The solar niobium abundance

The solar Nb abundance is derived from five Nb i and ten Nb ii lines in the photospheric spectrum. Equivalent widths are obtained from measurements on spectra recorded at Kitt Peak National Observatory. Synthetic spectrum calculations gave abundances of 2.23 and 2.08 from neutral and ionized lines respectively in the logarithmic A _H = 12.00 scale. This gives an average abundance value of A _Nb = 2.13 ± 0.10.     

Solar abundance of praseodymium

16 lines of Pr ii possibly present in the solar photospheric spectrum have been studied. When including hyperfine structure in synthetic calculations, investigations of 9 lines result in an abundance A _Pr = 0.71 ± 0.08 in the log A _H = 12.00 scale.     

The solar photospheric abundance of zirconium

Zirconium (Zr), together with strontium and yttrium, is an important element in the understanding of the Galactic nucleosynthesis. In fact, the triad Sr‐Y‐Zr constitutes the first peak of s‐process elements. Despite its general relevance not many studies of the solar abundance of Zr were conducted. We derive the zirconium abundance in the solar photosphere with the same CO⁵BOLD hydrodynamical model of the solar atmosphere that we previously used to investigate the abundances of C‐N‐O. We review the zirconium lines available in the observed solar spectra and select a sample of lines to determine the zirconium abundance, considering lines of neutral and singly ionised zirconium. We apply different line profile fitting strategies for a reliable analysis of Zr lines that are blended by lines of other elements. The abundance obtained from lines of neutral zirconium is very uncertain because these lines are commonly blended and weak in the solar spectrum. However, we believe that some lines of ionised zirconium are reliable abundance indicators. Restricting the set to Zr II lines, from the CO⁵BOLD 3D model atmosphere we derive A (Zr) = 2.62 ± 0.06, where the quoted error is the RMS line‐to‐line scatter (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The solar photospheric abundance of iron

A new value of the solar photospheric abundance of iron, independent of line-shape parameters, is derived. Our analysis is based on a study of 40 weak infrared lines (0.85<λ<2.5 μ) for which theoretical oscillator strengths (calculated with configuration interactions taken into account) have recently been computed by Kurucz (1974). The abundance obtained, A _Fe = 7.57±0.11 (in the usual scale where log N _H = 12.00) is in agreement with the ‘high’ solar values recently reported in the literature and with the meteoritic abundance.     

NLTE formation of the solar spectrum of silicon: Abundance of silicon in a three-dimensional model of the solar atmosphere

We investigated the NLTE formation of the solar spectrum of neutral silicon using 3D hydrodynamic model of the solar atmosphere and realistic atomic model. We show that, within the intergranular region, combined action of the deficit in the source function and excess in opacity due to the overpopulation of the lower Si I levels leads to a considerably higher increase in the central depth D and equivalent width W of these lines as compared to the granules. We have fitted silicon abundances A _W and A _D from the equivalent widths W and central depths D for 65 Si I lines using a 3D model. We show that a total error in the calculated silicon abundance due to neglecting NLTE and 3D effects, as well as the uncertainty in the van der Waals broadening constant γ₆, turns out to be ?0.1 dex. Using a semiclassical theory by Anstee, Barklem, and O’Mara in calculating γ₆ yields a fair coincidence between the values of A _W and A _D , because the average difference A _W — A _D does not exceed 0.01 dex for both NLTE and LTE. When applying the Unsold’s approximation in calculating γ₆ with an enhancement factor E = 1.5, the abundances A _W and A _D proved to be in disagreement with one another. We analyzed the “solar” oscillator strength scale by Gurtovenko and Kostik, as well as the experimental one by Garz and Becker et al. We show that using “solar” oscillator strengths log gfw leads to a minimum trend with the equivalent widths for NLTE abundances A _W , A _D , their difference A _W — A _D , and standard deviations. The NLTE abundance of silicon obtained using solar oscillator strength scale by Gurtovenko and Kostik is A _W ^NTLE = 7.549 ± 0.016. This value is in good agreement with the value of silicon abundance recommended by Grevesse and Sauval for the CI chondrite meteorites.     

The solar hafnium abundance

The solar Hf abundance is determined using nine Hf ii lines in the photospheric spectrum. The transition probabilities were obtained from lifetime measurements performed by the beam-foil technique. The abundance derived from synthetic spectrum calculations is A(Hf) = 0.88 ± 0.08 in the logarithmic A(H) = 12.00 scale.     

The solar abundance of germanium

The solar abundance of germanium, deduced from two relatively unblended Ge i lines, λ3039.06 and λ3269.50 is found to be log N(Ge) = 3.50 ± 0.05 on the scale log N(H) = 12.00 in good agreement with Cameron's recent solar system abundance logN(Ge) = 3.56 (on assumption log N(Si) = 7.50).     

One- and multi-component models of the upper photosphere based on molecular spectra

Non-LTE synthetic spectra derived from a detailed analysis of the formation of the CN (0, 0) λ13883 Å spectrum are compared with center-limb photoelectric spectra taken at Kitt Peak National Observatory. Kitt Peak National Observatory is operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation. Significant non-LTE effects are found and the Kurucz, Altrock-Cannon, Mount-Linsky II, and HSRA models are compared. We derive a solar carbon abundance of A _c =8.30±0.10 for the Mount-Linsky model and A _c =8.40±0.10 for the Altrock-Cannon model, compared to the HSRA value of A _c =8.55±0.10, assuming a nitrogen abundance of logA _N=7.93. In addition we specify the regions of formation for the CN(0, 0) 3883.35 Å bandhead at disc center and limb.     

One- and multi-component models of the upper photosphere based on molecular spectra

We have obtained center-to-limb photoelectric spectra of the CN(1,1) B-X bandhead region λ3868–3872 Å at Kitt Peak National Observatory. From these spectra and a detailed analysis of the formation of the CN (1, 1) spectrum we derive a best-fit upper photospheric model differing from the HSRA which is consistent with our previous CN(0, 0) λ3883 spectra. We derive a solar carbon abundance of log A _c = 8.30 ± 0.10 compared to the HSRA value of log A _c = 8.55 ± 0.10. In addition we specify the regions of formation for the CN(0, 0) λ3883.35 and CN(1, 1) λ 3871.38 bandheads at disc center and limb.     

NLTE formation of the solar silicon spectrum: Silicon abundance in one-dimensional models of the solar atmosphere

NLTE formation of the silicon spectrum is studied in three one-dimensional semiempirical models of the solar atmosphere: HOLMUL, MACKKL, and VAL,C. The NLTE silicon abundance calculated from 65 Si I lines of different strengths is almost independent of the excitation potentials, wavelengths, and equivalent widths if the van der Waals damping constant ??₆ is calculated using the Unsold approximation with an enhancement factor E = 1.5. The NLTE silicon abundance range from 7.547 ± 0.012 (HOLMUL) to 7.582 ± 0.013 (VAL,C). The use of the Anstee-Barklem-O??Mara (ABO) theory to calculate ??₆ leads to a decrease in the silicon abundance with an increase in the equivalent widths. It is found that the NLTE silicon abundance corrections are, on average, ?0.05 dex. The errors in the NTLE abundance due to uncertainties in the cross sections of photoionization and inelastic collisions with electrons and hydrogen atoms are 0.02 dex or less. It is shown that the use of the shifted Gurtovenko-Kostyk ??solar?? oscillator-strength scale instead of the experimental scale proposed by Becker et al. gives almost the same silicon abundance.     

NLTE formation of the resonance Ba II line λ 455.4 nm in the solar atmosphere

We consider the NLTE formation of the resonance Ba II line λ 455.4 nm in the solar spectrum for three one-dimensional and one three-dimensional hydrodynamic models of the quiet solar atmosphere. The sensitivity of the line to atomic parameters, microturbulent and macroturbulent velocities, as well as to oscillator strength and barium abundance uncertainties was examined. The wings of the barium line are shown to be most sensitive to the van der Waals broadening constant. Another important parameter is the barium abundance. Our NLTE estimate of the solar barium abundance (A _Ba = 2.16) derived with allowance made for the nonuniform solar atmosphere structure is in good agreement with earlier results. The influence of granular convective motions on the line profile shape was studied, and the profiles formed in granules and in intergranular lanes are shown to be asymmetric and differently shaped. We demonstrate that the theoretical profiles match well the observed ones when the NLTE effects and the granular structure are taken into account.     

Influence of departures from LTE on oxygen abundance determination in the atmospheres of A-K stars

We have performed non-LTE calculations for O I with a multilevel model atom using currently available atomic data for a set of parameters corresponding to stars of spectral types from A to K. Departures from LTE lead to a strengthening of O I lines, and the difference between the non-LTE and LTE abundances (non-LTE correction) is negative. The non-LTE correction does not exceed 0.05 dex in absolute value for visible O I lines for main-sequence stars in the entire temperature range. For the infrared O I 7771 Å line, the non-LTE correction can reach ?1.9 dex. The departures from LTE are enhanced with increasing temperature and decreasing surface gravity. We have derived the oxygen abundance for three A-type mainsequence stars with reliably determined parameters (Vega, Sirius, HD 32115). For each of the stars, allowance for the departures from LTE leads to a decrease in the difference between the abundances from infrared and visible lines, for example, for Vega from 1.17 dex in LTE to 0.14 dex when abandoning LTE. In the case of Procyon and the Sun, inelastic collisions with HI affect the statistical equilibrium of OI, and agreement between the abundances from different lines is achieved when using Drawin’s classical formalism. Based on the O I 6300, 6158, 7771-5, and 8446 Å lines of the solar spectrum, we have derived the mean oxygen abundance log ? = 8.74 ± 0.05 using a classical plane-parallel model solar atmosphere and log ? _+3D = 8.78 ± 0.03 by applying the 3D corrections taken from the literature.     

The solar abundance of thulium

The solar spectrum contains one relatively unblended line λ 3131.258 Tm ii which yields a thulium abundance of log N(Tm)/N(H) + 12 = {Tm} = 0.80 ± 0.10, with the Corliss and Bozman f-value. A recent beam-foil experiment suggests that the thulium abundance may be reduced to {Tm} = 0.30.     

Estimates of methane and ammonia abundance in the Jovian atmosphere with allowance for scattering in the clouds

Results of photoelectric measurements of the intensity in CH₄ 5430, 6190, and 7250 Å absorption bands, CH₄ absorption lines in the 3ν₃ band, and the NH₃ 6457.1 Å line are examined from the point of view of a model which takes into account the role of multiple scattering inside a homogeneous semi-infinite cloud layer in the formation of absorption components in the Jovian spectrum. Introduced are a number of simple ratios between depths of lines and bands and the parameters which characterize the properties of the cloud layer and the atmosphere above the clouds for occurrence of the Henyey-Greenstein scattering phase function at various degrees of asymmetry in g. The CH₄ content inside the cloud layer is determined as an equivalent thickness on the mean free path between scattering events. The latter was found to be equal to A_L ? 10 ± 2 m-amagat at g = 0.75 or A_L ? 20 ± 3 m-amagat at g = 0.5 along all the above-mentioned CH₄ absorption bands. For NH₃ it is A_L ? 31 ± 4 cm-amagat at g = 0.75 and A_L ? 62 ± 8 cm-amagat at g = 0.5.The weakening of the CH₄ absorption bands toward the edges of the Jovian disc requires a volume scattering coefficient in the cloud layer of σ_a ～ 10^?6 cm^?1. The mean specific abundance of NH₃ obtained within the cloud layer does not contradict the calculated abundance of saturated gaseous ammonia.     

Lithium abundance in the sunspot from the observational data of August 1981

A spectrum of a sunspot in the range of the Li I ?? 670.8 nm line and some lines of Ca I, Ti I, Al I, and Na I was measured. Observations were carried out with the TST-2 telescope of the Crimean astrophysical observatory on August 21, 1981. A model of the spot was calculated from the observed profiles of the Ca I, Ti I, Al I, and Na I lines. From the calculated model and the observed profile of the Li I ?? 670.8 nm line, the lithium abundance was estimated as log(N _Li) = 0.78 (in the scale of logA(H)= 12.0).     

Helium abundance variations in the solar wind

Helium abundance variations in the solar wind have been studied using data obtained with Los Alamos plasma instrumentation on IMP 6, 7, and 8 from 1971 through 1978. For the first time, average flow characteristics have been determined as a function of helium abundance, A(He). Low and average values of A(He) are each preferentially identified with a different characteristic plasma ‘state’ these correspond to what have previously been recognized as the signatures of interplanetary magnetic field polarity reversals and high speed streams, respectively. Helium enhancements at 1 AU also can be identified with a characteristic plasma state, which includes high magnetic field intensity and low proton temperature. This is further evidence that such enhancements are a signal of coronal transient mass ejections. Long-term averages of A(He) at least partially reflect the relative frequency with which coronal streamers, holes, and transients extend their influence into the ecliptic plane at 1 AU. As a result, there is a real and pronounced solar cycle variation of solar wind H(He).     

Forbidden Ca ii in the Sun unmasked by way of Venus

Eleven high-dispersion spectra of Venus, taken with blue Doppler shifts have enabled us to unmask the 7323.88 Å forbidden line of Ca ii from terrestrial absorption. We obtain an equivalent width of 7.4±0.4 mÅ for this line in integrated sunlight. Our value of W _λ is smaller than previous values and much more accurate. The HSRA solar model gives a solar calcium abundance of A _Ca = 6.21.     

The solar abundance of calcium and collision broadening of Ca i- and Ca ii-Fraunhofer lines by hydrogen

An abundance analysis of the solar calcium spectrum is carried out using 46 lines with known f-values in the visible and near infrared spectral region. Resonance, forbidden and autoionizing lines are included. The solar abundance of calcium resulting from the 25 weaker, nearly damping-independent lines only is log _Ca=6.36±0.07, on the scale log H = 12. The great variety of transitions involved in the solar calcium spectrum, ranging from 0 eV lines of CaI to 7.5 eV lines of CaII and including autoionizing lines, are in reasonable agreement (Figure 1b). Therefore notable non-LTE effects on their equivalent widths can be excluded.Together with the sodium abundance log _Na = 6.30 determined earlier, the solar abundance ratio Ca/Na = 1.15 is obtained with an accuracy of 10%. Comparison with meteorites (carbonaceous chondrites I) shows that solar and meteoritic ratio agree within these limits.The line broadening by collisions with hydrogen atoms is determined empirically from a comparison of weak and strong Fraunhofer lines of CaI and CaII, thereby using the solar atmosphere as an absorption tube of comparatively well-known physical state. The damping half-widths H turn out to be larger than predicted from pure van der Waals interaction, the average enhancement factor being 3.0 for CaI and 1.7 for CaII, independent of term properties to a first approximation. Regardless of the reason for this enhancement — inaccurate van der Waals theory or predominance of repulsive interaction these results can be used in the spectroscopy of other stars.     

The potassium abundance in the solar photosphere

High precision center-limb spectrograms of the K i resonance doublet line at λ 7699 Å were used to study the line formation and to determine the abundance of potassium in the solar atmosphere. The LTE assumption is not valid for these lines. Synthetic profiles computed in NLTE reproduce very well the observed center-limb line behaviour and yield log? _K = 5.14±0.10 for the solar abundance of potassium (on the scale of log? _H = 12 for Hydrogen).     

The photospheric barium spectrum: Solar abundance and collision broadening of Baii lines by hydrogen

A study of the solar Ba ii spectrum leads to a solar abundance of barium of log ba = = 2.11±0.12, on the scale log h = 12. The observed asymmetry of the resonance line 4554 is consistent with an isotopic abundance ratio equal to the terrestrial one. The meteoritic Ba/Si abundance ratio found in carbonaceous chondrites appears to exceed the solar ratio by 0.1 to 0.2 dex (Section 5).The broadening by collisions with hydrogen atoms is determined from the solar spectrum (Section 4). Damping half-widths, h, of the three stronger Ba ii lines turn out to be larger by a factor of about 3.0 than predicted from pure van der Waals interaction of dipoles. Departures from LTE appear to be present in the cores of the resonance lines and of the lines arising from the metastable 5D levels (Section 6). The equivalent widths, however, remain practically unaffected.Equivalent widths of neutral barium lines are predicted and some new identifications of photospheric Ba i lines are suggested (Section 7).