An integrated approach to understanding Apollo 16 impact glasses: Chemistry,isotopes, and shape

Abstract The major‐ and minor‐element abundances were determined by electron microprobe in 1039 glasses from regoliths and regolith breccias to define the compositional topology of lunar glasses at the Apollo 16 landing site in the central highlands of the Moon. While impact glasses with chemical compositions similar to local materials (i.e., Apollo 16 rocks and regoliths) are abundant, glasses with exotic compositions (i.e., transported from other areas of the Moon) account for up to ?30% of the population. A higher proportion of compositionally exotic, angular glass fragments exists when compared to compositionally exotic glass spherules. Ratios of non‐volatile lithophile elements (i.e., Al, Ti, Mg) have been used to constrain the original source materials of the impact glasses. This approach is immune to the effects of open‐system losses of volatile elements (e.g., Si, Na, K). Four impact glasses from one compositionally exotic group (low‐Mg high‐K Fra Mauro; lmHKFM) were selected for ⁴⁰Ar/³⁹ Ar dating. The individual fragments of lmHKFM glass all yielded ages of ?3750 ± 50 Ma for the time of the impact event. Based on the petrography of these individual glasses, we conclude that the likely age of the impact event that formed these 4 glasses, as well as the possible time of their ballistic arrival at the Apollo 16 site from a large and distant cratering event (perhaps in the Procellarum KREEP terrain) (Zeigler et al. 2004), is 3730 ± 40 Ma, close to the accepted age for Imbrium.     

How old is the crater copernicus?

Two KREEP glass concentrates separated from lunar soil 12033 have been dated with the Ar³⁹/Ar⁴⁰ method. Both samples show low-temperature plateaus in accordance with a major outgassing of the KREEP glasses (800 ± 40) × 10⁶ yr ago. This is the age of Copernicus, provided the identification of KREEP glass as ray material ejected during the Copernican event is true (Hubbardet al., 1971). The exposure age of the two KREEP glass concentrates is 200 × 10⁶ yr and thus distinctly smaller than the ejection age. Possible explanations for this are discussed.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

Lunar regolith breccia Dhofar 287B: A record of lunar volcanism

Abstract— Dhofar 287 (Dho 287), a recently found lunar meteorite, consists in large part (95%) of low‐Ti mare basalt (Dho 287A) and a minor, attached portion (?5%) of regolith breccia (Dho 287B). The present study is directed mainly at the breccia portion of this meteorite. This breccia consists of a variety of lithic clasts and mineral fragments set in a fine‐grained matrix and minor impact melt. The majority of clasts and minerals appear to have been mainly derived from the low‐Ti basalt suite, similar to that of Dho 287A. Very low‐Ti (VLT) basalts are a minor lithology of the breccia. These are significantly lower in Mg# and slightly higher in Ti compared to Luna 24 and Apollo 17 VLT basalts. Picritic glasses constitute another minor component of the breccia and are compositionally similar to Apollo 15 green glasses. Dho 287B also contains abundant fragments of Mg‐rich pyroxene and anorthite‐rich plagioclase grains that are absent in the lithic clasts. Such fragments appear to have been derived from a coarse‐grained, Mg#‐rich, Na‐poor lithology. A KREEP component is apparent in chemistry, but no highlands lithologies were identified. The Dho 287 basaltic lithologies cannot be explained by near‐surface fractionation of a single parental magma. Instead, magma compositions are represented by a picritic glass; a low‐Ti, Na‐poor glass; and a low‐Ti, Na‐enriched source (similar to the Dho 287A parental melt). Compositional differences among parent melts could reflect inhomogeneity of the lunar mantle. Alternatively, the low‐Ti, Na‐poor, and Dho 287A parent melts could be of hybrid compositions, resulting from assimilation of KREEP by picritic magma. Thus, the Dho 287B breccia contains lithologies from multiple magmatic eruptions, which differed in composition, formational conditions, and cooling histories. Based on this study, the Dho 287 is inferred to have been ejected from a region located distal to highlands terrains, possibly from the western limb of the lunar nearside, dominated by mare basalts and KREEP‐rich lithologies.     

The regolith portion of the lunar meteorite Sayh al Uhaymir 169

Abstract— –Sayh al Uhaymir (SaU) 169 is a composite lunar meteorite from Oman that consists of polymict regolith breccia (8.44 ppm Th), adhering to impact‐melt breccia (IMB; 32.7 ppm Th). In this contribution we consider the regolith breccia portion of SaU 169, and demonstrate that it is composed of two generations representing two formation stages, labeled II and III. The regolith breccia also contains the following clasts: Ti‐poor to Ti‐rich basalts, gabbros to granulites, and incorporated regolith breccias. The average SaU 169 regolith breccia bulk composition lies within the range of Apollo 12 and 14 soil and regolith breccias, with the closest correspondence being with that of Apollo 14, but Sc contents indicate a higher portion of mare basalts. This is supported by relations between Sm‐Al₂O₃, FeO‐Cr₂O₃‐TiO₂, Sm/Eu and Th‐K₂O. The composition can best be modeled as a mixture of high‐K KREEP, mare basalt and norite/troctolite, consistent with the rareness of anorthositic rocks. The largest KREEP breccia clast in the regolith is identical in its chemical composition and total REE content to the incompatible trace‐element (ITE)‐ rich high‐K KREEP rocks of the Apollo 14 landing site, pointing to a similar source. In contrast to Apollo 14 soil, SaU 169 IMB and SaU 169 KREEP breccia clast, the SaU 169 regolith is not depleted in K/Th, indicating a low contribution of high‐Th IMB such as the SaU 169 main lithology in the regolith. The data presented here indicate the SaU 169 regolith breccia is from the lunar front side, and has a strong Procellarum KREEP Terrane signature.     

Evidence for multiple 4.0–3.7 Ga impact events within the Apollo 16 collection

In a histogram of lunar impact ages from the Apollo 16 site, there is a spike circa 3.9 Ga that has been interpreted to represent either a large number of nearly synchronous events or an abundance of samples that were affected slightly differently by the event that produced the Imbrium basin. To further scrutinize those age relationships, we extracted six centimeter‐sized clasts of impact melt from ancient regolith breccia 60016 and performed petrological and geochronological (⁴⁰Ar‐³⁹Ar) analyses. Three clasts have similar poikilitic textures, while others have porphyritic, aphanitic, or intergranular textures. Compositions and abundances of relict minerals are different in all six clasts and variously imply Mg‐suite and ferroan anorthosite target sequences. Estimated bulk compositions of four clasts are similar to previously defined group 1 Apollo 16 impact melt rocks, while the other two have higher Al₂O₃ and lower FeO+MgO compositions. All six clasts have similar K₂O and P₂O₅ concentrations, which could have been derived from a KREEP‐bearing component among target sequences. Eighteen ⁴⁰Ar/³⁹Ar analyses of the six clasts produced an age range from 3823 ± 75 to 4000 ± 23 Ma, consistent with estimates for the proposed late heavy bombardment. Four clasts have multiple temperature steps that define plateau ages. These ages are distinct, so they cannot be explained by a single impact event, such as the one that produced the Imbrium impact basin. The conclusion that these represent distinct ages remains after considering the possibility of artifacts in defining plateaus.     

The Hadley‐Apennine KREEP basalt igneous province

Abstract– We have studied 27 KREEP basalt fragments in six thin sections of samples collected from four Apollo 15 stations. Based on local geology and regional remote sensing data, these samples represent KREEP basalt lava flows that lie beneath the younger, local Apollo 15 mare basalts and under other mare flows north of the Apollo 15 site. Some of these rocks were deposited at the site as ejecta from the large craters Aristillus and Autolycus. KREEP basalts in this igneous province have a volume of 10³–2 × 10⁴ km³. Mineral and bulk compositional data indicate that the erupted magmas had Mg# [100 × molar Mg/(Mg + Fe)] up to 73, corresponding to orthopyroxene‐rich interior source regions with Mg# up to 90. Minor element variations in the parent magmas of the KREEP basalts, inferred from compositions of the most magnesian pyroxene and most calcic plagioclase in each sample, indicate small but significant differences in the concentrations of minor elements and Mg#, reflecting variations in the composition of lower crustal or mantle source regions and/or different amounts of partial melting of those source regions.     

Exploring the variability of argon loss in Apollo 17 impact melt rock 77135 using high‐spatial resolution 40Ar/39Ar geochronology

⁴⁰Ar/³⁹Ar incremental heating experiments on whole‐rock lunar samples commonly provide evidence of varying degrees of radiogenic ⁴⁰Ar (⁴⁰Ar*) loss. However, these experiments provide limited information about whether or not ⁴⁰Ar* is preferentially lost from specific glasses, minerals, or polyphase domains. Ultraviolet laser ablation microprobe (UVLAMP) ⁴⁰Ar/³⁹Ar dating and electron probe microanalysis of mineral clasts and polyphase melt assemblages in Apollo 17 poikilitic impact melt rock 77135 show evidence of geochemical controls on ⁴⁰Ar/³⁹Ar dates. Potassium‐rich glass and K‐feldspar in the mesostasis are the dominant sources for Ar released during low‐temperature steps of published ⁴⁰Ar/³⁹Ar release spectra for this rock, while pyroxene oikocrysts with enclosed plagioclase chadacrysts contribute Ar predominantly to intermediate‐ to high‐temperature steps. Additionally, UVLAMP analysis of a mm‐scale plagioclase clast demonstrates the potential to use stranded ⁴⁰Ar* diffusive loss profiles to constrain the thermal evolution of lunar impact melt deposits and indicates that the melt component of 77135 cooled quickly. While some submillimeter clasts of plagioclase are distinctly older than the melt, other small clasts yield dates younger than the oldest melt components in 77135, plausibly due to subgrain fast diffusion pathways and/or ⁴⁰Ar* loss during brief episodes of reheating at high temperatures. Our data suggest that integrated petrologic and microanalytical geochronologic studies are necessary complements to bulk sample geochronologic studies in order to fully evaluate competing models for the impactor flux during the first billion years of the Moon's evolution.     

Petrogenesis of Chang'E-5 young mare low-Ti basalts

The regolith samples returned by the Chang'E-5 mission (CE-5) contain the youngest radiometrically dated mare basaltic clasts, which provide an opportunity to elucidate the magmatic activities on the Moon during the late Eratosthenian. In this study, detailed petrographic observations and comprehensive geochemical analyses were performed on the CE-5 basaltic clasts. The major element concentrations in individual plagioclase grain of the CE-5 basalts may vary slightly from core to rim, whereas pyroxene has clear chemical zonation. The crystallization sequence of the CE-5 mare basalts was determined using petrographic and geochemical relations in the basaltic clasts. In addition, both fractional crystallization (FC) and assimilation and fractional crystallization models were applied to simulate the chemical evolution of melt equilibrated with plagioclase in CE-5 basalts. Our results reveal that the melt had a TiO₂ content of ~3 wt% and an Mg# of ~45 at the onset of plagioclase crystallization, suggesting a low-Ti parental melt of the CE-5 basalts. The relatively high FeO content (>14.5 wt%) in melt equilibrated with plagioclase could have resulted in extensive crystallization of ilmenite, unlike in Apollo low-Ti basalts. Furthermore, our calculations showed that the geochemical evolution of CE-5 basaltic melt could not have occurred in a closed system. On the contrary, the CE-5 basalts could have assimilated mineral, rock, and glass fragments that have higher concentrations of KREEP elements (potassium, rare earth elements, and phosphorus) in the regolith during magma flow on the Moon's surface. The presence of the KREEP signature in the CE-5 basalts is consistent with literature remote sensing data obtained from the CE-5 landing site. These KREEP-bearing fragments could originate from KREEP basaltic melts that may have been emplaced at the landing site earlier than the CE-5 basalts.     

The early geological history of the Moon inferred from ancient lunar meteorite Miller Range 13317

Miller Range (MIL) 13317 is a heterogeneous basalt‐bearing lunar regolith breccia that provides insights into the early magmatic history of the Moon. MIL 13317 is formed from a mixture of material with clasts having an affinity to Apollo ferroan anorthosites and basaltic volcanic rocks. Noble gas data indicate that MIL 13317 was consolidated into a breccia between 2610 ± 780 Ma and 1570 ± 470 Ma where it experienced a complex near‐surface irradiation history for ~835 ± 84 Myr, at an average depth of ~30 cm. The fusion crust has an intermediate composition (Al₂O₃ 15.9 wt%; FeO 12.3 wt%) with an added incompatible trace element (Th 5.4 ppm) chemical component. Taking the fusion crust to be indicative of the bulk sample composition, this implies that MIL 13317 originated from a regolith that is associated with a mare‐highland boundary that is KREEP‐rich (i.e., K, rare earth elements, and P). A comparison of bulk chemical data from MIL 13317 with remote sensing data from the Lunar Prospector orbiter suggests that MIL 13317 likely originated from the northwest region of Oceanus Procellarum, east of Mare Nubium, or at the eastern edge of Mare Frigoris. All these potential source areas are on the near side of the Moon, indicating a close association with the Procellarum KREEP Terrane. Basalt clasts in MIL 13317 are from a very low‐Ti to low‐Ti (between 0.14 and 0.32 wt%) source region. The similar mineral fractionation trends of the different basalt clasts in the sample suggest they are comagmatic in origin. Zircon‐bearing phases and Ca‐phosphate grains in basalt clasts and matrix grains yield ²⁰⁷Pb/²⁰⁶Pb ages between 4344 ± 4 and 4333 ± 5 Ma. These ancient ²⁰⁷Pb/²⁰⁶Pb ages indicate that the meteorite has sampled a range of Pre‐Nectarian volcanic rocks that are poorly represented in the Apollo, Luna, and lunar meteorite collections. As such, MIL 13317 adds to the growing evidence that basaltic volcanic activity on the Moon started as early as ~4340 Ma, before the main period of lunar mare basalt volcanism at ~3850 Ma.     

Chemistry of the Calcalong Creek lunar meteorite and its relationship to lunar terranes

Abstract— The Calcalong Creek lunar meteorite is a polymict breccia that contains clasts of both highlands and mare affinity. Reported here is a compilation of major, minor, and trace element data for bulk, clast, and matrix samples determined by instrumental neutron activation analysis (INAA). Petrographic information and results of electron microprobe analyses are included. The relationship of Calcalong Creek to lunar terranes, especially the Procellarum KREEP Terrane and Feldspathic Highlands Terrane, is established by the abundance of thorium, incompatible elements and their KREEP‐like CI chondrite normalized pattern, FeO, and TiO₂. The highlands component is associated with Apollo 15 KREEP basalt but represents a variant of the KREEP‐derived material widely found on the moon. Sources of Calcalong Creek's mare basalt components may be related to low‐titanium (LT) and very low‐titanium (VLT) basalts seen in other lunar meteorites but do not sample the same source. The content of some components of Calcalong Creek are found to display similarities to the composition of the South Pole‐Aitken Terrane. What appear to be VLT relationships could represent new high aluminum, low titanium basalt types.     

Apollo 17 regolith, 71501,262: A record of impact events and mare volcanism in lunar glasses

Abstract— Thirteen glasses from Apollo 17 regolith 71501,262 have been chemically analyzed by electron microprobe and isotopically dated with the ⁴⁰Ar/³⁹Ar dating method. We report here the first isotopic age obtained for the Apollo 17 very low titanium (VLT) volcanic glasses, 3630 ± 40 Ma. Twelve impact glasses that span a wide compositional range have been found to record ages ranging from 102 ± 20 Ma to 3740 ± 50 Ma. The compositions of these impact glasses show that some have been produced by impact events within the Apollo 17 region, whereas others appear to be exotic to the landing site. As the data sets that include compositions and ages of lunar impact glasses increase, the impact history in the Earth‐Moon system will become better constrained.     

New lunar meteorite NWA 10986: A mingled impact melt breccia from the highlands—A complete cross section of the lunar crust

Northwest Africa (NWA) 10986 is a new mingled lunar meteorite found in 2015 in Western Sahara. This impact melt breccia contains abundant impact melt glass and clasts as large as 0.75 mm. Clasts are predominantly plagioclase and pyroxene‐rich and represent both highland and basalt lithologies. Highland lithologies include troctolites, gabbronorites, anorthositic norites, and troctolitic anorthosites. Basalt lithologies include crystalline clasts with large zoned pyroxenes representing very low titanium to low titanium basalts. In situ geochemical analysis of minerals within clasts indicates that they represent ferroan anorthosite, Mg‐suite, and gabbronorite lithologies as defined by the Apollo sample collection. Clasts representing magnesian anorthosite, or “gap” lithologies, are prevalent in this meteorite. Whole rock and in situ impact glass measurements indicate low incompatible trace element concentrations. Basalt clasts also have low incompatible trace element concentrations and lack evolved KREEP mineralogy although pyroxferroite grains are present. The juxtaposition of evolved, basaltic clasts without KREEP signatures and highland lithologies suggests that these basaltic clasts may represent cryptomare. The lithologies found in NWA 10986 offer a unique and possibly a complete cross section view of the Moon sourced outside of the Procellarum KREEP Terrane.     

Petrography,mineralogy, and trace element geochemistry of lunar meteorite Dhofar 1180

Abstract— Here we report the petrography, mineralogy, and trace element geochemistry of the Dhofar 1180 lunar meteorite. Dhofar 1180 is predominantly composed of fine‐grained matrix with abundant mineral fragments and a few lithic and glassy clasts. Lithic clasts show a variety of textures including cataclastic, gabbroic, granulitic, ophitic/subophitic, and microporphyritic. Both feldspathic and mafic lithic clasts are present. Most feldspathic lithic clasts have a strong affinity to ferroan anorthositic suite rocks and one to magnesian suite rocks. Mafic lithic clasts are moderately to extremely Fe‐rich. The Ti/[Ti+Cr]‐Fe/[Fe+Mg] compositional trend of pyroxenes in mafic lithic clasts is consistent with that of low‐Ti mare basalts. Glasses display a wide chemical variation from mafic to feldspathic. Some glasses are very similar to those from Apollo 16 soils. KREEP components are essentially absent in Dhofar 1180. One glassy clast is rich in K, REE and P, but its Mg/[Mg+Fe] is very low (0.25). It is probably a last‐stage differentiation product of mare basalt. Molar Fe/Mn ratios of both olivine and pyroxene are essentially consistent with a lunar origin. Dhofar 1180 has a LREE‐enriched (La 18 × CI, Sm 14 × CI) pattern with a small positive Eu anomaly (Eu 15 × CI). Th concentration is 0.7 ppm in Dhofar 1180. Petrography, mineralogy, and trace element geochemistry of Dhofar 1180 are different from those of other lunar meteorites, indicating that Dhofar 1180 represents a unique mingled lunar breccia derived from an area on the lunar nearside but far away from the center of the Imbrium Basin.     

MAJOR ELEMENT COMPOSITION OF GLASSES IN THREE APOLLO 15 SOILS

Approximately 180 glasses in each of three Apollo 15 soils have been analyzed for nine elements. Cluster analysis techniques allow the recognition of preferred glass compositions that are equated with parent rock compositions Green glass rich in Fe and Mg, poor in Al and Ti may be derived from deep seated pyroxenitic material now present at the Apennine Front. Fra Mauro basalt (KREEP) is most abundant in the LM soil and is tentatively identified as ray material from the Aristillus-Autolycus area. Highland basalt (anorthositic gabbro), believed to be derived from the lunar highlands, has the same composition as at other landing sites, but is less abundant. The Apennine Front is probably not true highland material but may contain a substantial amount of material with the composition of Fra Mauro basalt, but lacking the high-K content. Glasses with mare basalt compositions are present in the soils and four subgroups are recognized, one of which is compositionally equivalent to the large Apollo 15 basalt samples     

Geochemistry and 40Ar‐39Ar geochronology of impact‐melt clasts in feldspathic lunar meteorites: Implications for lunar bombardment history

Abstract— We studied 42 impact‐melt clasts from lunar feldspathic regolith breccias MacAlpine Hills (MAC) 88105, Queen Alexandra Range (QUE) 93069, Dar al Gani (DaG) 262, and DaG 400 for texture, chemical composition, and/or chronology. Although the textures are similar to the impactmelt clasts identified in mafic Apollo and Luna samples, the meteorite clasts are chemically distinct from them, having lower Fe, Ti, K, and P, thus representing previously unsampled impacts. The ⁴⁰Ar‐³⁹Ar ages on 31 of the impact melts, the first ages on impact‐melt samples from outside the region of the Apollo and Luna sampling sites, range from ～4 to ～2.5 Ga. We interpret these samples to have been created in at least six, and possibly nine or more, different impact events. One inferred impact event may be consistent with the Apollo impact‐melt rock age cluster at 3.9 Ga, but the meteorite impact‐melt clasts with this age are different in chemistry from the Apollo samples, suggesting that the mechanism responsible for the 3.9 Ga peak in lunar impact‐melt clast ages is a lunar‐wide phenomenon. No meteorite impact melts have ages more than 1s? older than 4.0 Ga. This observation is consistent with, but does not require, a lunar cataclysm.     

Northwest Africa 482: A crystalline impact‐melt breccia from the lunar highlands

Abstract— Northwest Africa 482 (NWA 482) is a crystalline impact‐melt breccia from the Moon with highlands affinities. The recrystallized matrix and the clast population are both highly anorthositic. Clasts are all related to the ferroan anorthosite suite, and include isolated plagioclase crystals and lithic anorthosites, troctolites, and spinel troctolites. Potassium‐, rare‐earth‐element‐, and phosphorus‐bearing (KREEP) and mare lithologies are both absent, constraining the source area of this meteorite to a highland terrain with little to no KREEP component, most likely on the far side of the Moon. Glass is present in shock veins cutting through the sample and in several large melt pockets, indicating a second impact event. There are two separate events recorded in the ⁴⁰Ar‐³⁹Ar system: one at ～3750 Ma, which completely reset the K‐Ar system, and one at ?2400 Ma, which caused only partial degassing. These events could represent, respectively, crystallization of the impact‐melt breccia and later formation of the glass, or the formation of the glass and a later thermal event. The terrestrial age of the meteorite is 8.6 ± 1.3 ka. This age corresponds well with the modest amount of weathering in the rock, in the form of secondary phyllosilicates and carbonates. Based on terrestrial age and location, lithology, and chemistry, NWA 482 is unique among known lunar meteorites.     

Laser argon-40-argon-39 age determinations of Luna 24 mare basalts

Abstract— The ages of seven rock fragments from the soil fraction of the Luna 24 core have been determined using a laser ⁴⁰Ar-³⁹Ar stepped heating technique. The investigated lithologies include fragments of fine-grained ophitic basalt, coarse-grained basalt, metabasalts and a regolith breccia. Most of the samples contain nonradiogenic Ar components of variable ³⁶Ar/⁴⁰Ar composition. These surface-correlated trapped components are predominantly released at low temperature and can be distinguished from volume-correlated radiogenic and cosmogenic components released at higher temperature during stepped heating. Binary mixtures of radiogenic and cosmogenic Ar components give linear correlations on ³⁶Ar_t/⁴⁰Ar-³⁹Ar/⁴⁰Ar diagrams from which the age and ³⁶Ar/⁴⁰Ar value of trapped Ar can be determined. The ages obtained span a narrow range between 3.18-3.28 Ga with an average of 3.22 ± 0.04 Ga. This is interpreted as being the age of the basalts at the Luna 24 sampling site. Systematic age differences between lithologies were not detected; however, a single age of 2.93 Ga obtained from a coarse-grained basalt hints at the possibility of younger volcanism. The results of this work effectively triple the chronological information available for Mare Crisium and are within the range of radiometric age measurements of Luna 24 mare basalts obtained previously.     

Major and trace elements in igneous rocks from apollo 15

The concentrations of major and trace elements have been determined in igneous rocks from Apollo 15. All materials analyzed have typical depletions of Eu except for minerals separated from sample 15085. Four samples have concentrations of trace elements that are similar to those of KREEP. The samples of mare basalt from Apollo 15 have higher concentrations of FeO, MgO, Mn, and Cr and lower concentrations of CaO, Na₂O, K₂O, and rare-earth elements (REE) as compared to the samples of mare basalt from Apollos 11, 12, and 14. The samples can be divided into two groups on the basis of their normative compositions. One group is quartz normative and has low concentrations of FeO while the other is olivine normative and has high concentrations of FeO. The trace element data indicate that the samples of olivine normative basalt could be from different portions of a single lava flow. At least two and possible three parent magmas can be identified from the samples of the quartz normative group on the basis of their concentration ratios of Sm to Eu. Within each group, the compositions of the samples appear to be related by crystallization of olivine or pyroxene. Significant variations of the ratio of concentration of Sm to Eu cannot be produced without plagioclase-liquid equilibrium. The source material of mare basalt may be depleted in Eu. Alternatively, the magmas may have assimilated a small volume of material similar to KREEP.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

Geochemistry and petrology of lunar meteorite Queen Alexandra Range 94281, a mixed mare and highland regolith breccia,with special emphasis on very-low-titanium mafic components

Abstract— Queen Alexandra Range (QUE) 94281, a lunar meteorite recently discovered in Antarctica, is a glassy-matrix, clast-rich regolith breccia containing a mixture of mafic, volcanic-glass and gabbroic constituents and a diverse set of highland constituents. In thin section, the clast assemblage is dominated by coarse mineral debris from a shallow intrusive or hypabyssal setting, or from deep within a thick mare flow. Abundant coarse-grained pyroxene clasts have fine-scale exsolution lamellae and compositions similar to pyroxenes of known lunar very-low-Ti (VLT) basalts and other lunar meteorites of basaltic composition. Pyroxene compositions follow Fe-enrichment extending to hedenbergite, which is associated with fayalite and cristobalite, indicating slow cooling. We refer to the protolith of the crystalline VLT component as VLT gabbro. Fragments of pyroclastic glasses that have high Fe and low Ti concentrations, similar to the pyroclastic green glasses known from Apollo samples, are common. Lithic clasts include abundant subrounded, glassy to cryptocrystalline, aluminous (～17–30 wt% Al₂O₃) KREEP-poor melt breccias of highland origin and a variety of other feldspathic impactites. On the basis of composition of our subsamples, QUE 94281 consists of ～54 wt% mafic or “mare” components and 46 wt% feldspathic or “highland” components. The bulk composition of QUE 94281 is similar to that of Yamato (Y) 793274, but QUE 94281 has slightly greater concentrations of some siderophile elements and slightly lower concentrations of those elements contributed mainly by mafic constituents. Differences in siderophile element concentrations are consistent with longer surface exposure of QUE 94281. Minor differences in trace element variations of subsamples of the two meteorites suggest subtle differences in the composition of their highland constituents. Nonetheless, the overall similarity of compositions supports the possibility that they were ejected from the same source region on the Moon. The crystalline VLT component of QUE 94281 differs from those known from Apollo 17 and Luna 24 VLT lithologies and from that of basaltic breccia Elephant Moraine (EET) 87521. The VLT-gabbro component and the ferroan VLT volcanic glasses in QUE 94281 have compositions that may be petrogenetically related by derivation from a common picritic parent composition, represented by an ultramafic glass found in QUE 94281.     

Petrology and provenance of a very‐low‐titanium picrite clast in lunar highland regolith breccia 15295

Clast 100 in regolith breccia 15295 could be a key to resolving the relationship(s) between mare basalts and lunar picritic glasses. The clast is basaltic, with texture, mineralogy, mineral compositions, and calculated bulk composition suggesting that it crystallized in a thick lava flow or shallow intrusive body from a very‐low‐titanium (VLT) basaltic magma. The estimated bulk composition of clast 15295,100 is primitive (i.e., magnesian) compared to those of known VLT basalts, and is very close to those of VLT picritic green glasses, especially the Apollo 14 A green glass. From these similarities, we infer that clast 15295,100 is a crystalline product of a picritic magma similar to the Apollo 14 A glass. Clementine and M³ remotely sensed data of the lunar surface were used to find areas that have chemical compositions consistent with those of clast 15295,100, not only near the Apollo 15 site, but in a broad region surrounding the site. Two regions are consistent with clast's 15295,100 compositional data. The larger region is in southern Mare Imbrium, and a smaller region is in the eastern half of Sinus Aestuum. These locations should be considered as candidates for future missions focusing on sample science.