The distribution of oxygen and hydrogen sulfide in Black Sea waters during winter-spring period

Regularities of oxygen and hydrogen sulfide are examined, using the method of spatial isopycnic analysis. The contribution that ventilation of winter-time surface waters over the domes of cyclonic gyres makes to the transfer of O₂ towards the upper boundary of the constant pycnocline and to the oxicline layer is demonstrated. The paper provides spatial scales of this phenomenon and indicates the areas where the upper boundary of the anoxic layer in the Black Sea, relative to the conventional density, is located much higher compared with the rest of the sea. The suboxic zone is shown to be a specific feature of the O₂/H₂S distribution in the Black Sea waters, typical, at least, of the northern part of the basin. Analysis of the suboxic spatial variability in the vertical has been conducted. Translated by Vladimir A. Puchkin.     

Vertical mesostructure of deep waters in the Black Sea

Studies of mesoscaleT, S characteristics of deep waters in the Black Sea carried out during 1978–1988 are generalized. Transformed lower Bosphorus waters are spread in the layer from 400 m to the bottom following density isosurfaces corresponding to this water. This is the way that interlayers ofT, S inversions are formed; their vertical thickness reaches 100–200 m in the Anatolian flow. The streamwise decrease of theT, S maxima and the location of isotherms in the cross-sections of these tongues permit the estimation of the order of the values of the coefficients of the vertical and horizontal turbulent diffusion.Translated by Mikhail M. Trufanov.     

Petroleum hydrocarbons and particulate organic matter in the Sea of Azov waters

The paper discusses the results of investigations on contamination of the Sea of Azov by petroleum hydrocarbons and particulate organic matter. After cessation of open sea observations in 1992, the contamination of the sea by petroleum hydrocarbons is predicted for the period from 1993 to 1997. Translated by Vladimir A. Puchkin.     

Sulfate reduction and anaerobic methane oxidation in Black Sea sediments

Beyond the shelf break at ca. 150 m water depth, sulfate reduction is the only important process of organic matter oxidation in Black Sea sediments from the surface down to the sulfate–methane transition at 2–4 m depth. Sulfate reduction rates were measured experimentally with ³⁵SO₄²⁻, and the rates were compared with results of two diffusion-reaction models. The results showed that, even in these non-bioirrigated sediments without sulfide reoxidation, modeling strongly underestimated the high reduction rates near the sediment surface. A hybrid modeling approach, in which experimentally measured rates in the upper sediment layers force a model that includes also the deeper layers, probably provides the most realistic estimate of sulfate reduction rates. Areal rates of sulfate reduction were 0.65–1.43 mmol SO₄²⁻ m⁻² d⁻¹, highest in sediments just below the chemocline. Anaerobic methane oxidation accounted for 7–11% of the total sulfate reduction in slope and deep-sea sediments. Although this methane-driven sulfate reduction shaped the entire sulfate gradient, it was only equivalent to the sulfate reduction in the uppermost 1.5 cm of surface sediment. Methane oxidation was complete, yet the process was very sluggish with turnover times of methane within the sulfate–methane transition zone of 20 yr or more.     

Thermohaline structure of abyssal and near-bottom waters of the Black Sea

The paper considers the thermohaline structure of Black Sea abyssal and near-bottom waters on the basis of exact measurements recorded in recent years under the HYDROBLACK and COMSBLACK international projects. The surface water mass (along with the cold mixed layer), the intermediate, abyssal, and near-bottom masses are identified. The upper boundary of deep waters is defined as a depth level where the density ratio decreases down to 0.1 This depth roughly corresponds to the 900–1100 m depth levels. Furthermore, the paper provides potential temperature and salinily values in the near-bottom layer, with an error of, respectively, 0.002°C and 0.002‰, at most. Translated by Vladimir A. Puchkin.     

Spatio-temporal variability of the relative transparency of Black Sea waters

The Black Sea relative transparency database covering the period from 1922 to 1993 is described. Seasonal and interannual variabilities of the Secchi disc depthz _σ are studied, along with the meteorological, hydrophysical and biological parameters affecting it. Translated by Vladimir A. Puchkin.     

Estimation of the upwelling rate of deep waters in the Black Sea from the H2S vertical distribution

The expression for the bottom convection intensity is derived from the equality of the advective vertical flux of H₂S within 1000–2000 m to the diffusion turbulent flow close to the H₂S zone upper boundary. The upwelling rate, which is expressed via the H₂S concentration in deep waters and the gradient of the H₂S concentration near the upper boundary, is 10^–4 cm/s. It is shown that the H₂S diffusion flux in deep waters is an order less than the advective one. The conclusion that below 1000 m the age of H₂S does not exceed 30 years and H₂S reaches the upper boundary in approximately 150 years is derived.Translated by Mikhail M. Trufanov.     

Experimental research on the hydrophysical characteristics and dynamics of waters in the north-west Black Sea in the region of the main Black Sea current

The results of measurements of hydrophysical parameters in the upper layer of the sea at an observation site located south-west of the Crimea are reported. The current pattern, the distribution of the upwelling and downwelling zones at the observation site, and the location of the mesoscale fronts are discussed.Translated by Mikhail M. Trufanov.     

Chemical speciation of copper and zinc in surface waters of the western Black Sea

The chemical speciation of Cu and Zn was investigated by voltammetric titration methods in the surface waters (10 m) of the western Black Sea during an Istanbul–Sevastopol cruise conducted in November 1998. Supporting parameters (temperature (T), salinity (S), pH, alkalinity (Alk), suspended particulate matter (SPM) and dissolved and particulate ²³⁴Th) were obtained in order to distinguish hydrographic features against involvement of the metals in biogeochemical processes. In the Turkish continental slope region, the cruise track intersected a narrow vein of colder water originating on the western shelf. The core of this cold water vein was characterised by a relatively low salinity, higher specific alkalinity and higher metal (especially Cu) and metal-binding ligand concentrations.A very large portion of Cu (93–99.8%) and Zn (82–97%) was organically complexed. The degree of complexation was highest in shelf waters and lowest in the central gyre. Titration data for Cu were modelled by two classes of organic binding ligands characterised by (C_L1=3–12 nM, log K₁′=13.1–13.9) and (C_L2=20–70 nM, log K₂′=9.4–11.2). These ligands occurred mainly in the ‘dissolved’ phase, as defined by 0.4-μm filtration. The stronger Cu-binding ligand seemed to be produced in situ in response to Cu concentration, whereas the weaker Cu-binding ligand appeared to be derived from terrestrial sources and/or reducing shelf sediments. Titration results for Zn were generally represented by one class of ligands (C_L1=8–23 nM, log K₁′=9.4–10.2), which were almost uniformly distributed between the ‘dissolved’ (78±8%) and the particulate phase (22±8%). The concentration of these strong Zn-binding ligands showed a very good correlation with SPM (r²=0.64), which improved when the dissolved ligands alone were considered (r²=0.78). It is hypothesised that these ligands were produced in situ by the bacterial breakdown of particulate organic matter.     

Radioactive isotopes of caesium in the waters and near-water atmospheric layer of the Black Sea

The concentrations of¹³⁷Cs and¹³⁴Cs were measured using the sorption method in the waters of the Black Sea during 1986–1987. An inhomogeneous character of the contamination of the surface waters in the Black Sea due to the Chernobyl disaster is shown. The subsequent migration and redistribution of caesium radionuclides in the various seasons of the year were studied. The amount of¹³⁷Cs and¹³⁴Cs in the upper 50 m layer was estimated. The results of measuring the concentration of caesium radionuclides in the near-water atmospheric layer over the Black Sea and Mediterranean Sea in 1986–1987 are also reported.Translated by Mikhail M. Trufanov.     

Viral abundance and distribution in mesopelagic and bathypelagic waters of the Mediterranean Sea

Despite the fact that marine viruses have been increasingly investigated in the last decade, knowledge on virus abundance, biomass and distribution in mesopelagic and bathypelagic waters is limited. We report here the results of a large-spatial-scale study (covering more than 3000 km) on the virioplankton distribution in epi-, meso- and bathypelagic waters in 19 areas of the Mediterranean Sea, from the Alboran Sea and Western Mediterranean, to the Tyrrhenian Sea, Sicily Channel and Ionian Sea. Integrated viral abundance in epipelagic waters was significantly higher than in deep-sea waters (on average, 2.4 vs. 0.5×10¹² viruses m⁻³). However, abundance of viruses in the deep-Mediterranean waters was the highest reported so far for deep seas worldwide (7.0 and 3.1×10¹¹ viruses m⁻³ in mesopelagic and bathypelagic waters, respectively) and their biomass accounted for 13–18% of total prokaryotic C biomass. The significant relationship between viral abundance and prokaryotic abundance and production in deep waters suggests that also deep-sea viruses are closely dependent on the abundance and metabolism of their hosts. Moreover, virus to prokaryote (and nucleoid-containing cell (NuCC)) abundance ratio increased with increasing depths suggesting that deep waters may represent optimal environments for viral survival or proliferation. Overall, our results indicate that deep waters may represent a significant reservoir of viruses and open new perspectives for future investigations of viral impact on the functioning of meso-bathypelagic ecosystems.     

Analysis of the nitrate distribution in the Black Sea density field

The paper discusses the results derived from the analysis of the vertical distribution of nitrates in the Black Sea density field during the winter of 1994. It has been shown that in the absence of winter-time convective mixing of waters, the vertical structure of nitrates is isopycnically defined. Maximum nitrates concentration persists throughout the warm period, normally changing from 5 to 9 μmol in the deep-water part of the area, and has not altered, in comparison with the 1980 data. Translated by Vladimir A. Puchkin.     

Vertical distribution of the hydrogen sulphide sources in the Black Sea

Data on the diffusion coefficientK _zand the concentration of H₂S in the Black Sea are used to compute the depth distribution of the vertical flux, and the intensity of the H₂S sources and sinks. On average, the total production of H₂S in the Black Sea reaches 37×10⁶ t/year. The main bulk of H₂S is produced not at the bottom, but in the layer of 450–1300 m. Destruction of H₂S prevails above the 400 m layer. Dissolved oxygen penetrating the H₂S zone can oxidize only half of the hydrogen sulphide produced in the sea.Translated by Mikhail M. Trufanov.     

Mathematical model for the ecosystem of the Black Sea hydrogen sulphide zone

A model for the ecosystem of the Black Sea hydrogen sulphide zone is suggested which incorporates seven components, namely, the concentrations of hydrogen sulphide, oxygen, dead organic matter, thiosulphates, molecular sulphur, and the biomass of sulphate-reducing and thiobacteria. With the minor terms neglected in the equations governing the system under consideration, the latter was divided into subsystems which allow an approximate calculation of the model components' vertical stationary profiles. The derived components' profiles agree qualitatively with available observations.Translated by V. Puchkin.     

Specific features of the vertical distribution of elements of the main biogenic cycles in waters of the Northwest shelf of the Black Sea

We study specific features of the vertical distribution of elements of the main biogenic cycle in the upper layers of waters on the northwest shelf of the Black Sea in spring and autumn and the correlation between the specific features of the vertical distributions of hydrochemical and hydrological characteristics. It is shown that the location of the halocline always specifies the location of the chemocline, whereas the effect of the thermocline on the distribution of hydrochemical characteristics is ambiguous. The vertical distribution of the hydrochemical parameters can be homogeneous in the presence of the seasonal thermocline. At the same time, in its absence, one may observe significant vertical gradients in the distributions of hydrochemical characteristics inside the upper mixed layer.     

Numerical simulation of a quasi-tropical cyclone over the Black Sea

The paper describes results of numerical experiments on the simulation of a mesoscale quasi-tropical cyclone, a rare event for the Black Sea, with the MM5 regional atmospheric circulation model. General characteristics of the cyclone and its evolution and physical formation mechanisms are discussed. The balances of the momentum components have been estimated, and sensitivity experiments have been performed. It is shown that, according to its main physical properties and energy supply mechanisms, the cyclone can be related to quasi-tropical cyclones.     

Peculiarities in the distribution of hydrocarbons in the southeastern part of the Baltic Sea

Data on the contents and compositions of the hydrocarbons (HCs)—aliphatic (AHCs) and polycyclic aromatic (PAHs)—are provided in comparison with the contents of the total organic carbon (C_org), the lipids in the particulates, and the C_org in bottom sediments. Particular attention has been paid to the distribution of the HCs in the water area of the Kravtsov oil field. It has been established that the concentrations of AHCs in the water are governed by the content of particulates, and the elevated AHC concentrations are confined to the coastal areas. In the water area of platform D-6, the sandy bottom sediments were notable for the great variability of the HC concentrations, both laterally and from year to year. In the summer of 2010, the content of AHCs averaged 40 μg/g (19% in the C_org), and that of PAHs, 23 ng/g. Natural seepage from the sediment mass is considered to be a source of HCs along with oil contamination.     

Some statistical properties of the inter-annual variability of the relative transparency of Black Sea waters

The Secchi disk data-base compiled in the Black Sea from 1992 to 1993 has been investigated. The space-time variability of statistical properties (RMS deviations and trends) of the series of inter-annual anomalies of the relative water transparency is described. Translated by Vladimir A. Puchkin.     

A quasitropical cyclone over the Black Sea: Observations and numerical simulation

A long-living mesoscale cyclone observed over the Black Sea in September 2005 was characterized by a high wind velocity (25 m/sec) and induced an abnormal lowering of the sea-surface temperature (by more than 10°C). We performed the numerical simulation of this cyclone by using the MM5 model and the data of global operative analysis. The evolution of the cyclone and its structure similar to the structure of a tropical cyclone are reproduced. The primary azimuthal and secondary radial circulations, the clear-sky eye with warm core at medium levels, and the eyewall with strong air updraft and intense convection and precipitation are well visible. The fluxes of sensible and latent heat on the sea surface played the key role in the initiation and development of this cyclone. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 3, pp. 41–55, May–June, 2008.     

Monsoon-forced distribution and assemblages of appendicularians in the northwestern coastal waters of South China Sea

This study examines species composition and abundance of appendicularians in the northwestern coastal waters of South China Sea based on in situ data obtained by 169 μm planktonic nets during summer and winter, and discusses the influence of environmental factors on their distribution and assemblages. A total of 19 appendicularian species (including one unidentified species) was collected. Species richness is higher in summer than in winter, and it increases from inshore to offshore waters. Average abundance of appendicularians is 103.1 (±198.1) and 54.6 (±111.1) ind. m⁻³ in summer and winter, respectively. The abundance distribution of appendicularians is generally high around inshore waters during summer and winter, and with a higher abundance assemblage along the eastern coast from Leizhou Peninsula to Hainan Island, especially at the eastern mouth of Qiongzhou Strait in summer. Oikopleurids accounted for 97.5% and 99.6% of total appendicularians abundance in summer and winter, and the region of high values was the same to that of total appendicularians abundance. Oikopleura longicauda, Oikopleura rufescens, and Oikopleura fusiformis are dominant species during summer and winter. Results showed that spatial distribution of species richness of appendicularians is considered to be the result of physical factors such as temperature and salinity in summer and winter, while variations in abundance of appendicularians are affected by the combination of physical and biological factors. In particular, variations of appendicularians abundance are affected by food availability in summer.