Kinetic Modeling of Diagenesis of Eogene Lacustrine Sandstone Reservoirs in the Jianghan Basin,Southeastern China

In the Tuoshi oilfield,located in the Cenozoic Jianghan Basin of southeastern China ,there have been found hydrocarbon reservoirs hosted in lacustrine sandstones of the Eogene Xingouzui Formation.The main diagenetic features identified in these sandstones include the dissolution of detrital K-feldspar and albite grains,the precipitation of quartz as overgrowths and /or cements ,and the precipitation and /or transformation of clay minerals.These diagenetic features were interpreted to have occurred in early,intermediate and late stages,based on the burial depth.The kinetics of fluid-mineral reactions and the concentrations of aqueous species au each stage of diagenesis were simulated numerically for these lacustrine sandstones,using a quasi-sta-tionary state approximation that incorporates simultaneous chemical reactions in a time-space continuum.During the early diagenetic stage,pore fluid was weakly acidic,which resulted in dissolution of K-feldspar and albite and,therefore,led to the release of K^ ,Na^ ,Al^3 and SiO2(aq) into the diagenetic fluid.The increased K^ ,Na^ ,Al^3 and SiO2(aq) concentrations in the diagenetic fluid caused the precipitation of quartz,kaolinite and illite.At the beginning of the intermediate diagenetic stage the concentration of H^ was built up due to the decomposition of organic matter,which was responsible for further dissolution of K-feldspar and albite and pre-cipitation of quartz,kaolinite,and illite.During the late diagenetic stage,the pore fluid was weakly alkaline,K-feldspar became stable and was precipitated with quartz and clay minerals.When the burial depth was greater than 3000 m,the pore fluids became supersaturated with respect to allbite,but undersaturated with respect to quartz,resulting in the precipitation of albite and the dissolution of quartz.The diagenetic reactions forecasted in the numerical modeling closely matched the diagenet-ic features identified by petrographic examination, and therefore,can help us to gain a better understanding of the diagenetic processes and associated porosity evolution in sandstone reservoirs.     

K- and Si-Metasomatism, Mineral Transformation and Formation of Granitoids from Basic Rocks in Qooshchi Area, NW Iran. A Mineralogical Context

The Qooshchi area lies to northwest of Orumieh Lake in western Azerbaijan, NW Iran. A basement metamorphic complex, consisting of Precambrian schists and gneisses, has been intruded by gabbres and diorites. Granitolds are grouped into five suites according to their mineralogy, texture and exposed features. The main body, pink Qooshchi granite, and apophyse-like, myrmekite-bearing granit-oids are discussed in this paper. On the basis of field observations and microscopic studies, an intensive metasonmtism has overprinted the country rocks, especially gabbros, transforming them into a more felsic composition. A prior event of intensive deformation and cataclasis preceded the metasonmtism, al-lowing the introduction of hydrothermal fluids. K-metasonmtism converted plagiuclase into K-feldspar (microdme), myrmekite, and sodic plagioclase as Si-metasomatism replaced the ferromagnesian silicates by quartz. Apophyse-like bodies within gabbros, called leucometasomatites, are formed during this process.