technique (XRD). The present study indicates great promise regarding the use of electro-osmotic technique with inorganic additives as a quick remedial measure for the in-situ stabilization of coastal marine clay deposits.     

Experimental Evaluation of Leaching Effects on the Compressibility of Marine Clay and its Strain Rate Dependency

This study investigated how leaching affects compressibility behavior of marine clay and its strain rate dependency based on laboratory tests using three pairs of specimens. Each pair of specimens consisted of leached and unleached samples with identical geotechnical properties except soil salinity. The behavior characteristics of the leached and unleached specimens were evaluated using several series of constant rate-of-strain (CRS) tests with differing strain rates. The results revealed that the compressibility of leached clay increased as its salinity decreased. However, void ratio, Atterberg limits, and preconsolidation pressure in leached samples were lower than those in unleached clay. The increased compressibility and decreased preconsolidation pressure may be induced from a weakening of the interparticle bonds in the leached soil skeleton. The CRS test results with differing strain rates revealed that higher strain rates corresponded with higher levels of effective stress and higher apparent preconsolidation pressure in both leached and unleached clays.     

Enhancing the mechanical properties of marine clay using cement solidification

Abstract

The use of soft clay and dredged marine clays as the construction material is challenging. This is because the high water content, high compressibility and low permeability of the clay causing the instability of ground and structure. This detrimental effect of soft clay can be improved by the cement solidification process, which is relatively cheap and efficient. This paper mainly focuses on the study of improvement on the mechanical behavior of cement mixed marine clay. The soil is reconstituted by using ordinary Portland cement of 5%, 10%, 15% and 20% by its mass. The study reveals that cementation of clay significantly improves the peak and residual strength of soil. Similarly, the primary yield stress of the soil is also improved from 16 to 275?kPa as cement content increases from 5% to 20%, respectively. By using statistical tools, the relationships between various parameters are established, which are very important to define the mechanical behavior of the clay. This study reveals that the yield surface of the solidified marine clay is not a smooth elliptical surface. Rather it is composed of two linear surfaces followed by a log-linear surface which can be modeled by using simple parameters obtained from triaxial tests.     

Gravitational Sedimentation Behavior of Sensitive Marine Ariake Clays

It has been well documented that natural marine Ariake clays are sensitive clays. In this study, extensive data of marine Ariake clays are obtained to investigate the gravitational compression behavior for sensitive clays. Analysis results indicate that the compression behavior of remolded Ariake clays is not different from that of other remolded/reconstituted soils. But natural Ariake clays do not follow the gravitational compression pattern reported by Skempton (1970) for natural sedimentary soils. At a given value of effective overburden pressure, the void ratios of natural Ariake clays are almost independent of liquid limits. Most natural Ariake clays lie above the sedimentation compression line proposed by Burland (1990). When the liquid limit is larger than 90% and the ratio of natural water content over liquid limit ranges 0.8-1.1, the natural Ariake clays lie around the sedimentation compression line. In addition, the natural Ariake clay with higher value of the ratio of natural water content over liquid limit lies above the natural Ariake clay with lower value of the ratio of natural water content over liquid limit. Salt removal is the most probable cause for such a phenomenon.     

Consolidation and creep behaviors of two typical marine clays in China

This paper presents an experimental investigation into the deformation characteristics of two typical marine clays obtained from Dalian and Shanghai, respectively, in China. Three kinds of laboratory tests, i.e. conventional oedometer tests, one-dimensional and triaxial creep tests were carried out. The results obtained from consolidation tests demonstrate linear v e ？ log？ relationships for Shanghai clay at normally consolidated state, while partly or even global non-linearrelationships for Dalian clay. The compression index c C for both clays follows the correlation of Cc=0.009（WL-10）where WL is the liquid limit of soil. The relationship between v log Kv （ Kv is the hydraulic conductivity of soil） and voidratio e is generally linear and the hydraulic conductivity change index kv C can be described by their initial void ratio forboth clays. The secondary compressibility of Dalian clay lies in medium to high range and is higher than that of Shanghaiclay which lies in the range of low to medium. Furthermore, based on drained triaxial creep tests, the stress-strain-timerelationships following Mesri＇s creep equation have been developed for Dalian and Shanghai clays which can predict thelong-term deformation of both clays reasonably well.     

Rheological characteristics and one-dimensional isotache modelling of marine soft clays

Abstract

This paper presents a novel elasto-viscoplastic constitutive formulation based on the isotache concepts and the Nishihara model. Incorporating a novel viscoelastic body to include the delay elastic deformation of marine soft clays under the external load, the proposed model is used to evaluate the theories of consolidation-creep coupling, strain rate dependency and stress relaxation of saturated marine soft clays, and hence, the methodology used to determine the parameters of the model is discussed. Ningbo marine soft clay is selected as an example to interpret the determination of the model parameters on a field scale. A series of conventional oedometer tests are conducted as well. Eventually, we utilize the model to simulate several kinds of rheological tests, including one-dimensional (1-D) long-term compression tests on Ningbo marine soft clays, 1-D constant rate of strain (CRS) tests on Batiscan clays and 1-D stress relaxation tests on Hong Kong marine deposits. These findings indicate good agreement between the computational and experimental results, suggesting the given model can provide reliable forecasts for the rheological characteristics of marine soft clays.     

Engineering behaviour of MICP treated marine clays

Abstract

In the present scenario, with much focus on sustainable development worldwide, Microbially Induced Calcite Precipitation (MICP) is a promising biological soil improvement technology. However, only very limited research is reported on the effectiveness of this technique in marine clays. This paper presents the salient features of an experimental study conducted on two typical marine clays stabilised by MICP. Effectiveness of the technique was evaluated through a series of one-dimensional consolidation tests, unconfined compression tests, and index property determinations. It is found that biostimulation approach is not effective in marine clay; bio-augmentation is needed for soil improvement. Bio-augmentation results in the reduction of liquid limit and plasticity index to about 29% and 47%, respectively for the marine clays. A comparable improvement in volume change behaviour is also observed. There is a marked increase in undrained shear strength, upto about 148%, of MICP treated marine clays at toughness limit water content. Curing is also found to have a significant role in soil improvement. The observed transition in the nature of the tested marine clays from that of fat clay to elastic silt suggests the potential of the proposed approach. An empirical equation is also proposed to predict compression index of MICP treated marine clays.     

A simple experimental method to regain the mechanical behavior of naturally structured marine clays

Quantitative laboratory studies on the structural behavior of natural intact marine clays require a large number of identical natural samples leading to an expensive and challenging task. This study proposes a simple method to reconstruct an artificial structured marine clay as the state of its natural intact clay at both macro and micro levels. For this purpose, the Shanghai marine clay is selected and mixed with low cement contents (1–6%). The clay-cement slurry is mixed in a container with the ice-covered sides at a low temperature about 0 ± 2 °C to postpone the hydration reactions until consolidation began. The purpose of adding cement is to generate the inter-particle bonding and structure in reconstituted samples. Initially, the reconstituted samples are consolidated under the in situ stress of 98 kPa and then under the pre-consolidation pressure of 50 kPa. Mechanical characteristics such as compression index, yield stress, unconfined compression strength, shear strength ratio, and the stress paths from triaxial tests are compared with natural intact clay accordingly. Scanning electron microscope and mercury intrusion porosimetry analyses are also performed to analyze the microstructure of clays for comparison. Furthermore, the proposed method is also examined by using natural intact marine clays of different locations and characteristics.     

Étude isotopique (SrNd) de l'origine des dépôts fins holocènes du littoral atlantique (S-O France)

The fine-grained sediments of the West Gironde mud patch derive mainly from materials supplied via the Gironde estuary. Between 1500 and 1200/1300 years BP and 300/400 years BP and the present day, the Sr isotopic and chemical compositions of the estuarine silty clay inputs are the same. In contrast, these compositions were different during the period 1200/1300 to 300/400 years BP. These variations probably reflect anthropogenic activities including cultivation and agriculture, in the Garonne and Dordogne drainage basins during the medieval period. Modem silty clay sedimentation in the mud flats of the Marennes-Oleron basin and Perthuis Breton is characterised by the occurrence of important quantities (between 40 and 90 % of the total) of detritus that issues from the Gironde estuary. The autochthonous silty clays derived from outcrops of Jurassic green marls and Flandrian deposits are mixed with estuarine allochthonous clays delivered by coastal surface currents. In the Anse de l'Aiguillon, the muds are mainly composed of these autochthonous silty clays. The silty clay infilling of these mud flats has been highly influenced by the development of the oyster and shellfish aquaculture.