Base flow hydrology and water quality of an Ozarks spring and associated recharge area,southern Missouri,USA

Human activities in the karst Ozark Plateaus can impact water quality of springs where surface water is rapidly transferred to subsurface conduits. Bennett Spring, in southern Missouri, is the fourth largest spring in the state and supports local tourism activities. Questions regarding poorly functioning on-site wastewater systems (OWS) have raised concerns over the long-term water quality of the spring. This study reports the results of a surface water quality monitoring program in the recharge area where monthly samples were collected at base flow to identify potential pollution sources to the spring. Base flow hydrology of the recharge area was highly variable over the study period, which was drier than normal, causing an incomplete sampling record due to no flow conditions at some sites. For most of the year, nutrient levels were less than the eutrophic threshold (ET) of 0.075 mg/l total phosphorus (TP) and 1.5 mg/l total nitrogen (TN). Sites that consistently displayed concentrations of TP and TN higher than the ET were influenced by wastewater treatment plants (WTP) or OWS. Sites with nutrient concentrations above the ET were likely influenced by the re-release of nonpoint source related TP and TN delivered to streams during storm events. Water quality and discharge at the spring outlet remained consistent over the sampling period suggesting diffuse recharge from a deep aquifer source is able to dilute shallow ground water sources carrying nonpoint pollutants at base flow. Historical and regional data comparisons show these trends have been consistent over at least the last two decades.     

基于WEAP模型的西苕溪流域水质安全保障方案

针对西苕溪流域水质安全问题,基于WEAP建模平台,构建了西苕溪流域水资源评估与规划模型。在模型验证基础上,分析了西苕溪流域2001～2020年河道水功能目标满足度及水供需关系,识别了流域水资源利用存在的问题,并探讨了水源地和中下游区水质安全保障措施及其改善水质的效用,在此基础上提出了西苕溪流域水质安全保障方案。研究表明:TN是影响水源地供水安全的限制性因素,TN、TP是影响河道水功能的重要指标。通过综合实施废水处理厂、节水型设备、退耕还林等水资源管理措施能起到较好地削减TN产出的效果,水源地河道TN浓度降低,基本上能保证全年实现河道Ⅲ类水功能目标,中下游河道TP、TN浓度亦能达到Ⅲ类水功能要求。     

Evaluation of weir construction on water quality related to algal blooms in the Nakdong River

Understanding the effect of various environmental factors on algal blooms is essential for proper management of water resources. Eight weirs were constructed on the Nakdong River in South Korea between 2010 and 2011 to manage water resources and deal with possible floods and droughts. In this study, water quality observation data were collected from eight representative monitoring sites in the Nakdong River between 2001 and 2016. Particularly, the effect of the weirs construction on water retention time was statistically analyzed in terms of algal growth and other important water quality parameters. While there was slight increase of water temperature (0.8 °C) over 16 years, the concentrations of total phosphorous (TP) and total nitrogen (TN) decreased by 62.3, and 12.9%, respectively, after the construction of weirs. This TP decrease was noticeable, but still high enough to maintain the eutrophic state of the river. Correlation statistical analysis suggests that the Chl-a concentration is positively affected by the changes of TP, TN and chemical oxygen demand. However, there was no direct correlation between Chl-a concentration and the increased water retention time from the weir construction.     

长江中下游不同营养水平湖泊水体环境变化特征及机制

选择长江中下游49个湖泊进行不同季节的水体溶解无机氮(DIN)、总氮(TN)、总磷(TP),溶解性无机磷(DIP)以及叶绿素a(Chla)等环境参数分析,开展不同营养水平湖泊水体环境变化特征及生物响应机制研究。结果表明:DIN、TN/TP随TP的变化规律反映了不同营养水平和季节下地球化学作用的影响;氨氮(NH₄-N)、TP、DIP、Chla尤其是NH₄-N的季节性变化规律与营养水平关系密切;TP<0.05 mg/L时,NH₄-N随总磷升高的趋势夏季大于其他季节,TN/TP与硝态氮(NO₃-N)、TN相关性好,营养源组成和氨化作用是主要影响因素;0.05 mg/L4-N随总磷升高的趋势基本相同,TN/TP与亚硝态氮(NO₂-N)、NO₃-N、TN相关好,水生植物利用、氨化和反硝化作用是主要影响因素。TP>0.1 mg/L,冬季NH₄-N随总磷升高的趋势明显大于其他季节,TN/TP在冬季和春季与TN、NO₃-N相关性好,夏季和秋季与TP相关性好,其主要原因在于夏季和秋季水生植物对DIN的利用量、反硝化作用和湖泊内源释放的显著增强。     

Evaluating sedimentation effect on reservoirs water quality: a case study,Shahriyar reservoir

In this research, total dissolved solids (TDS) was simulated by CE-QUAL-W2 software in two scenarios of with and without sedimentation in normal, dry, and wet periods of inflow for Shahriyar reservoir, an under-construction dam located in Iran. Shahriyar reservoir is a dam with a total capacity of 700 million cubic meters (MCM) and a dead volume of 360 MCM. In case of with sedimentation compared with without sedimentation, results showed an annual average increase of 4, 4.3, and 8.7% in TDS of outflow for normal, wet, and dry periods, respectively. There is no significant change in TDS profile of the reservoir in both conditions. According to the average outflow TDS of 1448, 1301, and 1555 mg/L compared with the average inflow TDS of 1714, 1520, and 1835 in normal, wet, and dry conditions, respectively, the effect of dam on inflow TDS adjustment can be also observed. With the mentioned outflow TDS, there is no limitation to use of reservoir water for agricultural purposes based on FAO irrigation guidelines for both scenarios.     

Characteristics of Non—Point Source Pollution in the Watershed of Miyun Reservoir,Beijing,China

Nitrogen and phosphorus are the major nutrients to cause eutrophication to degrade water quality of the Miyun Reservoir,a very important drinking water source of Bijing,China,and they are mainly from non-point sources.The watershed in Miyun County was selected as the study region with a totoal area of 1400km^2.Four typical monitoring catchments and two experimental units were used to monitor the precipitation,runoff,sediment yield and pollutant loading related to various land uses in the meantime.The results show that the total nutrient loss amounts of TN and TP are 898.07t/a,and 40.70t/a,respectively,in which nutrients N and P carried by runoff are 91.3% and 77.3%,respectively.There is relatively heavier soil eroson in the northern mountain area whereas the main nutrient loss occurs near the northeast edge of the reservoir.Different land uses would influence the loss amounts of non-point source pollutants.The amount of nutrient loss from the agricultural land per unit is highest,that from forestry comes next that from grassland is lowest.However,due to the variability of land use areas,agricultural land contributes a lot to TP and forestry lands to TN.     

Lake water quality assessment: a case study of Shahu Lake in the semiarid loess area of northwest China

A comprehensive assessment on lake water quality was carried out in Shahu Lake, northwest China, to provide valuable information about present lake water quality for decision making. Major ions, general parameters, bacteriological parameters, organics and trace metals monitored monthly in 2014 were considered. Monitored parameters were compared with quality criteria for surface water of China, and overall water quality assessment was carried out using an entropy weighted water quality index (EWQI) based on 20 selected parameters. Lake water quality was also assessed for irrigation purpose. The results show that the lake water is of Cl·SO₄–Na facies with high salinity and COD. The geochemistry of the lake water is regulated by intense evaporation and human activities. TP, TN and F^? are major inorganic contaminants, with over 50% of the water samples polluted by them. Oil, mainly attributed by leaky motor tourist boats, is the major organic pollutants in the lake water, with 10 samples (37.04%) showing higher oil content than the permissible limit. The concentrations of other inorganic and organic contaminants as well as trace metals are well below the permissible limits. The present study indicates that inorganic contamination in the lake water is more severe than organic pollution. The overall lake water quality, assessed by EWQI, is poor and very poor with SO₄ ^2?, TDS, TH and Cl^? being the dominant contributing factors. The lake water is suitable for irrigation in terms of alkalinity, but is unsuitable for irrigation from the salinity point of view. Accelerating the circulation and replenishment of the lake water is an important way of reducing contaminant concentrations. This study is important in providing comprehensive information on lake water quality for decision makers and valuable reference for international lake water researchers.     

Land-based sources of pollution along the Izmit Bay and their effect on the coastal waters

The degree and the contribution of each point source to the pollution were determined in the Izmit Bay during the period 1999–2000. During 8 campaigns, samples from 11 points in the channels and water samples from 5 points in the coastal sea were collected for chemical analysis. The important pollutant parameters taken into account are inflow of total organic carbon (TOC), total suspended solids (TSS), total phosphorus (TP), total nitrogen (TN), nitrate, ortho-phosphate, ammonia and total polycyclic aromatic hydrocarbons (t-PAHs) in the discharge channels, and TOC, TSS, nitrate, ortho-phosphate, chlorophyll-a, temperature, dissolved oxygen (DO), and salinity in the coastal stations of the Bay. It should be pointed out that the industrial wastewaters entering the bay are partially treated but domestic wastes are discharged directly into the surface waters without any treatment. Of the pollution parameters measured in the channels, the highest concentrations, except TP, were observed in the Dil River and in the Eastern Channel. Concentrations of TOC, TSS, TN, TP, ammonia, nitrate and o-phosphate were found at concentrations of 231, 290, 152, 3.8, 16, 79, and 3.07 mg/L, respectively. Annual inflows of TOC were 21,301, 580, and 775 t/year and for TSS were 26,742, 585, and 1505 t/year in the western, central and eastern parts, respectively. The results show that the water quality of the bay has been deteriorated and 80% of the pollution was caused by Dil River for all parameters measured.     

Changes in irrigation management and quantity and quality of drainage water in a traditional irrigated land

Irrigated agriculture allows for the increase of agrarian yields and stability in food supply and raw materials, being, at the same time, responsible for the reduction of water resources availability and for the pollution by salts and nitrate. This work aims to analyze the impact of changes in irrigation management (establishment of an on-demand flood irrigated system, assignment of irrigation allowances and water payment for surface and irrigation water consumption) in a traditional irrigated land on drainage flow, electrical conductivity and nitrate concentration in irrigation return flows between the year 2001 and the period 2005–2008. Changes in water management significantly modified quantity (lower drainage) and quality (electrical conductivity and nitrate) of irrigation return flows, keeping similar evolution paths during the year with water ameliorants in summer due to the use of good irrigation water quality. Salinity in irrigation return flows is not a current problem in the area as electrical conductivity values in water did not exceed the limit established for water used in irrigation or intended for human consumption. Despite the fact that changes in irrigation management and crop distribution have reduced nitrate concentrations in irrigation return flows by 43 %, the water still presents nitrate values exceeding the 50 mg NO₃ ^?/l. Thus, nitrate remains as the main agro-environmental problem in this irrigation area. However, the nitrate concentration trends detected in this work mark the possibility of reaching nitrate values below 50 mg NO₃ ^?/l in the case of maintenance of the conditions in this agricultural system.     

Visualizing the spatial water quality of Bentota,Sri Lanka in the presence of seawater intrusion

Seawater flows towards the inlands along with the rivers and canals, through the process of infiltration and leaks in the ground water characterized by high concentrations of soluble salts. High salinity concentrations can make groundwater unsuitable for public consumption and surface water unsuitable for irrigation and agricultural activities. This study envisages the fluctuations of ground and surface water quality of Bentota area in the presence of seawater intrusion. The temporal and spatial variations of eleven water parameters were monitored by collecting the water samples during one year period. Spatial distributions were assessed by applying the Inverse distance weighted (IDW) interpolation method in Arc GIS 10.5 software. Water quality is assessed on the integration of all parameters in terms of an index based on the World Health Organization (WHO) standards. The significant linear relationship between the considered parameters of surface water (SW) and groundwater (GW) were identified applying correlation analysis using SPSS software. All parameters of surface water were above the permissible limits of WHO standards. Surface water quality index values with respect to 60% of canals show very poor quality (>1 250) of surface water indicating their unsuitability for irrigation activities. Those surface water bodies indicated very highly saline conditions during dry months. The spatial distribution of ground water quality index with respect to the highest parameter values of each sampling location indicates that 52.2% of total land extent of Bentota Divisional Secretariat Division (DSD) has good quality of ground water which is suitable for drinking. Its 47.2% of total land extent has poor quality of ground water for drinking purpose and less than 0.5% of the area consists of excellent or very poor quality of ground water in each. This study helps to manage coastal aquifers by understanding the extreme water quality conditions and coastal salinity.     

Visualizing the spatial water quality of Bentota,Sri Lanka in the presence of seawater intrusion

Seawater flows towards the inlands along with the rivers and canals, through the process of infiltration and leaks in the ground water characterized by high concentrations of soluble salts. High salinity concentrations can make groundwater unsuitable for public consumption and surface water unsuitable for irrigation and agricultural activities. This study envisages the fluctuations of ground and surface water quality of Bentota area in the presence of seawater intrusion. The temporal and spatial variations of eleven water parameters were monitored by collecting the water samples during one year period. Spatial distributions were assessed by applying the Inverse distance weighted (IDW) interpolation method in Arc GIS 10.5 software. Water quality is assessed on the integration of all parameters in terms of an index based on the World Health Organization (WHO) standards. The significant linear relationship between the considered parameters of surface water (SW) and groundwater (GW) were identified applying correlation analysis using SPSS software. All parameters of surface water were above the permissible limits of WHO standards. Surface water quality index values with respect to 60% of canals show very poor quality (>1 250) of surface water indicating their unsuitability for irrigation activities. Those surface water bodies indicated very highly saline conditions during dry months. The spatial distribution of ground water quality index with respect to the highest parameter values of each sampling location indicates that 52.2% of total land extent of Bentota Divisional Secretariat Division (DSD) has good quality of ground water which is suitable for drinking. Its 47.2% of total land extent has poor quality of ground water for drinking purpose and less than 0.5% of the area consists of excellent or very poor quality of ground water in each. This study helps to manage coastal aquifers by understanding the extreme water quality conditions and coastal salinity.     

Hydrochemical assessment of a deep Jordanian aquifer

 This paper was mainly initiated to estimate some parameters of the quality and hydraulics of water in the vicinity of a proposed dam site in Jordan. The assessment of the chemical character was carried out to examine the suitability of the groundwater for domestic, municipal, industrial or irrigation use. Also, the anticipated problems associated with the quality of the reservoir water were delineated. Pumping tests were conducted at some wells that were drilled within the dam site zone and drawdown-time curves were constructed, by means of which the transmissivity and storage coefficients were assessed using two different methods. Total dissolved solids and electrical conductance were also measured and the relationship between them established. In addition, sodium ion concentrations at different piezometric tip elevations were measured in a number of wells that were previously drilled inside the dam site zone. This data indicates that the water quality as expressed in terms of total dissolved solids, electrical conductance, and sodium ion concentration limits do not comply with internationally recommended standards. The usage of this water for usual domestic purposes is therefore not viable, while the utilization of this water for irrigation purposes is very restricted. Received: 1 September 1995 · Accepted: 2 April 1995     

Quality of spring water used for irrigation in the Almora District of Uttarakhand, India

This paper aims to propose a quality profile of springs of the study area for irrigation. In the present study, fifty-four springs in Almora have been identified from rural as well as urban localities for calculation of irriga- tional water quality parameters during pre-monsoon, monsoon and post-monsoon, 2008. Spring water samples are collected and analyzed for pH, electrical conductivity (EC), total dissolved solids (TDS), Na+ , K+ , Ca2+ , Mg2+ , HCO3- , Cl- , and SO42- . Different irrigation quality parameters viz. salinity, sodium adsorption ratio (SAR), soluble sodium percentage (SSP), residual sodium carbonate (RSC), magnesium hazards (MH) and permeability index (PI) are calculated for the evaluation of spring water quality for irrigation purposes. All springs are found excellent to good based on irrigation quality parameters. Based on Wilcox diagram, about 98% of the water resources are grouped as C1S1 (low-low) and C2S1 (medium-low) classes, so springs are suitable for normal irrigation.     

Sediment characteristics and water physicochemical parameters of the Lysimachia Lake, Western Greece

In the present paper, we present the sedimentological characteristics and the water physicochemical parameters of Lysimachia Lake, which is one of the most important lakes of Western Greece, as it is protected by international conventions and is listed in the Natura 2000 European Network. Sedimentological analysis involved grain size analyses, moment measures, total organic carbon (TOC), total nitrogen (TN) and total phosphorus (TP) measurements, as well as determination of the clay minerals content. Water physicochemical parameters such as pH, temperature, conductivity and dissolved oxygen were measured in situ with portable equipment, while nutrients such as nitrates, nitrites, phosphates and ammonium ions, as well as TOC and TN were analyzed in a time period of 1 year seasonal monitoring. Geographical distribution of grain size and geochemical parameters indicated a clear partition in the northern and southern parts of the lake. This phenomenon can related to the discharging of a channel into the lake, the discharging of sewage effluents from Agrinio city during the last years as well as the type of clay minerals distribution. Clay minerals analyses indicated that smectite predominates in the northern part of the lake, whereas chlorite is more abundant in the southern parts. This explain the higher amounts of TOC and TN observed in the northern part of the lake and can be correlated with the higher external surface and adsorption capacity of minerals in the smectite-rich sediments. The four seasons monitoring of water physicochemical parameters indicates a relatively higher values of TOC and TN in the northern part of the lake, while nutrient concentrations indicate a uniform geographical distribution along the lake.     

Evaluation of groundwater quality in Madurai City,South India for drinking,irrigation and construction purposes

The present research is contributed on groundwater quality, its deterioration and evaluation based on drinking, irrigation, and construction standards. The study area chosen for investigation on water quality is the Tirunagar (TN) area, located in the south-west of Madurai City. The TN area was formerly an agricultural land but presently a residential area that is at a starvation of drinking water quality. A total of 49 bore well samples from TN and Amaithisolai (AS) were investigated for drinking, irrigation, and construction qualities based on various physicochemical parameters. The chemistry of groundwater samples was reflected from very hard and noncarbonate-dominating species. TN was recorded with higher inorganic species in groundwater sources than AS. The Water Quality Index values indicated that 75 % of the samples fall under excellent category and the positive Langelier Saturation Index values of the samples highlighted their tendency to deposit calcium carbonate. The Gibbs plot showed that AS samples were categorized under the domination of rock–water interaction whereas the TN samples under evaporation zone. The US Salinity Laboratory Staff plot depicted that all the groundwater sources at AS with C3S1 type whereas 88 % of the TN sources represented C4S1 type. The results from Wilcox diagram for irrigation inferred that the groundwater sources at AS were permissible, but 68 % of the samples at TN was registered under unfit type. The suitability of groundwater from the knowledge of residual sodium carbonate, sodium absorption ratio, and sodium percentage was also investigated. The perception based on standards recommended the groundwater sources for construction activities. The contribution of ionic species and inter-relationship among the ions were also interpreted from the knowledge of statistical studies.     

太湖流域营养盐产量演变和趋势的数值模拟研究

认识流域湖泊水体富营养化的演变和趋势是湖泊污染控制和治理中的重要研究课题。本文将在分析和论证太湖流域营养盐自然本底、人类活动作用急剧增加的近50年来太湖流域营养盐的变化情况、以及全球气候变化和流域经济发展未来30年太湖流域营养盐变化趋势等三方面的基础上,对太湖流域营养盐产量变化做出评估和预测。研究表明,在未来气候变化概率分析和区域经济发展规划基础上,太湖流域未来30年营养盐流域产量将比现代（2000s）增加25%～33%,这将增大太湖水体污染的压力。     

Impacts of climate change on stream flow and water quality in a drinking water source area,Northern China

Understanding the impacts of climate change on water quality and stream flow is important for management of water resources and environment. Miyun Reservoir is the only surface drinking water source in Beijing, which is currently experiencing a serious water shortage. Therefore, it is vital to identify the impacts of climate change on water quality and quantity of the Miyun Reservoir watershed. Based on long-time-series data of meteorological observation, future climate change scenarios for this study area were predicted using global climate models (GCMs), the statistical downscaling model (SDSM), and the National Climate Centre/Gothenburg University—Weather Generator (NWG). Future trends of nonpoint source pollution load were estimated and the response of nonpoint pollution to climate change was determined using the Soil and Water Assessment Tool (SWAT) model. Results showed that the simulation results of SWAT model were reasonable in this study area. The comparative analysis of precipitation and air temperature simulated using the SDSM and NWG separately showed that both tools have similar results, but the former had a larger variability of simulation results than the latter. With respect to simulation variance, the NWG has certain advantages in the numerical simulation of precipitation, but the SDSM is superior in simulating precipitation and air temperature changes. The changes in future precipitation and air temperature under different climate scenarios occur basically in the same way, that is, an overall increase is estimated. Particularly, future precipitation will increase significantly as predicted. Due to the influence of climate change, discharge, total nitrogen (TN) and total phosphorus (TP) loads from the study area will increase over the next 30 years by model evaluation. Compared to average value of 1961?~?1990, discharge will experience the highest increase (15%), whereas TN and TP loads will experience a smaller increase with a greater range of annual fluctuations of 2021 ~ 2050.     

洪湖流域自然农耕条件下营养盐沉积输移演化模拟研究

选择洪湖流域为研究区域,应用分布式流域模型SWAT,从长期演化的角度出发,对流域营养盐输移演化进行模拟。模拟的边界条件设置为自然农耕背景,探讨百年尺度洪湖流域营养盐输移演变规律。对TN、TP的模拟分汛期与非汛期两个时间段,分别进行200年的模拟运算。模拟结果显示模型可以很好的体现流域营养盐沉积输移演变的基本特征。TN、TP浓度变化有明显的季节特征,随时间变化特征与沉积记录相一致。模拟结果的时间序列分析,TN、TP显示出不同的变化趋势。流域模型为百年时间尺度上流域营养盐沉积输移演化的自然趋势研究,提供了很好评价依据。     

Environmental isotope investigation for the identification of source of springs observed in the hillock on the left flank of Gollaleru Earthen Dam,Andhra Pradesh,India

A hydrometric, hydrochemical and environmental isotopic study was conducted to identify the source and origin of observed springs on the foot of the hillock abutting the left flank of the Gollaleru earthen dam, Nandyal, Andhra Pradesh, India. Water samples (springs, reservoir water and groundwater) in and around the dam area were collected and analyzed for environmental isotopes (\(\updelta ^{18}\!\hbox {O}\), \(\updelta ^{2}\hbox {H}\) and \(^{3}\hbox {H}\)) and hydrochemistry. Reservoir level, spring discharges and physico-chemical parameters (temperature, electrical conductivity, pH, etc.) were monitored in-situ. Isotopic results indicated that the source of springs is from the Owk reservoir and groundwater contribution to the springs is insignificant. Based on hydrometric observations, it is inferred that the springs might be originated from the reservoir level of 209 m amsl. It is found that the lower spring discharges were derived from diffuse sources (seepage) which could be a mixture of reservoir water and the groundwater, while the relatively higher spring discharges were resulted from concentrated sources (leakage) from the reservoir. Thus, the study portraits the usefulness of isotope techniques in understanding the dam seepage/leakage related problems.     

渭河干流典型断面非点源污染监测与负荷估算

渭河水质在较大程度上受非点源污染的影响,因此,有必要对其负荷和比重进行研究。2009年至2010年,对渭河干流关中段咸阳和临潼断面进行了洪水期和非洪水期水质水量同步监测。根据监测结果及水文站实测流量资料,分别采用改进的水文分割法和平均浓度法对两断面的非点源污染负荷进行了计算,分析了非点源污染的特点。结果表明:渭河干流关中段主要污染物为COD、NH₃-N和TN,两断面洪水期间各指标的平均浓度基本都小于平时的平均浓度;各指标非洪水期浓度变化总体上小于洪水期浓度变化幅度,量级较大的洪水水质变化幅度相对较小;改进的水文分割法和已被检验并被广泛采用的平均浓度法计算结果符合良好。2009年(枯水年,P=68%)渭河咸阳和临潼站各指标非点源污染所占比例基本在20%～30%左右;2009年渭河干流咸阳-临潼河段污染以点源污染为主,构成比例在80%以上。对比2006年(枯水年,P=69%),2009年临潼站COD、NH₃-N和TN年点源负荷分别减少11937t、791t和29t,渭河点源治理取得一定成效;此外,临潼站这两年的污染构成比例基本相同。非点源污染在渭河水污染中占较大比重,其对渭河水质的影响不容忽视。