Nitrate removal and young stream water fractions at the catchment scale

Despite extensive research on nitrate export and removal, nutrient contamination remains a major threat to water bodies worldwide. At the local scale, nitrate removal is governed by biogeochemical conditions that vary in space and time, making integration to entire landscapes critical. Water transit times have often been used to describe solute transport, but the relation between water age and nitrate removal at the catchment scale is still poorly understood. We test the hypothesis that nitrate removal peaks when the fraction of young water in discharge is at its minimum, because nitrate removal occurs mostly under dry conditions where deeper, older groundwater dominates streamflow. We tested this hypothesis by exploring a detailed water quality record from the Kervidy–Naizin catchment (FR) and comparing the dynamics of nitrate to those of a conservative solute (chloride). We find that estimates of nitrate removal are consistent with previous estimates at the site and they show a good (inverse) correlation with the fraction of streamflow that is younger than 2.5 months. However, this young water fraction cannot be used to predict nitrate removal in the winter–spring period, when no removal is observed regardless of streamflow age. While this leads us to reject our hypothesis during the winter period, it also suggests that water age distributions and their correlation with nitrate removal can possibly reveal distinct sources of stream water at different hydrologic regimes and relevant biogeochemical reactions.     

Water-rock interactions drive chemostasis

The western U.S. is experiencing shifts in recharge due to climate change, and it is currently unclear how hydrologic shifts will impact geochemical weathering and stream concentration–discharge (C–Q) patterns. Hydrologists often use C–Q analyses to assess feedbacks between stream discharge and geochemistry, given abundant stream discharge and chemistry data. Chemostasis is commonly observed, indicating that geochemical controls, rather than changes in discharge, are shaping stream C–Q patterns. However, few C–Q studies investigate how geochemical reactions evolve along groundwater flowpaths before groundwater contributes to streamflow, resulting in potential omission of important C–Q controls such as coupled mineral dissolution and clay precipitation and subsequent cation exchange. Here, we use field observations—including groundwater age, stream discharge, and stream and groundwater chemistry—to analyse C–Q relations in the Manitou Experimental Forest in the Colorado Front Range, USA, a site where chemostasis is observed. We combine field data with laboratory analyses of whole rock and clay x-ray diffraction and soil cation-extraction experiments to investigate the role that clays play in influencing stream chemistry. We use Geochemist's Workbench to identify geochemical reactions driving stream chemistry and subsequently suggest how climate change will impact stream C–Q trends. We show that as groundwater age increases, C–Q slope and stream solute response are not impacted. Instead, primary mineral dissolution and subsequent clay precipitation drive strong chemostasis for silica and aluminium and enable cation exchange that buffers calcium and magnesium concentrations, leading to weak chemostatic behaviour for divalent cations. The influence of clays on stream C–Q highlights the importance of delineating geochemical controls along flowpaths, as upgradient mineral dissolution and clay precipitation enable downgradient cation exchange. Our results suggest that geochemical reactions will not be impacted by future decreasing flows, and thus where chemostasis currently exists, it will continue to persist despite changes in recharge.     

Linking tracers,water age and conceptual models to identify dominant runoff processes in a sparsely monitored humid tropical catchment

Assessing catchment runoff response remains a key research frontier because of limitations in current observational techniques to fully characterize water source areas and transit times in diverse geographical environments. Here, we report a study that combines empirical data with modelling to identify dominant runoff processes in a sparsely monitored humid tropical catchment. The analysis integrated isotope tracers into conceptual rainfall–runoff models of varying complexity (from 5 to 11 calibrated parameters) that are able to simulate discharge and tracer concentrations and track the evolving age of stream water exiting the catchment. The model structures can be seen as competing hypotheses of catchment functioning and were simultaneously calibrated against uncertain streamflow gaugings and a 2‐year daily isotope rainfall–runoff record. Comparison of the models was facilitated using global parameter sensitivity analysis and the resulting effect on calibration. We show that a variety of tested model structures reproduced water and tracer dynamics in stream, but the simpler models failed to adequately reproduce both. The resulting water age distributions of the tested models varied significantly with little similarity between the stream water age and stored water age distributions. The sensitivity analysis revealed that only some of the more complex models (from eight parameters) could be better constrained to infer more plausible water age distributions and catchment storage estimates. These models indicated that the age of water stored in the catchment is generally older compared with the age of water fluxes, with evapotranspiration age being younger compared with streamflow. However, the water age distributions followed a similar temporal behaviour dominated by climatic seasonality. Stream water ages increased during the dry season (greater than 1 year) and decreased with increased streamflow (a few weeks old) during the wet season. We further show that the ratios of the streamwater age to stored water age distribution and the water age distribution of actual evapotranspiration to the stored water age distribution from constrained models could potentially serve as useful hydrological indicators of catchment functioning. Copyright © 2016 John Wiley & Sons, Ltd.     

Temporal patterns and controls on runoff magnitude and solution chemistry of urban catchments in the semiarid southwestern United States

Urban expansion and the scarcity of water supplies in arid and semiarid regions have increased the importance of urban runoff to localized water resources. However, urban catchment responses to precipitation are poorly understood in semiarid regions where intense rainfall often results in large runoff events during the short summer monsoon season. To evaluate how urban runoff quantity and quality respond to rainfall magnitude and timing, we collected stream stage data and runoff samples throughout the 2007 and 2008 summer monsoons from four ephemeral drainages in Tucson, Arizona. Antecedent rainfall explained 20% to 30% of discharge (mm) and runoff ratio in the least impervious (22%) catchment but was not statistically related to hydrologic responses at more impervious sites. Regression models indicated that rainfall depth, imperviousness and their combined effect control discharge and runoff ratios (p < 0.01, r² = 0.91 and 0.75, respectively). In contrast, runoff quality did not vary with imperviousness or catchment size. Rainfall depth and duration, time since antecedent rainfall and event and cumulative discharge controlled runoff hydrochemistry and resulted in five specific solute response patterns: (i) strong event and seasonal solute mobilization (solute flush), (ii) event chemostasis and strong seasonal flush, (iii) event chemostasis and weak seasonal flush, (iv) event and seasonal chemostasis and (v) late seasonal flush. Our results indicate that hydrologic responses of semiarid catchments are controlled by rainfall partitioning at the event scale, whereas wetting magnitude, frequency and timing alter solute stores readily available for transport and control temporal runoff quality. Copyright © 2012 John Wiley & Sons, Ltd.     

Influence of climate on alpine stream chemistry and water sources

The resilience of alpine/subalpine watersheds may be viewed as the resistance of streamflow or stream chemistry to change under varying climatic conditions, which is governed by the relative size (volume) and transit time of surface and subsurface water sources. Here, we use end‐member mixing analysis in Andrews Creek, an alpine stream in Rocky Mountain National Park, Colorado, from water year 1994 to 2015, to explore how the partitioning of water sources and associated hydrologic resilience change in response to climate. Our results indicate that four water sources are significant contributors to Andrews Creek, including snow, rain, soil water, and talus groundwater. Seasonal patterns in source‐water contributions reflected the seasonal hydrologic cycle, which is driven by the accumulation and melting of seasonal snowpack. Flushing of soil water had a large effect on stream chemistry during spring snowmelt, despite making only a small contribution to streamflow volume. Snow had a large influence on stream chemistry as well, contributing large amounts of water with low concentrations of weathering products. Interannual patterns in end‐member contributions reflected responses to drought and wet periods. Moderate and significant correlations exist between annual end‐member contributions and regional‐scale climate indices (the Palmer Drought Severity Index, the Palmer Hydrologic Drought Index, and the Modified Palmer Drought Severity Index). From water year 1994 to 2015, the percent contribution from the talus‐groundwater end member to Andrews Creek increased an average of 0.5% per year (p < 0.0001), whereas the percent contributions from snow plus rain decreased by a similar amount (p = 0.001). Our results show how water and solute sources in alpine environments shift in response to climate variability and highlight the role of talus groundwater and soil water in providing hydrologic resilience to the system.     

Concentration–discharge relationships in the coal mined region of the New River basin and Indian Fork sub‐basin,Tennessee, USA

For many basins, identifying changes to water quality over time and understanding current hydrologic processes are hindered by fragmented and discontinuous water‐quality and hydrology data. In the coal mined region of the New River basin and Indian Fork sub‐basin, muted and pronounced changes, respectively, to concentration–discharge (C–Q) relationships were identified using linear regression on log‐transformed historical (1970s–1980s) and recent (2000s) water‐quality and streamflow data. Changes to C–Q relationships were related to coal mining histories and shifts in land use. Hysteresis plots of individual storms from 2007 (New River) and the fall of 2009 (Indian Fork) were used to understand current hydrologic processes in the basins. In the New River, storm magnitude was found to be closely related to the reversal of loop rotation in hysteresis plots; a peak‐flow threshold of 25 cubic meters per second (m³/s) segregates hysteresis patterns into clockwise and counterclockwise rotational groups. Small storms with peak flow less than 25 m³/s often resulted in dilution of constituent concentrations in headwater tributaries like Indian Fork and concentration of constituents downstream in the mainstem of the New River. Conceptual two or three component mixing models for the basins were used to infer the influence of water derived from spoil material on water quality. Copyright © 2012 John Wiley & Sons, Ltd.     

Surface and subsurface water contributions to streamflow from a mesoscale watershed in complex mountain terrain

An understanding of surface and subsurface water contributions to streamflow is essential for accurate predictions of water supply from mountain watersheds that often serve as water towers for downstream communities. As such, this study used the end‐member mixing analysis technique to investigate source water contributions and hydrologic flow paths of the 264 km² Boulder Creek Watershed, which drains the Colorado Front Range, USA. Four conservative hydrochemical tracers were used to describe this watershed as a 3 end‐member system, and tracer concentration reconstruction suggested that the application of end‐member mixing analysis was robust. On average from 2009 to 2011, snowmelt and rainwater from the subalpine zone and groundwater sampled from the upper montane zone contributed 54%, 22%, and 24% of the annual streamflow, respectively. These values demonstrate increased rainwater and decreased snow water contributions to streamflow relative to area‐weighted mean values derived from previous work at the headwater scale. Young water (2.3 ± 0.8 months) fractions of streamflow decreased from 18–22% in the alpine catchment to 8–10% in the lower elevation catchments and the watershed outlet with implications for subsurface storage and hydrological connectivity. These results contribute to a process‐based understanding of the seasonal source water composition of a mesoscale watershed that can be used to extrapolate headwater streamflow generation predictions to larger spatial scales.     

Ecohydrologic separation alters interpreted hydrologic stores and fluxes in a headwater mountain catchment

Recent studies have demonstrated that compartmentalized pools of water preferentially supply either plant transpiration (poorly mobile water) or streamflow and groundwater (highly mobile water) in some catchments, a phenomenon referred to as ecohydrologic separation. The omission of processes accounting for ecohydrologic separation in standard applications of hydrological models is expected to influence estimates of water residence times and plant water availability. However, few studies have tested this expectation or investigated how ecohydrologic separation alters interpretations of stores and fluxes of water within a catchment. In this study, we compare two rainfall‐runoff models that integrate catchment‐scale representations of transport, one that incorporates ecohydrologic separation and one that does not. The models were developed for a second‐order watershed at the H.J. Andrews Experimental Forest (Oregon, USA), the site where ecohydrologic separation was first observed, and calibrated against multiple years of stream discharge and chloride concentration. Model structural variations caused mixed results for differences in calibrated parameters and differences in storage between reservoirs. However, large differences in catchment storage volumes and fluxes arise when considering only mobile water. These changes influence interpreted residence times for streamflow‐generating water, demonstrating the importance of ecohydrologic separation in catchment‐scale water and solute transport.     

Changes in streamflow regimes and their responses to different soil and water conservation measures in the Loess Plateau watersheds,China

Investigating the changes in streamflow regimes in response to various influencing factors contributes to our understanding of the mechanisms of hydrological processes in different watersheds and to water resource management strategies. This study examined streamflow regime changes by applying the indicators of hydrologic alteration method and eco-flow metrics to daily runoff data (1965–2016) from the Sandu, Hulu and Dali Rivers on the Chinese Loess Plateau, and then determined their responses to terracing, afforestation and damming. The Budyko water balance equation and the double mass curve method were used to separate the impacts of climate change and human activities on the mean discharge changes. The results showed that the terraced and dammed watersheds exhibited significant decreases in annual runoff. All hydrologic metrics indicated that the highest degree of hydrologic alteration was in the Sandu River watershed (terraced), where the monthly and extreme flows reduced significantly. In contrast, the annual eco-deficit increased significantly, indicating the highest reduction in streamflow among the three watersheds. The regulation of dams and reservoirs in the Dali River watershed has altered the flow regime, and obvious decreases in the maximum flow and slight increases in the minimum flow and baseflow indices were observed. In the Hulu River watershed (afforested), the monthly flow and extreme flows decreased slightly and were categorized as low-degree alteration, indicating that the long-term delayed effects of afforestation on hydrological processes. The magnitude of the eco-flow metrics varied with the alteration of annual precipitation. Climate change contributed 67.47% to the runoff reduction in the Hulu River watershed, while human activities played predominant roles in reducing runoff in the Sandu and Dali River watersheds. The findings revealed distinct patterns and causes of streamflow regime alteration due to different conservation measures, emphasizing the need to optimize the spatial allocation of measures to control soil erosion and utilize water resources on the Loess Plateau.     

Role of reservoir regulation and groundwater feedback in a simulated ground-soil-vegetation continuum: A long-term regional scale analysis

The regional terrestrial water cycle is strongly altered by human activities. Among them, reservoir regulation is a way to spatially and temporally allocate water resources in a basin for multi-purposes. However, it is still not sufficiently understood how reservoir regulation modifies the regional terrestrial- and subsequently, the atmospheric water cycle. To address this question, the representation of reservoir regulation into the terrestrial component of fully coupled regional Earth system models is required. In this study, an existing process-based reservoir network module is implemented into NOAH-HMS, that is, the terrestrial component of an atmospheric–hydrologic modelling system, namely, the WRF-HMS. It allows to quantitatively differentiate role of reservoir regulation and of groundwater feedback in a simulated ground-soil-vegetation continuum. Our study focuses on the Poyang Lake basin, where the largest freshwater lake of China and reservoirs of different sizes are located. As compared to streamflow observations, the newly extended NOAH-HMS slightly improves the streamflow and streamflow duration curves simulation for the Poyang Lake basin for the period 1979–1986. The inclusion of reservoir regulation leads to major changes in the simulated groundwater recharges and evaporation from reservoirs at local scale, but has minor effects on the simulated soil moisture and surface runoff at basin scale. The performed groundwater feedback sensitivity analysis shows that the strength of the groundwater feedback is not altered by the consideration of reservoir regulation. Furthermore, both reservoir regulation and groundwater feedback modify the partitioning of the simulated evapotranspiration, thus affecting the atmospheric water cycle in the Poyang Lake region. This finding motivates future research with our extended fully coupled atmospheric–hydrologic modelling system by the community.     

A comprehensive assessment framework for attributing trends in streamflow and groundwater storage to climatic and anthropogenic changes: A case study in the typical semi-arid catchments of southern India

The clearest signs of hydrologic change can be observed from the trends in streamflow and groundwater levels in a catchment. During 1980–2007, significant declines in streamflow (−3.03 mm/year) and groundwater levels (−0.22 m/year) were observed in Himayat Sagar (HS) catchment, India. We examined the degree to which hydrologic changes observed in the HS catchment can be attributed to various internal and external drivers of change (climatic and anthropogenic changes). This study used an investigative approach to attribute hydrologic changes. First, it involves to develop a model and test its ability to predict hydrologic trends in a catchment that has undergone significant changes. Second, it examines the relative importance of different causes of change on the hydrologic response. The analysis was carried out using Modified Soil and Water Assessment Tool (SWAT), a semi-distributed rainfall-runoff model coupled with a lumped groundwater model for each sub- catchment. The model results indicated that the decline in potential evapotranspiration (PET) appears to be partially offset by a significant response to changes in rainfall. Measures that enhance recharge, such as watershed hydrological structures, have had limited success in terms of reducing impacts on the catchment-scale water balance. Groundwater storage has declined at a rate of 5 mm/y due to impact of land use changes and this was replaced by a net addition of 2 mm/y by hydrological structures. The impact of land use change on streamflow is an order of magnitude larger than the impact of hydrological structures and about is 2.5 times higher in terms of groundwater impact. Model results indicate that both exogenous and endogenous changes can have large impacts on catchment hydrology and should be considered together. The proposed comprehensive framework and approach demonstrated here is valuable in attributing trends in streamflow and groundwater levels to catchment climatic and anthropogenic changes.     

Concentration–discharge relationships reflect chemostatic characteristics of US catchments

Concentration–discharge relationships have been widely used as clues to the hydrochemical processes that control runoff chemistry. Here we examine concentration–discharge relationships for solutes produced primarily by mineral weathering in 59 geochemically diverse US catchments. We show that these catchments exhibit nearly chemostatic behaviour; their stream concentrations of weathering products such as Ca, Mg, Na, and Si typically vary by factors of only 3 to 20 while discharge varies by several orders of magnitude. Similar patterns are observed at the inter‐annual time scale. This behaviour implies that solute concentrations in stream water are not determined by simple dilution of a fixed solute flux by a variable flux of water, and that rates of solute production and/or mobilization must be nearly proportional to water fluxes, both on storm and inter‐annual timescales. We compared these catchments' concentration–discharge relationships to the predictions of several simple hydrological and geochemical models. Most of these models can be forced to approximately fit the observed concentration–discharge relationships, but often only by assuming unrealistic or internally inconsistent parameter values. We propose a new model that also fits the data and may be more robust. We suggest possible tests of the new model for future studies. The relative stability of concentration under widely varying discharge may help make aquatic environments habitable. It also implies that fluxes of weathering solutes in streams, and thus fluxes of alkalinity to the oceans, are determined primarily by water fluxes. Thus, hydrology may be a major driver of the ocean‐alkalinity feedback regulating climate change. Copyright © 2009 John Wiley & Sons, Ltd.     

Concentration–discharge relationships describe solute and sediment mobilization,reaction, and transport at event and longer timescales

Concentration–discharge (C‐Q) relationships reflect material sources, storage, reaction, proximity, and transport in catchments. Differences in hydrologic pathways and connectivity influence observed C‐Q patterns at the catchment outlet. We examined solute and sediment C‐Q relationships at event and interannual timescales in a small mid‐Atlantic (USA) catchment. We found systematic differences in the C‐Q behaviour of geogenic/exogenous solutes (e.g., calcium and nitrate), biologically associated solutes (e.g., dissolved organic carbon), and particulate materials (e.g., total suspended solids). Negative log(C)–log(Q) regression slopes, indicating dilution, were common for geogenic solutes whereas positive slopes, indicating concentration increase, were common for biologically associated solutes. Biologically associated solutes often exhibited counterclockwise hysteresis during events whereas geogenic solutes exhibited clockwise hysteresis. Across event and interannual timescales, solute C‐Q patterns are linked to the spatial distribution of hydrologic sources and the timing and sequence of hydro‐biogeochemical source contributions to the stream. Groundwater is the primary source of stormflow during the earliest and latest stages of events, whereas precipitation and soil water become increasingly connected to the stream near peakflow. This sequence and timing of flowpath connectivity results in dilution and clockwise hysteresis for geogenic/exogenous solutes and concentration increase and counterclockwise hysteresis for biologically associated solutes. Particulate materials demonstrated positive C‐Q slopes over the long‐term and clockwise hysteresis during individual events. Drivers of particulate and solute C‐Q relationships differ, based on longitudinal and lateral expansion of active channels and changing shear stresses with increasing flows. Although important distinctions exist between the drivers of solute and sediment C‐Q relationships, overall solute and sediment C‐Q patterns at event and interannual timescales reflect consistent catchment hydro‐biogeochemical processes.     

Aspect control of water movement on hillslopes near the rain–snow transition of the Colorado Front Range

In the Colorado Front Range, forested catchments near the rain–snow transition are likely to experience changes in snowmelt delivery and subsurface water transport with climate warming and associated shifts in precipitation patterns. Snowpack dynamics are strongly affected by aspect: Lodgepole pine forested north‐facing slopes develop a seasonal snowpack, whereas Ponderosa pine‐dotted south‐facing slopes experience intermittent snow accumulation throughout winter and spring. We tested the degree to which these contrasting water input patterns cause different near‐surface hydrologic response on north‐facing and south‐facing hillslopes during the snowmelt period. During spring snowmelt, we applied lithium bromide (LiBr) tracer to instrumented plots along a north–south catchment transect. Bromide broke through immediately at 10‐ and 30‐cm depths on the north‐facing slope and was transported out of soil waters within 40 days. On the south‐facing slope, Br^? was transported to significant depths only during spring storms and remained above the detection limit throughout the study. Modelling of unsaturated zone hydrologic response using Hydrus‐1D corroborated these aspect‐driven differences in subsurface transport. Our multiple lines of evidence suggest that north‐facing slopes are dominated by connected flow through the soil matrix, whereas south‐facing slope soils experience brief periods of rapid vertical transport following snowmelt events and are drier overall than north‐facing slopes. These differences in hydrologic response were largely a function of energy‐driven differences in water supply, emphasizing the importance of aspect and climate forcing when considering contributions of water and solutes to streamflow in catchments near the snow line. Copyright © 2012 John Wiley & Sons, Ltd.     

Enhancing hydrologic modelling through the representation of traditional rainwater harvesting systems: A case study of water tanks in South India

Water tanks as traditional rainwater harvesting systems for agriculture are widely distributed in South India. They have a strong impact on hydrological processes, affecting streamflow in rivers as well as evapotranspiration. This study aims at an accurate representation of water harvesting systems in a hydrologic model to improve model performance and assessment of the catchment water balance. To this end, spatio-temporal variations of water bodies between the years 2016 and 2018 and the months of January and May 2017 were derived from Sentinel-2 satellite data to parameterize the water tanks (reservoir) parameters in the Soil and Water Assessment Tool (SWAT+) model of the Adyar basin, Chennai, India. Approximately 16% of the basin is covered by water tanks. The initial model performance was evaluated for two model setups, with and without water tanks. The best model run was selected with a multi-metric approach comparing observed and modelled monthly streamflow for 5000 model runs. The final model evaluation was carried out by comparing estimated water body areas by the model and remote sensing observations for January to May 2017. The results showed that representing water tanks in the hydrologic model led to an improvement in the representation of the seasonal variations of streamflow for the whole simulation period (2004–2018). The model performance was classified as good and very good for the calibration (2004–2011) and validation (2012–2018) periods as NSE varies between 0.67 and 0.85, KGE varies between 0.65 and 0.72, PBIAS varies between −24.1 and −23.6, and RSR varies between 0.57 and 0.39. The best fit was shown for the high and middle flow segments of the hydrograph where the coefficient of determination (R²) ranges from 0.81 to 0.97 and 0.75 to 0.81, respectively. The monthly variation of water body areas in 2017 estimated by the hydrologic model was consistent with changes observed in remote sensing surveys. In summary, the water tank parametrization using remote sensing techniques enhanced the hydrologic model's efficiency and applicability for future studies.     

Evaluation of basin storage–discharge sensitivity in Taiwan using low‐flow recession analysis

Sensitivity analysis of the hydrological behaviour of basins has mainly focused on the correlation between streamflow and climate, ignoring the uncertainty of future climate and not utilizing complex hydrological models. However, groundwater storage is affected by climatic change and human activities. The streamflow of many basins is primarily sourced from the natural discharge of aquifers in upstream regions. The correlation between streamflow and groundwater storage has not been thoroughly discussed. In this study, the storage–discharge sensitivity of 22 basins in Taiwan was investigated by means of daily streamflow and rainfall data obtained over more than 30 years. The relationship between storage and discharge variance was evaluated using low‐flow recession analysis and a water balance equation that ignores the influence of rainfall and evapotranspiration. Based on the obtained storage–discharge sensitivity, this study explored whether the water storage and discharge behaviour of the studied basins is susceptible to climate change or human activities and discusses the regional differences in storage–discharge sensitivity. The results showed that the average storage–discharge sensitivities were 0.056 and 0.162 mm^?1 in the northern and southern regions of Taiwan, respectively. In the central and eastern regions, the values were both 0.020 mm^?1. The storage–discharge sensitivity was very high in the southern region. The regional differences in storage–discharge sensitivity with similar climate conditions are primarily due to differences in aquifer properties. Based on the recession curve, other factors responsible for these differences include land utilization, land coverage, and rainfall patterns during dry and wet seasons. These factors lead to differences in groundwater recharge and thus to regional differences in storage–discharge sensitivity.     

Modelling the potential impacts of groundwater hydrology on long‐term drainage basin evolution

Fluvial erosion processes are driven by water discharge on the land surface, which is produced by surface runoff and groundwater discharge. Although groundwater is often neglected in long‐term landscape evolution problems, water table levels control patterns of Dunne runoff production, and groundwater discharge can contribute significantly to storm flows. In this analysis, we investigate the role that groundwater movement plays in long‐term drainage basin evolution by modifying a widely used landscape evolution model to include a more detailed representation of basin hydrology. Precipitation is generated by a stochastic process, and the precipitation is partitioned between surface runoff and groundwater recharge using a specified infiltration capacity. Groundwater flow is simulated by a dynamic two‐dimensional Dupuit equation for an unconfined aquifer with an irregular underlying impervious layer. The model is applied to the WE‐38 basin, an experimental catchment in Pennsylvania, because 60–80 per cent of the discharge is derived from groundwater and substantial hydrologic and geomorphic information is available. The hydrologic model is first calibrated to match the observed streamflows, and then the combined hydrologic/geomorphic model is used to simulate scenarios with different infiltration capacities. The results of this modelling exercise indicate that the basin can be divided into three zones with distinct streamflow‐generating characteristics, and different parts of the basin can have different geomorphic effective events. Over long periods of time, scenarios in which groundwater discharge is large tend to modify the topography in a way that promotes groundwater discharge and inhibits Dunne runoff. Copyright © 2006 John Wiley & Sons, Ltd.     

Sensitivity of streamflow simulation in the Delaware River Basin to forecasted land‐cover change for 2030 and 2060

In order to simulate the potential effect of forecasted land‐cover change on streamflow and water availability, there has to be confidence that the hydrologic model used is sensitive to small changes in land cover (<10%) and that this land‐cover change exceeds the inherent uncertainty in forecasted conditions. To investigate this, a 26‐year streamflow record was simulated for 33 basins (54–928 km²) in the Delaware River Basin using three dates of land cover: the 2011 National Land‐Cover Dataset (Homer, Fry, & Barnes, 2012 ), 2030 land‐cover conditions representing median values from 101 equally‐likely forecasts, and 2060 land‐cover conditions corresponding to the same iterations used to represent 2030. Streamflow was simulated using a process‐based hydrologic model that includes both pervious and impervious methods as parameterized by three land‐cover‐based hydrologic response units (HRUs)—forested, agricultural, and developed land. Small, but significant differences in streamflow magnitude, variability, and seasonality were seen among the three time periods—2011, 2030, and 2060. Temporal differences were discernible from the range of conditions simulated with 101 equally likely forecasts for 2030. Development was co‐located with the most frequent landscape components, as characterized by topographic wetness index, resulting in a change in hydrology for each HRU, highlighting that knowing the location of disturbance is key to understanding potential streamflow changes. These results show that streamflow simulation using regional calibration that incorporates land‐cover‐based HRUs can be sensitive to relatively small changes in land‐cover and that temporal trends resulting from land‐cover change can be isolated in order to evaluate other changes that might affect water resources.