小流域农业面源污染监测断面设置与污染物通量估算研究进展

流域尺度面源污染的监测是系统认识农业面源污染的发生、迁移及转化过程,并对其进行有效控制的重要基础.当前,田块尺度的面源污染监测方法比较成熟,而流域尺度的监测,尤其是监测断面的布设及采样频率设置等方面的研究较少.本文详细梳理了小流域采样断面布设、采样频率优化和河流断面通量估算3方面的主要进展.1)从小流域样点布设来看,包括常规监测采样设计、针对性监测采样设计和融合前两种类型的监测采样设计3种类型,点位布设方法上有遗传算法、模糊逻辑法、熵值法和模型法等,样品采集方式包括随机采样、复合采样、综合采样以及连续采样4种类型,其中复合采样应用广泛;2)从采样频率来看,1～2周一次的采样频率即可精准获取污染负荷通量,若需要进一步提高精度,可在水文/水质变异大的时期提高监测频率及在特殊断面加密布点;3)在通量估算上,当前主要的计算方法有平均法、插值法和回归/曲线法3类方法,其中流量加权的浓度估计法、插值算法和LOADEST法是简便且精确的方法,方法的选择上也可根据不同时期流域污染源特征进一步优化.     

宜兴太湖防护林对农业面源污染的减源增汇作用浅析

为探讨太湖沿岸防护林宜兴段对农业面源污染物的控制效果,通过在宜兴市太湖防护林采集土壤样品,测定其中营养元素含量,结合周边农业生产施肥概况,初步分析了该区域防护林对农业面源污染的减源—增汇效应.结果表明,2009年10月份防护林地上部分固定的C、N、P和K分别为2439.48、18.34、2.48和13.42 g/m2;2011年5月份固定量分别为3114.12、23.42、3.16和17.13 g/m2;而2013年8月份固定量分别为4722.46、35.53、4.81和25.99 g/m2.可见C、N、P和K的固定量是逐年增加的,相比2009年,分别增加了93.6%、93.7%、94.0%和93.7%.结果说明宜兴段太湖沿岸防护林对农业面源污染的控制效果较显著,有助于太湖水污染的治理.     

基于湖库水质目标的流域氮、磷减排与分区管理——以天目湖沙河水库为例

湖库水环境保护在保障生产与生活用水、维系生态平衡、发展旅游等方面发挥着重要的作用.水质目标管理是保护湖库水质的最佳管理办法.本文以天目湖地区沙河水库及其流域为研究区域,建立模型模拟沙河水库流域的水文与水质,评估入库污染通量和主要来源;依据水质目标测算氮、磷污染的容量和减排量,结合土地的生态保护与开发适宜性评估,提出氮、磷污染分区减排和土地管控的对策和措施.研究结果表明,沙河水库氮、磷污染物入库通量分别为206.01和3.29 t/a,面源总氮和总磷分别占总入库量的85.7%和67.5%.不同土地利用类型氮、磷输出强度有显著差异,总氮输出强度依次为茶园 >耕地 >建筑用地 >裸地 >草地 >退耕地 >林地 >河湖漫滩,总磷输出强度与地表覆盖度有关,依次为裸地 >建筑用地 >茶园 >耕地 >草地 >退耕地 >林地和河湖漫滩.从氮、磷输移过程来看,沙河水库流域总氮排放量为321.64 t/a,进入河流的为255.53 t/a,在河道输送过程中损失19.4%,最终有206.01 t/a进入水库;沙河水库流域总磷排放量为13.42 t/a,进入河流的为7.90 t/a,在河道输送过程中损失58.3%,最终有3.29 t/a进入水库.不同分区河流氮、磷滞留降解率有很大的差异,中田河总氮、总磷滞留降解能力最强,分别为34.71%和84.31%.2009年的通量计算结果显示,沙河水库总氮达到Ⅳ类水质目标需要的入湖减少量为32.01 t/a,入湖削减比例为15.50%,总氮达到Ⅲ类水质目标需要的入湖减少量为59.66 t/a,入湖削减比例为29.00%;总磷达到Ⅲ类水需要的入湖减少量为0.682 t/a,入湖削减比例为20.70%,总磷达到Ⅱ类水需要的入湖减少量为1.479 t/a,入湖削减比例为44.90%.为了实现基于土地利用的面源污染减排管控,选定植被覆盖度、水源涵养能力、地形坡度、土地利用、氮磷分区贡献量、与道路和村落距离等指标综合评估生态保护价值和开发适宜性,并划定禁止开发区、限制开发区和保护性开发区3个管理分区,最终确定各分区的开发强度限制和管控方式.     

基于数学建模的潜在地震破裂面源检测方法研究

大多数地震破裂面源检测方法都是通过简化地震震源,将地震震源表示成线源或者点源,无法有效描述地震带地震破裂面源产状和大小,不适用地震震级较大的情况下地震危险性检测。因此提出基于数学建模的潜在地震破裂面源检测方法,在地震震级较大时仍能检测出地震危险性概率。选取适宜的地震基岩水平峰值加速度衰减关系,分析地震震级、破裂长度、破裂宽度相互关系,确定地震引起的潜在地震破裂面源大小,计算给定地震动小于在场点处产生地震动的概率,将该概率同地震动加速度衰减关系结合,得到地震动年超越概率,分析地震危险性。经过实验检测发现,所提方法检测出的年超越概率与峰值加速度、最大震级有关,该概率能精准表示地震带地震破裂面源产状和大小,说明该方法检测地震危险性是合理的。     

基于潜在破裂面源模型的南北地震带南段地震区划研究

南北地震带南段大震活动频繁。已有的研究结果表明,大震近场范围场点的地震危险性与地震破裂面产状及其尺度密切相关。因此,在南北地震带南段需要考虑潜在震源三维特征进行地震危险性分析和地震区划研究。本文在充分搜集大震发震构造资料的基础上,在南北地震带南段构建了考虑震源尺度和产状的潜在震源模型,改进了地震危险性概率分析方法,进而对该地区进行地震区划研究。结果表明,考虑潜在震源三维特征的地震危险性分析结果可以有效地反映南北地震带南段发震构造的产状和尺寸特征,提高地震区划结果的合理性。     

The non-point source pollution in livestock-breeding areas of the Heihe River basin in Yellow River

A GIS-based distributed soil and water assessment tools (SWAT) model was used to simulate the runoff, sediment yield and the load of the non-point source pollution in the Heihe River basin, which is a tributary and main water supply source of the Yellow River. It is a typical stockbreeding area, and its industry and agriculture are not well developed. The main pollution source of the Heihe River was livestock related non-point source pollution. With GIS and remote sensing techniques, a database of non-point source pollution in the Heihe River basin was established. The SWAT model was parameterized for this area. The pollution load and transportation rules such as nitrogen were illustrated. After several years of hard work, the situations of point source pollution were more and more accurate. This paper provided an effective way to assess and calculate the pollution load in the wide agriculture area in China. With the help of historical data formulated parameters, the non-point source load and the theory of pollution load distribution were illustrated about the Heihe River basin. In 2000, the soluble N load in this area was 1.06 × 106 kg. By the simulation, the main pollution sources were in the south east of the basin, where the pasturing areas located in the south-east of Ruoergai County and in north of the Hongyuan County.     

稻虾轮作模式面源污染排放特征及其能值评估

为探明稻虾轮作模式面源污染排放特征并合理评价该模式的环境可持续性,通过对江汉平原稻虾轮作模式小龙虾养殖排放尾水中总氮(TN)、总磷(TP)、COD和氨氮(NH₃-N)浓度进行监测,对稻虾轮作模式稻田养殖小龙虾的排污系数进行了估算,并采用等标污染负荷法进行了主要污染物解析。运用能值分析方法对稻虾轮作模式进行了包含面源污染的能值评估,对比单季稻模式,对其可持续发展能力进行了定量评价。结果表明：江汉平原稻虾轮作模式小龙虾养殖排放尾水中TN、TP、COD和NH₃-N的浓度范围分别为0.53～5.36、0.12～0.70、6.60～78.39和0.34～1.75 mg/L,TN、TP和COD平均排放浓度高于《地表水环境质量标准》(GB 3838-2002)Ⅲ类水质标准。等标污染负荷法分析结果表明TN的等标负荷比最高,是稻虾轮作模式面源污染控制的关键污染物。稻虾轮作模式小龙虾养殖排放尾水中TN、TP、COD和NH₃-N的排污系数分别为2.994、0.458、35.132和1.405 kg/t,表明稻虾轮作模式面源污染排放系数较低,对...     

40 年来江苏石梁河水库重金属污染的沉积记录

根据石梁河水库沉积物粒度和重金属元素(Cu,Cr,Zn,As和Pb)含量的分析,结合137Cs放射性比活度精确定年,研究了石梁河水库沉积速率和重金属的污染变化特征,并利用地累积指数法评价了重金属的污染程度.结果表明:石梁河水库 40年来平均淤积速率为3.85cm/a,Cu,Cr和zn地累积指数一直小于1,处于轻微污染;As污染水平变化较大.现处于低水平的轻度污染;Pb污染水平自柱底始持续恶化,目前地累积指数大于1,且有污染加剧趋势.     

Reservoir-type water source vulnerability assessment: a case study of the Yuqiao Reservoir,China

ABSTRACT

In this study, we developed a method to assess reservoir-type water source vulnerability (WSV) and adapted the method to the Yuqiao Reservoir (in Tianjin in North China). First, we identified the factors that influence reservoir vulnerability and selected suitable indexes for vulnerability assessment. Second, the CRITIC, AHP and integrated weighting methods were applied to quantify the index weight. Third, the information diffusion method was applied to process the index data. Finally, the vulnerability of the Yuqiao Reservoir was assessed, and the results showed that the vulnerability of the Yuqiao Reservoir is high, with social factors (i.e. the road traffic system, automatic management control system, potential menace in evaluation scope, destructive man-made accidents, emergency management plan, and per capita water consumption) being the main reasons.     

Detection of spatial fluctuations of non-point source fecal pollution in coral reef surrounding waters in southwestern Puerto Rico using PCR-based assays

Human fecal contamination of coral reefs is a major cause of concern. Conventional methods used to monitor microbial water quality cannot be used to discriminate between different fecal pollution sources. Fecal coliforms, enterococci, and human-specific Bacteroides (HF183, HF134), general Bacteroides-Prevotella (GB32), and Clostridium coccoides group (CP) 16S rDNA PCR assays were used to test for the presence of non-point source fecal contamination across the southwestern Puerto Rico shelf. Inshore waters were highly turbid, consistently receiving fecal pollution from variable sources, and showing the highest frequency of positive molecular marker signals. Signals were also detected at offshore waters in compliance with existing microbiological quality regulations. Phylogenetic analysis showed that most isolates were of human fecal origin. The geographic extent of non-point source fecal pollution was large and impacted extensive coral reef systems. This could have deleterious long-term impacts on public health, local fisheries and in tourism potential if not adequately addressed.     

The physico-chemical conditions of Turkwel Gorge Reservoir, a new man made lake in Northern Kenya

Variations in some physical, chemical, and nutrient conditions were investigated at Turkwel Gorge Reservoir and its inflowing river, Suam between 1994 and 1995. Seasonal changes in inflow volume had the greatest impact on the reservoir and river conditions investigated. A wide fluctuation in inflow volume combined with a regulated outflow independent of season resulted in a draw down of over 10 m in each year. Flood inflows during the wet season resulted in the lowest values of Secchi depth (range, 0.09–2.16 m), electrical conductivity (EC, range = 140–200 mS cm⁻¹) and total alkalinity (TA, range = 75–111 mg l⁻¹) while the highest values were measured during the dry season. A functional relation between EC and TA (TA = 0.529 mg l⁻¹, EC: R² = 0.876) suggests a predominance of carbonates among the anions. Vertical profiles of temperature and dissolved oxygen (DO) revealed that the reservoir is monomictic with a wide variation in the depth of the daily mixed layer. High values of pH (range = 6.7–8.9) and DO (range = 4.9–9.2 mg l⁻¹) were associated with periods of peak phytoplankton photosynthesis while the lowest values followed reservoir mixing. Peak total nitrogen (TN, range = 119–526 μg l⁻¹) and total phosphorus (TP, range = 8.9–71.6 μg l⁻¹) levels during the wet season resulted from increased river loading. Values of dissolved reactive silica (DRS, range = 0.41–9.77 mg l⁻¹) showed a wet season decline which was related to diatom depletion during the wet season. Annual reservoir areal loading rates of 27.38, 10.90 and 408.5 mg m⁻² were computed for TN, TP and DRS respectively based on estimates of inflowing river loads in 1994.

At the inflowing river Suam, low levels of EC (range = 107–210 μS cm⁻¹) and TA (range = 62–125 mg l⁻¹) occurred during the wet season while the highest levels occurred shortly before the river dried up. The first flood water at the resumption of river inflow in March was characterized by very low levels of DO (range = 1.8–8.2 mg l⁻¹) and high levels of TN (range = 205–3354 μg l⁻¹) and TP (102–1259 μg l⁻¹). River pII (6.9–7.7) and DRs (range = 9.01–19.93 mg l⁻¹) varied irregularly throughout the year.     

基于EFDC模型的河道型水库藻类生长对流域污染负荷削减的响应——以广东长潭水库为例

将环境(EFDC)模型应用于广东梅州的河道型水库——长潭水库,经过模型的验证,建立长潭水库水生态数学模型,模拟出水库在现状污染负荷下的藻类生长情况,以叶绿素a浓度为指标,研究水库在丰水年与枯水年富营养化改善程度对不同流域污染削减方案的响应关系.结果表明:现状污染负荷削减10%,在丰水年库尾、库中和库首点位的叶绿素a平均浓度分别降低13.99%、12.00%和10.35%;枯水年3个代表点位叶绿素a平均浓度分别下降8.42%、5.63%和2.10%.污染削减20%的情况下,丰水年3个代表点位的叶绿素a浓度分别降低26.78%、19.25%和17.04%,枯水年对应的降低幅度分别为11.72%、7.97%和5.12%;库尾地区表现出河道的特征,在污染负荷削减的情况下藻类生长能够受到有效遏制,库首地区则表现出湖泊的特性,枯水年这一特征表现更加突出,污染削减20%的情况下,叶绿素a的平均浓度仅降低5.12%.     

Non-point source pollution estimation in the Pingqiao River Basin,China, using a spatial hydrograph-separation approach

For efficient and targeted management, this study demonstrates a recently developed non-point source (NPS) pollution model for a year-long estimation in the Pingqiao River Basin (22.3 km²) in China. This simple but physically reasonable model estimates NPS export in terms of land use by reflecting spatial hydrological features and source runoff measurements under different land-use types. The NPS export was separately analysed by a distributed hydrological model, a spatial hydrograph-separation technique, and an empirical water quality sub-model. Simulation results suggest that 57 890 kg of total nitrogen (TN) and 1148 kg of total phosphorus (TP) were delivered. The results, validated with observed stream concentrations, show relative errors of 23.3% for TN and 47.4% for TP. Countermeasures for urban areas (5.3% of total area) were prioritized because of the high contribution rate to TN (14.1%) and TP (26.2%) which is caused by the high degree of runoff (8.5%) and pollution source.     

江苏省石梁河水库高分辨率沉积速率变化及环境意义

石梁河水库是江苏省最大的人工湖泊.开展水库沉积速率研究,对认识水库环境变化具有重要意义.本文对石梁河水库沉积物岩芯粒度组成特征进行了分析,表明沉积物以黏土质粉砂和粉砂质黏土为主,从底部向上呈明显的变细趋势,并记录了1970年的强降雨事件.采用¹³⁷Cs同位素测年分析,得到1963年和1986年两个时标.通过石梁河水库的沉积年代序列,推算出平均沉积速率:1963 1970年为10.85 cm/a,1970 1986年为3.81 cm/a,1986 2005年为1.32 cm/a.对比粒度沉积特征和流域降水记录,粗颗粒物质和降雨量的变化趋势基本相同,沉积物粒度组成特点直接反映了沉积时的降水、水动力搬运强度等信息.在河川来水来沙、坝前水位变化和地形等条件下,石梁河水库表现为三角洲淤积,且沉积速率逐渐变缓,符合水库淤积的一般规律.此外,石梁河水库上游建设的众多大型水库,拦截了大量泥沙,也使得沉积速率呈现减小趋势.