Linking snowmelt‐derived fluxes and groundwater flow in a high elevation meadow system,Sierra Nevada Mountains,California

Quantifying snowmelt‐derived fluxes at the watershed scale within hillslope environments is critical for investigating local meadow scale groundwater dynamics in high elevation riparian ecosystems. In this article, we investigate the impact of snowmelt‐derived groundwater flux from the surrounding hillslopes on water table dynamics in Tuolumne Meadows, which is located in the Sierra Nevada Mountains of California, USA. Results show water levels within the meadow are controlled by a combination of fluxes at the hillslope boundaries, snowmelt within the meadow and changes in the stream stage. Observed water level fluctuations at the boundaries of the meadow show the hydrologic connection and subsequent disconnection between the hillslope and meadow aquifers. Timing of groundwater flux entering the meadow as a result of spring snowmelt can vary over 20 days based on the location, aspect, and local geology of the contributing area within the larger watershed. Identifying this temporal and spatial variability in flux entering the meadow is critical for simulating changes in water levels within the meadow. Model results can vary significantly based on the temporal and spatial scales at which watershed processes are linked to local processes within the meadow causing errors when boundary fluxes are lumped in time or space. Without a clear understanding of the surrounding hillslope hydrology, it is difficult to simulate groundwater dynamics within high elevation riparian ecosystems with the accuracy necessary for understanding ecosystem response. Copyright © 2010 John Wiley & Sons, Ltd.     

Controls on sediment evacuation from glacially modified and unmodified catchments in the eastern Sierra Nevada,California

The degree of glacial modification in small catchments along the eastern Sierra Nevada, California, controls the timing and pattern of sediment flux to the adjacent fans. There is a close relationship between the depth of fan‐head incision and the pattern and degree of Late Pleistocene catchment erosion by valley glaciers; catchments with significant glacial activity are associated with deeply incised fan heads, whereas fans emerging from glacially unmodified catchments are unincised. We suggest that the depth of fan‐head incision is controlled by the potential for sediment storage during relatively dry ice‐free periods, which in turn is related to the downstream length of the glacially modified valley and creation of accommodation through valley floor slope lowering and glacial valley overdeepening and widening. Significant storage in glacially modified basins during ice‐free periods leads to sediment supply‐limited conditions at the fan head and causes deep incision. In contrast, a lack of sediment trapping allows quasi‐continuous sediment supply to the fan and prevents incision of the fan head. Sediment evacuation rates should thus show large variations in glacially modified basins, with major peaks during glacial and lows during interglacial or ice‐free periods, respectively. In contrast, sediment removal from glacially unmodified catchments in this type of setting should be free of this effect, and will be dominated instead by short‐term variations, modulated for example by changes in vegetation cover or storm frequency. This distinction may help improve our understanding of long‐term sediment yields as a measure of erosional efficiency. Copyright © 2008 John Wiley & Sons, Ltd.     

Hydrogeological characterization of groundwater storage and drainage in an alpine karst aquifer (the Kanin massif,Julian Alps)

The Kanin massif is an important trans‐boundary aquifer, which stretches between Slovenia and Italy. The groundwater is only partially exploited, mainly for water supply, but the aquifer exhibits great potential for future exploitation. Since no consistent regional overview of the hydrogeological functioning of the Kanin massif was available, the decision was made to perform a study of this area, using a pragmatic approach based on 3D geological and hydrogeological modelling. The so‐called KARSYS approach was applied, with the aim of characterizing the groundwater reserves within this karst massif and of locating the main drainage axes that carry groundwater from the recharge areas to the respective springs. Delineation of the catchment areas of the corresponding springs was carried out, and some new explanations were obtained, especially with regard to the Mo?nica spring, which is located in Slovenia and forms a potential source of drinking water. It was found that this spring's catchment area extends as far as the Italian ski resort of Sella Nevea. The conceptual model also provides a possible explanation about the underground drainage towards the Boka spring and waterfall, which has been a challenge for decades. This new explanation is based on the existence of a perched groundwater body that feeds the Boka spring via a system of conduits. Despite some limitations, the results, which consist of a visualization of the underground drainage and groundwater storage within the Kanin massif, can be used as a basis for planning the sustainable management of karst waters in the studied area. Copyright © 2014 John Wiley & Sons, Ltd.     

A two‐component hydrograph separation for three high‐elevation catchments in the Sierra Nevada,California

Two‐component hydrograph separations were performed for three, nested, snowmelt‐dominated catchments in Sequoia National Park. The purpose of the hydrograph separations was to: (i) differentiate between the old and new water contributions to discharge during snowmelt using δ¹⁸O signatures; (ii) identify the fraction of snowmelt that travelled through the subsurface (reactive) compartment during the snowmelt period using silica or sodium; and (iii) investigate the impact of changing end‐member signatures on the separations. ‘Old’ water refers to water that was stored in the watershed during the previous year, whereas ‘new’ water is current snowmelt. Hydrograph separations were performed for both a high‐accumulation (1998, annual precipitation 2·4 m) and an average year (1999, 1·3 m). The proportion of old water contribution to discharge during the rising limb of the hydrograph was 10–20%, with 80–100% of snowmelt being reactive, i.e. passing through soil and talus. Estimates of old and new soil water and direct snowmelt entering the stream varied among the catchments in 1999. Differences between these components were minimal in 1998, regardless of varying topography and differing proportions of soil, rock and talus. Using time‐dependent rather than constant δ¹⁸O meltwater and silica soil‐water signatures made a meaningful impact on both new and old water, and reactive and unreactive, estimates. Copyright © 2004 John Wiley & Sons, Ltd.     

Controls of streamflow generation in small catchments across the snow–rain transition in the Southern Sierra Nevada,California

Processes controlling streamflow generation were determined using geochemical tracers for water years 2004–2007 at eight headwater catchments at the Kings River Experimental Watersheds in southern Sierra Nevada. Four catchments are snow‐dominated, and four receive a mix of rain and snow. Results of diagnostic tools of mixing models indicate that Ca²⁺, Mg²⁺, K⁺ and Cl^? behaved conservatively in the streamflow at all catchments, reflecting mixing of three endmembers. Using endmember mixing analysis, the endmembers were determined to be snowmelt runoff (including rain on snow), subsurface flow and fall storm runoff. In seven of the eight catchments, streamflow was dominated by subsurface flow, with an average relative contribution (% of streamflow discharge) greater than 60%. Snowmelt runoff contributed less than 40%, and fall storm runoff less than 7% on average. Streamflow peaked 2–4 weeks earlier at mixed rain–snow than snow‐dominated catchments, but relative endmember contributions were not significantly different between the two groups of catchments. Both soil water in the unsaturated zone and regional groundwater were not significant contributors to streamflow. The contributions of snowmelt runoff and subsurface flow, when expressed as discharge, were linearly correlated with streamflow discharge (R² of 0.85–0.99). These results suggest that subsurface flow is generated from the soil–bedrock interface through preferential pathways and is not very sensitive to snow–rain proportions. Thus, a declining of the snow–rain ratio under a warming climate should not systematically affect the processes controlling the streamflow generation at these catchments. Copyright © 2012 John Wiley & Sons, Ltd.     

Projected risks to groundwater‐dependent terrestrial vegetation caused by changing climate and groundwater abstraction in the Central Perth Basin,Western Australia

The effect of potential climate change on groundwater‐dependent vegetation largely depends on the nature of the climate change (drying or wetting) and the level of current ecosystem dependence on groundwater resources. In south‐western Australia, climate projections suggest a high likelihood of a warmer and drier climate. The paper examines the potential environmental impacts by 2030 at the regional scale on groundwater‐dependent terrestrial vegetation (GDTV) adapted to various watertable depths, on the basis of the combined consideration of groundwater modelling results and the framework for GDTV risk assessment. The methodology was tested for the historical period from 1984 to 2007, allowing validation of the groundwater model results' applicability to such an assessment. Climate change effects on GDTV were evaluated using nine global climate models under three greenhouse gas emission scenarios by applying the climate projections to groundwater models. It was estimated that under dry climate scenarios, GDTV is likely to be under high and severe risk over more than 20% of its current habitat area. The risk is also likely to be higher under an increase in groundwater abstraction above current volumes. The significance of climate change risk varied across the region, depending on both the intensity of the change in water regime and the sensitivity of the GDTV to such change. Greater effects were projected for terrestrial vegetation dependent on deeper groundwater (6–10 m). Copyright © 2013 John Wiley & Sons, Ltd.     

A multi‐storage groundwater concept for the SWAT model to emphasize nonlinear groundwater dynamics in lowland catchments

Hydrological models are useful tools to analyze present and future conditions of water quantity and quality. The integrated modelling of water and nutrients needs an adequate representation of the different discharge components. In common with many lowlands, groundwater contribution to the discharge in the North German lowlands is a key factor for a reasonable representation of the water balance, especially in low flow periods. Several studies revealed that the widely used Soil and Water Assessment Tool (SWAT) model performs poorly for low flow periods. This paper deals with the extension of the groundwater module of the SWAT model to enhance low flow representation. The current two‐storage concept of SWAT was further developed to a three‐storage concept. This was realized due to modification of the groundwater module by splitting the active groundwater storage into a fast and a slow contributing aquifer. The results of this study show that the groundwater module with three storages leads to a good prediction of the overall discharge especially for the recession limbs and the low flow periods. The improved performance is reflected in the signature measures for the mid‐segment (percent bias ?2.4% vs ?15.9%) and the low segment (percent bias 14.8% vs 46.8%) of the flow duration curve. The three‐storage groundwater module is more process oriented than the original version due to the introduction of a fast and a slow groundwater flow component. The three‐storage version includes a modular approach, because groundwater storages can be activated or deactivated independently for subbasin and hydrological response unit level. Copyright © 2013 John Wiley & Sons, Ltd.     

Assessing hydrogeologic controls on dynamic groundwater storage using long‐term instrumental records of water table levels

This study analyzes a long‐term regional compilation of water table response to climate variability based on 124 long‐term groundwater wells distributed across New England, USA, screened in a variety of geologic materials. The New England region of the USA is located in a humid‐temperature climate underlain by low‐storage‐fractured metamorphic and crystalline bedrock dissected by north–south trending valleys filled with glacial and post‐glacial valley fill sediments. Uplands are covered by thin glacial till that comprises more than 60% of the total area. Annual and multi‐annual responses of the water table to climate variability are assessed to understand how local hydraulic properties and hydrogeologic setting (located in recharge/discharge region) of the aquifer influence the hydrologic sensitivity of the aquifer system to climate variability. This study documents that upland aquifer systems dominated by thin deposits of surface till comprise ~70% of the active and dynamic storage of the region. Total aquifer storage changes of +5 to ?7 km³ occur over the region during the study interval. The storage response is dominated by thin and low permeability surficial till aquifer that fills and drains on a multi‐annual basis and serves as the main mechanism to deliver water to valley fill aquifers and underlying bedrock aquifers. Whereas the till aquifer system is traditionally neglected as an important storage reservoir, this study highlights the importance of a process‐based understanding of how different landscape hydrogeologic units contribute to the overall hydrologic response of a region.     

Integration of aquifer geology,groundwater flow and arsenic distribution in deltaic aquifers – A unifying concept

Groundwater arsenic (As) presents a public health risk of great magnitude in densely populated Asian delta regions, most acutely in the Bengal Basin (West Bengal, India and Bangladesh). Research has focused on the sources, mobilisation, and heterogeneity of groundwater As, but a consistent explanation of As distribution from local to basin scale remains elusive. We show for the Bengal Aquifer System that the numerous, discontinuous silt‐clay layers together with surface topography impose a hierarchical pattern of groundwater flow, which constrains As penetration into the aquifer and controls its redistribution towards discharge zones, where it is re‐sequestered to solid phases. This is particularly so for the discrete periods of As release to groundwater in the shallow subsurface associated with sea level high‐stand conditions of Quaternary inter‐glacial periods. We propose a hypothesis concerning groundwater flow ( S ilt‐clay layers I mpose H ierarchical groundwater flow patterns constraining A rsenic progression [SIHA]), which links consensus views on the As source and history of sedimentation in the basin to the variety of spatial and depth distributions of groundwater As reported in the literature. SIHA reconciles apparent inconsistencies between independent, in some cases contrasting, field observations. We infer that lithological and topographic controls on groundwater flow, inherent to SIHA, apply more generally to deltaic aquifers elsewhere. The analysis suggests that groundwater As may persist in the aquifers of Asian deltas over thousands of years, but in certain regions, particularly at deeper levels, As will not exceed low background concentrations unless groundwater flow systems are short‐circuited by excessive pumping.     

Dynamic river–groundwater exchange in the presence of a saline,semi‐confined aquifer

Understanding groundwater–surface water exchange in river banks is crucial for effective water management and a range of scientific disciplines. While there has been much research on bank storage, many studies assume idealized aquifer systems. This paper presents a field‐based study of the Tambo Catchment (southeast Australia) where the Tambo River interacts with both an unconfined aquifer containing relatively young and fresh groundwater (<500 μS/cm and <100 years old) and a semi‐confined artesian aquifer containing old and saline groundwater (electrical conductivity > 2500 μS/cm and >10 000 years old). Continuous groundwater elevation and electrical conductivity monitoring within the different aquifers and the river suggest that the degree of mixing between the two aquifers and the river varies significantly in response to changing hydrological conditions. Numerical modelling using MODFLOW and the solute transport package MT3DMS indicates that saline water in the river bank moves away from the river during flooding as hydraulic gradients reverse. This water then returns during flood recession as baseflow hydraulic gradients are re‐established. Modelling also indicates that the concentration of a simulated conservative groundwater solute can increase for up to ~34 days at distances of 20 and 40 m from the river in response to flood events approximately 10 m in height. For the same flood event, simulated solute concentrations within 10 m of the river increase for only ~15 days as the infiltrating low‐salinity river water drives groundwater dilution. Average groundwater fluxes to the river stretch estimated using Darcy's law were 7 m³/m/day compared with 26 and 3 m³/m/day for the same periods via mass balance using Radon (²²²Rn) and chloride (Cl), respectively. The study shows that by coupling numerical modelling with continuous groundwater–surface water monitoring, the transient nature of bank storage can be evaluated, leading to a better understanding of the hydrological system and better interpretation of hydrochemical data. Copyright © 2015 John Wiley & Sons, Ltd.     

Application of ground‐penetrating radar to the identification of subsurface piping in blanket peat

Natural soil pipes are common and significant in upland blanket peat catchments yet there are major problems in finding and defining the subsurface pipe networks. This is particularly important because pipeflow can contribute a large proportion of runoff to the river systems in these upland environments and may significantly influence catchment sediment and solute yields. Traditional methods such as digging soil pits are destructive and time‐consuming (particularly in deep peat) and only provide single point sources of information. This paper presents results from an experiment to assess the use of ground‐penetrating radar (GPR) to remotely sense pipes in blanket peat. The technique is shown to be successful in identifying most of the pipes tested in the pilot catchment. Comparison of data on pipes identified by GPR and verified by manual measurement suggests that pipes can be located in the soil profile with a depth accuracy of 20 to 30 cm. GPR‐identified pipes were found throughout the soil profile; however, those within 10–20 cm of the surface could not be identified using the 100 or 200 MHz antennae due to multiple surface reflections. Generally pipes smaller than 10 cm in diameter could not be identified using the technique although modifications are suggested that will allow enhanced resolution. Future work would benefit from the development of dual‐frequency antennae that will allow the combination of high‐resolution data with the depth of penetration required in a wetland environment. The GPR experiment shows that pipe network densities were much greater than could be detected from surface observation alone. Thus, GPR provides a non‐destructive, fast technique which can produce continuous profiles of peat depth and indicate pipe locations across survey transects. Copyright © 2002 John Wiley & Sons, Ltd.     

The effect of low‐permeability fault zones on groundwater flow in a compartmentalized system. Experimental evidence from a carbonate aquifer (Southern Italy)

The hydrogeological behaviour of fault zones in carbonate aquifers is often neglected in conceptual and numerical models. Furthermore, no information is available regarding the relationships between piezometric levels when significant compartmentalization occurs due to the occurrence of low‐flow fault zones. The aim of this study was to refine the conceptualization of subsurface flow in faulted carbonate aquifers and to analyse relationships between sub‐basins within a compartmentalized aquifer system in Southern Italy. The interactions between compartments that straddle low‐flow faults were investigated over four hydrologic years using a statistical approach to compare (i) the hydraulic heads within two wells located up‐ and down‐gradient of tectonic discontinuities as well as (ii) the rainfall and piezometric levels. The results of this study suggest that a set of barriers exists between the wells, and, therefore, the total head loss observed between the wells (approximately 80 m) should be distributed across several aquitards, with one aquitard exhibiting a relatively high permeability or low degree of integrity. Due to slight differences in permeability, transient conditions in aquitards can occur over relatively short periods, which is in agreement with the results of the statistical data analysis. Consequently, rather than being caused by pure aquitards, aquifer system compartmentalization likely results from slight differences in the permeability between lower‐permeability fault zones and adjacent higher‐permeability protoliths. Copyright © 2014 John Wiley & Sons, Ltd.     

Modelling the potential impacts of groundwater hydrology on long‐term drainage basin evolution

Fluvial erosion processes are driven by water discharge on the land surface, which is produced by surface runoff and groundwater discharge. Although groundwater is often neglected in long‐term landscape evolution problems, water table levels control patterns of Dunne runoff production, and groundwater discharge can contribute significantly to storm flows. In this analysis, we investigate the role that groundwater movement plays in long‐term drainage basin evolution by modifying a widely used landscape evolution model to include a more detailed representation of basin hydrology. Precipitation is generated by a stochastic process, and the precipitation is partitioned between surface runoff and groundwater recharge using a specified infiltration capacity. Groundwater flow is simulated by a dynamic two‐dimensional Dupuit equation for an unconfined aquifer with an irregular underlying impervious layer. The model is applied to the WE‐38 basin, an experimental catchment in Pennsylvania, because 60–80 per cent of the discharge is derived from groundwater and substantial hydrologic and geomorphic information is available. The hydrologic model is first calibrated to match the observed streamflows, and then the combined hydrologic/geomorphic model is used to simulate scenarios with different infiltration capacities. The results of this modelling exercise indicate that the basin can be divided into three zones with distinct streamflow‐generating characteristics, and different parts of the basin can have different geomorphic effective events. Over long periods of time, scenarios in which groundwater discharge is large tend to modify the topography in a way that promotes groundwater discharge and inhibits Dunne runoff. Copyright © 2006 John Wiley & Sons, Ltd.     

Impact of groundwater flow on meandering; example from the Geul River,The Netherlands

The Geul River, located in the south‐eastern part of The Netherlands, is a meandering river with a planform shape characterized by large loops consisting of multiple bends. We evaluate the effect(s) of groundwater flow on the shapes of meanders as a possible explanation for the multi‐bend loops, using a combined meandering–groundwater computer model. In the model seeping groundwater enhances bank erodibility. Based on the simulation results, we present a conceptual, generalized model for groundwater–meandering interaction, based on wavelength selection and fixation effects. Wavelength selection occurs because of the positive feedback between growing meander bends and groundwater flow patterns and velocities. The promoted wavelengths have the same spatial scale as the groundwater flow system in the aquifer underlying the floodplain. In the case of the Geul River these wavelengths are of the order of 100 m. Since groundwater flow velocities are largest close to the recharging hill‐slopes, the seepage‐enhanced bank erodibilities are at a maximum near the floodplain limits. At these locations the difference in erodibility between banks facing the floodplain and those facing the hill slopes is large, so it is difficult for the river to migrate away from the floodplain limits. This causes long stretches of the river to be aligned along the floodplain limits, which we term a fixation effect. This mechanism best explains the multi‐bend loops of the Geul River. The general interaction between groundwater flow and meandering is site specific since it depends on climatic, fluvial and hydrogeological parameters. The Geul is characterized by a wide floodplain and steep hill‐slopes, and it is underlain by coarse‐grained deposits with good aquifer properties, favoring an important groundwater system. Since this kind of river frequently occurs, our results could apply to many other river systems. Copyright © 2008 John Wiley & Sons, Ltd.     

Modelling how vegetation cover affects climate change impacts on streamflow timing and magnitude in the snowmelt‐dominated upper Tuolumne Basin,Sierra Nevada

We investigated, through hydrologic modelling, the impact of the extent and density of canopy cover on streamflow timing and on the magnitude of peak and late summer flows in the upper Tuolumne basin (2600–4000 m) of the Sierra Nevada, California, under current and warmer temperatures. We used the Distributed Hydrology Soil Vegetation Model for the hydrologic modelling of the basin, assuming four vegetation scenarios: current forest (partial cover, 80% density), all forest (uniform coverage, 80% density), all barren (no forest) and thinned forest (partial cover, 40% density) for a medium‐high emissions scenario causing a 3.9 °C warming over a 100‐year period (2001–2100). Significant advances in streamflow timing, quantified as the centre of mass (COM) of over 1 month were projected for all vegetation scenarios. However, the COM advances faster with increased forest coverage. For example, when forest covered the entire area, the COM occurred on average 12 days earlier compared with the current forest coverage, with the rate of advance higher by about 0.06 days year^?1 over 100 years and with peak and late summer flows lower by about 20% and 27%, respectively. Examination of modelled changes in energy balance components at forested and barren sites as temperatures rise indicated that increases in net longwave radiation are higher in the forest case and have a higher contribution to melting earlier in the calendar year when shortwave radiation is a smaller fraction of the energy budget. These increases contributed to increased midwinter melt under the forest at temperatures above freezing, causing decreases in total accumulation and higher winter and early spring melt rates. These results highlight the importance of carefully considering the combined impacts of changing forest cover and climate on downstream water supply and mountain ecosystems. Copyright © 2013 John Wiley & Sons, Ltd.     

Numerical studies on the influences of the South‐to‐North Water Transfer Project on groundwater level changes in the Beijing Plain,China

Groundwater is an important component of the water supply, and overexploitation has triggered many problems in the Beijing Plain. The South‐to‐North Water Transfer Project has been proposed as a promising solution to alleviate these problems. Evaluation of different scenarios of groundwater management after the implementation of the South‐to‐North Water Transfer Project is necessarily required. In this study, a numerical model of groundwater flow was established using FEFLOW software and was well calibrated by parameter optimization and groundwater withdrawal inversion in the Beijing Plain. Sixteen scenarios that considered groundwater exploitation, artificial recharge, and precipitation were designed to simulate the groundwater dynamics after 11 years of the project. The results showed that the groundwater level in the study area would recover to various degrees due to the reductions of groundwater withdrawal and the increments of infiltration; additionally, it was concluded that groundwater was significantly affected by precipitation. Generally, in the designed scenarios, the groundwater‐level increment in the upper streams of the model area was higher than that in the lower streams. The groundwater level would obviously increase from artificial recharge in the immediate and adjacent areas. In addition, modes of reducing exploitation had no significant influence on the change in groundwater level during the 11‐year study period. The developed model offers a reliable and effective way to improve groundwater management.     

Impact of the 6 April 2009 L'Aquila earthquake on groundwater flow in the Gran Sasso carbonate aquifer,Central Italy

The Mw = 6·3 L'Aquila earthquake on 6 April 2009 produced a mainshock that caused significant changes in the hydrogeology of the Gran Sasso carbonate fractured aquifer: (i) the sudden disappearance at the time of the mainshock of some springs located exactly along the surface trace of the Paganica normal fault (PF); (ii) an immediate increase in the discharge of the Gran Sasso highway tunnel drainages and of other springs and (iii) a progressive increase of the water table elevation at the boundary of the Gran Sasso aquifer during the following months. Using the data collected since the 1990s that include aftershock monitoring as well as data regarding spring discharge, water table elevations, turbidity and rainfall events, a conceptual model of the earthquake's consequences on the Gran Sasso aquifer is proposed herein. In this model that excludes the contribution of seasonal recharge, the short‐term hydrologic effects registered immediately after the mainshock are determined to have been caused by a pore pressure increase related to aquifer deformation. Mid‐term effects observed in the months following the mainshock suggest that there was a change in groundwater hydrodynamics. Supplementary groundwater that flows towards aquifer boundaries and springs in discharge areas reflects a possible increase in hydraulic conductivity in the recharge area, nearby the earthquake fault zone. This increase can be attributed to fracture clearing and/or dilatancy. Simulations by numerical modelling, related to pore pressure and permeability changes with time, show results in accordance with observed field data, supporting the conceptual model and confirming the processes that influenced the answer of the Gran Sasso aquifer to the L'Aquila earthquake. Copyright © 2010 John Wiley & Sons, Ltd.     

Groundwater quality in the semi‐arid region of the Chahardouly basin,West Iran

Chahardouly basin is located in the western part of Iran and is characterized by semi‐arid climatic conditions and scarcity in water resources. The main aquifer systems are developed within alluvial deposits. The availability of groundwater is rather erratic owing to the occurrence of hard rock formation and a saline zone in some parts of the area. The aquifer systems of the area show signs of depletion, which have taken place in recent years due to a decline in water levels. Groundwater samples collected from shallow and deep wells were analysed to examine the quality characteristics of groundwater. The major ion chemistry of groundwater is dominated by Ca²⁺ and HCO₃^?, while higher values of total dissolved solids (TDS) in groundwater are associated with high concentrations of all major ions. An increase in salinity is recorded in the down‐gradient part of the basin. The occurrence of saline groundwater, as witnessed by the high electrical conductivity (EC), may be attributed to the long residence time of water and the dissolution of minerals, as well as evaporation of rainfall and irrigation return flow. Based on SAR values and sodium content (%Na), salinity appears to be responsible for the poor groundwater quality, rendering most of the samples not suitable for irrigation use. Copyright © 2007 John Wiley & Sons, Ltd.     

Identification of groundwater recharge sources and processes in a heterogeneous alluvial aquifer: results from multi‐level monitoring of hydrochemistry and environmental isotopes in a riverside agricultural area in Korea

We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO₃^? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO₃^?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ¹⁸O and δ²H values of groundwater were also different between the two zones. Hydrochemical and δ¹⁸O? δ²H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO₃^?. The ³H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ¹⁸O and δ²H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.     

Spatio‐temporal evaluation of the groundwater quality in Kafr Al‐Zayat District,Egypt

Eighteen groundwater well sites located in Kafr Al‐Zayat (Egypt) were sampled monthly from January 2009 to November 2011 for microbial content, Mn⁺², Fe⁺², total dissolved solids (TDS), total hardness, NO₃^?, and turbidity. The data were analyzed combining the integrated use of factor and cluster analyses as well as the geostatistical semi‐variogram modeling. The prime objectives were to assess the groundwater suitability for drinking, to document the factors governing the spatio‐tempral variability, and to recognize distinctive groundwater quality patterns to help enable effective sustainability and proactive management of the limited resource. The groundwater microbial, Mn⁺², Fe⁺², TDS, and total hardness contents violated the drinking water local standards while the turbidity and the nitrate content complied with them. Factor analysis indicated that the microbial content is the most influential factor raising the variability potential followed, in decreasing order, by Mn²⁺, Fe²⁺, TDS, NO₃^?, turbidity, and finally the total hardness. Turbidity resulting from urban and agricultural runoff was strongly associated with most of the quality parameters. Quality parameters fluctuate sporadically without concrete pattern in space and time while their variability scores peak in November every year. Three spatially distinctive quality patterns were recognized that were consistent with and affected by the cumulative effects of the local topography, depth to water table, thickness of the silty clay (cap layer), surface water, and groundwater flow direction and hence the recharge from contaminated surface canals and agricultural drains. Copyright © 2013 John Wiley & Sons, Ltd.