Evaluation of the 210Po method at the Midwest uranium deposit,Northern Saskatchewan,Canada

Vertical profiles of ²¹⁰Po in soils near the Midwest uranium deposit and an associated surficial radioactive sandstone boulder train in northern Saskatchewan show a high ²¹⁰Po background in air-dried forest litter (24 pCi/g) and Ah horizon soil (11 pCi/g) relative to lower soil horizons (<1 pCi/g). These high levels mask the ²¹⁰Po signal from the radioactive boulders in the near-surface soil horizons. Only in the Bf and C horizons can the existence of the radioactive boulders be inferred from ²¹⁰Po determinations. For comparative purposes profiles for ²²⁶Ra, U, Ni, and other trace elements are also presented.Escape of most of the Rn from near surface soils into the atmosphere, homogenization and decay of Rn, and precipitation of decay products back onto surface soils satisfactorily explain the field observations discussed here.Compared to the highly anomalous ²²²Rn signal in soil gases over this boulder train the ²¹⁰Po contrast is very weak and is of little use for prospecting for this type of boulder train. The relatively high ²¹⁰Po background in surficial materials relative to lower soil horizons dictates that great care be taken with the ²¹⁰Po method; the deepest possible horizons should be sampled.     

The relationship of soil 210Po and 210Pb geochemical dispersion patterns to uranium mineralization

²¹⁰Po and ²¹⁰Pb measurements of soils delineated uranium anomalies at three out of four test sites in Ontario, Canada. Measurements were made of ²¹⁰Po in solutions produced by both complete digestion and partial leaching of soil samples. Direct plating of ²¹⁰Po onto metal plates was followed by measuring the alpha activity. Subsequent plating of ²¹⁰Po in-grown from ²¹⁰Pb in solution several months later confirmed the anomalies.The ²¹⁰Po and ²¹⁰Pb anomalies at three of the test sites coincided with ²²⁶Ra and ²²²Rn anomalies. Samples from the fourth uranium occurrence associated with a known ²²²Rn anomaly failed to show either a ²²⁶Ra anomaly on the one hand, or ²¹⁰Po or ²¹⁰Pb anomalies on the other. This suggests that the ²¹⁰Po and ²¹⁰Pb anomalies were probably produced by the decay of ²²⁶Ra contained within secondary dispersion haloes.Although anomalies due to the ²¹⁰Po and ²¹⁰Pb products of ²²²Rn have now been documented, prospecting methods based on their use as direct tracers of the migration paths of ²²²Rn require much further development.     

The relationship of soil Po and Pb geochemical dispersion patterns to uranium mineralization

²¹⁰Po and ²¹⁰Pb measurements of soils delineated uranium anomalies at three out of four test sites in Ontario, Canada. Measurements were made of ²¹⁰Po in solutions produced by both complete digestion and partial leaching of soil samples. Direct plating of ²¹⁰Po onto metal plates was followed by measuring the alpha activity. Subsequent plating of ²¹⁰Po in-grown from ²¹⁰Pb in solution several months later confirmed the anomalies.The ²¹⁰Po and ²¹⁰Pb anomalies at three of the test sites coincided with ²²⁶Ra and ²²²Rn anomalies. Samples from the fourth uranium occurrence associated with a known ²²²Rn anomaly failed to show either a ²²⁶Ra anomaly on the one hand, or ²¹⁰Po or ²¹⁰Pb anomalies on the other. This suggests that the ²¹⁰Po and ²¹⁰Pb anomalies were probably produced by the decay of ²²⁶Ra contained within secondary dispersion haloes.Although anomalies due to the ²¹⁰Po and ²¹⁰Pb products of ²²²Rn have now been documented, prospecting methods based on their use as direct tracers of the migration paths of ²²²Rn require much further development.     

Lead isotopic compositions in fault gouges and their parent rocks: implications for ancient fault activities

This is the first study on Pb stable isotopes in fault gouges and their parent rocks. We analyzed the composition of Pb isotopes and contents of U and Pb in 10 pairs of fault gouges and their parent rocks collected along several active faults in central Japan. Thorium-232-²⁰⁸Pb ages of two fault systems were determined as pre-Tertiary, which are consistent with the data from KAr ages and geological considerations.Naturally, the²³⁵U²⁰⁷Pb system is of little use for dating because the magnitude of difference in²⁰⁷Pb/²⁰⁴Pb between gouges and parent rocks is too small. It is found that the²⁰⁶Pb/²⁰⁴Pb can indicate the contribution of²⁰⁶Pb resulting from excess supplies of²²⁶Ra and²²²Rn along the fault. The excess²⁰⁶Pb accumulation rate corresponds to the average²²²Rn concentration in soil gas or groundwater through geological time since the gouge formation. A comparison of Quaternary fault activity and estimated Tertiary activity reveals the characteristics of each fault system.     

Analysis of the exchange of groundwater and river water by using Radon-222 in the middle Heihe Basin of northwestern China

In arid regions of western China, water resources come from mountain watersheds and disappear in the desert plain. The exchange of surface water and groundwater takes place two or three times in a basin. It is essential to analyze the interaction of groundwater with surface water to use water resources effectively and predict the change in the water environment. The conventional method of analysis, however, measures only the flow of a stream and cannot determine groundwater seepage accurately. As the concentration of Radon-222 (²²²Rn) in groundwater is much higher than in surface water, the use of ²²²Rn was examined as an indicator for the analysis of the interaction between surface water and groundwater. Measurement of the ²²²Rn concentration in surface water was conducted to detect groundwater seepage into a stream in the middle Heihe Basin of northwestern China. Furthermore, the simultaneous groundwater flow into and out of a stream from the aquifers was quantified by solving the ²²²Rn mass balance equation, in which the losses of gas exchange and radioactive decay of ²²²Rn are considered. Meanwhile, river runoff was gauged to determine the exchange rates between surface water and groundwater. The result shows that ²²²Rn isotope can be used as a good environmental tracer with high sensitivity for the interaction between surface water and groundwater, especially in the fractured aquifer system, karst aquifer system and discharge basins.     

Statistical approach for the geochemical signature of two active normal faults in the western Corinth Gulf Rift (Greece)

Soil–gas measurements of different gas species were performed in two distinct areas of the Corinth Gulf Rift (Greece): the Aigion-Neos Erineos-Lambiri (ANEL) fault zone and the Rion-Patras fault zone. Both zones lie in one of the most seismically active areas of the Euro-Mediterranean region, where a fast-opening continental rift is located. In particular, the geochemical investigations were focused on fault segments and fracture systems previously inferred by geomorphological, lithological and structural studies.In this work the applicability of soil–gas geochemistry surveys for the exploration of buried/hidden faults was tested by using various statistical methods. Moreover, a comprehensive geostatistical treatment of the collected data provided new insights into the control exerted by active structures on deep-seated gas migration towards the surface. In both investigated areas, the highest ²²²Rn and CO₂ concentration peaks correspond with zones where the interaction among fracture and fault segments was inferred by structural and morphological methods. This indicates a clear correlation between the shape and orientation of the anomalies and the different attitude and kinematic behavior of the faults recognized in the two areas. Furthermore, obtained results show that gases migrate preferentially through zones of brittle deformation by advective processes, as suggested by the relatively high rate of migration needed to obtain anomalies of short-lived ²²²Rn in the soil pores.     

Study of radon in soil gas,trace elements and climatic parameters around South Kordofan state,Sudan

This study was conducted primarily to measure and map radon activity concentration in soil gas and to understand the effect of geology and lithology and meteorology on radon concentration. Portable radon meter has been used for the measurement of soil gas radon at 30 different locations around Uro and Korn area in eastern Nuba Mountain South Kordofan State. The results indicate that the activity concentrations of ²²²Rn in soil gas fall within the range of 20–1,359 Bq/m³ with geometric mean of 102.80 Bq/cm³. The obtained data show that samples around Uro have anomaly of ²²²Rn concentrations than the sample around Korn. The reason could be attributed to differences in the geological structure, lithology and climate parameters. GIS predicative map has shown that the elevated levels of radon concentration were measured in North study area. Upon comparing the results with global data, it was found that the obtained values are far below the reported range of India, Slovenia, Portugal and Syria. However, the range of ²²²Rn concentrations in the soil observed in this study is significantly high relative to similar data reported from Libya. The regression analysis has shown that no correlation was noted between radon concentrations, climatic parameters and trace element.     

Integrated geophysics and soil gas profiles as a tool to characterize active faults: the Amer fault example (Pyrenees, NE Spain)

The combined use of geophysical and soil gas composition exploration methods allows to rapidly obtain at relative low cost information that might be related to seismic activity conditions. In this study, we carried out geochemical soil gas sampling (²²²Rn, ²²⁰Rn and CO₂), electrical resistivity tomography and seismic refraction profiles in two selected zones near the town of Amer in the Spanish Pyrenees, where the presence of recent fractures is evident in the field. Data analysis clearly reveals anomalous values for each gas at specific positions along the electrical imaging transects. Geomorphologic and hydrogeologic data and the integration of geophysical data and soil gas measurements indicate that: (1) endogene gases radon (²²²Rn) and carbon dioxide (CO₂) are released from the meta-sedimentary basement rocks across the main fractured zones with higher permeability values, while lower Cenozoic detrital sedimentary formations act as an impervious boundary; (2) sites with highest radon concentrations (52?kBq?m^?3) coincide with the zones in the Amer fault showing more recent geomorphic evidence of activity, and more specifically with those areas covered by thinner surficial formations; (3) the lowest ²²²Rn values (0.2?C0.4?kBq?m^?3) were recorded just on the master active fault plane. This pattern could be explained by a dilution effect resulting from high rates of soil CO₂ efflux (267?g?m^?2?day^?1); (4) soil thoron (²²⁰Rn) activity is maximum (143?kBq?m^?3) in areas with high surficial fracturing; (5) groundwater pumping may cause important distortions in the natural flow dynamics and in the measured concentrations of gases. The agreement between the different data (geochemical, geophysical, and hydrogeological) and field observations (geology and geomorphology) leads us to propose a preliminary tectonic-gravitational model for the study area.     

Collection of radon decay products — a uranium exploration technique

The spontaneous deposition of short-lived radon decay products onto solid surfaces (“collectors”) provides the basis for a simple and efficient way of prospecting for uranium. The alpha activity of two of the decay products, ²¹⁸Po and ²¹⁴Po, can be measured by conventional counting techniques following the exposure of a collector to a radon source. Laboratory studies have shown: (a) radon decay products can be collected on a wide variety of materials; (b) the number of radon decay products increases with the collector surface area; (c) a negative charge applied to the collectors enhances the number of decay products collected; (d) the shape of the collectors is relatively unimportant; and (e) reproducibility is about ± 5% of the measured value.Field tests on known uranium anomalies involved suspending collectors for an overnight exposure, in either covered holes or inverted containers buried in soil. Subsequent removal of the collectors was immediately followed by counting the alpha activity. Anomalies were readily detected at three different test sites. Replicate measurements at selected sites both on an hour-to-hour and on a day-to-day basis showed remarkably good agreement. Some anomalies were also outlined using activity measurements from collectors suspended above soil aliquots in sealed containers.Because the half-lives of two of the thoron (²²⁰Rn) decay products are much longer than those of the radon (²²²Rn) decay products, a thoron correction can be applied to the original activity measured from the collectors, thus discriminating against thoron in thorium-rich terrains.The counting of radon decay products deposited onto collectors is an effective method for delineating radon anomalies in uranium exploration. The field techniques are simple to apply, and results are available after very short exposure times (about 18 hours) and after short counting intervals (5 minutes).     

Mechanism of transport of U-Th series radioisotopes from solids into ground water

A set of experiments conducted to understand the mechanism responsible for release of large quantities of ²²²Rn from solids into ground water reveals that a major part of Rn moving into the intergranular water comes from within the grains (solids), not by recoil from the outer surface. We have deduced that the solids we have studied are permeated, to a varying degree, with pores having very large wall area but very small volume, i.e., having width of opening of the order of 10–20 nm. Recoil from the walls of these openings introduces Rn and other isotopes into the water contained in these openings (nanopores). Radon, an inert gas, is able to diffuse from nanopore water into the intergranular water in substantial quantities. In contrast, nongaseous isotopes of the U-Th series recoiled into the nanopore water in comparable quantities are adsorbed within the nanopores on the large internal area available there. Further, it appears that a large part of the inventory of long-lived isotopes produced by decay of radon in intergranular water is slowly transported to and adsorbed on the large internal area available in the nanopores. Thus, most of the inventory of all long-lived non-gaseous emanation isotopes exist in an adsorbed state in the nanopores, while radon is located in intergranular water.     

Controls on pore-fluid concentration of 4He and 222Rn and the calculation of 4He/222Rn ages

Controls governing the production of ⁴He and ²²²Rn in the solid phase as well as parameters and processes contributing to their transport into the pore fluid are discussed. ²²²Rn activity is used to quantify the uranium sources for ⁴He and the result is a simplified pore-fluid age equation which is virtually independent of the porosity, the water/rock ratio, the rock density and the uranium concentration, but does require a Th/U estimate. The crucial parameter is the ratio of the release factors for the two species, /GL_Rn//GL_He, which is discussed in terms of three possible release mechanisms: (1) recoil; (2) recoil followed by diffusion; and (3) weathering release of accumulated ⁴He. It was found that /GL_Rn//GL_He can vary over several orders of magnitude, but can be expressed in terms of the effective grain size r, and the diffusive half-length for ²²²Rn decay, r_e.⁴He measurements are used to “date” gases from known gas fields and the agreement with the assumed source-rock age is good. Application of ⁴He/ ²²²Rn measurements to continental freshwater springs indicates that the weathering release of accumulated ⁴He dominates the input and results in a large overestimate of groundwater age. Measurement in the Lardarello geothermal field indicates that the ⁴He/²²²Rn method can indicate relative transport direction. Other possible applications in various geochemical fields are suggested.     

Controls on pore-fluid concentration of He and Rn and the calculation of He/Rn ages

Controls governing the production of ⁴He and ²²²Rn in the solid phase as well as parameters and processes contributing to their transport into the pore fluid are discussed. ²²²Rn activity is used to quantify the uranium sources for ⁴He and the result is a simplified pore-fluid age equation which is virtually independent of the porosity, the water/rock ratio, the rock density and the uranium concentration, but does require a Th/U estimate. The crucial parameter is the ratio of the release factors for the two species, /GL_Rn//GL_He, which is discussed in terms of three possible release mechanisms: (1) recoil; (2) recoil followed by diffusion; and (3) weathering release of accumulated ⁴He. It was found that /GL_Rn//GL_He can vary over several orders of magnitude, but can be expressed in terms of the effective grain size r, and the diffusive half-length for ²²²Rn decay, r_e.⁴He measurements are used to “date” gases from known gas fields and the agreement with the assumed source-rock age is good. Application of ⁴He/ ²²²Rn measurements to continental freshwater springs indicates that the weathering release of accumulated ⁴He dominates the input and results in a large overestimate of groundwater age. Measurement in the Lardarello geothermal field indicates that the ⁴He/²²²Rn method can indicate relative transport direction. Other possible applications in various geochemical fields are suggested.     

Soil radon in winter months under snowpack in Hokkaido, Japan

Soil radon (²²²Rn) has been monitored during winter months under cool-temperate deciduous stands of different surface geology in Tomakomai and in Sapporo, Hokkaido, Japan. Radon level was lower in Tomakomai of immature soil of porous volcanic ash emitted from an active volcano (Mt. Tarumae), compared with those in Sapporo of alluvial sediments. In Tomakomai, mean value of the ²²²Rn activity concentration was higher in winter (570 Bq m^?3) than in summer (350 Bq m^?3) at a depth of 1 m, which is consistent with the results in cold and dry winter reported in the literature. In contrast, soil radon decreasing with decreasing soil temperature from mid-September (5.0 kBq m^?3) remained low (2.6 kBq m^?3) under persistent snow in Sapporo, which had already been observed in the same location. Measurements of the activity concentrations of ²²²Rn in snow and in snow air as well as in soil air indicate that the small amount of ²²²Rn is released from the ground surface to the overlying snowpack with a ²²²Rn flux density of 0.4 mBq m^?2 s^?1 under thick snow cover in Sapporo.     

Statistical analysis of the radon-222 potential of rocks in Virginia,U.S.A.

More than 3,200 indoor radon-222 (²²²Rn) measurements were made seasonally in an area of about 1,000 square kilometers of the Coastal Plain and Piedmont physiographic provinces in Virginia, U.S.A. Results of these measurements indicate that some geological units are associated, on the average, with twice as much indoor²²²Rn as other geological units, and that indoor²²²Rn varies seasonally. The Kruskal-Wallis test was used to test whether indoor²²²Rn concentrations for data gathered over the winter and summer seasons differ significantly by rock unit. The tests concluded that indoor²²²Rn concentrations for different rock units were not equal at the 5-percent significance level. The rocks associated with the highest median indoor²²²Rn concentration are specific rocks in the Mesozoic Culpeper basin, including shale and siltstone units with Jurassic diabase intrusives, and mica schists in the Piedmont physiographic province. The pre-Triassic Peters Creek Schist has the highest ranking in terms of indoor²²²Rn concentration. The rocks associated with the lowest indoor²²²Rn concentrations include coastal plain sediments, the Occoquan Granite, Falls Church Tonalite, Piney Branch Mafic and Ultramafic complex, and unnamed mafic and ultramafic inclusions, respectively. The rocks have been ranked according to observed²²²Rn concentration by transforming the average rank of indoor²²²Rn concentrations to z scores.     

Radioactive elements in natural gas: a case study on distribution of gaseous 222radon and its origin mechanism

As natural gas becomes increasingly important in our daily life, studies have been carried out on trace elements such as mercury and arsenic within it. Other than those, the existence of radioactive gaseous radon from the combustion of natural gas indoors can cause severe diseases and damages to body organs, putting a hazardous impact on human health. At the same time, the radon can also corrode gas production and transportation equipment. A review of the literature on radon concentrations in natural gas produced from gas reservoirs in China and other countries have been studied. Radon is a decay product from ²³⁸U, which is closely related to the accumulation and migration of organic matter during diagenesis. Gas recovered from reservoirs with higher than average natural ²³⁸U contains higher than average levels of ²²²Rn. Massive fault systems and fracture zones appear to play a significant role in radon concentrations in natural gas.     

The decay products of 222rn in etched track radon detection

Precipitation of decay products of atmospheric ²²²Rn in small containers and the effects of their precipitation on alpha-particle-track-measurements of radon activities were studied. From decay curves of decay product activities on surfaces exposed to radon-containing air the ratios ²¹⁴Pb/²¹⁸Po (=r) in the precipitates were determined. From r average ages of precipitating decay products were calculated. Average ages and r were low, indicating rapid precipitation of decay products, and decreased with container size. Activities on exposed surfaces were approximately those expected if decay products precipitate completely and uniformly on the internal surfaces of containers.Decay products precipitated on foils of correct thickness covering cellulose nitrate (CN) track detectors produce tracks. Therefore track densities produced by given radon activities are increased by such covers to extents predictable from the decay product activities on the overlays. Tracks formed under overlays may etch to larger, more vertical-sided, more easily counted forms. When suspended, uncovered, in air at distances from surfaces greater than the ranges of the alpha particles, three types of CN recorded tracks at the rate (ρ′) of 0.12 tracks cm^?2 (pCi Rn)^?1 1^?1 hr^?1 as predicted by a theoretical expression. In small containers (ρ′) varied with position and container size.     

Tracing of residual multiple DNAPL sources in the subsurface using 222Rn as a natural tracer at an industrial complex in Wonju, Korea

Depth-discrete tracing of residual dense non-aqueous phase liquid (DNAPL) sources in the subsurface is of great importance in making decisions related to contaminated groundwater remediation. Temporal variations in the natural tracer ²²²Rn and contaminant concentrations in groundwater contaminated with multiple chlorinated contaminants, such as trichloroethene, carbon tetrachloride, and chloroform, were examined to trace residual multiple DNAPL contaminants at an industrial complex in Wonju, Korea. The ²²²Rn activities and multiple DNAPL concentrations in the groundwater fluctuated irregularly according to the groundwater recharge. The natural tracer ²²²Rn in groundwater present in the soil layer, originating from the underlying crystalline biotite granite, had a wide range from 29,000 to 179,000 Bq/m³, and total concentrations of chlorinated solvents ranged from 0.06 to 17.77 mg/l, indicating the ambiguous results of ²²²Rn for tracing the residual DNAPL sources. In this paper, a method is presented to locate zones with a high probability of containing depth-discrete residual multiple DNAPL sources using ²²²Rn and considering relative contaminant concentrations. The results demonstrate that the combination of the ²²²Rn activities as a natural tracer and the relative contaminant concentrations is able to be used as a useful tool for tracing residual DNAPLs.     

Measurement of soil-gas radon in some areas of northern Rajasthan,India

The health hazards of the radioactive gas radon on general public are well known. In order to understand the level and distribution of ²²²Rn concentrations in soil-gas in Sri Ganganagar district of Rajasthan, a ²²²Rn survey was carried out for the first time using RAD7, an electronic radon detector manufactured by Durridge Company (USA), at different locations covering a total area of 10,978 km ², having a population of approximately 20 lakh. The measurement of ²²²Rn concentration in soil-gas was carried out at four different depths (10, 40, 70, and 100 cm). The radon concentration in soil-gas for 10, 40, 70, and 100 cm depths ranged from 0.09–4.25, 0.15–6.30, 0.50–9.18, and 0.72–10.40 kBq m ^?3, respectively. The minimum value of radon concentration is observed in 33 GB village at 10 cm depth and maximum for Mohanpura village at 100 cm depth. As expected, our data show an increase of soil-gas radon concentration levels with depth. The present results are compared with the available radon data from other studies.     

Uranium prospecting with Rn in frozen terrain

Published reports show that ²²²Rn contents of soil gas can increase under snow-covered or frozen soils. By utilizing these observations and results of field tests described here, it can be stated that U prospecting with ²²²Rn in frozen terrain is practicable.Rn profiles in frozen and snow-covered soils over U mineralization in the Bancroft area of Ontario outlined known radioactive zones more clearly than did scintillometer profiles.Tests in Gatineau Park, Quebec, in the proximity of a radioactive pegmatite dike showed that lake ice acts as a restrictive barrier to Rn movement from lake waters beneath. Water samples, collected and allowed to freeze in plastic bottles, retained dissolved Rn quite effectively thus permitting sample collection and storage under the most severe winter conditions. Rn sampling of through-ice lake waters is therefore a feasible prospecting tool.Samples of spring run-off (snow-melt) waters and slushy snow collected from within a known weakly radioactive zone near South March, Ontario, were shown to contain less Rn than found in the same stream waters in the summer. No pronounced Rn degassing event of frozen soils was apparent early in the spring thaw in percolating run-off waters draining from the zone. The usefulness of spring thaw hydrogeochemistry using Rn is discussed.     

The decay products of rn in etched track radon detection

Precipitation of decay products of atmospheric ²²²Rn in small containers and the effects of their precipitation on alpha-particle-track-measurements of radon activities were studied. From decay curves of decay product activities on surfaces exposed to radon-containing air the ratios ²¹⁴Pb/²¹⁸Po (=r) in the precipitates were determined. From r average ages of precipitating decay products were calculated. Average ages and r were low, indicating rapid precipitation of decay products, and decreased with container size. Activities on exposed surfaces were approximately those expected if decay products precipitate completely and uniformly on the internal surfaces of containers.Decay products precipitated on foils of correct thickness covering cellulose nitrate (CN) track detectors produce tracks. Therefore track densities produced by given radon activities are increased by such covers to extents predictable from the decay product activities on the overlays. Tracks formed under overlays may etch to larger, more vertical-sided, more easily counted forms. When suspended, uncovered, in air at distances from surfaces greater than the ranges of the alpha particles, three types of CN recorded tracks at the rate (ρ′) of 0.12 tracks cm⁻² (pCi Rn)⁻¹ 1⁻¹ hr⁻¹ as predicted by a theoretical expression. In small containers (ρ′) varied with position and container size.