多孔介质中非水相流体运移的数值模拟

针对多孔介质中水、气和非水相流体(NAPLs)的多相流动特点,建立了非水相流体(NAPLs)污染物迁移模型,分析了非水相流体在土壤非饱和区和地下水系统中的运移规律。通过有限元数值解对轻非水相流体和重非水相流体在土壤系统中的迁移过程进行模拟,得到了污染物的时空分布特征和污染范围。计算结果表明,数值模拟方法能够合理地描述非水相流体的运移过程和污染特征。土体渗透性和污染物残余饱和度是其重要影响因素。     

Simulation of polychlorinated biphenyls transport in the vadose zone

Polychlorinated biphenyls (PCBs) are the main constituents of clophen (the liquid of the electric transformers and capacitors) and have been characterized as potential human carcinogens. PCBs can be a hazardous contaminant of soil and groundwater. We used the mathematical model variably saturated 2D flow and transport (VS2DT model) to simulate the transport of PCBs from the soil surface to groundwater for a time period of 30 years. We also used a mathematical model to simulate the colloid-facilitated PCB transport, under saturated flow conditions. The results showed that PCBs dissolved in water cannot be transported to large depths in unsaturated soils, because of their strong sorption onto soil and low solubility in water. For soils with very low or no organic matter content, PCB transport is much faster and the probability of groundwater contamination is much higher. PCBs can partition to colloids originating from dissolved organic matter in groundwater. Colloid-facilitated PCB transport is faster compared to PCB transport in aqueous solution with no colloids present.     

考虑污染物扩散风险的场地地下水污染多层次风险评估方法

地下水中污染物具有迁移性和扩散性,会对下游敏感受体造成威胁,目前场地地下水风险评估主要关注人体健康风险,还未能综合考虑地下水污染的整体风险,尤其是忽视了污染物迁移引起的对下游敏感受体的风险。本研究基于“源-径-汇”模型构建了考虑污染物扩散风险的场地地下水污染风险评估的指标体系与风险评估模式。在指标体系构建方面,重点考虑场地地下水的污染源、迁移路径和敏感受体3个方面。在风险评估模式方面,根据场地不同地下水污染状态开展3个层次的风险评估。基于假想的铬污染场地开展了案例分析,设置了地下水污染状态的4种情景,利用Wexler溶质运移模型计算了地下水污染羽的时空变化,并针对地下水污染的不同层次开展了风险评估。结果表明,在场地地下水污染羽未到达场地边界的2种情形中,场地地下水的风险评分分别为4.0,6.2,分别属于低风险与中风险。在场地地下水污染羽到达或超出场地边界的2种情形中,场地地下水的风险评分分别为7.0,8.8,分别属于中风险与高风险。综合而言,本研究构建的方法能够用来对场地地下水进行系统全面的评估和对比,能够根据风险结果对污染场地进行有效的分级管控,为污染场地的风险管控提供技术支撑。     

PHREEQC在地下水溶质反应-运移模拟中的应用

由于地下水污染的加剧,对地下水中污染物运移规律的研究日益受到重视。地下水中的溶质在运移过程中伴随着溶质组分间的化学反应,因此需要建立地下水溶质运移与化学反应的耦合模型。PHREEQC是近年来发展起来的描述局部平衡反应、动态生物化学反应的水文地球化学模拟软件。本文利用该模拟软件对一维地下水流动过程中溶质离子交换反应和动态氧化还原反应进行了模拟。结果表明,PHREEQC能够成功地进行溶质运移情况下复杂水化学反应模拟,但对于复杂地下水流和溶质运动的情况,有必要耦合其它的地下水流动和溶质运移软件来共同完成。     

Groundwater vulnerability to pesticides in Northwest Bangladesh

The transport and leaching potential hazards of various pesticides were studied in a shallow unconfined aquifer located in Northwest Bangladesh. Pesticide leaching potential was quantified using a one-dimensional advective–dispersive transport equation for a non-conservative chemical that follows first-order decay and linear adsorption in soils. Leaching potential index (LPI) was calculated for 69 sites in the study area to evaluate the relative vulnerability to pesticide leaching and to prioritize sites for model study and soil sampling. The numerical ranks of computed LPI were grouped by quantiles into very high, high, moderate, low and very low categories; and based on these rankings, the most vulnerable site was selected. The fate and transport of pesticides in this most vulnerable site was modeled using MT3D. The model results indicate that pesticides with high sorptivity and moderate to high persistence have low potential impact on groundwater. Top soils are found to be particularly vulnerable to the accumulation of organochlorine pesticides. Results also revealed that decreasing the soil organic matter and increasing the half-life of the pesticides at deeper depths did not make any significant change. Finally, six soil samples were collected from the same site at depths of 0.0, 1.5, 3.0, 4.5, 6.0, and 7.5 m for the analysis of pesticide residues. The soil–water was extracted from the samples following standard extraction technique and tested using gas chromatography (GC) and high-performance liquid chromatography (HPLC) for pesticide residues. Results showed no trace of pesticide residues in the soil–water; however, a few unknown peaks were detected indicating the use of some unknown brand of chemicals in the study area.     

Ways of investigating radionuclide migration processes in the lithosphere and hydrosphere

In Russia, until recently, it was considered that groundwater was protected from surface radioactive contamination by soil and rocks in the zone aeration. Groundwater was not a subject of radiation control. The accident at the Chernobyl Nuclear Power Plant showed, however, that groundwater is vulnerable to radioactive contamination. In this connection, the vulnerability of groundwater to and the problems of protecting groundwater from radioactive contamination became urgent. The assessment of natural protection of groundwater from radioactive contamination is now considered a top priority. The zone of aeration is generally considered to be the zone separating groundwater from surface contamination. In respect to radioactive contamination, soils that may fix a large quantity of radionuclides serve as a protection zone of a higher order. The mapping of protectibility was done for each radionuclide taking into consideration the specific structure of the flow medium and migration properties of a radionuclide.⁹⁰Sr and¹³⁷Cs have different mechanisms of transport; convective transport is characteristic of the former and diffusive transfer of the latter. This is conditioned by different physico-chemical properties of the radionuclides and principally by their sorption capacities. The coefficient of distribution of⁹⁰Sr is in many times less than the coefficient of distribution of¹³⁷Cs. The environmental protection problem in regions with nuclear power plants and in areas subjected to radioactive contamination may be solved using a monitoring, system including interrelated systems of observation and prediction of the lithosphere and the hydrosphere. The problem of mathematical modeling of migration processes is related to the complexities of modeling the processes of flow, mass transfer, and the accompanying physicochemical processes in zones of full and partial saturation, as well as difficulties in mathematical calculations.     

Sorption behaviour of pentachlorophenol in sub-Saharan tropical soils: soil types sorption dynamics

In order to predict exposure risks as well as appropriate remediation strategies for pesticides in soils, knowledge of pesticides sorption processes onto various representative soils is vital. Hence, laboratory batch experiments were carried out to study sorption of a pesticide, pentachlorophenol (PCP), on five soils obtained from different sub-Saharan agro-ecological zones (AEZs) in order to understand sorption equilibrium, kinetics, and thermodynamics. Experimental data showed that sorption equilibrium was attained within 24 h. The fitting of kinetic results and equilibrium data to different models suggested partly surface adsorption and partly partitioning of PCP within voids of the various soil components. Sorption was mainly attributed to sharing or exchange of valence electrons between negatively charged PCP molecules and positively charged soil sorption sites. The sorption process was spontaneous and accompanied by decreased entropy, but was pH and temperature dependent, reducing with increase in pH and temperature. The various soils’ PCP sorption capacities were directly proportional to their cation exchange capacities. The low PCP sorption observed in these soils suggested high risk of PCP being present in soil water solution, especially at higher temperatures, which can lead to contamination of the aquifer. This risk may be higher for soils obtained from AEZs with warmer natural temperatures.     

地下水和土壤环境中雌激素运移和归宿的研究进展

环境内分泌干扰物已成为引起全球关注的环境问题;地下水和包气带土壤中雌激素的富集、运移和归宿关系到人类和生态健康。本文通过对环境雌激素的性质、分类、检测方法等方面进行综述,揭示其对生物体乃至环境的多种危害和风险,针对地下水和土壤环境特征分析其迁移转化过程、理解其控制和治理技术方法,进而为降低雌激素的生态和环境风险提供指导。通过论述研究环境雌激素的重要意义,提出对雌激素对地下水系统污染防控可能研究领域进行系统展望。     

Modified DRASTIC assessment for intrinsic vulnerability mapping of karst aquifers: a case study

Groundwater in karstic aquifers can be dangerously sensitive to contamination. In this paper, DRASTIC assessment was modified and applied, for the first time, to address the intrinsic vulnerability for karst aquifers. The theoretical weights of two of DRASTIC’s parameters (aquifer media and hydraulic conductivity) were modified through sensitivity analysis. Two tests of sensitivity analyses were carried out: the map removal and the single parameter sensitivity analyses. The modified assessment was applied for the karst aquifers underlying Ramallah District (Palestine) as a case study. The aquifer vulnerability map indicated that the case study area is under low, moderate and high vulnerability of groundwater to contamination. The vulnerability index can assist in the implementation of groundwater management strategies to prevent degradation of groundwater quality. The modified DRASTIC assessment has proven to be effective because it is relatively straightforward, use data that are commonly available or estimated and produces an end product that is easily interpreted.     

Pesticides associated with suspended sediemnts entering San Francisco Bay following the first major storm of water year 1996

Estuaries receive large quantities of suspended sediments following the first major storm of the water year. The first-flush events transport the majority of suspended sediments in any given year, and because of their relative freshness in the hydrologic system, these sediments may carry a significant amount of the sediment-associated pesticide load transported into estuaries. To characterize sediment-associated pesticides during a first-flush event, water and suspended sediment samples were collected at the head of the San Francisco Bay during the peak in suspended sediment concentration that followed the first major storm of the 1996 hydrologic year. Samples were analyzed for a variety of parameters as well as 19 pesticides and degradation products that span a wide range of hydrophobicity. Tidal mixing at the head of the estuary mixed relatively fresh suspended sediment transported down the rivers with suspended sediments in estuary waters. Segregation of the samples into groups with similar degrees of mixing between river and estuary water revealed that transport of suspended sediments from the Sacramento-San Joaquin drainage basin strongly influenced the concentration and distribution of sediment-associated pesticides entering the San Francisco Bay. The less-mixed suspended sediment contained a different distribution of pesticides than the sediments exposed to greater mixing. Temporal trends were evident in pesticide content after samples were segregated according to mixing history. These results indicate sampling strategies that collect at a low frequency or do not compare samples with similar mixing histories will not elucidate basin processes. Despite the considerable influence of mixing, a large number of pesticides were found associated with the suspended sediments. Few pesticides were found in the concurrent water samples and in concentrations much lower than predicted from equilibrium partitioning between the aqueous and sedimentary phases. The observed sediment-associated pesticide concentrations may reflect disequilibria between sedimentary and aqueous phases resulting from long equilibration times at locations where pesticides were applied, and relatively short transit times over which re-equilibration may occur.     

Assessment of aquifer vulnerability to contamination in Khanyounis Governorate, Gaza Strip—Palestine, using the DRASTIC model within GIS environment

Groundwater is a very important natural resource in Khanyounis Governorate (the study area) for water supply and development. Historically, the exploitation of aquifers in Khanyounis Governorate has been undertaken without proper concern for environmental impact. In view of the importance of quality groundwater, it might be expected that aquifer protection to prevent groundwater quality deterioration would have received due attention. In the long term, however, protection of groundwater resources is of direct practical importance because, once pollution of groundwater has been allowed to occur, the scale and persistence of such pollution makes restoration technically difficult and costly. In order to maintain basin aquifer as a source of water for the area, it is necessary to find out, whether certain locations in this groundwater basin are susceptible to receive and transmit contamination. This study aims to: (1) assess the vulnerability of the aquifer to contamination in Khanyounis governorate, (2) find out the groundwater vulnerable zones to contamination in the aquifer of the study area, and (3) provide a spatial analysis of the parameters and conditions under which groundwater may become contaminate. To achieve that, DRASTIC model within geographic information system (GIS) environment was applied. The model uses seven environmental parameters: depth of water table, net recharge, aquifer media, soil media, topography, impact of vadose zone, and hydraulic conductivity to evaluate aquifer vulnerability. Based on this model and by using ArcGIS 9.3 software, an attempt was made to create vulnerability maps for the study area. According to the DRASTIC model index, the study has shown that in the western part of the study area the vulnerability to contamination ranges between high and very high due to the relatively shallow water table with moderate to high recharge potential, and permeable soils. To the east of the previous part and in the south-eastern part, vulnerability to contamination is moderate. In the central and the eastern part, vulnerability to contamination is low due to depth of water table. Vulnerability analysis of the DRASTIC Model indicates that the highest risk of contamination of groundwater in the study area originates from the soil media. The impact of vadose zone, depth to water level, and hydraulic conductivity imply moderate risks of contamination, while net recharge, aquifer media, and topography impose a low risk of aquifer contamination. The coefficient of variation indicates that a high contribution to the variation of vulnerability index is made by the topography. Moderate contribution is made by the depth to water level, and net recharge, while impact of vadose zone, hydraulic conductivity, soil media, and Aquifer media are the least variable parameters. The low variability of the parameters implies a smaller contribution to the variation of the vulnerability index across the study area. Moreover, the “effective” weights of the DRASTIC parameters obtained in this study exhibited some deviation from that of the “theoretical” weights. Soil media and the impact of vadose zone were the most effective parameters in the vulnerability assessment because their mean “effective” weights were higher than their respective “theoretical” weights. The depth of water table showed that both “effective” and “theoretical” weights were equal. The rest of the parameters exhibit lower “effective” weights compared with the “theoretical” weights. This explains the importance of soil media and vadose layers in the DRASTIC model. Therefore, it is important to get the accurate and detailed information of these two specific parameters. The GIS technique has provided an efficient environment for analysis and high capabilities of handling large spatial data. Considering these results, DRASTIC model highlights as a useful tool that can be used by national authorities and decision makers especially in the agricultural areas applying chemicals and pesticides which are most likely to contaminate groundwater resources.     

Effects of water extraction in a vulnerable phreatic aquifer: Consequences for groundwater contamination by pesticides, Sint-Jansteen area, The Netherlands

Pesticides are a potential threat to the quality of extracted groundwater when the water-supply area is used for agricultural activities. This problem is discussed for the water-supply area of Sint-Jansteen, The Netherlands, where measured pesticide concentrations in the extracted water regularly exceed EU limits (0.1 μg/L). Groundwater samples taken from the aquifer within the water-supply area show low contamination, but samples taken from the extracted water occasionally contain pesticides, making the water inadequate for drinking-water purposes. The more intense contamination of the extracted water is caused by the change in the natural groundwater flow pattern near the extraction wells. In this area, pesticide use cannot be avoided easily, and an approach is given to differentiate pesticide use in the area according to expected travel time toward the wells and the chemical characteristics of the pesticides. A groundwater flow model for the area is developed and the effects of groundwater extraction on the natural flow pattern are evaluated. Using particle tracking, the travel-time zones are determined. Combining these results and the degradation behavior of certain pesticides led to an optimal scheme to integrate agricultural activities and groundwater extraction in the area. This is illustrated for five different types of pesticides (atrazine, simazine, bentazone, MCPA, and mecoprop). Received, October 1998/Revised, July 1999, September 1999/Accepted, November 1999     

Groundwater quality and rural drinking-water supplies in the Republic of Moldova

 This paper describes the results of a groundwater quality assessment conducted in two pilot areas, Balatina and Carpineni, in the Republic of Moldova. Shallow groundwater is the main source of drinking water in rural areas, but reliable data on its quality are currently insufficient for developing rural water-supply systems with standard designs. The main components of the study included a field sampling program (including pesticides), an evaluation of the reliability of existing drinking-water data, an analysis of land use and groundwater-pollution risks using GIS, and the formulation of recommendations to reduce risks for public health. Microbiological, nitrate, and selenium contamination are most serious in the villages. These contaminants should be given priority in addressing drinking-water aspects for rural water-supply development in the two pilot areas. Pollution occurs mainly due to poor sanitary conditions. In a few shallow wells, traces of selected pesticides were observed, but the effect of these levels of pesticides on public health is still unclear. Limited resources of shallow groundwater of good quality occur outside the villages. Additional pilot studies should be implemented to prove the technical and institutional feasibility of developing and protecting these resources. Received, September 1997 Revised, September 1998 Accepted, March 1999     

Soil and groundwater pollution of an urban catchment by trace metals: case study of the Addis Ababa region, central Ethiopia

Analysis of the total heavy metal (Cr, Cd, Pb, As, Cu, Ni, Zn, Co) concentration was performed on 33 soil samples taken from different profiles and soil types in a highly urbanized and industrial sector of Addis Ababa, central Ethiopia. They were analyzed using aqua regia extraction coupled with a four-stage sequential extraction (SE) procedure. The objectives of the analysis were to investigate the degree of soil heavy metal contamination, its binding forms, mobility and the implications for the groundwater resource. The results show a relatively high content of the analyzed trace metals in the soil attributed to anthropogenic and geogenic sources. Although most of the trace metals are found in the upper few centimeters of the residual soils, because of churning processes within the black cotton soils, vertical distribution of the trace metals is complex. According to the heavy metal SE analysis, the major heavy metal contribution is from the residual followed by the hydroxide phases. Groundwater heavy metal contamination is present with more than 90 and 50% of the analyzed groundwater samples exceeding WHO guidelines for Cr and Cd, respectively. Since the degree of soil heavy metal contamination has apparently not surpassed the soil’s buffering capacity, it appears that the transport path of these toxic metals to the groundwater is through fractures, joints, and related preferential flow paths.     

Movement of DBCP in laboratory soil columns and field soils to groundwater

The nematocide DBCP has been an effective chemical for the control of nematodes but, because of contamination of groundwaters and for health reasons, its use has been curtailed. To evaluate the tendency of DBCP to leach, adsorption and transport characteristics were examined on laboratory samples of a field soil through which the chemical was also leached. Adsorption of DBCP on Panoche clay loam was small, and displacement experiments in soil columns demonstrated that loading rate and flux of water were significant for the dissipation of the chemical by microbial degradation and/or volatilization. Dissipation rate constants were estimated by optimizing the fit to experimental BTCs of the convective-dispersion equation with linear adsorption and a first-order degradation rate. Although field measurements did not establish conclusively that leaching to groundwater would occur in a fine-textured soil, evidence was obtained that leaching below the root zone could occur in many soils.     

Effect of copper on biochemical responses of the earthworm Eiseniafetida

Contamination sites pose significant environmental hazards to terrestrial ecosystems. Evaluation of the effects of contaminants in soils has become a priority for OECD countries. The biomarker approach is widely used both in vertebrates and in invertebrates for environmental biomonitoring. Eisenia fetida would provide diagnostic and prognostic early warning tests for monitoring soil contamination. These responses, often called early warning signals, would, in fact, give very important information when assessing the environmental risks of contamination. However, the use of biomarkers requires the identification of every possible variation that can influence the biochemical response, because ecosystems are generally subject to a mixture of pollutants,     

Numerical study of soil heterogeneity effects on contaminant transport in unsaturated soil (model development and validation)

The movement of chemicals through soil to groundwater is a major cause of degradation of water resources. In many cases, serious human and stock health implications are associated with this form of pollution. The study of the effects of different factors involved in transport phenomena can provide valuable information to find the best remediation approaches. Numerical models are increasingly being used for predicting or analyzing solute transport processes in soils and groundwater. This article presents the development of a stochastic finite element model for the simulation of contaminant transport through soils with the main focus being on the incorporation of the effects of soil heterogeneity in the model. The governing equations of contaminant transport are presented. The mathematical framework and the numerical implementation of the model are described. The comparison of the results obtained from the developed stochastic model with those obtained from a deterministic method and some experimental results shows that the stochastic model is capable of predicting the transport of solutes in unsaturated soil with higher accuracy than deterministic one. The importance of the consideration of the effects of soil heterogeneity on contaminant fate is highlighted through a sensitivity analysis regarding the variance of saturated hydraulic conductivity as an index of soil heterogeneity. Copyright © 2011 John Wiley & Sons, Ltd.     

构建地下水污染防护与修复管理中的综合决策系统(英文)

试图阐述如何对一个国家或地区在可持续发展国策下优化资金及人力配置,采取必要的防护和修复地下水污染的可行措施,从而最大限度减少由地下水污染对人类及生态可能产生的危害。提出了一个管理地下水污染防护与修复的综合决策系统框架。该系统框架的构筑是基于资金及人力的有限性、系统优化原理、地下水污染对人类及生态可能产生的危害,地下水防护与修复的难度或费用高低、地下水保护的效益与价值,以及同时考虑满足可持续发展要求。其中,由不同地下水污染防护与修复措施产生的地下水污染危害减少量构成了优化分析的目标函数。有限资金的最佳配置是通过使目标函数的最大化,并满足所有的管理、资源等限制条件加以确定的。还就执行该决策系统框架中所需完成的主要任务及步骤给予简述,并就几个相关的前沿性问题加以探讨。     

Transport,fate, and infectivity of <Emphasis Type="Italic">Cryptosporidium parvum</Emphasis> oocysts released from manure and leached through macroporous soil

A major mode of transmission of Cryptosporidium parvum, a widespread waterborne pathogen, is via contaminated drinking and recreational waters. Oocyst transport to surface water can occur by deposition of manure directly in the water or by wash off in surface runoff. Oocyst transport to groundwater is less straightforward and requires that the oocysts move through soil and bedrock to reach the water table. The purpose of this study was to determine the relative concentration and infectivity of C. parvum oocysts released from manure and leached through columns of undisturbed, macroporous karst soil. Modeling the fate of oocysts in this system over time can provide baseline data for evaluating real world events. Substantially more oocysts leached from undisturbed soil columns than disturbed soil columns. Oocyst survival studies using BALB/c neonatal suckling mice showed that about 85% of oocysts were infective at the beginning of leaching experiments. The oocyst infectivity decreased to about 20% after 12 weeks of leaching from soil columns maintained at 10°C. Cool (10°C) temperatures appear to increase survivability and maintain infectivity of many oocysts for 3 months or longer. Cool temperatures also appear to increase rates of release of oocysts from manure and leaching through soil. This study demonstrated that leaching is an important mechanism of oocyst transport in karst soils where infiltration capacities are high and long, continuous macropores exist. Karst groundwater systems might be especially vulnerable to contamination by leached oocysts, because of the prevalence of shallow soils and rapid groundwater movement. Oocysts leaching from soils into the epikarst could accumulate and remain viable for months until hydrological conditions are right for flushing the oocysts into the conduit flow system.