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1.
Five ferruginous deposit samples formed from neutral hot springs were analyzed to determine whether they consisted of a mixture of silica, hydrous iron oxide or iron silicate by differential thermal analysis (DTA), infrared (IR) spectroscopy, powder X-ray diffraction (XRD), and 57Fe Mssbauer spectroscopy. The Si/Fe atomic ratios of the deposits ranged from 0.25 to 0.45, and were smaller than those of hisingerite (12), but apparently close to those of siliceous ferrihydrite (0.250.5). Si was confirmed to be present as monomeric or oligomeric silicate from the Si-O stretching vibration frequencies on the IR spectra. Judging from the results of DTA, which minerals starting to produce after heating, and a relationship between Si-O stretching vibration frequency and Si/Fe atomic ratio proposed by Henmi et al. (1981), all the deposits in this study were concluded to be mixtures of various siliceous ferri-hydrites with low and high Si/Fe atomic ratios. Moreover, by comparing the chemical properties of hot spring waters, the formation conditions of siliceous ferrihydrite were also discussed.  相似文献   

2.
Mercury distribution was determined in all types of solid materials from the supergene zone of geothermal deposits in southern Kamchatka: rocks, hydrothermally altered rocks (metasomatic rocks), soils, soil—pyroclastic cover, bottom sediments of perennial and intermittent streams, hydrothermal clays, artificial siliceous precipitates, and iron sulfides formed owing to thermal water discharge from a well. The mercury content varies from background values for the Kurile-Kamchatka region in fresh rocks to high and extremely high values in hydrothermal clays and monomineralic pyrite samples. The sources, migration conditions, and concentration mechanisms of mercury were evaluated. Mercury is supplied to the surface of geothermal deposits and thermal fields by a deep hydrothermal flow and is concentrated on thermodynamic barriers in hydrothermal clays, siliceous sinters (silica gel), and soils showing high salinity owing to the deposition in them of silica, sulfates, and other compounds from a vapor-water mixture. Newly formed clay minerals, iron sulfides (pyrite), silica gel, and biological materials (peat) can probably efficiently sorb mercury under geothermal conditions at atmospheric pressure and temperatures from 20°C to 120°C.  相似文献   

3.
The Hadamengou gold deposit is located in western part of the northern margin of the North China craton. It is a hydrothermal deposit related to alkaline magmatism. Dissolution of Au, Fe from pyrite and iron oxide (including magnetite and hematite) individual minerals in the three main types of ore shows: in iron oxides (magnetite and hematite), Au and Fe were dissolved simultaneously and their solubilities are positively correlated, which means Au is mainly chemical-bonded (lattice gold) and/or colloidal-adsorbed in iron oxides; while in pyrite, on the contrary, Au dissolution obviously lags behind Fe and the solubility of Au shows negative relationship with that of Fe, which indicates Au is mainly hosted as grains of elemental gold (or native gold) within pyrite. Previous studies revealed that the Hadamengou gold deposit is characterized by intensive K-feldspathization and holds high content of iron oxides occasionally replaced by sulfides, which was caused by oxidizing K-enriched alkaline fluids under a stretching geodynamic setting. These geological features, together with the high Au-content in iron oxides, comparable with that of the Olympic Dam deposit in South Australia, suggest that this deposit is the first example of iron oxide-type gold deposits in China.  相似文献   

4.
The Huai Kham On gold deposit is located in the central part of the Sukhothai Fold Belt, northern Thailand. The Sukhothai Fold Belt represents an accretionary complex formed by subduction and collision between the Indochina and Sibumasu Terranes. There are many small gold deposits in the Sukhothai Fold Belt; however, the styles and formation environments of those gold deposits are not clear. The geology of the Huai Kham On deposit consists of volcanic and volcanosedimentary rocks, limestone, and low‐grade metamorphic rocks of Carboniferous to Triassic age. Gold‐bearing quartz veins are hosted by volcanic and volcanosedimentary rocks. The quartz veins can be divided into four stages. The mineral assemblage of the gold‐bearing quartz veins of Stages I and II comprises quartz, calcite, illite, pyrite, native gold, galena, chalcopyrite, and sphalerite. Quartz veins of Stage III consist of microcrystalline quartz, dolomite, calcite, pyrite, native gold, and chalcopyrite. Veins of Stage IV consist of calcite, dolomite, chlorite, and quartz. Fluid inclusions in quartz veins are classified into liquid‐rich two‐phase (Types IA and IB), carbonic‐aqueous (Type II), and carbonic (Type III) fluid inclusions. The homogenization temperatures of Types IA and II fluid inclusions that are related to the gold‐bearing quartz veins from Stages I to III ranged from 240° to 280°C. The δ18O values of quartz veins of Stages I to III range from +12.9 to +13.4‰, suggesting the presence of a homogeneous hydrothermal solution without temperature variation such as a decrease of temperature during the formation of gold‐bearing quartz veins from Stages I to III in the Huai Kham On gold deposit. Based on the calculated formation temperature of 280°C, the δ18O values of the hydrothermal solution that formed the gold‐bearing quartz veins range from +3.2 to +3.7‰, which falls into the range of metamorphic waters. The gold‐bearing quartz veins of the Huai Kham On deposit are interpreted to be the products of metamorphic water.  相似文献   

5.
The Dongchuang gold deposit in the Xiaoqinling area is an orogenic-type lode gold deposit. It is one of the few superlarge (>100 t Au) deposits in China. Although it has been argued that it was formed in the Mesozoic, related isotopic age data have not been reported in previous studies. Based on detailed geological study, the authors have carried out isotopic dating on various metallogenic generations. The ore-forming process of the Dongchuang gold deposit consists of four stages: coarse-grained pyrite-bearing quartz veins (stage Ⅰ), fine-grained pyrite-quartz veinlets (stage Ⅱ), multi-sulfides (stage Ⅲ) and carbonate-quartz veinlets (stage IV). Ar-Ar dating on mineral separates of stages Ⅰ, Ⅱ and Ⅲ yields plateau ages of 142.9±2.9 Ma, 132.2±2.6 Ma and 128.3±6.2 Ma, respectively. Sericite separates from stage Ⅱ assemblage also yield an Ar-Ar isochron age of 132.6±2.7 Ma, similar to the Ar-Ar plateau age. These results suggest that the Dongchuang gold deposit was mainly formed during 143-128 M  相似文献   

6.
陈国华  黄树桃 《铀矿地质》1998,14(4):207-213
在拉尔玛金铀矿床研究中鉴别出一种新的金矿控矿构造──热液隐爆机构。该机构在平面上呈近椭圆形,剖面上呈漏斗状,顶部为一由热液硅岩构成的“硅盖”,中心部位为热液隐爆角砾岩,其分布范围与金矿体吻合。热液隐爆机构的形成机制为:在硅岩与板岩的交界处形成的热液硅岩“盖”阻塞了热液系统,导致出现过压的地热环境,约49.5Ma时,由于东西向断裂复活,使脆性的硅岩发生破裂,最终导致了热液隐爆作用的发生。热液隐爆作用促使金元素从热液中沉淀,而热液隐爆机构则为金矿化提供了赋存空间。  相似文献   

7.
辽宁朝阳小塔子沟-东五家子金矿田地球化学特征   总被引:1,自引:1,他引:0  
在朝阳小塔子沟-东五家子金矿田范围内,北地金矿、小塔子沟金矿和东五家子金矿,因距离岩体的远近不同,形成了不同的特征.石英流体包裹体研究表明,位于岩体内接触带的北地金矿为中温、中-深成热液矿床,位于岩体外接触带的小塔子沟金矿为中温、中成热液矿床,远离岩体的东五家子金矿为中-低温、浅成热液矿床.氢、氧同位素研究表明,北地金矿和小塔子沟金矿的成矿流体主要为岩浆水,东五家子金矿的成矿流体为岩浆水和大气降水混合成因.微量元素研究表明,北地金矿矿石以Mo、Bi等元素相对富集为特征,小塔子沟金矿矿石以Cu、Zn等元素相对富集为特征,东五家子金矿矿石以Pb、Ag等元素相对富集为特征.矿床离岩体越远,金矿物中Au/Ag比值越小.  相似文献   

8.
The Shuiyindong deposit is one of the largest (more than 100 tonnes of Au) and highest grade (more than 7×10-6-10×10-6), strata-bound Carlin-type gold deposits in southwestern Guizhou Province, China. The deposit is controlled by both structure and favorable lithology. It is situated near the axis of the striking Huijiabao anticline and is hosted in bioclastic limestone of the Permian Longtan Formation. Gold mineralization occurred under low temperature with Th of 220℃± and is closely associated with decarbonation, silicification, sulfidation and dolomitization. The deposit has a characteristic elemental assemblage of Au-As-Hg-Tl. Studies of geochemistry and isotope compositions indicated that the ore-bearing materials and fluids of the gold deposit mainly originated from a plutonic source, and possess a mixing feature with the strata matter during transportation from mantle to crust. Fluid inclusions in vein quartz from the gold deposit are rich in volatile flux, indicating that metallogenic fluid is an overpressured one. The activity and geothermal state of the Earth's crust in the long period of time are favorable for the formation of overpressured fluids in a large area, and extensive structures would drive the fluids into ore-forming system and make gold deposits formed. The complexity of structural movement in the upper crust of southwestern Guizhou Province resulted in complicated gold mineralization. Through metallogenic prognosis and exploration, the proven reserves of the deposit increased by tens of tonnes of Au and the deposit has become a super-large strata-bound Carlin-type gold deposit.  相似文献   

9.
研究矿床的复合成矿作用和矿床组合具有重要的经济和理论意义.作者认为,矿床是与由硅铝层(包括部分绿岩带)深熔而成的花岗岩有成因联系,为绿岩带中的金、银、铁等元素经岩浆的混合作用和后期火山-次火山热液的活化迁移而成的.金矿床的多种成因类型和不同地质特点,与成矿的多期性和阶段性有关.  相似文献   

10.
王登红  陈毓川 《矿床地质》2001,20(2):112-118
文章初步厘定了与海相火作用有关的铁、铜、铅、锌矿床成矿系列类型的概念,并对其进行了分类,讨论了其成因,认为内生外成(沉)是其主要特征,即成矿物质主要由火山作用从深部提供,而矿石又是通过沉积作用在海底形成的。在一定程度上,可从成矿类型的角度将块状硫化物矿床与BIF型或磁铁石英岩型矿床联系起来考虑。该类矿床成矿系列类型的演化特点在一定程度上可以反映地球演化的历史轨迹。  相似文献   

11.
西秦岭造山带发育有大量三叠纪的金矿床,早子沟和加甘滩金矿床是其中最典型的两个矿床,其金资源量分别为116 t和154 t,均为特大型金矿床。早子沟、加甘滩金矿床均位于夏河—合作区域性逆冲推覆断裂以南。早子沟赋矿地层为三叠统古浪堤组,赋矿岩石为泥质板岩、条带状硅质板岩及粉砂质板岩;加甘滩矿区出露地层为三叠统隆务河组,金矿体赋存于长石石英变砂岩夹粉砂质板岩岩性段内。加甘滩金矿床的研究程度相对较低,属中低温构造蚀变岩型金矿床;早子沟金矿床研究程度较高,但是对它的成因仍有不同的认识。石英的微量元素地球化学特征能够提供成矿流体来源与演化的信息,通过对早子沟和加甘滩金矿床开展石英的微量元素地球化学特征研究,探讨其成矿流体来源、成矿条件以及石英微量元素对金矿床形成的指示,为西秦岭造山带金矿床成因研究提供重要的信息。早子沟和加甘滩金矿床不同类型矿石中石英具有相似的稀土元素球粒陨石标准化配分曲线,总体表现出轻稀土元素相对富集、重稀土元素轻微亏损的特征,而且轻稀土元素与重稀土元素分馏程度高,重稀土元素内部分馏程度弱。 早子沟金矿床成矿期热液石英中Rb与Li呈负相关,Rb与Cs呈正相关,而加甘滩金矿床热液石英中Rb与Li、Cs相关性不明显,表明早子沟金矿床石英中Li含量随流体含量的增加而减少,而Cs含量随流体含量的增加而增加。大多数样品具有Eu负异常和弱的Ce正异常,表明早子沟和加甘滩金矿床形成于还原环境,成矿温度较低。样品的(La/Yb)N较大,反映成矿深度相对较浅。石英的Y/Ho值分别为25.14~30.14和23.40~28.94,指示成矿流体与地壳关系密切。大多数石英样品的Th/La和 Nb/La 值小于1,在大陆地壳标准化图解中具有明显的Sc负异常,Cr、W、Pb和U正异常,表明成矿流体富Cl-,相对富集Cr、W、Pb和U等元素。结合大地构造背景分析,早子沟和加甘滩金矿形成于大陆边缘环境。  相似文献   

12.
哈达门沟金矿床产于华北克拉通北缘西段,形成于伸展构造背景中,成矿流体富钾高碱且氧化性强,矿石建造中铁氧化物含量高,并且可见铁氧化物被硫化物交代的现象。文章拟揭示金在铁氧化物中的含量和赋存状态,并探讨金矿床成因。对哈达门沟金矿3种类型矿石中的黄铁矿、铁氧化物(磁铁矿和赤铁矿)单矿物进行金、铁浸取实验,结果表明:铁氧化物含金较高;黄铁矿中的金和铁的浸出曲线不同步,金浸出率与铁浸出率呈负相关,表明黄铁矿中的金主要以颗粒金形式存在;铁氧化物中金、铁同步浸出,浸出率为正相关,表明铁氧化物中的金主要以品格金和(或)胶体吸附金形式存在。哈达门沟金矿床的上述特征均表明其具铁氧化物型金矿床的特点。  相似文献   

13.
阮诗昆 《地质学刊》2019,43(1):50-56
三矿沟—多宝山—争光成矿带为东北地区重要的金属矿集区,发育有三矿沟矽卡岩铜铁矿床、多宝山斑岩铜钼矿床、争光浅成低温金矿床等典型矿床。基于已获得的研究成果,结合前人的资料,重点解剖多宝山、三矿沟和争光3个典型矿床的地质特征,发现3个矿床的成矿类型和地质特征大不相同,成矿时代(加里东期、燕山早期和燕山中期)各异。综合地质研究表明,多宝山矿床形成于岩浆弧背景,三矿沟矿床为弧后伸展背景的产物,争光矿床形成于碰撞后陆壳伸展背景。  相似文献   

14.
蓟县地区雾迷山组风暴硅质岩沉积序列   总被引:2,自引:0,他引:2  
从岩石学和沉积学方面对蓟县雾迷山组硅质岩沉积序列的研究表明,蓟县雾迷山组硅质岩沉积为典型的风暴沉积.蓟县雾迷山组广泛发育风暴沉积,在硅质条带状白云岩中发育的硅质砾屑具奇特的菊花状构造,这种构造形成于成岩作用后期,在岩石尚未完全固结成坚硬的岩石时期,遭遇风暴破坏,将原有的水平层理打碎,继而被风暴流搅起,风暴流的涡动使得岩石碎片或直立,或呈发散状,后经成岩作用保留了这种构造形态,与上下岩层形成典型的风暴沉积序列.通过野外与镜下观察并结合有机地球化学分析得出,蓟县地区雾迷山组硅质岩来源于海底热水活动.风暴硅质岩有两种沉积环境,对于异地搬运再沉积的风暴硅质岩,其沉积环境为潮上坪低能环境,即开阔台地中的泛溢沉积;而对于原地型的风暴硅质岩,其沉积环境应该是潮间带,因此推测其沉积环境为碳酸盐岩台地前缘斜坡.  相似文献   

15.
The Cihai iron-cobalt deposit is located in the southern part of the eastern Tianshan ironpolymetallic metallogenic belt. Anomalous native gold and bismuth have been newly identified in Cinan mining section of the Cihai deposit. Ore formation in the deposit can be divided into three stages based on geological and petrographical observations:(I) skarn, with the main mineral assemblage being garnet-pyroxene-magnetite;(II) retrograde alteration, forming the main iron ores and including massive magnetite, native gold, native bismuth, and cobalt-bearing minerals, with the main mineral assemblage being ilvaite-magnetite-native gold-native bismuth; and(III) quartz-calcitesulfide assemblage that contains quartz, calcite, pyrrhotite, cobaltite, and safflorite. Native gold mainly coexists with native bismuth, and they are paragenetically related. The temperature of initial skarn formation was higher than 340℃, and then subsequently decreased to ~312℃ and ~266℃. The temperature of the hydrothermal fluid during the iron ore depositional event was higher than the melting point of native bismuth(271℃), and native bismuth melt scavenged gold in the hydrothermal fluid, forming a Bi-Au melt. As the temperature decreased, the Bi-Au melt was decomposed into native gold and native bismuth. The native gold and native bismuth identified during this study can provide a scientific basis for prospecting and exploration for both gold- and bismuth-bearing deposits in the Cihai mining area. The gold mineralization in Cihai is a part of the Early Permian Cu-Ni-Au-Fe polymetallic ore-forming event, and its discovery has implications for the resource potential of other iron skarn deposits in the eastern Tianshan.  相似文献   

16.
浅成低温热液型金矿特点、分布和找矿前景   总被引:12,自引:0,他引:12  
浅成低温热液矿床的概念,最初由Lindgren首先提出.20世纪80年代以来环太平洋活动带上一系列大型、超大型金矿床的发现,在世界范围内掀起了一股空前的"浅成低温金矿"热.浅成低温金矿具有低温、低压、低盐度、成矿深度浅的特点.矿化作用发生在火山活动晚期,最终定位于火山地热系统波及范围内.全球浅成低温金矿明显呈集中成带分布的特点,绝大多数分布在著名的环太平洋带、古特提斯带和中亚-蒙古(古亚洲)带.此类金矿成矿在时间上的分布特点大体是①第三纪(最重要)、②第四纪更新世(次重要)、③中生代(重要)、④石炭-二叠纪(次要).成矿环境主要为岛弧带、板内走滑断裂带和上叠火山盆地、陆内裂谷.我国地处三大浅成低温成矿带分布区,已经发现诸如阿希、团结沟、紫金山等金(铜)矿床,找寻同类矿产前景广阔.  相似文献   

17.
The Laloki and Federal Flag deposits are two of the many (over 45) polymetallic massive sulfide deposits that occur in the Astrolabe Mineral Field, Papua New Guinea. New data of the mineralogical compositions, mineral textures, and fluid inclusion studies on sphalerite from Laloki and Federal Flag deposits were investigated to clarify physiochemical conditions of the mineralization at both deposits. The two deposits are located about 2 km apart and they are stratigraphically hosted by siliceous to carbonaceous claystone and rare gray chert of Paleocene–Eocene age. Massive sulfide ore and host rock samples were collected from each deposit for mineralogical, geochemical, and fluid inclusion studies. Mineralization at the Laloki deposit consists of early‐stage massive sulfide mineralization (sphalerite‐barite, chalcopyrite, and pyrite–marcasite) and late‐stage brecciation and remobilization of early‐stage massive sulfides that was accompanied by late‐stage sphalerite mineralization. Occurrence of native gold blebs in early‐stage massive pyrite–marcasite‐chalcopyrite ore with the association of pyrrhotite‐hematite and abundant planktonic foraminifera remnants was due to reduction of hydrothermal fluids by the reaction with organic‐rich sediments and seawater mixing. Precipitation of fine‐grained gold blebs in late‐stage Fe‐rich sphalerite resulted from low temperature and higher salinity ore fluids in sulfur reducing conditions. In contrast, the massive sulfide ores from the Federal Flag deposit contain Fe‐rich sphalerite and subordinate sulfarsenides. Native gold blebs occur as inclusions in Fe‐rich sphalerite, along sphalerite grain boundaries, and in the siliceous‐hematitic matrix. Such occurrences of native gold suggest that gold was initially precipitated from high‐temperature, moderate to highly reduced, low‐sulfur ore fluids. Concentrations of Au and Ag from both Laloki and Federal Flag deposits were within the range (<10 ppm Au and <100 ppm Ag) of massive sulfides at a mid‐ocean ridge setting rather than typical arc‐type massive sulfides. The complex relationship between FeS contents in sphalerite and gold grades of both deposits is probably due to the initial deposition of gold on the seafloor that may have been controlled by factors such as Au complexes, pH, and fO2 in combination with temperature and sulfur fugacity.  相似文献   

18.
前寒武纪时期铁矿形成过程中铁物质如何迁移的研究,已取得了众多科研成果,但仍有些问题未得到很好的解决。尤其是对陆壳来源性铁矿床(非Algoma类型)的成因,仍然具有诸多争议,焦点主要集中在铁迁移问题。笔者以朝鲜半岛龙渊铁矿床为例研究了铁介质形成和运输的问题。首先通过铁矿石的地球化学研究和前人研究结果的考察,发现此铁矿床不属于Algoma类型,而是在强酸性介质条件下陆壳物质风化、移动和沉积而形成的。那么为什么会出现如此强大的酸性环境条件呢?为了揭示这一点,对在当时环境下把水的性质能够变成酸性的物质进行了热力学计算。研究结果表明,当硫化物如黄铁矿风化时,形成了能够使铁源物质风化和迁移的介质。这些结果也符合这样一个事实,即目前从富含硫化物地层淋沥的水的pH值小于3.5,并且铁含量远高于非硫化物类型的地层。本次研究结果表明,陆壳来源的铁矿床形成过程中,不能忽视硫化物的风化作用。  相似文献   

19.
The Mupane gold deposit, which is one of the numerous gold occurrences in the Tati Greenstone Belt in the northeastern part of Botswana, consists of four orebodies, namely Tau, Tawana, Kwena, and Tholo deposits. The present research, which focuses on the genesis of the Tau deposit, was based on ore petrography, mineral chemistry of sulfides, and sulfur isotope data. Mineralogical characteristics of the host rocks indicate that banded iron formation at the Tau deposit includes iron oxides (magnetite), carbonates (siderite and ankerite), silicates (chlorite and amphibole), and sulfides (arsenopyrite and pyrrhotite). The deposit features arsenopyrite-rich zones associated with biotite-chlorite veins, which are indicative of the precipitation of arsenopyrite concomitant with potassic alteration. The replacement of magnetite by pyrrhotite in some samples suggests that sulfidation was likely the dominant gold precipitation mechanism because it is considered to have destabilized gold-thiocomplexes in the ore-forming fluids. Based on textural relationships and chemical composition, arsenopyrite is interpreted to reflect two generations. Arsenopyrite 1 is possibly early in origin, sieve textured with abundant inclusions of pyrrhotite. Arsenopyrite 1 was then overgrown by late arsenopyrite 2 with no porous textures and rare inclusions of pyrrhotite. Gold mineralization was initiated by focused fluid flow and sulfidation of the oxide facies banded iron formation, leading to an epigenetic gold mineralization. The mineralogical assemblages, textures, and mineral chemistry data at the Tau gold deposit revealed two-stage gold mineralizations commencing with the deposition of invisible gold in arsenopyrite 1 followed by the later formation of native gold during hydrothermal alteration and post-depositional recrystallization of arsenopyrite 1. Laser ablation inductively coupled plasma mass spectrometric analysis of arsenopyrite from the Tau deposit revealed that the hydrothermal event responsible for the formation of late native gold also affected the distribution of other trace elements within the grains as evidenced by varying trace elements contents in arsenopyrite 1 and arsenopyrite 2. The range of δ34S of gold-bearing assemblages from the Tau deposit is restricted from +1.6 to +3.9‰, which is typical of Archean orogenic gold deposits and indicates that overall reduced hydrothermal conditions prevailed during the gold mineralization process at the Tau deposit. The results from this study suggest that gold mineralization involved multi-processes such as sulfidation, metamorphism, deformation, hydrothermal alteration, and gold remobilization.  相似文献   

20.
贵州老万场红土型金矿地球化学特征及其成因   总被引:4,自引:0,他引:4  
陈履安 《地质论评》2000,46(6):628-637
对贵州西南部晴隆老万场红土型金矿与相关岩石(矿石)和喀斯特红土等进行了常量元素、微量元素和稀土元素地球化学比较研究,阐明了矿床的各类元素的地球化学特征,追溯了矿术的物质来源。研究表明,本类红土型金矿的物质来源是高硅质(石英)、富铁质(黄铁矿等)的富金矿(岩)石;具有Au-As-Sb-Hg-Tl-W-Ag-Ba的微量元素组合特征,与卡林型金矿十分相似,是原始卡林型金矿风化演化的产物。常量元素和稀土元  相似文献   

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