Optimization of a PRB structure with modified chitosan restoring Cr(VI)-contaminated groundwater

Hexavalent chromium is a soluble, mobile, and highly toxic metal ion in groundwater. Adsorption by permeable reactive barriers (PRBs) with special sorbent is a common method to remove hexavalent chromium. A series of experiments have been performed to remove hexavalent chromium in groundwater under PRB with modified chitosan. Therefore, in this paper, the authors first estimated adsorption characteristics of the modified chitosan in a column test, and then calibrated the PRB adsorption parameters in a sandbox test, and finally designed an optimal width, length, and depth of the PRB with the same reactive media in a three-dimensional aquifer. The results showed that the modified chitosan might be a potential adsorption medium. The design schemes can meet the water quality standard of 0.1 mg/L Cr(VI). Heterogeneity of dispersion is a crucial factor when designing the PRB. Therefore, the design of the PRB structures can be appropriate and serve as reference for groundwater remediation.     

Degradation of carbon tetrachloride in a reducing groundwater environment: implications for natural attenuation

Several laboratory experiments have demonstrated degradation of carbon tetrachloride (CT) in groundwater, but there appear to have been no corroborating long-term field studies. Investigations conducted in 1989 and 1999 at an industrial site constructed on an infilled estuarine environment in France provide data over a decade for which CT degradation could be evaluated. A Dense Non-Aqueous Phase Liquid (DNAPL) containing oil and >90% CT that was present in 1989 was absent in the extremely reducing site groundwater in both 1999 and 2000 (average Eh=−170 mV at pH 7, sulfide up to 21 mg l⁻¹, and Fe⁺² up to 3.2 mg l⁻¹). These conditions facilitated dechlorination of CT to chloroform (CF) present at up to 46 mg l⁻¹, and methylene chloride (up to 75 mg l⁻¹). Carbon disulfide (CS₂), a terminal degradation product in reducing environments in laboratory experiments, was present at a mass ratio averaging 2.4:1 CF:CS₂, indicative of abiotic degradation. The lack of detection of the separate phase CT, the ratio of CF:CS₂, the presence of low molecular weight organic acids (i.e., acetate ∼900 mg l⁻¹; citrate 360 mg l⁻¹; and propionate, up to 111 mg l⁻¹) and pyrite in conjunction with excess inorganic Cl in groundwater are all indicators of ongoing degradation of the chlorinated compounds. However, while natural attenuation of chloromethanes may be a viable adjunct to strategies designed to remediate CT in reducing groundwater, its efficacy is hard to quantify in complex field environments where upgradient sources are still present.     

某化工场地土壤与地下水中多环芳烃的分布特征及迁移规律

选取某化工场地作为研究对象,采集不同深度的原状土壤样品和原状地下水样品,对土壤样品和地下水样品的16种优控多环芳烃进行定量分析,研究不同种类的多环芳烃在包气带和饱和带中的分布特征和迁移规律.研究表明,在平面上,多环芳烃在土壤和地下水中的污染高值区与生产车间分布基本一致;在垂向上,土壤中的16种多环芳烃集中分布在杂填土层...     

Assessing the effectiveness of nanoscale zero-valent iron particles produced by green tea for Cr(VI)-contaminated groundwater remediation

Nanoscale zero-valent iron particles(NZVI) produced by using green tea(GT) extract as a reductant can remove Cr(Ⅵ) from water effectively,which can be utilized in groundwater remediation.In order to define the reaction mechanism and removal effect in the aquifer,in this study,GT-NZVI particles were prepared and measured by some characterization methods to define their surface performance,and then batch and one-dimensional experiments were carried out to reveal the reaction properties of GT-NZVI ...     

Assessing the role of alkaline soils on the carbon cycle at a playa site

Alkaline soils occupy approximately 5 % of the Earth’s land surface (7 million km), and this may increase due to the global trend towards increasing desertification, yet the extent to which these soils modulate carbon dynamics on regional and global scales is inadequately studied and poorly understood. Railroad Valley (RRV) playa (Nevada, USA) is a semi-arid playa with highly alkaline soils (pH > 10) and no vegetation. The extreme, alkaline environment and absence of vascular vegetation make RRV an ideal site to investigate the role of physiochemical processes of soil-atmosphere CO₂ exchange. Both field and laboratory investigations were conducted. This work shows how the atmospheric CO₂ mixing ratio decreases at nighttime at RRV playa to a value well below the average global background CO₂ concentration. Laboratory investigations using soil samples collected at RRV playa confirmed that CO₂ uptake by RRV playa soils occurs when temperatures are decreased. Both field and laboratory studies suggest that the alkaline RRV soil acts as a CO₂ reservoir during colder periods, such as at nighttime. These results highlight the importance of investigating carbon dynamics in previously understudied environments. Given how little information is available on the CO₂ flux in desert and semi-arid alkaline ecosystems lacking vegetation, our findings draw attention to these environments as becoming increasingly important for carbon fluxes on regional and global scales.     

Containment of groundwater pollution (methyl tertiary butyl ether and benzene) to protect a drinking-water production site in Belgium

The subsurface migration of methyl tertiary butyl ether (MTBE) and benzene towards a drinking-water production site in Belgium was monitored for 9 years. A large gasoline spill at a nearby fuel station had caused a 500-m long and 50-m-wide pollution plume of MTBE (10?30 mg/L) and benzene (2?10 mg/L). In order to prevent any intrusion of pollutants into the drinking-water supply, a conceptual model was used to design a pump-and-treat system that intercepted the gasoline-contaminated groundwater emanating from the spill. The contaminated soil in the spill zone was excavated. A numerical mass transport model was developed to evaluate the ongoing plume containment. The model describes the subsurface MTBE migration and was regularly updated, based on groundwater monitoring data and the measured mass of MTBE extracted with the pump-and-treat system. With continued interception pumping, the MTBE plume can be remediated in 14 years. Without it, MTBE and benzene concentrations up to 600 μg/L could have reached the drinking-water production site and the plume would persist for 9 years longer. Source zone treatment combined with plume interception pumping is a suitable risk-based remediation strategy for the containment of MTBE and benzene groundwater pollution.     

Characterization of groundwater flow in the Bailin hazardous waste-disposal site (Huesca, Spain)

 A serious problem in Spain is presented, where the water and soil were contaminated by lindane produced by the chemical industry, at a time when environmental legislation was limited, and the hydrogeological characterization of the low permeability materials was insufficient. The waste-disposal sites where the lindane accumulated lacked suitable sealing and also had notable filtration. The non-existence of a safe waste-disposal site, and the economic and social problems of transporting lindane residues forced the alternative proposal of confining these residues in situ (Government of Aragón, 1995, 1996). Once the surface sealing was carried out, the problem centred on the site's underground confinement. The purpose of this publication is to present the particular hydrogeological behaviour of materials, which were initially considered impermeable because of the presence of very consolidated sandstone beddings and the vertical disposition of the strata, and so allowed the lindane to escape through the groundwater. In addition, this publication describes the procedures carried out in order to achieve effective underground confinement at the waste-disposal site. Received: 12 October 1999 · Accepted: 31 January 2000     

Fluorescence spectroscopy of U(VI)-silicates and U(VI)-contaminated Hanford sediment

Time-resolved U(VI) laser fluorescence spectra (TRLFS) were recorded for a series of natural uranium-silicate minerals including boltwoodite, uranophane, soddyite, kasolite, sklodowskite, cuprosklodowskite, haiweeite, and weeksite, a synthetic boltwoodite, and four U(VI)-contaminated Hanford vadose zone sediments. Lowering the sample temperature from RT to ∼ 5.5 K significantly enhanced the fluorescence intensity and spectral resolution of both the minerals and sediments, offering improved possibilities for identifying uranyl species in environmental samples. At 5.5 K, all of the uranyl silicates showed unique, well-resolved fluorescence spectra. The symmetric O = U = O stretching frequency, as determined from the peak spacing of the vibronic bands in the emission spectra, were between 705 to 823 cm⁻¹ for the uranyl silicates. These were lower than those reported for uranyl phosphate, carbonate, or oxy-hydroxides. The fluorescence emission spectra of all four sediment samples were similar to each other. Their spectra shifted minimally at different time delays or upon contact with basic Na/Ca-carbonate electrolyte solutions that dissolved up to 60% of the precipitated U(VI) pool. The well-resolved vibronic peaks in the fluorescence spectra of the sediments indicated that the major fluorescence species was a crystalline uranyl mineral phase, while the peak spacing of the vibronic bands pointed to the likely presence of uranyl silicate. Although an exact match was not found between the U(VI) fluorescence spectra of the sediments with that of any individual uranyl silicates, the major spectral characteristics indicated that the sediment U(VI) was a uranophane-type solid (uranophane, boltwoodite) or soddyite, as was concluded from microprobe, EXAFS, and solubility analyses.     

Monitoring groundwater flow and chemical and isotopic composition at a demonstration site for carbon dioxide storage in a depleted natural gas reservoir

Between March 2008 and August 2009, 65,445 tonnes of ∼75 mol% CO₂ gas were injected in a depleted natural gas reservoir approximately 2000 m below surface at the Otway project site in Victoria, Australia. Groundwater flow and composition were monitored biannually in two overlying aquifers between June 2006 and March 2011, spanning the pre-, syn- and post-injection periods. The shallower (∼0–100 m), unconfined, porous and karstic aquifer of the Port Campbell Limestone and the deeper (∼600–900 m), confined and porous aquifer of the Dilwyn Formation contain valuable fresh to brackish water resources. Groundwater levels in either aquifer have not been affected by the drilling, pumping and injection activities that were taking place, or by the rainfall increase during the project. In terms of groundwater composition, the Port Campbell Limestone groundwater is brackish (electrical conductivity = 801–3900 μS cm⁻¹), cool (temperature = 12.9–22.5 °C), and near-neutral (pH = 6.62–7.45), whilst the Dilwyn Aquifer groundwater is fresher (electrical conductivity = 505–1473 μS cm⁻¹), warmer (temperature = 42.5–48.5 °C), and more alkaline (pH = 7.43–9.35). Carbonate dissolution, evapotranspiration and cation exchange control the composition of the groundwaters. Comparing the chemical and isotopic composition of the groundwaters collected before, during and after injection shows no statistically significant changes; even if they were statistically significant, they are mostly not consistent with those expected if CO₂ addition had taken place. The monitoring program reveals no impact on the groundwater resources attributable to the C storage demonstration project.     

Behaviour of metals and nutrients in soils and groundwater of a karst polje

The Croatian south part of the country is mainly composed of strongly krastified carbonate rocks. Also in this south part of Croatia is lacking of large depressions and poljes with thick covers. Some karst poljes and depressions may have thick covers, like for example the Vransko polje. The Vransko polje is characterised by an intensive agricultural activity. At the centre of the polje is located a karst spring (Turanjsko jezero), which is used for the water supply of the town Biograd and its surroundings. Total metals, nutrients (nitrate, ammonia, phosphate), organic matter content and cation exchange capacity (CEC) were measured in soil samples collected from the polje. Metals and nutrients were also measured in the water samples of channel Kotarka (which is passing through the area) and three springs (Turanjsko jezero, Kakma and Tinj). Measured total concentrations of metals of soil samples were treated by R-cluster multivariate statistical analysis. The result of statistical analysis showed grouping of metals with similar behaviour. Content of metals and nutrients were low in the spring samples but high in the water sample of the channel Kotarka, because the channel drains the water from the surroundings. Although agricultural activity in the Vransko polje is high, there is no high anthropogenic influence on groundwater and soil. They are both of good quality.     

Hydrogeological investigation of a groundwater contamination site in southern Taiwan

 Groundwater samples taken from wells adjacent to a food machinery manufacturing plant in southern Taiwan indicate that there is a serious phenolic contamination. To understand the hydrogeological properties, and to prepare for remedial action, a series of hydrogeological investigations were conducted. Investigative work included collecting background information, analyzing existing data, measuring the groundwater, and conducting a slug test, pumping and recovery test, aerial photography analysis and electrical resistivity survey. Results from these investigations show that the local groundwater aquifer may be classified as an unconfined or confined formation, depending on the thickness of the interbedded clay layer. The direction of local groundwater flow is from southwest to northeast, with high transmissivity. The contaminant moves much more slowly than the average groundwater velocity, and it is limited to an area centered around the plant. The local geology of the contaminated area exhibits significant heterogeneity; it is not likely to have been formed by natural sedimentation. Data from the field aerial photography analysis and electrical resistivity survey also suggest that this shallow formation may result from artificial back-filling. Received: 1 September 1994 · Accepted: 28 December 1995     

Accuracy of CFC groundwater dating in a crystalline bedrock aquifer: Data from a site in southern Sweden

The concentrations of chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) and tritium were determined in groundwater in fractured crystalline bedrock at Finnsjön, Sweden. The specific goal was to investigate the accuracy of CFC dating in such an environment, taking potential degradation and mixing of water into consideration. The water was sampled to a depth of 42 m in three boreholes along an 800-m transect, from a recharge area to a local discharge area. The CFC-113 concentration was at the detection limit in most samples. The apparent recharge date obtained from CFC-11 was earlier than from CFC-12 for all samples, with a difference of over 20 years for some samples. The difference was probably caused by degradation of CFC-11. The CFC-12 dating of the samples ranged from before 1945 to 1975, with the exception of a sample from the water table, which had a present-day concentration. Conclusions about flow paths or groundwater velocity could not be drawn from the CFCs. The comparison between CFC-12 and tritium concentrations showed that most samples could be unmixed or mixtures of waters with different ages, and the binary mixtures that matched the measured concentrations were determined. The mixing model approach can be extended with additional tracers.

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Resumen Precisión en la datación de aguas subterráneas utilizando CFC en un acuífero de rocas cristalinas: datos provenientes de un sitio al sur de Suecia.Se determinaron las concentraciones de clorofluorucarbonos (CFC-11, CFC-12, y CFC-113) y de tritio en aguas subterráneas alojadas en rocas cristalinas fracturadas de Finnsjön, Suecia. El objetivo específico consistió en investigar la precisión de la datación de aguas subterráneas con CFC en este tipo de ambiente, tomando en consideración la degradación potencial y la mezcla de agua. Las muestras de agua se tomaron a una profundidad de 42 m en tres pozos ubicados a lo largo de una línea de 800 m transversal a una zona de recarga y de zona de descarga local. En la mayoría de las muestras se encontró que la concentración de CFC-113 estuvo en el límite de detección. La edad que se estimó en todas las muestras para la recarga aparente en base a CFC-11 fue más joven que la edad proveniente de CFC-12, con una diferencia de más de 20 años para algunas muestras. Esta diferencia fue causada probablemente por la degradación del CFC-11. La datación CFC-12 de las muestras varió de antes de 1945 a 1975, con la excepción de una muestra tomada en el nivel freático, la cual presentó concentración actual. No fue posible obtener conclusiones acerca de las trayectorias de flujo o la velocidad de agua subterránea a partir de los CFCs. La comparación entre las concentraciones de CFC-12 y tritio mostró que la mayoría de las muestras pueden tener composición sencilla o bien consistir de mezclas de aguas de diferentes edades. Esta comparación también permitió determinar las mezclas binarias que corresponden a las concentraciones medidas. Pueden utilizarse trazadores adicionales para ampliar el modelo de mezclas propuesto.

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Résumé Précision de la datation au CFC dans un aquifère rocheux-fracturé: données dun site du sud de la Suède.Les concentrations en chlorofluorocarbones (CFC-11, CFC-12, CFC-113) et entritium ont été déterminées dans leau souterraine dun massif fracturé à Finnsjön en Suède. Le but de cette étude est de mieux cerner la précision de la méthode de datation au CFC dans ce type denvironnement hydrogéologique, tout en considérant déventuels phénomènes de dégradation et de mélange deaux. Leau a été échantillonnée à une profondeur de 42 mètres dans trois forages alignés sur 800 mètres entre une zone de recharge et une zone de déversement. Les concentrations en CFC-113 sont dans la plupart des échantillons à la limite de détection. Pour tous les échantillons, la date de la recharge établie avec le CFC-11 est antérieure à la date établie avec le CFC-12. La différence entre les deux dates peut dépasser 20 ans et sexplique—probablement—par la dégradation du CFC-11. Les dates de recharge de la nappe mesurées au CFC-12 sont comprises entre 1945 et 1975, excepté pour un échantillon qui possède une concentration actuelle. Il nest pas possible de tirer des conclusions concernant la direction des écoulements et la vitesse de leau souterraine. La comparaison entre CFC-12 et tritium montre que des échantillons pourraient être soit le résultat du mélange deaux dâges différents, soit des échantillons non-mélangés. Dans le cas dun mélange binaire, les rapports du mélange composant la concentration mesurée sont déterminés. Lapproche par modèle de mélange peut être étendue à des traceurs additionnels.

     

Migration of transuranic elements in groundwater from the near-surface radioactive waste site

Field experiments and laboratory studies were performed to investigate migration processes of plutonium isotopes from a near-surface radioactive waste trench to the underlying sandy aquifer at the Red Forest waste dump in the Chernobyl zone. The objectives of these experiments were to characterize the spatial distribution and possible migration mechanisms of plutonium in the aquifer. During 2002–2007 experimental investigations were carried out and spatial distributions of plutonium isotopes (^239,240Pu, ²³⁸Pu), ⁹⁰Sr and major ions in the aquifer in the direction of the groundwater flow were obtained. Specific activities of radionuclides in groundwater depended on the location of the piezometer and varied in the range of 1–360 mBq kg⁻¹ for ^239,240Pu, 0.5–180 mBq kg⁻¹ for ²³⁸Pu and n–n·10⁴ Bq kg⁻¹ for ⁹⁰Sr. It was found that the spatial features of the distributions of plutonium and strontium specific activities in the upper eolian aquifer were similar, i.e. there was a correlation between the positions of the activity maxima of the radionuclides. The Pu isotopes plume in the aquifer spreads about 15 m downstream of the radionuclides source. Characterization of the initial radionuclide composition of the waste showed that all plutonium in the aquifer originated from the trench. The ratio of plutonium isotopes (^239,240Pu/²³⁸Pu) at the sampling time was the same in waste material and in groundwater samples. In situ ultrafiltration of several groundwater samples was carried out. The size fractionation data obtained suggest that a significant part of plutonium (50–98%) in the groundwater sampled close to the source from the upper part of the aquifer is associated with a very low molecular weight fraction (<1 kDa).     

Assessment of groundwater contamination from a hazardous dump site in Ranipet, Tamil Nadu, India

Tanneries located in an industrial development area of Ranipet (India) manufactured chromate chemicals during 1976?C1996. A large quantity of associated hazardous solid wastes has been stacked about 5-m high above ground level, spread over 3.5?ha inside one of the factory premises. The study area receives an average annual rainfall of 1,100?mm. The granitic formation in the northern part of Palar River catchment has high infiltration rates and has resulted in fast migration of the contamination to the water table. Chromium levels in the groundwater were found up to 275?mg/l. The available hydrogeological, geophysical and groundwater quality data bases have been used to construct a groundwater flow and mass transport model for assessing the groundwater contamination and it has been calibrated for the next 30?years. The migration has been found to be very slow, with a groundwater velocity of 10?m/year. This is the first field-scale study of its kind in this industrial area. The findings are of relevance to addressing the groundwater pollution due to indiscriminate disposal practices of hazardous waste in areas located on the phreatic aquifer. Further, it has been reported that the untreated effluent discharge adjacent to the chromium dump site is most influential in the migration of contaminants.     

Mapping of bipolar outflows and methanol masers in the CS(2-1)line

Eighteen regions (bipolar outflows and methanol masers) are mapped in the CS(2-1) line using the 20-m Onsala radio telescope. The coordinates of the CS emission peaks are refined. The sizes and masses of dense regions are estimated for 13 maps. Measurement of the angular sizes of regions of emission indicates that all the sources were resolved by the Onsala radio telescope. The lower limit for the linear dimensions of the CS condensations studied is 0.2–2.1 pc. The hydrogen densities and masses of the CS condensations are estimated to be n(H₂)=(0.3–13.1)×10⁴ cm^?3 and (M ≈ 7–2800M _⊙). Methanol masers are associated with denser and more massive regions, whether or not the maser condensation is connected with a bipolar outflow.     

Intrinsic bioremediation of MTBE-contaminated groundwater at a petroleum-hydrocarbon spill site

An oil-refining plant site located in southern Taiwan has been identified as a petroleum-hydrocarbon [mainly methyl tert-butyl ether (MTBE) and benzene, toluene, ethylbenzene, and xylenes (BTEX)] spill site. In this study, groundwater samples collected from the site were analyzed to assess the occurrence of intrinsic MTBE biodegradation. Microcosm experiments were conducted to evaluate the feasibility of biodegrading MTBE by indigenous microorganisms under aerobic, cometabolic, iron reducing, and methanogenic conditions. Results from the field investigation and microbial enumeration indicate that the intrinsic biodegradation of MTBE and BTEX is occurring and causing the decrease in MTBE and BTEX concentrations. Microcosm results show that the indigenous microorganisms were able to biodegrade MTBE under aerobic conditions using MTBE as the sole primary substrate. The detected biodegradation byproduct, tri-butyl alcohol (TBA), can also be biodegraded by the indigenous microorganisms. In addition, microcosms with site groundwater as the medium solution show higher MTBE biodegradation rate. This indicates that the site groundwater might contain some trace minerals or organics, which could enhance the MTBE biodegradation. Results show that the addition of BTEX at low levels could also enhance the MTBE removal. No MTBE removal was detected in iron reducing and methanogenic microcosms. This might be due to the effects of low dissolved oxygen (approximately 0.3 mg/L) within the plume. The low iron reducers and methanogens (<1.8×10³ cell/g of soil) observed in the aquifer also indicate that the iron reduction and methanogenesis are not the dominant biodegradation patterns in the contaminant plume. Results from the microcosm study reveal that preliminary laboratory study is required to determine the appropriate substrates and oxidation-reduction conditions to enhance the biodegradation of MTBE. Results suggest that in situ or on-site aerobic bioremediation using indigenous microorganisms would be a feasible technology to clean up this MTBE-contaminated site.     

Simulation of groundwater mounding at a West Australian mine site

Few studies exist that investigate the potential impact of groundwater mounding due to mining near an environmentally sensitive area in a real world scenario. This paper presents a case study in which the development and extent of groundwater mounding due to mining near the Shark Bay World Heritage Property (SBWHP) in Western Australia (WA) has been simulated. A numerical model was developed that enabled a detailed simulation of groundwater level response to the discharge of a water saturated sand slurry during mining at the project site near Coburn in WA. The simulations showed that after a mining period of around two and a half years, a groundwater mound of around 2.5 m would develop along the margins of the open pit at the SBWHP boundary. 500 m further into the SBWHP, the groundwater mound is predicted to be around 1 m high. A depth to water analysis showed that the groundwater may come within 4 m of the surface in the area of a sand dune swale that traverses from SW to NE near the SBWHP boundary. The results of these analyses provide a perspective of mine-related impacts in a unique environment. The results have been included in an environmental impact assessment (EIA) and used for mine water balance predictions.     

含饱和土的层状场地的动力响应

利用精确的土层和半空间动力刚度矩阵求解了含饱和土的层状场地的动力响应,给出了含饱和土层状场地的自由场（入射P波、SV波）、动力Green函数及刚性条形基础动力刚度的计算方法,由此建立的场地模型更接近实际情况。建议方法的退化结果与单相场地结果一致。研究了界面不同透水条件对基础动力刚度的影响,并与相应单相场地结果进行了对比。研究表明：界面透水条件对竖向弹簧系数影响最大,饱和土体中孔隙水对场地动力响应具有不可忽视的影响。     

Enabling global exchange of groundwater data: GroundWaterML2 (GWML2)

GWML2 is an international standard for the online exchange of groundwater data that addresses the problem of data heterogeneity. This problem makes groundwater data hard to find and use because the data are diversely structured and fragmented into numerous data silos. Overcoming data heterogeneity requires a common data format; however, until the development of GWML2, an appropriate international standard has been lacking. GWML2 represents key hydrogeological entities such as aquifers and water wells, as well as related measurements and groundwater flows. It is developed and tested by an international consortium of groundwater data providers from North America, Europe, and Australasia, and facilitates many forms of data exchange, information representation, and the development of online web portals and tools.     

不同基质共代谢降解地下水中四氯乙烯的研究

文中以甲醇、乙醇、甲酸盐、乙酸盐、乳酸盐和葡萄糖作为共代谢基质,利用某污水处理厂厌氧池中的污水(泥)作为接种物,对厌氧微生物进行培养和驯化,降解四氯乙烯(PCE)。实验结果表明,在厌氧污水(泥)和土壤混合环境下培养的微生物,以COD为培养指标,11d可培养成熟。6种基质均能使PCE还原脱氯降解成三氯乙烯(TCE)和1,1-二氯乙烯(1,1-DCE),PCE的降解均符合一级反应动力学方程,反应速率常数大小依次为K乙酸盐>K葡萄糖>K乳酸盐>K乙醇>K甲酸盐>K甲醇,其中乙酸盐是最有效的共代谢基质,其反应速率常数为0·6632d-1。