Response of salinity distribution around the Yellow River mouth to abrupt changes in river discharge

To investigate how salinity changes with abrupt increases and decreases in river discharge, three surveys were conducted along six sections around the Yellow River mouth before, during and after a water regulation event during which the river discharge was increased from ∼200 to >3000 m³ s⁻¹ for the first 3 days, was maintained at >3000 m³ s⁻¹ for the next 9 days and was decreased to <1000 m³ s⁻¹ for the final 4 days. The mean salinity in the Yellow River estuary area during the event varied ∼1.21, which is much larger than its seasonal variation (∼0.50) and interannual variation (∼0.05). Before the event, a small plume was observed near the river mouth. During the event, the plume extended over 24 km offshore in the surface layer in the direction of river water outflow. After the event, the plume diminished in size but remained larger than before the event. The downstream propagation of the plume (as in a Kelvin wave sense) was apparent in the bottom layer during the second survey and in both the surface and bottom layers during the third survey. The plume sizes predicted by the formulas from theoretical studies are larger than those we observed, indicating that factors neglected by theoretical studies such as the temporal variation in river discharge and vertical mixing in the sea could be very important for plume evolution. In addition to the horizontal variation of the plume, we also observed the penetration of freshwater from the surface layer into the bottom layer. A comparison of two vertical processes, wind mixing and tidal mixing, suggests that the impact of wind mixing may be comparable with that of tidal mixing in the area close to the river mouth and may be dominant over offshore areas. The change in Kelvin number indicates an alteration of plume dynamics due to the abrupt change in river discharge during the water regulation event.     

On the processes that influence the transport and fate of Mississippi waters under flooding outflow conditions

The Mississippi River (MR) freshwater outflow is a major circulation forcing mechanism for the Northern Gulf of Mexico. We investigate the transport and fate of the brackish waters under flood conditions. The largest outflow in history (45,000 m³/s in 2011) is compared with the second largest outflow in the last 8 years (41,000 m³/s in 2008). Realistically forced simulations reveal the synergistic effect of enhanced discharge, winds, stratification of ambient shelf waters, and offshore circulation over the transport of plume waters. The strongest impact is attributed to the evolution of the Loop Current (LC) and associated frontal cyclonic eddies and anticyclonic rings, which exhibited distinctly different influence during the two study periods. The northward LC intrusion in the summer of 2011 weakened and blocked the buoyancy-driven downstream (westward) transport of brackish waters. The 2011 flood was thus characterized by upstream (eastward) flow and an extensive coverage of the Mississippi–Alabama–Florida shelf. An immediate response between the LC and the brackish offshore eastward spreading is computed during and after this historic event. The absence of a LC northward intrusion during the 2008 flood, in combination with wind effects, promotes downstream advection of MR waters towards the Louisiana–Texas shelf; large amounts of buoyant waters are also retained near the Delta, subject to local offshore advection under the synergistic action of LC-associated counter-rotating eddies.     

Implementation of a wetting-and-drying model in simulating the Kennebec–Androscoggin plume and the circulation in Casco Bay

A high-resolution coastal ocean model was developed to simulate the temporal/spatial variability of the Kennebec–Androscoggin (K–A) river plume and the circulation in Casco Bay. The model results agree favorably with the moored and shipboard observations of velocity, temperature, and salinity. The surface salinity gradient was used to distinguish the plume from the ambient coastal water. The calculated plume thickness suggests that the K–A plume is surface trapped. Its horizontal scales correlate well with Q ^0.25, where Q is the volume discharge of the rivers. Directional spreading is affected by the wind with the upwelling favorable wind transporting the plume water offshore. Both the wind and the tide also enhance mixing in the plume. The inclusion of a wetting-and-drying (WAD) scheme appears to enhance the mixing and entrainment processes near the estuary. The plume becomes thicker near the mouth of the estuary, the outflow velocity of the plume is weaker, and the radius of the river plume shrinks. The flow field in the model run with the WAD is noisier, not only in shallow areas of Casco Bay but also in the plume and even on the shelf. We speculate that the WAD processes can affect much larger areas than the intertidal zones, especially via a river plume that feeds into a coastal current.     

Factors affecting longitudinal dispersion in estuaries of different scale

Traditionally, the overall diluting capacity of an estuary is characterized using a coefficient of longitudinal dispersion, K_xe, which is given by the ratio of the dispersive flux of a dissolved substance to its tidally averaged longitudinal gradient. A steady-state model, which assumes a balance between the dispersive and non-dispersive fluxes and an exponential increase in estuary cross-sectional area towards the sea, has been used to derive expressions for the axial salinity distribution and the dispersive flux of salt. The model was set up assuming either a constant dispersion coefficient along the estuary or one that increased with distance towards the sea. By comparing salinity predictions with data from five UK estuaries, estimates were made of the maximum dispersive salt flux and the corresponding maximum salinity gradient for each system. The results indicated that there was an approximately linear relation between the fluxes and gradients, and the slope of a line plotted through the origin provided an estimate of a common K_xe for all five estuaries. The magnitude of K_xe was found to be about 90 m² s^–1 with a standard deviation of approximately ±32 m² s^–1. It is concluded that a representative value of 100 m² s^–1 for K_xe is a reasonable first choice when setting up a cross-sectionally averaged estuary model. The results also showed that larger systems, such as the Thames, had lower salinity gradients and lower dispersive salt fluxes, whilst smaller estuaries displayed the opposite characteristics. The model was used to predict the variation in the non-advective flux of salt along an estuary. The distribution was found to be similar to the corresponding flux distribution estimated from observations at the seaward end of the Tees estuary, despite appreciable spatial variations in the individual flux components. Allowing for a small decrease in freshwater flow, the model indicated that there was a decrease in the maximum dispersive flux between neap and spring tides. It is argued that such a reduction in flux can result in a seaward shift in the salinity distribution to a region of greater cross-section, where the freshwater transport per unit area again balances the reduced upstream dispersive flux, as found in the neap to spring response in the Tees estuary.Responsible Editor: Hans Burchard     

Space–time variability of the Plata plume inferred from ocean color

Satellite ocean color and surface salinity data are used to characterize the space–time variability of the Río de la Plata plume. River outflow and satellite wind data are also used to assess their combined effect on the plume spreading over the Southwestern South Atlantic continental shelf. Over the continental shelf satellite-derived surface chlorophyll-a (CSAT) estimated by the OC4v4 SeaWiFS retrieval algorithm is a good indicator of surface salinity. The log (CSAT) distribution over the shelf presents three distinct modes, each associated to: Subantarctic Shelf Water, Subtropical Shelf Water and Plata Plume water. The log (CSAT) 0.4–0.8 range is associated with a sharp surface salinity transition across the offshore edge of the Plata plume from 28.5 to 32.5. Waters of surface salinity <31, derived from mixtures of Plata waters with continental shelf waters, are associated to log (CSAT)>0.5. In austral winter CSAT maxima extend northeastward from the Plata estuary beyond 30°S. In summer the high CSAT waters along the southern Brazil shelf retreat to 32°S and extend south of the estuary to about 37.5°S, only exceeding this latitude during extraordinary events. The seasonal CSAT variations northeast of the estuary are primarily controlled by reversals of the along-shore wind stress and surface currents. Along-shore wind stress and CSAT variations in the inner and mid-shelves are in phase north of the estuary and 180° out of phase south of the estuary. At interannual time scales northernmost Plata plume penetrations in winter (∼1200 km from the estuary) are associated with more intense and persistent northeastward wind stress, which in the period 2000–2003, prevailed over the shelf south of 26°S. In contrast, in winter 1999, 2004 and 2005, characterized by weaker northeastward wind stress, the plume only reached between 650 and 900 km. Intense southwestward plume extensions beyond 38°S are dominated by interannual time scales and appear to be related to the magnitude of the river outflow. The plume response to large river outflow fluctuations observed at interannual time scales is moderate, except offshore from the estuary mouth, where outflow variations lead CSAT variations by about 2 months.     

Deep circulation driven by strong vertical mixing in the Timor Basin

The importance of deep mixing in driving the deep part of the overturning circulation has been a long debated question at the global scale. Our observations provide an illustration of this process at the Timor Basin scale of ～1000 km. Long-term averaged moored velocity data at the Timor western sill suggest that a deep circulation is present in the Timor Basin. An inflow transport of ～0.15 Sv is observed between 1600 m and the bottom at 1890 m. Since the basin is closed on its eastern side below 1250 m depth, a return flow must be generated above 1600 m with a ～0.15 Sv outflow. The vertical turbulent diffusivity is inferred from a heat and transport balance at the basin scale and from Thorpe scale analysis. Basin averaged vertical diffusivity is as large as 1 × 10^?3 m² s^?1. Observations are compared with regional low-resolution numerical simulations, and the deep observed circulation is only recovered when a strong vertical diffusivity resulting from the parameterization of internal tidal mixing is considered. Furthermore, the deep vertical mixing appears to be strongly dependent on the choice of the internal tide mixing parameterization and also on the prescribed value of the mixing efficiency.     

Impact of eddies on ocean diapycnal mixing in Gulf Stream region

Based on high-resolution,Array for Real-time Geostrophic Oceanography(Argo)profiles and Sea Level Anomaly(SLA)data,this study statistically analyzes and compares turbulent diapycnal mixing profiles inside and outside mesoscale eddies in the Gulf Stream region.The result indicates that average diapycnal diffusivity at 300–540 m depths in anticyclonic eddies reaches4.0×10-5 m2 s-1.This is significantly higher than the 1.6×10-5 m2 s-1 outside eddies and 0.8×10-5 m2 s-1 in cyclonic eddies.Probabilities of diapycnal diffusivity greater than 10-4 m2 s-1 within anticyclonic and cyclonic eddies and outside eddies are29%,5%and 12%,respectively.However,magnitudes of average diapycnal diffusivity at 540–900 m depths in these three cases are of the same order,10-5 m2 s-1.Twenty-four of a total 38 anticyclonic eddies had enhanced mixing in the ocean interior,and 22 were observed during or shortly after strong winds.The coincidence between enhanced mixing and strong wind stress indicates that more wind-induced,near-inertial wave energy propagates downward in anticyclonic eddies.The deeper part of 12 profiles(below 540 m)in anticyclonic eddies had vertical overturns with Thorpe scale exceeding 5 m,among which three profiles had overturns reaching 20 m.Enhanced mixing may have occurred in deep layers of some profiles,although it was not evident in average conditions.     

Patos Lagoon outflow within the Río de la Plata plume using an airborne salinity mapper: Observing an embedded plume

Major river systems discharging into continental shelf waters frequently form buoyant coastal currents that propagate along the continental shelf in the direction of coastal trapped wave propagation (with the coast on the right/left, in the northern/southern hemisphere). The combined flow of the Uruguay and Paraná Rivers, which discharges freshwater into the Río de la Plata estuary (Lat. ∼36°S), often gives rise to a buoyant coastal current (the ‘Plata plume’) that extends northward along the continental shelf off Uruguay and Southern Brazil. Depending upon the prevailing rainfall, wind and tidal conditions, the Patos/Mirim Lagoon complex (Lat. ∼32°S) may also produce a freshwater outflow plume that expands across the inner continental shelf. Under these circumstances the Patos outflow plume can be embedded in temperature, salinity and current fields that are strongly influenced by the larger Plata plume. The purpose of this paper is to present observations of such an embedded plume structure and to determine the dynamical characteristics of the ambient and embedded plumes.     

Numerical study of circulation on the inner Amazon Shelf

We studied the circulation on the coastal domain of the Amazon Shelf by applying the hydrodynamic module of the estuarine and coastal ocean model and sediment transport. The first barotropic experiment aimed to explain the major bathymetric effects on tides and those generated by anisotropy in sediment distribution. We analyzed the continental shelf response of barotropic tides under realistic bottom stress parametrization (C _d ), considering sediment granulometry obtained from a faciologic map, where river mud deposits and reworked sediments areas are well distinguished, among others classes of sediments. Very low C _d values were set in the fluid mud regions off the Amapá coast (1.0 10^???4), in contrast to values around 3.5 10^???3 for coarser sediment regions off the Pará coast. Three-dimensional experiments represented the Amazon River discharge and trade winds, combined to barotropic tide influences and induced vertical mixing. The quasiresonant response of the Amazon Shelf to the M₂ tide acts on the local hydrodynamics by increasing tidal admittance, along with tidal forcing at the shelf break and extensive fluid mud regions. Harmonic analysis of modeled currents agreed well with the analysis of the AMASSEDS observational data set. Tidal-induced vertical shear provided strong homogenization of threshold waters, which are subject to a kind of hydraulic control due to the topographic steepness. Ahead of the hydraulic jump, the low-salinity plume is disconnected from the bottom and acquires negative vorticity, turning southeastward. Tides act as a generator mechanism and topography, via hydraulic control, acts as a maintainer mechanism for the low-salinity frontal zone positioning. Tidally induced southeastward plume fate is overwhelmed by northwestward trade winds so that they, along with background circulation, probably play the most important role on the plume fate and variability over the Amazon Shelf.     

Comparison of hypoxia among four river-dominated ocean margins: The Changjiang (Yangtze), Mississippi,Pearl, and Rhône rivers

We examined the occurrence of seasonal hypoxia (O₂<2 mg l⁻¹) in the bottom waters of four river-dominated ocean margins (off the Changjiang, Mississippi, Pearl and Rhône Rivers) and compared the processes leading to the depletion of oxygen. Consumption of oxygen in bottom waters is linked to biological oxygen demand fueled by organic matter from primary production in the nutrient-rich river plume and perhaps terrigenous inputs. Hypoxia occurs when this consumption exceeds replenishment by diffusion, turbulent mixing or lateral advection of oxygenated water. The margins off the Mississippi and Changjiang are affected the most by summer hypoxia, while the margins off the Rhône and the Pearl rivers systems are less affected, although nutrient concentrations in the river water are very similar in the four systems. Spring and summer primary production is high overall for the shelves adjacent to the Mississippi, Changjiang and Pearl (1–10 g C m⁻² d⁻¹), and lower off the Rhône River (<1 g C m⁻² d⁻¹), which could be one of the reasons of the absence of hypoxia on the Rhône shelf. The residence time of the bottom water is also related to the occurrence of hypoxia, with the Mississippi margin showing a long residence time and frequent occurrences of hypoxia during summer over very large spatial scales, whereas the East China Sea (ECS)/Changjiang displays hypoxia less regularly due to a shorter residence time of the bottom water. Physical stratification plays an important role with both the Changjiang and Mississippi shelf showing strong thermohaline stratification during summer over extended periods of time, whereas summer stratification is less prominent for the Pearl and Rhône partly due to the wind effect on mixing. The shape of the shelf is the last important factor since hypoxia occurs at intermediate depths (between 5 and 50 m) on broad shelves (Gulf of Mexico and ECS). Shallow estuaries with low residence time such as the Pearl River estuary during the summer wet season when mixing and flushing are dominant features, or deeper shelves, such as the Gulf of Lion off the Rhône show little or no hypoxia.     

Nitrate content and potential microbial signature of rock glacier outflow,Colorado Front Range

Here we characterize the nutrient content in the outflow of the Green Lake 5 rock glacier, located in the Green Lakes Valley of the Colorado Front Range. Dissolved organic carbon (DOC) was present in all samples with a mean concentration of 0·85 mg L^?1 . A one‐way analysis of variance test shows no statistical difference in DOC amounts among surface waters (p = 0·42). Average nitrate concentrations were 69 µmoles L^?1 in the outflow of the rock glacier, compared to 7 µmoles L^?1 in snow and 25 µmoles L^?1 in rain. Nitrate concentrations from the rock glacier generally increased with time, with maximum concentrations of 135 µmoles L^?1 in October, among the highest nitrate concentrations reported for high‐elevation surface waters. These high nitrate concentrations appear to be characteristic of rock glacier outflow in the Rocky Mountains, as a paired‐difference t‐test shows that nitrate concentrations from the outflow of 7 additional rock glaciers were significantly greater compared to their reference streams (p = 0·003). End‐member mixing analysis suggest that snow was the dominant source of nitrate in June, ‘soil’ solution was the dominant nitrate source in July, and base flow was the dominant source in September. Fluoresence index values and PARAFAC analyses of dissolved organic matter (DOM) are also consistent with a switch from terrestrial DOM in the summer time period to an increasing aquatic‐like microbial source during the autumn months. Copyright © 2006 John Wiley & Sons, Ltd.     

Numerical study of circulation and temperature-salinity distributions in the Bras d’Or Lakes

The Bras d’Or Lakes (BdOL) are a large, complex and virtually land-locked estuary in central Cape Breton Island of Nova Scotia and one of Canada’s charismatic ecosystems, sustaining ecological and cultural communities unique in many aspects. The BdOL comprise two major basins, many deep and shallow bays, several narrow channels and straits and a large, geologically complex watershed. Predictive knowledge of the water movement within the estuary is a key requirement for effective management and sustainable development of the BdOL ecosystem. A three-dimensional (3D) primitive-equation ocean circulation model is used to examine the estuary’s response to tides, winds and buoyancy forcing associated with freshwater runoff in a series of numerical experiments validated with empirical data. The model results generate intense, jet-like tidal flows of about 1 m s^?1 in the channels between the basins and connecting them to the ocean and relatively weak tidal currents in other regions, which agrees well with previous observations and numerical results. Wind forcing and buoyancy forcing associated with river runoff play important roles in generating the significant sub-tidal circulations in the estuary, including narrow channels, deep basins and shallow bays. The circulation model is also used to reconstruct the 3D circulation and temperature-salinity distributions in the summer months of 1974, when current and hydrographic measurements were made at several locations. The sub-tidal circulation in the estuary produced by the model is characterised by wind and barometric set-up and set-down in different sections of the system, and a classic two-layer estuarine circulation in which brackish, near-surface waters flow seaward from the estuary into the Atlantic Ocean, and deep salty waters flow landward through the major channel. The model results reproduce reasonably well the overall features of observed circulation and temperature-salinity fields made in the BdOL in 1974 but generally underestimate the observed currents and density stratification. The model discrepancies reflect the use of spatially mean wind forcing and spatially and monthly mean surface heat flux and the inability of the coarse model horizontal resolution (～500 m) to resolve narrow channels and straits.     

Mechanisms leading to the frequent occurrences of hypoxia and a preliminary analysis of the associated acidification off the Changiiang estuary in summer

Based on literature data and shipboard observations,this study investigated the main environmental characteristics of the seafloor topography,current field,front,and upwelling that are closely related to hypoxia occurrence off the Changjiang estuary.The physical processes of the plume front and upwelling off the Changjiang estuary in summer were coupled.The vertical distribution pattern of the plume front was closely related to the upwelling.By reviewing and analyzing the historical summer hypoxia events off the Changjiang estuary,we statistically demonstrated the spatial structure of the horizontal distribution of the hypoxic zone and investigated the location of occurrence zone of the hypoxia.We found that the dissolved oxygen(DO)concentration on the inner continental shelf off the estuary showed a"V"shape in relation to station depth.Therefore,we noted that the hypoxic water on the inner continental shelf mostly occurred on the slopes with steep seafloor topography.Base on the current understanding of the hypoxic mechanisms off the Changjiang estuary,we analyzed the biogeochemical mechanisms that could cause the steep terrain off the Changjiang estuary to become the main areas prone to summer hypoxia and explained the internal relations between the location of the hypoxic zone on the slopes and the plume front and upwelling.The plume front and upwelling off the Changjiang estuary and their coupling were important driving forces of summer hypoxia.The continuous supply of nutrients affected by the interaction of the plume front extension of the Changjiang Diluted Water(CDW)and upwelling and the favorable light conditions were important mechanisms causing the phytoplankton blooms and benthic hypoxia off the Changjiang estuary in summer.By analyzing oxygen utilization,organic carbon mineralization,and nutrient regeneration in the hypoxic zone,we observed that the significant oxygen utilization process off the Changjiang estuary in summer also mainly occurred near the steep slopes with front and upwelling features and confirmed the apparent nutrient loss in the benthic hypoxic zone.Meanwhile,our analysis revealed that the sediment resuspension in the benthic boundary layer in the mud areas off the Changjiang estuary could also affect the oxygen utilization and mineralization of organic carbon and nutrient recycling and regeneration.This study also demonstrated that the steep terrain off the Changjiang estuary was the main location for summer acidification,and the coupling between the plume front and upwelling on the steep slopes was an important physical driving force inducing summer benthic acidification.Finally,we discussed issues to address in future studies of the hypoxic zone and water acidification off the Changjiang estuary.     

Groundwater supply of lakes: the case of Lake Raduńskie Górne (northern Poland,Kashubian Lake District)

ABSTRACT

The aim of the study was to locate and describe groundwater outflows in a selected lake basin and measure the spring output of water and the physical characteristics of the studied waters (temperature and conductivity). The final aim was to gauge the effects of the spring output on the lake hydrology. The time scope of the work included the period from January 2011 to September 2012. The spatial scope of the work included the area of Lake Raduńskie Górne and its direct catchment located in the Kashubian Lake District in northern Poland. Four groundwater outflows were located in the course of the study. Their total output was 4.6 L s^?1 and ranged between 0.5 and 2.5 L s^?1. This produces an annual yield of about 145 000 m³ year^?1. These results confirm that one of the forms of supply to the lakes are the under-lake springs. For lakes located in the area of young glacial accumulation this can be decisive.

Editor D. Koutsoyiannis Associate editor D. Gerten     

Input and behaviour of linear alkylbenzenesulphonates (LAS) in a stratified estuary

Input and distribution of linear alkylbenzenesulphonates (LAS) in the highly stratified Krka River estuary were studied during 1990–1991. Determinations of individual LAS homologues in wastewater and estuarine waters were performed using reversed-phase high-performance liquid chromatography (HPLC) with spectrofluorimetric detection. The investigated municipal wastewaters contained LAS homologues with alkyl-chain lengths from C₁₀ to C₁₃ at total concentrations in the range of 285–1041 μg l⁻¹. Total LAS input via wastewaters into ibenik Harbour, the most polluted part of the estuary, was estimated at 12.6 kg day⁻¹. A relatively large fraction of total LAS, depending on the wastewater particle load, was found in particulate form (11–59%). Distributions of the individual homologues in dissolved and particulate fractions were rather different, the latter being significantly enriched in higher homologues (C₁₂, C₁₃). The LAS concentration in the estuary was quite low (0.2–23.9 μg l⁻¹) which was caused chiefly by a strong and fast dilution process. However, characteristic vertical distribution of LAS in the estuarine water column indicated that the wastewater plume spreads almost exclusively in the upper (brackish) layer. The concentration maxima were observed in the surface microlayer and at the brackish water/seawater boundary.     

Nutrient processes and chlorophyll in the estuaries and plume of the Gulf of Papua

This paper investigates the waters of the Gulf of Papua during three cruises of the TROPICS (Tropical River Ocean Processes In Coastal Settings) programme. Plume characteristics were investigated during Leg 1 (May 1997), and estuarine properties during Leg 5a (September 1997) and Leg 7 (January 1999). During Leg 1 the plume was apparent as a well mixed layer up to 30 m deep extending offshore to a distance of 150 km off the Fly River. Lowest salinities were found off the Taruma Delta. Highest chlorophyll concentrations were found at the inner plume close to the river mouth. Dissolved phosphate and nitrate are removed in this zone, whereas silicate behaves conservatively. Primary productivity within the plume appears to rely upon recycled nutrients, with organic fractions representing the majority of the nutrient pool. In the estuaries nutrients were found to behave differently during the monsoon than during the low flow of the extremely dry conditions associated with the 1997 El Niño event. Normally the Fly is characterised by remineralisation of organic nitrogen in the upper estuary, but during drought conditions DON production and NH₄⁺ uptake suggest that bacterial activity is more prevalent. Ocean Colour and Temperature Scanner imagery shows a number of features of the plume, but generally overestimates chlorophyll concentrations due to the effects of high suspended sediment concentrations and, to a lesser extent, coloured dissolved organic matter.     

Mechanisms leading to the frequent occurrences of hypoxia and a preliminary analysis of the associated acidification off the Changjiang estuary in summer

Based on literature data and shipboard observations, this study investigated the main environmental characteristics of the seafloor topography, current field, front, and upwelling that are closely related to hypoxia occurrence off the Changjiang estuary. The physical processes of the plume front and upwelling off the Changjiang estuary in summer were coupled. The vertical distribution pattern of the plume front was closely related to the upwelling. By reviewing and analyzing the historical summer hypoxia events off the Changjiang estuary, we statistically demonstrated the spatial structure of the horizontal distribution of the hypoxic zone and investigated the location of occurrence zone of the hypoxia. We found that the dissolved oxygen (DO) concentration on the inner continental shelf off the estuary showed a “V” shape in relation to station depth. Therefore, we noted that the hypoxic water on the inner continental shelf mostly occurred on the slopes with steep seafloor topography. Base on the current understanding of the hypoxic mechanisms off the Changjiang estuary, we analyzed the biogeochemical mechanisms that could cause the steep terrain off the Changjiang estuary to become the main areas prone to summer hypoxia and explained the internal relations between the location of the hypoxic zone on the slopes and the plume front and upwelling. The plume front and upwelling off the Changjiang estuary and their coupling were important driving forces of summer hypoxia. The continuous supply of nutrients affected by the interaction of the plume front extension of the Changjiang Diluted Water (CDW) and upwelling and the favorable light conditions were important mechanisms causing the phytoplankton blooms and benthic hypoxia off the Changjiang estuary in summer. By analyzing oxygen utilization, organic carbon mineralization, and nutrient regeneration in the hypoxic zone, we observed that the significant oxygen utilization process off the Changjiang estuary in summer also mainly occurred near the steep slopes with front and upwelling features and confirmed the apparent nutrient loss in the benthic hypoxic zone. Meanwhile, our analysis revealed that the sediment resuspension in the benthic boundary layer in the mud areas off the Changjiang estuary could also affect the oxygen utilization and mineralization of organic carbon and nutrient recycling and regeneration. This study also demonstrated that the steep terrain off the Changjiang estuary was the main location for summer acidification, and the coupling between the plume front and upwelling on the steep slopes was an important physical driving force inducing summer benthic acidification. Finally, we discussed issues to address in future studies of the hypoxic zone and water acidification off the Changjiang estuary.     

Factors controlling the chemical evolution of travertine‐depositing rivers of the Barkly karst,northern Australia

Groundwaters feeding travertine‐depositing rivers of the northeastern segment of the Barkly karst (NW Queensland, Australia) are of comparable chemical composition, allowing a detailed investigation of how the rate of downstream chemical evolution varies from river to river. The discharge, pH, temperature, conductivity and major‐ion concentrations of five rivers were determined by standard field and laboratory techniques. The results show that each river experiences similar patterns of downstream chemical evolution, with CO₂ outgassing driving the waters to high levels of calcite supersaturation, which in turn leads to widespread calcium carbonate deposition. However, the rate at which the waters evolve, measured as the loss of CaCO₃ per kilometre, varies from river to river, and depends primarily upon discharge at the time of sampling and stream gradient. For example, Louie Creek (Q = 0·11 m³ s^?1) and Carl Creek (Q = 0·50 m³ s^?1) have identical stream gradients, but the loss of CaCO₃ per kilometre for Louie Creek is twice that of Carl Creek. The Gregory River (Q = 3·07 m³ s^?1), O'Shanassy River (Q = 0·57 m³ s^?1) and Lawn Hill Creek (Q = 0·72 m³ s^?1) have very similar gradients, but the rate of hydrochemical evolution of the Gregory River is significantly less than either of the other two systems. The results have major implications for travertine deposition: the stream reach required for waters to evolve to critical levels of calcite supersaturation will, all others things being equal, increase with increasing discharge, and the length of reach over which travertine is deposited will also increase with increasing discharge. This implies that fossil travertine deposits preserved well downstream of modern deposition limits are likely to have been formed under higher discharge regimes. Copyright © 2002 John Wiley & Sons, Ltd.     

Nutrients,irradiance, and mixing as factors regulating primary production in coastal waters impacted by the Mississippi River plume

Relationships among primary production, chlorophyll, nutrients, irradiance and mixing processes were examined along the salinity gradient in the Mississippi River outflow region. A series of six cruises were conducted during 1988–1992 at various times of year and stages of river discharge. Maximum values of biomass and primary production were typically observed at intermediate salinities and coincided with non-conservative decreases in nutrients along the salinity gradient. Highest values of productivity (>10 gC m⁻² d⁻¹) and biomass (>30 mg chlorophyll a m⁻³) were observed in April 1988, July–August 1990 and April–May 1992; values were lower in March and September 1991. Rates of primary production were apparently constrained by low irradiance and mixing in the more turbid, low salinity regions of the plume, and by nutrient limitation outside the plume. Highest values of primary production occurred at stations where surface nutrient concentrations exhibited large deviations from conservative mixing relationships, indicating that depletion of nutrients was related to phytoplankton uptake. Mixing and advection were important in determining the location and magnitude of primary production maxima and nutrient depletion. In addition to growth within plume surface waters, enhanced growth and/or retention of biomass may have occurred in longer residence time waters at the plume edge and/or beneath the surface plume. Vertical structure of some plume stations revealed the presence of subsurface biomass maxima in intermediate salinity water that was depleted in nutrients presumably by uptake processes. Exchange between subsurface water and the surface plume apparently contributed to the reduction in nutrients at intermediate salinities in the surface layer. DIN (=nitrate+nitrite+ammonium) : PO₄ (=phosphate) ratios in river water varied seasonally, with high values in winter and spring and low values in late summer and fall. Periods of high DIN : PO₄ ratios in river nutrients coincided with cruises when surface nutrient concentrations and their ratios indicated a high probability for P limitation. N limitation was more likely to occur at high salinities and during late summer and fall. Evidence for Si limitation was also found, particularly in spring.