An examination of geochemical modelling approaches to tracing sediment sources incorporating distribution mixing and elemental correlations

The identification of sediment sources is fundamental to the management of increasingly scarce water resources. Tracing the origin of sediment with elemental geochemistry is a well‐established approach to determining sediment provenance. Fundamental to the confident apportionment of sediment to their lithogenic sources is the modelling process. Recent approaches have incorporated distributions throughout the modelling process including source contribution terms for two end‐member sources. The shift from modelling source samples to modelling samples drawn from distributions has removed relationships, including potential correlations between elemental concentrations, from the modelling process. Here, we present a novel modelling approach that re‐incorporates correlations between elemental concentrations and models distributions for source contribution terms for multiple source end members. Artificial mixtures, based on catchment sources samples, were created to test the accuracy of this correlated distribution model and also examine modelling approaches used in the literature. The most accurate model incorporates correlations between elements, uses the absolute mixing model difference and does not use any weighting. This model was then applied to identify the sources of sediment in three South East Queensland catchments and demonstrated that Quaternary Alluvium is the most dominant source of sediment in these catchments (μ 44%, σ 12%). This study demonstrates that it is important to understand how different weightings may impact modelling results. Copyright © 2014 John Wiley & Sons, Ltd.     

A preliminary study on sediment flux in the Changjiang Delta during the postglacial period

During the last 7000 years since the Changjiang Delta was formed, how much sediment brought by the Changjiang River remained in the modern Changjiang Delta? And how much sediment was delivered into the sea and adjacent coasts? These are very important que…     

Modelling localized sources of sediment in mountain catchments for provenance studies

A hydrology–sediment modelling framework based on the model Topkapi-ETH combined with basin geomorphic mapping is used to investigate the role of localized sediment sources in a mountain river basin (Kleine Emme, Switzerland). The periodic sediment mobilization from incised areas and landslides by hillslope runoff and river discharge is simulated in addition to overland flow erosion to quantify their contributions to suspended sediment fluxes. The framework simulates the suspended sediment load provenance at the outlet and its temporal dynamics, by routing fine sediment along topographically driven pathways from the distinct sediment sources to the outlet. We show that accounting for localized sediment sources substantially improves the modelling of observed sediment concentrations and loads at the outlet compared to overland flow erosion alone. We demonstrate that the modelled river basin can shift between channel-process and hillslope-process dominant behaviour depending on the model parameter describing gully competence on landslide surfaces. The simulations in which channel processes dominate were found to be more consistent with observations, and with two independent validations in the Kleine Emme, by topographic analysis of surface roughness and by sediment tracing with ¹⁰ Be concentrations. This research shows that spatially explicit modelling can be used to infer the dominant sediment production process in a river basin, to inform and optimize sediment sampling strategies for denudation rate estimates, and in general to support sediment provenance studies. © 2020 John Wiley & Sons, Ltd.     

Suspended‐sediment sources in an urban watershed,Northeast Branch Anacostia River,Maryland

Fine sediment sources were characterized by chemical composition in an urban watershed, the Northeast Branch Anacostia River, which drains to the Chesapeake Bay. Concentrations of 63 elements and two radionuclides were measured in possible land‐based sediment sources and suspended sediment collected from the water column at the watershed outlet during storm events. These tracer concentrations were used to determine the relative quantity of suspended sediment contributed by each source. Although this is an urbanized watershed, there was not a distinct urban signature that can be evaluated except for the contributions from road surfaces. We identified the sources of fine sediment by both physiographic province (Piedmont and Coastal Plain) and source locale (streambanks, upland and street residue) by using different sets of elemental tracers. The Piedmont contributed the majority of the fine sediment for seven of the eight measured storms. The streambanks contributed the greatest quantity of fine sediment when evaluated by source locale. Street residue contributed 13% of the total suspended sediment on average and was the source most concentrated in anthropogenically enriched elements. Combining results from the source locale and physiographic province analyses, most fine sediment in the Northeast Branch watershed is derived from streambanks that contain sediment eroded from the Piedmont physiographic province of the watershed. Sediment fingerprinting analyses are most useful when longer term evaluations of sediment erosion and storage are also available from streambank‐erosion measurements, sediment budget and other methods. Copyright © 2010 John Wiley & Sons, Ltd.     

Suspended sediment balance for the mainstem of Changjiang (Yangtze River) in the period 1964–1985

Suspended sediment dynamics during the period 1964–1985 are examined along the mainstem of Changjiang (Yangtze River). The period represents a basin condition prior to major changes in land management policy and dam building on the river's mainstem. The downstream sediment dynamics reflect basin geology and topography and channel morphology. Sediment exchange within the mainstem was calculated by the development of reach sediment balances that reveal complex temporal and spatial patterns. There is relatively little sediment exchange in the upper, bedrock‐controlled reaches, with systematic increases in the downstream alluvial reaches. Degrading, transfer, and aggrading reaches were identified. Relations between input and output in all reaches were significant but no relation was found between sediment exchange and input/output. Comparison between ‘short‐term’ (22 years) and ‘long‐term’ (52 years) records demonstrates the importance of the record length in studying the suspended sediment dynamics in a large fluvial system. The longer record yielded better correlation and different trends than the shorter record. Sediment transfer (output/input ratio) changes downstream: the dominance of the upstream contributing area in sustaining the appearance of net degradation through most of the river system highlights the importance of reach length on characterisation of suspended sediment dynamics in large fluvial systems. Copyright © 2011 John Wiley & Sons, Ltd.     

Hydrocarbons in surface sediments from the Changjiang (Yangtze River) Estuary, East China Sea

Sedimentary aliphatic (AH) and polycyclic aromatic hydrocarbons (PAHs) were studied in the Changjiang Estuary and the adjacent East China Sea. Total AH ranged from 2.20 to 11.82 μg g⁻¹ and consisted of n-alkanes and a dominant petroleum-related unresolved complex mixture (UCM). Within the n-alkanes, terrestrial plant wax compounds prevailed at nearly all stations. Of the PAHs, biogenic perylene dominated at stations receiving riverine inputs. Anthropogenic PAHs originating from combustion/pyrolysis processes varied from 17 to 157 ng g⁻¹, while fossil PAH concentrations ranged from 42 to 187 ng g⁻¹. Both biogenic and anthropogenic hydrocarbons are primarily derived from riverine discharges and accumulate at shallow-water stations. Distinct phase associations lead, nevertheless, to different sedimentation patterns. Fossil PAHs are enhanced at offshore stations where they are introduced directly by shipping activities. Biomarker fingerprints ascribe their source to Chinese crude oils. The overall levels of anthropogenic hydrocarbons are low compared to relevant areas worldwide and reveal a low/moderate level of hydrocarbon pollution.     

Fingerprinting upland sediment sources: particle size‐specific magnetic linkages between soils,lake sediments and suspended sediments

Accelerated erosion of fine‐grained sediment is an environmental problem of international dimensions. Erosion control strategies and targeting of mitigation measures require robust and quantitative identification of sediment sources. Here, we use magnetic ‘fingerprinting’ to characterize soils, and examine their affinity with and contribution to suspended sediments transported within two subcatchments feeding Bassenthwaite Lake, northwest England. A high‐resolution soil magnetic susceptibility survey was made using a field susceptometer (ZH Instruments, SM400 probe). Combining the spatial and vertical (down‐profile) soil magnetic data, a subset of soil profiles was selected for detailed, laboratory‐based magnetic remanence analyses. The magnetic properties of the catchment soils are highly particle size‐dependent. Magnetic analyses were performed on the 31–63 µm fraction, for particle size‐specific comparison both with the suspended sediments and lake sediments. Fuzzy cluster analysis groups the soil magnetic data into six clusters, apparently reflecting variations in parent material and horizon type, with three magnetically hard soils as unclassified outliers. Examination of the cluster affinity of the soils, suspended sediments and lake sediments indicates that topsoils of the upper Newlands Valley and subsoils around Keskadale Beck are a major source of the Newlands Beck suspended load, and the recent (post‐nineteenth century) sediments in the deep lake basin. Older lake sediments show strong affinity with a small number of the Derwent suspended sediments and one of the Glenderamackin soils. A large number of Derwent suspended sediments show no affinity with any of the soils or lake sediments, instead forming a coherent, discrete and statistically unclassified group, possibly resulting from mixing between the magnetically hard subsoils of the medium to high‐altitude Glenderamackin and Troutbeck areas and softer, lower altitude Glenderamackin soils. The lack of any affinity of these suspended sediments with the lake sediments may indicate deposition along the Derwent flood plain and/or in the shallow delta of Lake Bassenthwaite. Particle size‐specific magnetic fingerprinting is thus shown to be both highly discriminatory and quantitatively robust even within the homogeneous geological units of this catchment area. Such a methodological approach has important implications for small–large scale catchment management where sources of sediment arising from areas with uniform geology have been difficult to determine using other approaches, such as geochemical or radionuclide analyses. Copyright © 2009 John Wiley & Sons, Ltd.     

Effect of reservoir construction on suspended sediment load in a large river system: thresholds and complex response

Dam construction greatly alters the channel boundary of rivers, making the dammed river system a human‐controlled system. Based on hydrometric data in the upper Changjiang River basin, the change in behaviour of sediment transport of some dammed rivers was studied. As a result, some phenomena of threshold and complex response were found. When the coefficient (C_r,a) of actual runoff regulation by reservoirs, defined as the ratio of total capacity of reservoirs to annual runoff input, is smaller than 10%, suspended sediment load at Yichang station, the control station of the Changjiang River, shows a mild decreasing trend. When this coefficient becomes larger than 10%, suspended sediment load decreases sharply. The coefficient of 10% can be regarded as a threshold. The C_r,a of 10% is also a threshold, when the variation of suspended sediment concentration (SSC) with C_r,a at Yichang station is considered. The impacts of reservoir construction can be divided into several stages, including road construction, dam building and closure, water storage and sediment trapping. During these stages, some complex response was identified. At the station below the dam, SSC increases and reaches a maximum, and then declines sharply. This phenomenon was found on the main‐stem and several major tributaries of the upper Changjiang River. In the Minjiang River, where a series of dams were built successively, the response of SSC is more complicated. Copyright © 2010 John Wiley & Sons, Ltd.     

Mechanisms of isotopic control of precipitation in the Yellow River source region

The study of water vapour sources and water cycle patterns in the Yellow River source region is of great significance for ensuring water resource security in the arid and semi-arid regions of northern China. We established a precipitation stable isotope observation system in the Yellow River source region for three consecutive years (2020–2022), systematically analysed the spatial and temporal distribution characteristics of precipitation stable isotopes ²H and ¹⁸O in the Yellow River source region and their interrelationships with environmental factors and topography, and explored the regional water vapour transport pathways by using the HYSPLIT model and combining with the global reanalysis data. The results show that: (1) the δ¹⁸O and δ²H values of precipitation in the Yellow River source region follow the seasonal pattern, with the first half of the year being richer than the second half of the year; (2) the spatial variations of δ¹⁸O of precipitation in the Yellow River source region show a low in the southwest and a high in the northeast; (3) the water vapour source in the source area is basically stable, and the complex transport paths and the cross-effects of the local factors determine the stable isotope characteristics of the water, and the stable isotope characteristics of the water are determined by the cross-effects of the local factors, because the source of the water vapour and the local factors such as the height will not change significantly in the short term. Since the source of water vapour and local elevation factors will not change significantly in the short term, the precipitation pattern in the source area of the Yellow River can be considered to be basically stable.     

Use of composite fingerprints to determine the provenance of the contemporary suspended sediment load transported by rivers

Sediment fingerprinting appears to offer a valuable alternative to direct monitoring for elucidating the provenance of suspended sediment and the relative importance of spatial zones or subcatchments comprising larger (>500 km²) drainage basins. Against this background, a quantitative composite fingerprinting technique, incorporating both statistically verified multicomponent signatures and a multivariate sediment-mixing model, has been employed to determine the spatial origin of contemporary suspended sediment transported from the upper and middle reaches of the River Exe (601 km²) and River Severn (4325 km²) basins, UK. Spatial origin is addressed in terms of the relative contribution from three distinct geological subareas constituting each study basin. The consistency of the composite fingerprinting approach is examined using the estimates for mean and seasonal variations in source area contributions and also a comparison between the results obtained for individual flood events and alternative lines of evidence provided by flood travel times and the spatial distribution of precipitation. It is argued that fingerprinting estimates for sediment provenance are consistent with existing information on suspended sediment yields from different subcatchments within the study basins, although in the Severn, the role of storage and remobilization in producing signature ‘averaging’ may complicate comparison of the fingerprinting data with typical floodwater routing times. Validation represents the greatest problem for the cost–benefit of fingerprinting and scope still exists for further refinement of the procedures involved. © 1998 John Wiley & Sons, Ltd.     

The rare earth element compositions of the Changjiang (Yangtze) and Huanghe (Yellow) river sediments

Thirty-four samples from the Changjiang and Huanghe were analyzed to characterize their rare earth element (REE) compositions. Although REE concentrations in the Changjiang sediments are higher than those of the Huanghe sediments, the former are less variable. Bulk samples and acid-leachable fractions have convex REE patterns and middle REE enrichments relative to upper continental crust, whereas flat patterns are present in the residual fractions. Source rock composition is the primary control on REE composition, and weathering processes play a minor role. Grain size exerts some influence on REE composition, as demonstrated by the higher REE contents of clay minerals in sediments from both rivers. Heavy minerals contribute about 10-20% of the total REE in the sediments. Apatite is rare in the river sediments, and contributes less than 2% of the REE content, but other heavy minerals such as sphene, allanite and zircon are important reservoirs of residual REE fractions. The Fe-Mn oxides phase accounts for about 14% of bulk REE content in the Changjiang sediments, which could be one of the more important factors controlling REE fractionation in the leachable fraction.     

Major element chemistry of sediments from the Darling–Barwon river and its tributaries: implications for sediment and phosphorus sources

In 1991, one of Australia's longest rivers, the Darling–Barwon, experienced one of the world's largest recorded algal blooms. Nearly 1000 km of river were affected. At the time of the bloom phosphorus originating from anthropogenic sources was believed to be the principal cause. In this study we have used major element chemistry to examine the sources of sediment and sediment‐associated phosphorus delivered to the Darling–Barwon River. We show that the sediments are derived primarily from the sedimentary and granitic bedrock areas of the catchment, not the intensively farmed basalt areas. We also show that the sediment currently in transport in the Darling–Barwon does not originate from contemporary upland erosion, but is probably derived from lowland areas of the catchment that contain more weathered material. Phosphorus concentrations in the sediments are consistent with those in natural soils of the region, and evidence from two sediment cores indicates that phosphorus concentrations have not changed significantly in the last 200 years. The implications of these findings for algal growth control strategies are discussed. Copyright © 2000 John Wiley & Sons, Ltd.     

Mineral magnetic characterization of sediment sources from an analysis of lake and floodplain sediments in the catchments of the Old Mill reservoir and Slapton Ley,South Devon,UK

Research on suspended sediment transport in the catchments of the Old Mill reservoir and Slapton Lower Ley, South Devon, has attempted to discriminate changing catchment sources on the basis of downcore variations in the mineral magnetic properties of lake, reservoir and floodplain sediments. Here, we examine these downcore variations and also explore the variability in catchment sources and the influence of topographic controls on mineral magnetic signatures of topsoils and subsoils. Particle size controls on the mineral magnetic signatures are explored by an analysis of a fractionated sediment sample, whilst the possible impact of diagenesis is assessed by an examination of the Mn profiles in the lake and reservoir sediments. From this analysis it is evident that the mineral magnetic signatures of well sorted floodplain deposits are more likely to reflect the particle size composition of the transported material. By contrast, the mineral magnetic record in the sediment of Slapton Ley appears to be most strongly influenced by dissolution of magnetic minerals. The sediment of the Old Mill reservoir provides the only suitable record for the application of a simple mixing model which is developed in order to quantify changes in the relative contribution of topsoil and subsoil through time. The research has important implications for attempting to reconstruct sediment sources in highly eutrophic lakes and emphasizes the uncertainty in the application of simple mixing models. © 1998 John Wiley & Sons, Ltd.     

Strontium and neodymium isotopic compositions of detrital sediment of NS90-103 from South China Sea: Variations and their paleoclimate implication

Strontium, neodymium isotopic compositions and trace elements of the detrital sediments of Core NS90-103 from South China Sea were analyzed. The results show that the⁸⁷Sr/⁸⁶Sr ratios of the detritus during the last glacial range from 0.722 4 to 0.723 0. They are significantly higher than those during the Holocene and the maximum of the last interglacial, which range from 0.721 0 to 0.721 7. This indicates stronger continental weathering during the last glacial. On the other hand, the¹⁴³Nd/¹⁴⁴Nd ratios of these detritus are higher during the last glacial too, similar to the variation of the⁸⁷Sr/⁸⁶Sr ratios. The trace element geochemistry of these detritus indicates that more authigenic sediments, such as ferromanganese, during the last glacial may partly contribute to the increase of¹⁴³Nd/¹⁴⁴Nd ratios. Furthermore, much more detritus from continent of South China to the north of the South China Sea may probably contribute to¹⁴³Nd/¹⁴⁴Nd ratios increase during the last glacial, which was the result of the enhancement of northeast monsoon.     

Downstream variation in bed sediment size along the East Carpathian rivers: evidence of the role of sediment sources

Taking as an example six main rivers that drain the western flank of the Eastern Carpathians, a conceptual model has been developed, according to which fluvial bed sediment bimodality can be explained by the overlapping of two grain size distribution curves of different origins. Thus, for Carpathian tributaries of the Siret, coarse gravel joins an unimodal distribution presenting a right skewness with enhanced downstream fining. The source of the coarse material distributions is autohtonous (by abrasion and hydraulic sorting mechanisms). A second distribution with a sandy mode is, in general, skewed to the left. The source of the second distribution is allohtonous (the quantity of sand that reaches the river‐bed through the erosion of the hillslope basin terrains). The intersection of the two distributions occurs in the area of the 0·5–8 mm fractions, where, in fact, the right skewness (for gravel) and left skewness (for sand) histogram tails meet. This also explains the lack of particles in the 0·5–8 mm interval. For rivers where fine sediment sources are low, the 0·5–8 mm fractions have a higher proportion than the fractions under 1 mm. For the Siret River itself, bed sediment bimodality is greatly enhanced due to the fact that the second mode is more than 25% of the full sample. As opposed to its tributaries, the source of the first mode, of gravel, is allohtonous to the Siret river, generated by the massive input of coarse sediment through the Carpathian tributaries, while the second mode, of the sands, is local. In this case we can also observe that the two distributions of particles of different origins overlap in the 0·5–8 mm fraction domain, creating the illusion of ‘particle lack’ in the fluvial bed sediments. Copyright © 2007 John Wiley & Sons, Ltd.     

鄱阳湖流域典型水源水库水华暴发成因及氮污染溯源

富营养化导致的藻类水华是水源地水库面临的主要生态问题之一。探究水源水库中水华暴发成因并开展污染物溯源研究,是预防水华暴发的重要前提。本文选择鄱阳湖流域赣江水系吉安市某典型水源水库为研究对象,通过分析无水华期和水华暴发期水环境特征及其演变规律,探讨了水华暴发的成因及其促发条件,并针对识别出的主要污染因子,开展了同位素溯源研究。结果表明:(1)水库水华暴发的主要原因为水体总氮浓度显著升高(由0.77 mg/L升高至1.57 mg/L),超出了国际公认的水华暴发总氮阈值(0.5~1.2 mg/L),加之夏季高温(32℃)、水库库容量较低,促进了水华暴发;(2)无水华期,水库表层水总氮主要赋存形态为硝酸盐氮(占比>90%),水华暴发期,表层水总氮主要赋存形态由硝酸盐氮转变为有机氮(占比~86%),氮赋存形态转化的主要原因为藻类同化吸收作用;(3)硝酸盐氮、氧同位素示踪结果表明,水库硝酸盐氮主要来源于上游稻田流失的氮肥(负荷贡献率64.45%),其次为上游山区土壤氮流失(14.08%)、大气沉降(12.35%)和农村生活污水(9.12%),因此水库总氮优先控制污染源为上游稻田流失的氮肥。     

Isotope mixing models require individual isotopic tracer content for correct quantification of sediment source contributions

The use of isotopic tracers for sediment source apportionment is gaining interest with recent introduction of compound‐specific stable isotope tracers. The method relies on linear mixing of source isotopic tracers, and deconvolution of a sediment mixture initially quantifies the contribution of sources to the mixture's tracer signature. Therefore, a correction to obtain real sediment source proportions is subsequently required. As far as we are aware, all published studies to date have used total isotopic tracer content or a proxy (e.g., soil carbon content) for this post‐unmixing correction. However, as the relationship between the isotopic tracer mixture and the source mixture is different for each isotopic tracer, post‐unmixing corrections cannot be carried out with one single factor. This contribution presents an isotopic tracer model structure—the concentration‐dependent isotope mixing model (CD‐IMM)—to overcome this limitation. Herein, we aim to clarify why the “conventional” approach to converting isotopic tracer proportions to source proportions using a single factor is wrong. In an initial mathematical assessment, error incurred by not using CD‐IMM (NCD‐IMM) in unmixing two sources with two isotopic tracers showed a complex relation as a function of relative tracer contents. Next, three artificial mixtures with different proportions of three soil sources were prepared and deconvoluted using ¹³C of fatty acids using CD‐IMM and NCD‐IMM. Using NCD‐IMM affected both accuracy (mean average error increased up to a threefold compared with the CD‐IMM output) and precision (interquartile range was up to 2.5 times larger). Finally, as an illustrative example, the proportional source contribution reported in a published study was recalculated using CD‐IMM. This resulted in changes in estimated source proportions and associated uncertainties. Content of isotopic tracers is seldom reported in published work concerning use of isotopic tracers for sediment source partitioning. The magnitude of errors made by miscalculation in former studies is therefore difficult to assess. With this contribution, we hope the community will acknowledge the limitations of prior approaches and use a CD‐IMM in future studies.     

长江三角洲顶部冰后期地层的沉积特征

钻探证实,镇江市谏壁镇长江北岸高桥镇北部埋藏硬粘土层,之上为冰后期松散沉积物。沉积物主要为粉砂、粘土质粉砂、砂泥互层,中部局部夹含细砾中细砂,顶部见淤泥质粘土;夹数十层植物炭屑层;以水平纹理为主,局部见小型交错层理、波状层理。表明冰后期以来该地处于水动力较弱的河湖环境,为多期湖沼相沉积夹汉道河流相沉积,局部有海相沉积物加入。根据碳化植物碎屑^14C年龄,推测冰后期底界年龄约13000aBP,海侵到达该地的时间约为9000aBP,海侵最高位时间约为6500aBP。冰后期平均沉积速率约为4．9m／ka,湖沼相3．4～6m／ka,河流相10～15m／ka。对全新统的底界年龄和海相层的埋藏深度进行了讨论。     

紫坪铺水库沉积物Sr同位素及元素组成变化对2008年汶川大地震的响应

2008年5月12日里氏7.9级汶川大地震引发了超过56000多个山体滑坡,在龙门山地区产生巨量的碎屑物质,极大地影响了流域的地表过程.然而,地震对河流碎屑物质组成及沉积过程的改变却知之甚少.紫坪铺水库超高沉积速率（平均74 cm/a）的沉积物完整记录了汶川地震前后的沉积过程,为研究2008年汶川地震对流域地表物质搬运及沉积物组成的影响提供了宝贵的素材.本研究测试了汶川地震前后紫坪铺水库沉积物的Sr同位素以及元素组成,结果表明其在地震之后均发生了显著变化.震后沉积物⁸⁷Sr/⁸⁶Sr与Rb/Sr比值同步降低,并且和沉积物化学蚀变指数（CIA）呈正相关性,反映了地震滑坡导致的新鲜物质对沉积物的贡献,特别是地震后强径流的2010—2011年.地震前后沉积物组成的差异性,为利用沉积物反演水文气候和构造事件及其环境效应提供了基础和潜在指标.