Pollution records from sediments of three lakes in New York State

Sediment core segments from Sylvan Lake, Lake Champlain and Lake Canadarago were dated radiometrically with ²¹⁰Pb and ¹³⁷Cs. Their respective sedimentation rates were determined to be 0.11, 0.14 and 0.52 g cm^?2 yr^?1. For the two lakes of lower sedimentation the variations of selected elemental abundances as function of depth were analyzed. Two groupings were found: Al, K, Ti, Rb and Zr were correlated among themselves but reflected different variations in the input of terrigenous erosion material to the lakes. The Cu, Zn and Pb correlated among themselves showed similar depth dependence with increasing concentrations toward the top which can be attributed to cultural pollution. Recent ‘excess’ fluxes to the sediments above the natural contribution by clastic material were derived for the location of the cores, which for Cu, Zn and Pb amounted to 3.8, 24 and 16 μg cm^?2 yr^?1 respectively for Sylvan Lake and 4.9, 20 and 16 μg cm^?2 yr^?1 for Lake Champlain. The corresponding ²¹⁰Pb flux was 3.3 and 2.3 dpm cm^?2 yr^?1, respectively for the two lakes.Approximate residence times in the water column were obtained for trace metals at the Lake Champlain location. Short residence times estimated for Pb (< 0.15 yr) and Cu (< 0.4 yr) indicate fast removal, whereas those for Zn (1.0 ± 0.3 yr) and Cr (2.0 ± 0.5 yr) appeared to be dominated by the water residence time.     

Quantifying the seasonal variations in fluvial and eolian sources of terrigenous material to Cariaco Basin,Venezuela

The varved sediments that accumulate in the Cariaco Basin provide a detailed archive of the region’s climatic history, including a record of the quantity of fluvial and wind-transported material. In this study, we examine the sedimentological characteristics (clay mineralogy and grain size) of both surface sediments and sinking lithogenic material collected from sediment trap samples over a three-year period from 1997 to 2000. Data from biweekly sediment trap samples show a tri-modal particle size distribution, with prominent peaks at 2, 22 and 80 μm, indicating sediment contributions from both eolian and fluvial sources. The clay mineralogy of the water column samples collected from 1997 to 1999 also shows distinctive characteristics of eolian and fluvial material. An examination of surface sediment samples from the Cariaco Basin indicates that the Unare River is the main source of riverine sediments to the eastern sub-basin. By combining these sedimentological proxies, we estimate that ～10% of the terrigenous material delivered to the Cariaco Basin is eolian, while ～90% is fluvial. This represents an annual dust accumulation rate of ～0.59 mg/cm²/yr. Since aerosols are closely linked to climate variability, the ability to quantify paleo-dust fluxes using sedimentological characteristics will be a useful tool for future paleoclimate studies looking at sub-Saharan aridity and latitudinal migration of the Intertropical Convergence Zone.     

Metal accumulation rates in northwest Atlantic pelagic sediments

Measurements of ²³⁰Th, ${}^{87}\text{Sr}{}^{86}\text{Sr}$ and twenty-four metals were made on cores from the Nares Abyssal Plain. The sediment is characterized by slowly-accumulating (0.3–0.7 g/cm² 10³ yr) pelagic red clays and rapidly deposited grey clays transported by turbidity currents. Despite their colour differences and the enrichment of Mn, Fe, Cu, Co, Ni, Zn, V and, to a lesser degree, the rare earths in the red clays, Sr isotope evidence demonstrates that the clays have the same terrigenous origin. The excesses of metals in the red clays have been attributed to metal removal from the water column and a comparison with the grey clays has enabled the authigenic fluxes of metals to be estimated. The fluxes obtained are in the ranges 20–50 μmol/cm² 10³ yr for Mn and Fe, 0.1–0.4 μmol/cm² 10³ yr for Cu, Co, Ni, Zn, V, Sr and Ce, 10–20 nmol/cm² 10³ yr for La and Nd, and 0.5-3 nmol/cm² 10³ yr for Sm, Eu, Gd, Dy, Er and Yb. Authigenic fluxes of Y, Nb, Cr, Zr, Rb, U and Th were not resolvable. Fluxes appear to be near constant on the Plain but comparison with other areas shows that they are quite variable both between and within ocean basins. The chief factor controlling authigenic fluxes is the geochemical abundances of the elements but fractionation within both the transition element and rare earth series can be recognized from inter-element comparisons and from differences in fluxes between Atlantic and Pacific red clays corresponding to the oceanic reactivities of the elements.     

Bottom sediments and near-bottom currents in the Southwestern Atlantic

On the basis of the author’s data on the composition of sediments and seismic cross sections, together with literature data, the bottom topography was described and the main structural features of the top 10–100 m thick sedimentary sequence in the Southwestern Atlantic (Brazil Basin) were identified. The presence of a heavy northward flow of Antarctic bottom water (AABW) and its active erosive activity were confirmed. The AABW caused the erosion or redeposition of red pelagic clays and hemipelagic clays, which accumulated in the Brazil Basin in the Holocene and Pleistocene; the clays contain abundant redeposited Pleistocene diatoms and Neogene and Paleogene discoasters. In most of the sediment cores of the Brazil Basin, the red pelagic clays are of Pleistocene age. Contourites and sandy microlayers have been found in the sediments at the foot of the continental slope of South America; this is the effect of the Deep Western Boundary Current on the ocean floor. The AABW transfers Antarctic diatom species along the continental slope of South America to 10°-5° S. The presence of the Equatorial Midocean Channel with a relative depth of 149 m in the western pelagic equatorial part of the Atlantic was confirmed, and new channels, such as Vavilov and Akademik Ioffe, have been found. The AABW flows northward along the Equatorial Mid-Ocean Channel. Apparently, the Akademik Ioffe Channel is not a proper midocean channel. At 20° S (at a depth of 5000 m), Pleistocene diatomic (Ethmodiscus rex) ooze containing up to 74% amorphous SiO₂ was detected. On the Amazon-Mid-Atlantic Ridge profile, the AABW flows into the Guyana Basin through only one valley of the Nara Plain, with a depth of 4620 m. Near the Ceara Rise and on the Amazon Fan, no geologic traces of the AABW flow into the Guyana Basin were found. Near the Rio Grande Rise, the AABW might have appeared in the Eocene. The formation of the Vema Channel, which separates the Rio Grande Rise from South America, also began at that time. The AABW flows were the heaviest before the largest glaciations (particularly at isotopic stages 7/6 and 3/2).     

Biogeochemical cycling in an organic rich coastal marine basin—II. Nutrient sediment-water exchange processes

The release of remineralized N and P from the organic-rich anoxic sediments of Cape Lookout Bight is controlled by processes occurring within the sediment column and at the sediment-water interface. The relatively rapid rates of temperature dependent microbial degradation of organic matter support seasonally varying nutrient fluxes ranging from 20 to 1200 μmol·m^?2·hr^?1 for dissolved ammonium and from ? 20 to 120 μmol·m^?2·hr^?1 for total dissolved phosphate (measured in situ over the period October, 1976 to October, 1978). Molecular diffusion along steep vertical pore water concentration gradients measured simultaneously cannot explain the high fluxes observed during warmer months. Gradients for ammonium and phosphate ranged from 0.33 to 1.10 and from 0 to 0.29 μmol·cm^?3_pw·cm^?1_s respectively. These high summertime fluxes appear to result from increased sediment-water transport associated with bubble tubes created and maintained by low-tide methane gas bubble ebullition. When these tubes are present, apparent bulk sediment diffusivities calculated from concurrent studies of methane and radon-222 sediment-water exchange are 1.0–3.1 times greater than molecular diffusivities. Nutrient fluxes calculated via Fick's first law taking into account this enhanced transport and the differential diffusive mobilities of dissolved ammonium, phosphate and phosphate ion pairs indicate that removal by aerobic adsorption and/or biological uptake at the sediment-water interface plays an important role in controlling nutrient exchange in these sediments.     

新疆艾比湖地区盐尘的沉积通量及其物质组成

以新疆准噶尔盆地西部的艾比湖地区为研究区,通过野外降尘监测、采样分析等方法,研究了艾比湖地区含盐粉尘的沉积通量和物质组成特征.结果表明:艾比湖干涸湖底是盐尘的输出源,盐尘的化学组成主要是无水芒硝、白钠镁矾、氯化钠等盐碱粉尘及Cr、Pb、Mn、Cu、Ni等潜在毒性元素.艾比湖地区盐尘的沉积通量约为79~381 g·m-2·a-1,盐的沉积通量约为4~61 g·m-2·a-1.盐尘的粒径分布以2~63μm的粉砂粒级为主,大于63μm的砂粒级所占比例很小.特殊的地形条件、大风天气、稀疏的植被覆盖、疏松的大面积尘源是艾比湖湖底风蚀和盐尘输送的有利条件.     

Interaction of the Western Boundary Undercurrent with the continental margin off Newfoundland

Sedimentation on the Newfoundland rise is strongly influenced by the Western Boundary Undercurrent (WBU). The upper rise (2600-2800 m) is swept by a rapid (ū= 8·5 cm sec^?1), south-flowing core of the WBU which has generated a sandy contourite facies characterized by coarse gravelly, sandy sediments; current-induced bedforms such as scour moats, lineations and lee drifts; ferro-manganese-stained gravel clasts; a high proportion of broken foraminiferal tests and a diagnostic benthic foraminiferal assemblage. The overlying nepheloid layer, when compared to adjacent waters, is thickest (800 m), most sediment laden (80 μg 1^?1), contains the highest proportion of terrigenous sediment and exhibits the best developed bottom mixed layer (～ 15 m thick). Comparisons with earlier data from the same area imply the dimensions and sediment load of the nepheloid layer vary with time. Empirical considerations, based on near-bottom current meter records from Labrador and Newfoundland, suggest the WBU is capable of transporting bedload with threshold friction velocities (u*) of around 0·87-1·14 cm sec^?1 for between 1 and 15% of the time. The prevailing transport direction is southwards along the rise, but this may be punctuated periodically by brief incursions to the north. The erosional regime of the upper rise is bordered by a regime of fine-grained deposition typified by muddy contourites. Both the lower slope and lower rise are mantled by bioturbated muds, the former zone having terrigenous mud and the latter, biogenic calcareous mud. The accompanying nepheloid layer is thin, biogenic-rich and devoid of an identifiable mixed layer.     

Lead-210 sediment geochronology in a changing coastal environment

Sediment accumulation rate studies utilizing excess ²¹⁰Pb and ¹³⁷Cs were conducted as part of recent investigations of biogeochemical cycling at a single site in Cape Lookout Bight, a rapidly changing coastal basin on the Outer Banks of North Carolina (U.S.A.). Cores three meters in length reveal a depositional history for the bight interior characterized by a gradual transition in texture from coarse-grained to fine-grained material over the period 1946–1979. This transition is controlled by progressive enclosure of the bight by an active northerly migrating recurved spit. The textural gradation is periodically interrupted by layers of well-sorted sand associated with major storm events. Lead-210 data indicate that the upper meter of the sediment has accumulated at a rate of 3.35 to 4.71 g · cm^?2 · yr^?1 or approximately 8.4 to 11.8 cm · yr^?1 (at ø = 0.84). Below 120 cm depth, dilution of clay and silt by low activity sand necessitates correction of the ²¹⁰Pb profile in order to establish a geochronology. Grain size ²¹⁰Pb distribution measurements at three depths reveal that the specific activity (dpm · g^?1) of clay is 3.2 times that of silt and 24.7 times that of sand. Corrections of bulk sediment excess ²¹⁰Pb activities based on these measurements lead to dates for textural changes which are consistent with charted changes in basin morphology and major storm events.Sixteen ¹³⁷Cs measurements between 33–241 cm depth reveal a peak activity at 105–115 cm and indicate a minimum sedimentation rate of approximately 2.7 g · cm^?2 · yr^?1.     

Submergent shorelines in the SW Pacific: evidence for an episodic post-glacial transgression

ABSTRACT High resolution seismic profiles, supported where possible by radiocarbon dates and regional stratigraphic data, indicate that the last post-glacial transgression in the SW Pacific was episodic, comprising major stillstands punctuated by rapid rises in sea-level. On the terrigenous continental shelf east of South Island, New Zealand, a succession of shorelines (S8-S1) are recognized, as follows: S8 =c. ?113 m, 18,000 yr BP; S7 =c. ?88 m, 17,000 yr BP; S6 =c. ?75 m, 15,000 yr BP; S5 =c. ?56 m, 12,000 yr BP; S4 =c. ?46 m, 11,000 yr BP; S3 =c. ?28 m, 9,500 yr BP; S3a =c. ?24 m, 9,000 yr BP; S2 =c. ?9 m, 7,500 yr BP; S1 = 0 m, 6,500 yr BP. With the exception of S8, and possibly S2, the shorelines are associated with wedges of sediment, the size and presence of which imply that (1) sea-level stabilized at some shorelines for a considerable period of time (up to 1-2,000 yr); and (2) the intervening rises of sea-level, estimated to have been at least 10-12 m 10³ yr^?1, were too rapid to allow the reworking of the wedges into a transgressive sediment sheet, as favoured in some current models. On the Great Barrier Reef shelf, off Queensland Australia, shorelines S8-S1 have also been recognized, with a further shoreline feature S4a occurring at c. -39 m. Shorelines S1a (0 m/0 yr BP), Sib (+ 2-3 m/6,000 yr BP) and Sic (0 m/6,500yr BP) are recognized as discrete aspects of the post-6,500 yr BP sea-level behaviour in north-eastern Australia. The rapid rise in sea-level, at least between shorelines S5 (12,000 yr BP) and S3 (9,500 yr Bp), is known to have outpaced reef growth, causing in situ drowning of reefs located along the deeper shorelines. All modern reefs so far drilled and dated began their development at or above S3 (-28 m, 9,500 yr BP). Some of the shorelines, particularly S5, appear to correlate between the northern and southern hemispheres on the basis of age, succession and general depth of occurrence, suggesting (1) that they may be global features controlled by the post-glacial pattern of ice-sheet decay; and (2) that hydro-isostatic adjustment may exert only a minor control on the depth of particular shorelines, at least during the earlier parts of the post-glacial transgression.     

Changes of lead and barium with time in California off-shore basin sediments

During ancient times the natural deposition fluxes of lead which can be leached with dilute acid from sediments in Santa Barbara, Santa Monica and San Pedro basins offshore from the Los Angeles Urban complex, were about 0.7, 0.1 and 0.2 μg Pb/cm² yr respectively. Since there was little difference in biological productivity in surface waters of these basins, it is proposed that clay is a major transport vehicle for sequestered soluble lead, which then explains why the lead deposition flux within the Santa Barbara basin was so much larger compared to the other basins. The fluxes of silicate mud in the basins in ancient times were about 92, 19 and 30 mg/cm² yr in Santa Barbara, Santa Monica and San Pedro basins respectively. Today deposition fluxes of acid soluble lead within these three basins are 3- to 9-fold greater, being about 2.1, 1.1 and 1.8 μg Pb/cm² yr respectively, partly in the form of directly deposited large sewage particles, which account for none, $\text{2}\text{3}$ and $\text{3}\text{4}$ of the total industrial lead deposition fluxes in the respective basins. Concentrations of leachable lead in varve dated sediment layers increase with time and isotopic compositions of these leads change in accordance with corresponding known changes of isotopic compositions of industrial lead in the Los Angeles atmosphere. Lead remaining in acid leached sediment residues originates from igneous and clay minerals, exhibiting no change in concentration or isotopic composition since pre-industrial times.Deposition fluxes of total barium in sediments among the three basins were proportional to mass deposition fluxes before 1950 in the same manner as for lead. Afterwards, there are barium concentration maxima with time in both Santa Monica and San Pedro Basin sediments which are attributable to industrial sewage rather than to episodic erosion from barium-rich sedimentary evaporite strata exposed locally along the shore. An increase of barium concentrations in present day Santa Barbara basin sediments may reflect dispersal of barium-rich drilling mud from local drilling operations.     

Shingled Quaternary debris flow lenses on the north-east Newfoundland Slope

Debris flow deposits are the principal component of Quaternary continental slope sediments between the north-east Newfoundland Shelf and central Orphan Basin. In seismic profiles, these deposits occur as shingled, elongate, acoustically transparent lenses with their long axes orientated downslope. Deposits of individual flows form positive mounds on the sea floor; subsequent flows were diverted by the pre-existing topography into bathymetric lows between older debris flow deposits. These deposits show a large variation in the area of sea floor covered by individual flows (about 60–1000 km²), average thickness of deposits (9–37 m) and volume of sediment displaced (1–27 km³). The ratio of average thickness to a measure of deposit diameter, termed the aspect ratio, has a threefold variation from 0·0006 to 0·0021. Very low depositional slopes and low aspect ratios suggest relatively low viscosities, probably due to inmixing of water during downslope transport. Stratified sediments form three distinct horizons and are locally interbedded with the debris flow deposits. These are mainly hemipelagic deposits. The slope and rise to the west of the Orphan Basin are constructional in character. The apparent absence of upper slope erosional features and the abundance of debris flow deposits on the slope suggest that the supply of sediment to the continental slope occurred predominantly during times of maximum extent of Quaternary glacial ice. The ice sheet grounding line during several glacial maxima must have been situated at or near the present shelf break, supplying vast amounts of sediment directly to the upper slope. Oversteepening and subsequent slope failures fed material into deeper water.     

Three‐dimensional seismic analysis of sediment waves and related geomorphological features on a carbonate shelf exposed to large amplitude internal waves,Browse Basin region,Australia

This study analyses the three‐dimensional geometry of sedimentary features recorded on the modern sea floor and in the shallow subsurface of a shelf to upper slope region offshore Australia that is characterized by a pronounced internal wave regime. The data interpreted comprise an extensive, >12 500 km² industrial three‐dimensional seismic‐reflection survey that images the northern part of the Browse Basin, Australian North West Shelf. The most prominent seismic–morphological features on the modern sea floor are submarine terrace escarpments, fault‐scarps and incised channels, as well as restricted areas of seismic distortion interpreted as mass wasting deposits. Besides these kilometre‐scale sea floor irregularities, smaller bedforms were discovered also, including a multitude of sediment waves with a lateral extent of several kilometres and heights up to 10 m. These sedimentological features generally occur in extensive fields in water depths below 250 m mostly at the foot of submerged terraces, along the scarps of modern faults and along the shelf break between the outer shelf and the upper continental rise. Additional bedforms that characterize the more planar regions of the outer shelf are elongate, north‐west/south‐east oriented furrows and ridges. The formation of both sediment waves and furrow‐ridge systems requires flow velocities between 0·3 m sec^?1 and 1·5 m sec^?1, which could be generated by oceanic currents, gravity currents or internal waves. In the studied setting, these velocities can be best explained as being generated by bottom currents induced by internal waves, an interpretation that is discussed against oceanographic background data and modelling results. In addition to the documentation of three‐dimensional seismic–geomorphological features of the modern sea floor, it was also possible to map kilometre‐scale buried sediment wave fields in the seismic volume down to ca 500 ms two‐way‐time below the present sea floor, indicating the general potential for the preservation of such bedforms in the sedimentary record.     

Biogeochemical cycling in an organic-rich coastal marine basin—I. Methane sediment-water exchange processes

Methane produced in anoxic organic-rich sediments of Cape Lookout Bight, North Carolina, enters the water column via two seasonally dependent mechanisms: diffusion and bubble ebullition. Diffusive transport measured in situ with benthic chambers averages 49 and 163 μmol · m ^?2 · hr ^?1 during November–May and June–October respectively. High summer sediment methane production causes saturation concentrations and formation of bubbles near the sediment-water interface. Subsequent bubble ebullition is triggered by low-tide hydrostatic pressure release. June–October sediment-water gas fluxes at the surface average 411 ml (377 ml STP: 16.8 mmol) · m^?2 per low tide. Bubbling maintains open bubble tubes which apparently enhance diffusive transport. When tubes are present, apparent sediment diffusivities are 1.2–3.1-fold higher than theoretical molecular values reaching a peak value of 5.2 × 10^?5 cm² · sec^?1. Dissolution of 15% of the rising bubble flux containing 86% methane supplies 170μmol · m^?2 · hr^?1 of methane to the bight water column during summer months; the remainder is lost to the troposphere. Bottom water methane concentration increases observed during bubbling can be predicted using a 5–15 μm stagnant boundary layer dissolution model. Advective transport to surrounding waters is the major dissolved methane sink: aerobic oxidation and diffusive atmospheric evasion losses are minor within the bight.     

210Pb activities in and fluxes to sediments of the Washington continental slope and shelf

Surface sediments of the Washington coast have ²¹⁰Pb activites which average 104 ± 48dpm/g for submarine canyon and slope regimes and 18 ± 12dpm/g for the continental shelf regime. ²¹⁰Pb sedimentary fluxes are also higher in canyons, averaging 18 ± 13dpm/cm² per yr, compared to 5.2 ± 3.1 dpm/cm² per yr for slope and 4.8 ± 1.8dpm/cm² per year for shelf regions. These ²¹⁰Pb activities and fluxes are 2–7 times greater than those reported for other coastal regions. Inputs from the atmosphere and the Columbia River are not sufficient to supply the ²¹⁰Pb, but advection of seawater containing dissolved ²¹⁰Pb produced in situ from ²²⁶Ra provides an input several times larger than the sedimentary fluxes. The sedimentary ²¹⁰Pb flux is limited by scavenging reactions rather than by supply of dissolved ²¹⁰Pb.Calculations of maximum biological uptake and fluxes of ²¹⁰Pb and ‘selective’ chemical leaching experiments all show that the primary scavenging processes are due to hydrous Mn and Fe oxides rather than biological phases. The pattern of higher ²¹⁰Pb depositional fluxes in canyons than in nearby open slope areas of comparable water depth is most reasonably explained by enhanced scavenging of dissolved ²¹⁰Pb near the sea floor, rather than by processes operating throughout the water column. Relatively rapid removal of dissolved ²¹⁰Pb from the near bottom nepheloid layer to slope and canyon sediments is shown by its mean residence time of less than two years in this layer.     

A comparative study of iron and manganese diagenesis in continental slope and deep sea basin sediments off Uruguay (SW Atlantic)

Pore water and solid phase from surface sediments of the continental slope off Uruguay and from the Argentine Basin (southwestern Atlantic) were investigated geochemically to ascribe characteristic early diagenetic reactions of iron and manganese. Solid-phase iron speciation was determined by extractions as well as by Mössbauer spectroscopy. Both methods showed good agreement ( <6% deviation) for total-Fe speciation. The proportion of easy reducible iron oxyhydroxide relative to total-Fe oxides decreased from the continental slope to the deep sea which is attributed to an increase in crystallinity during transport as well as to a general decrease of iron mobilization. The product of iron reoxidation is Fe oxyhydroxide which made up less than 5% of total Fe. In addition to this fraction, a proportion of smectite bound iron was found to be redox reactive. This fraction made up to 10% of total Fe in sediments of the Argentine Basin and was quantitatively extracted by 1?N HCl. The redox reactive Fe(+II) fraction of smectite was almost completely reoxidized within 24?h under air atmosphere and may therefore considerably contribute to iron redox cycling if bioturbation occurs. In the case of the slope sediments we found concurrent iron and manganese release to pore water. It is not clear whether this is caused by dissimilatory iron and manganese reduction at the same depth or dissimilatory iron reduction alone inducing Mn(+IV) reduction by (abiotic) reaction with released Fe²⁺. The Argentine Basin sediment showed a significant manganese solid-phase enrichment above the denitrification depth despite the absence of a distinct pore-water gradient of Mn. This implies a recent termination of manganese mobilization and thus a non-steady-state situation with respect to sedimentation or to organic carbon burial rate.     

The high-supply,current-dominated continental margin of southeastern South America during the late Quaternary

The continental margin off the La Plata Estuary (SE South America) is characterized by high fluvial sediment supply and strong ocean currents. High-resolution sediment-acoustic data combined with sedimentary facies analysis, AMS-¹⁴C ages, and neodymium isotopic data allowed us to reconstruct late Quaternary sedimentary dynamics in relation to the two major sediment sources, the La Plata Estuary and the Argentine margin. Sediments from these two provinces show completely different dispersal patterns. We show that the northward-trending La Plata paleo-valley was the sole transit path for the huge volumes of fluvial material during lower sea levels. In contrast, material from the Argentine margin sector was transported northwards by the strong current system. Despite the large sediment volumes supplied by both sources, wide parts of the shelf were characterized by either persistent non-deposition or local short-term depocenter formation. The location and formation history of these depocenters were primarily controlled by the interplay of sea level with current strength and local morphology. The high sediment supply was of secondary importance to the stratigraphic construction, though locally resulting in high sedimentation rates. Thus, the shelf system off the La Plata Estuary can be considered as a hydrodynamic-controlled end-member.     

Sea-level and tectonic control of middle to late Pleistocene turbidite systems in Santa Monica Basin, offshore California

Small turbidite systems offshore from southern California provide an opportunity to track sediment from river source through the turbidity‐current initiation process to ultimate deposition, and to evaluate the impact of changing sea level and tectonics. The Santa Monica Basin is almost a closed system for terrigenous sediment input, and is supplied principally from the Santa Clara River. The Hueneme fan is supplied directly by the river, whereas the smaller Mugu and Dume fans are nourished by southward longshore drift. This study of the Late Quaternary turbidite fill of the Santa Monica Basin uses a dense grid of high‐resolution seismic‐reflection profiles tied to new radiocarbon ages for Ocean Drilling Program (ODP) Site 1015 back to 32 ka. Over the last glacial cycle, sedimentation rates in the distal part of Santa Monica Basin averaged 2–3 mm yr^?1, with increases at times of extreme relative sea‐level lowstand. Coarser‐grained mid‐fan lobes prograded into the basin from the Hueneme, Mugu and Dume fans at times of rapid sea‐level fall. These pulses of coarse‐grained sediment resulted from river channel incision and delta cannibalization. During the extreme lowstand of the last glacial maximum, sediment delivery was concentrated on the Hueneme Fan, with mean depositional rates of up to 13 mm yr^?1 on the mid‐ and upper fan. During the marine isotope stage (MIS) 2 transgression, enhanced rates of sedimentation of > 4 mm yr^?1 occurred on the Mugu and Dume fans, as a result of distributary switching and southward littoral drift providing nourishment to these fan systems. Longer‐term sediment delivery to Santa Monica Basin was controlled by tectonics. Prior to MIS 10, the Anacapa ridge blocked the southward discharge of the Santa Clara River into the Santa Monica Basin. The pattern and distribution of turbidite sedimentation was strongly controlled by sea level through the rate of supply of coarse sediment and the style of initiation of turbidity currents. These two factors appear to have been more important than the absolute position of sea level.     

Deep-water sediment wave fields, bottom current sand channels and gravity flow channel-lobe systems: Gulf of Cadiz, NE Atlantic

Abstract A study of the seafloor of the Gulf of Cadiz west of the Strait of Gibraltar, using an integrated geophysical and sedimentological data set, gives new insights into sediment deposition from downslope thermohaline bottom currents. In this area, the Mediterranean Outflow (MO) begins to mix with North Atlantic waters and separates into alongslope geostrophic and downslope ageostrophic components. Changes in bedform morphology across the study area indicate a decrease in the peak velocity of the MO from >1 m s^?1 to <0·5 m s^?1. The associated sediment waves form a continuum from sand waves to muddy sand waves to mud waves. A series of downslope‐oriented channels, formed by the MO, are found where the MO starts to descend the continental slope at a water depth of ≈700 m. These channels are up to 40 km long, have gradients of <0·5°, a fairly constant width of ≈2 km and a depth of ≈75 m. Sand waves move down the channels that have mud wave‐covered levees similar to those seen in turbidite channel–levee systems, although the channel size and levee thickness do not decrease downslope as in typical turbidite channel systems. The channels terminate abruptly where the MO lifts off the seafloor. Gravity flow channels with lobes on the basin floor exist downslope from several of the bottom current channels. Each gravity flow system has a narrow, slightly sinuous channel, up to 20 m deep, feeding a depositional lobe up to 7 km long. Cores from the lobes recovered up to 8·5 m of massive, well‐sorted, fine sand, with occasional mud clasts. This work provides an insight into the complex facies patterns associated with strong bottom currents and highlights key differences between bottom current and gravity flow channel–levee systems. The distribution of sand within these systems is of particular interest, with applications in understanding the architecture of hydrocarbon reservoirs formed in continental slope settings.     

Amino acid composition of suspended particles,sediment-trap material,and benthic sediment in the Potomac Estuary

Sediment trap deployments in estuaries provide a method for estimating the amount of organic material transported to the sediments from the euphotic zone. The amino acid composition of suspended particles, benthic sediment, and sediment-trap material collected at 2.4 m, 5.8 m, and 7.9 m depths in the Potomac Estuary was determined in stratified summer waters, and in well-mixed oxygenated waters (DO) in late fall. The total vertical flow, or flux, of material into the top traps ranged from 3 g m^?2 d^?1 in August to 4.9 g m^?2 d^?1 in October. The carbon and nitrogen fluxes increased in the deepest traps relative to the surface traps during both sampling periods, along with that of the total material flux (up to 47.3 g m^?2 d^?1 in the deepest trap), although the actual weight percent of organic carbon and organic nitrogen decreased with depth. Amino acid concentrations ranged from 129 mg g^?1 in surface water particulate material to 22 mg g^?1 in particulate material in 9-m-deep waters and in the benthic sediment. Amino acid concentrations from 2.4-mg-depth sediment traps averaged 104±29 mg g^?1 in stratified waters and 164±81 mg g^?1 in well-mixed waters. The deep trap samples averaed, 77.3±4.8 mg g^?1 amino acids in summer waters and 37±16 mg g^?1 in oxygenated fall waters. Amino acids comprised 13% to 39% of the organic carbon and 12% to 89% of the orgnaic nitrogen in these samples. Analysis of the flux results suggest that resuspension combined with lateral advection from adjacent slopes can account for up to 27% of the material in the deep traps when the estuary was well-mixed and unstratified. When the estuary was stratified in late summer, the amino acid carbon produced by primary productivity in the euphotic zone decreased by 85% (86% for total organic carbon) at the pycnocline at 6 m depth, leaving up to 15% of the vertical organic flux available for benthic sediment deposition.     

The composition and diagenesis of interstitial solutions—I. Fluxes across the seawater-sediment interface in the Atlantic Ocean

Studies of the composition of interstitial solutions of marine sediments have been carried out utilizing in situ sampling techniques. Samples were obtained from the Caribbean, North Atlantic and South Atlantic. In virtually all cases, diagenesis has led to the uptake of Mg²⁺ and K⁺ and the release of Ca²⁺, HCO^?₃ and Na⁺ by the solid phases. SO^2?₄ is slightly enriched at nearly all stations, reduction being observed only at continental margin stations. Cl^? is conservative within experimental precision.The reactions controlling the fluxes of most components across the water-sediment interface occur almost entirely in the upper 100 cm of sediment. Contributions of Mg ²⁺, Ca ²⁺, K⁺ and HCO^?₃ from below 100 cm amount to less than 15% of the calculated fluxes across the interface. Reactions in the upper 30 cm account for 70–90% of the fluxes of these components across the interface. Only Na⁺ has a deep source, gradients often being linear in the upper 2m of sediment.Calculated fluxes across the sediment-water interface are of the same order of magnitude as river inputs for the components studied. In the case of Mg²⁺ and K ⁺, 60–100% of the river input can be balanced by diagenetic uptake in the sediment. For Ca²⁺ and HCO^?₃ additions to seawater augment the river supply by 25–50%. When the uptake of Mg²⁺ and K⁺ by the sediment is calculated by integrating the fluxes across the interface, calculated concentrations of both of these elements are inconsistent with published average concentrations for the types of sediment studied.