Modeling of mineralogical composition,density and elastic wave velocities in anhydrous magmatic rocks

We use the technique of direct minimization of the Gibbs free energy of the 8-component (K₂O-Na₂O-Fe₂O₃-FeO-CaO-MgO-Al₂O₃-SiO₂) multiphase system in order to determine the equilibrium mineral assemblages of rocks of different bulk chemical compositions equilibrated at various P-T conditions. The calculated modal compositions of rocks and experimental data on elastic moduli of single crystals are then used to calculate densities and isotropic elastic wave velocities of rocks together with their pressure and temperature derivatives. Sufficient accuracy of the calculations is confirmed by comparison with experimental data on the gabbro-eclogite transformation and precise ultrasonic measurements of elastic wave velocities in a number of magmatic and metamorphic rocks.We present calculated phase diagrams with isolines of density, elastic wave velocities, and their pressure and temperature derivatives for several anhydrous magmatic rocks, from granite to lherzolite. Density and elastic properties of rocks are controlled by their chemical compositions, especially the SiO₂ content, and by P-T of equilibration, and they increase with pressure due to mineral reactions changing mineral assemblages from plagioclase-bearing and garnet-free to garnetbearing and plagioclase-free. TheV _p -density correlation is high, and shows two clear trends: one for iron-poor ultramafic rocks and another for all the other rocks considered. Mineral reactions, which occur at high pressures, changeV _p and density of anhydrous magmatic rocks following the well-known Birch (or a similar) law.Felsic, intermediate and mafic rocks can be well distinguished in theV _p -V _p /V _s - diagram, although their values ofV _p can be close to one another. TheV _p -V _p /V _s -density diagrams together with calculated phase diagrams can serve as efficient instruments for petrologic interpretation of seismic velocities.     

V p /V s anomalies in dilatant rock samples

Summary In a series of triaxial experiments we have measuredV _p ,V _s and volumetric strain simultaneously in dilating dry and saturated rocks. For the first time these data permit quantitative comparison of seismic velocities or their ratio and dilatant volumetric strain. In air-dry samplesV _p /V _s decreases by a few per cent at strains of 10^–3; in saturated materials with high pore pressure,V _p /V _s increases by a comparable amount. Decreases in seismic velocity ratio are difficult to generate in initially saturated rocks even with low pore pressures and at strain rates of 10^–4/sec. A liquid-vapor transition will not produce a significant drop inV _p /V _s . If dilatancy and fluid flow are responsible for seismic travel time anomalies prior to earthquakes, our results suggest that such anomalies will occur only in regions where pore fluid source to sink dimensions are of the order of 10 km or more, or in regions where the rocks are not saturated to begin with.     

Controls on sonic velocity in carbonates

Compressional and shear-wave velocities (V _p andV _s) of 210 minicores of carbonates from different areas and ages were measured under variable confining and pore-fluid pressures. The lithologies of the samples range from unconsolidated carbonate mud to completely lithified limestones. The velocity measurements enable us to relate velocity variations in carbonates to factors such as mineralogy, porosity, pore types and density and to quantify the velocity effects of compaction and other diagenetic alterations.Pure carbonate rocks show, unlike siliciclastic or shaly sediments, little direct correlation between acoustic properties (V _p andV _s) with age or burial depth of the sediments so that velocity inversions with increasing depth are common. Rather, sonic velocity in carbonates is controlled by the combined effect of depositional lithology and several post-depositional processes, such as cementation or dissolution, which results in fabrics specific to carbonates. These diagenetic fabrics can be directly correlated to the sonic velocity of the rocks.At 8 MPa effective pressureV _p ranges from 1700 to 6500 m/s, andV _s ranges from 800 to 3400 m/s. This range is mainly caused by variations in the amount and type of porosity and not by variations in mineralogy. In general, the measured velocities show a positive correlation with density and an inverse correlation with porosity, but departures from the general trends of correlation can be as high as 2500 m/s. These deviations can be explained by the occurrence of different pore types that form during specific diagenetic phases. Our data set further suggests that commonly used correlations like Gardner's Law (V _p-density) or the time-average-equation (V _p-porosity) should be significantly modified towards higher velocities before being applied to carbonates.The velocity measurements of unconsolidated carbonate mud at different stages of experimental compaction show that the velocity increase due to compaction is lower than the observed velocity increase at decreasing porosities in natural rocks. This discrepancy shows that diagenetic changes that accompany compaction influence velocity more than solely compaction at increasing overburden pressure.The susceptibility of carbonates to diagenetic changes, that occur far more quickly than compaction, causes a special velocity distribution in carbonates and complicates velocity estimations. By assigning characteristic velocity patterns to the observed diagenetic processes, we are able to link sonic velocity to the diagenetic stage of the rock.     

Radioactive heat production in rocks and its relation to other petrophysical parameters

Summary Radioactive heat productionA is a scalar and isotropic petrophysical property independent of in situ temperature and pressure. Its value is usually expressed in HGU units (1 HGU=10^–13 cal/cm³ sec) and depends on the amounts of uranium, thorium and potassium.A varies with rock type over several orders of magnitude and reflects the geochemical conditions during rock formation (magmatic differentiation, sedimentation or metamorphism).In order to assign realistic thermal parameters to deeper-seated rocks correlations with seismic velocity (which can be determined from the surface) have been looked for. In the range characteristic for crystalline rocks of the crust (5–8 km/sec)A is strongly correlated with density and compressional wave velocityv _p:A decreases with increasingv _p orp. From this relationship it is now possible to estimate heat production values for any particular layer of a crustal section from measured seismic velocities. Contrary to earlier belief there is, as shown by experimental determinations, no correlation between heat productionA and thermal conductivityK in igneous and metamorphic rocks. In sediments however, especially in sand/shale sequences, a correlation betweenK andA is most likely: increasing clay mineral content, characterized by increasingA, causes the decrease ofK in these rocks.Contribution No. 111, Institute of Geophysics, Swiss Federal Institute of Technology, Zurich, Switzerland.     

The influence of dry and water saturated cracks on seismic velocities of crustal rocks - A comparison of experimental data with theoretical model

The pressure dependence of P- and S-wave velocities, velocity anisotropy, shear wave splitting and crack-porosity has been investigated in a number of samples from different crustal rock types for dry and wet (water saturated) conditions. At atmospheric pressure, P-wave velocities of the saturated, low-porosity rocks (< 1%) are significantly higher than in dry rocks, whereas the differences for S-wave velocities are less pronounced. The effect of intercrystalline fluids on seismic properties at increased pressure conditions is particularly reflected by the variation of the Poisson's ratio because P-wave velocities are more sensitive to fluids than S-wave velocities in the low-porosity rocks. Based on the experimental data, the respective crack-density parameter (), which is a measure of the number of flat cracks per volume unit contained within the background medium (crack-free matrix), has been calculated for dry and saturated conditions. There is a good correlation between the calculated crack-densities and crack-porosities derived from the experimentally determined volumetric strain curves. The shear wave velocity data, along with the shear wave polarisation referred to a orthogonal reference system, have been used to derive the spatial orientation of effective oriented cracks within a foliated biotite gneiss. The experimental data are in reasonable agreement with the self consistent model of O'Connell and Budiansky (1974). Taking the various lithologies into account, it is clear from the present study, that combined seismic measurements ofV _p andV _s , using theV _p V _s -ratio, may give evidence for fluids on grain boundaries and, in addition, may provide an estimate on the in-situ crack-densities.     

Combined geothermal-geophysical models of the earth's crust and upper mantle for the European continent

An attempt is made to obtain a combined geophysical model along two regional profiles: Black Sea— White Sea and Russian Platform—French Central Massif. The process of the model construction had the following stages: 1. The relation between seismic velocity (V_p, km/s) and density (σ, g/cm³) in crustal rocks was determined from seismic profiles and observed gravity fields employing the trial and error method. 2. Relations between heat production HP (μW/m³), velocity and density were established from heat flow data and crustal models of old platforms where the mantle heat flow HF_M is supposed to be constant. The HF_M value was also determined to 11 ± 5 mW/m². 3. A petrological model of the old platform crust is proposed from the velocity-density models and the observed heat flow. It includes 10–12 km of acid rocks, 15–20 km of basic/metamorphic rocks and 7–10 km of basic ones. 4. Calculation of the crustal gravity effects; its substraction from the observed field gave the mantle gravity anomalies. Extensively negative anomalies have been found in the southern part of Eastern Europe (50–70 mgal) and in Western Europe (up to 200 mgal). They correlate with high heat flow and lower velocity in the uppermost mantle. 5. A polymorphic advection mechanism for deep tectonic processes was proposed as a thermal model of the upper mantle. Deep matter in active regions is assumed to be transported (advected) upwards under the crust and in its place the relatively cold material of the uppermost mantle descends. The resulting temperature distribution depends on the type of endogeneous regime, on the age and size of geostructure. Polymorphic transitions were also taken into account.     

Vp and Vp/Vs structures in the crust and upper mantle of the Taiwan region, China

A tomographic study of the V _p and V _p/V _s structures in the crust and upper mantle beneath the Taiwan region of China is conducted by simultaneous inversion of P and S arrival times. Compared with the previous tomographic results, the spherical finite difference technique is suitable for the strong heterogeneous velocity structure, and may improve the accuracy in the travel time and three-dimensional ray tracing calculations. The V _p and V _p/V _s structures derived from joint inversion and the relocated earthquakes can provide better constraints for analyzing the lateral heterogeneity and deep tectonic characters in the crust and upper mantle. Our tomographic results reveal significant relations between the seismic wavespeed structure and the tectonic characters. In the shallow depth, sedimentary basins and orogen show distinct wavespeed anomalies, with low V _p, high V _p/V _s in basins and high V _p, low V _p/V _s in orogen. As the suture zone of Eurasian Plate and Philippine Sea Plate, Longitudinal Valley is characterized by a significant high V _p/V _s anomaly extending to the middle-lower crust and upper mantle, which reflects the impact of rock cracking, partial melting, and the presence of fluids. In the northeast Taiwan, the V _p, V _p/V _s anomalies and relocated earthquakes depict the subducting Philippine Sea Plate under the Eurasian Plate. The high V _p of oceanic plate and the low V _p, high V _p/V _s atop the subducted oceanic plate extend to 80 km depth. Along the east-west profiles, the thickness of crust reaches 60 km at the east of Central Range with eastward dipping trend, which reveals the eastward subduction of the thickened and deformed crust of the Eurasian continental plate. Supported by Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. KZCX3-SW-234-2), National Basic Research Program of China (Grant No. 2007CB411701), National High Technology Research and Development Program of China (Grant No. 2006AA09A101-0201) and National Natural Science Foundation of China (Grant Nos. 40804016, 40704013)     

Solar cycle and seasonal variations in F-region vertical drifts over Kodaikanal,India

Measurements of the changes in phase path of F-region reflections at normal incidence at Kodaikanal (77° 28′E, 10° 14′N, dip 3°N) from February 1991 to February 1993 are used to determine the variation of the equatorial evening F-region vertical drifts (V_z) with season, solar and magnetic activity. It is found that on average, at Kodaikanal, the post-sunset peak in V_z(V_zp) is higher in equinox and local winter months than in local summer. The day-to-day variability in V_zp is highest in summer and lowest in winter. This seasonal trend persists even on magnetically quiet days (A_p\leq14). V_zp is found to increase with 10.7 cm solar flux in all three seasons but tends to saturate for large flux values (>230 units) during local summer and winter months. Magnetic activity [represented by A_p as well as the time-weighted accumulations of a_p and a_p ()] does not seem to have any statistically significant effect on V_zp, except during equinoctial months of moderate solar activity, when V_zp decreases as magnetic activity increases.     

Tomographic imaging of seismic velocity structure in and around the Onikobe volcanic area, northeastern Japan: implications for fluid distribution

We estimated three-dimensional P- (V_p) and S-wave velocity (V_s) and V_p/V_s structures in and around the Onikobe volcanic area, northeastern Japan, by local travel time tomography. We used travel time data from source and receiver pairs located within and outside the study area, which plays an important role in obtaining the optimum ray coverage and in elucidating the deeper structure more accurately. Detailed information on deeper structures is essential for imaging the complete volcanic system from the magmatic source zone through areas of shallow hydrothermal circulation. More than 50 000 travel time data for the P-waves and 35 000 for the S-waves were used to image the velocity structure. Our results show the following dominant features: (1) two conduits in the upper crust with low V_p and low V_s indicative of H₂O-rich fluid pathways: one lying beneath Naruko volcano, the other beneath the focal area of the 1962 Northern Miyagi earthquake (M6.5); (2) an underlying broad region in the lower crust with low V_p, low V_s and high V_p/V_s, suggestive of a zone of partial melt, from which the fluids in (1) are derived; and (3) low V_p/V_s areas near the surface of the Sanzugawa and Onikobe calderas, suggesting a diffuse vapor-saturated cap.     

Velocities of compressional and shear waves in limestones

Carbonate rocks are important hydrocarbon reservoir rocks with complex textures and petrophysical properties (porosity and permeability) mainly resulting from various diagenetic processes (compaction, dissolution, precipitation, cementation, etc.). These complexities make prediction of reservoir characteristics (e.g. porosity and permeability) from their seismic properties very difficult. To explore the relationship between the seismic, petrophysical and geological properties, ultrasonic compressional‐ and shear‐wave velocity measurements were made under a simulated in situ condition of pressure (50 MPa hydrostatic effective pressure) at frequencies of approximately 0.85 MHz and 0.7 MHz, respectively, using a pulse‐echo method. The measurements were made both in vacuum‐dry and fully saturated conditions in oolitic limestones of the Great Oolite Formation of southern England. Some of the rocks were fully saturated with oil. The acoustic measurements were supplemented by porosity and permeability measurements, petrological and pore geometry studies of resin‐impregnated polished thin sections, X‐ray diffraction analyses and scanning electron microscope studies to investigate submicroscopic textures and micropores. It is shown that the compressional‐ and shear‐wave velocities (V_p and V_s, respectively) decrease with increasing porosity and that V_p decreases approximately twice as fast as V_s. The systematic differences in pore structures (e.g. the aspect ratio) of the limestones produce large residuals in the velocity versus porosity relationship. It is demonstrated that the velocity versus porosity relationship can be improved by removing the pore‐structure‐dependent variations from the residuals. The introduction of water into the pore space decreases the shear moduli of the rocks by about 2 GPa, suggesting that there exists a fluid/matrix interaction at grain contacts, which reduces the rigidity. The predicted Biot–Gassmann velocity values are greater than the measured velocity values due to the rock–fluid interaction. This is not accounted for in the Biot–Gassmann velocity models and velocity dispersion due to a local flow mechanism. The velocities predicted by the Raymer and time‐average relationships overestimated the measured velocities even more than the Biot model.     

Modelling shear waves in OBS data from the Vøring basin (Northern Norway) by 2-D ray-tracing

Three component recordings from an array of five ocean bottom seismographs in the northwestern part of the Vøring basin have been used to obtain a 2-D shear-wave (S-wave) velocity-depth model. The shear waves are identified by means of travel-time differences compared to the compressional (P) waves, and by analyzing their particle motions. The model has been obtained by kinematic (travel-time) ray-tracing modelling of the OBS horizontal components.The shear-wave modelling indicates that mode conversions occur at several high velocity interfaces (sills) in the 4–10 km depth range, previously defined by a compressional-wave velocity-depth model using the same data set.An averageV _p /V _s ratio of 2.1 is inferred for the layers above the uppermost sill, indicative of both poorly consolidated sediments and a low sand/shale ratio. A significant decrease in theV _p /V _s ratio (1.7) below the first sill may in part be atributed to well consolidated sediments, and to a change in lithology to more sandy sediments. This layer is interpreted to lie within the lower Cretaceous sequence. At 5–10 km depthV _p /V _s ratios of 1.85 indicate a lower sand/shale ratio consistent with the expected lithologies. The averageV _p /V _s ratio inferred for the crust is 1.75, which is consistent with values obtained north of Vøring, in the Lofoten area. An eastward thinning of the crystalline basement is supported by the shear-wave modelling.     

Resistive instabilities in rapidly rotating fluids: Linear theory of the convective modes

Abstract

This paper analyzes the linear stability of a rapidly-rotating, stratified sheet pinch in a gravitational field, g, perpendicular to the sheet. The sheet pinch is a layer (O ? z ? d) of inviscid, Boussinesq fluid of electrical conductivity σ, magnetic permeability μ, and almost uniform density ρ _o; z is height. The prevailing magnetic field. B _o(z), is horizontal at each z level, but varies in direction with z. The angular velocity, Ω, is vertical and large (Ω ? V_A/d, where V_A = B₀√(μρ₀) is the Alfvén velocity). The Elsasser number, Λ = σB² ₀/2Ωρ₀, measures σ. A (modified) Rayleigh number, R = gβd²/ρ₀V² _A, measures the buoyancy force, where β is the imposed density gradient, antiparallel to g. A Prandtl number, P_K = μσK, measures the diffusivity, k, of density differences.     

The degree of metamorphism of organic matter in sedimentary rocks as a paleo-geothermometer,applied to the Upper Rhine Graben

The subsidence of sedimentary layers implies increasing temperature downwards within the sedimentary column, so that the degree of coalification of organic matter increases continually. Apart from temperature, the slowly reacting chemical compounds of the organic matter strongly depend on time, too.It is shown that the coal rank is proportional to the integral of temperature and time of burial (t) for the Tertiary sedimentary rocks of the Upper Rhine Graben. This relationship is used to calculate paleogeothermal gradients (gradT) for some boreholes in the Upper Rhine Graben, from which the rate of burial during geological history (z(t)) is known. The degree of coalification is measured by its mean optical reflectivity (R _m), so that the relationship between coalification and geothermal history isR _m ² gradT z(t) dt.The results show high heat flow during Lower Tertiary and a decrease during Upper Tertiary at some locations of the Upper Rhine Graben. The recent high heat flow is not detectable in coalification. The young thermal anomaly is perhaps caused by ascending pore fluid and/or by heat conduction from a heat source in the lower crust.     

Vp‐Vs relationship and amplitude variation with offset modelling of glauconitic greensand‡

The relationship between V_p and V_s may be used to predict V_s where only V_p is known. V_p/V_s is also used to identify pore fluids from seismic data and amplitude variation with offset analysis. Theoretical, physical, as well as statistical empirical V_p‐V_s relationships have been proposed for reservoir characterization when shear‐wave data are not available. In published work, the focus is primarily on the V_p‐V_s relationship of quartzitic sandstone. In order to broaden the picture we present V_p‐V_s relationships of greensand composed of quartz and glauconite by using data from the Paleocene greensand Nini oil field in the North Sea. A V_p‐V_s relationship derived from modelling is compared with empirical V_p‐V_s regressions from laboratory data as well as from log data. The accuracy of V_s prediction is quantified in terms of root‐mean‐square error. We find that the V_p‐V_s relationship derived from modelling works well for greensand shear‐wave velocity prediction. We model the seismic response of glauconitic greensand by using laboratory data from the Nini field. Our studies here reveal that brine‐saturated glauconitic greensand can have a similar seismic response to that from oil‐saturated quartzitic sandstone and that oil‐saturated strongly cemented greensand can have a similar amplitude variation with offset response to that from brine‐saturated weakly cemented greensand.     

Effect of soil stiffness in the attenuation of Rayleigh-wave motions from field measurements

The amplitude of vertical ground surface vibrations generated by impact tests on the ground surface was measured at various radial distances from the point of impact at locations of Greece. The results of measurements were analyzed in the frequency domain (in the range from 0–100 Hz) and the attenuation characteristics of soil materials were studied in terms of a frequency-independent attenuation coefficient, a₀, of the empirical Bornitz equation. The aim of the study was to investigate the effect of soil stiffness (expressed by the value of low-amplitude shear wave velocity of soil, V_SO) on the value of attenuation coefficient, a₀. Values of V_SO for the tested soils were estimated by applying the methodology of Spectral Analysis of Surface Waves (SASW) technique and utilizing the surface vibration data. An empirical relationship between a₀ and V_SO1 (V_SO1 is the representative value of V_SO for the soil profile up to a depth of one wavelength) was established for values of V_SO1 ranging from 140 to 1000 m/s. A similar relationship in terms of the low-amplitude shear modulus of soil, G_O1, was also established by converting the V_SO1 values to G_O1 values. The experimental results were compared to values reported in the literature for comparable soil types and frequencies of vibration and a reasonable agreement was found to exist. The proposed empirical relationship can be utilized in many practical applications of soil dynamics requiring the knowledge of the attenuation rate of Rayleigh waves with distance in various types of soils.     

CrustalP-wave velocity and velocity-ratio study in northeast India by a microearthquake survey

The upper crustal (20 km)P-wave velocity beneath the Shillong Plateau and Nowgong area has been studied by the time-distance plot method. TheP-arrival data of the shallow (20 km) microearthquakes from three temporary networks are used, and the average velocity is found to be 5.55 km/s. The velocity ratio (V _p /V _s ) for the upper crust (0–20 km) as well as for the lower crust (21–40 km) are determined by the Wadati-plot method and station-by-station method. The average value obtained by the two methods is compatible; theV _p /V _s ranges between 1.74 to 1.76. A generalized seismic velocity model of the area is suggested by this study, which has been very useful for microearthquake location.     

Use of mode-converted waves in marine seismic data to investigate the lithology of the sub-bottom sediments in Isfjorden,Svalbard

The compression wavefield is efficiently converted to shear-wave energy at post-critical angles in areas of high impedance contrast at the sea floor. We have analysed mode-converted shear waves in a data set acquired with a hybrid marine/land geometry in Isfjorden, Svalbard. Through a kinematic 2D ray-tracing modellingV _p/V_s ratios for part of the uppermost 5km of the crust are obtained. Low values (V _p /V _s =1.65) are tentatively associated with the section of Devonian sandstones which appears to attain a minimum thickness of 1.5km below 3 km depth about 10km west of Kapp Thorden.     

AN ULTRASONIC PROFILING INVESTIGATION ON SOME FRESH AND WEATHERED GRANITES OF HYDERABAD,INDIA*

The ultrasonic profiling method of measuring the compressional and shear wave velocities in cylindrical rock samples is extended to measurements in some weathered and fresh granite blocks collected from the Hyderabad (India) region. This possibility of the method provides a means of investigating the elastic properties of the less compact rocks, of which the near-surface formations are particularly important. In this article the important parts of the ultrasonic profiling instrument developed are described and the relevant aspects of the seismic wave fields and identification of the individual waves in the wavetrain responses to longitudinal excitation are considered. Compressional, shear and surface (Rayleigh) wave velocities in some fresh and weathered granites are detailed. The compressional velocities range from 4.8 km/s to 5.5 km/s in fresh granites and lie between 1.1 km/s and 2.5 km/s in weathered granites. Young's modulus and Poisson's ratios computed from the measured velocities are also presented. An empirical relation of the form log E= 4.27 + 2.11 log V_p between Young's modulus E and compressional velocities V_p in the fresh granites studied is deduced. The versatility of the approach is thus demonstrated.     

Effective medium theory and multiple linear regression-based velocity estimation in syn-rift clastic sequence of the Krishna–Godavari basin,India

An inclusion model, based on the Kuster–Toksöz effective medium theory along with Gassmann theory, is tested to forward model velocities for fluid-saturated rocks. A simulated annealing algorithm, along with the inclusion model, effectively inverts measured compressional velocity (V_P) to achieve an effective pore aspect ratio at each depth in a depth variant manner, continuously along with depth. Early Cretaceous syn-rift clastic sediments at two different depth intervals from two wells [well A (2160–2274 m) and well B (5222–5303 m)], in the Krishna–Godavari basin, India, are used for this study. Shear velocity (V_S) estimated using modelled pore aspect ratio offers a high correlation coefficient (>0.95 for both the wells) with measured data. The modelled pore aspect ratio distribution suggests the decrease in pore aspect ratio for the deeper interval, mainly due to increased effective vertical stress. The pore aspect ratio analysis in relation to total porosity and volume of clay reveals that the clay volume has insignificant influence in shaping the pore geometry in the studied intervals. An approach based on multiple linear regression method effectively predicts velocity as a linear function of total porosity, the volume of clay and the modelled pore-space aspect ratio of the rock. We achieved a significant match between measured and predicted velocities. The correlation coefficients between measured and modelled velocities are considerably high (approximately 0.85 and 0.8, for V_P and V_S, respectively). This process indicates the possible influence of pore geometry along with total porosity and volume of clay on velocity.     

The spatial and temporal changes inV p /V s before strong earthquakes in Kamchatka

A method was developed to obtain from a signal station the spatial and temporal distribution ofV _p /V _s ratios before earthquakes of magnitude>6. It was shown thatV _p /V _s values strongly depend upon the relative positions of the stations, the future large earthquake and the foci of the smaller earthquakes used forV _p /V _s determination. The appearance of a zone of anomalousV _p /V _s values with linear dimensions of the order of 100 km was noted at least 4 years before a deep earthquake of magnitude 7. Similar size anomalous zones were detected one year before some magnitude 6 earthquakes. V _p /V _s values decreased by a small but distinct amount during this time. Additionally, local short term minima inV _p /V _s ratios were observed some months before the major event. The epicenters of the large earthquakes were located within the 100 km size zone where the gradients of theV _p /V _s field were largest.