首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 46 毫秒
1.
李国会  马光祖 《岩矿测试》1994,13(4):264-268
研究工作表明在粉末压片试样中,由于不同价态的硫所发射的X射线谱发生位移,Ka/kβ谱线强度比不一致;以及粉末压片-XPE测定硫的结果随保存时间的增长发生变化,导致了分析地质试样中全硫时的测定误差,提出采用熔融粉末压片法制样,试样中硫全面部转为在硫酸盐硫,克服了谱线位移和试样不稳定问题,提高了全硫分析结果的准确性。  相似文献   

2.
钒的Kβ谱带精细结构的测定及钒的价态分析   总被引:3,自引:2,他引:1  
孙伟莹  谭秉和 《岩矿测试》1998,17(2):107-111
用普通X射线荧光光谱仪测定了钒的氧化物、钒酸盐及含钒混合物中V的Kβ谱线,借助一套有效的谱处理程序,获得了有关Kβ谱线精细结构的谱峰参数,证实了谱线轮廓(Kβ″峰逐渐显著,Kβ5、Kβ″向高能端位移,Kβ5与Kβ1,3的分开趋势,Kβ1,3半峰宽发生变化)及谱峰参数(Kβ5峰能量,Kβ5与Kβ1,3能量差,Kβ5与Kβ1,3及Kβ″与Kβ1,3的强度比,以及Kβ5和Kβ1,3的不对称因子)与V的氧化数变化呈很强的相关性及规律性变化。  相似文献   

3.
谭秉和  张香荣 《岩矿测试》1994,13(3):169-174
在普通的XRF光谱仪上测定金属锰,氧化锰、锰的化合物中MnKβ发射谱带,经谱数据处理获得了谱线的轮廓线及谱峰参数(峰位,峰高,峰宽,峰宽,峰函数比例因子,不对称因子);研究了谱参数与价态间的关系。结果表明MnKβ谱带结构与化合价,氧化数,化学键及配位状况有关,利用所得出的规律对太平洋锰结核的价态作了定性测定,并用谱峰分解法对Mn3O4试样进行化学价态定量分析的浓度量,得到满意的结果。  相似文献   

4.
针对白云岩主次量组分同时测定中存在的问题,采用熔融玻璃片和粉末压片法制样(运用熔片-压片法相结合),选用有关的国家一级标准物质和省二级标准物质,以经验α系数法和散射线内标法校正元素谱线重叠干扰和基体效应,采用X射线荧光光谱法对白云岩样品中的氧化钙、氧化镁、氧化铝、二氧化硅、磷、氧化锰、全三氧化二铁和硫8个组分进行测定,分析结果与标准值或化学值吻合,各组分12次重复测定的相对标准偏差小于10%。方法操作简便、快捷。  相似文献   

5.
X射线能地测定土壤中7种主次量元素   总被引:3,自引:0,他引:3  
黄近丹 《岩矿测试》1999,18(4):308-310
采用粉末样品压片制样,土壤标准物质以及人工合成标样为标准,用X射线荧光能谱仪对土壤试样中的Si、K、ca、Ti、Mn、Fe、Sr7种、次量元素进行测定。讨论了基体疚及校正等问题。方法经土壤标样分析验证,其结果与标准值符合较好,方法的精密度《3%  相似文献   

6.
X射线荧光光谱法直接测定碳酸盐岩石中主次痕量元素   总被引:12,自引:10,他引:12  
采用粉末样品压片制样,碳酸盐岩石标样及人工合成标样为标准,使用理论α系数及散射线内标法校正元素的吸收_增强效应,用X射线光谱仪对碳酸盐岩石试样中的Na、Mg、Al、Si、P、S、Cl、K、Ca、Sc、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Ga、Rb、Sr、Y、Zr、Nb、Ba、Pb、La、Ce和Th等30种主次痕量元素进行测定,其分析结果与标样标准值(或化学法值)符合较好,方法的精密度(RSD,n=10)<10%(除含量在检出限附近的元素外),各元素检出限基本满足化探要求  相似文献   

7.
X射线荧光光谱法测定海洋沉积物中35种元素   总被引:19,自引:1,他引:19  
李国会 《地质实验室》1997,13(4):225-229
采用混合熔剂熔融和粉末压片法制样,使用理论α系数和攻射线内标法校正元素间的吸收一增效应,用3080E2型X射线荧光光谱仪对试样中的35种元素进行测定,其分析结果的精密度和准确度可与化学法相媲美。  相似文献   

8.
X射线荧光光谱法测定钒的原子价平均值   总被引:1,自引:1,他引:1  
孙伟莹  谭秉和 《岩矿测试》1998,17(3):193-196
用X射线荧光光谱法测定了一系列钒的氧化物混合物中V的Kβ谱线的精细结构,研究了钒的氧化物中Kβ谱峰参数随混合物平均原子价变化的规律,并利用所作的定标曲线对一些实际样品,如钒渣、磁铁矿中钒的平均原子价进行了定量测定。  相似文献   

9.
理学3080E型X射线荧光光谱仪分辨率的改善   总被引:2,自引:1,他引:1  
通过对理学3080E型X射线荧光光谱仪第二准直器的改造,使谱仪对SKβ谱线的相对分辨率减少了近20%,即改造后的谱仪分辨能力提高了近20%,而且谱峰强度仍保持在较高水平。为开展硫等轻元素化学价态的分析研究与元素谱线互相重叠干扰复杂的试料分析提供了有利条件。  相似文献   

10.
采用粉末样品压片制样,土壤标准物质以及人工合成标样为标准,用X 射线荧光能谱仪对土壤试样中的Si、K、Ca 、Ti、Mn 、Fe 和Sr 7 种主、次量元素进行测定。讨论了基体效应及校正等问题。方法经土壤标样分析验证,其结果与标准值符合较好,方法的精密度( RSD,n = 5) < 3 % 。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

13.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

14.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

15.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

16.
17.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

18.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

19.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

20.
GEOCHEMISTRY     
正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号