Geochemistry of mafic dykes in the Antarctic Peninsula continental-margin batholith: a record of arc evolution

Mafic dykes of the Antarctic Peninsula continental-margin arc are compositionally diverse, comprising calc-alkaline (dominant), shoshonite, tholeiite, and OIB-like varieties. Their compositions give information about different mafic magma sources tapped during arc evolution. The compositional groups represent partial melts of at least five distinct mantle sources: a low-ɛNd subduction-modified, garnet-bearing, lithospheric mantle (older calc-alkaline); a high-ɛNd subduction-modified, garnet-bearing, lithospheric mantle (shoshonites); a high-ɛNd subduction-modified, spinel-bearing, asthenospheric mantle (younger calc-alkaline); E-MORB-like spinel-bearing asthenosphere depleted by a previous melting event (tholeiites); and within-plate non-subduction modified, garnet- and spinel-bearing, asthenosphere (OIB-like). Slab-derived fluids, subducted sediment, and arc crust also contributed to the magmas. Consideration of previous work in the light of our new compositional and geochronological data enables presentation of a summary of arc evolution. For most of the Cretaceous and Tertiary, the tectonic regime of the Antarctic Peninsula arc was transtensional, and calc-alkaline magmas intruded. An oceanic spreading centre collided with the trench during the Late Cretaceous and induced tectonic changes which caused tapping of different magma sources. A pulse of shoshonitic, tholeiitic, and OIB-like mafic magmatism resulted. Three ridge-trench collisions are now recognized during the history of the arc, in Mid–Late Jurassic, Late Cretaceous, and Early–Mid Tertiary times. Received: 13 January 1997 / Accepted: 5 December 1997     

Cenozoic magmatism in Kalimantan and its related geodynamic evolution

The NE–SW Tertiary magmatic belt of central Kalimantan is related to two separate periods of subduction; during the Eocene–Oligocene and Late Oligocene–Miocene. The younger magmatic belt is superimposed upon the earlier belt. This magmatic belt is characterized chiefly by Late Oligocene–Miocene volcanic products, among which limited exposures of the Eocene volcanics have also been mapped by previous investigators. This calc-alkaline magmatic belt has become known as the ‘gold belt’ of Central West Kalimantan on account of a number of discoveries of Neogene epithermal gold mineralization. This mineralization is found in central to proximal volcanic settings and occurred at relatively shallow depths. The earliest known subduction-related magmatism took place in the Eocene–Early Oligocene with the emplacement of calc-alkaline silicic pyroclastics, followed by a period of continental collision. Subsequent subduction-related magmatism continued from Late Oligocene–Pleistocene, during which time the magma evolved from calc-alkaline to potassic calc-alkaline. Plio-Pleistocene magmatism resulted in the formation of basalt flows. The present available K–Ar ages of the Cenozoic volcanics range from 51 to 1 Ma.     

Petrogenesis of Silicic Rocks from the Krksfjrdur Central Volcano, NW Iceland

Calc-alkaline dacites are found in the Tertiary Kroksfjordurcentral volcano besides the more typical tholeiitic dacitesand rhyolites characteristic of Icelandic rift zones. It isclear that these calc-alkaline dacites are not subduction related,but their chemistry and petrography are definitely calc-alkaline.They are much lower in Fe and higher in Ca and Al than otherrocks from Iceland with comparable silica percentages. Theyare significantly depleted in the high field strength elements(HFSE, e.g., Nb, Zr, Y, and heavy rare earth elements), andsome of them contain hydrous phases or their relics. The anhydrousphase assemblage and relatively high Fe content of the tholeiiticsilicic rocks indicate generation at shallow depths (P_H2o <1kb). The high Ca and Al contents and the depletion of HFSE inthe calc-alkaline dacites indicate generation by partial meltingof amphibolite facies rocks at 5–6 km depth. The generationof the tholeiitic silicic rocks requires a shallow magma chamber,where they could be formed by fractionation of basaltic magma,or by partial melting of country rock heated by basaltic magma.The calc-alkaline dacites require a different volcanotectonicenvironment for their generation. The geothermal gradient requiredis comparable with that of regional geothermal gradients closeto the active rift zones. They were probably formed when thecentral volcano was drifting away from the rift axis and itsactivity was waning. Intrusion of basaltic magma, probably relatedto another volcanic center, mobilized the dacite magma.     

Contexte lithostructural, âges 40K40Ar et géochimie du volcanisme calco-alcalin tertiaire de Cap-d'Ail dans le tunnel ferroviaire de Monaco

Lithostratigraphic and structural framework, chronology and geochemistry of the Tertiary calc-alkaline volcanism of Cap-d'Ail (French Maritime Alps) are specified according to the new data collected during the earthworks of the recent railway tunnel built between Cap-d'Ail and Monaco. Two different magmatic events were dated: the first one, to Palaeogene, the other one, to Neogene. To cite this article: J.-P. Ivaldi et al., C. R. Geoscience 335 (2003).     

Young Alpine dykes south of the Tauern Window (Austria): a K-Ar and Sr isotope study

Fortyfive new K-Ar ages and Sr isotope data on amphiboles, biotites, clinopyroxenes and whole rock samples from subvolcanic dykes south of the Tauern Window establish, that alkalibasaltic dykes were intruded 30 m.y. ago and shoshonitic volcanism occured between 30 and 24 m.y. ago. Two calc-alkaline rocks of high-potassium composition yielded ages of 40 and 26 m.y. resp., a spread which may or may not be real. Calc-alkaline dykes with medium and low potassium contain excess argon and are hence undatable. Alkalibasaltic dykes have ⁸⁷Sr/⁸⁶Sr ratios of 0.7056–0.7070, shoshonitic rocks 0.7075–0.7133, potassium rich calc-alkaline dykes 0.7077–0.7100. ⁸⁷Sr/⁸⁶Sr of all other calc-alkaline rocks scatter between 0.7074 and 0.7150. Sr data indicate that dykes studied do not represent closed Sr systems, but that Sr characteristics result from selective strontium assimilation en route to surface. Primary Sr isotopic ratios of alkalibasaltic dykes point to an origin of these rocks in enriched sub-continental upper mantle. The source region of shoshonitic and high-potassium calcalkaline rocks could have ⁸⁷Sr/⁸⁶Sr around 0.707, which is assigned to the input of a component rich in alkalies, LREE and LIL elements. Genetic relationships with other Tertiary magmatites of similar geotectonic position are explained in terms of plate tectonic models of the Eastern Alps.     

Age and Chemistry of Miocene Volcanic. Rocks from the Kiraz Basin of the Küçük Menderes Graben: Its Significance for the Extensional Tectonics of Southwestern Anatolia,Turkey'

Neogene volcanic rocks and granitoid plutons are among the most important geological components of western Turkey. Although they are voluminous north of the Gediz Graben, they are very scarce to the south, where volcanic rocks occur as isolated small exposures in a small number of localities. The Kiraz Basin of the Küçük Menderes Graben is a key locality, in which Tertiary volcanic rocks crop out at three locations. These rocks have been chemically analysed and dated (³⁹Ar-⁴⁰Ar whole rock and biotite analyses) in order to understand their tectonic setting of emplacement and its relation to the wider structure of western Anatolia. Whole rock and biotite ³⁹Ar-⁴⁰Ar ages vary between 13.9 ± 0.2 Ma and 14.6 ± 0.2 Ma.

The Kiraz volcanic rocks are calc-alkaline, with a compositional range from basaltic andesite to dacite. They are strongly enriched in the light ion lithophile elements (LILE) and have chemistries typical of lavas erupted in subduction-related settings. Their close association with rift-bounding faults suggests eruptions via conduits flanking grabens in an extensional environment. The difference in chemical composition and age between the Kiraz volcanic rocks and the slightly older calc-alkaline volcanic rocks north of the Gediz Graben is attributed to their relatively younger ages and greater proximity to the Aegean Arc. Their calc-alkaline chemistry reflects magma generation influenced by the slab descending beneath this arc and eruption/emplacement in an extensional setting.     

西南极菲尔德斯半岛第三纪钙碱性火山岩的生成与演化

西南极菲尔德斯半岛第三纪火山岩的岩石学和岩石化学特征表明,它们基本属于钙碱性火山岩系列,是岛弧火山作用的产物。该岩石组合中,随岩石中SiO_2含量的增加,斜长石斑晶数量减少,微量元素Cr、V丰度降低,Sr、Ba丰度下降,这些揭示了岩浆中斜长石和单斜辉石的分离结晶作用。稀土元素的系统变化也证明了这一点。主元素和微量元素的定量计算所验证了岩浆的分离结晶作用演化过程。     

Geochemistry of the Adamello massif (northern Italy)

The Tertiary Adamello massif, outcropping over an area of more than 550 km² in the southern Alps (northern Italy) is composed mainly of granitoid rocks (granodiorite, tonalite, quartz diorite) with minor amounts of diorite and gabbro. The major and trace element composition of these rocks is comparable to calc-alkaline volcanic rocks of continental margins. The granitoid rocks display spatial and temporal variations in their composition, particularly in Na, P, Sr, La, Nb and Y contents and ⁸⁷Sr/⁸⁶Sr ratios. The variations were probably produced by concurrent contamination/wall-rock assimilation and fractional crystallization of high-alumina basaltic magma.     

Alkaline Lavas in the Volcanic Front of the Western Mexican Volcanic Belt: Geology and Petrology of the Ayutla and Tapalpa Volcanic Fields

The Plio-Quaternary Ayutla and Tapalpa volcanic fields in thevolcanic front of the western Mexican Volcanic Belt (WMVB) containa wide variety of alkaline volcanic rocks, rather than onlycalc-alkaline rocks as found in many continental arcs. Thereare three principal rock series in this region: an intraplatealkaline series (alkali basalts and hawaiites), a potassic series(lamprophyres and trachylavas), and a calc-alkaline series.Phlogopite-clinopyroxenite and hornblende-gabbro cumulate xenolithsfrom an augite minette lava flow have orthocumulate textures.The phlogopite-clinopyroxenite xenoliths also contain apatiteand titanomagnetite and probably formed by accumulation of mineralsfractionated from an augite minette more primitive than thehost. The intraplate alkaline series is probably generated bydecompression melting of asthenospheric mantle as a result ofcorner flow in the mantle wedge beneath the arc. Alkaline magmasmay be common in the WMVB as a result of prior metasomatism(during Tertiary Sierra Madre Occidental magmatism) of the Mexicansub-arc mantle. Generation of the more evolved andesites anddacites of the calc-alkaline series is due to either combinedassimilation and fractional crystallization (AFC) or magma mixing.The preponderance of alkaline and hydrous lavas in this regiondemonstrates that these lava types are the norm, rather thanthe exception in western Mexico, and occur in regions that arenot necessarily associated with active rifting. KEY WORDS: arc basalt; subduction; alkali basalt; minette; hawaiite; metasomatism     

Geology and geochemistry of Tertiary basalt in south Wadi Hodein area, South Eastern Desert, Egypt

Tertiary basalt is widespread in the area south of Wadi Hodein, south Eastern Desert, Egypt. It is the youngest unit in the basement rocks of the Central Eastern Desert classification of El Shazly (Proc 22nd Intl Geol Congr, New Delhi 10:88–101, 1964) and El Ramly (Ann Geol Surv Egypt II:1–17, 1972), traversed all the previous succession of the basement rocks as well as the Nubia Sandstone of Cretaceous age, forming sheets, small hills, ridges, and dikes. This Tertiary basalt is strongly associated with the opening of the Red Sea. Geologic, petrographic, and petrochemical studies as well as microprobe and X-ray analyses were performed on samples from Wadi Hodein Tertiary basalt. Field and petrographic studies classified the Tertiary basalt in south Wadi Hodein into porphyritic olivine basalt, plagiophyric basalt, and doleritic basalt. Opaque minerals (magnetite and ilmenite) constitute 6–7.5% of this basalt. Petrochemical studies and microprobe analyses reveal that they are low-TiO₂ basalt with low uranium and thorium contents, classified as being basaltic andesite to andesite, originated from calc-alkaline magma, and developed in within-plate tectonic environment. Scanning electron microscopy shows that magnetite and ilmenite are the prevalent opaque minerals in this Tertiary basalt. Field radiometric measurements of the Tertiary basalt in south Wadi Hodein reveals low uranium and thorium contents. Uranium contents range from 0.5 to 0.9 ppm, while thorium contents range from 1.2 to 3.2 ppm. Fractional crystallization and mass balance modeling indicate that the most-silica low-TiO₂ Tertiary basalt in south Wadi Hodein can be derived from the relatively less-silica low-TiO₂ Tertiary basalt of south Quseir and Gabal Qatrani through fractional crystallization of plagioclase, olivine, augite, and titanomagnetite oxides. Tertiary basalts in south Wadi Hodein and south Quseir have nearly the same age, 25 Ma (Sherif, The Fifth International Conference on the Geology of Africa, 2007), 24 Ma (Meneisy and Abdel Aal, Ain Shams Sci Bull 25(24B): 163–176, 1984), and 27 Ma (El Shazly et al., Egypt J Geol 1975), respectively. Finally, the fractionation modeling and geochemical characteristics of these basalts suggested their origination from one basaltic magma emplaced in late Oligocene.     

Plate tectonics and volcanism in the gibraltar arc

Late Tertiary and Quaternary volcanism of southeastern Spain can be fitted in a platetectonics model, taking into account the post-Paleozoic evolution of the stable and semimobile Iberian areas and the new orogenic belts bordering the Mediterranean between Africa and the Iberian Peninsula.The occurrence and distribution of calc-alkaline and potassic volcanism suggest an oceanic crust sinking downwards from the Iberian plate. This active margin is causally related to the convergence and collision of Iberia and Africa during Late Cretaceous—Early Miocene time span.A pre-collision distensive phase is inferred from the stratigraphie and tectonic record between the Triassic and Late Cretaceous, while since the Late Miocene another distensive phase is related to the actualistic features.     

The “andesitic” magmatism in the south-western Tyrol and its geodynamic significance

The researches carried out on the recent dyke activity in the south-western Tyrol have revealed a widespread “andesitic” magmatism in the austroalpine realm. The magmatic activity developed at least in two distinct phases; but in this paper we are only concerned with the unmetamorphosed dykes which are younger than the alpine folding. The existence of a calc-alkaline magmatism mainly of the intermediate type, and the occurrence of garnet as the first mineral on the liquidus, imply a very deep origin of such a magmatism, which agrees with the geodynamic models, providing the subduction of oceanic crust recently hypothesized for the Alpine evolution. Regarding the age of dyke activity, very recent radiometric results (K/Ar) testify for the first time in the Alps an “andesitic” magmatism from Upper Cretaceous to Tertiary and suggest both continuous or separate subductive processes from the Upper Cretaceous onwards.     

富金斑岩铜矿床研究进展

富金斑岩型铜矿床作为斑岩型矿床的一类,自20世纪70年代起逐渐引起了人们的重视.近年来又取得了很多重要进展,主要体现在以下5个方面:①富金斑岩型铜矿不仅在全世界范围内大量发现,而且部分矿床规模巨大;②绝大多数富金斑岩型矿床集中在新生代和中生代产出,尤以第三纪最为普遍;③富金斑岩型铜矿床不仅仅发育于汇聚板块边缘的岩浆弧环境,在大陆碰撞带甚至是陆内环境也发现了大量此类矿床;④含矿斑岩绝大多数为钙碱性岩浆系列,但部分矿床与高钾钙碱性(甚至钾玄质)岩浆密切相关;⑤富金斑岩型矿床金的富集,与大地构造背景、成矿时代、含矿斑岩性质、围岩性质、蚀变与矿化类型等因素关系不大,而主要受地幔岩浆过程、岩浆-热液过程及热液过程控制.     

青藏高原东北缘伯阳地区第三系流纹岩地球化学及岩石成因

伯阳第三系流纹岩出露于青藏高原东北缘特殊的构造部位,位于青藏、华北和扬子三大构造域的交接转换区域。岩石的w(Si O2)介于68%~76%,w(K2O)>w(Na2O),w(K2O)/w(Na2O)平均值1·25,为一套典型的壳源流纹岩岩石系列。岩石微量及稀土元素具有典型的板内火山岩特征,K、Th、Rb等元素呈较明显的富集状态,而岩石显著的低Sr特征((19~120)×10-6)表明其并非源自加厚的下地壳,而是起源于斜长石稳定的正常下地壳。正是由于新生代期间青藏高原东北缘强烈的造山环境,加之渭河断裂的发育为下地壳物质提供了减压熔融的有利条件,从而诱发下地壳的局部熔融,形成伯阳酸性火山岩的原始岩浆。该岩浆体系沿区域断裂构造体系上升,并经历了较强的结晶分异和演化,最终形成伯阳第三系流纹岩系列。     

Structural evolution of the Port Wells gold mining district,Prince William Sound,south central Alaska: Implications for the origin of the gold lodes

Data collected in the Port Wells gold mining district, Alaska, indicate several stages in the structural history of the district. The first stage was the accretion and associated deformation of the Valdez group flysch sequence at the end of the Cretaceous. The deformation of the semilithified rocks included two folding phases forming isoclinal NE-SW-striking and SE-vergent folds during a D₁ phase, and minor open warps in NW-SE direction during a D₂ phase. Intrusion of early Oligocene (36 Ma) calc-alkaline granitoids followed deformation and was terminated by the emplacement of aplitic dikes. The major fracturing processes in both the granitoids and the country rocks occurred subsequently, probably during the uplift of the Chugach mountains in the late Tertiary. Several generations of epigenetic gold-bearing quartz veins were emplaced along the fractures at a later stage. Due to the significant time gap between peak metamorphism and mineralization, the metamorphic secretion model proposed for the vein formation is reconsidered.     

40Ar–39Ar dating, whole-rock and Sr–Nd–Pb isotope geochemistry of post-collisional Eocene volcanic rocks in the southern part of the Eastern Pontides (NE Turkey): implications for magma evolution in extension-induced origin

The Eocene volcano-sedimentary units in the southern part of the Eastern Pontides (NE Turkey) are confined within a narrow zone of east–west trending, semi-isolated basins in Bayburt, Gümü?hane, ?iran and Alucra areas. The volcanic rocks in these areas are mainly basalt and andesite through dacite, with a dominant calc-alkaline to rare tholeiitic tendency. ⁴⁰Ar–³⁹Ar dating of these volcanic rocks places them between 37.7 ± 0.2 and 44.5 ± 0.2 Ma (Middle Eocene). Differences in the major and trace element variations can be explained by the fractionation of clinopyroxene ± magnetite in basaltic rocks and that of hornblende + plagioclase ± magnetite ± apatite in andesitic rocks. Primitive mantle-normalized multi-element variations exhibit enrichment of large-ion lithophile elements and to a lesser extent, of light rare earth elements, as well as depletion of high field strength elements, thus revealing that volcanic rocks evolved from a parental magma derived from an enriched mantle source. Chondrite-normalized rare earth element patterns of the aforementioned volcanic rocks resemble each other and are spoon-shaped with low-to-medium enrichment (La_N/Lu_N = 2–14), indicating similar spinel lherzolitic mantle source(s). Sr, Nd and Pb isotopic systematics imply that the volcanic rocks are derived from a subduction-modified subcontinental lithospheric mantle. Furthermore, post-collisional thickened continental crust, lithospheric delamination and a subduction-imposed thermal structure are very important in generating Tertiary magma(s). The predominantly calc-alkaline nature of Eocene volcanic rocks is associated with increasing geodynamic regime-extension, whereas tholeiitic volcanism results from local variations in the stress regime of the ongoing extension and the thermal structure, as well as the thickness of the crust and the mantle-crust source regions. Based on volcanic variety and distribution, as well as on petrological data, Tertiary magmatic activity in Eastern Pontides is closely related to post-collisional thinning of the young lithosphere, which, in turn, is caused by extension and lithospheric delamination after collisional events between the Tauride–Anatolide Platform and the Eurasian Plate.     

2: Hydrothermal ore deposits related to post-orogenic extensional magmatism and core complex formation: The Rhodope Massif of Bulgaria and Greece

The Rhodope Massif in southern Bulgaria and northern Greece hosts a range of Pb–Zn–Ag, Cu–Mo and Au–Ag deposits in high-grade metamorphic, continental sedimentary and igneous rocks. Following a protracted thrusting history as part of the Alpine–Himalayan collision, major late orogenic extension led to the formation of metamorphic core complexes, block faulting, sedimentary basin formation, acid to basic magmatism and hydrothermal activity within a relatively short period of time during the Early Tertiary. Large vein and carbonate replacement Pb–Zn deposits hosted by high-grade metamorphic rocks in the Central Rhodopean Dome (e.g., the Madan ore field) are spatially associated with low-angle detachment faults as well as local silicic dyke swarms and/or ignimbrites. Ore formation is essentially synchronous with post-extensional dome uplift and magmatism, which has a dominant crustal magma component according to Pb and Sr isotope data. Intermediate- and high-sulphidation Pb–Zn–Ag–Au deposits and minor porphyry Cu–Mo mineralization in the Eastern Rhodopes are predominantly hosted by veins in shoshonitic to high-K calc-alkaline volcanic rocks of closely similar age. Base-metal-poor, high-grade gold deposits of low sulphidation character occurring in continental sedimentary rocks of synextensional basins (e.g., Ada Tepe) show a close spatial and temporal relation to detachment faulting prior and during metamorphic core complex formation. Their formation predates local magmatism but may involve fluids from deep mantle magmas.The change in geochemical signatures of Palaeogene magmatic rocks, from predominantly silicic types in the Central Rhodopes to strongly fractionated shoshonitic (Bulgaria) to calc-alkaline and high-K calc-alkaline (Greece) magmas in the Eastern Rhodopes, coincides with the enrichment in Cu and Au relative to Pb and Zn of the associated ore deposits. This trend also correlates with a decrease in the radiogenic Pb and Sr isotope components of the magmatic rocks from west to east, reflecting a reduced crustal contamination of mantle magmas, which in turn correlates with a decreasing crustal thickness that can be observed today. Hydrogen and oxygen isotopic compositions of the related hydrothermal systems show a concomitant increase of magmatic relative to meteoric fluids, from the Pb–Zn–Ag deposits of the Central Rhodopes to the magmatic rock-hosted polymetallic gold deposits of the Eastern Rhodopes.     

Timing of formation and geological setting of low-sulphidation epithermal gold deposits in the continental margin of NE China

The margin of NE China, a part of the West Pacific metallogenic belt, contains innumerable low-sulphidation mineral deposits. Gold deposits in this region can be classified into three distinct types based on geology and ore mineral paragenesis: (1) low-sulphidation epithermal silver–gold deposits, (2) low-sulphidation tellurium–gold deposits, and (3) low-sulphidation epithermal tellurium–gold deposits. Ores formed during the late Early Cretaceous and the early Late Cretaceous reflect three distinct metallogenic periods: the Fuxin Stage at 115.98 ± 0.89 Ma, the Quantou Stage at 107.2 ± 0.6 Ma or <103 Ma, and the Qingshankou or Yaojiajie Stage at < 97 Ma and 88.2 ± 1.4 Ma. The Fuxin Stage is dominated by trachyandesitic magmatism, with magmas emplaced at hypabyssal depths. In comparison, the Quantou Stage is characterized by high-K calc-alkaline, calc-alkaline, and sodic andesitic, dacitic, and rhyolitic magmatism of three different suites. The first of these is a high-K calc-alkaline andesitic magmatic suite that was accompanied by the emplacement of a calc-alkaline sodic dacite during the formation of the Ciweigou and Wufeng ore deposits. The second suite is dominated by calc-alkaline sodic rhyolite and high-K calc-alkaline sodic dacite magmatism associated with the formation of the Sipingshan ore deposit. The third suite is typified by high-K calc-alkaline andesitic magmatism associated with the emplacement of calc-alkaline hypabyssal granitoid complexes accompanying the formation of the Dong'an and Tuanjiegou ore deposits. The Qingshankou or Yaojia Stage is characterized by calc-alkaline sodic dacite magmatism associated with the formation of the Wuxing ore deposit. Metallogenesis during the Fuxin Stage characterized by trachytic magmatism is closely related to the formation of a deep-seated fault within a magmatic arc or the back-arc region of an immature continental margin and is associated with the Early Cretaceous subduction of the Pacific plate beneath Eurasia. Ore deposits that formed during the Fuxin Stage were generally related to magmato-hydrothermal fluids associated with mantle-derived magmas. In contrast, metallogenesis during the Quantou and Qingshankou or Yaojiajie stages was closely related to the formation of a mature high-K calc-alkaline magmatic arc within a continental margin setting again associated with the westward subduction of the Pacific plate. This metallogenic event was a product of magmato-hydrothermal systems derived from crust–mantle interaction and mixing of magmas derived from partial melting of different sections of the continental crust.     

Circum-Caribbean Granitoids: Characteristics and Origin

Caribbean granitoids occur among a series of widespread magmatic arcs that developed during a period of major oceanic plate convergence and subduction that began in Late Cretaceous time. Evaluation of Caribbean granitoids reveals that two main suites of granitoids are widespread. Low-K granitoids, including gabbro, diorite, quartz diorite, tonalite, and trondhjemite, comprise one of these suites. The second main type is distinctly more potassic and consists primarily of quartz monzodiorite and granodiorite, but also includes monzodiorite, quartz monzonite, and granite. Both groups contain rocks that are transitional to the other group. The granitoids are part of an extensive Caribbean calc-alkaline assemblage that includes low-K, medium-K, and high-K rocks. Island-arc tholeiitic and normal-K calc-alkalic compositions reflect geochemical continua within the orogenic granitoids. The granitoids (including low-K rocks) lie within the calc-alkaline field on FeO^T/MgO and AFM diagrams. Alkali-lime indices generally correlate with potassium content, the low-K varieties being calcic (tholeiitic) and the higher K rocks being calc-alkalic.

Rare-earth-element concentrations range from fairly primitive compositions having flat patterns and abundances of ～10 to 30 times chondrites to more evolved types that show mild enrichment in the light rare earths and typically are normal calc-alkaline. Mean initial ⁸⁷Sr/⁸⁶Sr ratios are commonly between 0.703 and 0.704. These low ratios are consistent with a mantle source in which assimilation of old sediments is not a factor. Limited isotopic and trace-element data suggest, instead, that the granitoids formed by partial melting in the mantle wedge and that at least some of the melting was accompanied by the addition of an aqueous fluid phase that was derived from the subducted oceanic plate.

Normative An-Ab-Or compositions are consistent with the presence of two groups of Caribbean granitoids. The group that is low in normative Or follows fractional crystallization vectors of parent magmas that typically are depleted in incompatible elements. The second group has higher normative Or and fractionates toward more enriched incompatible-element compositions. Normative compositions also indicate that there are temporal relations between the intrusive and extrusive rocks of Puerto Rico. Granitoids and lavas of Middle Cretaceous (125 to 100 Ma) and Early Tertiary (65 to 35 Ma) age are geochemically primitive types that display only limited degrees of mantle enrichment. In contrast, intrusive and extrusive rocks of Late Cretaceous age (100 to 65 Ma) show a wide range of incompatible-element concentrations, reflecting varying degrees of mantle enrichment.     

Zircon U–Pb geochronology of Ordovician magmatism in the polycyclic Ruitor Massif (Internal W Alps)

Among the Middle Penninic basements of the Internal NW-Alps, the Ruitor massif shows the best preserved remnants of pre-Permian metamorphic rocks. Their Barrovian-type mineral associations are somewhat masked by the greenschist to blueschist Alpine metamorphism of Tertiary age. Four Ruitor gneisses have been analysed, showing geochemical characters of granitoids from orogenic zones. Zircon morphology also suggests magmatic protoliths and a crustal source; some of the morphological zircon types suggest anatectic granites. The first U-Pb ages on zircon for this massif have been obtained concurrently through conventional multigrain and ion microprobe dating. Two metavolcanic rocks at 471LJ and 468ᆪ Ma could be slightly older than the porphyritic augen gneisses at 465ᆟ and 460lj Ma. Regional data from the other Internal basement massifs suggest that the Variscan event is poorly recorded, except in Ruitor-type units. Ruitor and Sapey gneisses belonged to the same unit (Nappe des Pontis), which was affected by a 480-450-Ma event including volcanism and anatexis and ended with a late calc-alkaline granite emplacement at 460-450 Ma. The distribution of Variscan basement units roughly parallels Alpine zonation.