Aluminum in the East China Sea and Okinawa Trough, marginal sea areas of the Western North Pacific

The distribution of aluminum (Al) in seawater has been investigated in the continental slope and the Okinawa Trough areas of the East China Sea, which is one of the marginal seas in the western North Pacific Ocean. Aluminum concentration in waters over the slope and the Trough ranged from 5.6 to 25 nmol/kg in the surface layer (0–100 m), and had a minima of 1.1 nmol/kg between 400 and 500 m depth and ranged from 1.3 to 9.7 nmol/kg in the deep or bottom waters. Aluminum values were higher than in the surface waters of the central North Pacific, while minimum values were similar to levels in the intermediate or deep waters of the central North Pacific, except for the bottom water over the slope. This suggests that the high Al concentration in the surface reflects the large atmospheric input of Asian dust around the western side of the North Pacific region. On the continental slope, Al concentrations in the upper 500 m depth decreased slopeward. This horizontal gradient of Al can be explained from the combination of dilution by upwelling of Al-poor water originated from the North Pacific Intermediate Water (NPIW) which intrudes into the mid-depth of the Okinawa Trough and the scavenging of Al by biogenic particles in the continental slope zone.     

北太平洋西部和印度洋东部及其邻近海域表层水体中137Cs的分布

对北太平洋西部海域、苏禄海及印尼海、中国南海、印度洋东部海域、孟加拉湾及安达曼海等表层水体中放射性核素137Cs的活度进行了测定。结果表明,上述海域表层水体中137Cs活度显示了较大的变化范围,最低值出现在南极附近的南大洋(1.1Bqm-3),较高的活度值则出现在北太平洋西部海域及中国南海(3Bqm-3)。在所研究水域范围内,137Cs活度的纬度分布特征并没有完全有效地反映出137Cs的全球理论大气沉降趋势及其纬度效应。综合本研究及Miyake等人(1988)的测定结果,我们计算出137Cs自表层海水中的析出速率在苏禄海及印尼海约为0.016/a,在孟加拉湾及安达曼海约为0.033/a,在中国南海约为0.029/a,这一结果明显低于西北太平洋日本沿海表层水体中137Cs的析出速率。这可能是因为在这些海域,横向及纵向的水体混合过程相对都较慢,而且颗粒物对137Cs的吸附析出过程也比较弱所致。     

印尼贯穿流源区马鲁古海和哈马黑拉海水团来源的气候态分析

本文利用World Ocean Atlas 2013（WOA2013）气候态的温盐资料和the Simple Ocean Data Assimilation （SODA v3.3.1）流场数据,分析印尼贯穿流东部源区马鲁古海和哈马黑拉海的水团垂向分布特征及其来源,特别是次表层、中层及深层水的来源和路径。结果表明,气候态下,马鲁古海次表层的高温高盐水来自于北太平洋,与北太平洋热带水性质接近,哈马黑拉海次表层主要是来自南太平洋热带水;中层水以低温低盐为特征,马鲁古海的中层水来自南太平洋,受南极中层水控制,哈马黑拉海的中层水可能是从马鲁古海而来的南太平洋水;对于次表层和中层之间的过渡层,马鲁古海与哈马黑拉海的水源为南、北太平洋的混合水,且两个海域之间也存在着水团交换;在深层,马鲁古海的水源更倾向于班达海北部及塞兰海,而与太平洋水无关,哈马黑拉海由于地形阻挡也难以与太平洋直接发生水团交换。     

西太平洋暖池热含量与南海夏季风强度的关系

为了进一步明确西太平洋暖池热含量对南海夏季风强度的影响,利用1948~2012年日本气象厅(japan meteorological agency,JMA)逐月的海温资料、Hadley中心的海表面温度(Sea Surface Temperature,SST)资料以及NCEP/NCAR再分析资料,分析比较了南海夏季风强度与热带太平洋上层海洋热含量和SST的关系;探讨了海洋热含量影响南海夏季风强度的机制。结果表明:(1)相比于西太暖池SST,西太暖池上层海洋热含量是南海夏季风强度更好的预测因子;(2)前期冬春季的西太平洋暖池热含量与南海夏季风强度呈现显著的正相关,尤其在3月,二者相关系数最大;当暖池热含量偏高(低)时,西太平洋副热带高压偏弱(强),赤道印度洋出现异常反气旋(气旋),印度洋上空的Walker环流分支偏强(弱),南海越赤道气流增强(减弱),最终使得南海夏季风强度偏强(弱)。     

Seasonal and areal variation of continental aerosol in the surface air over the western North Pacific region

Weekly aerosol samples were collected for two years from 1981 at six stations in the western North Pacific region. The samples were analyzed for aluminum to determine the mineral dust concentration in the air. By combining our data with observations in the central and eastern North Pacific by a US research group, the following results and conclusions have been obtained. Spring peaks in atmospheric mineral dust were observed at all the stations accompanied byKosa episodes (hazes due to mineral dust of Chinese origin). The spring peaks, however, varied from year to year. The mean concentration of mineral dust depends not only on the distance from the Asian coast but also on the latitude of the sampling station. The half-decrease distance of the atmospheric mineral dust turned out to be 500–600 km for all latitudes in the western North Pacific. This indicates that the rate of deposition of mineral dust in the western North Pacific is much larger than that in the central and eastern North Pacific.     

Lead in the southern East China Sea

At present, in most oceans the lead (Pb) biogeochemical cycling has been disturbed by anthropogenic Pb through atmospheric input. The Pb concentrations in the upper water positively correlate with atmospheric input fluxes of Pb. The North Pacific is affected greatly by atmospheric substances via long-range transport from eastern Asia, especially from Mainland China. Mainland China may export considerable amounts of pollutants into the seas via rivers and the atmosphere owing to its recent fast growth in industry and economy. The East China Sea lies in an important geographical position--a transit between Mainland China and the western North Pacific. However, no data are available for seawater concentrations of Pb, a representative element with anthropogenic origin. In this work seawater samples from both 5 and 30-50 m water layers of 15 stations occupied over a cyclonic eddy in the southern East China Sea were analyzed for particulate Pb (PPb) and dissolved Pb (DPb). The Mean concentration of DPb (approximately 128 ng/l) in the southern East China Sea upper waters (< or = 50 m) is approximately several times higher than those in the Pacific; the high DPb concentrations in the southern East China Sea waters correspond to much higher atmospheric supplies of Pb to the East China Sea. Thus, this study partly fills the 'data gap' of the marginal seas. Also, it indicates that the East China Sea may be considerably contaminated by deposited polluted aerosols. Spatial distributions of DPb in the surface water show a tendency of increasing concentrations with distance offshore, that depends on the magnitudes of atmospheric Pb inputs and on particle scavenging processes. In contrast to DPb, spatial distributions of PPb basically display an 'omega'-like picture and a tendency of decreasing concentrations with distance offshore. These are related to riverine and scavenging sources and to the drive by the eddy. Additionally, the residence times of DPb in the surface water were estimated to be about 2 years, agreeing well with the reported data.     

北太平洋大气沉降的时空特征及其对副极区海洋生态系统的影响

北太平洋副极地海区作为全球海洋三个高营养盐低叶绿素(high nutrient and low chlorophyll, HNLC)海区之一, 其浮游植物生长受到微量元素铁的限制。对于开阔大洋, 大气沉降是海洋表层铁的一个重要来源, 铁元素沉降进入海洋后能够促进浮游植物生长, 进而引起海洋初级生产力和生物泵的响应。本文利用SPRINTARS(Spectral Radiation-Transport Model for Aerosol Species)模式的时长为20a的日均大气沉降数据, 对北太平洋海区大气沉降的时空特征进行了分析。结果表明, 进入北太平洋海区的大气沉降量为26.81Tg·a^-1, 并且存在显著的季节变化: 春季最高, 冬季最低, 5月份进入海洋的沉降量达到峰值。大气沉降主要来源于陆地区域, 在风场的驱动下向海洋传输, 因此大气沉降量的空间分布呈现出西高东低的特征。本文以2010年8月中旬卫星观测到的一次强沙尘(即高大气沉降量)事件为例, 研究了大气沙尘的传播路径。进一步结合2001年4月9—12日及2008年4月20—22日的沙尘事件, 分析了西北太平洋K2站位(47°N, 160°E)附近海域海洋初级生产力对大气沉降——沙尘事件的响应。结果表明, 三次沙尘事件后, K2站位的颗粒有机碳通量、叶绿素浓度均有明显增加, 即沙尘事件对北太平洋副极区海洋初级生产力存在促进作用。     

基于历史资料和Argo资料的印尼贯通流次表层和中层水起源与路径探讨

利用Argo资料和《世界海洋数据集2001版》(WOD01)温盐历史资料,通过对代表性等位势面上盐度分布的分析,探讨了次表层和中层等不同层次上印尼贯通流(ITF)的起源与路径问题.分析结果表明,ITF的次表层水源主要来自北太平洋,中层水源地既包括北太平洋、南太平洋,同时也不能排除有印度洋的可能性.在印度尼西亚海域西部,ITF的次表层和中层水源分别为北太平洋热带水(NPTW)和中层水(NPIW),经苏拉威西海、望加锡海峡到达弗洛勒斯海,层次越深特征越明显.在印度尼西亚海域东部,发现哈马黑拉-新几内亚水道附近存在次表层强盐度锋面,阻隔了南太平洋热带水(SPTW)由此进入ITF海域;中层水具有高于NPIW和来自南太平洋的南极中层水(AAIW)的盐度值,既可能是AAIW和SPTW在当地发生剧烈垂直混合而形成,也可能是来自印度洋的AAIW向北延伸进入ITF的结果.     

Trace metals (Co,Ni, Cu,Cd, and Pb) in the southern East/Japan Sea

Total dissolvable metals (Co, Ni, Cu, Cd, and Pb) in both surface waters and the water columns were acquired in the southern East/Japan Sea during a cruise around the Ulleung Basin in June 2001 to understand the spatial distributions of the metals. Concentrations in offshore surface waters were found to be Co 60 ± 12 pM, Ni 2.16 ± 0.25 nM, Cu 1.85 ± 0.55 nM, Cd 0.134 ± 0.018 nM, and Pb 155 ± 40 pM. Spatial distributions in surface waters showed that metal levels were generally enhanced at coastal sites in both Korea and Japan, where the metal distributions indicated complex patterns due to inputs, biogeochemical processes, and physical factors including upwelling. The Co distributions in the water columns seemed to be influenced predominantly by surface and bottom inputs, scavenged rather than regenerated at depth. For Cd, there was generally good agreement between the Cd and PO₄ depth distributions, in agreement with the literature. The Cd/PO₄ ratio from the water columns was found to be 0.133–0.203, lower than that in other marginal seas (e.g. the East/South China Seas and the Philippine Sea) of the western Pacific Ocean; this might be a result of the fast ventilation rate in this sea. The vertical Pb profile showed typical scavenged-type behavior with a surface maximum and deep minimum. From a comparison of inputs from the atmosphere and the Tsushima Warm Current, atmospheric deposition is substantial enough that it cannot be ignored, and its role in metal cycling is more significant in the offshore zone.     

南海夏季风异常及其对南海与周边地区的大气和海洋要素的影响

通过对南海夏季风异常年夏季南海及周边地区主要海-气要素场的对比分析,得到以下主要结论:强、弱季风年夏季南海及周边地区的主要海-气要素都表现出明显的差异。强季风年夏季南海中南部地区低层西风加强、高层东风加强,以南海北部为中心存在气旋性距平环流,上升运动增强。相应地,南海及我国东南沿海地区对流和降水增强,而长江中下游地区降水偏少。弱季风年则表现出与强季风年几近相反的分布特征。此外,强季风年西太平洋副热带高压较弱季风年位置明显偏东、强度明显偏弱。与对流和降水的分布相对应,强、弱季风年夏季南海及周边地区大气热源状态的分布也表现出明显的差异,差别最显著的区域正是在南海及周边地区。在强季风年,西起孟加拉湾东至菲律宾以东的洋面上为较明显的热源增强区,而弱季风年则为明显的热源减弱区。此外,强、弱季风年,南海海域的海面高度、海洋环流、海表温度等表征海洋状况的要素分布也明显不同,分布形势几近相反。海温作为重要的外源强迫,不仅对季风环流的形成有重要作用,而且明显受到季风异常的影响,进而对局地的天气气候产生重要的滞后影响。     

南沙群岛海域表层沉积物中有机物、铁和锰的分布特征

通过1997年11月（冬季）和1999年7月（夏季）两个航次对南沙群岛海域的现场调查，实测了南沙深海盆表层沉积物中的有机物，Fe和Mn的含量，讨论了沉积物中Fe、Mn的平面和深度分布。在沉积物的上层几厘米处Fe和Mn都出现了峰值，这是上层Mn^2 （Fe^2 ）氧化，再沉淀引起的，沉积物中Fe和Mn的深度分布是氧化锰（铁）和氢氧化锰（铁）的还原，扩散和再沉淀的结果，细菌在海洋环境的Fe、Mn循环中起着重要的作用，在大洋底的厌氧环境中细菌将Fe、Mn还原为低价离子或可溶性化合物向间隙水和上覆水移动，在沉积物表层的氧化条件下细菌又使环境中的Fe、Mn沉淀，使其再次富集。     

Origins and pathways of the subsurface and intermediate water masses of the Indonesian Throughflow derived from historical and Argo data

On the basis of Argo data and historic temperature/salinity data from the World Ocean Database 2001 （ WOD01 ）, origins and spreading pathways of the subsurface and intermediate water masses in the Indonesian Throughflow （ITF） region were discussed by analyzing distributions of salinity on representative isopyenal layers. Results were shown that, subsurface water mostly comes from the North Pacific Ocean while the intermediate water originates from both the North and South Pacific Ocean, even possibly from the Indian Ocean. Spreading through the Sulawesi Sea, the Makassar Strait, and file Flores Sea, the North Pacific subsurface water and the North Pacific Intermediate water dominate the western part of the Indonesian Archipelago. Furthermore as the depth increases, the features of the North Pacific sourced water masses become more obvious. In the eastern part of the waters, high sa- linity South Pacific subsurface water is blocked by a strong salinity front between Halmahera and New Guinea. Intermediate water in the eastern interior region owns salinity higher than the North Pacific intermediate water and the antarctic intermediate water （ AAIW）, possibly coming from the vertical mixing between subsurface water and the AAIW from the Pacific Ocean, and possibly coming from the northward extending of the AAIW from the Indian Ocean as well.     

南海及邻近海域异常海温影响局域大气环流的初步试验

南海及邻近海域表层海温（SST）异常的气候意义可以通过IAP－AGCM的数值模拟得到反映。数值试验表明，东亚大气环流对这种SST异常的响应具有时变性（或称季节性），在空间上维持一定的经向结构和纬向结构。确切地说，南海冷水年份，即南海和孟加拉湾负距平、西太平洋正距平的年份，2，3月份南海有东北风异常；夏季菲律宾附近维持一个反气旋式的差值环流，它的低频活动造成了这个地区九水场的低频振荡；与环流较一致的是夏季西太平洋副热带高压活动有所减弱、东移，造成了水汽经向输送的异常分布。     

Distribution of Organic Matter, Iron, Mangenese in SurfaceSediments in the Nansha Islands Sea Area, South China Sea

Concentrations of organic matter, iron and manganese in the deep sea surface sediments in the Nansha Islands sea area, South China Sea are measured, Horizontal and vertical distributions of iron and manganese are discussed. The vertical distribution of iron and manganese in the sediments results from reduction, diffusion, and redeposition of manganese (or iron) oxide and hydroxide in the sediment. There are the maxima of iron and manganese in solid phase in the top of the sediment, which is caused by the penetration of O2 and the upward flux of Mn^2 ( or Fe^2 ). Manganese bacteria play a very important role in the cycle of solid-phase iron and manganese in the ocean environment. Manganese bacteria oxidize Mn^2 ( or Fe^2 ) in dissolved state to Mn^4 ( or Fe^3 ) in oxidized state under the aerobic condition, whereas they reduce iron and manganese in anaerobic conditions.     

On the relationship between convection intensity of South China Sea summer monsoon and air-sea temperature difference in the tropical oceans

The annual, interannual and inter-decadal variability of convection intensity of South China Sea (SCS) summer monsoon and air-sea temperature difference in the tropical ocean is analyzed, and their relationship is discussed using two data sets of 48-a SODA (simple ocean data assimilation) and NCEP/NCAR. Analyses show that in wintertime Indian Ocean (WIO), springtime central tropical Pacific (SCTP) and summertime South China Sea-West Pacific (SSCSWP), air-sea temperature difference is significantly associated with the convection intensity of South China Sea summer monsoon. Correlation of the inter-decadal time scale (above 10 a) is higher and more stable. There is interdecadal variability of correlation in scales less than 10 a and it is related with the air-sea temperature difference itself for corresponding waters. The inter-decadal variability of the convection intensity during the South China Sea summer monsoon is closely related to the inter-decadal variability of the general circulation of the atmosphere. Since the late period of the 1970s, in the lower troposphere, the cross-equatorial flow from the Southern Hemisphere has intensified. At the upper troposphere layer, the South Asian high and cross-equatorial flow from the Northern Hemisphere has intensified at the same time. Then the monsoon cell has also strengthened and resulted in the reinforcing of the convection of South China Sea summer monsoon.     

中尺度涡影响下的南海西部活性铝分布

To understand the distribution of aluminum(Al) under the influence of mesocale eddies in the western South China Sea(SCS), sea level anomaly, geostrophic current, environmental parameters and reactive Al were investigated in the western SCS in August 2013. The highest reactive Al concentration((180±64) nmol/L) was observed in the surface waters, indicating a substantial atmospheric input. Vertically, the reactive Al decreased from the surface high concentration to the subsurface minima at the depth of chlorophyll a(Chl a) maxima and then increased again with depth at most of the stations. The average concentration of reactive Al in the upper 100 m water column was significantly lower in the cyclonic eddy((137±6) nmol/L) as compared with that in the noneddy waters((180±21) nmol/L). By contrast, the average concentrations of Chl a and silicate in the upper 100 m water column were higher in the cyclonic eddy and lower in the anticyclonic eddy. There was a significant negative correlation between the average concentrations of reactive Al and Chl a in the upper 100 m water column. The vertical distribution of reactive Al and the negative correlation between reactive Al and Chl a both suggest that the reactive Al in the upper water column was significantly influenced by biological removal processes. Our results indicate that mesoscale eddies could regulate the distribution of reactive Al by influencing the primary production and phytoplankton community structure in the western SCS.     

On the relationship between convection intensity of South China Sea summer monsoon and air-sea temperature difference in the tropical oceans

The annual, interannual and inter-decadal variability of convection intensity of South China Sea (SCS) summer monsoon and air-sea temperature difference in the tropical ocean is analyzed, and their relationship is discussed using two data sets of 48-a SODA (simple ocean data assimilation) and NCEP/NCAR. Analyses show that in wintertime Indian Ocean (WIO), springtime central tropical Pacific (SCTP) and summertime South China Sea-West Pacific (SSCSWP), air-sea temperature difference is significantly associated with the convection intensity of South China Sea summer monsoon. Correlation of the inter-decadal time scale (above 10 a) is higher and more stable. There is inter-decadal variability of correlation in scales less than 10 a and it is related with the air-sea temperature difference itself for corresponding waters. The inter-decadal variability of the convection intensity during the South China Sea summer monsoon is closely related to the inter-decadal variability of the general circulation of the atmosphere. Since the late period of the 1970s, in the lower troposphere, the cross-equatorial flow from the Southern Hemisphere has intensified. At the upper troposphere layer, the South Asian high and cross-equatorial flow from the Northern Hemisphere has intensified at the same time. Then the monsoon cell has also strengthened and resulted in the reinforcing of the convection of South China Sea summer monsoon.     

印尼贯穿流源区马鲁古海与哈马黑拉海水团来源的季节和年际变化

So far, large uncertainties of the Indonesian throughflow(ITF) reside in the eastern Indonesian seas, such as the Maluku Sea and the Halmahera Sea. In this study, the water sources of the Maluku Sea and the Halmahera Sea are diagnosed at seasonal and interannual timescales and at different vertical layers, using the state-of-the-art simulations of the Ocean General Circulation Model(OGCM) for Earth Simulator(OFES). Asian monsoon leaves clear seasonal footprints on the eastern Indonesian seas. Consequently, the subsurface waters(around 24.5σ_θ and at ～150 m) in both the Maluku Sea and the Halmahera Sea stem from the South Pacific(SP) during winter monsoon, but during summer monsoon the Maluku Sea is from the North Pacific(NP), and the Halmahera Sea is a mixture of waters originating from the NP and the SP. The monsoon impact decreases with depth, so that in the Maluku Sea, the intermediate water(around 26.8σ_θ and at ～480 m) is always from the northern Banda Sea and the Halmahera Sea water is mainly from the SP in winter and the Banda Sea in summer. The deep waters(around27.2σ_θ and at ～1 040 m) in both seas are from the SP, with weak seasonal variability. At the interannual timescale,the subsurface water in the Maluku Sea originates from the NP/SP during El Ni?o/La Ni?a, while the subsurface water in the Halmahera Sea always originates from the SP. Similar to the seasonal variability, the intermediate water in Maluku Sea mainly comes from the Banda Sea and the Halmahera Sea always originates from the SP. The deep waters in both seas are from the SP. Our findings are helpful for drawing a comprehensive picture of the water properties in the Indonesian seas and will contribute to a better understanding of the ocean-atmosphere interaction over the maritime continent.     

Marine ferromanganese concretions from the polish exclusive economic zone: Influence of major inflows of north sea water

Ferromanganese concretions within the Polish Exclusive Economic Zone (EEZ) are found mainly in the depth range 60–70 m on the thresholds between the Bomholm Basin and Slupsk Furrow and between the Gotland and Gdansk Basins. They also occur on elevations of the seafloor within the Bomholm Basin, on the southern slopes of Slupsk Furrow, and on the lower southwestern slopes of the Gotland Basin. They occur mainly as surface deposits on very thin (<0.2 m), poorly sorted lag deposits. The concretions are predominantly discoidal and are formed around a single nucleus of sandstone or erratic rock of variable size. The ferromanganese oxides display internal layering with alternate layers of almost black manganese oxides and buff iron axyhydroxides. The concretions consist mainly of todorokite and quartz, with lesser amounts of feldspar, kaolinite, and montmorillonite. They are characterized by relatively high Fe/Mn ratios (0.9–3.5) and high contents of detrital elements (Ti, Na, K, Ca, and Mg) but low contents of the transition elements (Cu, Zn, Pb, Cr, Co, and Ni). The deposits are associated with the very dynamic environment near the halocline, where internal waves erode the sediment and create conditions of sediment nondeposition favorable for the formation of the concretions. A number of factors contribute to the high abundance of ferromanganese concretions in the Baltic Sea. One is the high input of iron and manganese by the rivers draining into it This is a consequence of the widespread occurrence of bogs and swamps in the catchment area of the Baltic Sea, which results in the river waters having high humic acid contents and low pH. Another major factor is the buildup of dissolved iron and manganese in the anoxic basins of the Baltic Sea during periods of stagnation. These waters are flushed during major inflow events, when oxygenated water from the North Sea displaces the stagnant waters of the anoxic basins. Iron and manganese in these waters are then transported laterally and deposited in the surface of ferromanganese concretions on topographic highs. We believe that the iron is deposited rapidly after such events but that the manganese is deposited over a much longer time period, thus accounting for the layering in the concretions. The rate of deposition of these elements is essentially controlled by the input of oxygen in the waters of the North Sea. These periods of major inflows are grouped but significant events, for concretions occur on average about 11 times per century. We therefore estimate that the concretions have grown much more slowly than previously thought (about 0.013–0.018 mm/yr), and that a concretion 20 mm in diameter would have an age of about 500–800 years. Higher concentrations of heavy metals have been recorded in the outer layers of the concretions, and it is possible that these can serve as indicators of heavy‐metal pollution in the Baltic Sea. The concretions range from sporadic to intermediate abundance. As such, they have no economic potential.     

A numerical study of the South China Sea deep circulation and its relation to the Luzon Strait transport

A fine-resolution MOM code is used to study the South China Sea basin-scale circulationand its relation to the mass transport through the Luzon Strait. The model domain includes the South China Sea, part of the East China Sea, and part of the Philippine Sea so that the currents in the vicinity of the Luzon Strait are free to evolve. In addition, all channels between the South China Sea and the Indonesian seas are closed so that the focus is on the Luzon Strait transport. The model is driven by specified Philippine Sea currents and by surface heat and salt flux conditions. For simplicity, no wind-stress is applied at the surface.The simulated Luzon Strait transport and the South China Sea circulation feature a sandwich vertical structure from the surface to the bottom. The Philippine Sea water is simulated to enter the South China Sea at the surface and in the deep ocean and is carried to the southern basin by western boundary currents. At the intermediate depth, the net Luzon Strait transport is out of t