Fe‐bearing phases in a ureilite fragment from the asteroid 2008 TC3 (= Almahata Sitta meteorites): A combined Mössbauer spectroscopy and X‐ray diffraction study

The iron‐bearing phases in a ureilite fragment (AS#051) from the Almahata Sitta meteorite are studied using Mössbauer spectroscopy, X‐ray diffraction (XRD), and electron microprobe analysis (EMPA). AS#051 has a typical ureilite texture of medium‐ to coarse‐grained silicates (olivine, orthopyroxene, and pigeonite) with minor opaques (Fe‐Ni metal, troilite, and graphite). The silicate compositions, determined by EMPA, are homogeneous: olivine (Fo_90.2), orthopyroxene (En_86.3Fs_8.6Wo_5.1), and pigeonite (En_81.6Fs_8.9Wo_9.5), and are similar to those of magnesian ureilites. The modal abundance of mineral phases was determined by Rietveld refinement of the powder XRD data. The Mössbauer spectra at 295 K and 78 K are composed of two sharp well‐defined paramagnetic doublets superimposed on a well‐resolved magnetic sextet and other weak absorption features. The two paramagnetic doublets are assigned to olivine and pyroxene (orthopyroxene and pigeonite), and the ferromagnetic sextet to kamacite (magnetic hyperfine field ≈ 33.2 T), in agreement with the XRD characterization. The Mössbauer results also show the presence of small amounts of troilite (FeS) and cohenite ([Fe,Ni,Co]₃C). Using the Mössbauer data, the relative abundance of each Fe‐bearing phase is determined and compared with the results obtained by XRD.     

Mineralogy and petrology of the Dar al Gani 476 martian meteorite: Implications for its cooling history and relationship to other shergottites

Abstract— Dar al Gani 476, the 13th martian meteorite, was recovered from the Sahara in 1998. It is a basaltic shergottitic rock composed of olivine megacrysts reaching 5 mm (24 vol%) set in a finegrained groundmass of pyroxene (59 vol%) and maskelynitized plagioclase (12 vol%) with minor amounts of accessory phases (spinel, merrillite, ilmenite). Dar al Gani 476 is similar to lithology A of Elephant Moraine A79001 (EETA79001) in petrography and mineralogy, but is distinct in several aspects. Low‐Ca pyroxenes in the Dar al Gani 476 groundmass are more magnesian (En₇₆Fs₂₁ Wo₃～En₅₈Fs₃₀Wo₁₂) than those in lithology A of EETA79001 (En₇₃Fs₂₂Wo₅～En₄₅Fs₄₃Wo₁₂), rather similar to pyroxenes in lherzolitic martian meteorites (En₇₆Fs₂₁ Wo₃～En₆₃Fs₂₂Wo₁₅). Dar al Gani 476 olivine is less magnesian and shows a narrower compositional range (Fo_76‐58) than EETA79001 olivine (Fo_81‐53), and is also similar to olivines in lherzolitic martian meteorites (Fo_74‐65). The orthopyroxene‐olivine‐chromite xenolith typical in the lithology A of EETA79001 is absent in Dar al Gani 476. It seems that Dar al Gani 476 crystallized from a slightly more primitive mafic magma than lithology A of EETA79001 and several phases (olivine, pyroxene, chromite, and ilmenite) in Dar al Gani 476 may have petrogenetic similarities to those of lherzolitic martian meteorites. Olivine megacrysts in Dar al Gani 476 are in disequilibrium with the bulk composition. The presence of fractured olivine grains in which the most Mg‐rich parts are in contact with the groundmass suggests that little diffusive modification of original olivine compositions occurred during cooling. This observation enabled us to estimate the cooling rates of Dar al Gani 476 and EETA79001 olivines, giving similar cooling rates of 0.03‐3 °C/h for Dar al Gani 476 and 0.05‐5 °C/h for EETA79001. This suggests that they were cooled near the surface (burial depth shallower than about 3 m at most), probably in lava flows during crystallization of groundmass. As is proposed for lithology A of EETA79001, it may be possible to consider that Dar al Gani 476 has an impact melt origin, a mixture of martian lherzolite and other martian rock (Queen Alexandra Range 94201, nakhlites?).     

Al Huwaysah 010: The most reduced brachinite,so far

Al Huwaysah 010 is an ungrouped achondrite meteorite, recently referred to as a brachinite-like meteorite. This meteorite, showing a fine-grained assemblage of low-Ca pyroxene and opaque phases, is strongly reduced in comparison to other reduced brachinites. The occurrence of some tiny plates of graphite and oldhamite in this meteorite suggests that a partial melt residue has experienced a further reduction process. Olivine, the most abundant phase, is compositionally homogeneous (Fo_83.3) as well as the clinopyroxene (En_45.5Fs_10.8Wo_43.7) and the plagioclase (Ab_69.5). Orthopyroxene (En_85.4Fs_13.9Wo_0.7) also occurs but only in a fine intergrowth. Other accessory phases are Fe metal grains (Ni-free or Cr-bearing Fe-Ni alloy), troilite, chlorapatite, pentlandite (as inclusions in chromite). The sample shows two different closure temperatures: the highest (≈900°C) is determined via the olivine–chromite intercrystalline geothermometer and the lowest temperature (≈520°C) is determined via the pyroxene-based intracrystalline geothermometer. These temperatures may represent, respectively, the closure temperature associated with the formation and a subsequent impact event excavating the sample from the parental body. The visible to near-infrared (VNIR) reflectance spectra of Al Huwaysah 010 exhibit low reflectance, consistent with the presence of darkening components, and weak absorptions indicative of olivine and pyroxene. Comparing the spectral parameters of Al Huwaysah 010 to potential parent bodies characterized by olivine–pyroxene mineralogy, we find that it falls within the field previously attributed to the SIII type asteroids. These results lead us to classify the Al Huwaysah 010 meteorite as the most reduced brachinite, whose VNIR spectral features show strong affinities with those of SIII asteroids.     

NEPHELINE AND SODALITE IN A BARRED OLIVINE CHONDRULE FROM THE ALLENDE METEORITE

Nepheline and sodalite have been found in association with glass in a barred olivine chondrule from the Allende C3V meteorite. The major minerals of the chondrule are olivine (Fo_80–88), bronzite (En₈₅Fs₁₂Wo₃), and chromite. Olivine bars are separated by glass of nearly pure plagioclase composition (An_81–99). Olivine composition is more Fe-rich than predicted by olivine-liquid equilibria (Fo₉₆). Conditions of non-equilibrium are implied from this and the presence of plagioclase glass and small amounts of subcalcic diopside (En₇₅Fs₁₂Wo₁₃) in the chondrule. The properties of this chondrule are consistent with liquid condensation, but melting of an amoeboid olivine aggregate or similar object could also have generated the chondrule-forming liquid. Nepheline and sodalite appear to have crystallized from this liquid under non-equilibrium conditions.     

In situ micro‐Raman and X‐ray diffraction study of diamonds and petrology of the new ureilite UAE 001 from the United Arab Emirates

Abstract— A new olivine‐pigeonite ureilite containing abundant diamonds and graphite was found in the United Arab Emirates. This is the first report of a meteorite in this country. The sample is heavily altered, of medium shock level, and has a total weight of 155 g. Bulk rock, olivine (Fo_79.8–81.8) and pyroxene (En_73.9–75.2, Fs_15.5–16.9, Wo_8.8–9.5) compositions are typical of ureilites. Olivine rims are reduced with Fo increasing up to Fo_96.1–96.8. Metal in these rims is completely altered to Fehydroxide during terrestrial weathering. We studied diamond and graphite using micro‐Raman and in situ synchrotron X‐ray diffraction. The main diamond Raman band (LO = TO mode at ?1332 cm^?1) is broadened when compared to well‐ordered diamond single crystals. Full widths at half maximum (FWHM) values scatter around 7 cm^?1. These values resemble FWHM values obtained from chemical vapor deposition (CVD) diamond. In situ XRD measurements show that diamonds have large grain sizes, up to >5 μm. Some of the graphite measured is compressed graphite. We explore the possibilities of CVD versus impact shock origin of diamonds and conclude that a shock origin is much more plausible. The broadening of the Raman bands might be explained by prolonged shock pressure resulting in a transitional Raman signal between experimentally shock‐produced and natural diamonds.     

Petrology and geochemistry of the Elephant Moraine A79002 diogenite: A genomict breccia containing a magnesian harzburgite component

Abstract— The Elephant Moraine A79002 (EETA79002) diogenite is a fragmental breccia with a subtle lightdark structure. It is composed of orthopyroxene, with minor olivine, chromite, and ubiquitous, inhomogeneously distributed, approximately 5–500 μm sized troilite and metal grains. These latter are present in the matrix, and as inclusions in and as symplectic intergrowths with orthopyroxene and olivine. Trace amounts of silica and diopside are also present. Most orthopyroxene compositions (typical orthopyroxenes) are in the narrow range Wo_2.1–2.7En_74.1–75.6Fs_22.2–23.8 like those of most diogenites. A few magnesian orthopyroxenes are present with compositions of Wo_1.7‐2.5En_77.5–80.2 Fs_18.2–20.3. These are among the most magnesian orthopyroxenes known from diogenites. A few ferroan orthopyroxenes have compositions of Wo_2.1–2.9En_71.7–73.7Fs_24.2–25.5. Differences in Al₂O₃, TiO₂, and Cr₂O₃ between the different orthopyroxene groups are inconsistent with a simple igneous fractionation relationship between them. Olivine compositions are Fo_75.0–76.9. The olivines could be in equilibrium with the magnesian orthopyroxenes, but not with the typical or ferroan orthopyroxenes that form the bulk of EETA79002. Metal grains exhibit a range of Ni and Co contents and Ni/Co ratios; their compositions indicate that they are primary igneous metal. Metal and troilite grains are more prevalent in the dark samples. The trace incompatible lithophile element contents of 16 samples are remarkably uniform. Their Yb concentrations are all within their 2s? analytical uncertainties of the mean. The uniformity and low content of light rare earth elements in EETA79002 indicate that negligible amounts of a trapped liquid component, or foreign material mixed in the breccia, could be present. The siderophile and chalcophile element data show that the light‐dark structure is due to the distribution of metal and troilite grains; dark samples contain higher Ni, Co, and Se compared to light samples. Meteorite EETA79002 appears to contain material from three or more related plutons, a magnesian harzburgite, and two orthopyroxenites, and is a genomict breccia.     

Comparison of the LEW88516 and ALHA77005 martian meteorites: Similar but distinct

Abstract By mineral and bulk compositions, the Lewis Cliff (LEW) 88516 meteorite is quite similar to the ALHA77005 martian meteorite. These two meteorites are not paired because their mineral compositions are distinct, they were found 500 km apart in ice fields with different sources for meteorites, and their terrestrial residence ages are different. Minerals in LEW88516 include: olivine, pyroxenes (low- and high-Ca), and maskelynite (after plagioclase); and the minor minerals chromite, whitlockite, ilmenite, and pyrrhotite. Mineral grains in LEW88516 range up to a few mm. Texturally, the meteorite is complex, with regions of olivine and chromite poikilitically enclosed in pyroxene, regions of interstitial basaltic texture, and glass-rich (shock) veinlets. Olivine compositions range from Fo₆₄ to Fo₇₀, (avg. Fo₆₇), more ferroan and with more variation than in ALHA77005 (Fo₆₉ to Fo₇₃). Pyroxene compositions fall between En₇₇Wo₄ and En₆₅Wo₁₅ and in clusters near En₆₃Wo₉ and En₅₃Wo₃₃, on average more magnesian and with more variation than in ALHA77005. Shock features in LEW88516 range from weak deformation through complete melting. Bulk chemical analyses by modal recombination of electron microprobe analyses, instrumental neutron activation, and radiochemical neutron activation confirm that LEW88516 is more closely related to ALHA77005 than to other known martian meteorites. Key element abundance ratios are typical of martian meteorites, as is its non-chondritic rare earth pattern. Differences between the chemical compositions of LEW88516 and ALHA77005 are consistent with slight differences in the proportions of their constituent minerals and not from fundamental petrogenetic differences. Noble gas abundances in LEW88516, like those in ALHA77005, show modest excesses of ⁴⁰Ar and ¹²⁹Xe from trapped (shock-implanted) gas. As with other ALHA77005 and the shergottite martian meteorites (except EETA79001), noble gas isotope abundances in LEW88516 are consistent with exposure to cosmic rays for 2.5–3 Ma. The absence of substantial effects of shielding from cosmic rays suggest LEW88516 spent this time as an object no larger than a few cm in diameter.     

THE LOOP CHONDRITE: PETROLOGY,MINERAL CHEMISTRY,AND OPAQUE MINERALOGY

The Loop meteorite was found in 1962 in Gaines County, Texas, at a location very close to that where the Ashmore chondrite was found in 1969. The two specimens were assumed to be fragments of the same meteorite. The Loop meteorite is a type L6 chondrite composed of olivine (Fo_75.4Fa_24.6), orthopyroxene (En_77.6Wo_1.5Fs_20.9), clinopyroxene (En_47.5Wo_45.1Fs_7.4), plagioclase (Ab_84.3Or_5.5An_10.2), Fe-Ni metal, troilite, and chromite. Fe-Ni metal is represented by kamacite (5.8-6.4 wt % Ni, 0.88-1.00 wt % Co), taenite (30.0–52.9 wt % Ni, 0.16-0.34 wt % Co), and plessite (16.8–28.5 wt % Ni, 0.38-0.54 wt % Co). Native copper occurs as rare inclusions in Fe-Ni metal. Both chondrules and matrix have similar mineral compositions. The mineral chemistry of the Loop meteorite is quite different from that of the Ashmore, which was classified as an H5 chondrite by Bryan and Kullerud (1975). Therefore, the Ashmore and Loop meteorites are two different chondrites, even though they were recovered from the same geographic location.     

Jiddat al Harasis 422: A ureilite with an extremely high degree of shock melting

The Jiddat al Harasis (JaH) 422 ureilite was found in the Sultanate of Oman; it is classified as a ureilitic impact melt breccia. The meteorite consists of rounded polycrystalline olivine clasts (35%), pores (8%), and microcrystalline matrix (57%). Clasts and matrix have oxygen isotopic values and chemical compositions (major and trace elements) characteristic of the ureilite group. The matrix contains olivine (Fo_83–90), low‐Ca pyroxene (En_84–92Wo_0–5), augite (En_71–56Wo_20–31), graphite, diamond, Fe‐metal, sulfides, chromite, and felsic glass. Pores are partly filled by secondary Fe‐oxihydroxide and desert alteration products. Pores are surrounded by strongly reduced silicates. Clasts consist of fine‐grained aggregates of polygonal olivine. These clasts have an approximately 250 μm wide reaction rim, in which olivine composition evolves progressively from the core composition (Fo_79–81) to the matrix composition (Fo_84–87). Veins crossing the clasts comprise pyroxene, Fe‐oxihydroxide, C‐phases, and chromite. Clasts contain Ca‐, Al‐, and Cr‐rich glass along olivine grain boundaries (<1 μm wide). We suggest that a significant portion of JaH 422, including olivine and all the pyroxenes, was molten as a result of an impact. In comparison with other impact‐melted ureilites, JaH 422 shows the highest melt portion. Based on textural and compositional considerations, clasts and matrix probably originated from the same protolith, with the clasts representing relict olivine that survived, but was recrystallized in the impact melt. During the melt stage, the high availability of FeO and elevated temperatures controlled oxygen fugacity at values high enough to stabilize olivine with Fo_～83–87 and chromite. Along pores, high Mg# compositions of silicates indicate that in a late stage or after melt crystallization FeO became less available and fO₂ conditions were controlled by C?CO + CO₂.     

Northwest Africa 4797: A strongly shocked ultramafic poikilitic shergottite related to compositionally intermediate Martian meteorites

Abstract– Northwest Africa (NWA) 4797 is an ultramafic Martian meteorite composed of olivine (40.3 vol%), pigeonite (22.2%), augite (11.9%), plagioclase (9.1%), vesicles (1.6%), and a shock vein (10.3%). Minor phases include chromite (3.4%), merrillite (0.8%), and magmatic inclusions (0.4%). Olivine and pyroxene compositions range from Fo_66–72,En_58–74Fs_19–28Wo_6–15, and En_46–60Fs_14–22Wo_34–40, respectively. The rock is texturally similar to “lherzolitic” shergottites. The oxygen fugacity was QFM?2.9 near the liquidus, increasing to QFM?1.7 as crystallization proceeded. Shock effects in olivine and pyroxene include strong mosaicism, grain boundary melting, local recrystallization, and pervasive fracturing. Shock heating has completely melted and vesiculated igneous plagioclase, which upon cooling has quench‐crystallized plagioclase microlites in glass. A mm‐size shock melt vein transects the rock, containing phosphoran olivine (Fo_69–79), pyroxene (En_44–51Fs_14–18Wo_30–42), and chromite in a groundmass of alkali‐rich glass containing iron sulfide spheres. Trace element analysis reveals that (1) REE in plagioclase and the shock melt vein mimics the whole rock pattern; and (2) the reconstructed NWA 4797 whole rock is slightly enriched in LREE relative to other intermediate ultramafic shergottites, attributable to local mobilization of melt by shock. The shock melt vein represents bulk melting of NWA 4797 injected during pressure release. Calculated oxygen fugacity for NWA 4797 indicates that oxygen fugacity is decoupled from incompatible element concentrations. This is attributed to subsolidus re‐equilibration. We propose an alternative nomenclature for “lherzolitic” shergottites that removes genetic connotations. NWA 4797 is classified as an ultramafic poikilitic shergottite with intermediate trace element characteristics.     

Petrology and geochemistry of Patuxent Range 91501, a clast‐poor impact melt from the L‐chondrite parent body and Lewis Cliff 88663, an L7 chondrite

Abstract— We have performed petrologic and geochemical studies of Patuxent Range (PAT) 91501 and Lewis Cliff (LEW) 88663. PAT 91501, originally classified as an L7 chondrite, is rather a unique, near total impact melt from the L‐chondrite parent body. Lewis Cliff 88663 was originally classified as an “achondrite (?)”, but we find that it is a very weakly shocked L7 chondrite. PAT 91501 is an unshocked, homogeneous, igneous‐textured ultramafic rock composed of euhedral to subhedral olivine, low‐Ca pyroxene, augite and chrome‐rich spinels with interstitial albitic plagioclase and minor silica‐alumina‐alkali‐rich glass. Only ～10% relic chondritic material is present. Olivine grains are homogeneous (Fa_25.2–26.8). Low‐Ca pyroxene (Wo_1.9–7.2En_71.9–78.2Fs_19.9–20.9) and augite (Wo_29.8–39.0En_49.2–55.3Fs_11.8–14.9) display a strong linear TiO₂‐Al₂O₃ correlation resulting from igneous fractionation. Plagioclase is variable in composition; Or_3.0–7.7Ab_79.8–84.1An_8.2–17.2.‐Chrome‐rich spinels are variable in composition and zoned from Cr‐rich cores to Ti‐Al‐rich rims. Some have evolved compositions with up to 7.9 wt% TiO₂. PAT 91501 bulk silicate has an L‐chondrite lithophile element composition except for depletions in Zn and Br. Siderophile and chalcophile elements are highly depleted due to sequestration in centimeter‐size metal‐troilite nodules. The minerals in LEW 88663 are more uniform in composition than those in PAT 91501. Olivine grains have low CaO and Cr₂O₃ contents similar to those in L5–6 chondrites. Pyroxenes have high TiO₂ contents with only a diffuse TiO₂‐Al₂O₃ correlation. Low‐Ca pyroxenes are less calcic (Wo_1.6–3.1En_76.5–77.0Fs_20.4–21.4), while augites (Wo_39.5–45.6En_46.8–51.1Fs_7.6–9.4) and plagioclases (Or_2.6–5.7Ab_74.1–83.1An_11.2–23.3) are more calcic. Spinels are homogeneous and compositionally similar to those in L6 chondrites. LEW 88663 has an L‐chondrite bulk composition for lithophile elements, and only slight depletions in siderophile and chalcophile elements that are plausibly due to weathering and/or sample heterogeneity.     

Petrology,geochemistry, and cosmic‐ray exposure age of Iherzolitic shergottite Northwest Africa 1950

Northwest Africa (NWA) 1950 is a new member of the lherzolitic shergottite clan of the Martian meteorites recently found in the Atlas Mountains. The petrological, mineralogical, and geochemical data are very close to those of the other known lherzolitic shergottites. The meteorite has a cumulate gabbroic texture and its mineralogy consists of olivine (Fo₆₆ to Fo₇₅), low and high‐Ca pyroxenes (En₇₈Fs₁₉Wo₂‐En₆₀Fs₂₆W₁₄; En₅₃Fs₁₆Wo₃₁‐En₄₅Fs₁₄Wo₄₁), and plagioclase (An₅₇Ab₄₁Or₁ to An₄₀Ab₅₇Or₃; entirely converted into maskelynite during intense shock metamorphism). Accessory minerals include phosphates (merrillite), chromite and spinels, sulfides, and a glass rich in potassium. The oxygen isotopic values lie on the fractional line defined by the other SNC meteorites (Δ¹⁷O = 0.312 %o). The composition of NWA 1950 is very similar to the other lherzolitic shergottites and suggests an origin from the same magmatic system, or at least crystallization from a close parental melt. Cosmogenic ages indicate an ejection age similar to those of the other lherzolitic shergottites. The intensity of the shock is similar to that observed in other shergottites, as shown by the occurrence of small melt pockets containing glass interwoven with stishovite.     

THE BEAVER-HARRISON,BEAVER COUNTY,UTAH L6 CHONDRITE

The Beaver-Harrison, Utah chondrite (find July 24, 1979), a single, shock-veined stone of 925 grams, consists of major olivine (Fa_25.0), low-Ca pyroxene (En_77.3Fs_21.1Wo_1.6) and metallic nickel-iron; minor troilite and plagioclase (Ab_82.6An_11.1Or_6.3), accessory high-Ca pyroxene (En_47.0Fs_8.5Wo_44.5), chromite (Cm_8.7Sp_10.6Uv_9.4Pc_0.6Hc_0.7), chlorapatite and whitlockite; and hydrous ferric oxide of terrestrial weathering origin. Mineral compositions indicate L-group classification, and homogeneity of minerals, highly recrystallized texture and presence of clear plagioclase suggest that the meteorite belongs to petrologic type 6.     

THE NAKHLITES PART I: PETROGRAPHY AND MINERAL CHEMISTRY

The only two Nakhlite meteorites, Nakhla and Lafayette, are identical in mineral composition, consisting of augite (Wo₃₉En₃₈Fs₂₃), olivine (Fo_32–35), plagioclase (An₂₇), K-feldspar (Or₇₅Ab₂₂An₃), titaniferous magnetite with exsolved ilmenite, iddingsite (?), and minor amounts of fluor-chlorapatite, FeS, pyrite, chalcopyrite, and K-rich glass. The texture is suggestive of a cumulative origin.     

Sayh al Uhaymir 094: A new martian meteorite from the Oman desert

Abstract— Sayhal Uhaymir (SaU) 094 is a 223.3 g, partially crusted, strongly to very strongly shocked melanocratic olivine-porphyric rock of the shergottite group showing a microgabbroic texture. The rock consists of pyroxene (52.0–58.2 vol%)—dominantly prismatic pigeonite (En_60–68Fs_20–27Wo^7–9) associated with minor augite (En_46–49Fs_15–16Wo_28–31)—brown (shock-oxidized) olivine (Fo_65–69; 22.1–31%), completely isotropic interstitial plagioclase glass (maskelynite; An_50–64Or_0.3-0.9; 8.6–13.0%), chromite and titanian magnesian chromite (0.9-1.0%), traces of ilmenite (Ilm_80–86), pyrrhotite (Fe_92–100; 0.1-0.2%), merrillite (<<0.1%), and pockets (4.8-6.7%) consisting of green basaltic to basaltic andesitic shock glass that is partially devitrified into a brown to black product along boundaries with the primary minerals. The average maximum dimensions of minerals are: olivine (1.5 mm), pyroxene (0.3 mm) and maskelynite (0.3 mm). Primary melt inclusions in olivine and chromite are common and account for 0.1-0.6% of the rock. X-ray tomography revealed that the specimen contains ˜0.4 vol% of shock-melt associated vesicles, up to 3 mm in size, which show a preferred orientation. Fluidization of the maskelynite, melting and recrystallization of pyroxene, olivine and pyrrhotite indicate shock stage S6. Minor terrestrial weathering resulted in calcite-veining and minor oxidation of sulfides. The meteorite is interpreted as paired with SaU 005/008/051. The modal composition is similar to Dar al Gani 476/489/670/735/876, with the exception that neither mesostasis nor titanomagnetite nor apatite are present and that all phases show little zonation. The restricted mineral composition, predominance of chromite among the oxides, and abundance of olivine indicate affinities to the lherzolitic shergottites.     

Transmission electron microscope texture and crystal chemistry of coexisting ortho- and clinopyroxene in the Antarctic ureilite Frontier Mountain 90054: Implications for thermal history

Abstract— Frontier Mountain (FRO) 90054, from Antarctica, is a rare clino- and orthopyroxene-bearing ureilite with a coarse equigranular oriented texture (grains up to 3 mm); it is classified as a low-shock Ca-rich type. The crystal chemistry of its clinopyroxene (Wo_39.3En_54.6Fs_6.1), orthopyroxene (En_{84 2}Fs₁₁Wo_4.8) and olivine (Fa_12.6Fo_86.9) was investigated by single-crystal x-ray structural refinements and transmission electron microscope (TEM) observations to obtain data on the evolutionary history of the parent body. The M1 octahedron and unit cell volumes of the orthopyroxene and clinopyroxene are consistent with low-pressure crystallization. The closure temperatures for intracrystalline Mg-Fe²⁺ ordering yielded values of 674 °C and 804 °C for opx and 596 °C for cpx, which indicate high-temperature equilibration and fast cooling. Trasmission electron microscope investigations were performed on clinopyroxene, orthopyroxene and pigeonite. The (100) twin lamellae in the clinopyroxene and intergrowth of clino- and orthoenstatite lamellae in orthopyroxene most probably originated by deformation. Exsolution was not observed in any of the phases, which suggests rapid cooling. Analysis by TEM also revealed interstitial Na-rich glass and pigeonite with sharp h + k odd reflections and rare stacking faults parallel to (100). Textural and crystal chemical data, obtained by TEM, indicated rapid cooling that was probably due to fast radiative heat loss as a result of the disintegration of the parent body into small fragments, which subsequently reassembled into a larger body. One or more collisional events caused fine-scale stacking faults and partial melting.     

Petrology and geochemistry of the fine‐grained,unbrecciated diogenite Northwest Africa 4215

Abstract— We report on the petrology and geochemistry of Northwest Africa (NWA) 4215, an unbrecciated diogenite recovered in the Sahara. This single stone, weighing 46.4 g, displays a wellpreserved cumulative texture. It consists of zoned xenomorphic orthopyroxene grains on the order of 500 μm in size, along with a few large chromite crystals (<5 vol%, up to 3 mm). Accessory olivine and scarce diopside grains occur within the groundmass, usually around the chromite crystals. Minor phases are cristobalite, troilite, and metal. Unlike other diogenites, orthopyroxenes (En_76.2Wo_1.1Fs_22.7 to En_68.6Wo_5.5Fs_25.9), olivines (Fo₇₆ to Fo₇₁), and chromites (Mg# = 14.3 44.0, Cr# = 42.2–86.5) are chemically zoned. The minor element behavior in orthopyroxenes and the intricate chemical profiles obtained in chromites indicate that the zonings do not mirror the evolution of the parental melt. We suggest that they resulted from reaction of the crystals with intercumulus melt. In order to preserve the observed zoning profiles, NWA 4215 clearly cooled significantly faster than other diogenites. Indeed, the cooling rate determined from the diffusion of Cr in olivine abutting chromite is in the order of 10–50 °C/a, suggesting that NWA 4215 formed within a small, shallow intrusion. The bulk composition of NWA 4215 has been determined for major and trace elements. This meteorite is weathered and its fractures are filled with calcite, limonite, and gypsum, typical of hot desert alteration. In particular, the FeO, CaO abundances and most of the trace element concentrations (Sr, Ba, Pb, and REE among others) are high and indicate a significant contribution from the secondary minerals. To remove the terrestrial contribution, we have leached with HCl a subsample of the meteorite. The residue, made essentially of orthopyroxene and chromite, has similar major and trace element abundances to diogenites as shown by the shape of its REE pattern or by its high Al/Ga ratio. The connection of NWA 4215 with diogenites is confirmed by its O‐isotopic composition (δ¹⁷O = 1.431 ± 0.102‰, δ¹⁸O = 3.203 ± 0.205‰, Δ¹⁷O = ?0.248 ± 0.005‰).     

The Loxton meteorite: A new olivine-bronzite chondrite from South Australia

Abstract— The Loxton meteorite is a single stone of 22 g found in South Australia in 1968. It has been classified as an L5 chondrite, shock facies ‘a,’ and contains olivine (Fa₂₄), orthopyroxene (Fs_21–22), clinopyroxene (Wo_44.7En_45.9Fs_9.4), nickel-iron, troilite, chromite and chlorapatite.     

The Linum Chondrite

Abstract— Based on optical microscopy and electron microprobe analysis, Linum is classified as an L6b chondrite that contains olivine (Fa₂₄), orthopyroxene (Fs₂₀), clinopyroxene (Wo₄₅En₄₇Fs₈), plagioclase (An₁₀Ab₈₄Or₆), nickel-iron, troilite, chromite and accessory amounts of chlorapatite and whitlockite.     

NWA 1152 and Sahara 00182: New primitive carbonaceous chondrites with affinities to the CR and CV groups

Abstract— We have investigated the mineralogy, petrography, bulk chemistry, and light element isotope composition of the ungrouped chondrites North West Africa (NWA) 1152 and Sahara 00182. NWA 1152 contains predominantly type 1 porphyritic olivine (PO) and porphyritic olivinepyroxene (POP) chondrules. Chondrule silicates are magnesium‐rich (Fo_{98.8 ± 1.2}, n = 36; Fs_{2.3 ± 2.1} Wo_{1.2 ± 0.3}, n = 23). Matrix comprises ?40 vol% of the sample and is composed of a micron sized silicate groundmass with larger silicate, sulfide, magnetite, and Fe‐Ni metal (Ni ?50 wt%) grains. Phyllosilicates were not observed in the matrix. Refractory inclusions are rare (0.3 vol%) and are spinel pyroxene aggregates or amoeboid olivine aggregates; melilite is absent from the refractory inclusions. Sahara 00182 contains predominantly type 1 PO chondrules, POP chondrules are less common. Most chondrules contain blebs of, and are often rimmed with, Fe‐Ni metal and sulfide. Chondrule phenocrysts are magnesium‐rich (Fo_{92.2 ± 0.6}, n = 129; Fs_{4.4 ± 1.8} Wo_{1.3 ± 1.1}, n = 16). Matrix comprises ?30 vol% of the meteorite and is predominantly sub‐micron silicates, with rare larger silicate gains. Matrix Fe‐Ni metal (mean Ni = 5.8 wt%) and sulfide grains are up to mm scale. No phyllosilicates were observed in the matrix. Refractory inclusions are rare (1.1 vol%) and melilite is absent. The oxygen isotope composition of NWA 1152 falls within the range of the CV chondrites with δ¹⁷O = ?3.43%0 δ¹⁸O = 0.70%0 and is similar to Sahara 00182, δ¹⁷O = ?3.89%0, δ¹⁸O = ?0.19%0 (Grossman and Zipfel 2001). Based on mineralogical and petrographic characteristics, we suggest NWA 1152 and Sahara 00182 show many similarities with the CR chondrites, however, oxygen isotopes suggest affinity with the CVs. Thus, neither sample can be assigned to any of the currently known carbonaceous chondrite groups based on traditionally recognized characteristics. Both samples demonstrate the complexity of inter‐ and intra‐group relationships of the carbonaceous chondrites. Whatever their classification, N WA 1152 and Sahara 00182 represent a source of relatively pristine solar system material.