Changes in the importance of lotic and littoral diatoms in a high arctic lake over the last 191 years

Both habitat preferences and community associations for some of the most prominent pennate taxa in our profile were established using samples from the modern lake and its watershed. Habitat preferences were used to establish a simple indicator for the relative contribution of lotic communities in this lake (Lotic Index) and indicator taxa for both littoral (Achnanthes spp. and Cymbella spp.) and lotic (Hannaea arcus and Meridion circulare) communities. When profiled, the Lotic Index showed a clear positive relationship to sedimentation rate as recorded in the varves, while profiles of littoral indicator taxa show the opposite trends. It seems likely that the patterns we observed in the Lotic Index are related to changes in runoff. Apparently, there was a period of declining runoff beginning ca. two centuries ago and ending in the late 1800's. This was followed by increasing runoff lasting until the middle of the 20th century. A brief minimum occurred in ca. 1970 followed by a recovery by ca. 1980.A strong positive relationship was also found between the dates of major turbidites, exceptionally thick varves and the concentration of valves in the sediment. It is possible that many of the thicker varves in the profiles contain littoral material transported to the site of deposition by turbid interflows and underflows. For this reason, the concentration of valves in the sediment in our cores appears to be a proxy for sediment deposition from turbidity currents.This is the sixth in a series of papers published in this issue on the Taconite Inlet Lakes project. These papers were collected by Dr R. S. Bradley.     

The palaeolimnology of Lake Fidler, a meromictic lake in south-west Tasmania and the significance of recent human impact

Three meromictic lakes in the World Heritage Area of south-west Tasmania possess unusual microbiological communities. Their meromixis is maintained by periodic incursions of brackish water from the nearby Gordon River which, in its lower reaches, is a salt-wedge estuary. In 1977 the construction of a dam in the middle reaches of the river restricted penetration of the salt-wedge and meromixis rapidly declined in all three lakes. A palaeolimnological study was carried out on one of the lakes, Lake Fidler, firstly to determine the history of meromixis and its associated microbiological communities, and secondly to assess whether the recent and rapid decline of meromixis is inconsistent with natural rates of development of the Gordon River meromictic lakes. One part of this study included the analysis of the stratigraphy of fossil diatoms from a 17-metre sediment core dating back 8000 yrs. Detrended Correspondence Analysis and Analog Matching were used to compare diatom species assemblages in core samples with diatom samples from a reference dataset consisting of a selection of lake and river sites in the lower Gordon River valley. Five distinct stratigraphic zones were identified in the core. These zones indicated specific stages in the development of the Gordon River lakes from river backwaters to ectogenically-maintained meromictic lakes which will, finally, become terrestrialised by encroaching rainforest. The onset of a stratified water column was identified by the emergence of a dominant freshwater algal flora which suggested that the lake had developed a mixolimnion and become meromictic ca. 2070 ± 50 ¹⁴C yrs ago. In the context of this long history of meromixis, the rapid demise in meromictic stability following construction of the dam is judged to be inconsistent with natural rates of development. The palaeolimnological studies, of which this paper is one part, prompt recommendations for a management strategy to prevent the further decay of these meromictic lakes in the World Heritage Area.     

Reconstructing past eutrophication trends from diatoms and biogenic silica in the sediment and the pelagic zone of Lake Constance, Germany

In Lake Constance, phosphorus concentrations and the seasonal development of phytoplankton communities in water samples from the pelagic zone were regularly recorded since the 1950's. Before the 1950's, there were occasional investigations of plankton communities since 1896. We compared these data with the sedimentary record in two sediment cores. Then, the eutrophication history of Lake Constance was inferred from diatoms. The record of biogenic silica in the cores is discussed with respect to diatom biomass increase.Diatom assemblages in the sediment cores precisely reflected the pelagic diatom development for the period 1971--1992. Both sediment cores and the water samples have a high interannual variability of diatom assemblages. Below a sediment depth of 27 cm (AD 1920), more than 50% of the diatoms were partly corroded, and we limited the reconstruction of trophic state changes to the interval of 1920--1993. Oligotrophic conditions of Lake Constance were indicated by the dominance of various Cyclotella taxa from 1920 to 1940. Since 1939/1940, increasing abundance of it Tabellaria fenestrata showed oligotrophic to mesotrophic conditions. Between 1953 and 1956, increasing Stephanodiscus hantzschii and disappearing Cyclotella indicated advanced eutrophication and total phosphorus values ranged between 8--10 mg m-3 during turnover in late winter. Further eutrophication was shown by disappearing T. fenestrata and increasing S. minutulus in 1963. Maximum TP concentrations of 87 mg m-3 occurred in 1979/80 and was accompanied by increasing abundances of Aulacoseira granulata. From 1986 to 1992, reoccurrence of Tabellaria fenestrata and Cyclotella indicate some recovery of Lake Constance.Biogenic silica and diatom abundances were similar among cores but indicate a 3--4 fold increase of diatom biomass only. This was far below the estimate of biomass increase from sedimentary pigment data (25 fold) and the estimate of phytoplankton data from the literature (70 fold).     

The late Quaternary development of three ancient tarns on southwestern Cumberland Peninsula, Baffin Island, Arctic Canada: paleolimnological evidence from diatoms and sediment chemistry

Sediment diatom and chemical analyses of cores from three poorly buffered extra-glacial lakes on the northeastern margin of the Canadian Shield (Cumberland Peninsula, Baffin Island) record interactions between aquatic and terrestrial spheres that were influenced by late Quaternary climatic conditions. Although differences exist between each of the lakes, notably with regards to the intensity of pre-Holocene catchment erosion and the timing of the onset of organic sedimentation, an underlying pattern of lake ontogeny, common to all three lakes, is identified. Although intensified watershed erosion characterized the Late Wisconsinan and Neoglacial cold periods, the lakes nonetheless remained viable ecosystems at these times. Sudden catchment stabilization during the late-glacial to earliest Holocene is associated with incipient organic sedimentation. Lake-water pH increased at this time, likely in response both longer base cation residence times as lake flushing rates decreased, and enhanced alkalinity production from sediment biogeochemical reactions. Subsequently, as the catchments remained stable during the productive early Holocene (c.9–7 ka BP), then gradually received a renewed increase of minerogenic sedimentation, the breakdown of sources of lake alkalinity resulted in natural acidification. Burial of cation-rich mineral sediments and the loss of permanent sedimentary sinks for the products of microbial reduction likely impeded within-lake alkalinity production, and catchment-derived base cations appeared ineffective in curtailing pH declines. The general nature of the Holocene development of these lakes is similar to that observed elsewhere on crystalline terrains, following deglaciation. Our data therefore suggest that catchment glaciation is not a necessary precursor for models of lake development characterized by initial base cation enrichment and subsequent gradual acidification.     

Calibration of diatoms along a nutrient gradient in Florida Everglades Water Conservation Area-2A, USA

The relationship between diatom taxa preserved in surface soils and environmental variables at 31 sites in Water Conservation Area 2A (WCA-2A) of the Florida Everglades was explored using multivariate analyses. Surface soils were collected along a phosphorus (P) gradient and analyzed for diatoms, total P, % nitrogen (N), %carbon (C), calcium (Ca), and biogenic silica (BSi). Phosphorus varied from 315-1781 g g^-1, and was not found to be correlated with the other geochemical variables. Canonical correspondence analysis (CCA) was used to examine which environmental variables correlated most closely with the distributions in diatom taxa. Canonical correspondence analysis with forward selection, constrained and partial CCA, and Monte Carlo permutation tests of significance show the most significant changes in diatom assemblages along the P gradient (p < 0.01), with additional species differences correlated with soil C, N, Ca, and BSi.Weighted-averaging (WA) regression and calibration models of diatom assemblages to P and BSi were developed. The diatom-based inference model for soil [P] had a high apparent r² (0.86) with RMSE_boot = 218 g g^-1. Indicator diatom species identified by assessing species WA optima and WA tolerance to [P], such as Nitzschia amphibia and N. palea for high [P] (~1300-1400 g^-1) and Achnanthes minutissima var. scotica and Mastogloia smithii for low [P] (~400-600 g g^-1), may be useful as monitoring tools for eutrophication in WCA-2A as well as other areas of the Everglades. Diatom assemblages analyzed by cluster analysis were related to location within WCA-2A, and dominant taxa within clusters are discussed in relation to the geochemical variables measured as well as hydrology and pH. Diversity of diatom assemblages and a Disturbance Index based on diatom data are discussed in relation to the historically P-limited Everglades ecosystem. Diatom assemblages should be very useful for reconstructions of [P] through time in the Florida Everglades, provided diatoms are well preserved in soil cores.     

Relationship of Mn-carbonates in varved lake-sediments to catchment vegetation in Big Watab Lake, MN, USA

Mn-carbonates are documented in the late-glacial varved sediments from Big Watab Lake, Minnesota, USA. The Mn-carbonate is authigenic and forms rims around contemporaneous epilimnetic calcite. Although such carbonates are found in minor amounts throughout the entire late-glacial sequence, significant quantities of Mn-carbonate are associated mainly with laminated intervals.Because of the suspected difference in isotopic fractionation between different carbonate minerals, the stable-isotopic compositions of bulk carbonate samples are used as a proxy for relative amounts of the Mn-carbonate in the sediment. High ¹⁸O and low ¹³C values are associated with abundant Mn-carbonates. Low ¹⁸O and high ¹³C values are associated with only minor concentrations of Mn-carbonates.The oxygen-18 record is correlated with fluctuations in the vegetation assemblage based on pollen spectra using a multiple regression model with backward elimination. The proposed link between the sedimentary archive and local vegetation is the mediation of advective mixing in the lake by forest composition. In this model, periods of forest closure resulted in a well-stratified water column that was anoxic at the sediment/water interface, permitting the formation of authigenic Mn-carbonates. Openings of Artemisia in the forest allowed wind shear to mix oxygen to depth, causing bioturbation of the laminations and preventing the formation of Mn-carbonate.     

Fossil diatoms and the mid to late holocene paleolimnology of Lake Turkana,Kenya: a reconnaissance study

A 12 m sediment core recovered from the south basin of Lake Turkana, northwestern Kenya, reveals four major diatom assemblages that span approximately 5450 to 1070 years BP based on AMS radiocarbon analyses. The oldest assemblage, Zone D (5450 to 4850 yr BP), is dominated by Melosira nyassensis and Stephanodiscus spp. and is interpreted to reflect higher lake levels, fresher water and more variable seasonal mixing of the water column than the modern lake. Melosira dominates the assemblage in Zone C (4850 to 3900 yr BP) with some Surirella engleri and Stephanodiscus. This assemblage indicates a continuation of relatively high lake levels and seasonal mixing of a stratified lake. The brief peak of Surirella, interpreted as benthic, suggests an episode of slightly lower lake level. Thalassiosira rudolfi and Surirella predominate since the beginning of Zone B (3900 to 1900 yr BP), reflecting a decrease in lake level and increase in water column salinity. Increasing dominance of Surirella in Zone A (1900 to 1070 yr BP) may suggest that the lake continued to decrease in depth. Salinity probably rose to levels comparable with the modern lake. These results are consistent with paleoclimatic interpretations based on carbonate abundance, lamination thickness, oxygen isotope and bulk geochemistry profiles from this core and cores recovered from the north basin. It extends the known paleolimnology beyond 4000 yr BP of the earlier research to 5450 yr BP and into the early to mid Holocene pluvial phase in northern intertropical east Africa.     

Variability in diatom and chrysophyte assemblages and inferred pH: paleolimnological studies of Big Moose Lake,New York,USA

We measured variability in the composition of diatom and chrysophyte assemblages, and the pH inferred from these assemblages, in sediment samples from Big Moose Lake, in the Adirondack Mountains of New York. Replicate samples were analyzed from (1) a single sediment core interval, (2) 12 different intervals from each of 3 separate cores, and (3) 10 widely spaced surface sediment samples (0–1 cm). The variability associated with sample preparation (subsampling, processing, and counting) was relatively small compared to between-core and within-lake variability. The relative abundances of the dominant diatom taxa varied to a greater extent than those of the chrysophyte scale assemblages. Standard deviations of pH inferences for multiple counts from the same sediment interval from diatom, chrysophyte, and diatom plus chrysophyte inference equations were 0.04 (n=8), 0.06 (n=32), and 0.06 (n=8) of a pH unit, respectively. Stratigraphic analysis of diatoms and chrysophytes from three widely spaced pelagic sediment cores provided a similar record of lake acidification trends, although with slight differences in temporal rates of change. Average standard deviations of pH inferences from diatom, chrysophyte and diatom plus chrysophyte inference equations for eight sediment intervals representing similar time periods but in different cores were 0.10, 0.20, and 0.09 pH unit, respectively. Our data support the assumption that a single sediment core can provide an accurate representation of historical change in a lake. The major sources of diatom variability in the surface sediments (i.e., top 1.0 cm) were (1) differences in diatom assemblage contributions from benthic and littoral sources, and (2) the rapid change in assemblage composition with sediment depth, which is characteristic of recently acidified lakes. Because scaled chrysophytes are exclusively planktonic, their spatial distribution in lake sediments is less variable than the diatom assemblages. Standard deviations of pH inferences for 10 widely spaced surface sediment samples from diatom, chrysophyte and diatom plus chrysophyte inference equations were 0.21, 0.09, and 0.16 of a pH unit, respectively.     

The CASPIA project: diatoms,salt lakes,and environmental change

The Climate and Salinity (CASPIA) Project is concerned with diatoms as environmental indicators in inland waters and their use in reconstructing salinity and major ion composition from fossil diatom assemblages in lake sediments. By comparing saline lake diatom floras from around the world the project aims to establish a common, harmonised approach to sample collection, diatom identification and nomenclature, and to develop techniques for numerical analysis and data storage.This is the first in a series of papers published in this issue on the paleolimnology of arid regions. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. R. Chivas served as guest editor for these papers.Palliser Triangle Global Change Project Contribution Number 19.     

The relationship between glacial activity and sediment production: evidence from a 4450-year varve record of neoglacial sedimentation in Hector Lake, Alberta, Canada

A 4450-year sequence of varves, spanning the entire Neoglacialinterval, has been recovered from Hector Lake, Alberta. The varve record is compared to records of regional glacial history toevaluate therelationship between alpine glacial activity and sediment production. Glacial controls on sediment production vary with the timescale considered. Long-term variations in sedimentation rate, of centuries to millennial duration, reflect changes in ice extent of the same timescale. Superimposed on these long-term changes is decadal-scale variability that is complexly related to upvalley ice extent. Over the short term, high sedimentation rates may be associated with glacier maximum stands, or with periods of glacier advance or recession. Overthe last millennium at least, highest sedimentation rates appear to have been associated with transitional periods, preceding or post-dating maximum ice stands, rather than with times of maximum ice extent.     

Assessment of freshwater diatoms as quantitative indicators of past climatic change in the Yukon and Northwest Territories,Canada

We identified, enumerated, and interpreted the diatom assemblages preserved in the surface sediments of 59 lakes located between Whitehorse in the Yukon and Tuktoyaktuk in the Northwest Territories (Canada). The lakes are distributed along a latitudinal gradient that includes several ecoclimatic zones. It also spans large gradients in limnological variables. Thus, the study lakes are ideal for environmental calibration of modern diatom assemblages. Canonical correspondence analysis, with forward selection and Monte Carlo permutation tests, showed that maximum lake depth and summer surface-water temperature were the two environmental variables that accounted for most of the variance in the diatom data. The concentrations of sodium and calcium were also important explanatory variables. Using weighted-averaging regression and calibration techniques, we developed a predictive statistical model to infer lake surface-water temperature, and we evaluated the feasibility of using diatoms as paleoclimate proxies. This model may be used to derive paleotemperature inferences from fossil diatom assemblages at appropriate sites in the western Canadian Arctic.     

The formation of biogeochemical laminations in Lake Bosumtwi, Ghana, and their usefulness as indicators of past environmental changes

The sediments from Lake Bosumtwi, Ghana contain a unique record of fine-scale (mm to sub-mm) laminations, which will provide a valuable annual chronometer for reconstructing paleoenvironmental changes in West Africa covering much of the last 1 Ma. Comparisons of laminae counts to independent ²¹⁰Pb dates and the rise in anthropogenic “bomb” radiocarbon support the interpretation of the laminations in the uppermost sediments as registering annual events. Radiocarbon dates on in-situ fish-bone collagen are in agreement with varve counts, further supporting the annual nature of our varve chronology. Over the instrumental period (1925–1999), dark-varve thickness measurements are correlated with local rainfall (r = 0.54) and appear able to resolve decadal-scale changes in precipitation. The relationship between varve thickness and rainfall provides support for our interpretation that dark-colored varve thickness records catchment runoff during the rainy season rather than dust flux during the dry season. Dark laminae alternate with organic and carbonate-rich light laminae formed during the fall period of enhanced productivity. Downcore, varves undergo significant microstratigraphic and geochemical variations, but retain the same pattern of alternating clastic and organic-rich laminae, providing support that the laminae may represent annual time markers for reconstructions of the deeper part of the record.     

Water and sediment chemistry of Lake Pumayum Co,South Tibet,China: implications for interpreting sediment carbonate

A combination of water and sediment chemistry was used to investigate carbonate production and preservation in Lake Pumayum Co (altitude 5,030 m a.s.l.), south Tibet, China. We compared the chemical composition of lake water in various parts of the lake with that of input rivers and found that the loss of Ca²⁺ results from calcite sedimentation induced by evaporation and biogenic precipitation. This is supported by evaporation data from the catchment and δ¹⁸O measurements on water. Results suggest that CaCO₃ is the predominant carbonate in this lake. There is a positive correlation in the sediments among concentrations of total inorganic carbon (TIC), Ca, total organic carbon (TOC), and total nitrogen, confirming that most carbonates in sediment are endogenic. The Jiaqu River is the largest inflow to Lake Pumayum Co and has a strong influence on both lake water chemistry and sediment composition. The river and lake bathymetry influence carbonate sedimentation by affecting water flow velocity and growing conditions for macrophytes. Different carbon contents and relationships between TIC and TOC in the two long cores from different depths in the lake reveal that hypolimnetic conditions also influence carbonate precipitation and preservation.     

Differences in the eutrophication dynamics of Ammersee and Starnberger See (Southern Germany), reflected by the diatom succession in varve-dated sediments

Diatom assemblages in the annually laminated sediments of two neighboring, pre-alpine lakes (Ammersee and Starnberger See, Southern Germany) were analyzed and compared year by year. Within both varve records of the last decades, the same 4-phase-succession of planktonic diatom species is preserved, consisting of 1. a dominance of Cyclotella species 2. assemblages of Fragilaria crotonensis, Asterionella formosa and Stephanodiscus minutulus 3. a mass bloom of Aulacoseira islandica, and 4. a dominance of Stephanodiscus species. This diatom sequence is considered as a model of a 'basic species sequence of eutrophication'. Time lags and differences in the duration of the phases between both lakes show evidence of an earlier start for nutrient loading in Starnberger See than in Ammersee, and a faster development to a higher trophic state level in the latter. The different reactions of the lakes are attributed to hydrological differences such as the existence or lack of a major tributary, the size of the catchment area, and the water residence time. The reconstruction of the eutrophication dynamics appears to be reliably hindcast by the inference of total phosphorus (TP) concentrations using weighted averaging regression and calibration techniques. Remarkable differences in the occurrence of some diatoms in both stratigraphies, which are not related to the general changes of the 'basic species sequence of eutrophication' model, may be due to the epilimnetic silica content (e.g. Fragilaria crotonensis) or competitive weaknesses (e.g. Tabellaria flocculosa).     

Sedimentation patterns of diatoms in Lake Holzmaar, Germany - (on the transfer of climate signals to biogenic silica oxygen isotope proxies)

The seasonal sedimentation pattern of diatom valves in Lake Holzmaar was investigated during 1995 by deploying sediment traps at three different lake depths. According to the sedimentation pattern, the major reproduction zone of diatoms was restricted to the upper 6 m of the water body. The population growth started late in April and blooms of Cyclotella cf. comensis Grun., which dominates the plankton diatoms, and Fragilaria crotonensis Kitton were collected in traps during June and September, and July, respectively. During summer, the seasonal sedimentation pattern of each taxon, as collected in the upper traps, was reflected in the concentrations in the lowest trap. However, in May and from September onwards, the community composition in the lowest trap and augmented trapping rates suggest both sediment focusing and resuspension of bottom sediments.The temperature signals as recorded by 18O values of diatom valves should, therefore, reflect integrated temperatures between 0 and 6 m depth. However, temperatures during summer and autumn are expected to be accentuated in the sedimentary record since the isotopic signal is weighted by both the number and the weight-mass of the valves. During summer, the transfer of these signals by the sedimenting diatoms retains the information pattern recorded, while in spring and autumn/winter additional influxes caused by resuspension may somewhat alter those temperature informations. The proxy signals finally stored in the sediments, may, therefore, not precisely represent the successive temperatures currently recorded during 1995 within mid-lake.     

Historical trends affecting accumulation of sediment and phosphorus in Lake Pepin,upper Mississippi River,USA

This study was conducted to collect historical land use information that would help explain the historical patterns in accumulation of sediment and phosphorus in Lake Pepin documented by Engstrom et al. (J Paleolimnol, this issue). A wide range of historical factors including cropping systems, phosphorus applications from fertilizer and manure, human and animal populations, river flows and phosphorus discharges from waste water treatment plants were studied using statistical methods. Results showed that sediment losses from the Minnesota River basin are significantly correlated with historical increases in river flows, row crop production acreage and basin population. Total phosphorus accumulations in the sediments of Lake Pepin are significantly correlated with increased phosphorus discharges from metropolitan area wastewater treatment plants, and increases in row crop acreage and river flows. Total phosphorus inflows to Lake Pepin are significantly correlated with increases in river flows, row crop acreage and phosphorus fertilizer applied to agricultural lands. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.     

Paleoindication of acidification in Kleiner Arbersee (Federal Republic of Germany,Bavarian Forest) by chydorids,chrysophytes, and diatoms

In a sediment core of Lake Kleiner Arbersee, located in the Bavarian Forest on gneiss bedrock and with spodosolic soils in the catchment, acidification was reconstructed using assemblages of chydorids, scaled chrysophytes, and diatoms as paleoindicators. All paleoindicators demonstrated acidification of Kleiner Arbersee. There were marked differences, however, in the extent of the indicated acidification: In lower layers, where scaled chrysophytes and chydorids clearly indicate beginning acidification, pH-decline inferred by diatoms lies within the standard deviation, and is statistically not significant until the 7 cm layer. We conclude that mallomonadaceans reflect the acidification of the water body and strongly respond to the lowest seasonal pH, as their indicated rate of acidification is higher than that of diatoms, which appear to more closely indicate the pH of the sediment/water interface, especially when the pH of the water column has dropped below ca. 5.5. Chydorids may additionally be influenced by proton release of dense Sphagnum-stands, which cover the littoral of Kleiner Arbersee completely.We dedicate this paper to Prof. Dipl.-Ing. L. Strobel, who encouraged new perspectives in limnological water management, on the occasion of his 65^th anniversary.     

Sediment chemistry and diatom stratigraphy of two high arctic isolation lakes,Truelove Lowland,Devon Island,N.W.T., Canada

Three sediment cores from two lakes, Fish Lake and Phalarope Lake, in Truelove Lowland, Devon Island, N.W.T. were analyzed for diatoms and chemical composition. Multivariate statistical techniques using a range of chemical variables successfully isolated three sediment groupings in the cores. Allochthonous and autochthonous chemical components in the sediments have been used to reconstruct paleoenvironmental conditions. The two lakes began approximately 10600 years ago as shallow marine lagoons that were isolated from the sea as a result of glacio-isostatic rebound. Based on the presence of distinctive diatom assemblages, the three stratigraphic zones are identified as a basal marine zone, an intermediate and transitional brackish/marine zone and an upper freshwater zone. Following isolation from the sea, the lakes were flushed with freshwater produced by snow and ice melt. In Fish Lake, the period of transition from marine to freshwater, which began approximately 7000 years ago, lasted approximately 800 years. In Phalarope Lake, which was isolated from the sea approximately 5000 years ago, flushing by fresh water was completed only within the last 300 years. Fe, Cr, and Mo in the sediments are associated with the isolation phase when lake sedimentation is sensitive to the presence of brackish water and erosion within the lake catchments. In particular, the precipitation of Mo as MoS₂ reflects the presence of hypolimnetic anoxia associated with lake isolation. During the early post-isolation phase the response of lake biota to an influx of nutrients is reflected in an increase in biological silica and organic carbon in the lake sediments. On the other hand, the generally low organic content of the sediments indicates that sedimentation in these lakes has been largely determined by variations in non-biogenic factors through time. During the mid Holocene the progressive stabilization of surface materials within the lake catchments is marked by decreasing Cr, As and Na in the sediments. At the same time, an increase in allochthonous Mn and Fe is attributed to progressive soil development. During the last 2500 years the catchments have experienced decreased erosion resulting in a decrease in both allochthonous clastic input and lake productivity.